Pub Date : 2024-08-01Epub Date: 2022-08-08DOI: 10.1080/10408347.2022.2107872
Mona Sargazi, Massoud Kaykhaii
Magnetic covalent organic frameworks are new emerging materials which, besides many other applications, have found unique applications in analytical chemistry as separating media and adsorbents. They have outstanding features such as special morphology, chemical and thermal stability, high adsorption capacity, good magnetic response, high specific surface area, uniform pore size distribution, strong π-π interactions with analytes and high reusability that makes reported studies on their properties and applications increased in the recent years. After discussing the methods of synthesis of MCOFs with different geometries that cause their special physic-chemical properties, this review focuses on their high potential which has been exhibited in various applications in extraction and pre-concentration of different analytes such as organic compounds, heavy metal ions and biological samples. The article also highlights the applications of magnetic covalent organic frameworks in other chemical analysis such as adsorbent and being used in sensors.
{"title":"Magnetic Covalent Organic Frameworks-Fundamentals and Applications in Analytical Chemistry.","authors":"Mona Sargazi, Massoud Kaykhaii","doi":"10.1080/10408347.2022.2107872","DOIUrl":"10.1080/10408347.2022.2107872","url":null,"abstract":"<p><p>Magnetic covalent organic frameworks are new emerging materials which, besides many other applications, have found unique applications in analytical chemistry as separating media and adsorbents. They have outstanding features such as special morphology, chemical and thermal stability, high adsorption capacity, good magnetic response, high specific surface area, uniform pore size distribution, strong π-π interactions with analytes and high reusability that makes reported studies on their properties and applications increased in the recent years. After discussing the methods of synthesis of MCOFs with different geometries that cause their special physic-chemical properties, this review focuses on their high potential which has been exhibited in various applications in extraction and pre-concentration of different analytes such as organic compounds, heavy metal ions and biological samples. The article also highlights the applications of magnetic covalent organic frameworks in other chemical analysis such as adsorbent and being used in sensors.</p>","PeriodicalId":10744,"journal":{"name":"Critical reviews in analytical chemistry","volume":null,"pages":null},"PeriodicalIF":4.2,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"40678708","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Cancer is most frequently treated with antineoplastic agents (ANAs) that are hazardous to patients undergoing chemotherapy and the healthcare workers who handle ANAs in the course of their duties. All aspects related to hazardous oncological drugs illustrate that the monitoring of ANAs is essential to minimize the risks associated with these drugs. Among all analytical techniques used to test ANAs, electrochemistry holds an important position. This review, for the first time, comprehensively describes the progress done in electrochemistry of ANAs by means of a variety of bare or modified (bio)sensors over the last four decades (in the period of 1982-2021). Attention is paid not only to the development of electrochemical sensing protocols of ANAs in various biological, environmental, and pharmaceutical matrices but also to achievements of electrochemical techniques in the examination of the interactions of ANAs with deoxyribonucleic acid (DNA), carcinogenic cells, biomimetic membranes, peptides, and enzymes. Other aspects, including the enantiopurity studies, differentiation between single-stranded and double-stranded DNA without using any label or tag, studies on ANAs degradation, and their pharmacokinetics, by means of electrochemical techniques are also commented. Finally, concluding remarks that underline the existence of a significant niche for the basic electrochemical research that should be filled in the future are presented.
