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Multivariate time series energy forecasting using a hybrid neural-SVM ensemble model: A data-driven approach for energy management in Bangladesh 使用混合神经-支持向量机集成模型的多元时间序列能源预测:孟加拉国能源管理的数据驱动方法
IF 9.5 Q1 ENERGY & FUELS Pub Date : 2026-01-10 DOI: 10.1016/j.nexus.2026.100641
Mohammad Mynul Islam Mahin, Md Jawad Bin Rouf, Shah Murtoza Morshed, Sheak Salman, Md Shihab Shakur, Mohammad Morshed, Md. Parvez
Energy forecasting of generation, demand, sources, and prices over short-time horizons is necessary for optimization of energy management. Given the increased use of developing technologies and reliance on renewable energy sources, strategic planning, management, and operational decision-making depend on accuracy and reliability of forecasting system. Complex interconnections reside among energy features in modern day power systems. Developing nations such as Bangladesh encounter challenges, including insufficient advanced tools for power planning and policy development. Previous studies have often focused on forecasting a single energy variable, like load or demand, with little attention on multiple energy parameters, and the interrelations among them. This study introduces a Hybrid Neural-SVM Ensemble (HNSE) model to simultaneously forecast day-ahead daily total energy generation, non-renewable energy generation, fuel cost, and evening peak demand of national grid of Bangladesh. Utilizing the Power Grid Company of Bangladesh’s (PGCB) data, HNSE went through processing and hyperparameter optimization. Performance evaluation based on five statistical indices demonstrated the model's predictive capabilities, with a coefficient of determination (R2) of 0.9744, and a mean squared error (MSE) of 0.0291. Additionally, the study utilizes the Kernel-based Changepoint Detection (KernelCPD) algorithm to detect structural shifts in residuals, and two explainable artificial intelligence (XAI) methods, Local Interpretable Model-Agnostic Explanations (LIME) and SHapley Additive exPlanations (SHAP), for feature contribution analysis to provide local and global interpretability. The aim is to offer actionable guidance for policymakers and stakeholders in mitigating current energy crises in Bangladesh through strategic decision-making and support the development of sustainable energy policies in emerging economies.
短期内的发电、需求、来源和价格预测是优化能源管理的必要条件。鉴于越来越多地使用发展中的技术和对可再生能源的依赖,战略规划、管理和业务决策取决于预测系统的准确性和可靠性。在现代电力系统中,复杂的互连存在于能源特征中。孟加拉国等发展中国家面临着挑战,包括缺乏先进的电力规划和政策制定工具。以往的研究往往侧重于预测单一的能源变量,如负荷或需求,很少关注多个能源参数及其相互关系。本文引入混合神经-支持向量机集成(HNSE)模型,对孟加拉国国家电网日前日总发电量、不可再生能源发电量、燃料成本和晚高峰需求进行同步预测。利用孟加拉国电网公司(PGCB)的数据,HNSE进行了处理和超参数优化。基于5个统计指标的绩效评价表明,模型具有较好的预测能力,决定系数(R2)为0.9744,均方误差(MSE)为0.0291。此外,该研究利用基于核的变化点检测(KernelCPD)算法检测残差的结构变化,并利用两种可解释的人工智能(XAI)方法,局部可解释模型不可知解释(LIME)和SHapley加性解释(SHAP)进行特征贡献分析,以提供局部和全局可解释性。其目的是为决策者和利益相关者提供可操作的指导,通过战略决策缓解孟加拉国当前的能源危机,并支持新兴经济体制定可持续能源政策。
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引用次数: 0
Study on the local electric field effect of electron transfer in straw-derived carbon microsphere-WO3 composite materials: Photocatalytic hydrogen production performance and mechanism under solar light 秸秆碳微球- wo3复合材料中电子转移的局域电场效应研究:太阳光照下光催化制氢性能及机理
IF 9.5 Q1 ENERGY & FUELS Pub Date : 2026-01-10 DOI: 10.1016/j.nexus.2026.100638
Zhou Yunlong , Sun Meng
Solar photocatalytic hydrogen production is an important technology for green hydrogen energy production. However, due to the limitation of the light absorption band of photocatalysts, the most commonly used catalysts are difficult to achieve efficient and stable photocatalysis under sunlight. Herein, a carbon microsphere-WO3 composite photocatalytic material was prepared by hydrothermal synthesis, which accelerated the directional transfer of photogenerated electrons. There is a strong local electric field effect in the carbon microsphere-WO3 composite photocatalytic material, promoting the directional transfer of electrons. Photogenerated carriers rapidly migrate from WO3 to the active sites on the surface of carbon microspheres, improving the kinetics of the photocatalytic H+ reduction reaction and accelerating the efficiency of solar photocatalytic hydrogen production. When the doping concentration of carbon microspheres is 30%, the photocatalytic hydrogen production rate of the composite material reaches 520 μmol·h-1·g-1, which is 32.5 times that of pure WO3. The carbon microsphere-WO3 composite photocatalytic material has superior photo-stability and recyclability. The experimental results reveal the reaction mechanism of the efficient catalysis of the composite material. This study opens up new prospects for the practical application of photocatalysts.
