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Crosslinked whole cells for the sucrose transfructosylation reaction in a continuous reactor 在连续反应器中进行蔗糖转果糖基化反应的交联全细胞
IF 1.2 4区 工程技术 Q3 Chemical Engineering Pub Date : 2023-01-01 DOI: 10.2298/ciceq221220015m
Ribeiro Menossi, Leandro da Rin de Sandre, Giancarlo de Souza Dias, Michelle da Cunha Abreu Xavier, A. D. de Almeida, E. D. da Silva, A. Maiorano, Rafael Firmani Perna, Sergio Andres Villalba Morales
Fructooligosaccharides (FOS) are fructose oligomers that are beneficial to human health and nutrition for being prebiotic sugars. Their production occurs by a transfructosylation reaction in sucrose molecules catalyzed by fructosyltransferase enzymes (FTase, E.C.2.4.1.9) adhered to microbial cells. The purpose of this work was to study the preparation, enzymatic activity, and stability of glutaraldehyde-crosslinked Aspergillus oryzae IPT-301 cells used as biocatalyst for the transfructosylation reaction of sucrose in a packed bed reactor (PBR), aiming at FOS production. The highest transfructosylation activity (AT) was presented by the biocatalyst prepared by crosslinking at 200 rpm and 45 min. The highest AT in the PBR were obtained at 50?C, flow rates from 3 mL min-1 to 5 mL min-1 and sucrose concentrations of 473 g L-1 and 500 g L-1. The enzymatic kinetics was described using the Michaelis-Menten model. Finally, the biocatalyst showed constant AT of approximately 75 U g-1 and 300 U g-1 for 12 h of reaction in the PBR operating in continuous and discontinuous flow, respectively. These results demonstrate a high potential of glutaraldehyde-crosslinked A. oryzae IPT-301 cells as heterogeneous biocatalysts for the continuous production of FOS in PBR reactors.
低聚果糖是一种果糖低聚物,作为益生元糖,对人体健康和营养有益。它们的产生是通过附着在微生物细胞上的果糖基转移酶(FTase, E.C.2.4.1.9)催化蔗糖分子的转果糖基化反应进行的。本研究的目的是研究戊二醛交联米曲霉IPT-301细胞的制备、酶活性和稳定性,该细胞作为生物催化剂在填充床反应器(PBR)中用于蔗糖的转果糖基化反应,以生产FOS。交联制备的生物催化剂在转速为200转/分、转速为45 min时转果糖基化活性最高。C,流速为3ml min-1至5ml min-1,蔗糖浓度为473 g L-1和500 g L-1。采用Michaelis-Menten模型描述酶促动力学。最后,生物催化剂在连续和不连续流动的PBR中反应12小时的恒定AT分别约为75 U g-1和300 U g-1。这些结果表明,戊二醛交联的m.o yzae IPT-301细胞作为PBR反应器中连续生产FOS的非均相生物催化剂具有很高的潜力。
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引用次数: 0
Fluoride removal from phosphogypsum: A study on pre-industrial scale and its mathematical analysis 磷石膏除氟:工业化前规模研究及数学分析
IF 1.2 4区 工程技术 Q3 Chemical Engineering Pub Date : 2023-01-01 DOI: 10.2298/ciceq230203009a
Cemre Avşar, S. Ertunç
This study discusses fluoride removal efficiency from phosphogypsum (PG) on lab-scale experiment matrix designed by Box-Behnken method. Temperature, solid/liquid ratio, and time were introduced as factors into various salt solution media to predict the fluoride removal efficiency from PG. Experiment matrices were designed according to salt solution types, namely sea water, 5% NaCl and 10% NaCl solutions. According to the factor- response analysis, results indicate that fluoride removal efficiency and temperature are directly proportional. The optimum fluoride removal conditions based on the experimental data obtained by the multi-variable design matrix were determined by the Design Expert v 12 software, in which temperature, time, and solid/liquid ratio were reported to be 80?C, 3 h and 0,174 in the case of sea water, respectively. 73,31% fluoride removal was predicted via the optimum conditions determined by the software, however experimental validation studies showed an actual 74,99% fluoride removal efficiency. Since the actual vs. predicted data show high consistency, results might also be useful when industrial-scale fluoride removal to a pre-determined level is required prior to a particular use of PG. This study provides a novel pre-industrial scale fluoride removal inventory especially for fertilizer and cement industry, in which PG has a high potential as an alternative raw material and fluoride removal might be of importance in recycling applications.
