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Resistance to frost action and microbiological corrosion of novel ceramic composites 新型陶瓷复合材料的抗冻作用和微生物腐蚀性能
IF 1.2 4区 工程技术 Q4 CHEMISTRY, APPLIED Pub Date : 2022-01-01 DOI: 10.2298/ciceq210904016j
V. Jovanov, S. Vučetić, S. Markov, B. Angjusheva, E. Fidančevska, J. Ranogajec
This work illustrates the prediction of frost action mechanisms on ceramic compacts, as well as their biocorrosion resistance to fungus action. The ceramic compacts were produced from two raw materials: coal fly ash (40 wt. %) and clay material (60 wt. %). The ceramics models were made in laboratory conditions by pressing (P = 45 MPa), drying (105?C, 3h) and sintering (1100?C, 1h; heating rates 3?C/min and 10?C/min.). The mechanisms responsible for the deterioration of the designed ceramic compacts were defined based on the values of the total porosity, pore size distribution, pore critical radius and the Maage factor, as well as on the values of water permeability. The process of biocorrosion was investigated by using Aspergillus niger fungus as a model microorganism. The different degrees of fungus colonization on the designed compacts were comparatively analysed based on the results of the Scanning Electron Microscopy investigation. The gained results are encouraging as they show that the utilization of fly ash (40 wt. %) in ceramic composites is possible without significantly deterioration of their durability (frost action and microbiological corrosion resistance) compared with the ones whose production was based only on clay material.
这项工作说明了对陶瓷压坯的霜冻作用机制的预测,以及它们对真菌作用的生物耐腐蚀性。陶瓷压坯由两种原料制成:粉煤灰(40 wt. %)和粘土材料(60 wt. %)。在实验室条件下,通过加压(P = 45 MPa)、干燥(105?C, 3h)和烧结(1100?C, 1 h;加热速率3?C/min和10?C/min)。根据总孔隙率、孔径分布、孔隙临界半径、Maage因子以及透水性值,确定了陶瓷压实材料的劣化机理。以黑曲霉为模型微生物,对生物腐蚀过程进行了研究。根据扫描电镜观察结果,对比分析了不同菌落在设计菌落上的程度。获得的结果令人鼓舞,因为它们表明,与仅基于粘土材料生产的陶瓷复合材料相比,在陶瓷复合材料中使用粉煤灰(40 wt. %)而不会显著降低其耐久性(霜冻作用和微生物耐腐蚀性)。
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引用次数: 0
CO2 mitigation studies in packed absorption column using iron oxide nano fluid 使用氧化铁纳米流体的填充吸收柱中二氧化碳减排研究
IF 1.2 4区 工程技术 Q4 CHEMISTRY, APPLIED Pub Date : 2022-01-01 DOI: 10.2298/ciceq210510023s
P. Selvi, R. Baskar
The challenging task in our ecosystem is to reduce acidic gas emissions to some extent. Many gases are emitted from the industries like H2S, CO, CO2, SO2, NO, and NO2 as exhaust gases. Among these gases CO2, NO2 and SO2 are known as acidic gases which result in adverse effects on human beings, animals, and plants. Owing to the increase in the emission of CO2 gases from both anthropogenic and industrial sources, it has resulted in CO2 mitigation studies. CO2 absorption studies have been carried out by employing iron oxide nanofluid with the novel structured packed absorption column. Iron oxide nanoparticles were synthesized and characterized using XRD analysis, SEM analysis, and TEM analysis. Ammonia is used as an absorbent along with iron oxide nanofluid of three different concentrations (0.0001 w/v%, 0.001 w/v%, and 0.0015 w/v%). It was found that the iron oxide nanofluid of 0.0015 w/v% showed an improved % CO2 removal efficiency. This enhanced % CO2 removal efficiency was due to the increased interfacial area of the ameliorated contact between the liquid and gas phase. Along with the packed column the magnetic field was introduced, which resulted in increased % CO2 removal efficiency of 1.5%.
