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Systematic review on bio-based insulation in Morocco: Research progress and policy challenges 摩洛哥生物基绝热材料的系统综述:研究进展与政策挑战
Pub Date : 2026-01-01 Epub Date: 2025-12-13 DOI: 10.1016/j.nxener.2025.100487
Omar Iken , Oussama Rahmoun , Oumaima Imghoure , Mohamed Touil , Salma Ouhaibi , Miloud Rahmoune , Naoual Belouaggadia , Rachid Saadani
This paper evaluates the initiatives undertaken by research and policy institutions in Morocco regarding energy efficiency in buildings. It explores the potential of thermal insulation materials derived from bio-based composites and textile waste, as circularly, sustainable, economical and high-performance solutions. To meet this objective, a Preferred Reporting Items for Systematic Reviews and Meta-Analyses (PRISMA) methodology has been used with over 133 studies and 10 projects to analyse quantitatively and qualitatively the efforts made to integrate recycled and bio-based materials for more energy efficient buildings. The quantitative side has shown that over 30 different types of eco-friendly materials were experimentally and numerically characterised in Morocco during the last 25 years. The qualitative side was conducted through a U-value and thickness based evaluation and a classification by thermal conductivity and volumetric heat capacity to specify the most suitable materials. A critical analysis of the research methodology and the national policy strategy towards building energy efficiency has been carried out. The findings have highlighted the main challenges facing the integration of these insulation materials in the construction sector, particularly in terms of regulations, awareness and market access. Finally, recommendations were proposed to encourage the adoption of these innovative materials and strengthen public policies in favour of the energy transition.
本文评估了摩洛哥研究和政策机构在建筑能效方面所采取的举措。它探索了从生物基复合材料和纺织废料中提取的保温材料的潜力,作为循环、可持续、经济和高性能的解决方案。为了实现这一目标,我们采用了系统评估和荟萃分析的首选报告项目(PRISMA)方法,对133项研究和10个项目进行了定量和定性分析,以综合利用再生材料和生物基材料,以实现更节能的建筑。定量方面表明,在过去的25年里,超过30种不同类型的环保材料在摩洛哥进行了实验和数值表征。定性方面是通过基于u值和厚度的评估以及导热性和体积热容的分类来指定最合适的材料。对研究方法和国家建筑节能政策战略进行了批判性分析。研究结果强调了这些绝缘材料在建筑行业整合所面临的主要挑战,特别是在法规、意识和市场准入方面。最后,提出了鼓励采用这些创新材料和加强有利于能源转型的公共政策的建议。
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引用次数: 0
Coupling geothermal energy with geological carbon storage: A holistic review of enhanced geothermal systems using CO₂ as a working fluid 地热能与地质碳储存的耦合:利用二氧化碳作为工作流体的增强型地热系统的整体综述
Pub Date : 2026-01-01 Epub Date: 2025-12-09 DOI: 10.1016/j.nxener.2025.100486
Jemal Worku Fentaw, Elvin Hajiyev, Abdul Rehman Baig, Hossein Emadi
CO2-based enhanced geothermal system (CO2-EGS), also known as CO2 plume geothermal, has emerged as a promising avenue to address the growing global energy demand and mitigate global climate concerns by exploiting renewable energy from geothermal reservoirs while concurrently sequestering CO2. In this method, CO2, in a supercritical state or dissolved in brine, is used as a working fluid to harness the geothermal energy held in hot reservoir rocks, with part of the CO2 being trapped in the reservoir. Despite their rapidly growing popularity, the integration assessment of CO2-EGS studies, fragmented into various subjects such as thermodynamics, heat transfer, multiphase flow, reservoir hydraulics, geomechanics, and geochemistry, remains insufficiently explored. Thus, a critical review that consolidates conducted studies, identifies gaps, and directs future research in this coupled technology is crucial. This review aims to provide a comprehensive assessment of CO2-EGS, emphasizing its significance, the major challenges affecting its performance and mitigation strategies, the thermophysical properties of CO2 as a working fluid, and CO2 storage while extracting geothermal energy. The study revealed the key benefits of CO2-EGS, including reducing corrosion and scaling effects in the wellbore, maintaining reservoir pressure, storing CO2, increasing sweep efficiency of the reservoir, lowering pumping power, and addressing water scarcity for geothermal systems. Despite its significance, CO2-EGS encounters major challenges, such as cost, drilling and operating wells in harsh geological conditions, CO2 leakage, lost circulation, premature thermal breakthrough, lower specific enthalpy, and incomplete heating. Key factors influencing its performance include properties of the reservoir, natural fractures and faults, geochemical and geomechanical factors, well design, type of thermodynamic cycle used, and CO2-related factors such as injection rate, injection pressure, temperature, and impurities. Overall, this review provides insights into significant advancements achieved and highlights future research to leverage CO2-EGS for reducing CO2 emissions while extracting geothermal energy.
