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River water heat pumps to decarbonise district heating and promote the resilience of hydrosystems: Technico-economic, environmental and sociological challenges 利用河水热泵实现区域供热的低碳化并提高水系的复原力:技术经济、环境和社会学挑战
IF 8 Q1 ENERGY & FUELS Pub Date : 2024-09-12 DOI: 10.1016/j.nexus.2024.100325

The interdependence between water and energy (water-energy nexus) has been identified as one of the major challenges at European level, with roadmaps calling for the development of integrated approaches in this sector. The increase in river temperature is at the heart of this nexus, with anthropogenic thermal pollution adding to the effect of global warming. River Water Heat Pumps can play a major role by decarbonising district heating network (DHN) while actively cooling the aquatic resource. Hence, the objective of this short communication is to identify the scientific challenges to be met and the progress to be achieved considering the current state of the art. To illustrate the point, a rapid evaluation of the potential is performed for the city of Lyon in France resulting in an achievable cooling of 1.5 K which is above the minimum threshold to see an effect on aquatic ecosystem while the CO2 savings are significant for the DHN ( divided by a factor of 10). Because of its holistic nature, the impact assessment of such a system implies considering a wide diversity of indicators: energy, environmental, economics and sociological that need to be appropriately defined and quantified. In each field, progress beyond the state of the art to be performed has been identified, e.g. 4E analysis, cold water plume dispersion, integration of biodiversity in LCA.

水与能源之间的相互依存关系(水-能源关系)已被确定为欧洲面临的主要挑战之一,路线图呼吁在这一领域制定综合方法。河流温度的升高是这一关系的核心,人为热污染加剧了全球变暖的影响。河水热泵可以发挥重要作用,在积极冷却水资源的同时,实现区域供热网络(DHN)的低碳化。因此,这篇短文的目的是根据目前的技术水平,确定需要应对的科学挑战和需要取得的进展。为了说明这一点,我们对法国里昂市的潜力进行了快速评估,结果显示可实现的降温幅度为 1.5 K,高于对水生生态系统产生影响的最低阈值,同时 DHN 可显著减少二氧化碳排放量(∼除以 10 倍)。由于该系统的整体性,对其影响的评估需要考虑能源、环境、经济和社会学等多方面的指标,并对其进行适当的定义和量化。在每个领域,都已确定了在现有技术基础上取得的进展,如 4E 分析、冷水羽流扩散、将生物多样性纳入生命周期评估等。
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引用次数: 0
State-of-the-art-solar energy-driven adsorption desalination systems 最先进的太阳能驱动吸附式海水淡化系统
IF 8 Q1 ENERGY & FUELS Pub Date : 2024-08-08 DOI: 10.1016/j.nexus.2024.100319

The present work presents a literature review of solar-driven adsorption desalination systems (ADS) from the perspective of hybrid systems, adsorption materials, and system configurations. The evaluation criteria were based on the daily water production rate (SDWP), gain output ratio, coefficient of performance (COP), and the specific cooling power (SCP) of the dual-cooling and desalination systems. Recommendations for effective systems that require further research and development to increase water productivity and enhance system performance are also mentioned. First, concerning hybrid systems, adding an ejector to the adsorption desalination cycle showed a significant improvement in SDWP, reaching 40 m3/ton per day (TPD). In comparison, using two ejectors in the ADS integrated with HDH reached 83.1 m3/TPD at a cost estimated at 1.49 $/m3. Secondly, concerning system configurations, a wire wound finned tube heat exchanger of ADS achieved high performance. The SDWP, SCP, and COP were 23.5 m3/TPD, 682 W/kg, and 0.32, respectively. Thirdly, concerning adsorption materials, the results showed promising adsorbent materials in the range of solar energy temperatures, and on top of them was sodium polyacrylate (SP)/CaCl2, where SDWP and COP were about 45 m3/TPD and 0.67, respectively, while the cost was estimated at 3.8 $/m3. Finally, it was recommended to introduce 2D adsorbents to improve the adsorption properties and heat exchangers with 3D structures to improve the overall heat transfer coefficient of ADS.

