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A significant turning point in the search for environmentally friendly energy storage options is the switch from lithium-ion to sodium-ion batteries. This review highlights the potential of sodium-ion battery (NIB) technology to address the environmental and financial issues related to lithium-ion systems by thoroughly examining recent developments in NIB technology. It is noted that sodium is more abundant and less expensive than lithium, NIBs have several benefits that could drastically lower the total cost of energy storage systems. In addition, this study examines new findings in important fields including electrolyte compositions, electrode materials, and battery performances of lithium-ion batteries (LIBs) and NIBs. The article highlights advancements in anode and cathode materials, with a focus on improving energy density, cycle stability, and rate capability of both LIBs and NIBs. The review also covers the advances made in comprehending the electrochemical mechanisms and special difficulties associated with NIBs, such as material degradation and sodium ion diffusion. Future research directions are discussed, with an emphasis on enhancing the scalability and commercial viability of sodium-ion technology over lithium on Electric Grid. Considering sustainability objectives and the integration of renewable energy sources, the review's assessment of sodium-ion batteries’ possible effects on the future state of energy storage is included in its conclusion.

Front Cover: In this perspective article, the synthesis and applications of TA have been thoroughly revised and critically discussed in terms of synthetic routes, biological properties, molecular reactivity and environmental impact. Sustainable synthesis and purification of tartaric acid provides renewable incentives for chemical industry. More details can be found in the article number e202400099 by Xin Jin and co-workers (DOl: 10.1002/tcr.202400099.

N-heterocyclic carbene (NHC) organocatalysis has been developed as a powerful tool in modern synthetic chemistry. NHC catalytic activation of ynals and alkynoic acid derivatives provided versatile reactions that involve acetylenic Breslow and/or acylazolium as key intermediates, and diverse transformations have been established for access to molecules with unique skeletons in efficient fashions. Herein we summarize the recent achievements in NHC-catalyzed reactions involving acetylenic Breslow and/or acylazolium intermediates. Different reactions belonging to three catalytic modes, including (1) conjugate additions to acetylenic Breslow derived α,β-unsaturated acylazolium intermediates, (2) β-umpolung of ynals via acetylenic Breslow intermediates, and (3) conjugate additions to acetylenic acylazolium intermediates, are emphasized with examples and plausible mechanisms cited to guide a better understanding.

Organic sulfur compounds encompass a vast and diverse variety of species that possess unique biological activity due to the presence of sulfur atoms or sulfur-containing functional groups. These compounds are widely present in natural products, pharmaceuticals, agricultural chemicals, and functional materials. In recent years, numerous sulfur-containing compounds such as thiols, thioethers, disulfides, thiourea, dimethyl sulfoxide, sulfonates and their derivatives, as well as sulfur-containing inorganic compounds, have been utilized as coupling agents to synthesize (hetero)aryl sulfides via C−H Functionalization. These novel transformations provide effective methods for constructing C−S bond of (hetero)arenes, while also expanding the scope of (hetero)aryl sulfides with the potential biological activity. Therefore, the synthesis of aryl sulfides through C−H bond functionalization has attracted widespread attention. This review mainly focuses on the construction of (hetero)aryl sulfides via C−H bond functionalization since 2015. We hope this review offers a useful conceptual overview and inspires further advancements in the efficient construction of C−S bonds.

Stink bugs (Hemiptera, Pentatomidae) are well known by the strong odor of the defensive compounds they release, which can mediate intra- and/or interspecific interactions. Pentatomidae is one of the largest families of Heteroptera and includes many phytophagous species that are considered pests of various crops, as well as predatory species that provide biological control. Against this background, numerous research papers in Chemical Ecology have focused on communication within this group. This paper reviews the chemical compounds reported for nearly ninety taxa, including sex and aggregation pheromones for fifty-three species of Pentatomidae. Based on these pheromones and proposed biosynthesis pathways, we hypothesize that sex/aggregation pheromones could play a role in taxonomic groups. Characters were determined and evaluated according to their distributions in recent taxonomic classifications, allowing for the inference of the phylogenetic positioning of three species never evaluated in previous taxonomic analyses.