基于二氧化碳的增强型地热系统(CO2- egs),也被称为二氧化碳羽流地热,已经成为解决日益增长的全球能源需求和缓解全球气候问题的一种有前途的途径,它可以从地热储层中开采可再生能源,同时封存二氧化碳。在这种方法中,超临界状态或溶解在盐水中的二氧化碳被用作工作流体,以利用热储层岩石中保存的地热能,部分二氧化碳被困在储层中。尽管二氧化碳- egs研究迅速普及,但其综合评估仍未得到充分的探索,这些研究分散在热力学、传热、多相流、油藏水力学、地质力学和地球化学等不同学科中。因此,对这一耦合技术进行综合研究、识别差距和指导未来研究的批判性回顾是至关重要的。本文旨在对CO2- egs进行全面评估,强调其重要性、影响其性能和缓解策略的主要挑战、CO2作为工作流体的热物理特性以及提取地热能时CO2的储存。该研究揭示了CO2- egs的主要优势,包括减少井筒中的腐蚀和结垢效应,保持油藏压力,储存二氧化碳,提高油藏波及效率,降低泵送功率,解决地热系统缺水问题。尽管具有重要意义,但CO2- egs也面临着一些重大挑战,如成本、恶劣地质条件下的钻井和作业、二氧化碳泄漏、漏失、热突破过早、比焓降低和加热不完全等。影响其性能的关键因素包括储层性质、天然裂缝和断层、地球化学和地质力学因素、井设计、使用的热力学循环类型,以及与二氧化碳相关的因素,如注入速度、注入压力、温度和杂质。总的来说,这篇综述提供了对已取得的重大进展的见解,并强调了在提取地热能的同时利用二氧化碳- egs减少二氧化碳排放的未来研究。
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引用次数: 0
High-performance spinel ferrites for supercapacitors: Solvothermal synthesis and electrochemical evaluation 超级电容器用高性能尖晶石铁氧体:溶剂热合成和电化学评价
Pub Date : 2026-01-01 Epub Date: 2026-01-09 DOI: 10.1016/j.nxener.2025.100506
Naeem Ullah, Tufail Ahmad, Asad Ullah, Sufaid Khan, Muhammad Nafees, Mehboob Ali, Yousra Noor, Fawad Ahmad Khan, Baseena Sardar, Majid Khan
Supercapacitors (SCs) are critical for sustainable energy storage due to their high power density and rapid charge-discharge capabilities, making them essential for renewable energy integration and electric vehicle applications. This study explores the solvothermal synthesis of spinel ferrites XFe2O4 (X = Mn, Co, Ni) as electrode materials for SCs. Structural characterization through X-ray diffraction confirmed phase-pure cubic structures with lattice parameters of 0.851 nm (MnFe2O4), 0.839 nm (CoFe2O4), and 0.834 nm (NiFe2O₄), and crystallite sizes of 13.72 nm, 20.72 nm, and 11.86 nm, respectively. Scanning electron microscopy revealed agglomerated nanoparticles for MnFe2O4 and CoFe2O4, and densely packed aggregates for NiFe2O4. Fourier-transform infrared spectroscopy identified a conductive carbonaceous layer from residual ethylene glycol, while UV-Vis spectroscopy determined bandgaps of 2.7 eV (CoFe2O4), 3.12 eV (MnFe2O4), and 3.7 eV (NiFe2O4). Electrochemical assessments using cyclic voltammetry, galvanostatic charge-discharge, and electrochemical impedance spectroscopy showed CoFe2O4 achieving a specific capacitance of 1518 F/g at 0.5 A/g with 99.9% retention after 5000 cycles, outperforming MnFe2O4 and NiFe2O4. Symmetric devices based on CoFe2O4 delivered a specific capacitance of 668 F/g at 1 A/g, an energy density of 33.38 Wh/kg, and a power density of 150 W/kg. These results position CoFe2O4 as a promising material for next-generation SCs, advancing energy storage for sustainable systems.
