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Layouts and tips for a typical final-year chemical engineering graduation project 典型化学工程毕业设计的布局和提示
IF 1 Q4 ENGINEERING, CHEMICAL Pub Date : 2024-07-19 DOI: 10.1515/cppm-2024-0046
A. Khadom
A fundamental step in the education and scientific research processes is the final-year project for undergraduate students. In chemical engineering departments, the final year project has unique properties since it deals with the design and production of specific materials or chemicals. It represents a whole plant design. In the present work, a layout and tips are proposed for a typical final-year chemical engineering graduation project. Six chapters are suggested. Each chapter is given a main theme and subtitles in order to facilitate the writing process of the project. Chapter one represents an introduction to the importance of the material that was produced, material properties, production process, etc. In chapter two, material and energy balance calculations are addressed. Chapter three handled the equipment design. Cost and environmental assessments are discussed in Chapter four. The results of chapters two and three are compared with software outcomes, which can be collected in chapter five. Finally, the main results, conclusion, and recommendations for future work are proposed to be in Chapter six. Furthermore, tips and advice are addressed to assist students in the writing of a typical graduation project.
本科生的毕业设计是教育和科研过程中的一个基本步骤。在化学工程系,毕业设计具有独特性,因为它涉及特定材料或化学品的设计和生产。它代表了整个工厂的设计。本论文提出了典型的化学工程毕业设计的布局和技巧。建议共分六章。每章都有一个主题和小标题,以方便项目的撰写过程。第一章介绍了生产材料的重要性、材料特性、生产工艺等。第二章涉及材料和能量平衡计算。第三章是设备设计。第四章讨论成本和环境评估。第二章和第三章的结果与第五章收集的软件结果进行了比较。最后,第六章提出了主要结果、结论和对未来工作的建议。此外,还提出了一些提示和建议,以帮助学生撰写典型的毕业设计。
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引用次数: 0
A parametric study on syngas production by adding CO2 and CH4 on steam gasification of biomass system using ASPEN Plus 利用 ASPEN Plus 对生物质蒸汽气化系统中添加 CO2 和 CH4 产生合成气的参数研究
IF 1 Q4 ENGINEERING, CHEMICAL Pub Date : 2024-07-09 DOI: 10.1515/cppm-2023-0100
Bingxin Chen
Biomass gasification technology is increasingly employed as an environmentally friendly energy source, primarily due to its minimal impact on the environment and its ability to mitigate pollution. This technology excels in producing gas with exceptionally high hydrogen content, making it a valuable source for both fuel and energy carriers. Hydrogen (H2), renowned for its stability and lack of detrimental environmental effects, holds great significance in various applications related to energy utilization and sustainability. In the current work, wood sawdust was utilized as the biomass feedstock for syngas production. The research focused on examining the impact of introducing carbon dioxide (CO2) and methane (CH4) gases into the Gibbs reactors. The steam gasification process was modeled by the ASPEN Plus software, allowing for comprehensive analysis and simulation of the gasification reactions. According to the obtained results, the modeling performed in this study demonstrates good predictive capability when compared to the experimental data. It was shown that when the ratio of CO2 to biomass (C/B) increases, the MFR (mass flow rates) of H2 as well as CH4 decrease, whereas the flow rates of CO2 and carbon monoxide (CO) increase. These findings indicate the influence of the C/B ratio on the distribution of different gases within the gasification process. The reduction in MFR of hydrogen when transitioning from C/B = 0 to C/B = 1 in modes a and b is quantified as 17.51 % and 16.39 %, respectively. These percentages represent the magnitude of the decrease in hydrogen MFR for each specific mode when comparing two carbon dioxide to biomass ratios. When the CH4 to biomass (M/B) ratio increases, the mass flow rates of H2 exhibit a consistent upward trend, while the MFR of CO2 displays a descending form. Specifically, when in the Gibbs reactor, M/B rises from 0 to 1 for modes a and b, the mass flow rates of H2 experience significant increases of 265 % and 243 %, respectively. These findings underscore the direct relationship between the M/B ratio and hydrogen production, highlighting the potential for enhanced hydrogen yields with higher M/B ratios in the studied modes.