太阳能光催化制氢是绿色制氢的重要技术。然而,由于光催化剂的光吸收带的限制,最常用的催化剂在阳光下难以实现高效稳定的光催化。本文采用水热法制备了碳微球- wo3复合光催化材料,该材料加速了光生电子的定向转移。碳微球- wo3复合光催化材料中存在很强的局部电场效应,促进了电子的定向转移。光生载体从WO3快速迁移到碳微球表面的活性位点,提高了光催化H+还原反应的动力学,加快了太阳能光催化制氢的效率。当碳微球掺杂浓度为30%时,复合材料的光催化产氢速率达到520 μmol·h-1·g-1,是纯WO3的32.5倍。碳微球- wo3复合光催化材料具有良好的光稳定性和可回收性。实验结果揭示了复合材料高效催化的反应机理。本研究为光催化剂的实际应用开辟了新的前景。
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引用次数: 0
Optimal techno-economic and environmental assessment of a standalone solar-powered irrigation system in North Africa based on the nexus approach 基于联系方法的北非独立太阳能灌溉系统的最佳技术经济和环境评估
IF 9.5 Q1 ENERGY & FUELS Pub Date : 2026-01-10 DOI: 10.1016/j.nexus.2026.100640
Safa Slouma , Abdessami Soyed
This study deals with a first approach to exploit the Nexus Approach applied to PV-powered irrigation in North Africa—a region with high solar potential but water scarcity, such as Tunisia. Tunisia had faced an arid and very changeable climate, including significant decreases in annual rainfall (455 mm per year). This research focuses on a techno-economic, social and environmental assessment of a standalone solar-powered irrigation system (SPVWPS) in the Tunisian area, based on the Water-Energy-Food (WEF) Nexus approach. It proposes a holistic assessment framework that synthesizes these interconnected dimensions. The study assesses the system's optimal sizing, economic feasibility, and social and environmental benefits by employing an optimization framework that combines solar energy potential, crop water requirements, and cost-effectiveness. Via PVsyst software, the system's performance is simulated under varying climatic conditions, with sensitivity analyses conducted to evaluate the component costs’ impact, solar irradiance variations, and water demand shapes. Economic indicators such as Net Present Value are analyzed, while environmental benefits are quantified in terms of CO₂ emissions reduction compared to conventional diesel-powered systems. Results demonstrate that the proposed SPVWPS is economically feasible and significant reductions in greenhouse gas emissions avoid >3348.57 kg of CO2 per year. The nexus approach further highlights the system's potential to enhance water-use efficiency with an average exceeding 20 m³ per day and crop productivity. This average can irrigate up to 1.5 hectares of olive crops. Policy recommendations are provided to facilitate large-scale adoption, emphasizing the role of subsidies and technical training. This study contributes to offering a replicable model for similar arid regions in North Africa.