在我们的生态系统中,具有挑战性的任务是在一定程度上减少酸性气体的排放。工业排放许多气体,如H2S、CO、CO2、SO2、NO和NO2作为废气。在这些气体中,CO2、NO2和SO2被称为酸性气体,对人类、动物和植物造成不利影响。由于人为和工业来源的二氧化碳气体排放量增加,因此开展了减缓二氧化碳的研究。采用氧化铁纳米流体和新型结构填充吸收柱对CO2进行了吸附研究。合成了氧化铁纳米颗粒,并用XRD、SEM和TEM对其进行了表征。氨与三种不同浓度(0.0001 w/v%、0.001 w/v%和0.0015 w/v%)的氧化铁纳米流体一起用作吸收剂。结果表明,0.0015 w/v%的氧化铁纳米流体具有较好的CO2去除率。这种提高的% CO2去除效率是由于改善了液相和气相之间的接触,增加了界面面积。在填料塔的同时引入磁场,使CO2去除率提高1.5%。
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引用次数: 0
Effect of the different infrared levels on some properties of sage leaves 不同红外水平对鼠尾草叶片某些特性的影响
IF 1.2 4区 工程技术 Q4 CHEMISTRY, APPLIED Pub Date : 2022-01-01 DOI: 10.2298/ciceq220429030k
Selma Kayacan‐Cakmakoglu, İ. Atik, P. Akman, I. Doymaz, O. Sağdıç, S. Karasu
This study aims to investigate the effect of different infrared powers (IP) (38, 50, 62, 74, and 88 W) on drying kinetics, total phenolic content (TPC) and individual phenolics, antioxidant activity (AA) and antibacterial activity, and color quality of sage leaves. IP level significantly affected (p<0.05) drying kinetics and bioactive contents and color quality of sage leaves. Higher TPC and AA were obtained from the sample dried at 88 W. Rosmarinic acid, caffeic acid, gallic acid, and luteolin were found as major phenolic compounds and their higher levels were obtained from the samples dried at IP level of 88 W. All samples showed antibacterial activity on test pathogens. A higher correlation was observed between TPC, rosmarinic acid level, and antibacterial activity (P>0.80). This study suggested that sage leaves should be dried at 88 W regarding lower drying times and color changes, lower phenolic degradation, and higher antibacterial activity.
研究了不同红外功率(38、50、62、74和88 W)对鼠尾草叶片干燥动力学、总酚含量(TPC)和单个酚类物质含量、抗氧化活性(AA)和抗菌活性以及颜色品质的影响。IP水平显著影响(p0.80)。本研究表明,在88 W的干燥条件下,鼠尾草叶片的干燥时间短,颜色变化少,酚类物质降解率低,抗菌活性高。
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引用次数: 0
Artificial neural network modeling for drying kinetics of paddy using a cabinet tray dryer 稻谷柜式托盘干燥动力学的人工神经网络建模
IF 1.2 4区 工程技术 Q4 CHEMISTRY, APPLIED Pub Date : 2022-01-01 DOI: 10.2298/ciceq220106017s
R. Subramanyam, Meyyappan Narayanan
The study of drying kinetics and characteristics of agricultural products is essential for drying time estimation, designing dryers, and optimizing the drying process. Moisture diffusivity under different drying conditions is crucial to process and equipment design. The drying kinetics of paddy using a cabinet tray dryer was modeled using an Artificial Neural Network (ANN) technique. For predicting moisture ratio and drying rate, the Levenberg-Marquardt (L.M.) training algorithm with TANSIGMOID and TANSIGMOID hidden layer activation function provided superior results. A comparative evaluation of the predicting abilities of ANN and 12 different mathematical drying models was also carried out. The Midilli model was found to be adequate for fitting the experimental data with an R2 comparable to that of the ANN. However, the RMSE observed for ANN (0.0360) was significantly lower than that of the midilli model (0.1673 to 0.712). Effective moisture diffusivity increased with an increase in temperature from 15.05 to 28.5 x 10-9 m2/s. The activation energy for drying paddy grains varied between 6.8 to 7.3 kJ/mol, which showed a moderate energy requirement for moisture diffusion.
