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Liquefaction and filling of liquid methane and oxygen bipropellant in a common bulkhead tank equipped with a zero boil-off system 在装有零沸腾系统的共用舱壁罐中液化和填充液态甲烷和氧气双推进剂
IF 1.8 3区 工程技术 Q3 PHYSICS, APPLIED Pub Date : 2024-09-01 DOI: 10.1016/j.cryogenics.2024.103943
Wujie Zhang , Hao Zhang , Bin Wang , Wenbing Jiang , Ruijiao Miao , Yonghua Huang

An experimental setup incorporating a tank with a non-insulated common bulkhead inside and a zero-boil-off system outside was designed and established to investigate the transient thermodynamic characteristics of bipropellant liquid oxygen and methane during liquefaction, filling, and zero-boil-off storage processes. The results demonstrate the advantage of the non-insulated common bulkhead tank in storing liquid oxygen and liquid methane. The non-insulated common bulkhead provided an additional heat transfer pathway, allowing the cold energy released by liquid oxygen to be used to improve the cooling rate of methane and stabilize its storage state during the liquefaction and filling processes. Furthermore, the influence of the operational modes of the zero-boil-off system on the storage states of the fluids was examined. The cooling power delivered by the zero-boil-off system was identified as the most critical factor affecting the storage state of the fluids in the common bulkhead tank. In the absence of cooling power, the temperature rising rates in the liquid oxygen and liquid methane compartments were 4.3 K/h and 4.4 K/h, respectively. Compared with the results during the helium circulator standby stage, the pressure difference between the two compartments increased by 62.73 % in the absence of cooling power. The findings indicate the necessity of maintaining adequate cooling power to achieve stable zero boil-off storage, providing guidelines for the design and operation of practical liquid oxygen-liquid methane common bulkhead storage tanks with zero boil-off requirements.

为了研究双推进剂液氧和甲烷在液化、填充和零沸腾储存过程中的瞬态热力学特性,设计并建立了一个实验装置,其中包括一个内部装有非隔热共用隔板、外部装有零沸腾系统的储罐。结果表明了非隔热共用隔板储罐在储存液氧和液态甲烷方面的优势。非隔热共用隔板提供了额外的传热途径,使液氧释放的冷能可用于提高甲烷的冷却速度,并在液化和填充过程中稳定其储存状态。此外,还研究了零沸腾系统的运行模式对流体储存状态的影响。零沸腾系统提供的冷却功率被认为是影响共用隔板罐中液体储存状态的最关键因素。在没有冷却功率的情况下,液氧舱和液态甲烷舱的温度上升率分别为 4.3 K/h 和 4.4 K/h。与氦循环器备用阶段的结果相比,在没有冷却动力的情况下,两个舱室之间的压差增加了 62.73%。研究结果表明,要实现稳定的零沸腾贮存,必须保持足够的冷却功率,这为设计和运行具有零沸腾要求的实用液氧-液态甲烷共用隔板贮存罐提供了指导。
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引用次数: 0
Fault diagnosis of new type screw compressor of helium liquefier by vibration signal 通过振动信号诊断新型氦液化器螺杆压缩机的故障
IF 1.8 3区 工程技术 Q3 PHYSICS, APPLIED Pub Date : 2024-08-31 DOI: 10.1016/j.cryogenics.2024.103942
Zhongjun Hu , Xiajun Wu , Zhenzhong Zhu , Bingming Wang

A diagnostic method for screw compressor faults using vibration signals was introduced and applied to a new type of helium oil-injected screw compressor in the 80L/h helium liquefier. The study revealed that the destruction of the oil film due to impurity particles could lead to rotor rubbing and poor meshing, compromising the reliability of these compressors. Based on frequency-domain analysis, the major vibration occurred at the meshing frequency of screw rotors and a series of its harmonics. The vibration of the characteristic frequency of bearing parts also indicated that the bearing had slight wear in the early stage. The vibration waveform’s time domain diagram exhibited clear clipping, and the axis trajectory shew disorder, which were common characteristic of rotor rubbing. When compressing helium with low molecular weight, the meshing clearance, tooth tip clearance, and end clearance of the rotor were significantly lower than those of traditional refrigerants or air media. Additionally, the thermal gap caused by thermoelastic deformation was smaller due to the large adiabatic index of helium. Therefore, rubbing faults between rotors and between rotors and casing were more likely to occur. The article recommended establishing a vibration signal monitoring system, optimizing the design of helium screw rotor profiles, and setting up reliability standards for screw compressor operation, such as limiting the vibration speed to ≤ 8 mm/s. Additionally, attention should be given to cleaning gas pipelines in cryogenic engineering and monitoring compressor vibration and noise signals during operation to prevent rotor damage due to particle impurities.