本研究探讨了将Nexus方法应用于北非光伏灌溉的第一种方法,该地区太阳能潜力巨大,但水资源短缺,如突尼斯。突尼斯面临干旱和非常多变的气候,包括年降雨量显著减少(每年455毫米)。这项研究的重点是对突尼斯地区基于水-能源-粮食(WEF) Nexus方法的独立太阳能灌溉系统(SPVWPS)进行技术经济、社会和环境评估。它提出了一个综合这些相互关联的维度的整体评估框架。该研究通过采用结合太阳能潜力、作物需水量和成本效益的优化框架,评估了该系统的最佳规模、经济可行性以及社会和环境效益。通过PVsyst软件,模拟了系统在不同气候条件下的性能,并进行了敏感性分析,以评估组件成本的影响、太阳辐照度变化和水需求形状。分析净现值(Net Present Value)等经济指标,与传统柴油相比减少二氧化碳(CO₂)排放量,量化环境效益。结果表明,SPVWPS在经济上是可行的,每年可减少温室气体排放3348.57 kg。nexus方法进一步强调了该系统在提高平均每天超过20立方米的用水效率和作物生产力方面的潜力。这平均可以灌溉1.5公顷的橄榄作物。提出政策建议以促进大规模采用,强调补贴和技术培训的作用。该研究有助于为北非类似干旱地区提供可复制的模式。
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引用次数: 0
Synergizing In Vitro and energy-based computational approaches to investigate the potential of Lagenaria siceraria against olanzapine-induced cardiometabolic disorders using H9c2 (2-1) cardiomyocytes 协同体外和基于能量的计算方法,利用H9c2(2-1)心肌细胞研究锡拉根菌对抗奥氮平诱导的心脏代谢紊乱的潜力
IF 9.5 Q1 ENERGY & FUELS Pub Date : 2026-01-09 DOI: 10.1016/j.nexus.2026.100636
Faizan A. Beerwala , Shruti V. Kolambkar , Vishal S. Patil , Adilmehadi Karikazi , Nayeem A. Khatib , Harish R. Darasaguppe , Subarna Roy
Olanzapine (OLZ), a widely prescribed atypical antipsychotic, is notably associated with the onset of cardiometabolic disorders (CMDs). Lagenaria siceraria, traditionally recognized for its cardioprotective effects and benefits for CMD(s). However, its potential in mitigating OLZ-induced CMD(s) has not been extensively explored. This study aims to assess the efficacy and underlying mechanisms of Lagenaria siceraria hydroalcoholic extract (LSE) in counteracting OLZ-induced CMD(s) through in vitro and computational approaches. The effects of LSE on OLZ-challenged H9c2(2-1) cardiomyocytes were evaluated by measuring lactate dehydrogenase (LDH), creatine kinase-MB (CK-MB), nitric oxide (NO), and glucose utilization. Additionally, the expression of essential key genes (such as IL6, BAX, BCL2, CASP3, CAMK2B) implicated in OLZ-induced CMD(s) was analysed using qRT-PCR. Computational analyses, including gene set enrichment, network pharmacology, and molecular docking via (AutoDock Vina, POAP pipeline), followed by molecular dynamics (MD) simulations, MM-PBSA, and binding stability assessments via (GROMACS), were employed to predict compound-target interactions. The results demonstrated that LSE significantly attenuated OLZ-induced elevations in LDH, CK-MB, and NO levels while enhancing glucose utilization in cardiomyoblasts. LSE also modulated gene expression by downregulating IL6, BAX, CASP3, and CAMK2B, while upregulating BCL2. Network pharmacology identified 10 phytocompounds from LSE targeting 17 common proteins involved in OLZ-induced CMD(s), with beta-sitosterol- AKT and beta-sitosterol- CALM1 complexes exhibiting the strongest binding affinities. MD simulations confirmed the stability of these interactions over a 100 ns period. In conclusion, the findings suggest that LSE holds cardioprotective potential against OLZ-induced CMD(s). Further research, including studies with purified compounds and clinical trials, is necessary to evaluate LSE as an adjunctive therapeutic agent.
奥氮平(OLZ)是一种广泛使用的非典型抗精神病药物,与心脏代谢紊乱(CMDs)的发病密切相关。传统上认为Lagenaria siceraria具有心脏保护作用和对CMD的益处。然而,它在减轻olz诱导的CMD(s)方面的潜力尚未得到广泛探索。本研究旨在通过体外实验和计算方法,研究银根草(Lagenaria siceraria)水酒精提取物(LSE)对抗olz诱导的CMD(s)的作用及其机制。通过测定乳酸脱氢酶(LDH)、肌酸激酶- mb (CK-MB)、一氧化氮(NO)和葡萄糖利用率来评估LSE对olz刺激H9c2(2-1)心肌细胞的影响。此外,使用qRT-PCR分析了与olz诱导CMD相关的关键基因(如IL6、BAX、BCL2、CASP3、CAMK2B)的表达。计算分析,包括基因集富集、网络药理学和分子对接(AutoDock Vina, POAP管道),然后是分子动力学(MD)模拟、MM-PBSA和结合稳定性评估(GROMACS),用于预测化合物-靶标相互作用。结果表明,LSE可显著降低olz诱导的LDH、CK-MB和NO水平升高,同时增强心肌细胞对葡萄糖的利用。LSE还通过下调IL6、BAX、CASP3和CAMK2B,上调BCL2来调节基因表达。网络药理学鉴定了来自LSE的10种植物化合物靶向17种与olz诱导CMD相关的常见蛋白,其中β -谷甾醇- AKT和β -谷甾醇- CALM1复合物的结合亲和力最强。MD模拟证实了这些相互作用在100 ns周期内的稳定性。综上所述,研究结果表明LSE对olz诱导的CMD具有心脏保护潜力。进一步的研究,包括纯化化合物的研究和临床试验,需要评估LSE作为辅助治疗剂。
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引用次数: 0
Thermoeconomic assessment of a cement-plant waste-heat-driven trigeneration system for power, cooling, and desalination 用于发电、冷却和脱盐的水泥厂废热驱动三联发电系统的热经济评估
