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Removal of arsenic ions As (III) and As (V) from simulated aqueous solutions using modified rice husk by manganese oxide 氧化锰改性稻壳对模拟水溶液中砷离子As (III)和As (V)的去除
IF 9.5 Q1 ENERGY & FUELS Pub Date : 2025-12-01 Epub Date: 2025-10-16 DOI: 10.1016/j.nexus.2025.100554
Vanesa Zea-Linares , Betty M. Salazar-Pinto , José A. Villanueva-Salas , Elvis G. Gonzales-Condori
The present investigation aimed to remove arsenic ions As (III) and As (V) from simulated aqueous solutions using modified rice husk by manganese oxide. It was possible to demonstrate that rice husk (RH) cannot remove As (III) and As (V) ions; however, the modification of RH with MnO2 (RH-MnO2) confers to this residue the capacity to remove both As ions. The Response Surface Methodology was used to optimize the removal process, taking into account the factors of pH, initial arsenic concentration, and RH-MnO2 dosage. As a result, an RH-MnO2 dosage of 9.6 g/L, pH=5, and an initial concentration of 1 mg/L was obtained for 100 % removal of As (III) and (V) ions. The kinetic model that best fitted the removal process was the pseudo-second order kinetic model, which would indicate that the removal process of As (III) and As (V) ions would follow chemisorption mechanisms. The analysis of the adsorption isotherms showed that the adsorption process occurs in monolayer since the process was better adjusted to the mathematical model of the Langmuir isotherm, also, after performing adsorption experiments at 15, 25, and 35 °C it was possible to demonstrate that the increase in temperature influences the removal process achieving better values of maximum adsorption capacity (qm) at 35 °C being these of 0.186 mg/g and 0.133 mg/g for the removal of As (III) and As (V). The thermodynamic study showed that the adsorption process is spontaneous and endothermic. On the other hand, ATR-FTIR analysis indicates that adsorption of As (III) and As (V) ions is evident between 600 and 800 cm-1, this was also corroborated with EDS analysis. SEM analysis showed that RH-MnO2 exhibits a more heterogeneous and porous structure than RH unmodified. In conclusion, it was demonstrated that RH-MnO2 would achieve the remediation of arsenic-contaminated water, being a promising alternative for its scaling up to real conditions.
本研究旨在利用氧化锰改性稻壳去除模拟水溶液中的砷离子As (III)和As (V)。可以证明稻壳(RH)不能去除As (III)和As (V)离子;然而,用MnO2修饰RH (RH-MnO2)使该残留物具有去除两种As离子的能力。考虑pH、初始砷浓度、RH-MnO2投加量等因素,采用响应面法优化去除工艺。结果表明,RH-MnO2的投加量为9.6 g/L, pH=5,初始浓度为1 mg/L,可100%去除As (III)和(V)离子。拟二级动力学模型是最符合去除过程的动力学模型,表明As (III)和As (V)离子的去除过程遵循化学吸附机理。吸附等温线的分析表明,吸附过程发生在单层自过程更好地适应朗缪尔等温线的数学模型,同时,在15进行吸附实验后,25岁和35°C可以证明的增加温度影响最大吸附容量的去除过程实现更好的值(qm) 35°C被这些0.186毫克/克和0.133毫克/克的去除(III)和(V)。热力学研究表明,吸附过程是自发的吸热过程。另一方面,ATR-FTIR分析表明,在600 ~ 800 cm-1之间,As (III)和As (V)离子的吸附很明显,EDS分析也证实了这一点。SEM分析表明,RH- mno2比未改性的RH表现出更多相的多孔结构。综上所述,RH-MnO2可以实现砷污染水的修复,是一种很有前途的替代方案,可以扩大到实际条件。
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引用次数: 0
Optimized biohydrogen production from sewage sludge: Advanced pretreatment strategies in dark fermentation and microbial electrolysis cells 污水污泥产氢优化:暗发酵和微生物电解细胞的先进预处理策略
IF 9.5 Q1 ENERGY & FUELS Pub Date : 2025-12-01 Epub Date: 2025-10-17 DOI: 10.1016/j.nexus.2025.100573
Hikmatullah Ahmadi , Anam Jalil , Sohail Khan , Ndayisenga Fabrice , Chengyu Zhang , Zhisheng Yu
