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Intensification of thorium biosorption onto protonated orange peel using the response surface methodology 响应面法强化质子化橘皮对钍的生物吸附
IF 0.9 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-03-03 DOI: 10.1515/cppm-2022-0085
A. A. Ghorbanpour Khamseh, Younes Amini, Mohammad Mahdi Shademan, V. Ghazanfari
Abstract In this research work, intensifying the possibility of protonated orange peel to uptake thorium (IV) ions from aqueous solutions in a batch system was investigated and optimized using the response surface methodology. The effect of three independent process variables including thorium initial concentration, pH, and biosorbent dosage was assessed based on the central composite design. The validity of the quadratic model was verified by the coefficient of determination. The optimization results showed that the rate of thorium (IV) uptake under optimal conditions is 183.95 mg/g. The modeling results showed that the experimental data of thorium biosorption kinetics are fitted well by the pseudo-second-order model. According to the results, the biosorption process reached equilibrium after around 4 h of contact. The Langmuir isotherm describes the experimental biosorption equilibrium data well. The maximum absorption capacity of protonated orange peel for thorium adsorption was estimated by the Langmuir isotherm at 236.97 mg/g. Thermodynamic studies show that thorium adsorption on protonated orange peel is thermodynamically feasible, spontaneous, and endothermic.
摘要在本研究工作中,使用响应面方法研究并优化了质子化橙皮在间歇系统中从水溶液中吸收钍(IV)离子的可能性。基于中心复合设计评估了三个独立工艺变量的影响,包括钍初始浓度、pH和生物吸附剂剂量。确定系数验证了二次模型的有效性。优化结果表明,在最佳条件下,钍(IV)的吸收率为183.95mg/g。模拟结果表明,拟二阶模型对钍生物吸附动力学实验数据拟合良好。根据结果,生物吸附过程在接触约4小时后达到平衡。Langmuir等温线很好地描述了实验生物吸附平衡数据。通过Langmuir等温线估计质子化橙皮对钍吸附的最大吸收容量为236.97mg/g。热力学研究表明,钍在质子化橙皮上的吸附在热力学上是可行的、自发的和吸热的。
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引用次数: 9
Prediction of effect of wind speed on air pollution level using machine learning technique 利用机器学习技术预测风速对大气污染水平的影响
IF 0.9 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-02-20 DOI: 10.1515/cppm-2022-0052
Anuradha Pandey, Vipin Kumar, A. Rawat, Nekram Rawal
Abstract Air pollution is one of the most challenging issues poses serious threat to human health and environment. The increasing influx of population in metropolitan cities has further worsened the situation. Quantifying the air pollution experimentally is quite a challenging task as it depends on many parameters viz., wind speed, wind temperature, relative humidity, temperature etc. It requires the investment of huge money and manpower for controlling air pollution. Machine learning technique-based computer modelling reduces both of the parameters. In the present work, the dependence of air pollution level on wind speed and temperature has been taken up using machine learning in the form of ANN and LSTM model. The recorded data of air pollution level (PM2.5) is collected from a measurement station of Lucknow city situated at Central School, CPCB. The data is used in an Artificial Neural based network and in an LSTM model to predict suitably the level of air pollution for a known value of average wind speed and temperature without experimental measurements. LSTM model is found to predict the pollution level better than ANN for the developed ANN networks.