IF 9.5 Q1 ENERGY & FUELS Pub Date : 2026-01-09 DOI: 10.1016/j.nexus.2026.100631
Heba I. Khafajah , Mostafa M. Abdelsamie , Mohamed I. Hassan Ali
Cement production is one of the most energy- and carbon-intensive industrial activities, with a large fraction of the fuel input rejected as medium- and low-grade waste heat from cyclone preheaters and clinker coolers. This study proposes and evaluates a waste-heat-driven trigeneration system for a 5,000 t·day⁻¹ dry-process cement plant that simultaneously delivers electricity, process cooling, and desalinated water, thereby addressing coupled energy–water challenges in water-stressed regions. The configuration cascades multi-grade waste heat through three thermally coupled subsystems: (i) a cascade Organic Rankine Cycle (C-ORC) with high- and low-pressure loops matched to the preheater (300–380 °C) and clinker-cooler (250–340 °C) exhausts, (ii) an internally recuperated double-effect LiBr/H₂O absorption chiller (DEAC), and (iii) a 20-stage brine-recirculation multi-stage flash (MSF) desalination unit fed by a closed hot-water loop with a top-brine temperature of 103 °C, below typical CaSO₄/CaCO₃ scaling limits. Aspen Plus V14 simulations show that the preferred C-ORC layout delivers 6.30 MW with an exergy efficiency of 40.66%, while the selected DEAC configuration achieves a coefficient of performance of 1.40 and an exergy efficiency of 43%. The MSF subsystem attains a gained-output ratio of about 7.5–8 and produces 2.23 × 10⁶ m³·y⁻¹ of freshwater at a specific thermal energy consumption of 83.3 kWh·m⁻³. At system level, the integrated C-ORC–DEAC–MSF arrangement recovers 514.78 GWh·y⁻¹ of waste heat, corresponding to 142.88 GWhₑ·y⁻¹ on an electricity-equivalent basis, increases the overall energy utilization factor to 0.81, and avoids 128.6 × 10³ t CO₂·y⁻¹ under standard grid-displacement assumptions. Beyond these plant-scale metrics, the work provides a transferable thermo-economic and environmental assessment framework for waste-heat-driven trigeneration and illustrates the potential of such integrated schemes to co-produce low-carbon power, cooling, and desalinated water in energy- and water-constrained industrial systems.
水泥生产是能源和碳密集度最高的工业活动之一,其中很大一部分燃料输入作为旋风预热器和熟料冷却器产生的中低品位废热而被丢弃。本研究提出并评估了一个用于5000吨/天干法水泥厂的废热驱动三联产系统,该系统同时提供电力、工艺冷却和淡化水,从而解决缺水地区的能源-水耦合挑战。该配置通过三个热耦合子系统将多级废热级联:(i)串联有机朗肯循环(C- orc),具有与预热器(300-380°C)和熟料冷却器(250-340°C)排气相匹配的高压和低压循环,(ii)内部回收双效LiBr/H₂O吸收式冷水机(DEAC),以及(iii) 20级盐水再循环多级闪蒸(MSF)脱盐装置,由封闭热水循环提供,顶部盐水温度为103°C,低于典型的CaSO₄/CaCO₃结垢限制。Aspen Plus V14模拟表明,首选的C-ORC布局提供6.30 MW,火用效率为40.66%,而选择的DEAC配置的性能系数为1.40,火用效率为43%。MSF子系统的增益输出比约为7.5-8,产生2.23 × 10⁶m³·y毒血症,具体热能消耗为83.3 kWh·m·毒血症。在系统层面,C-ORC-DEAC-MSF一体化安排回收了514.78 GWh·y -毒血症,相当于142.88 GWhₑ·y -毒血症,将整体能量利用系数提高到0.81,在标准电网位移假设下避免了128.6 × 10³CO₂·y -毒血症。除了这些工厂规模的指标,这项工作还为废热驱动的三联发电提供了一个可转移的热经济和环境评估框架,并说明了这种综合方案在能源和水资源有限的工业系统中共同生产低碳电力、冷却和淡化水的潜力。
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引用次数: 0
Optimizing pumped hydro and hydrogen storage for water-dependent renewable systems 为依赖水的可再生能源系统优化抽水蓄能和储氢
IF 9.5 Q1 ENERGY & FUELS Pub Date : 2026-01-08 DOI: 10.1016/j.nexus.2026.100634
Claudinei de Moura Altea, Jurandir Itizo Yanagihara
<div><div>Brazil’s electricity sector is undergoing a profound transformation as the share of intermittent renewables, such as wind and solar, continues to grow. While the country benefits from abundant renewable resources and a historically hydro-dominated grid, this configuration is increasingly challenged by seasonal water variability, rising curtailments, and the need to phase out fossil-based backup generation. Addressing these challenges requires the deployment of long-duration energy storage technologies that can provide reliability, flexibility, and resilience at the system level.