生物质气化技术作为一种环境友好型能源被越来越多地采用,这主要是因为它对环境的影响最小,而且能够减轻污染。这种技术擅长生产氢含量极高的气体,使其成为燃料和能源载体的重要来源。氢气(H2)以其稳定性和对环境无有害影响而闻名,在与能源利用和可持续发展有关的各种应用中具有重要意义。在当前的研究中,木锯屑被用作生产合成气的生物质原料。研究重点是考察在吉布斯反应器中引入二氧化碳(CO2)和甲烷(CH4)气体的影响。ASPEN Plus 软件对蒸汽气化过程进行了建模,对气化反应进行了全面的分析和模拟。根据获得的结果,与实验数据相比,本研究中进行的建模显示出良好的预测能力。结果表明,当二氧化碳与生物质(C/B)的比例增加时,H2 和 CH4 的 MFR(质量流量)降低,而二氧化碳和一氧化碳(CO)的流量增加。这些发现表明了 C/B 比率对气化过程中不同气体分布的影响。在模式 a 和 b 中,当从 C/B = 0 过渡到 C/B = 1 时,氢气的 MFR 分别减少了 17.51 % 和 16.39 %。这些百分比代表了在比较两种二氧化碳与生物质比率时,每种特定模式下氢气 MFR 的下降幅度。当 CH4 与生物质 (M/B) 比率增加时,氢气的质量流量呈持续上升趋势,而二氧化碳的 MFR 则呈下降趋势。具体来说,在吉布斯反应器中,当模式 a 和模式 b 的 M/B 从 0 升至 1 时,H2 的质量流量分别显著增加了 265 % 和 243 %。这些发现强调了 M/B 比率与氢气产量之间的直接关系,突出表明在所研究的模式中,M/B 比率越高,氢气产量越高。
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引用次数: 0
Temperature optimization model to inhibit zero-order kinetic reactions 抑制零阶动力学反应的温度优化模型
IF 1 Q4 ENGINEERING, CHEMICAL Pub Date : 2024-07-05 DOI: 10.1515/cppm-2023-0101
Januardi Januardi, Aditya Sukma Nugraha
Abstract Originally, the Arrhenius parameters were used to estimate the rate of chemical reactions. This article aims to develop the optimal temperature to inhibit specific zero-order kinetic reactions. The model extends the use of the Arrhenius equation and heat capacity modeling to derive the optimal temperature solution. Specifically, the Arrhenius equation, which connects temperature to reaction rates, and the heat equation are formulated to create a comprehensive heat accumulation model. Analytical modeling is utilized through a derivative process to provide optimization. According to a case study of carotene oxidation, the derivative solution proposes −1.73 °C and can extend the reaction time by 206,160.29 days compared to a solution with no temperature change. The derivative solution also offers higher advantages in practical application than setting the lowest temperature limit due to the high initial energy requirement. The temperature derivative solution exhibits a global optimum property because of its high heat accumulation and slower kinetic reactions. These slower kinetic reactions can prevent reactant substances from deteriorating, making them valuable for maintaining a chemical’s shelf life. The temperature solutions offer valuable insights for devising an effective temperature strategy to inhibit specific chemical processes and verifying the relationship between temperature and heat accumulation with curvature.