介绍了一种利用振动信号诊断螺杆压缩机故障的方法,并将其应用于 80 升/小时氦液化器中的新型氦油喷射螺杆压缩机。研究发现,杂质颗粒对油膜的破坏会导致转子摩擦和啮合不良,从而影响这些压缩机的可靠性。根据频域分析,主要振动发生在螺杆转子的啮合频率及其一系列谐波上。轴承部件特征频率的振动也表明轴承在早期阶段有轻微磨损。振动波形的时域图显示出明显的削波和轴轨迹的紊乱,这是转子摩擦的常见特征。在压缩低分子量氦气时,转子的啮合间隙、齿尖间隙和端面间隙明显低于传统制冷剂或空气介质。此外,由于氦气的绝热指数较大,热弹性变形造成的热间隙也较小。因此,转子之间以及转子与外壳之间更容易发生摩擦故障。文章建议建立振动信号监测系统,优化氦气螺杆转子外形设计,并制定螺杆压缩机运行的可靠性标准,例如将振动速度限制在 ≤ 8 mm/s。此外,还应注意清洁低温工程中的气体管道,监测压缩机运行期间的振动和噪声信号,以防止颗粒杂质导致转子损坏。
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引用次数: 0
Numerical and experimental investigation of 12 W/60 K high-efficiency coaxial pulse tube cryocooler 12 W/60 K 高效同轴脉冲管低温冷却器的数值和实验研究
IF 1.8 3区 工程技术 Q3 PHYSICS, APPLIED Pub Date : 2024-08-30 DOI: 10.1016/j.cryogenics.2024.103941
Yanen Li , Nailiang Wang , Miguang Zhao , Qingjun Tang , Yuqiang Xun

Maintaining a low-temperature environment is paramount in pursuing reliable operation for infrared detectors. To address the rising demand for long-wave infrared detectors functioning in low-temperature environments around 60 K, this study investigates the enhanced efficiency of a 60 K coaxial pulse tube cryocooler (PTC) through both simulation analysis and experimental methods. A PTC model was developed using Sage software to optimize parameters such as cold finger size. Analysis of the internal flow field highlighted that variations in cold head temperature, frequency, and input power significantly impact phase angle distribution within the regenerator. Experimental results yielded the same conclusion and confirmed how these critical factors affect the PTC’s performance. Through systematic optimization of simulations and experiments, a cooling performance of 12.7 W/60 K was achieved with an input power of 300 W. Furthermore, when the input power of the PTC was 200 W, a cooling capacity of 9.2 W/60 K was achieved, demonstrating a relative Carnot efficiency of 18.3 %.

保持低温环境对红外探测器的可靠运行至关重要。为了满足在 60 K 左右低温环境中运行的长波红外探测器日益增长的需求,本研究通过模拟分析和实验方法研究了如何提高 60 K 同轴脉冲管低温冷却器(PTC)的效率。使用 Sage 软件开发了 PTC 模型,以优化冷指尺寸等参数。对内部流场的分析突出表明,冷头温度、频率和输入功率的变化对再生器内部的相角分布有显著影响。实验结果也得出了同样的结论,并证实了这些关键因素对 PTC 性能的影响。此外,当 PTC 的输入功率为 200 W 时,冷却能力为 9.2 W/60 K,相对卡诺效率为 18.3%。
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引用次数: 0
Experimental study and infrared detector application research of micro miniature refrigerators 微型电冰箱的实验研究和红外探测器的应用研究
IF 1.8 3区 工程技术 Q3 PHYSICS, APPLIED Pub Date : 2024-08-30 DOI: 10.1016/j.cryogenics.2024.103929
Xin Tong , Jie Qiu , Jia-peng Li , Kun-yuan Xie , Jun-yuan Chen , Yang Huai , Shu-fen Li , Yi-bin Huang , Wei Dong