本研究从混合系统、吸附材料和系统配置的角度对太阳能驱动的吸附海水淡化系统(ADS)进行了文献综述。评估标准基于双冷却和海水淡化系统的日产水率(SDWP)、增益产出比、性能系数(COP)和比冷却功率(SCP)。此外,还对需要进一步研究和开发的有效系统提出了建议,以提高水生产率和系统性能。首先,关于混合系统,在吸附脱盐循环中增加一个喷射器可显著提高 SDWP,达到每天 40 立方米/吨(TPD)。相比之下,在与 HDH 相结合的 ADS 中使用两个喷射器,可达到 83.1 立方米/吨/日,成本估计为 1.49 美元/立方米。其次,在系统配置方面,ADS 的绕线翅片管换热器实现了高性能。其 SDWP、SCP 和 COP 分别为 23.5 m3/TPD、682 W/kg 和 0.32。第三,在吸附材料方面,研究结果表明,在太阳能温度范围内,吸附材料是有前途的,其中最重要的是聚丙烯酸钠(SP)/氯化钙,其 SDWP 和 COP 分别约为 45 m3/TPD 和 0.67,而成本估计为 3.8 美元/m3。最后,建议采用二维吸附剂来提高吸附性能,并采用三维结构的热交换器来提高 ADS 的整体传热系数。
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引用次数: 0
Metamodeling life cycle assessment to explore interactions in the water-energy nexus of desalination processes 元模型生命周期评估,探索海水淡化过程中水与能源之间的相互作用
IF 8 Q1 ENERGY & FUELS Pub Date : 2024-08-03 DOI: 10.1016/j.nexus.2024.100321

The relationships within the Energy-Water nexus are inherently complex, necessitating sophisticated methods to optimize and manage these interactions effectively. Metamodeling emerges as a crucial technique in abstracting these complex relationships into a manageable analytical form. This study adopts a systematic approach to construct Life Cycle Assessment (LCA) metamodels, aimed at examining the interactions within the water-energy nexus of various desalination technologies. A critical aspect of the developed methodology is the selection of sampling points that align with LCA scenarios through a tailored designed experiment (DoE) model. These scenarios, which include Reverse Osmosis (RO), Electrodialysis (ED), and Multi-Effect Distillation (MED), are evaluated using a set of indicators the Energy-Water nexus, across tradeoff nexus policies. The results signify the impact of considering the Energy-Water Nexus on optimizing desalination processes, compared to evaluating energy and water metrics independently. In policies where nexus considerations were not integrated—focusing solely on cumulative energy or exclusively on water footprint—the RO with Wind Turbine (RO[WT]) scenario emerged as the optimal solution. This configuration consumed 7.540 MJ and 1.654 m³ of water and a carbon footprint of 0.719 kg CO2eq per cubic meter of desalinated water. Conversely, policies that incorporate a nexus approach favor the adoption of MED with Thermal Solar (MED[TS]) scenario. Characterized by its moderate energy consumption of 2.226 MJ, and a water footprint of 2.226 m³, per cubic meter. These findings illustrate the critical role of employing Energy-Water Nexus frameworks through metamodeling in minimizing the environmental impacts associated with desalination processes.