治疗癌症最常用的是抗肿瘤药物(ANAs),这些药物对接受化疗的患者和在工作中处理 ANAs 的医护人员都有危害。与危险肿瘤药物有关的各个方面都表明,要将这些药物的相关风险降至最低,就必须对 ANA 进行监测。在用于检测 ANA 的所有分析技术中,电化学技术占有重要地位。本综述首次全面介绍了过去四十年(1982-2021 年)中通过各种裸传感器或改良(生物)传感器对 ANA 进行电化学分析的进展情况。该书不仅关注各种生物、环境和制药基质中 ANA 的电化学传感方案的开发,还关注电化学技术在检测 ANA 与脱氧核糖核酸(DNA)、致癌细胞、生物膜、肽和酶的相互作用方面取得的成就。此外,还对其他方面进行了评论,包括对映体纯度研究、在不使用任何标签或标记的情况下区分单链和双链 DNA、通过电化学技术研究 ANA 的降解及其药代动力学。最后,总结性发言强调了基础电化学研究中存在的一个重要利基,未来应加以填补。
{"title":"Electrochemistry as a Powerful Tool for Investigations of Antineoplastic Agents: A Comprehensive Review.","authors":"Mariola Brycht, Lukasz Poltorak, Simona Baluchová, Karolina Sipa, Paulina Borgul, Konrad Rudnicki, Sławomira Skrzypek","doi":"10.1080/10408347.2022.2106117","DOIUrl":"10.1080/10408347.2022.2106117","url":null,"abstract":"<p><p>Cancer is most frequently treated with antineoplastic agents (ANAs) that are hazardous to patients undergoing chemotherapy and the healthcare workers who handle ANAs in the course of their duties. All aspects related to hazardous oncological drugs illustrate that the monitoring of ANAs is essential to minimize the risks associated with these drugs. Among all analytical techniques used to test ANAs, electrochemistry holds an important position. This review, for the first time, comprehensively describes the progress done in electrochemistry of ANAs by means of a variety of bare or modified (bio)sensors over the last four decades (in the period of 1982-2021). Attention is paid not only to the development of electrochemical sensing protocols of ANAs in various biological, environmental, and pharmaceutical matrices but also to achievements of electrochemical techniques in the examination of the interactions of ANAs with deoxyribonucleic acid (DNA), carcinogenic cells, biomimetic membranes, peptides, and enzymes. Other aspects, including the enantiopurity studies, differentiation between single-stranded and double-stranded DNA without using any label or tag, studies on ANAs degradation, and their pharmacokinetics, by means of electrochemical techniques are also commented. Finally, concluding remarks that underline the existence of a significant niche for the basic electrochemical research that should be filled in the future are presented.</p>","PeriodicalId":10744,"journal":{"name":"Critical reviews in analytical chemistry","volume":null,"pages":null},"PeriodicalIF":4.2,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"40711246","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-01Epub Date: 2022-08-23DOI: 10.1080/10408347.2022.2114785
Wei Long, Indrajit Patra, Firas Rahi Alhachami, Ulugbek Akhrarovich Sherbekov, Ali Majdi, Salwan Ali Abed
Accepting the fact that there is a huge number of virus particles in food that lead to several infectious diseases, eliminating of the foodborne virus from food is tangible. In 2020, the appearance of new SARS-CoV-2 variants had remarked the importance of food safety in our lives. Detection virus is a dynamic domain. Recently, many papers have tried to detect several foodborne viruses by using conventional sensing platforms including ELISA (enzyme-linked immunosorbent assay), PCR (polymerase chain reaction-based methods) and NASBA (nucleic acid sequence-based amplification). However, small sizes, low infective doses and discrete distribution of the foodborne virus have converted these microorganisms into the most challengeable pathogen in the food samples matrix. Foodborne virus detection exploiting aptamer-based biosensors has attracted considerable attention toward the numerous benefits of sourcing from aptamers in which a variety of viruses could be detected by conjugation of aptamer-virus. The development of multiple sensing methodologies and platforms in terms of aptasensor application in real food and environment samples has demonstrated promising results. In this review, we present the latest developments in myriad types of aptasensors (including electrochemical, optical and piezoelectric aptasensor) for the quantification of foodborne viruses. Working strategies, benefits and disadvantages of these platforms are argued.