研究农产品的干燥动力学和干燥特性对干燥时间的估计、干燥机的设计和干燥工艺的优化具有重要意义。不同干燥条件下的水分扩散率对工艺和设备设计至关重要。采用人工神经网络(ANN)技术对稻谷柜式托盘干燥机的干燥动力学进行了建模。对于水分比和干燥速率的预测,采用TANSIGMOID和TANSIGMOID隐层激活函数的Levenberg-Marquardt (L.M.)训练算法具有较好的预测效果。对比评价了人工神经网络与12种不同干燥数学模型的预测能力。发现Midilli模型足以拟合实验数据,其R2与人工神经网络相当。然而,ANN模型的RMSE(0.0360)显著低于midilli模型的RMSE(0.1673 ~ 0.712)。有效水分扩散率随着温度的升高而增加,从15.05增加到28.5 × 10-9 m2/s。稻谷干燥活化能在6.8 ~ 7.3 kJ/mol之间,水分扩散所需能量适中。
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引用次数: 1
An artificial neural network as a tool for kombucha fermentation improvement 人工神经网络在康普茶发酵过程中的应用
IF 1.2 4区 工程技术 Q4 CHEMISTRY, APPLIED Pub Date : 2022-01-01 DOI: 10.2298/ciceq211013002c
D. Cvetković, O. Šovljanski, Aleksandra Ranitović, A. Tomić, S. Markov, D. Savić, B. Danilović, L. Pezo
Kombucha as a tea-based fermented beverage has become progressively widespread, mainly in the functional food market because of health-improving benefits. As part of a daily diet for adults and children, kombucha stood out as a valuable non-alcoholic drink containing beneficial mixtures of organic acids, minerals, vitamins, proteins, polyphenols, etc. The influence of specific surface area of vessel, inoculum size, and initial tea concentration as operating parameters and fermentation time as output variable on the efficiency of kombucha fermentation was examined. The focus of this study is optimization and standardization of kombucha fermentation conditions using Box-Behnken's experimental design and applying an artificial neural network (ANN) predictive model for the fermentation process. The Broyden-Fletcher-Goldfarb-Shanno iterative algorithm was used to accelerate the calculation. The obtained ANN models for the pH value and titratable acidity showed good prediction capabilities (the r2 values during the training cycle for output variables were 0.990 and 0.994, respectively). Predictive ANN modelling demonstrated to be effective and reliable in establishing optimum kombucha fermentation process using selected operating parameters.
康普茶作为一种以茶为基础的发酵饮料已逐渐普及,主要是在功能性食品市场,因为它具有改善健康的好处。作为成人和儿童日常饮食的一部分,康普茶作为一种有价值的无酒精饮料脱颖而出,它含有有机酸、矿物质、维生素、蛋白质、多酚等有益的混合物。以容器比表面积、接种量、初始茶浓度为操作参数,以发酵时间为输出变量,考察了发酵效果的影响。本研究的重点是采用Box-Behnken实验设计,并应用人工神经网络(ANN)预测模型对康普茶发酵过程进行优化和标准化。采用Broyden-Fletcher-Goldfarb-Shanno迭代算法加速计算。所得的人工神经网络模型对pH值和可滴定酸度具有较好的预测能力(输出变量在训练周期内的r2分别为0.990和0.994)。预测人工神经网络模型被证明是有效和可靠的,在建立最佳的康普茶发酵过程中使用选定的操作参数。
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引用次数: 0
Heat transfer studies in a plate heat exchanger using Fe2O3-water-engine oil nanofluid fe2o3 -水发动机油纳米流体板式换热器的传热研究
IF 1.2 4区 工程技术 Q4 CHEMISTRY, APPLIED Pub Date : 2022-01-01 DOI: 10.2298/ciceq220430029s
P. Srinivasan, Nesakumar Dharmakkan, M. Vishnu, H. Prasath, Ramaraj Gokul, Ganeshan Thiyagarajan, Govindasamy Sivasubramani, Balachandran Moulidharan