采用Box-Behnken法对磷石膏(PG)的除氟效果进行了实验研究。以温度、料液比、时间为影响因素,对不同盐溶液介质中PG的除氟效果进行了预测,并根据盐溶液类型,即海水、5% NaCl和10% NaCl,设计了实验基质。因子响应分析结果表明,除氟效率与温度成正比。基于多变量设计矩阵得到的实验数据,通过design Expert v 12软件确定最佳除氟条件,其中温度、时间、料液比为80?在海水的情况下,分别为3 h和0.174 h。通过软件确定的最佳条件预测除氟率为73,31%,但实验验证研究显示实际除氟率为74,99%。由于实际数据与预测数据显示出高度的一致性,因此当工业规模的氟化物去除需要在特定使用PG之前达到预先确定的水平时,结果也可能有用。本研究为化肥和水泥工业提供了一种新的工业规模的氟化物去除清单,其中PG作为替代原料具有很高的潜力,并且氟化物去除在回收应用中可能很重要。
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引用次数: 0
Effects of exhaust gas recirculation on diesel engine using hybrid biodiesel 废气再循环对混合生物柴油柴油机的影响
IF 1.2 4区 工程技术 Q3 Chemical Engineering Pub Date : 2023-01-01 DOI: 10.2298/ciceq230303022a
S. Ananthakumar, R. Barathiraja, J. Thiyagaraj, M. Ashokkumar
The primary aim of this study is to alternate between conventional fossil fuels and reduce the emissions of greenhouse gases and sulphur dioxide from the diesel engine. In the current study, in order to mitigate NOx emissions, the EGR technique was implemented utilizing hybrid alternate biodiesel at three varying proportions of 5%, 10% and 15% at an optimum compression ratio of 20:1. The findings demonstrate that for a hybrid alternative biodiesel at a compression ratio of 20:1 and fully loaded, the BTHE is 31.8% with 10% EGR. With 15% EGR, the peak pressure for the hybrid biodiesel is lower than it would be without EGR by around 2.28%. When EGR is increased, the ignition delay and NOx emissions are reduced slightly. With only an increase in EGR rates of up to 10%, BSFC values were reduced efficiently. The hybrid biodiesel with 10% EGR achieves a reduction in exhaust gas temperature to 341 ?C.
这项研究的主要目的是在传统化石燃料之间进行替代,减少柴油发动机排放的温室气体和二氧化硫。在目前的研究中,为了减少NOx排放,EGR技术采用混合替代生物柴油,在5%、10%和15%的三种不同比例下,以20:1的最佳压缩比实施。研究结果表明,混合替代生物柴油在压缩比为20:1且满载时,BTHE为31.8%,EGR为10%。当EGR为15%时,混合生物柴油的峰值压力比没有EGR时低2.28%左右。当EGR增加时,点火延迟和NOx排放略有减少。只要EGR率增加10%,BSFC值就会有效降低。10% EGR的混合生物柴油可将废气温度降低至341℃。
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引用次数: 0
Bioaccumulation and biosorption study of heavy metals removal by Cyanobacteria Nostoc sp. 蓝藻去除重金属的生物积累与生物吸附研究。
IF 1.2 4区 工程技术 Q3 Chemical Engineering Pub Date : 2023-01-01 DOI: 10.2298/ciceq220511002r
Irena Rakic, Ž. Kevrešan, Renata Kovač, S. Kravić, Z. Svirčev, Ana Djurovic, Z. Stojanović
Nowadays various industrial and urban activities are resulting in discharging of enormous quantities of various pollutants and their accumulation in the environment. Considering that the presence of heavy metals in wastewater is a serious threat to the environment and human health and that conventional methods for their removal are not highly efficient, the current study mainly focuses to estimate cyanobacterial capability to accumulate different heavy metals from water and compare bioaccumulation and biosorption processes. Cyanobacteria Nostoc sp. was used and five heavy metals were selected for this experiment (Cd2+, Cu2+, Pb2+, Ni2+, Zn2+). Examined concentrations of HMs were 20, 80 and 200 mg/dm3 for the bioaccumulation study while for biosorption experiments 20 and 80 mg/dm3 of each HMs were used. Living cells of Nostoc sp. have the highest affinity for Pb2+ (98.15%) and Cu2+ (95.14%) removal from the solution by bioaccumulation. During the biosorption process, dried biomass of Nostoc sp., besides Pb2+ (92.27%) and Cu2+ (96.00%), shows a high affinity for Cd2+ (91.00%) removal. Living cyanobacterial cells of Nostoc sp. was capable to accumulate 82% of Zn, while dried biomass adsorbs 87% of Zn2+. The highest bioaccumulation of Ni2+ was only 38% while using the process of biosorption it was significantly higher (63.80%). These results could provide a preliminary study for further investigation in the direction of the development of immobilized biosorbents which could be used for industrial effluent treatment.