{"title":"Aptamer Based Nanoprobes for Detection of Foodborne Virus in Food and Environment Samples: Recent Progress and Challenges.","authors":"Wei Long, Indrajit Patra, Firas Rahi Alhachami, Ulugbek Akhrarovich Sherbekov, Ali Majdi, Salwan Ali Abed","doi":"10.1080/10408347.2022.2114785","DOIUrl":"10.1080/10408347.2022.2114785","url":null,"abstract":"<p><p>Accepting the fact that there is a huge number of virus particles in food that lead to several infectious diseases, eliminating of the foodborne virus from food is tangible. In 2020, the appearance of new SARS-CoV-2 variants had remarked the importance of food safety in our lives. Detection virus is a dynamic domain. Recently, many papers have tried to detect several foodborne viruses by using conventional sensing platforms including ELISA (enzyme-linked immunosorbent assay), PCR (polymerase chain reaction-based methods) and NASBA (nucleic acid sequence-based amplification). However, small sizes, low infective doses and discrete distribution of the foodborne virus have converted these microorganisms into the most challengeable pathogen in the food samples matrix. Foodborne virus detection exploiting aptamer-based biosensors has attracted considerable attention toward the numerous benefits of sourcing from aptamers in which a variety of viruses could be detected by conjugation of aptamer-virus. The development of multiple sensing methodologies and platforms in terms of aptasensor application in real food and environment samples has demonstrated promising results. In this review, we present the latest developments in myriad types of aptasensors (including electrochemical, optical and piezoelectric aptasensor) for the quantification of foodborne viruses. Working strategies, benefits and disadvantages of these platforms are argued.</p>","PeriodicalId":10744,"journal":{"name":"Critical reviews in analytical chemistry","volume":null,"pages":null},"PeriodicalIF":4.2,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"40413465","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Buprenorphine is one of the most commonly used pain-killing drugs due to its lengthy duration of action and high potency. However, excessive usage of buprenorphine can be harmful to one's health and prolonged use might result in addiction. Additionally, an increasing number of cases have been documented involving the illegal use of buprenorphine. Therefore, a variety of effective and reliable methods for pretreatment and determination of buprenorphine and its main metabolite norbuprenorphine have been established. This review aims to update the current state of pretreatment and detection techniques for buprenorphine and norbuprenorphine from January 2010 to March 2022. Pretreatment methods include several traditional extraction methods, solid-phase extraction, QuECHERS, various micro-extraction techniques, etc. while analytical methods include LC-MS, LC coupled with other detectors, GC-MS, capillary electrophoresis, electrochemical sensors, etc. The pros and cons of various techniques were compared and summarized, and the prospects were provided.HIGHLIGHTSProgress in pretreatment and detection methods for buprenorphine is demonstrated.Pros and cons of different pretreatment and analysis methods are compared.New materials (such as nanomaterials and magnetic materials) used in buprenorphine pretreatment are summarized.Newly emerged environmental-friendly methods are discussed.
{"title":"Recent Update on Pretreatment and Analysis Methods of Buprenorphine in Different Matrix.","authors":"Bo Pang, Yuan Zhang, Yu Zhou, Zhi-Fei Liu, Xiao-Jun Liu, Xue-Song Feng","doi":"10.1080/10408347.2022.2111196","DOIUrl":"10.1080/10408347.2022.2111196","url":null,"abstract":"<p><p>Buprenorphine is one of the most commonly used pain-killing drugs due to its lengthy duration of action and high potency. However, excessive usage of buprenorphine can be harmful to one's health and prolonged use might result in addiction. Additionally, an increasing number of cases have been documented involving the illegal use of buprenorphine. Therefore, a variety of effective and reliable methods for pretreatment and determination of buprenorphine and its main metabolite norbuprenorphine have been established. This review aims to update the current state of pretreatment and detection techniques for buprenorphine and norbuprenorphine from January 2010 to March 2022. Pretreatment methods include several traditional extraction methods, solid-phase extraction, QuECHERS, various micro-extraction techniques, etc. while analytical methods include LC-MS, LC coupled with other detectors, GC-MS, capillary electrophoresis, electrochemical sensors, etc. The pros and cons of various techniques were compared and summarized, and the prospects were provided.HIGHLIGHTSProgress in pretreatment and detection methods for buprenorphine is demonstrated.Pros and cons of different pretreatment and analysis methods are compared.New materials (such as nanomaterials and magnetic materials) used in buprenorphine pretreatment are summarized.Newly emerged environmental-friendly methods are discussed.</p>","PeriodicalId":10744,"journal":{"name":"Critical reviews in analytical chemistry","volume":null,"pages":null},"PeriodicalIF":4.2,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"40620250","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Sulfonamides are auspicious chemosensors which are capable to bind with ionic species through various ways like complexation, charge transfer, proton transfer etc. and produce a detection signal in the form of an optical change either in visible or UV-light and for electronic as well as fluorimetric spectra. Sulfonamides have gained much attention of analytical chemists these days as these are inexpensive, robust, green in nature and some what sensitive and selective to many anionic and cationic species. Due to their promising versatility in sensing properties, these are under great consideration in forensic, environmental, analytical and biochemistry laboratories. This review narrates how sulfonamides are being used to optically sense ionic species.