超级电容器(SCs)由于其高功率密度和快速充放电能力,对可持续能源存储至关重要,使其成为可再生能源集成和电动汽车应用的必要条件。本研究探讨了溶剂热合成尖晶石铁氧体XFe2O4 (X = Mn, Co, Ni)作为SCs电极材料的方法。通过x射线衍射表征,确定了相纯立方结构,晶格参数分别为0.851 nm (MnFe2O4)、0.839 nm (CoFe2O4)和0.834 nm (NiFe2O₄),晶粒尺寸分别为13.72 nm、20.72 nm和11.86 nm。扫描电镜显示,MnFe2O4和CoFe2O4为球状纳米颗粒,而NiFe2O4为密集堆积的团聚体。傅里叶变换红外光谱在残余乙二醇中发现了导电碳质层,紫外可见光谱测定了2.7 eV (CoFe2O4)、3.12 eV (MnFe2O4)和3.7 eV (NiFe2O4)的带隙。利用循环伏安法、恒流充放电法和电化学阻抗谱进行的电化学评价表明,在0.5 a /g下,CoFe2O4的比电容达到1518 F/g,循环5000次后保持率达到99.9%,优于MnFe2O4和NiFe2O4。基于CoFe2O4的对称器件在1 a /g时的比电容为668 F/g,能量密度为33.38 Wh/kg,功率密度为150 W/kg。这些结果将CoFe2O4定位为下一代超导材料的有前途的材料,推进可持续系统的能量存储。
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引用次数: 0
Hydrogen storage model for decarbonization of constant industrial processes 恒定工业过程脱碳的储氢模型
Pub Date : 2026-01-01 Epub Date: 2025-12-01 DOI: 10.1016/j.nxener.2025.100484
Simo Pekkinen , Mikko Muoniovaara , Eira Seppälä , Pekka Pirhonen , Mikael Rinne , Annukka Santasalo-Aarnio
The decarbonization of industrial processes will require large quantities of green hydrogen produced with renewable energy. The use of variable renewable energy for hydrogen production will, in turn, necessitate large-scale hydrogen storage to ensure the constant availability of hydrogen. In existing energy models, hydrogen storage is typically included as a ‘black box’ unit that simplifies the behavior of hydrogen during the operation of a storage cycle. In this study, a high-fidelity hydrogen gas storage model is developed. The model considers the behavior of hydrogen as a real gas during storage operations, a defining advancement compared to previous studies, and utilizes hourly data sets of renewable energy production. The model is first demonstrated on a baseline case located in Finland, where 121 MW of wind power capacity supplies an annual hydrogen demand of 6000 tonnes, mandating a hydrogen storage capacity of 575 tonnes. Next, a sensitivity analysis reveals that increasing wind power capacity or adding solar power to the energy mix decreases the storage requirement significantly. On the other hand, increasing the minimum storage pressure or reducing the electrolyzer capacity both increase the required storage capacity. Finally, the baseline case was used to compare storage technologies available in the Finnish context, and lined rock caverns were found to be the most cost-efficient option with a reasonable storage volume. Overall, the study concludes that significant storage capacities and thus investments are required for the industrial utilization of green hydrogen. Therefore, it is essential that the behavior of hydrogen as a real gas is considered when sizing storage systems.