能源与水之间的关系本身就很复杂,因此需要复杂的方法来优化和有效管理这些互动关系。元模型是将这些复杂关系抽象为可管理的分析形式的关键技术。本研究采用系统方法构建生命周期评估(LCA)元模型,旨在研究各种海水淡化技术在水与能源关系中的相互作用。所开发方法的一个关键方面是通过量身定制的设计实验(DoE)模型,选择与生命周期评估方案相一致的采样点。这些方案包括反渗透 (RO)、电渗析 (ED) 和多效蒸馏 (MED),使用一套能源-水关系指标和权衡关系政策对其进行评估。结果表明,与单独评估能源和水指标相比,考虑能源-水关系对优化海水淡化工艺的影响更大。在未综合考虑能源与水关系的政策中--仅关注累积能源或仅关注水足迹--带风力涡轮机的反渗透(RO[WT])方案成为最佳解决方案。这种配置消耗 7.540 兆焦耳和 1.654 立方米水,每立方米淡化水的碳足迹为 0.719 千克二氧化碳当量。相反,采用关联方法的政策有利于采用热太阳能 MED(MED[TS])方案。其特点是能耗适中,为 2.226 兆焦耳,每立方米水足迹为 2.226 立方米。这些研究结果表明,通过元建模采用能源-水关联框架在最大限度地减少与海水淡化工艺相关的环境影响方面发挥着至关重要的作用。
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引用次数: 0
Recent advances in magnetic solid catalysts: Synthesis, stabilization and application in cleaner production of biodiesel 磁性固体催化剂的最新进展:生物柴油清洁生产中的合成、稳定和应用
IF 8 Q1 ENERGY & FUELS Pub Date : 2024-08-02 DOI: 10.1016/j.nexus.2024.100318

Biodiesel is generally obtained by transesterification and esterification of appropriate feedstocks facilitated by a catalyst. It has emerged to be one of the most potential alternatives for the conventional fuels gaining worldwide attention. Heterogeneous catalysts are usually preferred than homogeneous for biodiesel synthesis due to facile separation and insignificant soap formation. However, the separation still possesses difficulty leading to mass transfer hindrance. Therefore, these catalysts can be further modified using magnetic separation techniques to develop magnetically separable catalysts. The magnetic nanoparticles (MNPs) are notable appealing catalysts due to huge surface area, high activity, amicable functional groups and structures, adaptable properties, conformity in pore size, and facile separation have made them desirable catalyst carriers for biodiesel synthesis. The MNPs are modified via functionalization to construct magnetically recoverable heterogeneous nanocatalysts. Magnetic catalysts can be utilized as a befitting option for biodiesel synthesis as these are environmentally benign, highly reusable and economically viable. The current review article discusses different magnetic solid catalysts such as magnetic base, acid, biocatalysts and bifunctional of acid base catalysts for efficient biodiesel synthesis. The prime focus of this paper rest on the catalytic performances of various magnetically recoverable catalysts, mechanisms and recyclability for biodiesel production processes. The synthesis methods of magnetic heterogeneous base and acid nanocatalysts, magnetic properties, functionalization and their reciprocity on the catalytic activity are reviewed in this article.

生物柴油一般是在催化剂的作用下,通过适当原料的酯交换和酯化反应获得的。它已成为传统燃料最有潜力的替代品之一,受到全世界的关注。在生物柴油合成过程中,异相催化剂通常比均相催化剂更受青睐,因为异相催化剂易于分离,且不易形成肥皂。然而,分离仍然存在困难,导致传质受阻。因此,可以利用磁分离技术对这些催化剂进行进一步改良,开发出磁可分离催化剂。磁性纳米颗粒(MNPs)具有巨大的比表面积、高活性、友好的官能团和结构、适应性强、孔径大小一致以及易于分离等特点,是一种极具吸引力的催化剂,使其成为合成生物柴油的理想催化剂载体。通过对 MNPs 进行功能化改性,可构建磁性可回收的异质纳米催化剂。磁性催化剂可作为生物柴油合成的合适选择,因为这些催化剂对环境无害、可重复使用且经济可行。本综述文章讨论了不同的磁性固体催化剂,如用于高效生物柴油合成的磁性碱催化剂、酸催化剂、生物催化剂和双功能酸碱催化剂。本文的重点在于各种磁性可回收催化剂在生物柴油生产过程中的催化性能、机理和可回收性。本文综述了磁性异质碱和酸纳米催化剂的合成方法、磁性能、官能化及其对催化活性的相互影响。
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引用次数: 0
Harnessing sound waves for sustainable energy: Advancements and challenges in thermoacoustic technology 利用声波实现可持续能源:热声技术的进步与挑战
IF 8 Q1 ENERGY & FUELS Pub Date : 2024-07-30 DOI: 10.1016/j.nexus.2024.100320