{"title":"Sulfonamides as Optical Chemosensors.","authors":"Madeeha Batool, Zartashia Afzal, Hafiz Muhammad Junaid, Amber Rehana Solangi, Areej Hassan","doi":"10.1080/10408347.2022.2105135","DOIUrl":"10.1080/10408347.2022.2105135","url":null,"abstract":"<p><p>Sulfonamides are auspicious chemosensors which are capable to bind with ionic species through various ways like complexation, charge transfer, proton transfer etc. and produce a detection signal in the form of an optical change either in visible or UV-light and for electronic as well as fluorimetric spectra. Sulfonamides have gained much attention of analytical chemists these days as these are inexpensive, robust, green in nature and some what sensitive and selective to many anionic and cationic species. Due to their promising versatility in sensing properties, these are under great consideration in forensic, environmental, analytical and biochemistry laboratories. This review narrates how sulfonamides are being used to optically sense ionic species.</p>","PeriodicalId":10744,"journal":{"name":"Critical reviews in analytical chemistry","volume":null,"pages":null},"PeriodicalIF":4.2,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"40669728","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-01Epub Date: 2022-07-20DOI: 10.1080/10408347.2022.2099733
Reena Solanki, Indrajit Patra, T Ch Anil Kumar, N Bharath Kumar, Mahmoud Kandeel, R Sivaraman, Abduladheem Turki Jalil, Ghulam Yasin, Sandhir Sharma, Haydar Abdulameer Marhoon
The development of portable and efficient nanoprobes to realize the quantitative/qualitative onsite determination of food pollutants is of immense importance for safeguarding human health and food safety. With the advent of the smartphone, the digital imaging property causes it to be an ideal diagnostic substrate to point-of-care analysis probes. Besides, merging the versatility of carbon dots nanostructures and bioreceptor abilities has opened an innovative assortment of construction blocks to design advanced nanoprobes or improving those existing ones. On this ground, massive endeavors have been made to combine mobile phones with smart nanomaterials to produce portable (bio)sensors in a reliable, low cost, rapid, and even facile-to-implement area with inadequate resources. Herein, this work outlines the latest advancement of carbon dots nanostructures on smartphone for onsite detecting of agri-food pollutants. Particularly, we afford a summary of numerous approaches applied for target molecule diagnosis (pesticides, mycotoxins, pathogens, antibiotics, and metal ions), for instance microscopic imaging, fluorescence, colorimetric, and electrochemical techniques. Authors tried to list those scaffolds that are well-recognized in complex media or those using novel constructions/techniques. Lastly, we also point out some challenges and appealing prospects related to the enhancement of high-efficiency smartphone based carbon dots systems.