Improving heat transfer performance of conventional fluid creates significant energy savings in process Industries. In this aspect, experimental study was performed to evaluate the heat transfer performance of Fe2O3-Water (W)-Engine Oil (EO) nanofluid at different concentrations and different hot fluid inlet temperatures in a plate heat exchanger. Experiments were conducted by mixing Fe2O3 nanoparticle (45 nm) in a base fluid of water-engine oil mixture with volume fractions of 5%EO + 95%W and 10%EO +90%W. Main aim of the present study is to assess the impact of variations in nanoparticle volume fraction and hot fluid inlet temperature on the heat transfer performance of prepared nanofluid. Based on the experimental results, convective heat transfer coefficient, Reynolds, Prandtl and Nusselt number were determined. Result shows that at the hot fluid inlet temperature of 75?C, the increase in Nusselt number and convective heat transfer co efficient are optimum at 0.9 vol. % nanoparticle for both the base fluid mixtures. The increase in heat transfer coefficient is because of the Brownian motion (increasing thermal conductivity) effect, motion caused by temperature gradient (Thermo-phoretic) and motion due to concentration gradient (Osmophoretic). If the volume fraction of nanoparticle increases then Reynolds number increment is higher than Prandtl number decrement, which augments Nusselt number as well as convective heat transfer coefficient.
改善传统流体的传热性能可在过程工业中节省大量能源。为此,在板式换热器中对Fe2O3-Water (W)-Engine Oil (EO)纳米流体在不同浓度和不同热流体入口温度下的换热性能进行了实验研究。将Fe2O3纳米颗粒(45 nm)掺入体积分数为5%EO + 95%W和10%EO +90%W的水-机油混合基液中进行实验。本研究的主要目的是评估纳米颗粒体积分数和热流体入口温度的变化对制备的纳米流体传热性能的影响。根据实验结果,确定了对流换热系数、雷诺数、普朗特数和努塞尔数。结果表明,在热流体进口温度为75?C,在0.9 vol. %纳米颗粒时,两种基液混合物的努塞尔数和对流换热系数的增加都是最佳的。传热系数的增加是由于布朗运动(增加导热系数)效应、温度梯度引起的运动(热渗透)和浓度梯度引起的运动(渗透)。当纳米颗粒体积分数增大时,雷诺数增量大于普朗特数减量,增大了努塞尔数,增大了对流换热系数。
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引用次数: 1
Foamed geopolymer with customized pore structure 具有定制孔隙结构的泡沫地质聚合物
IF 1.2 4区 工程技术 Q4 CHEMISTRY, APPLIED Pub Date : 2022-01-01 DOI: 10.2298/ciceq211007003b
Ida Balczár, Adrienn Boros, A. Kovacs, T. Korim
Geopolymer foams, due to their favorable production conditions and promising properties (e.g. low shrinkage after foaming, mechanical and chemical stability, high temperature resistance) are suitable for use as heat- and sound insulating as well as refractory building materials. Another promising field of application may be their use as catalyst supports in water treatment. Metakaolin based foams were prepared by direct foaming process with high total porosity (> 75 vol%), low bulk density (< 500 kg/m3), approximately 1 MPa compressive strength and low thermal conductivity (0.095 W/mK). By varying the concentration of foaming agent (H2O2 solution) and stabilizing agent (sodium oleate), it is possible to produce foams with designed porosity and pore size distribution. Foams with mainly closed pores are suitable for thermal insulation, while those with significantly open pores can use as catalyst supports. The computed tomography images showed that the concentration of stabilizing agent is a key parameter in the formation of a homogeneous pore structure and open pores; up to 24 vol% open porosity can be achieved without significantly affecting other properties. The physical properties of the foams are equally influenced by the thickness of cell walls and the size of the cells themselves.