The production of biohydrogen from sewage sludge presents a promising avenue for sustainable energy conversion and pollution control. This study systematically evaluates biohydrogen (bio-H₂) production through dark fermentation (DF) and single-chamber microbial electrolysis cells (MECs), employing diverse substrate pretreatment methods, including acidic, ultrasonic, heat, alkaline, and a novel combined CalciumCarbonate-2Potassiumhydroxide (CCPH) pretreatment. The findings reveal that these pretreatments significantly enhance the accumulation of proteins, carbohydrates, and volatile fatty acids (VFAs), with the DF phase further augmenting the solubilization of these critical components. Notably, 90–95% of carbohydrate and protein accumulation occurs during the pretreatment phase, which concurrently suppresses methanogenesis in sewage sludge, thereby optimizing conditions for bio-H₂ production in subsequent MEC processes. Among the pretreatments, CCPH-P demonstrates exceptional performance, achieving a total volatile fatty acid (TVFAs) concentration of 1,962 ± 124 mg/L post-dark fermentation, representing an 11.4-fold increase compared to untreated sludge. In MEC experiments, CCPH-P sludge attains a maximum current density of 172.5 A/m³ and an average bio-H₂ yield of 133.071 ml/g VS, underscoring its efficiency in electrochemical hydrogen recovery. Acetic and propionic acids, derived from sludge fermentation, emerge as the predominant electron donors, constituting approximately 80% of the total VFAs content across all pretreated substrates. Metagenomic analysis further reveals that Firmicutes exhibit the highest relative abundance, ranging from 60% to 88% in pretreated substrates, compared to merely 10.5% in untreated sewage sludge. These results collectively indicate that CCPH-pre-treatment serves as a viable and efficient method for enhancing biohydrogen recovery from sewage sludge through DF and MEC systems, thereby advancing the potential for waste-to-energy applications.
从污水污泥中生产生物氢为可持续能源转换和污染控制提供了一条有前途的途径。本研究系统地评价了通过暗发酵(DF)和单室微生物电解细胞(MECs)生产生物氢(bio-H₂),采用不同的底物预处理方法,包括酸性、超声波、热、碱性和新型碳酸钙-2氢氧化钾(CCPH)联合预处理。研究结果表明,这些预处理显著提高了蛋白质、碳水化合物和挥发性脂肪酸(VFAs)的积累,而DF相进一步增强了这些关键成分的增溶作用。值得注意的是,90-95%的碳水化合物和蛋白质积累发生在预处理阶段,这同时抑制了污泥中的甲烷生成,从而优化了后续MEC工艺中生物h 2生成的条件。在预处理中,CCPH-P表现出优异的性能,暗发酵后总挥发性脂肪酸(TVFAs)浓度为1,962±124 mg/L,比未经处理的污泥增加11.4倍。在MEC实验中,CCPH-P污泥的最大电流密度为172.5 a /m³,平均生物h₂产率为133.071 ml/g VS,体现了其电化学氢回收的效率。来自污泥发酵的乙酸和丙酸是主要的电子供体,约占所有预处理底物中VFAs总量的80%。宏基因组分析进一步显示,厚壁菌门的相对丰度最高,在预处理底物中为60%至88%,而在未经处理的污水污泥中仅为10.5%。这些结果共同表明,通过DF和MEC系统,ccph预处理是一种可行且有效的方法,可以提高污泥中生物氢的回收率,从而提高废物转化为能源的潜力。
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引用次数: 0
The effect of the morphology of highly polluted urban areas neighborhood on suspended particles of PM 2.5 and PM 10 air pollutants (Case Study: Ahvaz, Iran) 重污染城市周边地区形态对pm2.5和pm10空气污染物悬浮粒子的影响(以伊朗阿瓦士为例)
IF 9.5 Q1 ENERGY & FUELS Pub Date : 2025-12-01 Epub Date: 2025-08-27 DOI: 10.1016/j.nexus.2025.100527
Sadaf Vahidi , Mansour Yeganeh , Masoud Ghasaban
Air pollution is one of the serious environmental challenges in large and industrial cities, which has direct and indirect consequences on human health and the environment. In many large cities, improper design of building forms can increase the amount of suspended particles. With population growth and urban development, managing and reducing air pollution has become essential. This study was conducted to improve indoor air quality and reduce the infiltration of atmospheric pollutants into residential spaces, utilizing the ENVI-met software as a computational fluid dynamics (CFD)-based simulation tool. This tool enables the analysis of the impact of architectural form on climatic conditions in urban environments. For this purpose, the concentration of PM2.5 and PM10 pollutants as the main criteria of air pollution in Ahvaz city was collected from the Environment and Protection Organization, and using detailed simulations, the effect of different building forms, including square forms, central courtyard, l-shaped, T-shaped, U-shaped, linear and Plus-shaped have been investigated. Design variables such as height, occupation level, and orientation of the building were selected as critical