工业过程的脱碳将需要大量用可再生能源生产的绿色氢。使用可变的可再生能源生产氢气,反过来,需要大规模的氢气储存,以确保氢气的持续可用性。在现有的能源模型中,氢储存通常作为一个“黑盒子”单元,简化了氢在储存循环过程中的行为。在本研究中,建立了一个高保真的储氢模型。该模型考虑了氢气在储存过程中作为真实气体的行为,与之前的研究相比,这是一个决定性的进步,并利用了可再生能源生产的每小时数据集。该模型首先在芬兰的一个基线案例中进行了演示,在芬兰,121 兆瓦的风力发电能力提供了每年6000吨的氢气需求,要求氢储存能力为575吨。其次,敏感性分析表明,增加风能发电容量或在能源结构中增加太阳能发电可显著降低储能需求。另一方面,提高最低存储压力或降低电解槽容量都增加了所需的存储容量。最后,基线案例用于比较芬兰现有的存储技术,发现内衬岩洞是具有合理存储容量的最具成本效益的选择。总的来说,该研究得出结论,绿色氢的工业利用需要大量的储存能力和投资。因此,在确定存储系统的尺寸时,必须考虑氢气作为真实气体的行为。
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引用次数: 0
Green hydrogen production from industrial effluent electrolysis: A brief bibliometric analysis and literature review 工业废水电解绿色制氢:简要文献计量学分析与文献综述
Pub Date : 2026-01-01 Epub Date: 2025-12-04 DOI: 10.1016/j.nxener.2025.100481
Pedro Henrique de Lima Gomes , Vivian Carvalho de Araujo , Carla Freitas de Andrade , Daniel Silveira Serra , Mona Lisa Moura de Oliveira
Renewable energies are gaining ground in the global energy matrix due to their potential to decarbonize the economy. Currently, water electrolysis is one of the main commercial routes used to obtain green hydrogen, and there is a growing interest in alternative water sources to avoid competition between human and animal consumption and fuel production. In this context, a brief bibliometric analysis on "Green hydrogen via effluent electrolysis" was conducted, followed by a literature review aimed at answering the following guiding questions: (i) Are there green hydrogen production systems via effluent electrolysis?; (ii) What renewable energy sources are used by existing systems, and what is their configuration and production scale?; (iii) What electrolysis technologies are used in these systems?; (iv) What are the effluent sources used by existing systems, and what methods are employed for effluent treatment?; (v) What are the applications for hydrogen, oxygen, and residual heat obtained during effluent electrolysis? The results show that: (i) various types of effluent electrolysis systems have been reported; (ii) the main renewable energy source used in these systems is photovoltaic solar energy; (iii) the most commonly used electrolysis technology is the proton exchange membrane type; (iv) the most frequent effluent source is from municipal effluent treatment plants; and (v) the applications of green hydrogen, oxygen, and residual heat can meet the same demands as those of fossil origin hydrogen. Finally, it is evident that research involving effluent electrolysis for green hydrogen production is still in its early stages, indicating a wide field yet to be explored.