In the face of urgent global environmental challenges, the pursuit of sustainable technologies has become of utmost importance. Thermoacoustic technology has emerged as a promising energy conversion method with potential applications in various domains such as power generation, waste heat recovery, refrigeration, and air conditioning. This technology harnesses the thermodynamic properties of sound waves to convert heat into work or create cooling effects, offering simplicity, reliability, and environmental friendliness. Thermoacoustic devices, including refrigerators and engines, offer a low-carbon alternative to conventional power and refrigeration systems. With minimal mechanical components and no moving parts, they boast durability, easy maintenance, and reduced susceptibility to breakdowns. Despite the advantages, thermoacoustic technology currently faces challenges such as lower efficiency compared to traditional technologies. To achieve efficient performance, these devices depend on a comprehensive understanding of complex flow physics, which encompasses the transient nature of phenomena and the conversion of thermal and acoustic energies. This work provides a comprehensive overview of recent advancements in thermoacoustic technology, specifically emphasizing prime movers and refrigerators. We present insights into the working mechanisms and performance-affecting parameters of these devices, while discussing future research prospects and obstacles to commercial implementation. This review highlights the need for a deeper understanding of thermoacoustic system mechanisms, with a focus on addressing efficiency and scalability challenges. To make thermoacoustic systems more practical, research endeavors should concentrate on unraveling nonlinear phenomena, developing nonlinear thermoacoustics, and advancing transduction systems, system design, and component optimization. Innovative design strategies, beyond traditional multi-stage and phase-change approaches, along with exploration of alternative energy sources, hold the key to significantly improving overall thermoacoustic system performance, ensuring the continual evolution and prosperity of the field in the decades ahead.

面对紧迫的全球环境挑战,追求可持续发展技术已变得至关重要。热声技术已成为一种前景广阔的能源转换方法,有望应用于发电、废热回收、制冷和空调等多个领域。该技术利用声波的热力学特性将热量转化为功或产生冷却效果,具有简单、可靠和环保的特点。包括冰箱和发动机在内的热声设备是传统动力和制冷系统的低碳替代品。它们的机械部件最少,没有活动部件,因此经久耐用、易于维护,而且不易发生故障。尽管具有这些优势,热声技术目前仍面临着一些挑战,例如与传统技术相比效率较低。要实现高效性能,这些设备有赖于对复杂流动物理学的全面理解,其中包括现象的瞬态性质以及热能和声能的转换。本研究全面概述了热声技术的最新进展,特别强调了原动机和制冷机。我们深入探讨了这些设备的工作机制和影响性能的参数,同时讨论了未来的研究前景和商业实施的障碍。本综述强调了深入了解热声系统机制的必要性,重点是解决效率和可扩展性方面的挑战。为使热声系统更加实用,研究工作应集中于揭示非线性现象、开发非线性热声学、推进传导系统、系统设计和组件优化。除了传统的多级和相变方法之外,创新的设计策略以及对替代能源的探索,是大幅提高热声系统整体性能的关键,可确保该领域在未来几十年中不断发展和繁荣。
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引用次数: 0
Photocatalytic degradation of methamidophos in water using zinc oxide as a photocatalyst 利用氧化锌作为光催化剂光催化降解水中的甲胺磷
IF 8 Q1 ENERGY & FUELS Pub Date : 2024-07-14 DOI: 10.1016/j.nexus.2024.100317

Conventional agriculture and the need to satisfy the demand for food, cause different types of pesticides to be used indiscriminately, causing them to be dispersed into ecosystems by wind and water currents, representing a serious environmental problem. For this reason, it is important to apply effective technologies for the elimination of pesticides from water bodies. In the present research, heterogeneous photocatalysis using ZnO as a photocatalyst was applied to evaluate the degradation of methamidophos in contaminated water prepared in ultrapure water and river water. Considering the working parameters of 3 g/L of zinc oxide, a concentration of 50 mg/L of methamidophos, with constant agitation of 300 rpm, temperature 25 ± 2 °C and a natural pH, methamidophos degradation percentages of 86.66 % and 57.96 % were achieved in ultrapure water and river water, respectively. The chloride, sulfates, nitrates, and nitrites anions present in the river water could be responsible for the decrease in the effectiveness of the photocatalytic process. The mathematical models that best describe the degradation process were the pseudo-second order model and the Elovich model.