地聚合物泡沫材料具有良好的生产条件和良好的性能(发泡后收缩率低、机械化学稳定性好、耐高温等),适合用作隔热隔音和耐火建筑材料。另一个有前景的应用领域可能是它们在水处理中用作催化剂载体。采用直接发泡法制备的偏高岭土基泡沫具有高总孔隙率(> 75 vol%)、低容重(< 500 kg/m3)、抗压强度约1 MPa、低导热系数(0.095 W/mK)等特点。通过改变发泡剂(H2O2溶液)和稳定剂(油酸钠)的浓度,可以制备出具有设计孔隙度和孔径分布的泡沫。以闭孔为主的泡沫适于保温,而开孔明显的泡沫可用作催化剂载体。计算机断层成像结果表明,稳定剂的浓度是形成均匀孔隙结构和开放孔隙的关键参数;在不显著影响其他性能的情况下,可以实现高达24 vol%的孔隙度。泡沫的物理性质同样受到细胞壁厚度和细胞本身大小的影响。
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引用次数: 0
A review on modeling of proton exchange membrane fuel cell 质子交换膜燃料电池模型研究进展
IF 1.2 4区 工程技术 Q4 CHEMISTRY, APPLIED Pub Date : 2022-01-01 DOI: 10.2298/ciceq220126014h
Sahra Hamdollahi, Luo Jun
Fuel cells are electrochemical devices that convert chemical energy into electrical energy. Among various types of fuel cells proton exchange membrane fuel cell (PEMFC) is considered one of the most promising candidates for the next generation power sources because of high power densities, zero-emission, and low operation temperature. In order to understand and study the PEMFC phenomena, modeling has achieved huge attention and interest in recent years. This article reviews recent progress in PEMFC modeling. Empirical/semi-empirical, analytical and mechanistic models, zero to three dimensional models, multiphase flow models such as multiphase mixture, multi-fluid and VOF model are different types of PEMFC modeling approaches respectively in terms of parametric, dimensional and two or three-phase flow. The present study enlightens the importance of combining different modeling strategies and parameter identification in PEMFC modeling to achieve precise models to reduce the time and cost of experiments.
燃料电池是一种将化学能转化为电能的电化学装置。在各种类型的燃料电池中,质子交换膜燃料电池(PEMFC)因其高功率密度、零排放和低工作温度被认为是最有前途的下一代能源之一。为了理解和研究PEMFC现象,建模近年来引起了人们的极大关注和兴趣。本文综述了PEMFC建模的最新进展。经验/半经验模型、解析模型和力学模型、零至三维模型、多相混合流模型、多流体模型和VOF模型等多相流模型是PEMFC在参数流、多维流和两相或三相流方面的不同建模方法。本文的研究揭示了在PEMFC建模中结合不同的建模策略和参数识别来实现精确的模型以减少实验时间和成本的重要性。
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引用次数: 3
Evaluation of variable speed drives to improve energy efficiency and reduce gas emissions: Case study 评估变速驱动器,以提高能源效率和减少气体排放:案例研究
IF 1.2 4区 工程技术 Q4 CHEMISTRY, APPLIED Pub Date : 2022-01-01 DOI: 10.2298/ciceq220318018s
M. Sadek, R. El-Maghraby, Mohamed M. Fathy
Variable speed drives are the most promising technique to reduce electric motors energy consumption. This paper discusses energy savings achieved by installing variable speed drives to control rotating equipment motors such as pumps, compressors, blowers, and fans in oil processing facilities. In addition to energy savings, variable speed drives will improve overall equipment efficiency, increase reliability, and reduce greenhouse gases (GHG) emissions. An Energy audit was performed on a case study to investigate energy consumption for all electric motors. Technical and operational constraints for installing and operating variable speed drives have been discussed. Installation requires adjustments in operation schedules and parameters to allow reducing energy consumption. The case study has illustrated how to calculate energy savings for Pipelines, air coolers, air blowers for furnaces, pumps with variable flow rates and reciprocating compressing systems. Variable speed drives were technically and economically accepted in air blowers, fans, and pumps. Energy consumption and greenhouse gases have been reduced by 67%, Payback period for the whole project was less than 1 year. Meanwhile, it was not valid for reciprocating compressors as the Payback period was 6.2 years.