可再生能源由于具有使经济脱碳的潜力,正在全球能源矩阵中占据一席之地。目前,水电解是获得绿色氢的主要商业途径之一,人们对替代水源的兴趣日益浓厚,以避免人类和动物消费与燃料生产之间的竞争。在此背景下,对“通过废水电解生产绿色氢”进行了简短的文献计量学分析,然后进行了文献综述,旨在回答以下指导性问题:(i)是否存在通过废水电解生产绿色氢的系统?现有系统使用哪些可再生能源,其结构和生产规模如何?这些系统采用何种电解技术?(iv)现有系统使用的污水来源是什么,污水处理采用什么方法?(v)废水电解过程中获得的氢、氧和余热的用途是什么?结果表明:(1)已报道了各种类型的废水电解系统;(ii)在这些系统中使用的主要可再生能源是光伏太阳能;(三)最常用的电解技术是质子交换膜式;(iv)最常见的污水来源是市政污水处理厂;(5)绿色氢、氧和余热的应用可以满足与化石源氢相同的需求。最后,很明显,涉及废水电解绿色制氢的研究仍处于早期阶段,表明一个广阔的领域有待探索。
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引用次数: 0
Virtual inertia control for enhanced frequency stability in islanded microgrids: A multistage PID and modified golf optimization approach 提高孤岛微电网频率稳定性的虚拟惯性控制:多级PID和改进的高尔夫优化方法
Pub Date : 2026-01-01 Epub Date: 2026-01-02 DOI: 10.1016/j.nxener.2025.100503
Mihira Kumar Nath , N. Bhanu Prasad , Asini Kumar Baliarsingh
Renewable energy sources (RESs) hold a significant share in modern electrical networks, particularly in Microgrids (MGs). The inertia of the MG is significantly reduced due to the substitution of traditional synchronous generators with RESs. Frequency control of MG integrated with RESs is a challenging task. This research proposes a robust solution to enhance the frequency stability of an islanded MG by applying virtual inertia control (VIC) and damping strategies. A multistage proportional integral derivative (PID) ([PDF]-[1+PI]) controller optimized through a modified golf optimization algorithm (mGOA) in coordination with an energy storage system (ESS) is implemented as VIC. The mGOA algorithm performance is compared using various standard benchmark test functions with the original golf optimization algorithm (GOA) and with 10 other well-known optimization algorithms, particle swarm optimization, gravitational search algorithm, and genetic algorithm. To verify the effectiveness of the proposed mGOA algorithm, it is compared with the original GOA, grey wolf optimization (GWO), and whale optimization algorithm (WOA). It is demonstrated that the objective function value decreases by 53.07%, 56.01%, and 60.53% when compared with the original GOA, WOA, and GWO, respectively. The performance of the proportional derivative with filter (PDF)-(1+PI) controller was compared with that of conventional proportional integral (PI) controllers and PID controllers based on mGOA for random load fluctuation, parametric uncertainty, reduced capacity of ESS, and various renewable generation scenarios. The simulation result indicates that the mGOA-tuned multistage controller offers improved performance of 85.65% and 82.62% in terms of minimum objective function value in comparison to the mGOA-tuned PI and PID controllers, respectively. The performance of the proposed controller is evaluated under cyber attacks like false data injection attacks and denial of service attacks, as well as time latency. Performance of the proposed controller is tested by Hardware-In-The-Loop simulation, in OPAL-RT platform.
可再生能源(RESs)在现代电网,特别是微电网(MGs)中占有重要份额。由于用RESs代替了传统的同步发电机,MG的惯性大大降低。MG与RESs集成的频率控制是一项具有挑战性的任务。本研究提出了一种利用虚拟惯性控制和阻尼策略增强孤岛磁振器频率稳定性的鲁棒解决方案。采用改进的高尔夫优化算法(mGOA)优化了多级比例积分导数(PID) ([PDF]-[1+PI])控制器,并与储能系统(ESS)协同实现多级比例积分导数(PID)控制器。利用各种标准基准测试函数,将mGOA算法的性能与原始高尔夫优化算法(GOA)以及粒子群优化算法、引力搜索算法、遗传算法等10种知名优化算法进行比较。为了验证所提出的mGOA算法的有效性,将其与原始的GOA算法、灰狼优化算法(GWO)和鲸鱼优化算法(WOA)进行了比较。结果表明,目标函数值与原始GOA、WOA和GWO相比分别下降了53.07%、56.01%和60.53%。在负荷随机波动、参数不确定性、ESS容量减小以及各种可再生能源发电场景下,将带滤波器的比例导数(PDF)-(1+PI)控制器与传统比例积分(PI)控制器和基于mGOA的PID控制器的性能进行了比较。仿真结果表明,与经mgoa调谐的PI控制器和PID控制器相比,经mgoa调谐的多级控制器的最小目标函数值分别提高了85.65%和82.62%。在虚假数据注入攻击和拒绝服务攻击以及时间延迟等网络攻击下,对所提出的控制器的性能进行了评估。在OPAL-RT平台上进行了硬件在环仿真,验证了所提控制器的性能。
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引用次数: 0