parameters and modeled at three height levels and different percentages of occupation level, which finally led to the production of 63 simulation scenarios. The results showed that the U-shaped form with a height of 16 meters, an occupation level of 60 %, and an orientation towards the east (Leeward) shows the best performance in reducing the penetration of PM2.5 and PM10. Compared to the current situation, the proposed model demonstrated improved performance, achieving a 23.40 % reduction in pollutants compared to Lashkarabad, 13.32 % compared to Shahrek Naft, 12.3 % compared to Zeytoon Karmandi, and 27.3 % compared to Koye Ostadan, proving its effectiveness in enhancing air quality. The findings of this study demonstrate that selecting building forms with consideration of pollutant types and environmental conditions plays a significant role in reducing air pollution levels. Simulation as an analytical tool in the early design phase enables a more precise assessment of the impact of various architectural forms and can serve as an effective approach in the sustainable design process. The results assist designers in identifying optimal options and can be used as a scientific reference by policymakers and urban planners to improve urban environmental quality.
空气污染是大城市和工业城市面临的严重环境挑战之一,对人类健康和环境具有直接和间接的影响。在许多大城市,建筑形式设计不当会增加悬浮颗粒的数量。随着人口增长和城市发展,管理和减少空气污染已变得至关重要。本研究利用ENVI-met软件作为基于计算流体动力学(CFD)的模拟工具,旨在改善室内空气质量,减少大气污染物渗入住宅空间。这个工具能够分析建筑形式对城市环境中气候条件的影响。为此,收集了来自环境保护组织的PM2.5和PM10污染物浓度作为阿瓦士市空气污染的主要标准,并通过详细的模拟,研究了不同建筑形式的影响,包括方形,中央庭院,l形,t形,u形,线性和+形。选取建筑高度、职业等级、朝向等设计变量作为关键参数,分别在三个高度等级和不同职业等级百分比下进行建模,最终生成63个仿真场景。结果表明,高度为16米、占用度为60%、朝向东侧(背风)的u形建筑对降低PM2.5和PM10的穿透效果最好。与目前的情况相比,所提出的模型显示出改善的性能,与拉什卡拉巴德相比,污染物减少了23.40%,与Shahrek Naft相比减少了13.32%,与Zeytoon Karmandi相比减少了12.3%,与Koye Ostadan相比减少了27.3%,证明了其在改善空气质量方面的有效性。研究结果表明,考虑污染物类型和环境条件选择建筑形式对降低空气污染水平具有重要作用。模拟作为早期设计阶段的分析工具,可以更精确地评估各种建筑形式的影响,并且可以作为可持续设计过程中的有效方法。研究结果有助于设计者确定最优方案,并可作为政策制定者和城市规划者改善城市环境质量的科学参考。
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引用次数: 0
Economic viability of crop-specific solar irrigation designs under diverse agricultural management and grid-connected conditions: Insights from Qazvin Plain, Iran 在不同农业管理和并网条件下,特定作物太阳能灌溉设计的经济可行性:来自伊朗Qazvin平原的见解
IF 9.5 Q1 ENERGY & FUELS Pub Date : 2025-12-01 Epub Date: 2025-09-24 DOI: 10.1016/j.nexus.2025.100550
Mohammad Reza Mirahmad, Atefeh Parvaresh Rizi
The depletion of fossil fuels as the primary energy source and the associated environmental impacts contradicts sustainable development goals. A viable global solution involves harnessing renewable solar energy. With growing emphasis on pressurized irrigation systems in water-intensive agriculture and their significant energy demands, solar-powered irrigation has emerged as a promising alternative. However, financial viability remains a key challenge. This study examines solar irrigation systems tailored to the Qazvin Plain, Iran, focusing on fixed rain and strip sprinklers across three cultivated area scales for two crops—fodder corn and wheat—under single-season and double-season scenarios. Results highlight the critical role of crop type, cultivation scale, and irrigation methods in economic feasibility. Optimal system design prioritizing minimal energy use is essential, considering each agricultural plot's specific attributes. Notably, surplus electricity sales to the national grid could generate income 35–45 times the initial cost over 20 years for single-season plans and 31–38 times for double-season plans, with the initial investment recouped within six years. The net present value in all scenarios confirms the financial rationale for adopting solar irrigation systems, underscoring their potential to align agricultural practices with sustainability and economic efficiency.