传统农业和满足粮食需求的需要导致各种杀虫剂的滥用,使其随风和水流散布到生态系统中,造成严重的环境问题。因此,应用有效的技术消除水体中的农药非常重要。在本研究中,以氧化锌为光催化剂的异相光催化技术被用于评估甲胺磷在超纯水和河水制备的污染水中的降解情况。在氧化锌用量为 3 g/L、甲胺磷浓度为 50 mg/L、搅拌转速为 300 rpm、温度为 25 ± 2 °C、pH 值为自然条件下,超纯水和河水中甲胺磷的降解率分别为 86.66 % 和 57.96 %。河水中存在的氯化物、硫酸盐、硝酸盐和亚硝酸盐阴离子可能是导致光催化过程效果下降的原因。最能描述降解过程的数学模型是伪二阶模型和埃洛维奇模型。
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引用次数: 0
The development of fishery-photovoltaic complementary industry and the studies on its environmental, ecological and economic effects in China: A review 中国渔光互补产业的发展及其环境、生态和经济效应研究:综述
IF 8 Q1 ENERGY & FUELS Pub Date : 2024-07-02 DOI: 10.1016/j.nexus.2024.100316
Zihao Zhu , Zijie Song , Sihan Xu , Shoubing Wang , Xingyu Chen , Yongshuang Wang , Zhenhua Zhu

The fishery-photovoltaic complementary industry is an emerging industrial model in China that integrates aquaculture with the solar industry. This innovative model involves conducting aquaculture activities while installing photovoltaic modules on the water surface to harness solar energy for electricity generation. However, despite its rapid growth in China, this model lacks substantial scientific data support across various domains. Therefore, based on an analysis of relevant research literature, this study reviews the current development status, environmental and economic effects, as well as challenges faced by the fishery-photovoltaic complementary industry in China. The aim is to provide scientific references for promoting sustainable development within this sector. The findings reveal that existing fishery-photovoltaic complementary industry projects are primarily concentrated in the middle and lower reaches of the Yangtze River and Pearl River Basin. The geographical distribution of these projects is predominantly influenced by local aquaculture areas and available solar energy resources, with a greater impact observed from the former rather than the latter. During summer months when water is shaded by photovoltaic panels, a slight decrease in the average water quality parameters across cases was observed, such as a decrease of 0.2 units in pH, a decrease of 1.06 °C in water temperature, a decrease in dissolved oxygen levels of 0.8 mg/L, inorganic nitrogen content and total phosphorus concentration dropped by 0.08 mg/L and 0.02 mg/L respectively. Conversely, there is a moderate increase noted in total nitrogen and ammonia nitrogen levels. The conclusion of the effect on phytoplankton biomass is not uniform, but it will certainly reduce zooplankton biomass. The impact on the species diversity of the zooplankton community was minimal, and its direction, whether positive or negative, varied depending on the specific aquatic ecosystem. A certain degree of shade is advantageous for the cultivation of shade-loving fish. Through the strategic deployment of photovoltaic panels and the implementation of scientific stocking practices, it is possible to achieve sustained levels of fisheries production. This model also can reduce an average of 978.6 tons of CO2 emissions per megawatt per year through energy production, thus achieving the combined goals of energy conservation and emissions reduction, and ensuring the profitability of power generation. Additionally, compared with the land utilization area of 3.66 hm2 per megawatt of traditional ground-mounted photovoltaics, fishery-photovoltaic complementary only requires 1.64 hm2, which can significantly save land resources by utilizing water surfaces, which mitigates the conflict between land use for agriculture and renewable energy installations. At the same time, research also pointed out that the existence of fishery-photovoltaic complementary will inevitabl

