Critical reviews in analytical chemistry最新文献

Selenium (Se) is considered to be an essential trace element needed for all living organisms. The importance, deficiency, and toxic effects of Se mainly depend on its quantity and chemical nature. It has been observed that the inorganic versions of Se are more hazardous than the organic versions. This review is mainly focused on the application of different extraction methods used for Se extraction and determination such as microextraction, solid-phase extraction (SPE), and their modified modes in the last 12 years. The use of different dispersive medium (magnetic field, ultrasonic radiation, and vortex agitator) to enhance Se separation is also part of this review. The usage of environmentally friendly solvents such as supramolecular solvents, hydrophobic deep eutectic solvents (DESs), and ionic liquids (ILs) are also the focus of attention in this review. This review is also emphasized the application of advanced microextraction methods, particularly liquid-phase microextraction (LPME). The most recent advances in LPME extraction techniques for Se in various environmental samples, as well as their prospects, are reviewed. Additionally, a summary of cheap, simple, and accurate techniques that have not yet been used to determine small amounts of Se has been provided.

Sulfur-containing compounds are naturally found in crude oil, and they can be partially removed during the refining process. The wide use of fossil fuels has a significant contribution to sulfur emissions into the atmosphere, and Governments are striving to reduce the amount of the fuels by environmental regulations. The reduction of sulfur levels in diesel and other transportation fuels is beneficial from economic and environmental points, but meeting this standard represents a major operational and economic challenge for the oil and gas industry. Quantitative measurement of the sulfur amount must be taken along the oil refining chains guided by standards of measurement and recommended analytical methods such as various American Society for Testing and Materials methods (ASTM D2622, ASTM D5453, ASTM D7039, and ASTM D7220). Advancement in the refining processes and environmental regulations also require reliable measurements and well-defined criteria for compliance assessment. This work presented a brief review of the ASTM Standards used in the laboratories of the Brazilian oil and gas industry to determine the total sulfur content in fuels. We also presented an approach based on the reproducibility of the measurement methods and the guard band concept to evaluate the conformity statement.

Erectile dysfunction (ED) is one of the most common chronic diseases affecting men and its incidence increases with aging. Due to its substantial influence on the quality of life, phosphodiesterase type-5 (PDE5) inhibitors have been implemented to treat ED by increasing the penile blood flow that results in improving erection. PDE5 inhibitors is a class of drugs that affects many pharmacological sectors, and it is essential to review the different analytical methods described for their determination. Few reviews were published concerning this group of drugs. For this reason, this review article gathers the different analytical methods used to determine PDE5 inhibitors in pharmaceutical and biological samples over the past 20 years. Different analytical techniques were used to analyze these compounds in different matrices such as separation methods (capillary electrophoresis, LC-MS, UPLC-MS/MS, and GC-MS), spectroscopic methods (UV-visible methods, FT-IR spectroscopy and spectrofluorometry) and electrochemical methods (polarography, voltammetry and potentiometry). This review focuses on the different electrochemical methods and their use in analytical determination of PDE5 inhibitors in pharmaceutical dosage forms and biological samples. Moreover, it discusses the different modified electrodes used for their electroanalytical determination and the behavior of the studied drugs at different modified electrodes. Additionally, this review discusses the pharmacokinetics of the studied compounds and their interactions with other co-administered drugs especially the metabolic interactions between the studied compounds and other co-administered drugs in different matrices. This literature survey would provide a beneficial guide for future analytical investigation of PDE5 inhibitors.

Mycotoxin pollution in agricultural food products endangers animal and human health during the supply chains, therefore the development of accurate and rapid techniques for the determination of mycotoxins is of great importance for food safety guarantee. MXenes-based nanoprobes have attracted enormous attention as a complementary analysis and promising alternative strategies to conventional diagnostic methods, because of their fascinating features, like high electrical conductivity, various surface functional groups, high surface area, superb thermal resistance, good hydrophilicity, and environmentally-friendlier characteristics. In this study, we outline the state-of-the-art research on MXenes-based probes in detecting various mycotoxins like aflatoxin, ochratoxin, deoxynivalenol, zearalenone, and other toxins as a most commonly founded mycotoxin in the agri-food supply chain. First, we present the diverse synthesis approaches and exceptional characteristics of MXenes. Afterward, based on the detecting mechanism, we divide the biosensing utilizations of MXenes into two subcategories: electrochemical, and optical biosensors. Then their performance in effective sensing of mycotoxins is comprehensively deliberated. Finally, present challenges and prospective opportunities for MXenes are debated.

Liquid phase microextraction techniques are considered as the miniaturized version of traditional liquid-liquid extraction, which use only several microliters of a proper solvent to extract the analytes from sample. In these methods, the target analytes are migrated into a water-immiscible organic solvent (acceptor phase) from an aqueous sample (donor phase). They are mainly classified into three main groups including (a) single-drop microextraction, (b) dispersive liquid-liquid microextraction, and (c) hollow fiber-liquid phase microextraction. These techniques have been successfully applied to the assessment of different analytes in food samples, pharmaceuticals, beverages, and so on. This review mainly focuses on up-to-date information on the application of liquid phase microextraction techniques in dairy products. The advantages and disadvantages of the developed liquid phase microextraction methods were discussed.