化石燃料作为主要能源的枯竭及其相关的环境影响与可持续发展目标相矛盾。一个可行的全球解决方案是利用可再生太阳能。随着用水密集型农业越来越重视加压灌溉系统及其巨大的能源需求,太阳能灌溉已成为一种有希望的替代方案。然而,财务可行性仍然是一个关键挑战。本研究考察了为伊朗Qazvin平原量身定制的太阳能灌溉系统,重点研究了在单季和双季情况下,针对两种作物(饲料玉米和小麦)的三种种植面积规模的固定降雨和条形洒水装置。结果强调了作物类型、种植规模和灌溉方式对经济可行性的关键作用。考虑到每个农地的具体属性,优先考虑最小能源使用的优化系统设计是必不可少的。值得注意的是,出售给国家电网的剩余电力,单季计划可在20年内产生35-45倍于初始成本的收入,双季计划可产生31-38倍的收入,初始投资可在6年内收回。所有情况下的净现值都证实了采用太阳能灌溉系统的财政理由,强调了它们使农业实践与可持续性和经济效率相一致的潜力。
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引用次数: 0
Transforming arid regions: CLEWs–OSeMOSYS pathways for low-carbon jobs and circular resource loops 改造干旱地区:低碳工作和资源循环的CLEWs-OSeMOSYS途径
IF 9.5 Q1 ENERGY & FUELS Pub Date : 2025-12-01 Epub Date: 2025-10-17 DOI: 10.1016/j.nexus.2025.100552
Amirreza Khaleghian , Masoumeh Bararzadeh Ledari , Roya Vahedi , Maryam Fani
Arid regions face acute water scarcity, with traditional farming dominating groundwater use and employment. This study asks whether strict groundwater and carbon limits can sustain jobs while reducing emissions. Using the CLEWs–OSeMOSYS framework in Iran’s Khash region, this study quantifies low-carbon employment pathways and model circular resource loops—wastewater reuse, biowaste-to-energy, and CO₂ use in greenhouses.
Three 2020–2050 scenarios impose a 50 % groundwater cut and reduce traditional agriculture/livestock by 50–90 % under carbon caps of 30–90 %. In the base case, agriculture employs ∼32 000 workers (75 % of jobs), consumes 367 MCM of water, and emits 0.3 Mt CO₂. Under the most stringent pathway (SC III), withdrawals fall to 62 MCM (–84 %), emissions drop 90 %, and farm jobs shrink by 90 %. Yet total employment rises slightly (∼40 000), with 28 600 jobs in renewables, 8 100 in greenhouse farming, and 5 100 in CCUS-based ethylene. Circular measures generate 18.6 MW of biopower, meet 46 % of domestic water demand, and support 31.7 ha of CO₂-enriched greenhouses.
These results show that resource constraints can drive structural shifts toward resilient, low-carbon economies. Policy priorities include greenhouse adoption with reskilling, expansion of renewables and CCUS petrochemicals, and tariff reforms to incentivize reuse and biogas.