Climate-adaptive performance and environmental benchmarking of R600a refrigeration systems under tropical operating conditions R600a制冷系统在热带工况下的气候适应性能和环境基准测试
Pub Date : 2026-01-01 Epub Date: 2025-11-06 DOI: 10.1016/j.nxener.2025.100453
Aniket A. Dhavale , Mandar M. Lele
In the context of rising global temperatures and the urgent need for low-Global Warming Potential (GWP) alternatives, enhancing the climate adaptability of domestic refrigeration systems is essential for sustainable cooling. Tropical regions like India regularly experience ambient temperatures exceeding 35 °C, yet conventional energy rating protocols evaluate refrigerators under fixed and moderate conditions, which poorly reflect real-world usage. This discrepancy highlights a critical gap: the lack of performance data under dynamic, high-stress thermal environments that influence system efficiency, refrigerant behavior, and energy consumption. Addressing this, the present study experimentally investigates the thermodynamic behavior of a modified 190 L refrigerator using R600a, a natural hydrocarbon refrigerant with low global warming potential, under varying cabinet temperatures (0–15 °C) and ambient conditions (30–40 °C) that simulate tropical environments. Performance metrics such as evaporator heat absorption (Qₑᵥₐₚ), condenser heat rejection (Qcond), power consumption, compressor discharge temperature, and coefficient of performance (COP) were measured and analyzed. Results showed up to 17% and 20% increases in Qₑᵥₐₚ and Qcond, respectively, with rising cabinet temperatures. A 10 °C ambient temperature rise caused an 11.2% COP drop and a ∼16% increase in discharge temperature, indicating considerable thermal stress. Findings were validated against IMST-ART simulations with deviations within ±5–7%. By shifting away from idealized, static test conditions, this study offers climate-responsive insights into the real-world performance of R600a systems. Academically, it introduces climate responsive coefficient of performance and sustainaibility index as advanced performance indicators that address both engineering and sustainability goals. Socio-economically, the study underscores the potential for carbon savings, energy-efficient appliance policy reform, and better refrigerant selection for developing nations. Academically, it introduces performance mapping techniques that integrate thermal efficiency with environmental and economic metrics. Socio-economically, the study underscores the potential for carbon savings, energy-efficient appliance policy reform, and better refrigerant selection for developing nations. This work calls for an urgent transition toward climate-adaptive testing standards and supports the development of cooling systems engineered for high-heat environments bridging the gap between lab performance and field realities in the global pursuit of sustainable refrigeration.
在全球气温上升和迫切需要低全球变暖潜能值(GWP)替代品的背景下,提高家用制冷系统的气候适应性对于可持续制冷至关重要。印度等热带地区的环境温度经常超过35 °C,但传统的能源评级协议在固定和中等条件下评估冰箱,这很难反映实际使用情况。这种差异凸显了一个关键的差距:缺乏动态、高应力热环境下的性能数据,这些数据会影响系统效率、制冷剂行为和能耗。为了解决这一问题,本研究通过实验研究了在模拟热带环境的不同机柜温度(0-15 °C)和环境条件(30-40 °C)下,使用具有低全球变暖潜能值的天然碳氢化合物制冷剂R600a的改进190 L冰箱的热力学行为。测量和分析了蒸发器吸热(Qₑᵥₚ)、冷凝器排热(Qcond)、功耗、压缩机排气温度和性能系数(COP)等性能指标。结果显示,随着橱柜温度的升高,Qₑᵥₚ和Qcond分别增加了17%和20%。当环境温度升高10 °C时,COP下降11.2%,放电温度升高~ 16%,表明存在相当大的热应力。结果通过IMST-ART模拟验证,偏差在±5-7%之间。通过摆脱理想化的静态测试条件,本研究为R600a系统的实际性能提供了气候响应性见解。在学术上,它引入了气候响应性能系数和可持续性指数作为解决工程和可持续性目标的高级性能指标。从社会经济角度看,该研究强调了发展中国家在碳减排、节能电器政策改革和更好地选择制冷剂方面的潜力。在学术上,它引入了将热效率与环境和经济指标相结合的性能映射技术。从社会经济角度看,该研究强调了发展中国家在碳减排、节能电器政策改革和更好地选择制冷剂方面的潜力。这项工作要求向气候适应性测试标准的紧急过渡,并支持为高温环境设计的冷却系统的开发,弥合了全球追求可持续制冷的实验室性能和现场现实之间的差距。
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引用次数: 0