渔光互补产业是中国将水产养殖与太阳能产业相结合的新兴产业模式。这种创新模式是在开展水产养殖活动的同时,在水面安装光伏组件,利用太阳能发电。然而,尽管这种模式在中国发展迅速,却缺乏各领域大量科学数据的支持。因此,本研究在分析相关研究文献的基础上,回顾了中国渔业与光伏互补产业的发展现状、环境和经济效应以及面临的挑战。目的是为促进该行业的可持续发展提供科学参考。研究结果表明,现有的渔光互补产业项目主要集中在长江中下游和珠江流域。这些项目的地理分布主要受当地水产养殖区和可用太阳能资源的影响,前者的影响大于后者。在夏季,当水体被光伏板遮挡时,各案例的平均水质参数略有下降,如 pH 值下降 0.2 个单位,水温下降 1.06 °C,溶解氧水平下降 0.8 毫克/升,无机氮含量和总磷浓度分别下降 0.08 毫克/升和 0.02 毫克/升。相反,总氮和氨氮的含量则略有增加。对浮游植物生物量的影响结论并不一致,但肯定会减少浮游动物的生物量。对浮游动物群落物种多样性的影响微乎其微,其方向是积极的还是消极的,因具体的水生生态系统而异。一定程度的遮荫有利于喜阴鱼类的养殖。通过战略性地部署光伏板和实施科学的放养方法,可以实现持续的渔业生产水平。这种模式还可以通过能源生产平均每年每兆瓦减少 978.6 吨二氧化碳排放,从而实现节能减排的综合目标,并确保发电的盈利性。此外,与传统地面光伏每兆瓦 3.66 hm2 的土地利用面积相比,渔光互补仅需 1.64 hm2,利用水面可大幅节约土地资源,缓解了农业用地与可再生能源设施的矛盾。同时,研究也指出,渔光互补的存在不可避免地会对鸟类群落产生一些负面影响。经济分析表明,虽然初期基础设施成本和较长的投资回收期构成了挑战,但总体经济可行性是有希望的,特别是在政府支持和技术进步的情况下。然而,要进一步发展,还需要应对几个挑战:包括与基础设施建设和初期成本相关的困难、投资回收期长;经验和技术支持不足;以及缺乏对生态和环境影响的研究--特别是迫切需要进行包括环境和经济两方面的综合生命周期评估。未来的研究应侧重于生命周期评估、改进光伏技术集成和优化水产养殖实践。
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引用次数: 0
The TIMES Land-WEF model: An integrated analysis of the agricultural system of the Basilicata Region (Southern Italy) TIMES 土地-WEF 模型:对巴西利卡塔大区(意大利南部)农业系统的综合分析
IF 8 Q1 ENERGY & FUELS Pub Date : 2024-07-02 DOI: 10.1016/j.nexus.2024.100315
Senatro Di Leo , Maria Maddalena Tortorella , Patricia Fortes , Mauro Viccaro , Mario Cozzi , Severino Romano , Carmelina Cosmi

The unsustainable use of natural resources, in particular soil degradation and pollution, is one of the main factors contributing to the climate and biodiversity crisis. The European Union has outlined a new European Green Deal, whose objectives include increasing the overall quality of the agri-food chain in relation to environmental sustainability, focusing on reducing the use of pesticides and increasing the share of organic in overall production. A Nexus thinking perspective is applied to analyse this topic over a 50-year time horizon (2010–2060) for the agricultural system of the Basilicata Region (Southern Italy), represented by the TIMES Land-WEF, an optimizing, bottom-up energy-technology model, built to investigate the interactions and interrelations between water, energy food and land. The novelty of this modelling approach is the choice of land use as the guiding parameter of the optimization process. The main objectives of the Farm to Fork Strategy are modelled as system constraints and the scenario analysis allows to characterise their effects on the evolution of the agricultural system over the examined time. The results show that the pesticide reduction constraint leads to an increase in land use by organic crops from 24.6 % to 32.4 % in 2060. In particular, this is due to the increased contribution of cereal, forage, olive growing crops, permanent meadows and pastures, which lead to a 46 % reduction in irrigation water consumption. On the other hand, the reduction in inorganic fertilizers is not accompanied by a significant increase in organic crops, but resulted in the reduction of cereal crops.