干旱地区面临着严重的水资源短缺,传统农业主导着地下水的使用和就业。这项研究的问题是,严格的地下水和碳排放限制能否在减少排放的同时维持就业。本研究利用伊朗卡什地区的CLEWs-OSeMOSYS框架,量化了低碳就业途径,并建立了循环资源循环模型——废水回用、生物废物转化为能源和温室中的二氧化碳利用。2020-2050年的三种情景要求地下水减少50%,在碳排放上限为30 - 90%的情况下,传统农业/畜牧业减少50 - 90%。在基本情况下,农业雇佣了约3.2万名工人(占就业岗位的75%),消耗了3.67亿立方米的水,排放了30亿吨的二氧化碳。在最严格的途径(SC III)下,提取量下降到62mcm(- 84%),排放量下降90%,农业就业减少90%。然而,总就业人数略有增加(约4万人),其中可再生能源行业就业人数为28600人,温室农业就业人数为8100人,以ccus为基础的乙烯行业就业人数为5100人。循环措施产生了18.6兆瓦的生物能源,满足了46%的生活用水需求,并支持了31.7公顷的二氧化碳富集温室。这些结果表明,资源约束可以推动结构性转变,使其向有弹性的低碳经济转变。政策重点包括温室气体采用再培训,可再生能源和CCUS石化产品的扩大,以及激励再利用和沼气的关税改革。
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引用次数: 0
Rich enough to go green? A threshold regression analysis on the nonlinear effects of income on renewable energy demand 有钱到可以环保吗?收入对可再生能源需求非线性影响的阈值回归分析
IF 9.5 Q1 ENERGY & FUELS Pub Date : 2025-12-01 Epub Date: 2025-11-19 DOI: 10.1016/j.nexus.2025.100598
Swapnanil SenGupta , Anshita Sachan
We revisit whether the income-renewable energy nexus is nonlinear and regime-dependent, and complement the established U-shaped income-renewable energy relationship by determining threshold income values. Using a panel of up to 189 countries over 1990–2021, we estimate a dynamic panel threshold regression that accommodates endogeneity and lagged dependence. We identify statistically significant income thresholds of $13,726 (global), $43,000 (advanced economies, AEs), and $6588 (emerging markets and developing economies, EMDEs). Below the threshold, a 1% rise in income reduces renewable energy consumption by about 0.03% globally and 0.13% in EMDEs; above the threshold, the effect turns positive (about 0.16% globally and 0.01% in EMDEs). Thus, the Renewable Energy Kuznets Curve (RKC) is confirmed. For AEs, the association is positive on both sides and markedly stronger above the threshold. Thresholds and signs remain stable across five stress tests. The cut-offs stay within narrow bands (global $15,693-$17,189; AEs $38,522-$43,521; EMDEs $4989-$6412).
我们重新审视了收入-可再生能源关系是否是非线性和制度依赖的,并通过确定阈值来补充已建立的u型收入-可再生能源关系。在1990年至2021年期间,我们使用多达189个国家的面板,估计了一个动态面板阈值回归,以适应内生性和滞后依赖性。我们确定了具有统计学意义的收入门槛,分别为13,726美元(全球)、43,000美元(发达经济体)和6588美元(新兴市场和发展中经济体)。低于这一门槛,收入每增长1%,全球可再生能源消费将减少约0.03%,新兴市场和发展中国家可再生能源消费将减少0.13%;超过阈值,效应变为正(全球约0.16%,新兴市场国家约0.01%)。因此,可再生能源库兹涅茨曲线(RKC)得到了证实。对于ae,这种关联在两边都是正的,并且在阈值以上明显更强。在五次压力测试中,阈值和迹象保持稳定。下限保持在较窄的区间内(全球15693美元至17189美元;ae 38522美元至43521美元;EMDEs 4989美元至6412美元)。
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引用次数: 0
Towards collective intelligence in agriculture: Deep reinforcement learning and digital twins for efficient management of collective irrigation water distribution systems 迈向农业集体智慧:深度强化学习和数字孪生对集体灌溉配水系统的有效管理
IF 9.5 Q1 ENERGY & FUELS Pub Date : 2025-12-01 Epub Date: 2025-11-19 DOI: 10.1016/j.nexus.2025.100599
Chouaib El Hachimi , Salwa Belaqziz , Saïd Khabba , Hasan Karjoun , Mohamed Hakim Kharrou , Bouchra Ait Hssaine , Salah Er-Raki , Andre Daccache , Abdelghani Chehbouni , Qihao Weng
Optimizing traditional Open-Channel Irrigation Systems (OCIS) is crucial for enhancing water sustainability and food security in water-scarce regions. OCIS remains widely used in many countries but receives less research attention in optimization studies compared to the rapid advancements in precision agriculture, which leverage new technologies such as artificial intelligence, remote sensing, drones, and the internet of things. Here, this study aims to optimize Water Use Efficiency (WUE) in the context of OCIS by proposing a framework for an adaptive spatiotemporal distribution of sowing dates. The framework consists of an intelligent agent interacting with a Digital Twin (DT). R3 district, an irrigated area within the Tensift basin in Morocco was used as a study site. Agrometeorological data from an automatic