摘要空气污染是最具挑战性的问题之一,对人类健康和环境构成严重威胁。大都市人口的不断涌入使情况进一步恶化。实验量化空气污染是一项极具挑战性的任务,因为它取决于许多参数,即风速、风速、相对湿度、温度等。控制空气污染需要投入巨额资金和人力。基于机器学习技术的计算机建模减少了这两个参数。在目前的工作中,空气污染水平对风速和温度的依赖性已经使用机器学习以ANN和LSTM模型的形式进行了研究。空气污染水平(PM2.5)的记录数据是从勒克瑙市位于CPCB中央学校的一个测量站收集的。该数据用于基于人工神经的网络和LSTM模型,以在没有实验测量的情况下,适当地预测平均风速和温度的已知值的空气污染水平。对于所开发的人工神经网络,LSTM模型比人工神经网络更能预测污染水平。
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引用次数: 0
A nonlinear autoregressive exogenous neural network (NARX-NN) model for the prediction of solvent-based oil extraction from Hura crepitans seeds 基于非线性自回归外源神经网络(NARX-NN)模型的胡拉籽溶剂萃取过程预测
IF 0.9 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-02-15 DOI: 10.1515/cppm-2022-0032
Olajide Olukayode Ajala, Joel Olatunbosun Oyelade, E. Oke, O. Oniya, B. K. Adeoye
Abstract Vegetable oils are a crucial source of raw materials for many industries. In order to meet the rising demand for oil on global scale, it has become essential to investigate underutilized plant oilseeds. Hura crepitans seeds are one of the underused plant oilseeds from which oil can be produced via solvent-based extraction. For the purpose of predicting the oil yield from Hura crepitans seeds, the extraction process was modelled using a nonlinear autoregressive exogenous neural network (NARX-NN). The input variables to the model are seed/solvent ratio, extraction temperature and extraction time, while oil yield is the response output variable. NARX-NN model is based on 200 data samples, and model architecture comprises of 3 inputs, 1 hidden layer (with 15 neurons) and 1 output with 2 delay elements. The performance evaluation was carried out to examine the accuracy of the developed model in predicting oil yield from Hura crepitans using different statistical indices. The overall correlation coefficient, R (0.80829), mean square error, MSE (0.0120), root mean square error, RMSE (0.1080) and standard prediction error, SEP (0.1666) show that NARX-NN model can accurately be used for the prediction oil yield from Hura crepitans seeds.
摘要植物油是许多工业原料的重要来源。为了满足全球范围内日益增长的石油需求,研究未充分利用的植物油籽变得至关重要。胡拉可丽草籽是一种未被充分利用的植物油籽,可以通过溶剂萃取生产油。为了预测Hura crepitans种子的产油量,使用非线性自回归外源神经网络(NARX-NN)对提取过程进行了建模。模型的输入变量是种子/溶剂比、提取温度和提取时间,而油产量是响应输出变量。NARX-NN模型基于200个数据样本,模型架构包括3个输入、1个隐藏层(具有15个神经元)和1个具有2个延迟元件的输出。进行性能评估是为了检验所开发的模型在使用不同的统计指数预测Hura可丽耐油产量方面的准确性。总体相关系数R(0.80829)、均方误差MSE(0.0120)、均方根误差RMSE(0.1080)和标准预测误差SEP(0.1666。
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引用次数: 1
Numerical simulation of fluid flow mixing in flow-focusing microfluidic devices 聚焦微流控装置中流体混合流动的数值模拟
IF 0.9 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-02-09 DOI: 10.1515/cppm-2022-0023
Halimeh Aghaei, A. R. Solaimany Nazar
Abstract A numerical simulation through computational fluid dynamics is presented on the fluid flow mixing in a flow-focusing microfluidic device with three inlet channels confluence angles of 45, 67.5, and 90°. The effect of various parameters such as aspect ratio (0.5, 1, and 1.5), mixing channel length (1–4 mm), and Reynolds number (1–20) on the mixing efficiency, and the pressure drop are evaluated. The results demonstrate that the increase in mixing efficiency results from an increase in the Reynolds number and aspect ratio for all the angles. In addition, an increase in the pressure drop due to an increase in the Reynolds number and a decrease in the aspect ratio is observed. A longer length of the mixing channel indicates a higher mixing efficiency. The mixing efficiency is more suitable at an angle of 45° among the applied angles in terms of the operational and geometric parameters due to an increase in the contact surface of the flows at the inlet channels junction since the mixing index range is between 0.54 and 1 by varying the mentioned parameters.