不可持续地使用自然资源,特别是土壤退化和污染,是造成气候和生物多样性危机的主要因素之一。欧盟提出了一项新的 "欧洲绿色协议",其目标包括提高农业食品链在环境可持续性方面的整体质量,重点是减少杀虫剂的使用和提高有机食品在整个生产中的比例。该模型是一个自下而上的优化能源技术模型,用于研究水、能源、粮食和土地之间的相互作用和相互关系。这种建模方法的新颖之处在于选择土地利用作为优化过程的指导参数。从农场到餐桌战略 "的主要目标被模拟为系统约束条件,通过情景分析可以确定这些约束条件对农业系统在所考察时间内的演变所产生的影响。结果表明,减少农药的约束条件导致有机作物的土地使用率从 24.6% 增加到 2060 年的 32.4%。这主要是由于谷物、饲料、橄榄种植作物、永久草地和牧场的使用量增加,导致灌溉用水量减少 46%。另一方面,无机肥料的减少并没有带来有机作物的显著增加,反而导致谷物作物的减少。
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引用次数: 0
Bioelectricity production and bioremediation potential of Withania somnifera in plant microbial fuel cells 植物微生物燃料电池中的薇甘菊生物发电和生物修复潜力
IF 8 Q1 ENERGY & FUELS Pub Date : 2024-06-24 DOI: 10.1016/j.nexus.2024.100314
Debajyoti Bose , Riya Bhattacharya , Pranathi Ganti , Alwiya Rizvi , Gopinath Halder , Arjun Sarkar

In p-MFCs living plants photosynthesize within a bio-electrochemical circuit. The plant exudes organic waste material from the roots. In the rhizosphere, bacteria consume these wastes by oxidizing them in contrast to the atmosphere that reduces it. This redox reaction along with photosynthesis can be harnessed as bioelectricity. In this work, the plant Withania somnifera (L.) Dunal was used for generating bioelectricity from the root exudates and organic matter available in the soil. An open circuit voltage of 930±21 mV was achieved between multiple cycles of operation. The cell voltage further increased to 1260±140 mV with enrichment in the form of discards from vegetable matter. The peak recorded voltage was 1400 mV. Graphite fibre felt electrodes ensured uniform microbial growth with power densities that were achieved at 57 mW/m2 and 84 mW/m2 with and without enrichment respectively. ATR-FTIR demonstrated complete degradation of specific compounds attached to the carbon matrix in the soil along with the polysaccharide content from the enrichments. Additionally, this work also monitored the changes in soil pH and its homogeneity, the impact of photosynthetically active radiation, humidity, and the presence of CO2 in the air, and how it affects plant growth and ultimately the microbes at the rhizosphere which accounted for the bioremediation and the resultant bioelectricity production. SEM imaging provided additional evidence that the presence of electrochemically active soil bacteria, an anaerobic environment, and electrode characteristics are crucial for the development of conductive biofilms.

在 p-MFC 中,活体植物在生物电化学回路中进行光合作用。植物从根部排出有机废料。在根瘤菌圈中,细菌通过氧化消耗这些废物,而大气则将其还原。这种氧化还原反应和光合作用可作为生物电加以利用。在这项研究中,利用植物 Withania somnifera (L.) Dunal 的根部渗出物和土壤中的有机物产生生物电。在多次循环操作之间,开路电压达到 930±21 mV。随着植物废弃物的富集,电池电压进一步增至 1260±140 mV。记录的峰值电压为 1400 mV。石墨纤维毡电极确保了微生物的均匀生长,在富集和未富集的情况下,功率密度分别达到 57 mW/m2 和 84 mW/m2。ATR-FTIR 显示,附着在土壤中碳基质上的特定化合物以及富集物中的多糖成分完全降解。此外,这项研究还监测了土壤 pH 值及其均匀性的变化,光合有效辐射、湿度和空气中二氧化碳含量的影响,以及这些因素如何影响植物生长,并最终影响根瘤层的微生物,从而实现生物修复和生物发电。扫描电子显微镜成像提供了更多证据,证明电化学活性土壤细菌的存在、厌氧环境和电极特性对导电生物膜的发展至关重要。
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引用次数: 0
An experimental study on the parthenium biosorbents for removals of chlorides and hardness from contaminated water 关于部分铼生物吸附剂去除受污染水中的氯化物和硬度的实验研究
IF 8 Pub Date : 2024-06-13 DOI: 10.1016/j.nexus.2024.100309
Subhashish Dey, Taraka Naga Veerendra Ganugula, Siva Shanmukha Anjaneya Babu Padavala, Venkata Phani Manoj Akula

