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Recent Advancements in Fluorometric and Colorimetric Detection of Cd2+ Using Organic Chemosensors: A Review (2019-2024). 利用有机化学传感器对 Cd2+ 进行荧光和比色检测的最新进展:综述(2019-2024 年)》。
IF 5 2区 化学 Q1 Chemistry Pub Date : 2024-04-24 DOI: 10.1080/10408347.2024.2339968
Jari S Algethami, H. M. Al-Saidi, E. H. Alosaimi, Yaser A Alnaam, K. Al-Ahmary, Sikandar Khan
In recent decades, heavy metal ions have emerged as a significant global environmental concern, posing threats to the delicate balance of ecosystems worldwide. Their introduction into ecosystems occurs through various activities and poses a serious risk to human health. Among heavy metal ions, Cd2+ is recognized as a highly toxic pollutant. Its widespread use contributes to its accumulation in the environment. Chronic exposure to Cd2+ ions present serious risks to both the environment and human health. Therefore, the detection of these metal ions are very important. Organic fluorometric and colorimetric detection have emerged as promising tools for this purpose, offering advantages such as high sensitivity, selectivity, and sometimes reversibility. This review offers a comprehensive overview of the recent advancements in the fluorometric and colorimetric detection of Cd2+ using organic chemosensors from 2019 to 2024. We delve into key aspects of these studies, including the design strategies employed to design novel chemosensors and the underlying sensing mechanisms. Furthermore, we explore the diverse applications of these organic chemosensors, ranging from environmental monitoring to biomedical diagnostics. By analyzing the latest research findings, this review aims to offer insights into the current state-of-the-art in the field of Cd2+ detection using organic chemosensors. Additionally, it highlights the potential opportunities and challenges that lie ahead, paving the way for future advancements in this important area of research.
近几十年来,重金属离子已成为一个重大的全球环境问题,对全球生态系统的微妙平衡构成威胁。它们通过各种活动进入生态系统,对人类健康构成严重威胁。在重金属离子中,Cd2+ 是公认的剧毒污染物。它的广泛使用导致其在环境中的积累。长期接触 Cd2+ 离子会对环境和人类健康造成严重危害。因此,检测这些金属离子非常重要。有机荧光检测法和比色法具有灵敏度高、选择性强、有时还具有可逆性等优点,已成为很有前途的检测工具。本综述全面概述了 2019 年至 2024 年使用有机化学传感器对 Cd2+ 进行荧光和比色检测的最新进展。我们深入探讨了这些研究的关键方面,包括设计新型化学传感器所采用的设计策略和基本传感机制。此外,我们还探讨了这些有机化学传感器的各种应用,从环境监测到生物医学诊断。通过分析最新研究成果,本综述旨在深入探讨当前使用有机化学传感器检测 Cd2+ 领域的最新研究成果。此外,它还强调了未来的潜在机遇和挑战,为这一重要研究领域的未来发展铺平了道路。
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引用次数: 0
Innovative Graphene-Based Nanocomposites for Improvement of Electrochemical Sensors: Synthesis, Characterization, and Applications. 用于改进电化学传感器的创新型石墨烯基纳米复合材料:合成、表征和应用。
IF 5 2区 化学 Q1 Chemistry Pub Date : 2024-04-24 DOI: 10.1080/10408347.2024.2343854
Untika Pengsomjit, Fatima Alabdo, C. Karuwan, Charoenkwan Kraiya, Waleed Alahmad, S. A. Ozkan
Graphene, renowned for its exceptional physicochemical attributes, has emerged as a favored substrate for integrating a wide array of inorganic and organic materials in scientific endeavors and innovations. Electrochemical graphene-based nanocomposite sensors have been developed by incorporating diverse nanoparticles into graphene, effectively immobilized onto electrodes through various techniques. These graphene-based nanocomposite sensors have effectively detected and quantified various electroactive species in samples. This review delves into using graphene nanocomposites to fabricate electrochemical sensors, leveraging the exceptional electrical, mechanical, and thermal properties inherent to graphene derivatives. These nanocomposites showcase electrocatalytic activity, substantial surface area, superior electrical conductivity, adsorption capabilities, and notable porosity, which are highly advantageous for sensing applications. A myriad of characterization techniques, including Raman spectroscopy, scanning electron microscopy (SEM), transmission electron microscopy (TEM), BET surface area analysis, and X-ray diffraction (XRD), have proven effective in exploring the properties of graphene nanocomposites and validating the adjustable formation of these nanomaterials with graphene. The applicability of these sensors across various matrices, encompassing environmental, food, and biological domains, has been evaluated through electrochemical measurements, such as cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), and differential pulse voltammetry (DPV). This review provides a comprehensive overview of synthesis methods, characterization techniques, and sensor applications pertinent to graphene-based nanocomposites. Furthermore, it deliberates on the challenges and future prospects within this burgeoning field.