{"title":"Smartphone-Based Techniques Using Carbon Dot Nanomaterials for Food Safety Analysis.","authors":"Reena Solanki, Indrajit Patra, T Ch Anil Kumar, N Bharath Kumar, Mahmoud Kandeel, R Sivaraman, Abduladheem Turki Jalil, Ghulam Yasin, Sandhir Sharma, Haydar Abdulameer Marhoon","doi":"10.1080/10408347.2022.2099733","DOIUrl":"10.1080/10408347.2022.2099733","url":null,"abstract":"<p><p>The development of portable and efficient nanoprobes to realize the quantitative/qualitative onsite determination of food pollutants is of immense importance for safeguarding human health and food safety. With the advent of the smartphone, the digital imaging property causes it to be an ideal diagnostic substrate to point-of-care analysis probes. Besides, merging the versatility of carbon dots nanostructures and bioreceptor abilities has opened an innovative assortment of construction blocks to design advanced nanoprobes or improving those existing ones. On this ground, massive endeavors have been made to combine mobile phones with smart nanomaterials to produce portable (bio)sensors in a reliable, low cost, rapid, and even facile-to-implement area with inadequate resources. Herein, this work outlines the latest advancement of carbon dots nanostructures on smartphone for onsite detecting of agri-food pollutants. Particularly, we afford a summary of numerous approaches applied for target molecule diagnosis (pesticides, mycotoxins, pathogens, antibiotics, and metal ions), for instance microscopic imaging, fluorescence, colorimetric, and electrochemical techniques. Authors tried to list those scaffolds that are well-recognized in complex media or those using novel constructions/techniques. Lastly, we also point out some challenges and appealing prospects related to the enhancement of high-efficiency smartphone based carbon dots systems.</p>","PeriodicalId":10744,"journal":{"name":"Critical reviews in analytical chemistry","volume":null,"pages":null},"PeriodicalIF":4.2,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"40631814","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-01Epub Date: 2022-08-24DOI: 10.1080/10408347.2022.2113359
Mustafa Oguzhan Caglayan, Samet Şahin, Zafer Üstündağ
Endocrine disruptive compounds are natural or anthropogenic environmental micropollutants that alter the function of the endocrine system ultimately damaging the metabolism. Bisphenol A (BPA) is the most common of these pollutants and it is often used in epoxy coatings and polycarbonates as a plasticizer. Therefore, monitoring BPA levels in different environments is very important and challenging. In recent years, an increasing number of BPA detection methods have been proposed. This article presents a critical review of aptamer-based electrochemical, fluorescence-based, colorimetric, and several other BPA detection platforms published in the last decade. Furthermore, a statistical evaluation has been made using principle component analysis showing analytical performance parameters do not create very different clusters. Comparisons to other BPA detection methods are also presented so that the reader has an overall literature overview.
内分泌干扰化合物是天然或人为的环境微污染物,会改变内分泌系统的功能,最终破坏新陈代谢。双酚 A(BPA)是这类污染物中最常见的一种,它经常被用作环氧树脂涂料和聚碳酸酯的增塑剂。因此,监测不同环境中的双酚 A 含量非常重要,也极具挑战性。近年来,人们提出了越来越多的双酚 A 检测方法。本文对近十年来发表的基于适配体的电化学检测平台、基于荧光的检测平台、比色法检测平台以及其他一些双酚 A 检测平台进行了深入评述。此外,文章还使用原理成分分析法进行了统计评估,结果显示分析性能参数不会形成差异很大的群组。同时还介绍了与其他双酚 A 检测方法的比较,以便读者对文献有一个全面的了解。
{"title":"An Overview of Aptamer-Based Sensor Platforms for the Detection of Bisphenol-A.","authors":"Mustafa Oguzhan Caglayan, Samet Şahin, Zafer Üstündağ","doi":"10.1080/10408347.2022.2113359","DOIUrl":"10.1080/10408347.2022.2113359","url":null,"abstract":"<p><p>Endocrine disruptive compounds are natural or anthropogenic environmental micropollutants that alter the function of the endocrine system ultimately damaging the metabolism. Bisphenol A (BPA) is the most common of these pollutants and it is often used in epoxy coatings and polycarbonates as a plasticizer. Therefore, monitoring BPA levels in different environments is very important and challenging. In recent years, an increasing number of BPA detection methods have been proposed. This article presents a critical review of aptamer-based electrochemical, fluorescence-based, colorimetric, and several other BPA detection platforms published in the last decade. Furthermore, a statistical evaluation has been made using principle component analysis showing analytical performance parameters do not create very different clusters. Comparisons to other BPA detection methods are also presented so that the reader has an overall literature overview.</p>","PeriodicalId":10744,"journal":{"name":"Critical reviews in analytical chemistry","volume":null,"pages":null},"PeriodicalIF":4.2,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"40651661","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-01Epub Date: 2022-08-02DOI: 10.1080/10408347.2022.2105136
Goksu Ozcelikay, Ahmet Cetinkaya, S Irem Kaya, Merve Yence, Pembe Ece Canavar Eroğlu, Mehmet Altay Unal, Sibel A Ozkan
The rapid quantification of toxins in food and beverage products has become a significant issue in overcoming and preventing many life-threatening diseases. Aflatoxin-contaminated food is one of the reasons for primary liver cancer and induces some tumors and cancer types. Advancements in biosensors technology have brought out different analysis methods. Therefore, the sensing performance has been improved for agricultural and beverage industries or food control processes. Nanomaterials are widely used for the enhancement of sensing performance. The enzymes, molecularly imprinted polymers (MIP), antibodies, and aptamers can be used as biorecognition elements. The transducer part of the biosensor can be selected, such as optical, electrochemical, and mass-based. This review explains the classification of major types of aflatoxins, the importance of nanomaterials, electrochemical, optical biosensors, and QCM and their applications for the determination of aflatoxins.