Magnetic molecularly imprinted polymers (MMIPs) are used as artificial antibody materials. MMIPs have attracted a great deal of interest because of their low cost, wide practicality, predetermination, stability and their ability to achieve rapid separation from complex sample environments by the action of external magnetic field. MMIPs can simulate the natural recognition of entities. They are widely used because of their great advantages in terms of high selectivity. In this review article, the preparation methods of Fe₃O₄ NPs and a detailed summary of the commonly used methods for amination modification of Fe₃O₄ NPs are introduced, preparation of Ag NPs of different sizes and Au NPs of various shapes and preparation methods of magnetic molecularly imprinted plasmonic SERS composite nanoparticles such as Fe₃O₄@Ag NPs, Fe₃O₄/Ag NPs, Fe₃O₄@Au NPs, Fe₃O₄/Au NPs, Fe₃O₄@Au/Ag NPs and Fe₃O₄@Ag@Au NPs are main summarized. In addition, preparation process and the current application of MMIPs prepared from magnetic molecularly imprinted plasmonic SERS composite nanoparticles incorporating different functional monomers in a nuclear-satellite structure are also presented. Finally, the existing challenges and future prospects of MMIPs in applications are discussed.

Chlorination of seawater forms a range of secondary oxidative species, collectively termed "chlorine-produced oxidants" (CPOs). These compounds do not have the same biocidal efficacy, the same fate and behavior in the marine environment, the same potential formation of chlorination by-products (CBPs), nor the same effects on marine organisms. Their chemical speciation is an important step toward an accurate assessment of the effectiveness of chlorination and the potential impacts of its releases, among others. The aim of this paper - which is the second of a trilogy dedicated to the chemical speciation of CPOs in seawater - is to cover all aspects related to CPOs analysis in seawater, from sampling to instrumental determination. First, it discusses the procedures involved in synthesis, storage, and standardization of analytical standards. Second, it deals with sampling and sample preparation, addressing all relevant issues related to these two key steps. Third, it provides a comprehensive and up-to-date overview of the colorimetric, titrimetric, and electrochemical methods used for CPOs determination and thoroughly discusses their advantages and limitations. Finally, this review ends with some recommendations for progress in the field of CPO analysis with the three aforementioned approaches. Chromatographic and mass spectrometric-based methods will be covered in the third and final article (Part III).

Oxadiazoles, especially 1,3,4-oxadiazole scaffolds, stand among the foremost heterocyclic fragments with a broad spectrum of applications in diverse fields, including pharmacology, polymers, material science, and organic electronics, among others. In this comprehensive review, we summarize the pivotal synthetic strategies for 1,3,4-oxadiazole derivatives including dehydrogenative cyclization of 1,2-diacylhydrazines, oxidative cyclization of acylhydrazones, condensation cyclization, C-H activation of oxadiazole ring, decarboxylative cyclization and oxidative annulation along with plausible mechanisms. The set of 1,3,4-oxadiazoles selected from the literature and discussed herein epitomize the ease of synthesis as well as the possibility of linking π-conjugated groups; thereby encouraging the use of these molecules as important starting building blocks for a wide variety of fluorescent frameworks, particularly in the development of potential chemosensors. High photoluminescent quantum yield, excellent thermal and chemical stability, and the presence of potential coordination (N and O donor atoms) sites make these molecules a prominent choice for metal-ions sensors. An overview of selective metal-ion sensing, the detection limit along with the sensing mechanisms (photo-induced electron transfer, excited-state intramolecular proton transfer, and complex formation) is also included.

Herein we have discussed such important modified rhodamine compounds which have been used as chemosensors for the last 7-8 years. This review covered some chemosensors for the detection of metal ions like Al(III), Cu(II), Hg(II), Co(II), Fe(III), Au(III), Cr(III), and some anion like CN^-. The selectivity, sensitivity, photophysical properties (i.e., UV-Vis spectral studies, fluorescence studies giving special emphasis to absorption wavelength in UV-Vis spectra and excitation and emission wavelength in fluorescence spectra), binding affinity, the limit of detection, and the application of those chemosensors are described clearly. Here we have also discussed some functionalized rhodamine-based chemosensors that emit in the near-infrared region (NIR) and can target lysosomes and detect lysosomal pH. Their versatile applicability in the medicinal ground is also delineated. We have focused on the photophysical properties of spirolactam rhodamine photoswitches and applications in single-molecule localization microscopy and volumetric 3D light photoactivable dye displays. The real-time detection of radical intermediates has also been exemplified.

Diuretics are drugs that promote the excretion of water and electrolytes in the body and produce diuretic effects. Clinically, they are often used in the treatment of edema caused by various reasons and hypertension. In sports, diuretics are banned by the World Anti-Doping Agency (WADA). Therefore, in order to monitor blood drug concentration, identify drug quality and maintain the fairness of sports competition, accurate, rapid, highly selective and sensitive detection methods are essential. This review provides a comprehensive summary of the pretreatment and detection of diuretics in various samples since 2015. Commonly used techniques to extract diuretics include liquid-liquid extraction, liquid-phase microextraction, solid-phase extraction, solid-phase microextraction, among others. Determination methods include methods based on liquid chromatography, fluorescent spectroscopy, electrochemical sensor method, capillary electrophoresis and so on. The advantages and disadvantages of various pretreatment and analytical techniques are elaborated. In addition, future development prospects of these techniques are discussed.