The MMR(Micro Miniature Refrigerator)is a novel Joule-Thomson cryocooler manufactured by micro-machining technologies, its axial length is significantly shorter than traditional Joule-Thomson cryocoolers commonly employed in infrared detectors. MMRs can greatly reduce the size of infrared detectors upon successful implementation. However, contemporary MMR products encounter challenges such as relatively low cool-down rates, cooling power, and structural strength. To address these issues and enhance the cool-down performance of the MMR for effective application in infrared detectors, a calculation model describing flow and heat transfer besides working characteristics of the MMR is proposed and verified. MMR prototypes are fabricated and experimentally studied. Building upon theoretical analysis and experimental findings cooling performance enhancement methods including transitioning the MMR material from glass to metal and modifying the structure and channel patterns of the MMR are introduced, the cooling performance of the MMR is thus greatly improved. Furthermore, an integrated design incorporating an MMR into an infrared detector is proposed, the axial length of this infrared detector is reduced by 65.3 % compared to conventional infrared detectors. And the MMR is further enhanced to adapt the working conditions in infrared detectors, 60.9 MPa working pressure and 38 s cool-down time is achieved, the cool-down requirements of infrared detectors is satisfied. Notably, the proposed MMR and infrared detector design in this paper exhibit technical advantages over similar products reported in the literature.

MMR(微型制冷器)是一种利用微加工技术制造的新型焦耳-汤姆逊低温制冷器,其轴向长度明显短于红外探测器中常用的传统焦耳-汤姆逊低温制冷器。一旦成功实施,MMR 可大大缩小红外探测器的尺寸。然而,当代 MMR 产品遇到了一些挑战,如冷却速率、冷却功率和结构强度相对较低。为了解决这些问题,提高 MMR 的冷却性能,使其在红外探测器中得到有效应用,我们提出并验证了一个除 MMR 工作特性外,还能描述其流动和传热的计算模型。对 MMR 原型进行了制造和实验研究。在理论分析和实验结果的基础上,介绍了提高冷却性能的方法,包括将 MMR 材料从玻璃过渡到金属,以及修改 MMR 的结构和通道模式,从而大大提高了 MMR 的冷却性能。此外,还提出了一种将 MMR 集成到红外探测器中的集成设计,与传统红外探测器相比,这种红外探测器的轴向长度减少了 65.3%。为了适应红外探测器的工作条件,进一步增强了 MMR,实现了 60.9 MPa 的工作压力和 38 秒的冷却时间,满足了红外探测器的冷却要求。值得注意的是,与文献报道的同类产品相比,本文提出的 MMR 和红外探测器设计具有技术优势。
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引用次数: 0
Investigating Taconis oscillations in a U-shaped tube with hydrogen and helium 研究 U 型氢氦管中的塔康尼斯振荡
IF 1.8 3区 工程技术 Q3 PHYSICS, APPLIED Pub Date : 2024-08-30 DOI: 10.1016/j.cryogenics.2024.103940
Matthew P. Shenton, Jacob W. Leachman, Konstantin I. Matveev

Taconis oscillations are thermally induced spontaneous excitations of acoustic modes in tubes subjected to large temperature gradients. Cryogenic systems that experience these excitations suffer from increased heat leak and vibrations. This heat leak may also increase boil-off in long-term storage vessels for liquid hydrogen. In this study, U-shaped closed-end tubes with a cold mid-section are experimentally investigated to quantify the oscillation characteristics for hydrogen- and helium-filled systems at various mean pressures, including supercritical hydrogen states. Experimental measurements of the temperature distribution along the tube and acoustic pressure amplitudes and frequencies are taken in constant- and variable-diameter configurations near the onset of oscillations. Thirty different conditions are recorded with mean pressures ranging from 126 kPa to 1127 kPa for helium and 161 kPa to 1816 kPa for hydrogen. A low-amplitude thermoacoustic model is applied to predict the cold temperature and frequency corresponding to the onset of Taconis oscillations. The findings of this study indicate that Taconis oscillations in systems with hydrogen occur at smaller temperature differences than in more traditional helium systems by approximately 10 K. Hydrogen in the constant-diameter configuration excited when cryogenic temperatures reached 35–40 K, whereas helium excited when cryogenic temperatures reached 20–30 K. Special tubing networks, such as wider segments in the warm portion, can drastically elevate the excitation cold temperature resulting in onset temperatures between 50–60 K for both fluids. Taconis oscillations are also found to exist in conditions when liquid hydrogen starts forming in the cold zone of the system, as well as in supercritical states. The presented measurements are useful for designing cryogenic hydrogen storage systems to control these oscillations.