{"title":"Novel Sensor Approaches of Aflatoxins Determination in Food and Beverage Samples.","authors":"Goksu Ozcelikay, Ahmet Cetinkaya, S Irem Kaya, Merve Yence, Pembe Ece Canavar Eroğlu, Mehmet Altay Unal, Sibel A Ozkan","doi":"10.1080/10408347.2022.2105136","DOIUrl":"10.1080/10408347.2022.2105136","url":null,"abstract":"<p><p>The rapid quantification of toxins in food and beverage products has become a significant issue in overcoming and preventing many life-threatening diseases. Aflatoxin-contaminated food is one of the reasons for primary liver cancer and induces some tumors and cancer types. Advancements in biosensors technology have brought out different analysis methods. Therefore, the sensing performance has been improved for agricultural and beverage industries or food control processes. Nanomaterials are widely used for the enhancement of sensing performance. The enzymes, molecularly imprinted polymers (MIP), antibodies, and aptamers can be used as biorecognition elements. The transducer part of the biosensor can be selected, such as optical, electrochemical, and mass-based. This review explains the classification of major types of aflatoxins, the importance of nanomaterials, electrochemical, optical biosensors, and QCM and their applications for the determination of aflatoxins.</p>","PeriodicalId":10744,"journal":{"name":"Critical reviews in analytical chemistry","volume":null,"pages":null},"PeriodicalIF":4.2,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"40663754","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Cerium accumulation in the environment increases the health risk of humans due to the unavoidable usage of cerium in our day-to-day life. Therefore, developing a chemosensory scaffold for the rapid detection of cerium is necessary. With the objective of assessing and understanding the various factors involved in the sensing of Ce4+, this review consolidates all the 34 chemosensory molecules, mechanisms, techniques, matrices and discusses all the relevant parameters comprehensively. 23 out of 34 probes are directly utilizing the oxidative capability of Ce4+ for the detection and undergo color changes. Probes that are demonstrated with metal enhanced fluorescence exhibit lower detection limits. Based on the survey, we suggest that the investigation of the rigidity of "probe- Ce4+" and its impact on the emission/quenching should be considered for designing an efficient Ce4+ sensor. This is the first review report on the Ce4+ sensors and it could serve as a one-point reference source.