weather station installed in R3 district feeds the DT. This latter operates currently as a Digital Model with no bidirectional data integration, and comprises a module based on the AquaCrop model to simulate crop growth, development, and yield, and another module using graph theory to simulate the OCIS. The study evaluates genetic algorithms (GAs), an evolutionary optimization technique, versus a deep deterministic policy gradient (DDPG) agent for recommending the adaptive spatiotemporal distribution of sowing dates. The objective function is formulated as a constrained maximization of a Lagrangian function representing WUE, subject to the constraints imposed by the OCIS. The DDPG agent was trained for 1000 epochs, while GA ran for 100 generations. Results showed that the DDPG agent effectively learned the environment's dynamics through interactions with the R3 DT, as evidenced by increasing trend in the reward signals. However, GAs showed prolonged stagnation at multiple plateaus suggesting that GAs were unable to escape suboptimal solutions. In terms of training time, GAs take the longest. Additionally, comparing a same-day sowing date scenario to the adaptive sowing dates scenario recommended by the DDPG agent revealed a 4.69% increase in the total crop yield with WUE of 1.95 while adhering to the hydraulic constraints of OCIS. This study marks a first step toward utilizing intelligent agents in critical areas such as irrigation water management. Future work will focus on enhancing the R3 DT to increase the agent's robustness, enabling it to generate reliable recommendations for real-world applications.
优化传统的明渠灌溉系统(OCIS)对于提高缺水地区的水可持续性和粮食安全至关重要。OCIS在许多国家仍被广泛使用,但与利用人工智能、遥感、无人机和物联网等新技术的精准农业的快速发展相比,OCIS在优化研究中受到的关注较少。本研究旨在通过提出一个自适应播期时空分布框架,优化OCIS背景下的水分利用效率(WUE)。该框架由与数字孪生体(DT)交互的智能代理组成。R3区是摩洛哥Tensift盆地内的一个灌溉区,被用作研究地点。安装在R3区的自动气象站提供农业气象数据给DT。后者目前是一个数字模型,没有双向数据集成,包括一个基于AquaCrop模型的模块,用于模拟作物生长、发育和产量,另一个模块使用图论来模拟OCIS。研究评估了遗传算法(GAs),一种进化优化技术,与深度确定性策略梯度(DDPG)代理推荐播种日期的自适应时空分布。目标函数被表述为表示WUE的拉格朗日函数的约束最大化,受OCIS施加的约束。DDPG智能体的训练次数为1000次,GA智能体的训练次数为100次。结果表明,DDPG代理通过与R3 DT的相互作用有效地学习了环境的动态,奖励信号呈增加趋势。然而,GAs在多个平台上表现出长时间的停滞,这表明GAs无法摆脱次优解。就训练时间而言,GAs花费的时间最长。此外,将当天播种日期方案与DDPG代理推荐的自适应播种日期方案进行比较发现,在遵守OCIS水力约束的情况下,作物总产量提高4.69%,WUE为1.95。这项研究标志着在灌溉用水管理等关键领域利用智能代理迈出了第一步。未来的工作将侧重于增强R3 DT,以提高智能体的鲁棒性,使其能够为现实世界的应用生成可靠的建议。
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引用次数: 0
Reimagining landfills as energy hubs: A new integrated approach for biomethane and green hydrogen production 重新设想垃圾填埋场作为能源中心:生物甲烷和绿色氢生产的新综合方法
IF 9.5 Q1 ENERGY & FUELS Pub Date : 2025-12-01 Epub Date: 2025-10-16 DOI: 10.1016/j.nexus.2025.100561
Silvia De Paola , Giuseppina Oliva , Stefano Cairone , Diego Magrini , Giorgio Cardona , Vincenzo Cimini , Roberto Zocchi , Tiziano Zarra , Vincenzo Belgiorno , Vincenzo Naddeo
Landfills have long been seen as a suboptimal waste management solution, yet innovative strategies can repurpose them as energy hubs. This study investigates an integrated valorization approach combining landfill gas (LFG) upgrading via Vacuum Pressure Swing Adsorption (VPSA), multi-stage reverse osmosis (RO) treatment of landfill leachate (LL), and green hydrogen (H2) production via electrolysis powered by renewable energy. The proposed approach has been partially validated at the Borgo Montello landfill (Latina, Italy) through the implementation of LFG upgrading, LL treatment, and photovoltaic (PV) modules installed along the basin slopes to promote energy self-sufficiency. The strategy was evaluated through site-specific mass and energy balance analyses, comparing four scenarios: A) representing the conventional approach with LFG used in combined heat and power (CHP) units and external LL management; B) featuring LFG upgrading to