</div><div>For the first time in the Brazilian context, this study proposes a long-term optimization framework to assess the role of Pumped Hydro Storage (PHS) and Hydrogen (H₂) in enabling a cost-effective and sustainable expansion of Brazil’s power system. The framework simultaneously co-optimizes PHS siting—based on a geospatial inventory of 337 potential sites—together with modular H₂ deployment, renewable expansion, and hydrogen exports within a unified objective function. The model spans a 25-year planning horizon (2026–2050) with monthly resolution, explicitly integrating hydrological cycles and water-dependent dispatch, which is crucial for a hydro-dominated system like Brazil’s. It captures renewable expansion, storage deployment, hydrogen exports, and fossil imports. Decision variables include renewable capacity additions, the siting and adoption of PHS plants, and modular deployment of H₂ electrolysis and re-electrification units. The formulation incorporates round-trip efficiencies, investment and operating costs, CO₂ emissions with a carbon price, and penalties for curtailment, thereby ensuring an integrated assessment of technical, economic, and environmental trade-offs.</div><div>The results highlight distinct but complementary contributions of PHS and H₂. PHS consistently delivers higher round-trip efficiency and cost-effectiveness, confirming its role as a mature and reliable backbone for renewable integration. Hydrogen, in turn, provides strategic systemic flexibility, particularly under high-renewable penetration, enabling surplus absorption and export opportunities. In the optimal configuration (Scenario 7), the model deploys 101 PHS plants and 75 H₂ modules, and the system transitions from a negative net balance in the baseline to a positive economic outcome. While the baseline operates in a net cost position, the optimized configuration not only fully offsets this deficit but also generates additional revenues equivalent to 28 % of the original system costs, underscoring the economic superiority of the PHS–H₂ hybrid solution. Complementarily, the Fossil-Free scenario, which enforces the complete elimination of fossil-based imports in the final five years of the horizon, demonstrates the system’s ability to sustain a fully renewable and storage-backed operation, while maintaining overall system costs reduction within 4 % of the optimal config
随着风能和太阳能等间歇性可再生能源的份额持续增长,巴西的电力部门正在经历一场深刻的变革。虽然该国受益于丰富的可再生资源和历史上以水力发电为主的电网,但这种配置正日益受到季节性水资源变化、限电增加以及逐步淘汰化石燃料备用发电的需求的挑战。解决这些挑战需要部署能够在系统层面提供可靠性、灵活性和弹性的长期储能技术。本研究首次在巴西的背景下提出了一个长期优化框架,以评估抽水蓄能(PHS)和氢气(H₂)在实现巴西电力系统经济高效和可持续扩张方面的作用。该框架基于337个潜在地点的地理空间清单,同时协同优化PHS选址,以及统一目标函数内的模块化H₂部署、可再生能源扩展和氢气出口。该模型跨越了25年的规划周期(2026-2050年),每月都有分辨率,明确地整合了水文循环和依赖水的调度,这对巴西这样一个以水力为主的系统至关重要。它涵盖了可再生能源扩张、储能部署、氢出口和化石燃料进口。决策变量包括可再生能源容量的增加、PHS工厂的选址和采用、氢气电解和再电气化装置的模块化部署。该方案综合考虑了往返效率、投资和运营成本、二氧化碳排放和碳价以及限电处罚,从而确保了对技术、经济和环境权衡的综合评估。结果突出了小灵通和H₂的不同但互补的贡献。PHS持续提供更高的往返效率和成本效益,证实了其作为可再生能源整合成熟可靠的骨干的作用。反过来,氢提供了战略上的系统灵活性,特别是在可再生能源高度渗透的情况下,使剩余的吸收和出口机会成为可能。在最佳配置(场景7)中,该模型部署了101个PHS工厂和75个H₂模块,系统从基线的负净平衡转变为正的经济结果。虽然基线运行在净成本位置,但优化后的配置不仅完全抵消了这一赤字,而且还产生了相当于原始系统成本28%的额外收入,强调了PHS-H 2混合解决方案的经济优势。此外,无化石能源方案(Fossil-Free scenario)要求在未来五年内完全消除化石能源进口,这证明了该系统能够维持完全可再生能源和存储支持的运行,同时将整体系统成本降低到最佳配置的4%以内。总的来说,这项研究表明,巴西独特的可再生能源潜力,当与小灵通和氢₂战略结合时,可以支持一个有弹性的、低碳的、经济上可行的电力系统。该框架和研究结果为政策制定者和系统运营商提供了可操作的见解,强调了在向无化石燃料未来过渡的过程中,平衡经济竞争力、能源安全和气候可信度的综合规划的必要性。
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引用次数: 0
Advancing solar-assisted air gap membrane distillation through multi-short-channel module innovation 通过多短通道模块创新推进太阳能辅助气隙膜蒸馏
IF 9.5 Q1 ENERGY & FUELS Pub Date : 2026-01-08 DOI: 10.1016/j.nexus.2026.100632
Kabbir Ali , Mohamed I Hassan Ali