石墨烯以其优异的物理化学属性而闻名,已成为科学研究和创新中整合各种无机和有机材料的理想基底。在石墨烯中加入各种纳米粒子,并通过各种技术有效地固定在电极上,从而开发出了基于石墨烯的电化学纳米复合传感器。这些基于石墨烯的纳米复合传感器可以有效地检测和量化样品中的各种电活性物质。本综述将深入探讨如何利用石墨烯纳米复合材料制造电化学传感器,充分利用石墨烯衍生物固有的优异电学、机械和热学特性。这些纳米复合材料具有电催化活性、巨大的比表面积、优异的导电性、吸附能力和显著的多孔性,在传感应用中具有极大的优势。拉曼光谱、扫描电子显微镜 (SEM)、透射电子显微镜 (TEM)、BET 表面积分析和 X 射线衍射 (XRD) 等多种表征技术已被证明可有效探索石墨烯纳米复合材料的特性,并验证这些纳米材料与石墨烯的可调形成。通过循环伏安法 (CV)、电化学阻抗光谱法 (EIS) 和差分脉冲伏安法 (DPV) 等电化学测量方法,对这些传感器在各种基质(包括环境、食品和生物领域)中的适用性进行了评估。本综述全面概述了与石墨烯基纳米复合材料相关的合成方法、表征技术和传感器应用。此外,它还探讨了这一新兴领域所面临的挑战和未来前景。
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引用次数: 0
Investigation of Health Effects of Major Phenolic Compounds in Foods: Extraction Processes, Analytical Approaches and Applications. 食品中主要酚类化合物对健康影响的调查:萃取过程、分析方法和应用。
IF 5 2区 化学 Q1 Chemistry Pub Date : 2024-04-22 DOI: 10.1080/10408347.2024.2336981
M. M. Hurkul, Ahmet Cetinkaya, S. Kaya, Seyda Yayla, S. A. Ozkan
The escalating costs of healthcare services and a growing awareness of personal health responsibilities have led individuals to explore natural methods alongside conventional medicines for health improvement and disease prevention. The aging global population is experiencing increased health needs, notably related to conditions like diabetes, heart disease, and hypertension. Lifestyle-related diseases, poor dietary habits, and sedentary lifestyles underscore the importance of foods containing nutrients that can aid in preventing and managing these diseases. Phenolic compounds, a fundamental group of phytochemicals, are prominent in the chemical diversity of the natural world and are abundant in functional foods. Widely distributed in various plant parts, these compounds exhibit important functional and sensory properties, including color, taste, and aroma. Their diverse functionalities, particularly antioxidant activity, play a crucial role in mitigating cellular oxidative stress, potentially reducing damage associated with serious health issues such as cardiovascular disease, neurodegenerative disea23ses, and cancer. Phenolic compounds exist in different forms, some combined with glycosides, impacting their biological effects and absorption. Approximately 8000 polyphenols isolated from plants offer significant potential for natural medicines and nutritional supplements. Therefore, their extraction process and selective and sensitive food determination are very important. This review focuses on the extraction processes, analytical methods, and health effects of major phenolic compounds in foods. The examination encompasses a comprehensive analysis of analytical approaches and their applications in elucidating the presence and impact of these compounds on human health.