塔康尼振荡是在温度梯度较大的管道中,由热引起的声学模式自发激发。经历过这些激振的低温系统会受到热泄漏和振动加剧的影响。这种热泄漏还可能增加液氢长期储存容器的沸腾。本研究通过实验研究了具有冷中段的 U 型封闭端管,以量化氢气和氦气填充系统在不同平均压力(包括超临界氢状态)下的振荡特性。在振荡开始附近的恒定和可变直径配置中,对沿管子的温度分布以及声压振幅和频率进行了实验测量。记录了 30 种不同条件,氦气的平均压力从 126 kPa 到 1127 kPa,氢气的平均压力从 161 kPa 到 1816 kPa。应用低振幅热声模型来预测塔康尼振荡开始时的相应低温和频率。研究结果表明,氢气系统中的塔康尼振荡发生的温差比传统氦气系统中的温差小约 10 K。恒定直径配置中的氢气在低温达到 35-40 K 时发生激励,而氦气在低温达到 20-30 K 时发生激励。在系统冷区开始形成液氢以及超临界状态时,也会出现塔康尼振荡。这些测量结果有助于设计低温储氢系统来控制这些振荡。
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引用次数: 0
Theoretical investigation of HTS compact microstrip antennas printed on anisotropic substrates using hybrid cavity model 利用混合腔模型对各向异性基底上印刷的 HTS 紧凑型微带天线进行理论研究
IF 1.8 3区 工程技术 Q3 PHYSICS, APPLIED Pub Date : 2024-08-29 DOI: 10.1016/j.cryogenics.2024.103935
Mohamed Bedra , Sami Bedra , Tarek Fortaki , Djemai Arar , Djamel Benatia , Akram Bediaf

This work explores the effects of a compact, superconducting C-shaped patch printed on uniaxial anisotropic substrate, utilizing two uniaxial substrate materials: boron nitride and magnesium fluoride. This study employed the superconducting material BSCCO (2212 BSCCO crystal), with a critical temperature of 95 K. Using the hybrid cavity model, we identified and extracted two key parameters: the resonance frequency of conductive elements and the superconducting resonance frequency. We analyzed the impact of the operating temperature on the resonant frequency of a C-shaped superconductivity microstrip antenna, as well as the effect of the uniaxial substrate material and its thickness on the surface resistance and surface reactance. The results showed that temperature significantly affects the resonant frequency of the compact antenna. Our research highlighted the importance of selecting the correct operating temperature for a superconducting microstrip antenna to ensure optimal performance in compact microstrip antenna designs.

本研究利用氮化硼和氟化镁两种单轴基底材料,探索了在单轴各向异性基底上印刷紧凑型超导 C 形贴片的效果。这项研究采用了临界温度为 95 K 的超导材料 BSCCO(2212 BSCCO 晶体)。利用混合空腔模型,我们确定并提取了两个关键参数:导电元件的共振频率和超导共振频率。我们分析了工作温度对 C 型超导微带天线谐振频率的影响,以及单轴衬底材料及其厚度对表面电阻和表面电抗的影响。结果表明,温度对紧凑型天线的谐振频率有很大影响。我们的研究强调了为超导微带天线选择正确工作温度的重要性,以确保紧凑型微带天线设计的最佳性能。
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引用次数: 0
Performance optimization of a neon turboexpander based on the Kriging model and genetic algorithm 基于克里金模型和遗传算法的霓虹灯涡轮膨胀机性能优化
IF 1.8 3区 工程技术 Q3 PHYSICS, APPLIED Pub Date : 2024-08-28 DOI: 10.1016/j.cryogenics.2024.103938
Zhihang Zhang , Zhengze Chang , Changcheng Ma , Yi Huo , Rui Ge

The rapid development of high-temperature superconducting (HTS) technology has increased demand for stable and reliable cooling sources, with the neon refrigerator emerging as a favorable solution for HTS applications, among which neon turboexpander is the core component. This paper proposes an optimal design method tailored for the neon turboexpander, which combines a one-dimensional mean-line design, three-dimensional CFD analysis, adaptive Kriging surrogate model, and the genetic algorithm. The meridional contour of the turboexpander impeller is geometrically parameterized, and the three most critical structural parameters are selected through Sobol sensitivity analysis, and then the response surface analysis is carried out to analyze the coupling relationship between the structural parameters. After optimization, the total-to-static efficiency and output power of the neon turboexpander increased by 3.98% and 6.12%, respectively. Notably, the flow separation phenomenon within the optimized impeller is significantly improved, resulting in reduced flow loss. Furthermore, the optimized impeller demonstrates robust performance in a wide range of variable operating conditions. Therefore, the optimization design method has been proven effective, and the optimal turboexpander impeller structure can be obtained quickly and accurately.