摘要采用计算流体力学方法对进口通道合流角分别为45°、67.5°和90°的聚焦式微流控装置内的流体混合进行了数值模拟。考察了宽高比(0.5、1和1.5)、混合通道长度(1 ~ 4 mm)和雷诺数(1 ~ 20)等参数对混合效率和压降的影响。结果表明,混合效率的提高是由于各角度雷诺数和展弦比的增加。此外,由于雷诺数的增加和展弦比的减小,压降也会增加。混合通道长度越长,混合效率越高。从操作参数和几何参数的角度来看,由于进口通道交界处流动的接触面增加,混合指数范围在0.54 ~ 1之间,因此在45°角处的混合效率更合适。
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引用次数: 0
Frontmatter 头版头条
Q4 ENGINEERING, CHEMICAL Pub Date : 2023-02-01 DOI: 10.1515/cppm-2023-frontmatter1
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引用次数: 0
Pharmaceutical wastewater treatment using TiO2 nanosheets deposited by cobalt co-catalyst as hybrid photocatalysts: combined experimental study and artificial intelligence modeling 钴助催化剂沉积TiO2纳米片作为混合光催化剂处理制药废水:实验研究与人工智能建模相结合
IF 0.9 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-01-24 DOI: 10.1515/cppm-2022-0070
Amin Esmaeili, Salar Heydari Shalmani, Azadeh Ebrahimian Pirbazari, Fatemeh Esmaeili Khalil Saraei, Fatemeh-Sadat Tabatabai-Yazdi, Ali Ebrahimian Pirbazari, Ali Derakhshesh
Abstract In this work, we developed a facile method for photocatalytic deposition of cobalt atoms as co-catalyst on TiO2 nanosheets (Co(x)/T) under visible light instead of UV irradiation for the first time. The deposition of cobalt atoms on TNs in the Co(x)/T samples was confirmed by DRS, Raman spectroscopy, photoluminescence, nitrogen physisorption, and TEM analyses. The size of cobalt nanoparticles/cluster dispersed on the TiO2 nanosheets were in the range of 5–20 nm according to TEM results. The PXRD patterns showed that the crystal structure and the anatase phase of TNs were preserved in the Co(x)/T samples after the visible light-assisted deposition process. The Co(x)/T samples showed higher activity compared to pure TiO2 nanosheets for the visible light degradation of tetracycline (TC) as pharmaceutical pollutant due to presence of cobalt co-catalyst. We studied the effect of several parameters on the degradation process and proposed the mechanism of degradation according to quenching experiments results. Due to time-consuming and costly of experimental works, we designed two strong artificial intelligence (AI) models (artificial neural networks (ANN) and neuro-fuzzy inference systems (ANFIS)) to estimate the removal process of TC, and predict the removal percent of TC for new values of inputs before performing experiment. The experimental and computational studies showed that the fabricated photocatalysts are as promising candidates for industrial wastewater treatment to meet environmental regulations and provide a new avenue for practical implications.
摘要在这项工作中,我们首次开发了一种在可见光下而不是紫外线照射下在TiO2纳米片(co(x)/T)上光催化沉积钴原子作为助催化剂的简单方法。通过DRS、拉曼光谱、光致发光、氮物理吸附和TEM分析证实了钴原子在Co(x)/T样品中的TNs上的沉积。根据TEM结果,分散在TiO2纳米片上的钴纳米颗粒/团簇的尺寸在5–20 nm范围内。PXRD图谱显示,在可见光辅助沉积工艺后,在Co(x)/T样品中保留了TNs的晶体结构和锐钛矿相。由于钴助催化剂的存在,与纯TiO2纳米片相比,Co(x)/T样品在可见光降解作为药物污染物的四环素(TC)方面表现出更高的活性。研究了几个参数对降解过程的影响,并根据淬火实验结果提出了降解机理。由于实验工作耗时且成本高昂,我们设计了两个强人工智能(AI)模型(人工神经网络(ANN)和神经模糊推理系统(ANFIS))来估计TC的去除过程,并在进行实验前预测新输入值的TC去除率。实验和计算研究表明,所制备的光催化剂是工业废水处理的有前途的候选者,符合环境法规,并为实际应用提供了新的途径。
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引用次数: 0
pH prediction for a semi-batch cream cheese fermentation using a grey-box model 用灰盒模型预测半批奶油奶酪发酵的pH值
IF 0.9 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-01-16 DOI: 10.1515/cppm-2021-0048
Shiying Guo, Wei Yu, David I. Wilson, B. Young
Abstract Cream cheese, a popular condiment, is widely used in people’s daily diet and in dessert making. To ensure high-quality cream cheese production, the pH value is generally used as the indicator to determine the end point of cream cheese fermentation. The inoculation time and time-dependent concentrations of biomass, lactose, lactic acid are all crucial for pH prediction. However, the inoculation time could vary for industrial applications with multiple fermenters. Moreover, the inoculation time impact on fermentation has not been investigated. This paper aims to build a cream cheese fermentation model predicting pH. The model includes a semi-batch kinetic model and an artificial neural network (ANN) model. The outcome of the model will help the cream cheese industries understand the inoculation time impact on fermentation time and organise better fermenter scheduling.