biomethane (bioCH4) and LL treatment via RO; C) an advanced model integrating H2 production from treated LL using a PV-powered electrolyzer; and D) which builds upon Scenario C but proposes an alternative pathway for bioCH4 valorization that eliminates the need for liquefaction. The mass balances indicated that the upgrading and liquefaction system achieved an 87 % (m/m) yield and 98 % purity in terms of methane, while the RO treatment displaced 68 % of water recovery and 99.9 % of contaminants rejection. Energy balances confirmed the viability of all configurations, with Scenario D delivering the highest energy surplus of +8938 MWh/year, followed by Scenario C (+5729 MWh/year), Scenario A (+5161 MWh/year), and Scenario B (+2418 MWh/year). Although Scenario A yields relatively high energy production, it provides limited resource valorization and circular economy benefits compared to the other scenarios, which integrate bioCH4 and H2 production within a more resource-efficient model. Overall, the results demonstrate that landfills can be repurposed into multi-functional energy hubs, contributing to circular economy goals, decarbonization, and resource recovery.
长期以来,垃圾填埋场一直被视为一种次优的废物管理解决方案,但创新的策略可以将其重新定位为能源中心。本研究研究了一种综合增值方法,结合真空变压吸附(VPSA)、多级反渗透(RO)处理垃圾渗滤液(LL)和可再生能源电解生产绿色氢(H2)的垃圾填埋气(LFG)升级。提议的方法已经在Borgo Montello垃圾填埋场(意大利Latina)通过实施LFG升级、LL处理和沿盆地斜坡安装光伏(PV)模块来促进能源自给自足,部分得到了验证。通过特定地点的质量和能量平衡分析,对该策略进行了评估,比较了四种情况:A)代表传统方法,即在热电联产(CHP)机组和外部LL管理中使用LFG;B) LFG转化为生物甲烷(bioCH4),并通过反渗透处理LL;C)一种先进的模型,利用pv供电的电解槽将处理后的LL集成为H2生产;D)建立在方案C的基础上,但提出了一种替代途径来实现生物甲烷增值,从而消除了液化的需要。质量平衡表明,升级和液化系统的产率达到87% (m/m),甲烷纯度达到98%,而反渗透处理的水回收率为68%,污染物截除率为99.9%。能量平衡证实了所有配置的可行性,其中方案D提供最高的能量盈余+8938 MWh/年,其次是方案C (+5729 MWh/年),方案A (+5161 MWh/年)和方案B (+2418 MWh/年)。尽管情景A产生了相对较高的能源产量,但与其他情景相比,它提供的资源增值和循环经济效益有限,其他情景将生物ch4和H2的生产整合在一个资源效率更高的模型中。总体而言,研究结果表明,垃圾填埋场可以被改造成多功能能源中心,有助于实现循环经济目标、脱碳和资源回收。
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引用次数: 0
A literature review of the food–energy–water nexus trade-offs and synergies research at the household level 食物-能源-水关系的权衡和家庭层面的协同效应研究的文献综述
IF 9.5 Q1 ENERGY & FUELS Pub Date : 2025-12-01 Epub Date: 2025-10-17 DOI: 10.1016/j.nexus.2025.100562
Thulani Ningi , Jeffrey D Mullen
Food–energy–water (F–E–W) nexus research has increased because of the rising worldwide demand for nutritious food, affordable and efficient energy and high-quality water resources. However, current studies primarily focus on securing these resources without fully addressing interconnectedness, trade-offs and potential synergies. Hence, this review scrutinizes the F–E–W nexus literature to understand current research trends exploring the trade-offs and synergies within household-level food–energy–water interconnectedness, with the objective of aiding policy creation. Unlike existing reviews that primarily analyze the F–E–W nexus at global, national, or regional scales, this study uniquely examines the direct trade-offs and synergies that households experience daily. The analysis was conducted using databases such as Scopus and Web of Science. This review found that current research mostly studies pathways and correlations between resources but does not specifically identify the trade-offs that households may minimize or the synergies they can utilize to achieve optimal food, energy and water security. Many studies either analyse the trade-offs between two resources or consider trade-offs and synergies as distinct concepts. This review asserts that the interdependencies and interactions within the F–E–W nexus significantly affect the security of energy, food and water resources at the household level. It highlights the need to recognise these connections in the strategic planning and administration of these essential resources.