摘要 阿伦尼乌斯参数最初用于估算化学反应的速率。本文旨在开发抑制特定零阶动力学反应的最佳温度。该模型扩展了阿伦尼乌斯方程和热容量模型的使用,从而得出最佳温度解决方案。具体来说,将温度与反应速率联系起来的阿伦尼乌斯方程和热量方程被用来建立一个综合的热量积累模型。分析模型通过导数过程进行优化。根据胡萝卜素氧化的案例研究,与温度不变的解决方案相比,导数解决方案建议温度为-1.73 °C,可将反应时间延长 206160.29 天。由于初始能量要求较高,导数方案在实际应用中也比设定最低温度限制具有更高的优势。温度导数溶液具有全局最优特性,因为其热量积累高,动力学反应速度较慢。这些较慢的动力学反应可以防止反应物质变质,因此对保持化学品的保质期很有价值。温度解决方案为设计有效的温度策略以抑制特定化学过程以及验证温度和热量积累与曲率之间的关系提供了宝贵的见解。
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引用次数: 0
Numerical investigation of discharge pressure effect on steam ejector performance in renewable refrigeration cycle by considering wet steam model and dry gas model 通过考虑湿蒸汽模型和干气模型,对排放压力对可再生制冷循环中蒸汽喷射器性能的影响进行数值研究
IF 1 Q4 ENGINEERING, CHEMICAL Pub Date : 2024-07-04 DOI: 10.1515/cppm-2023-0092
Yongman Lin, Zaijin Xie, Weihua Guan, Lili Gan
Abstract In recent times, steam ejectors have garnered significant interest among researchers due to their environmental friendliness and the utilization of low-grade energy sources. However, a key drawback of the ejector refrigeration cycle (ERC) is its relatively low coefficient of performance (COP). Understanding the behavior of ejectors under various operating conditions is crucial for addressing this concern. This study specifically focuses on investigating the flow characteristics of ejectors in the single-choking mode. Both dry steam model (DSM) and wet steam model (WSM) are employed to analyze and evaluate the performance in this study. Based on the findings, it is evident that the discharge pressure (DP) significantly influences the flow characteristics. With increasing DP, there is a decrease in the Mach number and liquid mass fraction (LMF) within the ejector, while the temperature distribution shows an upward trend. Additionally, as the DP increases, there is a notable decline in the entrainment ratio (ER) and production entropy. With an increase in the DP, both the DSM and WSM exhibit similar trends. However, in the DSM, the ER reaches zero at an earlier stage compared to the WSM. Specifically, when the DP rises from 5000 Pa to 5600 Pa, there is a 12.6 % increase in the production entropy in the WSM, while the DSM experiences a slightly higher increase of 12.9 %.
摘要 近来,蒸汽喷射器因其环保性和可利用低品位能源而备受研究人员的关注。然而,喷射器制冷循环(ERC)的一个主要缺点是性能系数(COP)相对较低。要解决这一问题,了解喷射器在各种运行条件下的行为至关重要。本研究特别侧重于研究单焦化模式下喷射器的流动特性。本研究采用干蒸汽模型(DSM)和湿蒸汽模型(WSM)来分析和评估其性能。研究结果表明,排放压力(DP)对流动特性有显著影响。随着 DP 的增大,喷射器内的马赫数和液体质量分数 (LMF) 会下降,而温度分布则呈上升趋势。此外,随着 DP 的增加,夹带率 (ER) 和生产熵也明显下降。随着 DP 的增加,DSM 和 WSM 都呈现出类似的趋势。然而,与 WSM 相比,在 DSM 中,ER 在更早的阶段归零。具体来说,当 DP 从 5000 Pa 升至 5600 Pa 时,WSM 的生产熵增加了 12.6%,而 DSM 的增幅略高,为 12.9%。
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引用次数: 0
Energy efficiency in cooling systems: integrating machine learning and meta-heuristic algorithms for precise cooling load prediction 冷却系统的能效:整合机器学习和元启发式算法,实现精确的冷却负荷预测
IF 1 Q4 ENGINEERING, CHEMICAL Pub Date : 2024-07-01 DOI: 10.1515/cppm-2024-0006
Kunming Xu
Abstract Since cooling load estimation directly impacts air conditioning control and chiller optimization, it is essential for increasing the energy efficiency of cooling systems. Machine learning outshines traditional regression analysis by efficiently managing vast datasets and discerning complex patterns influenced by various factors like occupancy, building materials, and meteorology. These capabilities greatly enhance building management and energy optimization. The primary objective of this study is to introduce a framework based on ML algorithms to accurately predict cooling loads in buildings. The Decision Tree model was chosen as the core algorithm for this purpose. Furthermore, as an innovative approach, four metaheuristic algorithms – namely, the Improved Arithmetic Optimization Algorithm, Prairie Dog Optimization, Covariance Matrix Adaptation Evolution Strategy, and Coyote Optimization Algorithm – were employed to enhance the predictive capabilities of the Decision Tree model. The dataset which utilized in this study derived from previous studies, the data comprised of eight input parameters, including Relative Compactness, Surface Area, Wall Area, Roof Area, Overall Height, Orientation, Glazing Area, and Glazing Area Distribution. With an astonishing R2 value of 0.995 and a lowest Root Mean Square Error value of 0.660, the DTPD (DT + PDO) model performs exceptionally well. These astounding findings demonstrate the DTPD model’s unmatched precision in forecasting the results of cooling loads and point to its potential for useful implementation in actual building management situations. Properly predicting and managing cooling loads ensures that indoor environments remain comfortable and healthy for occupants. Maintaining optimal temperature and humidity levels not only enhances comfort but also supports good indoor air quality.