奶油奶酪是一种受欢迎的调味品,广泛应用于人们的日常饮食和甜点制作中。为保证生产出高质量的奶油奶酪,一般以pH值作为确定奶油奶酪发酵终点的指标。接种时间和随时间变化的生物量、乳糖、乳酸浓度都是预测pH值的关键。然而,接种时间可以改变工业应用与多个发酵罐。此外,接种时间对发酵的影响尚未研究。本文旨在建立奶油奶酪发酵ph预测模型,该模型包括半批动力学模型和人工神经网络(ANN)模型。该模型的结果将有助于奶油奶酪行业了解接种时间对发酵时间的影响,并更好地组织发酵罐调度。
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引用次数: 0
Modeling of carbon dioxide and hydrogen sulfide pollutants absorption in wetted-wire columns with alkanolamines 链烷醇胺湿线柱吸收二氧化碳和硫化氢污染物的模拟
IF 0.9 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-01-03 DOI: 10.1515/cppm-2022-0056
Amin Jasour, R. Alizadeh, Hesam Ahmadian
Abstract In this work, the modeling of flow equations and associated transported phenomena in wetted-wire columns (WWC) has been carried out by using the CFD method. The studied processes in this column included the absorption of H2S and CO2 gases from the gas stream by absorbent solution. In this regard, laboratory results were available only for CO2 absorption in a column with a single wire or 109 wires. Moreover, the fact that modeling of a wetted-wire column needs robust hardware. As a result, firstly, the process of CO2 absorption with monoethanolamine (MEA) solution in a column with a wire was modeled by COMSOL Multiphysics version 5.6. Then, the results of various parameters were compared with laboratory results (the error percentage was calculated to be 2.4%). It was observed that by increasing the liquid flow rate, the distance between the beads decreased and beads with larger diameters and higher velocities formed. Meanwhile, for the first time, the temperature profile inside the column was determined along the column, the temperature of the liquid phase increased. The gas stream after a slight increase in temperature, left the column with a temperature close to the incoming liquid. After model validation, other processes were investigated, resulting from changing desired gas for separation or liquid solution. Finally, different absorbents’ abilities were predicted to absorb gaseous pollutants and obtained that in terms of absorption efficiency, second-type alkanolamines perform better than other types in the simultaneous absorption of CO2 and H2S.
摘要在这项工作中,使用CFD方法对浸润线柱(WWC)中的流动方程和相关的传输现象进行了建模。该塔中研究的工艺包括通过吸收剂溶液从气流中吸收H2S和CO2气体。在这方面,实验室结果仅可用于在具有单根金属丝或109根金属丝的柱中吸收CO2。此外,浸润线柱的建模需要稳健的硬件。因此,首先,用COMSOL Multiphysics 5.6版对单乙醇胺(MEA)溶液在带金属丝的柱中吸收CO2的过程进行了建模。然后,将各种参数的结果与实验室结果进行比较(计算出误差百分比为2.4%)。观察到,随着液体流速的增加,珠粒之间的距离减小,形成了直径更大、速度更高的珠粒。同时,首次确定了柱内沿柱的温度分布,液相温度升高。气流在温度稍微升高后,以接近进入液体的温度离开柱。在模型验证后,对其他过程进行了研究,这些过程是由改变所需的分离气体或液体溶液引起的。最后,对不同吸收剂吸收气态污染物的能力进行了预测,得出就吸收效率而言,第二类链烷醇胺在同时吸收CO2和H2S方面比其他类型的链烷醇酰胺表现更好。
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引用次数: 1
Green synthesis of silver nanoparticles from Aspergillus flavus and their antibacterial performance 黄曲霉绿色合成纳米银及其抗菌性能研究
IF 0.9 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-01-02 DOI: 10.1515/cppm-2022-0054
Dinesh Reddy Gopa, Kalyani Pullapukuri