变速驱动是减少电动机能耗最有前途的技术。本文讨论了通过安装变速驱动器来控制石油加工设施中的旋转设备电机(如泵、压缩机、鼓风机和风扇)所实现的节能。除了节能,变速驱动器将提高整体设备效率,提高可靠性,并减少温室气体(GHG)排放。能源审计是在一个案例研究中进行的,以调查所有电动机的能源消耗。讨论了安装和操作变速驱动器的技术和操作限制。安装时需要调整操作时间表和参数,以降低能耗。案例研究说明了如何计算管道、空气冷却器、炉子鼓风机、可变流量泵和往复式压缩系统的节能。在鼓风机、风扇和泵中,变速驱动器在技术上和经济上都被接受。能源消耗和温室气体排放减少67%,整个项目投资回收期不到1年。对往复式压缩机不适用,投资回收期为6.2年。
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引用次数: 0
Enhancing MRR and accuracy with magnetized graphite tool in electrochemical micromachining of copper 利用磁化石墨刀具提高铜微细电化学加工的MRR和精度
IF 1.2 4区 工程技术 Q4 CHEMISTRY, APPLIED Pub Date : 2022-01-01 DOI: 10.2298/ciceq220731027p
Venugopal Palaniswamy, Kaliappan Seeniappan, Thanigaivelan Rajasekaran, Natrayan Lakshmaiya
Micro hole is the fundamental feature found in any device/components. Hence this paper aims to produces the micro holes using electrochemical micromachining (EMM). The existing machining techniques in EMM for creating micro holes are associated with more overcut (OC). Hence, it is very essential to reduce OC and enhance the machining rate (MR). This paper aspires to investigate the effect of graphite electrode with magnetic force on copper plate. Four different tools namely electromagnetic graphite tool (EMGT), permanent magnet graphite tool (PMGT), graphite tool and stainless steel (SS) tool are employed for these experiments. The major influencing factors are machining voltage in volts, duty cycle in % and electrolyte concentration in g/l was considered on MR and OC. The results exposed that EMGT, PMGT and graphite electrodes produce MR of 106.4%, 74.6 % and 44.5 % over SS tool at parameter level of 23 g/l, 15 V, and 85% respectively. Graphite and EMGT electrode resulting in 11.9% and 3.41 % reduced OC respectively than SS tool at parameter level of 8V, 95% and 28 g/l. Additionally, scanning electron microscope (SEM) picture examination is conducted to identify the magnetic field effect on the work surface.
微孔是任何器件/组件的基本特征。因此,本文旨在利用电化学微加工(EMM)制造微孔。现有的EMM微孔加工技术存在较大的过切现象。因此,降低加工温度,提高加工速率是十分必要的。本文研究了石墨电极对铜板的磁力作用。实验采用了电磁石墨刀具(EMGT)、永磁石墨刀具(PMGT)、石墨刀具和不锈钢刀具(SS)四种不同的刀具。MR和OC分别考虑了加工电压(伏特)、占空比(%)和电解液浓度(g/l)的影响。结果表明,在23 g/l、15 V和85%的参数水平下,EMGT、PMGT和石墨电极的MR分别比SS工具高106.4%、74.6%和44.5%。在8V、95%和28 g/l的参数水平下,石墨电极和EMGT电极的OC分别比SS工具降低11.9%和3.41%。此外,通过扫描电镜(SEM)图像检测,确定磁场对工作表面的影响。
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引用次数: 0
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Chemical Industry & Chemical Engineering Quarterly
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