摘要 由于冷却负荷估算直接影响空调控制和冷却器优化,因此对于提高冷却系统的能效至关重要。机器学习能有效地管理庞大的数据集,并辨别受占用、建筑材料和气象等各种因素影响的复杂模式,因而优于传统的回归分析。这些功能极大地增强了楼宇管理和能源优化。本研究的主要目的是引入一个基于 ML 算法的框架,以准确预测建筑物的冷却负荷。为此,我们选择了决策树模型作为核心算法。此外,作为一种创新方法,还采用了四种元启发式算法,即改进算术优化算法、草原犬优化算法、科沃斯矩阵适应进化策略和土狼优化算法,以增强决策树模型的预测能力。本研究中使用的数据集来自先前的研究,数据由八个输入参数组成,包括相对紧凑度、表面积、墙体面积、屋顶面积、总高度、朝向、玻璃面积和玻璃面积分布。DTPD (DT + PDO)模型的 R2 值达到了惊人的 0.995,均方根误差最小值为 0.660,表现非常出色。这些惊人的发现表明,DTPD 模型在预测冷负荷结果方面具有无与伦比的精确性,并指出了其在实际建筑管理中的应用潜力。正确预测和管理冷负荷可确保室内环境保持舒适,并保证居住者的健康。保持最佳的温度和湿度水平不仅能提高舒适度,还能保证良好的室内空气质量。
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引用次数: 0
Natural pigment indigoidine production: process design, simulation, and techno-economic assessment 天然色素靛红的生产:工艺设计、模拟和技术经济评估
IF 0.9 Q3 Chemical Engineering Pub Date : 2024-06-11 DOI: 10.1515/cppm-2023-0098
Jhared Axel Mora-Jiménez, Vanessa Andreina Alvarez-Rodriguez, Sebastián Cisneros-Hernández, Carolina Ramírez-Martínez, Alberto Ordaz
Abstract Natural pigment production represents an innovative and sustainable alternative to synthetic pigments. However, its industrial production to meet the global demand for pigments poses technological and economic challenges. In this work, a process design and simulation were conducted using SuperPro Designer to produce a blue natural pigment known as indigoidine, which is in high demand as a natural alternative to synthetic blue dyes in industries. The process design included upstream, bioreaction, and downstream processing to produce 113 tons per year of dry indigoidine. For the conception and design of the bioprocess, experimental data reported in the literature, such as kinetic and stoichiometric parameters, culture media, feeding strategy, and volumetric power input, were taken into account. The economic and profitability indicators of four scenarios were assessed based on a base scenario, which involved changing the typical stirred tank reactor to an airlift reactor, decreasing indigoidine recovery, and reducing biomass production. It was estimated that the use of an airlift reactor significantly improves the profitability of the bioprocess, while a 50 % decrease in biomass concentration (less than 40 g/L) significantly affected the profitability of the process. Finally, an equilibrium production point of around 56 tons per year was determined to balance total revenues with operational costs. This is the first work that offers valuable insights into the scaling-up of natural pigment indigoidine production using bacteria.