如今,各种工业和城市活动导致大量各种污染物的排放和它们在环境中的积累。考虑到废水中重金属的存在对环境和人类健康的严重威胁,以及传统的去除方法效率不高,目前的研究主要集中在评估蓝藻对水中不同重金属的富集能力,并比较生物富集和生物吸附过程。以蓝藻Nostoc sp.为研究对象,选取5种重金属(Cd2+、Cu2+、Pb2+、Ni2+、Zn2+)作为实验材料。生物积累实验中,HMs的检测浓度分别为20、80和200 mg/dm3,生物吸附实验中,每种HMs的检测浓度分别为20和80 mg/dm3。Nostoc sp.活细胞对Pb2+(98.15%)和Cu2+(95.14%)的生物富集去除效果最好。在生物吸附过程中,除Pb2+(92.27%)和Cu2+(96.00%)外,Nostoc sp.的干燥生物质对Cd2+(91.00%)具有较高的去除亲和力。Nostoc sp.活的蓝藻细胞能够积累82%的Zn,而干燥的生物质吸附87%的Zn2+。Ni2+的最高生物积累量仅为38%,而采用生物吸附法的Ni2+的最高生物积累量为63.80%。这些结果为进一步研究固定化生物吸附剂的发展方向提供了初步的研究,并可用于工业废水的处理。
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引用次数: 0
Biogas production and greenhouse gas mitigation using fish waste from Bragança/Brazil 利用布拉干帕拉/巴西的鱼类废物生产沼气和减少温室气体
IF 1.2 4区 工程技术 Q3 Chemical Engineering Pub Date : 2023-01-01 DOI: 10.2298/ciceq220614004s
Dayse da Silva, J. V. F. L. Cavalcanti, Adalberto Freire Júnior do Nascimento, S. Peres, Marileide Alves, M. Benachour
The potential of biogas production using fish waste (FW) and its effect on greenhouse gas (GHG) reduction and on energy production were evaluated on this research. FW was co-digested with anaerobic sewage sludge (SS). The FW was collected in the city of Bragan?a, northern Brazil, in which the fish industry is the main activity with a FW production of approximately 9,000 kg?day-1. The experimental part included five SS/FW ratios, and in two experiments hydrogen was added. The experiments were carried out for 30 days and the effect on the cumulative biogas and methane yields were analyzed. The GHG reduction was estimated using the amount of FW not discarded in the Bragan?a open dump; and the electricity generation was calculated using the methane yield. Besides, two kinetic models were performed. The results presented a GHG reduction of 1,619 tons of CO2e and an electricity production of 372 to 956 MWh?year-1. The analysis of variance indicated that the methane production was highly dependent on the SS/FW ratios which ranged from 76 to 138 mL?gvs-1. Finally, this research showed the benefit of using FW to generate biogas and electricity while reducing GHG emissions in a city where there is no energy project.