{"title":"Spectrophotometric, Spectrofluorometric and Colorimetric Sensing of Ce<sup>4+</sup> Ions Using Organic Molecules - A Review.","authors":"Sivakumar Krishnamoorthy, Parinamachivayam Ganasan","doi":"10.1080/10408347.2022.2103640","DOIUrl":"10.1080/10408347.2022.2103640","url":null,"abstract":"<p><p>Cerium accumulation in the environment increases the health risk of humans due to the unavoidable usage of cerium in our day-to-day life. Therefore, developing a chemosensory scaffold for the rapid detection of cerium is necessary. With the objective of assessing and understanding the various factors involved in the sensing of Ce<sup>4+</sup>, this review consolidates all the 34 chemosensory molecules, mechanisms, techniques, matrices and discusses all the relevant parameters comprehensively. 23 out of 34 probes are directly utilizing the oxidative capability of Ce<sup>4+</sup> for the detection and undergo color changes. Probes that are demonstrated with <i>metal enhanced fluorescence</i> exhibit lower detection limits. Based on the survey, we suggest that the investigation of the rigidity of \"<i>probe- Ce<sup>4+</sup></i>\" and its impact on the <i>emission/quenching</i> should be considered for designing an efficient <i>Ce<sup>4+</sup></i> sensor. This is the first review report on the Ce<sup>4+</sup> sensors and it could serve as a one-point reference source.</p>","PeriodicalId":10744,"journal":{"name":"Critical reviews in analytical chemistry","volume":null,"pages":null},"PeriodicalIF":4.2,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"40540721","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-01Epub Date: 2022-08-09DOI: 10.1080/10408347.2022.2109125
Ahmet Cetinkaya, S Irem Kaya, Goksu Ozcelikay, Fatma Budak, Sibel A Ozkan
Nowadays, the rapid improvements in the medical and pharmaceutical fields increase the diversity and use of drugs. However, problems such as the use of multiple or combined drugs in the treatment of diseases and insensible use of over-the-counter drugs have caused concerns about the side-effect profiles and therapeutic ranges of drugs and environmental contamination and pollution problems due to pharmaceuticals waste. Therefore, the analysis of drugs in various media such as biological, pharmaceutical, and environmental samples is an important topic of discussion. Electrochemical methods are advantageous for sensor applications due to their easy application, low cost, versatility, high sensitivity, and environmentally-friendliness. Carbon nanomaterials such as diamond-like carbon thin films, carbon nanotubes, carbon nanofibers, graphene oxide, and nanodiamonds are used to enhance the performance of the electrochemical sensors with catalytic effects. To further improve this effect, it is aimed to create hybrid platforms by using different carbon nanomaterials together or with materials such as conductive polymers and ionic liquids. In this review, the most used carbon nanoforms will be evaluated in terms of electrochemical characterizations and physicochemical properties. Furthermore, the effect of hybrid platforms developed in the most recent studies on electrochemical sensors will be examined and evaluated in terms of drug analysis studies in the last five years.
{"title":"Carbon Nanomaterials-Based Novel Hybrid Platforms for Electrochemical Sensor Applications in Drug Analysis.","authors":"Ahmet Cetinkaya, S Irem Kaya, Goksu Ozcelikay, Fatma Budak, Sibel A Ozkan","doi":"10.1080/10408347.2022.2109125","DOIUrl":"10.1080/10408347.2022.2109125","url":null,"abstract":"<p><p>Nowadays, the rapid improvements in the medical and pharmaceutical fields increase the diversity and use of drugs. However, problems such as the use of multiple or combined drugs in the treatment of diseases and insensible use of over-the-counter drugs have caused concerns about the side-effect profiles and therapeutic ranges of drugs and environmental contamination and pollution problems due to pharmaceuticals waste. Therefore, the analysis of drugs in various media such as biological, pharmaceutical, and environmental samples is an important topic of discussion. Electrochemical methods are advantageous for sensor applications due to their easy application, low cost, versatility, high sensitivity, and environmentally-friendliness. Carbon nanomaterials such as diamond-like carbon thin films, carbon nanotubes, carbon nanofibers, graphene oxide, and nanodiamonds are used to enhance the performance of the electrochemical sensors with catalytic effects. To further improve this effect, it is aimed to create hybrid platforms by using different carbon nanomaterials together or with materials such as conductive polymers and ionic liquids. In this review, the most used carbon nanoforms will be evaluated in terms of electrochemical characterizations and physicochemical properties. Furthermore, the effect of hybrid platforms developed in the most recent studies on electrochemical sensors will be examined and evaluated in terms of drug analysis studies in the last five years.</p>","PeriodicalId":10744,"journal":{"name":"Critical reviews in analytical chemistry","volume":null,"pages":null},"PeriodicalIF":4.2,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"40596618","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}