Among the problems most severe for the environment is the pollution of aqueous solution, specifically the creation of threats connected to hazardous heavy metals. In some rural places, it is hardness and chlorides that make groundwater or surface water dangerous in terms of the level of toxins. The requirement of hardness and chlorides is influenced because, in large quantities, when it comes to the quality of drinking water, it causes disease. Water is hazardous to the eyes because of its alkaline nature, inhalation organs, and skin problems. The more hardness and chlorides and related irritations there are, the larger the share. A naturally occurring physiochemical mechanism called biosorption enables certain biomass to passively adsorb hardness and chlorides into the biomass's cellular structure. In the lab, five distinct biosorbents were created, including parthenium, rice husk, rapeseed straw, sawdust, and egg cells, in that order. The parthenium biosorbents turned out to be the most successful biosorbents, despite the fact that each biosorbents has a different level of effectiveness in eliminating hardness and chlorides from water. By using the plant based biomass of parthenium, 65 % of chloride removal with 80 % of hardness removal was obtained. Having identified the best biosorbents, we optimized their parameters and took water samples from different sources. In chlorides removal over parthenium biosorbents, the optima dosage of biosorbents is 3.8 g, temperature is 35 °C, pH is 7, contact time is 120 min and optima agitation speed is 120 rpm. In hardness removal over parthenium biosorbents, the optima dosage of biosorbent is 5.4 g, temperature is 35 °C, pH is 6.5, contact time is 90 min and agitation speed is 150 rpm. Once the chlorides and hardness ions are removed from the water by the utilized biosorbents, the biosorption process may be homo cost effective through the regeneration and reuse of the biosorbent.

最严重的环境问题之一是水溶液污染,特别是与有害重金属有关的威胁。在一些农村地区,硬度和氯化物会使地下水或地表水的毒素含量达到危险水平。对硬度和氯化物的要求受到影响,因为大量的硬度和氯化物会影响饮用水的质量,导致疾病。水的碱性会对眼睛、吸入器官和皮肤造成危害。硬度和氯化物越多,相关的刺激就越大。一种名为生物吸附的天然生化机制能使某些生物质被动地将硬度和氯化物吸附到生物质的细胞结构中。在实验室中,我们制作了五种不同的生物吸附剂,它们依次是蕨类植物、稻壳、油菜秸秆、锯末和卵细胞。尽管每种生物吸附剂在消除水中的硬度和氯化物方面都有不同程度的效果,但结果表明,偏苯胺生物吸附剂是最成功的生物吸附剂。通过使用以植物为基础的半边莲生物质,氯化物的去除率为 65%,硬度的去除率为 80%。在确定了最佳生物吸附剂后,我们对其参数进行了优化,并从不同水源采集了水样。在用鄣铼生物吸附剂去除氯化物时,最佳生物吸附剂用量为 3.8 克,温度为 35 °C,pH 值为 7,接触时间为 120 分钟,最佳搅拌速度为 120 转/分钟。在使用鄣铼生物吸附剂去除硬度时,生物吸附剂的最佳用量为 5.4 克,温度为 35 °C,pH 值为 6.5,接触时间为 90 分钟,搅拌速度为 150 转/分钟。利用生物吸附剂去除水中的氯离子和硬度离子后,生物吸附过程可通过生物吸附剂的再生和再利用实现成本效益。
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引用次数: 0
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Energy nexus
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