Abstract Many methods have been developed for the synthesis of silver nanoparticles (Ag-NPs), yet disadvantages are there to declined their catalytic activity due to the large size with small surface area. Hence, herein, the fungus mediated synthesis of Ag-NPs has been reported. The synthesized Ag-NPs were further characterized by XRD, SEM, EDS, and UV–Vis spectroscopy to study the particle size, surface, crystalline nature, phase formation of Ag-NPs and the produced particles were found to be 41.9 nm. The antibacterial efficiency of synthesized Ag-NPs was examined on various bacteria including Streptococcus pyrogenes, Staphylococcus aureus, Bacillus coagulans, Klebsiella pneumoniae and Corynibacterium glutamicum. The Ag-NPs could be considered as excellent broad-spectrum antibacterial agent. More prominently, the Ag-NPs produced by Aspergillus flavus exhibited potent antibacterial activity against certain pathogens. Bacillus coagulans exhibited maximum zone of inhibition 25.16 ± 0.80 at 80 μg/mL with respective to the standard antibiotic 26.66 ± 1.22 at 30 μg/mL concentration.
摘要银纳米颗粒(Ag-NPs)的合成方法有很多,但由于其体积大、表面积小,导致其催化活性下降。因此,本文报道了真菌介导的Ag-NPs合成。通过XRD、SEM、EDS、UV-Vis等对合成的Ag-NPs进行了表征,研究了Ag-NPs的粒径、表面形貌、结晶性质、相形成等,得到的Ag-NPs粒径为41.9 nm。研究了合成的Ag-NPs对热原链球菌、金黄色葡萄球菌、凝固芽孢杆菌、肺炎克雷伯菌、谷氨酸冠状杆菌等多种细菌的抑菌效果。Ag-NPs是一种优良的广谱抗菌剂。更突出的是,由黄曲霉产生的Ag-NPs对某些病原体表现出强大的抗菌活性。凝结芽孢杆菌在80 μg/mL浓度下的最大抑菌带为25.16±0.80,标准抗生素在30 μg/mL浓度下的最大抑菌带为26.66±1.22。
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引用次数: 2
A novel nonlinear sliding mode observer to estimate biomass for lactic acid production 一种新的非线性滑模观测器估计乳酸生产的生物量
IF 0.9 Q4 ENGINEERING, CHEMICAL Pub Date : 2022-12-27 DOI: 10.1515/cppm-2021-0074
P. López-Pérez, Milagros López-López, C. Núñez-Colín, H. Mukhtar, R. Aguilar-López, V. Peña-Caballero
Abstract This study deals with the problem of estimating the amount of biomass and lactic acid concentration in a lactic acid production process. A continuous stirred tank bioreactor was used for the culture of Lactobacillus helveticus. A nonlinear sliding mode observer is proposed and designed, which gives an estimate of both the biomass and lactic acid concentrations as a function of glucose uptake from the culture medium. Numerical results are given to illustrate the effectiveness of the proposed observer against a standard sliding-mode observer. It was found that the proposed observer worked very well for the benchmark bioreactor model. Also, the numerical results indicated that the proposed estimation methodology was robust to the uncertainties associated with un-modelled dynamics. These new sensing technologies, when coupled to software models, improve performance for smart process control, monitoring, and prediction.
摘要本研究涉及乳酸生产过程中生物量和乳酸浓度的估计问题。采用连续搅拌槽生物反应器培养瑞士乳杆菌。提出并设计了一种非线性滑模观测器,该观测器估计了生物量和乳酸浓度作为培养基葡萄糖摄取的函数。数值结果说明了所提出的观测器相对于标准滑模观测器的有效性。研究发现,所提出的观测器对于基准生物反应器模型非常有效。此外,数值结果表明,所提出的估计方法对与未建模动力学相关的不确定性具有鲁棒性。这些新的传感技术与软件模型相结合,可以提高智能过程控制、监控和预测的性能。
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引用次数: 0
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Chemical Product and Process Modeling
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