医疗保健服务成本的不断攀升以及个人健康责任意识的不断增强,促使人们在使用传统药物改善健康和预防疾病的同时,也开始探索自然疗法。全球老龄化人口的健康需求不断增加,尤其是与糖尿病、心脏病和高血压等疾病有关的需求。与生活方式相关的疾病、不良的饮食习惯和久坐不动的生活方式,都凸显了含有营养物质的食物对预防和控制这些疾病的重要性。酚类化合物是植物化学物质的基本成分之一,在自然界的化学多样性中占有重要地位,在功能食品中含量丰富。这些化合物广泛分布于植物的各个部位,具有重要的功能和感官特性,包括颜色、味道和香气。它们具有多种功能,尤其是抗氧化活性,在减轻细胞氧化应激方面发挥着至关重要的作用,有可能减少与心血管疾病、神经退行性疾病23 和癌症等严重健康问题相关的损害。酚类化合物以不同的形式存在,有些与苷类结合在一起,影响其生物效应和吸收。从植物中分离出的约 8000 种多酚为天然药物和营养补充剂提供了巨大的潜力。因此,它们的提取过程以及选择性和灵敏的食品测定非常重要。本综述侧重于食品中主要酚类化合物的提取过程、分析方法和对健康的影响。文章全面分析了分析方法及其在阐明这些化合物的存在及其对人体健康的影响方面的应用。
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引用次数: 0
Advances of Transition Metal-Based Electrochemical Non-enzymatic Glucose Sensors for Glucose Analysis: A Review 用于葡萄糖分析的过渡金属基电化学非酶切葡萄糖传感器的进展:综述
IF 5 2区 化学 Q1 Chemistry Pub Date : 2024-04-18 DOI: 10.1080/10408347.2024.2339955
Haotian Li, Nan Xiao, Mengyi Jiang, Jianjun Long, Zhanhong Li, Zhigang Zhu
Glucose concentration is a crucial parameter for assessing human health. Over recent years, non-enzymatic electrochemical glucose sensors have drawn considerable attention due to their substantial ...
葡萄糖浓度是评估人体健康的一个重要参数。近年来,非酶电化学葡萄糖传感器因其巨大的潜力而备受关注。
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引用次数: 0
Current Analytical Methods for the Sensitive Assay of New-Generation Ovarian Cancer Drugs in Pharmaceutical and Biological Samples 当前用于灵敏检测药物和生物样本中新一代卵巢癌药物的分析方法
IF 5 2区 化学 Q1 Chemistry Pub Date : 2024-04-17 DOI: 10.1080/10408347.2024.2339962
Ahmet Cetinkaya, S. Irem Kaya, Fatma Budak, Sibel A Ozkan
Ovarian cancer, which affects the female reproductive organs, is one of the most common types of cancer. Since this type of cancer has a high mortality rate from gynaecological cancers, the scienti...
影响女性生殖器官的卵巢癌是最常见的癌症类型之一。由于这种癌症在妇科癌症中的死亡率很高,因此科学界对其进行了深入研究。
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引用次数: 0
Recent Progress on Potentiometric Sensor Applications Based on Nanoscale Metal Oxides: A Comprehensive Review 基于纳米级金属氧化物的电位传感器应用的最新进展:全面综述
IF 5 2区 化学 Q1 Chemistry Pub Date : 2024-04-09 DOI: 10.1080/10408347.2024.2337876
Umer Shahzad, Mohsin Saeed, Hadi M. Marwani, Jehan Y. Al-Humaidi, Shujah ur Rehman, Raed H. Althomali, Md. Rabiul Awual, Mohammed M. Rahman
Electrochemical sensors have been the subject of much research and development as of late, with several publications detailing new designs boasting enhanced performance metrics. That is, without a ...
近年来,电化学传感器一直是研究和开发的主题,一些出版物详细介绍了性能指标得到提升的新型设计。也就是说,如果没有...
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引用次数: 0
Recent Advancements and Future Prospects in NBD-Based Fluorescent Chemosensors: Design Strategy, Sensing Mechanism, and Biological Applications 基于 NBD 的荧光化学传感器的最新进展和未来展望:设计策略、传感机制和生物应用
IF 5 2区 化学 Q1 Chemistry Pub Date : 2024-04-09 DOI: 10.1080/10408347.2024.2337869
Gurdeep Kaur, Richa Rani, Jeevika Raina, Iqubal Singh
In recent years, the field of Supramolecular Chemistry has witnessed tremendous progress owing to the development of versatile optical sensors for the detection of harmful biological analytes. Nitr...
近年来,由于用于检测有害生物分析物的多功能光学传感器的开发,超分子化学领域取得了巨大进步。硝...