Advancements in carbon capture and utilization technologies: Transforming CO2 into valuable resources for a sustainable carbon economy 碳捕获和利用技术的进展:将二氧化碳转化为可持续碳经济的宝贵资源
Pub Date : 2026-01-01 Epub Date: 2025-11-08 DOI: 10.1016/j.nxener.2025.100476
Harish Kumar , Rahul Sharma , Ashok K. Malik , Ashok K. Sharma , Parvin Kumar , Devender Singh
The escalating atmospheric CO₂ concentration arising from fossil fuel combustion and industrial activities necessitates immediate mitigation strategies to address global warming and environmental degradation. Carbon Capture and Utilization (CCU) technologies have emerged as a pivotal approach to transforming CO₂ from a greenhouse gas into a valuable feedstock for fuels and chemicals. This review critically examines recent advancements in CO₂ capture techniques—including absorption, adsorption, membrane separation, and mineral carbonation—and their integration with various conversion routes such as thermocatalytic hydrogenation, electrochemical and photocatalytic reduction, and biological fixation. Particular emphasis is placed on the synthesis of methanol, ethanol, methane, syngas, cyclic carbonates, and biofuels, discussing their catalytic systems (Cu-, Ni-, and Ti-based catalysts, metal–organic frameworks, and nanostructured semiconductors), reaction mechanisms, and process efficiencies. The review also evaluates techno-economic feasibility, energy input–output ratios, and net CO₂ reduction potentials, highlighting strategies for coupling renewable hydrogen and solar-driven systems to improve sustainability. Finally, it outlines the current technology readiness levels (TRLs), life-cycle assessment (LCA) outcomes, and research priorities needed to accelerate the industrial implementation of CCU technologies toward a low and circular carbon economy.
化石燃料燃烧和工业活动引起的大气二氧化碳浓度不断上升,需要立即采取减缓战略,以应对全球变暖和环境退化。碳捕集与利用(CCU)技术已经成为将二氧化碳从温室气体转化为燃料和化学品的宝贵原料的关键方法。本文综述了二氧化碳捕获技术的最新进展,包括吸收、吸附、膜分离和矿物碳化,以及它们与各种转化途径(如热催化加氢、电化学和光催化还原以及生物固定)的整合。特别强调的是甲醇、乙醇、甲烷、合成气、环状碳酸盐和生物燃料的合成,讨论了它们的催化系统(铜、镍和钛基催化剂、金属有机框架和纳米结构半导体)、反应机制和过程效率。该报告还评估了技术经济可行性、能源投入产出比和净二氧化碳减排潜力,强调了将可再生氢和太阳能驱动系统结合起来以提高可持续性的战略。最后,概述了当前的技术准备水平(trl)、生命周期评估(LCA)结果,以及加速CCU技术向低碳和循环经济的工业实施所需的研究重点。
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引用次数: 0
Dynamic simulation of a PEM fuel cell: Insights into efficiency, thermal, and fluid management PEM燃料电池的动态模拟:对效率、热和流体管理的见解
Pub Date : 2026-01-01 Epub Date: 2025-12-11 DOI: 10.1016/j.nxener.2025.100489
Theodore Azemtsop Manfo
Proton exchange membrane (PEM) fuel cells are emerging as critical technology for clean and efficient energy conversion, providing a path to worldwide decarbonization and renewable power generation. Their successful integration into renewable and hybrid systems necessitates a thorough understanding of the interconnected electrochemical, thermal, and fluid processes that regulate performance. However, many existing models oversimplify these dynamic interactions, resulting in an inadequate understanding of system-level behavior and control optimization. This study fills that gap by creating a dynamic MATLAB/Simulink-based model of a PEM fuel cell to investigate how integrated thermal and fluid management affect efficiency, gas usage, and operational stability under changing loads. The model includes several critical subsystems, including the membrane electrode assembly, gas flow routes, heat regulation, and purge control. Simulation findings show a peak electrical output of 95 kW with a power density of 1.116 W cm⁻². This highlights the need for active cooling and purging strategies in reducing hydrogen loss and preserving stack performance. The findings aid sustainable PEM fuel cell design and real-time control development.