This research analyzes the performance and economic viability of a solar-assisted air gap membrane distillation (AGMD) system, comparing a conventional single long-channel module with an optimized multi-short-channel configuration. A computational fluid dynamics (CFD) model, validated against published literature data (<5% error), was developed to evaluate the effects of Reynolds number, solar irradiance, air gap thickness, and concentration ratio (CR) on thermal and mass transfer characteristics. The multi-short-channel design consistently outperformed the single-channel module, achieving up to 26% higher permeate flux and marginally improved thermal efficiency due to reduced temperature polarization, enhanced flow uniformity, and sustained high membrane surface temperatures. Parametric analysis revealed that thinner air gaps and lower flow rates favored higher flux, whereas thicker gaps improved thermal efficiency, indicating a trade-off between productivity and energy utilization. Integration with a concentrator photovoltaic (CPV) solar absorber further elevated feedwater temperatures, with higher CR values significantly boosting system output. Economic analysis demonstrated that the multi-short-channel configuration reduced freshwater production costs by up to ∼25% compared to the single-channel design, reaching as low as (5–18) $/m³ under optimal solar and hydraulic conditions. These findings highlight the potential of advanced channel geometries and solar-thermal integration to deliver cost-effective, energy-efficient desalination solutions, particularly for remote and off-grid regions.
本研究分析了太阳能辅助气隙膜蒸馏(AGMD)系统的性能和经济可行性,比较了传统的单长通道模块和优化的多短通道配置。建立了计算流体动力学(CFD)模型,并对已发表的文献数据进行了验证(误差为5%),以评估雷诺数、太阳辐照度、气隙厚度和浓度比(CR)对传热和传质特性的影响。多短通道设计始终优于单通道模块,通过降低温度极化、增强流动均匀性和维持较高的膜表面温度,可实现高达26%的高渗透通量,并略微提高热效率。参数分析表明,更薄的气隙和更低的流量有利于更高的通量,而更厚的气隙提高了热效率,这表明了生产力和能量利用之间的权衡。与聚光光伏(CPV)太阳能吸收器的集成进一步提高了给水温度,更高的CR值显着提高了系统输出。经济分析表明,与单通道设计相比,多短通道配置可将淡水生产成本降低高达25%,在最佳太阳能和水力条件下可低至(5-18)美元/m³。这些发现强调了先进的通道几何形状和太阳能热集成的潜力,以提供具有成本效益,节能的海水淡化解决方案,特别是在偏远和离网地区。
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引用次数: 0
High-performance electrochemical sensing of tetracycline via functionalised reduced graphene oxide nanocomposites 功能化还原氧化石墨烯纳米复合材料对四环素的高性能电化学传感
IF 9.5 Q1 ENERGY & FUELS Pub Date : 2025-12-11 DOI: 10.1016/j.nexus.2025.100619
Opeyemi A. Iresemowo, Vincent O. Nyamori, Olatunde S. Olatunji
The detection of antibiotic residues, particularly tetracyclines (TC), is crucial due to their potential risks to public health and environmental safety. This study reports the development of a selective and sensitive electrochemical sensor based on reduced graphene oxide functionalized with emeraldine salt and palladium nanoparticles (rGO-ES-Pd) for the detection of TC in simulated samples, urine, surface water, and wastewater. The rGO-ES-Pd nanocomposite was synthesised via a wet chemical method and drop-cast onto a glassy carbon electrode (GCE) to fabricate the rGO-ES-Pd/GCE sensor. To evaluate the impact of different polyaniline oxidation states, three additional nanocomposites, rGO-EB-Pd (emeraldine base), rGO-PG-Pd (pernigraniline), and rGO-LE-Pd (leucoemeraldine), were also prepared and tested. Comprehensive characterisation was performed using transmission electron microscopy (TEM), Fourier-transform infrared spectroscopy (FTIR), powder X-ray diffraction (XRD), electrochemical impedance spectroscopy (EIS), and cyclic voltammetry (CV). Among the tested nanocomposites, the rGO-ES-Pd/GCE sensor exhibited the highest electrocatalytic activity for TC detection, with a pH-dependent peak current response in the potential range of 0.1–0.4 V. The sensor demonstrated a wide linear detection range (0.01–5.0 × 10−6 M) and a low detection limit (1.51 × 10−7 M). Selectivity studies in the presence of common interfering substances, ibuprofen, erythromycin, and amoxicillin, revealed minimal interference and a low relative standard deviation (RSD) of 3.29 %, confirming the robustness of the sensor. The developed electrochemical method was successfully applied to detect TC in real environmental (river water, wastewater influent) and biological (urine) samples, showing excellent reproducibility and long-term stability.