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引用次数: 0
Exploring the Living Cell: Applications and Advances of Scanning Electrochemical Microscopy. 探索活细胞:扫描电化学显微镜的应用与进展》。
IF 5 2区 化学 Q1 Chemistry Pub Date : 2024-04-01 DOI: 10.1080/10408347.2024.2328135
Margarita Poderyte, Arunas Ramanavicius, Aušra Valiūnienė

A living cell is a complex network of molecular, biochemical and physiological processes. Cellular activities, such as ion transport, metabolic processes, and cell-cell interactions can be determined electrochemically by detecting the electrons or ions exchanged in these processes. Electrochemical methods often are noninvasive, and they can enable the real-time monitoring of cellular processes. Scanning electrochemical microscopy (SECM) is an advanced scanning probe electroanalysis technique that can map the surface topography and local reactivity of a substrate with high precision at the micro- or nanoscale. By measuring electrochemical signals, such as redox reactions, ion fluxes, and pH changes, SECM can provide valuable insights into cellular activity. As a result of its compatibility with liquid medium measurements and its nondestructive nature, SECM has gained popularity in living cell research. This review aims to furnish an overview of SECM, elucidating its principles, applications, and its potential to contribute significantly to advancements in cell biology, electroporation, and biosensors. As a multidisciplinary tool, SECM is distinguished by its ability to unravel the intricacies of living cells and offers promising avenues for breakthroughs in our understanding of cellular complexity.

活细胞是一个复杂的分子、生化和生理过程网络。通过检测这些过程中交换的电子或离子,可以用电化学方法确定细胞活动,如离子转运、新陈代谢过程和细胞间相互作用。电化学方法通常是非侵入性的,可以对细胞过程进行实时监测。扫描电化学显微镜(SECM)是一种先进的扫描探针电分析技术,可在微米或纳米尺度上高精度地绘制基底的表面形貌和局部反应性。通过测量氧化还原反应、离子通量和 pH 值变化等电化学信号,SECM 可以提供有关细胞活动的宝贵信息。由于其与液体介质测量的兼容性和无损性,SECM 在活细胞研究中越来越受欢迎。本综述旨在概述 SECM,阐明其原理、应用及其在推动细胞生物学、电穿孔和生物传感器方面的潜力。作为一种多学科工具,SECM 的独特之处在于它能够揭示活细胞的复杂性,并为我们突破对细胞复杂性的理解提供了一条充满希望的途径。
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引用次数: 0
Recent Advances on Metal Oxide Based Sensors for Environmental Gas Pollutants Detection 基于金属氧化物的环境气体污染物检测传感器的最新进展
IF 5 2区 化学 Q1 Chemistry Pub Date : 2024-03-20 DOI: 10.1080/10408347.2024.2325129
Sofian Kanan, Khaled Obeideen, Matthew Moyet, Heba Abed, Danyah Khan, Aysha Shabnam, Yehya El-Sayed, Mahreen Arooj, Ahmed A Mohamed
Optimizing materials and associated structures for detecting various environmental gas pollutant concentrations has been a major challenge in environmental sensing technology. Semiconducting metal ...
优化用于检测各种环境气体污染物浓度的材料和相关结构一直是环境传感技术的一大挑战。半导体金属...
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引用次数: 0
Advances in Fluorescent Nanosensors for Detection of Vitamin B12. 用于检测维生素 B12 的荧光纳米传感器的进展。
IF 5 2区 化学 Q1 Chemistry Pub Date : 2024-03-18 DOI: 10.1080/10408347.2024.2328104
Yongming Guo, Yijin Li, Yubin Xiang

Vitamin B12 plays a significant role in maintaining human health. Deficiency or excess intake of vitamin B12 may cause some diseases. Therefore, it is significant to fabricate sensors for sensitive assay of vitamin B12. In the past few years, a variety of nanomaterials have been developed for the fluorescence detection of vitamin B12 in tablets, injection, human serum and food. In the review, the assay mechanisms of fluorescent nanomaterials for sensing vitamin B12 were first briefly discussed. And the progress of various nanomaterials for fluorescence detection of vitamin B12 were systematically summarized. Furthermore, the sensing performance of fluorescent nanosensors was compared with fluorescent probes. Lastly, the challenges and perspectives about the topic were presented.

维生素 B12 在维护人类健康方面发挥着重要作用。缺乏或过量摄入维生素 B12 可能会导致某些疾病。因此,制造灵敏检测维生素 B12 的传感器意义重大。在过去几年中,已经开发出多种纳米材料,用于片剂、注射剂、人体血清和食品中维生素 B12 的荧光检测。在综述中,首先简要讨论了荧光纳米材料检测维生素 B12 的机理。并系统总结了各种纳米材料在荧光检测维生素 B12 方面的研究进展。此外,还比较了荧光纳米传感器与荧光探针的传感性能。最后,提出了有关该主题的挑战和展望。
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引用次数: 0
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Critical reviews in analytical chemistry
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