本研究评价了利用鱼废生产沼气的潜力及其对温室气体减排和能源生产的影响。FW与厌氧污泥(SS)共消化。FW是在布拉根市收集的?a,巴西北部,渔业是主要活动,FW产量约为9,000公斤/天。实验部分包括5个SS/FW比,其中2个实验添加了氢气。试验进行了30 d,分析了其对累积沼气和甲烷产量的影响。温室气体减量是用Bragan?露天垃圾场;利用甲烷产量计算了发电量。此外,还建立了两种动力学模型。结果表明,温室气体排放量减少了1,619吨二氧化碳当量,年发电量为372至956兆瓦时。方差分析表明,甲烷产量高度依赖于SS/FW比,其范围为76 ~ 138 mL?gvs-1。最后,这项研究表明,在一个没有能源项目的城市,使用FW产生沼气和电力同时减少温室气体排放的好处。
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引用次数: 0
Investigation of the thin layer drying of micropropagated Ocimum basilicum L: Modeling by derived equations, quality characteristics, and energy efficiency 微繁罗勒薄层干燥的研究:基于推导方程、质量特性和能量效率的建模
IF 1.2 4区 工程技术 Q3 Chemical Engineering Pub Date : 2023-01-01 DOI: 10.2298/ciceq220722003k
M. Kalender, A. Topdemir
This study presents modeling of thin layer drying of micropropagated O. basilicum L., some quality characteristics of dried product, and energy consumption analysis for the dryer used. In the statistical analyses, the experimental drying data obtained from a previous article were used. Modeling studies were statistically carried out using the experimental data at 1 m/s airflow rate and at the temperature of 30-50?C. The statistical analysis results showed that Verma equation was the best fit model having the lowest chi-square (?2) and AIC values at all temperatures studied. From statistical analyses using derived drying models, it was found that D9 equation having ?2 value of 0.0146 and AIC value of -528.022 was the best model fitting to experimental data. The total phenolic content, flavonoid, and antioxidant capacity of dried basil samples were measured as 2.538 ? 0.029 mg GAE/g, 2.017 ? 0.088 mg quercetin/g, and 2.263 ? 0.001 mmol TEAC/100 g DW, respectively. From FTIR spectra, dried basil samples had typical functional groups. SEM images showed that a collapse in the surface of the leaves occurred. But, this collapse is not affect the functional groups of the surface of the leaves. From energy consumption analyses, optimum drying optimum drying temperature was found to be 40?C. The SMER, MER, and SEC values calculated from energy consumption analysis at 40?C were 0.0043 kg/kWh, 0.0007 kg/h, and 234.81 kWh/kg, respectively.
本文介绍了微繁罗勒薄层干燥的建模、干燥产品的一些品质特性以及所使用的干燥机的能耗分析。在统计分析中,使用了前人文章中获得的实验干燥数据。利用实验数据,在风速为1m /s、温度为30-50℃的条件下,进行了模型研究统计。统计分析结果表明,在所有温度下,Verma方程是具有最低卡方值和AIC值的最佳拟合模型。通过对导出的干燥模型进行统计分析,发现D9方程的?2值为0.0146,AIC值为-528.022是最适合实验数据的模型。测定了罗勒干样品的总酚含量、类黄酮含量和抗氧化能力为2.538 ?0.029 mg GAE/g, 2.017 ?0.088 mg槲皮素/g, 2.263 ?0.001 mmol TEAC/100 g DW。从红外光谱上看,罗勒干样具有典型的官能团。扫描电镜图像显示,叶片表面发生了塌陷。但是,这种塌陷并不影响叶片表面的官能团。通过能耗分析,优选出最佳干燥温度为40℃。SMER、MER和SEC值是根据能耗分析在40?C分别为0.0043 kg/kWh、0.0007 kg/h和234.81 kWh/kg。
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引用次数: 1
Experimental investigation of micro-ECM on MONEL 400 alloy using particles mixed electrolyte 颗粒混合电解液对MONEL 400合金微电解加工的实验研究
IF 1.2 4区 工程技术 Q3 Chemical Engineering Pub Date : 2023-01-01 DOI: 10.2298/ciceq221115013g
L. Gokulanathan, A. Jegan
The machining of extremely hard material in conventional machining requires high energy. Therefore stress-free, burr-free, and high-accuracy machining technique like Electro Chemical Micro Machining (ECMM) with extra features is recommended. To improve efficiency, various electrolytes such as Magnet Associated Electrolytes (MGAE), Metal Particle Mixed Electrolytes (MPME), and Carbon Pellets Mixed Electrolytes (CPME) are employed. The micro-holes were drilled over the work material MONEL 400 alloy. The parameters for the studies are electrolyte type, concentration (g/l), machining voltage (V), and duty cycle (%). The responses of ECMM are estimated through material removal rate (MRR) in ?m/sec and overcut in ?m. The results are optimized using Multi-objective optimization based on ratio analysis (MOORA) and VlseKriterijumska Optimizacija I Kompromisno Resenje (VIKOR). Both techniques produce the same optimal parameter, 18th experiment CPME, 50% duty cycle, 11 V machining voltage, and 28 g/l electrolyte concentration. It is the best optimal parameter solution for machining. According to the ANOVA table of both, the type of electrolyte plays a 62.6 % and 60.37% contribution, respectively, to machining performance. Furthermore, the scanning electron microscope (SEM) image analysis perused on the micro holes to extend the effect of different electrolytes on machining surfaces.