抗生素残留的检测,特别是四环素(TC)的检测,由于其对公众健康和环境安全的潜在风险而至关重要。本研究报告了一种基于还原性氧化石墨烯与翡翠盐和钯纳米粒子功能化(rGO-ES-Pd)的选择性和敏感电化学传感器的开发,用于检测模拟样品、尿液、地表水和废水中的TC。rGO-ES-Pd纳米复合材料通过湿化学方法合成,并滴铸到玻碳电极(GCE)上,以制造rGO-ES-Pd/GCE传感器。为了评估不同聚苯胺氧化状态的影响,我们还制备并测试了另外三种纳米复合材料,即rGO-EB-Pd(祖母绿碱)、rGO-PG-Pd (pernigraniline)和rGO-LE-Pd (leucemeraldine)。采用透射电子显微镜(TEM)、傅里叶变换红外光谱(FTIR)、粉末x射线衍射(XRD)、电化学阻抗谱(EIS)和循环伏安法(CV)对样品进行了综合表征。在所测试的纳米复合材料中,rGO-ES-Pd/GCE传感器对TC检测表现出最高的电催化活性,在0.1-0.4 V的电位范围内具有ph依赖性的峰值电流响应。该传感器具有较宽的线性检测范围(0.01 ~ 5.0 × 10−6 M)和较低的检测限(1.51 × 10−7 M)。在常见干扰物质布洛芬、红霉素和阿莫西林存在下的选择性研究显示,干扰最小,相对标准偏差(RSD)为3.29%,证实了该传感器的鲁棒性。所建立的电化学方法成功地应用于实际环境(河水、废水)和生物(尿液)样品中TC的检测,具有良好的重现性和长期稳定性。
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引用次数: 0
Effects of red and blue light treatment on water, microclimate, soil and tomato crops in California 红蓝光处理对加州水分、小气候、土壤和番茄作物的影响
IF 9.5 Q1 ENERGY & FUELS Pub Date : 2025-12-11 DOI: 10.1016/j.nexus.2025.100609
Majdi Abou Najm , Andre Daccache , Matteo Camporese , Mohamed Emami
Recent advances in agrivoltaic systems (AVSs) have revived interest in understanding the effects of not only light intensity but also different light spectra on plants and overall land productivity, with research showing plant carbon assimilation being more efficient under red light, while the more energetic blue light would be more effective for producing solar electricity. AVSs are highly efficient in harvesting solar radiation for the co-generation of food and solar electricity, thus resulting in higher land productivity, compared to single-use alternatives, i.e., agriculture or utility-scale solar. This is particularly advantageous in arid and semi-arid areas with abundant sun and limited land and water. The question becomes: how much light and what particular spectra of light are more efficient for food and for energy conversion, and how can any light treatment impact water, soil, microclimate and plant productivity? This study explores the potentials of spectrally selective PV panels by testing the performance of field grown processing tomato with the focus on red and blue light treatments. The study evaluates crop productivity and water savings by monitoring microclimate, soil, and plant responses under two specific wavelength patterns (red and blue filters) compared to the full unfiltered light spectrum (control). The red and blue treatments, applied on processing tomatoes in Yolo County (California), yielded 67 % and 58 % of the control, respectively. However, changes in the microclimate — particularly the reduction in solar radiation —resulted in a significant decrease in evapotranspiration. Consequently, the potential water use efficiency (WUE) for the blue and red light treatments compared to the control was improved by 10 % and 13 %, respectively. Overall, our study suggests that benefits from renewable energy and reduced water usage could offset yield reductions, making spectrally selective AVSs a potentially viable and sustainable land-use option, especially in water-scarce regions.