Alkylation reactions and their products are considered crucial in various contexts. Synthetically, the alkylation of a nucleophile is usually promoted using hazardous alkyl halides. Here, we aim to highlight the potential of pnictogen (ammonium or phosphonium) and chalcogen salts (sulfonium, selenonium, and telluronium) to function as alkylating agents. These compounds can be considered as non-volatile electrophilic alkyl reservoirs. We will center our discussion on the strategies developed in recent years to expand the synthetic utility of these salts in terms of transferable alkyl groups, substrate scope, and product selectivity.

This review provides a comprehensive overview of research on 1,2,4-triazoles conducted over the last fifteen years. 1,2,4-Triazoles are highly significant in the pharmaceutical industry, with numerous compounds from this class used clinically as antifungal, antiviral, antibacterial, anti-inflammatory, and antitubercular agents. Beyond their pharmaceutical relevance, this review also explores their role in material science and agriculture. In material science, 1,2,4-triazoles are gaining prominence, particularly in the development of energetic materials (EMs), due to their exceptional properties such as thermal stability, coordination ability, and performance comparable to well-known explosives. Their applications extend to polymers, corrosion inhibitors, and metal-organic frameworks (MOFs), and they play a significant role in the development of functional materials for sensors, catalysis, and energy storage. Additionally, the review addresses general aspects and synthetic methodologies for the functionalization and construction of the 1,2,4-triazole ring. Synthetic methods discussed include metalation synthesis, cyclization of hydrazine derivatives, multicomponent reactions, cyclization of amides and amidines, and microwave-assisted synthesis. Given the significance of the triazole scaffold, its synthesis has garnered considerable attention due to its wide-ranging applications across various industrial sectors.

On June 1, 1965, R. B. Woodward and Roald Hoffmann published their third communication in the Journal of the American Chemical Society in which they applied orbital symmetry control to explain the mechanism of a wide variety of valence isomerizations that they termed “sigmatropic reactions.” This publication reveals the research trajectory taken by Hoffmann from which this portion of the no-mechanism problem was solved. Hoffmann used five different quantum chemical tools, all based on either extended Hückel theoretical calculations or frontier molecular orbital theory, in his research. Hoffmann′s laboratory notebooks and his three draft manuscripts along with Woodward′s four subsequent drafts have survived the past 59 years and provide an excellent window into the thinking and manuscript-writing processes used by these Nobel laureates in February-April 1965.

The existing and emerging demand for materials for life and health has contributed to the cultivation and development of respective markets. Nevertheless, the current generation of biomedical materials has yet to fully satisfy the clinical requirements of the market, which is still in its relative infancy. Research and development in this area must be prioritized in light of the pivotal role of new life and health materials in the biological field. Among many life and health materials, GQDs, an emerging nanomaterial, exhibit considerable promise in the biomedical field, primarily due to their exceptional properties. Furthermore, the direct preparation and functionalization of GQDs have facilitated the development of specific functional composites based on GQDs. The biological applications of GQDs are undergoing rapid growth, which makes it necessary to publish a review article presenting the latest advances in this field. This review provides an overview of the significant advances in synthesizing GQDs, the techniques employed for structural characterizations, and the properties that have been elucidated. Furthermore, it presents recent findings on applying GQDs in antimicrobial, anticancer, biosensing, drug delivery, and bioimaging applications. Finally, it explores the potential of GQDs in biomedicine and biotechnology, highlighting the current challenges that remain to be addressed.

This review provides a comprehensive examination of the applications of the seminal coupling principle introduced by Siegfried Dähne and Dieter Leupold in 1966. Their heuristic and groundbreaking work proposed that combining multiple polymethine subunits within a single chromophore enables orbital coupling, consequently narrowing the HOMO–LUMO gap, and yielding redshifted optical properties. These outcomes are particularly valuable for developing organic dyes tailored for visible-to-near-infrared applications. Despite their potential, coupled polymethines remain relatively underexplored, with most reported instances being serendipitous discoveries over the last six decades. In light of this, our review compiles and discusses the reported coupled polymethine structures, covering synthetic, spectroscopic, theoretical and applicative aspects, offering insights into the structure-property relationships of this unique class of dyes and perspectives for their future applications.