在常规加工中,对极硬材料的加工需要消耗高能量。因此,推荐使用具有额外功能的无应力,无毛刺和高精度加工技术,如电化学微加工(ECMM)。为了提高效率,使用了各种电解质,如磁体相关电解质(MGAE),金属颗粒混合电解质(MPME)和碳颗粒混合电解质(CPME)。在工作材料MONEL 400合金上钻微孔。研究的参数为电解液类型、浓度(g/l)、加工电压(V)和占空比(%)。通过材料去除率(MRR) (m/s)和过切率(m/s)来估计ECMM的响应。采用基于比率分析(MOORA)和VlseKriterijumska Optimizacija I Kompromisno Resenje (VIKOR)的多目标优化方法对结果进行优化。两种技术产生相同的最佳参数,第18次实验CPME, 50%占空比,11 V加工电压,28 g/l电解液浓度。这是加工中最优的参数解。根据两者的方差分析表,电解液类型对加工性能的贡献分别为62.6%和60.37%。此外,通过扫描电镜(SEM)对微孔进行图像分析,探讨了不同电解液对加工表面的影响。
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引用次数: 0
Bed expansion in turbulent bed contactor: Experiments and prediction 紊流床接触器的床膨胀:实验与预测
IF 1.2 4区 工程技术 Q3 Chemical Engineering Pub Date : 2023-01-01 DOI: 10.2298/ciceq230304010b
B. Bensebia, F. Chaouche, O. Bensebia, S. Moustefaï
In this work, the hydrodynamics of the turbulent bed contractor (TBC) have been studied in terms of bed expansion (Hd/Hst) using a particular approach for the prediction of this important property for the design of such equipment. The study is based on 1604 sets of experimental data of the bed expansion, obtained by varying the operating variables (gas velocity, liquid spray, packing characteristics, static bed height and free opening of the supporting grid. The prediction of the bed expansion necessitates the estimation of gas and liquid holdups. To achieve this, we employed a variety of correlations derived from existing literature, comprising six equations for gas holdup and twenty equations for liquid holdup estimation. Out of a total of 120 cases, bed expansion was estimated, and the accuracy of the model was evaluated by calculating the mean absolute error in percentage (MAPE), root mean square error (RMSE), correlation coefficient (?XY), and explained variance (VECV). This study enabled the identification of suitable correlations for gas and liquid holdups, leading to predictions with acceptable errors. Furthermore, statistical analysis was employed in a subsequent phase of the study to determine the most appropriate correlations for predicting bed expansion among those proposed by various authors.
在这项工作中,紊流床承包者(TBC)的流体力学已经在床膨胀(Hd/Hst)方面进行了研究,使用了一种特殊的方法来预测这种设备设计的重要性质。该研究基于1604组床层膨胀实验数据,通过改变操作变量(气速、液体喷雾、填料特性、静态床层高度和支撑网格的自由开度)获得。床层膨胀的预测需要估算气液含率。为了实现这一点,我们采用了来自现有文献的各种相关性,包括6个气体含率方程和20个液体含率估计方程。在总共120例病例中,估计床位扩张,并通过计算平均绝对误差百分比(MAPE)、均方根误差(RMSE)、相关系数(?XY)和解释方差(VECV)来评估模型的准确性。这项研究能够确定气液含率的适当相关性,从而得出可接受误差的预测。此外,在研究的后续阶段,采用统计分析来确定各种作者提出的预测床层膨胀的最合适相关性。
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引用次数: 0
System development for monitoring the production process of freeze-dried samples: A simple and low-cost approach 用于监控冻干样品生产过程的系统开发:一种简单而低成本的方法
IF 1.2 4区 工程技术 Q3 Chemical Engineering Pub Date : 2023-01-01 DOI: 10.2298/ciceq220821016d
Vanessa Dal-Bó, Heitor Nogueira Altino, J. Freire
The data acquisition from the freeze-drying process is important for obtaining freeze-dried samples with the desired final moisture content under various operating conditions. The current study presents in extensive detail a simple and low-cost methodology for the implementation of a data acquisition system in a laboratory-scale freeze dryer. The results showed that the use of higher drying temperatures (40?C) increased the errors involved in the measurements of the mass of material; nevertheless, the application of correction blank curves statistically significantly reduced those errors. In general, the system developed provided precise and accurate measurements of the temporal changes in the sample mass and temperature, and chamber pressure variations, allowing monitoring of the production process of freeze-dried samples with low final moisture contents.