农业光伏系统(AVSs)的最新进展重新唤起了人们对了解光强度以及不同光谱对植物和整体土地生产力的影响的兴趣,研究表明植物在红光下碳吸收更有效,而更有活力的蓝光则更有效地产生太阳能电力。与单一用途替代方案(即农业或公用事业规模的太阳能)相比,avs在收集太阳辐射以热电联产粮食和太阳能电力方面效率很高,从而提高了土地生产力。这在日照充足、土地和水有限的干旱和半干旱地区尤其有利。问题就变成了:对食物和能量转换来说,多少光和什么特定光谱的光更有效?任何光处理如何影响水、土壤、小气候和植物的生产力?本研究通过测试田间种植加工番茄的性能,重点研究了红光和蓝光处理,探索了光谱选择性光伏电池板的潜力。该研究通过监测小气候、土壤和植物在两种特定波长模式(红色和蓝色过滤器)下的反应,与未过滤的全光谱(对照)相比,来评估作物生产力和节水。在加州约洛县(Yolo County)的番茄加工过程中,红色和蓝色处理分别产生了对照的67%和58%。然而,小气候的变化——特别是太阳辐射的减少——导致了蒸散量的显著减少。因此,与对照相比,蓝光和红光处理的潜在水分利用效率(WUE)分别提高了10%和13%。总的来说,我们的研究表明,可再生能源和减少用水量的好处可以抵消产量的减少,使光谱选择性avs成为潜在可行和可持续的土地利用选择,特别是在缺水地区。
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引用次数: 0
Optimizing plant biomass from constructed wetlands for biogas production within the water-energy-food nexus 优化人工湿地的植物生物量,在水-能源-食物关系中生产沼气
IF 9.5 Q1 ENERGY & FUELS Pub Date : 2025-12-09 DOI: 10.1016/j.nexus.2025.100626
Giuseppe Mancuso, Dilia Carolina Duran Lugo, Emanuele Spizzirri, Attilio Toscano, Francesca Valenti
As the global demand for sustainable energy solutions grows, Constructed Wetlands (CWs) are gaining recognition not only for their effectiveness in wastewater treatment but also for their untapped potential as bioenergy sources. This study explores the viability of CW-derived plant biomass for biogas production, evaluating how plant species, maturity stages, and storage durations can influence methane yield. Using biomass from a free water surface wetland in Italy, four plant species, e.g., Phragmites australis, Typha latifolia, Carex spp., and Iris pseudacorus, were analyzed through Biomethane Potential (BMP) tests at three storage intervals: i) immediate – t(0), ii) three months after harvesting – t(1), and iii) six months – t(2) after harvesting, respectively. Results indicate that biogas yield peaked at t(1) for all species, with Iris pseudacorus showing consistent performance over time, and low carbon-to-nitrogen (C/N) ratios correlating with higher methane output. While plant maturity and storage significantly affected volatile solids and gas production, not all decreases in solids translated to higher methane yields. These findings indicate that CW biomass holds potential as a renewable feedstock for biogas production, though further optimization and scale-up studies are needed to confirm its practical applicability. By aligning with the Water-Energy-Food Nexus and Nature-based Solutions (NbS), the research promotes integrated approaches to enhance resource recovery, reduce waste, and support climate resilience.
随着全球对可持续能源解决方案的需求不断增长,人工湿地(CWs)不仅因其在废水处理方面的有效性而获得认可,而且因其作为生物能源的未开发潜力而获得认可。本研究探讨了以化粪肥为原料的植物生物量生产沼气的可行性,评估了植物种类、成熟期和储存时间对甲烷产量的影响。利用意大利一个自由水面湿地的生物量,通过生物甲烷势(BMP)测试分析了4种植物,即芦苇(Phragmites australis)、叶苔(Typha latifolia)、苔草(Carex spp)和假鸢尾花(Iris pseudoacorus),分别在3个储存间隔:i)收获后立即- t(0)、ii)收获后3个月- t(1)和iii)收获后6个月- t(2)。结果表明,所有物种的沼气产量在t(1)时达到峰值,其中假鸢尾在一段时间内表现一致,低碳氮比(C/N)与高甲烷产量相关。虽然植物成熟度和储存显著影响挥发性固体和气体的产量,但并非所有固体的减少都转化为更高的甲烷产量。这些发现表明,连续流化床生物质作为一种可再生的沼气原料具有潜力,尽管需要进一步的优化和规模化研究来证实其实际适用性。通过与水-能源-粮食关系和基于自然的解决方案(NbS)保持一致,该研究促进了加强资源回收、减少浪费和支持气候适应能力的综合方法。
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引用次数: 0
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