摘要 天然色素生产是合成色素的一种创新型可持续替代品。然而,为满足全球对颜料的需求而进行的工业化生产却带来了技术和经济上的挑战。在这项工作中,我们使用 SuperPro Designer 进行了工艺设计和模拟,以生产一种名为靛玉红的蓝色天然色素。工艺设计包括上游、生物反应和下游加工,每年可生产 113 吨干靛蓝。在构思和设计生物工艺时,考虑了文献中报道的实验数据,如动力学和化学计量参数、培养基、进料策略和容积功率输入。在基本方案的基础上,对四种方案的经济和盈利指标进行了评估,其中包括将典型的搅拌罐反应器改为气浮反应器、降低靛红素回收率和减少生物质产量。据估计,使用气提反应器可显著提高生物工艺的盈利能力,而生物质浓度降低 50%(低于 40 克/升)则会显著影响工艺的盈利能力。最后,确定了每年 56 吨左右的平衡生产点,以平衡总收入和运营成本。这是利用细菌扩大天然色素靛红生产规模的第一项有价值的研究成果。
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引用次数: 0
Hydrodynamic simulation-informed compartment modelling of an annular centrifugal contactor 环形离心接触器的流体动力学仿真隔室建模
IF 0.9 Q3 Chemical Engineering Pub Date : 2024-05-08 DOI: 10.1515/cppm-2023-0091
Banu Bulut Acar, Maram Al-Sayaghi, Alex Fells, Bruce Hanson
The geometrical and hydraulic parameters have a great impact on the mass transfer characteristics of annular centrifugal contactors. The objective of this study is to evaluate the mass transfer performance of a single annular centrifugal contactor by applying the computational fluid dynamics informed compartment modelling approach. In the study, a steady state compartment model of an annular centrifugal contactor is developed in gProms general purpose process modeller by using the hydrodynamic parameters obtained from computational fluid dynamics simulations performed in OpenFOAM with the GEneralised Multifluid Modelling Approach (GEMMA). The mass transfer rate predicted by the developed compartment model is compared with data obtained from uranium extraction with Tributyl Phosphate experiments performed with a laboratory-scale annular centrifugal contactor. Uranium concentrations in the organic and aqueous outlets and the mass transfer rate evaluated by the developed compartmented contactor model are in good agreement with the experimental data. The results reveal that the use of a hydrodynamic-informed compartment modelling approach raises the possibility of designing full-scale annular centrifugal contactors without the need for detailed computational fluid dynamics simulations and the prediction of mass transfer performance of the whole system from laboratory scale experiments.
几何参数和水力参数对环形离心接触器的传质特性有很大影响。本研究的目的是应用计算流体动力学的隔室建模方法,评估单个环形离心接触器的传质性能。在这项研究中,利用在使用通用多流体建模方法(GEMMA)的 OpenFOAM 中进行计算流体动力学模拟时获得的流体动力学参数,在 gProms 通用过程建模器中开发了环形离心接触器的稳态隔室模型。将所开发的分室模型预测的传质速率与使用实验室规模的环形离心接触器进行的磷酸三丁酯铀萃取实验所获得的数据进行了比较。有机物和水出口中的铀浓度以及所开发的分室接触器模型评估的传质速率与实验数据非常吻合。研究结果表明,采用流体动力学分室建模方法可以设计全尺寸环形离心接触器,而无需进行详细的计算流体动力学模拟,也无需根据实验室规模的实验来预测整个系统的传质性能。
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引用次数: 0
CPPM special issue in honor of Professor Faïçal Larachi 纪念 Faïçal Larachi 教授的 CPPM 特刊
IF 0.9 Q3 Chemical Engineering Pub Date : 2024-05-06 DOI: 10.1515/cppm-2024-0024
S. Hamoudi
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引用次数: 0
Simulation of single-effect and triple-effect evaporator for fruit juice concentration using Aspen HYSYS 使用 Aspen HYSYS 模拟浓缩果汁的单效和三效蒸发器
IF 0.9 Q3 Chemical Engineering Pub Date : 2024-04-16 DOI: 10.1515/cppm-2023-0093
Khalid W. Hameed, A. Khadom, Hameed B. Mahood
One of the most popular methods of fruit juice preservation is concentration since it offers a variety of advantages, like decreased volume, weight, packing, simpler transportation and handling, and a longer shelf life. The present paper studied the evaporation of fruit juice in single- and triple-effect evaporators using Aspen HYSYS software. The amount of juice was 3000 kg/h, and its concentration was raised from 10 to 50 °Brix. Four evaporator layouts were estimated and optimized: single-effect, modified single-effect, forward triple-effect, and triple-effect in parallel. It is a study of the effect of the temperature of saturated steam (120–300 °C) used to concentrate the juice and the pressure of the product (15–50 kPa) on the mass flow rate of steam required, economy, and overall heat transfer coefficient times area (UA) of the evaporator. The best operating conditions for each type of evaporation system were 15 kPa of the product’s pressure for all types of evaporators, 192, 240, 182, and 210 °C of the single-effect, modified single-effect, forward triple-effect, and parallel triple-effect, respectively. These operating conditions are equivalent to the steam required, economy, UA, and steam cost as follows: for each type, they were (3075, 338.4, 1224, and 1100 kg/h), (0.78, 7.1, 1.96, and 2.15), (40,182, 74,505, 539,987, 152,173 kJ/°C h), and (12.68 × 103, 12.76 × 103, 12.65 × 103, and 12.73 × 103 $/h), respectively.