质子交换膜(PEM)燃料电池正在成为清洁、高效能源转换的关键技术,为全球脱碳和可再生能源发电提供了一条途径。将其成功集成到可再生能源和混合动力系统中,需要对调节性能的相互关联的电化学、热和流体过程有透彻的了解。然而,许多现有的模型过度简化了这些动态交互,导致对系统级行为和控制优化的理解不足。本研究通过创建基于MATLAB/ simulink的PEM燃料电池动态模型来填补这一空白,以研究集成的热和流体管理如何影响效率、气体使用和变化负载下的运行稳定性。该模型包括几个关键子系统,包括膜电极组件,气体流动路线,热量调节和吹扫控制。模拟结果显示,峰值电输出为95 kW,功率密度为1.116 W cm⁻²。这突出了主动冷却和净化策略在减少氢损失和保持堆性能方面的必要性。这些发现有助于PEM燃料电池的可持续设计和实时控制的发展。
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引用次数: 0
Co-pyrolysis and co-gasification of biomass and plastics for next-generation fuel production and the effect of various operating parameters on it: A review 生物质与塑料共热解共气化新一代燃料的研究进展及不同操作参数对其的影响
Pub Date : 2026-01-01 Epub Date: 2025-11-14 DOI: 10.1016/j.nxener.2025.100475
Kuntalika Das , Sankar Bhattacharya , Sandeep Kumar
The use of fossil fuels leads to greenhouse gas emissions and climate change. At the same time, the finite reserves of crude oil, natural gas, and coal necessitate a shift to alternative energy sources. Apart from the typical non-conventional energy sources, waste-to-energy routes are gaining popularity. Non-biodegradable plastic waste, which possesses a high amount of energy, can be thermo-chemically treated (pyrolysis or gasification) to generate fuel. On the other hand, biomass (BM) thermochemical conversion has the potential to emerge as a green energy source with proper forest management. Co-pyrolysis and co-gasification of plastic and BM show the potential for further improvement in fuel quality and quantity. The available research works involve a range of BM and plastic types, making it difficult to conclude a generalised trend of product generation. The current work systematically reviews the recent research data by categorising the results as per the type of feedstock used and the conversion processes. A general trend of fuel yield for various feedstock types and relative contents is summarised. The effects of various parameters – operating temperature, gasifying agent, blending ratio, reactor type, and use of catalysts are also discussed, along with an insight into the catalytic conversion mechanism. The review will be beneficial to get a broad picture of the recent progress in BM-plastic co-pyrolysis and co-gasification, associated challenges, and potential applications.
化石燃料的使用导致温室气体排放和气候变化。与此同时,原油、天然气和煤炭的有限储量要求我们转向替代能源。除了典型的非常规能源外,废物转化为能源的途径也越来越受欢迎。不可生物降解的塑料垃圾拥有大量的能量,可以通过热化学处理(热解或气化)来产生燃料。另一方面,如果森林管理得当,生物质热化学转化有可能成为一种绿色能源。塑料和BM的共热解和共气化显示出燃料质量和数量进一步提高的潜力。现有的研究工作涉及一系列BM和塑料类型,因此很难得出产品生成的一般趋势。目前的工作系统地审查了最近的研究数据,根据所使用的原料类型和转化过程对结果进行了分类。总结了各种原料类型和相对含量的燃料产量的一般趋势。还讨论了操作温度、气化剂、混合比例、反应器类型和催化剂的使用等参数对催化转化的影响,并深入探讨了催化转化机理。综述了BM-plastic共热解和共气化的最新进展、相关挑战和潜在应用。
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引用次数: 0
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Next Energy
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