从冻干过程中获取的数据对于在各种操作条件下获得具有所需最终水分含量的冻干样品是重要的。目前的研究提出了广泛的细节,一个简单的和低成本的方法,用于在实验室规模的冷冻干燥机的数据采集系统的实施。结果表明,使用较高的干燥温度(40℃)会增加测量物料质量的误差;然而,校正空白曲线的应用在统计学上显著降低了这些误差。总的来说,开发的系统提供了样品质量和温度的时间变化以及腔室压力变化的精确和准确的测量,允许监测具有低最终水分含量的冻干样品的生产过程。
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引用次数: 0
Numerical simulation of the oscillating thin plate impact on nanofluids flow in channel 振荡薄板冲击通道内纳米流体流动的数值模拟
IF 1.2 4区 工程技术 Q3 Chemical Engineering Pub Date : 2023-01-01 DOI: 10.2298/ciceq230401017j
K. Jehhef, M. Rasheed, M. Siba
The present numerical study aims to present the effect of using a titled oscillating thin plate with different angles of inclination on the Al2O3-water nanofluid flow and heat transfer performance. The subsequent work establishes methods for forming fluid-structure interactions by impact of Al2O3-water nanofluid at 0.1-1.0 vol. % volume fraction upon the thin plate using COMSOL Multiphysics 5.4. The turbulent model is solved using the (k-?) model and the assembly of the flow around the thin plate obstacle has been confirmed at Reynolds number of Re=4?104. It exemplifies how Nanofluid flow interaction can distort structures. The current study donates to the study of the turbulent, two-dimensional, stationary and incompressible flow around an oscillating thin plate that has inclined angles with upstream and downstream that mounted inside a horizontal channel. The numerical study includes investigation the effect of five inclination angles of the thin plate as (30, 60, 90, 120 and 150?) on the pressure, velocity, and temperatures contours of the Al2O3-water nanofluid. Also, the study presented the profile of the drag and left force of the thin plate that causing by the fluid flow. The results showed that the occurrence of a titled oscillating thin plate inside the flow direction leads to an increase pressure drop, von mises deformation stress, x-displacement and drag force fields and the Nusselt number. Where the pressure increased from 2.61?103 to 6.21?103 pa, the von mises stress increased from 4.43?106 to 1.78?107 N/m, and the X-displacement increased from 1.6 to 5.5 mm when increasing the plate angle from 30 to 90?.
本文旨在研究不同倾斜角度的振荡薄板对al2o3 -水纳米流体流动和传热性能的影响。随后的工作利用COMSOL Multiphysics 5.4建立了通过0.1-1.0 vol. %体积分数的al2o3 -水纳米流体冲击薄板形成流固相互作用的方法。采用(k-?)模型求解了紊流模型,确定了雷诺数Re=4?104时薄板障碍物周围流动的集合。它举例说明了纳米流体相互作用如何扭曲结构。目前的研究有助于研究湍流、二维、静止和不可压缩的流动,这些流动围绕一个与上游和下游有倾斜角的振荡薄板,安装在一个水平通道内。数值研究了不同倾角(30度、60度、90度、120度和150度)对氧化铝-水纳米流体压力、速度和温度分布的影响。研究了流体流动对薄板的阻力和左力的影响。结果表明:流动方向内出现有标题的振荡薄板,导致压降、von mises变形应力、x-位移力场和阻力力场以及努塞尔数增大;压强从2.61增加到哪里?103到6.21?103pa时,von mises应力从4.43?106到1.78?当板角从30°增加到90°时,x -位移从1.6 mm增加到5.5 mm。
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引用次数: 0
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Chemical Industry & Chemical Engineering Quarterly
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