浓缩果汁是最受欢迎的果汁保存方法之一,因为它具有多种优点,如体积小、重量轻、包装简便、运输和处理简单以及保质期长。本文使用 Aspen HYSYS 软件研究了果汁在单效和三效蒸发器中的蒸发过程。果汁量为 3000 公斤/小时,浓度从 10 °Brix 提高到 50 °Brix。对四种蒸发器布局进行了估算和优化:单效蒸发器、改进型单效蒸发器、正向三效蒸发器和并联三效蒸发器。研究了用于浓缩果汁的饱和蒸汽温度(120-300 °C)和产品压力(15-50 kPa)对所需蒸汽质量流量、经济性和蒸发器整体传热系数乘以面积(UA)的影响。各类蒸发系统的最佳运行条件是:所有类型蒸发器的产品压力均为 15 kPa;单效、改良单效、正向三效和并联三效的温度分别为 192、240、182 和 210 ℃。这些运行条件相当于所需蒸汽量、经济性、UA 和蒸汽成本如下:对于每种类型,它们分别为(3075、338.4、1224 和 1100 kg/h)、(0.78、7.1、1.96 和 2.15)、(40 182、74 505、539 987 和 152 173 kJ/°C h)和(12.68 × 103、12.76 × 103、12.65 × 103 和 12.73 × 103 $/h)。
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引用次数: 0
Liquid-liquid flow pattern and mass transfer in a rotating millimeter channel reactor 旋转毫米通道反应器中的液-液流动模式和质量传递
IF 0.9 Q3 Chemical Engineering Pub Date : 2024-03-18 DOI: 10.1515/cppm-2023-0049
Liang Zheng, Yu-Hui Qi, Hai-Long Liao, Hai-Kui Zou, Ouyang Yi, Yong Luo, Jian-Feng Chen
Currently, microchannels are widely used in liquid-liquid heterogeneous mass transfer systems due to its excellent mass transfer performance. However, because of the passive mixing principle of traditional microchannels, the improvement of mass transfer performance has a bottleneck. This work proposes a novel rotating millimeter channel reactor (RMCR), capable of achieving liquid-liquid heterogeneous mass transfer enhance by centrifugal force. Three typical flow patterns of slug flow, parallel-droplet flow, and parallel flow in the RMCR were observed by high-speed photography technology. The volumetric mass transfer coefficient (K O a) of the RMCR increased with the increase of the total volumetric flow rate and rotational speed (N) increased. Compared with N = 0 r/min, the K O a of the RMCR increases by 61.5 % at 200 r/min, ranging from 0.013 to 0.021 s−1. The RMCR proposed in this work is expected to be applied to the liquid-liquid heterogeneous mass transfer system with high processing capacity and easy plugging.
目前,微通道因其优异的传质性能被广泛应用于液液异质传质系统中。然而,由于传统微通道的被动混合原理,传质性能的提高存在瓶颈。本研究提出了一种新型旋转毫米通道反应器(RMCR),能够通过离心力实现液-液异质传质增强。通过高速摄影技术观察了 RMCR 中的三种典型流动模式,即蛞蝓流、平行液滴流和平行流。随着总容积流量和转速(N)的增加,RMCR 的容积传质系数(K O a)也随之增加。与 N = 0 r/min 相比,RMCR 的 K O a 在 200 r/min 时增加了 61.5%,范围在 0.013 到 0.021 s-1 之间。本研究提出的 RMCR 可望应用于具有高处理能力和易堵塞的液-液异质传质系统。
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引用次数: 0
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Chemical Product and Process Modeling
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