粮食-能源-水(F-E-W)关系的研究已经增加,因为世界范围内对营养食品、负担得起的高效能源和高质量水资源的需求不断增加。然而,目前的研究主要集中在确保这些资源,而没有充分解决相互联系、权衡和潜在的协同作用。因此,本文回顾了F-E-W关系文献,以了解当前的研究趋势,探索家庭层面食物-能源-水相互联系中的权衡和协同作用,目的是帮助制定政策。与现有的主要分析全球、国家或地区尺度上的F-E-W关系的综述不同,本研究独特地考察了家庭日常经历的直接权衡和协同效应。分析是使用Scopus和Web of Science等数据库进行的。本综述发现,目前的研究主要研究资源之间的途径和相关性,但没有具体确定家庭可以最大限度地减少取舍,或者他们可以利用协同效应来实现最佳的粮食、能源和水安全。许多研究要么分析两种资源之间的权衡,要么将权衡和协同效应视为不同的概念。这篇综述认为,F-E-W关系内的相互依赖和相互作用显著影响家庭一级的能源、粮食和水资源安全。它强调了在这些重要资源的战略规划和管理中认识到这些联系的必要性。
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引用次数: 0
Design of tractor hybrid electric powertrain and optimization control strategy based on dynamic programming algorithm 拖拉机混合动力系统设计及基于动态规划算法的优化控制策略
IF 9.5 Q1 ENERGY & FUELS Pub Date : 2025-12-01 Epub Date: 2025-10-17 DOI: 10.1016/j.nexus.2025.100558
Baogang Li , Jinbo Pan , Yuhuan Li , Fazhan Yang , Hanjun Jiang , Fuhao Liu , Zunmin Liu
To improve energy efficiency and fuel consumption, this study proposed a high‐power hybrid tractor system and developed a control strategy. Building upon the typical working characteristics of traditional tractors and the continuous speed regulation features of planetary gear transmissions in hybrid systems, a novel high‐power hybrid architecture was designed. A corresponding simulation model was established, and an energy management strategy based on dynamic programming algorithms was developed for optimization. Simulation results demonstrated that the proposed hybrid tractor can deliver a maximum power output of over 200 kW, meeting the demands of high‐horsepower farm operations. Moreover, the dynamic programming‐based control strategy keeps both the engine and motor operating within high‐efficiency intervals, thereby considerably reducing fuel consumption. After optimization, the equivalent fuel consumption under traction conditions decreased from 2.76 L to 2.5 L-a reduction of 10.4 %. Under full operating load, the equivalent fuel consumption was reduced from 18.55 L to 16.7 L, achieving an 11.02 % improvement. These results confirmed a substantial increase in overall energy utilization efficiency. The high‐power hybrid tractor developed in this study provides valuable insights into the design of energy‐efficient agricultural machinery and offers a practical reference for formulating intelligent energy management strategies in agricultural engineering applications.
为了提高拖拉机的能源效率和燃料消耗,本研究提出了一种大功率混合动力拖拉机系统,并制定了控制策略。基于传统拖拉机的典型工作特性和混合动力系统中行星齿轮传动的连续调速特性,设计了一种新型的大功率混合动力机构。建立了相应的仿真模型,并开发了基于动态规划算法的能量管理策略进行优化。仿真结果表明,所提出的混合动力拖拉机可以提供超过200千瓦的最大功率输出,满足大马力农场运营的需求。此外,基于动态规划的控制策略使发动机和电机在高效率的间隔内运行,从而大大降低了燃油消耗。优化后,牵引力条件下的等效油耗从2.76升降至2.5升,降低10.4%。在全负荷工况下,当量油耗由18.55 L降至16.7 L,提高11.02%。这些结果证实了整体能源利用效率的大幅提高。本研究开发的大功率混合动力拖拉机为高效节能农业机械的设计提供了有价值的见解,并为农业工程应用中制定智能能源管理策略提供了实用参考。
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引用次数: 0
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Energy nexus
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