高温超导(HTS)技术的快速发展对稳定可靠的冷却源提出了更高的要求,氖制冷机成为 HTS 应用的有利解决方案,而氖涡轮膨胀机是其中的核心部件。本文结合一维平均线设计、三维 CFD 分析、自适应克里金代用模型和遗传算法,提出了针对氖涡轮膨胀机的优化设计方法。对涡轮增压器叶轮的子午线轮廓进行几何参数化,通过 Sobol 敏感性分析选出三个最关键的结构参数,然后进行响应面分析,分析结构参数之间的耦合关系。优化后,氖涡轮膨胀机的总静态效率和输出功率分别提高了 3.98% 和 6.12%。值得注意的是,优化后叶轮内的流动分离现象得到了显著改善,从而减少了流动损失。此外,优化后的叶轮在各种不同的运行条件下都表现出稳定的性能。因此,优化设计方法被证明是有效的,可以快速准确地获得最佳涡轮膨胀机叶轮结构。
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引用次数: 0
Highly sensitive one-dimensional Dielectric-Superconductor photonic crystal structure for low temperature sensing applications 用于低温传感应用的高灵敏度一维介电-超导体光子晶体结构
IF 1.8 3区 工程技术 Q3 PHYSICS, APPLIED Pub Date : 2024-08-27 DOI: 10.1016/j.cryogenics.2024.103934
Bishwajeet Pandey , Raju Hajare , Ranjith B Gowda , Wan Aezwani Wan Abu Bakar , Preeta Sharan

The work proposed in this paper investigates the design and simulation of low temperature refractive-index (RI) sensor using one-dimensional photonic crystal (1D-PhC) structure. The bilayer stack is created using dielectric and superconductor materials. The dielectric material is assumed to be air and the superconductor considered is YaBa2Cu3O7. Compared to superconductor material, air’s RI is hardly affected by the temperature. The parameter perceived by the suggested sensor for precise temperature measurement in the region of 10 K to 90 K is thought to be the superconductor’s RI, which is a function of temperature. To the best of our knowledge, the structural characteristics of single superconductor material have been precisely adjusted to increase sensor efficiency to a level never before seen in published research. According to the findings, the temperature sensitivity of 1.524 nm/K and the maximum RI sensitivity of 1079.42 nm/RIU are found in the proposed structure. Applications for bio-sensing are a good fit for the suggested sensing device.

本文提出的工作研究了利用一维光子晶体(1D-PhC)结构设计和模拟低温折射率(RI)传感器。双层堆栈是使用介电材料和超导体材料创建的。电介质材料假定为空气,超导体假定为 YaBa2Cu3O7。与超导体材料相比,空气的 RI 几乎不受温度影响。在 10 K 到 90 K 的温度范围内,建议的传感器所感知的精确温度测量参数被认为是超导体的 RI,它是温度的函数。据我们所知,单一超导体材料的结构特性已得到精确调整,从而将传感器的效率提高到已发表研究中从未见过的水平。根据研究结果,拟议结构的温度灵敏度为 1.524 nm/K,最大 RI 灵敏度为 1079.42 nm/RIU。建议的传感装置非常适合应用于生物传感。
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引用次数: 0
Evaporation characteristics of single free-falling liquefied natural gas droplet under different ambient conditions based on the VOF method 基于 VOF 方法的单个自由下落液化天然气液滴在不同环境条件下的蒸发特性
IF 1.8 3区 工程技术 Q3 PHYSICS, APPLIED Pub Date : 2024-08-22 DOI: 10.1016/j.cryogenics.2024.103928
Kang Cen , Wenxuan Li , Jun Jin , Mengxin Li , Siyu Chen , Lie Wei

The evaporation characteristics of droplets is a fundamental issue for accurate depictions of moving liquefied natural gas (LNG) droplets and constantly changing ambient environment owing to intense heat, mass transfer, and momentum exchanges. In this study, a modified droplet evaporation model is developed to investigate the evaporation behavior of a single free-falling LNG droplet under various ambient conditions. The proposed model captures the droplet interface and calculates the mass transfer rate through the vapor concentration gradient using the volume of fluid method integrated with a smooth function. Evaporation experiments were conducted on a single free-falling LNG droplet to capture the evaporation process. The results indicate that it is acceptable to ignore the effect of the Stefan flow of a single free-falling LNG droplet. This study also examined the impact of different ambient conditions on evaporation characteristics. The results indicate that the evolution of the droplet diameter is mainly influenced by the ambient temperature because it affects the thermal properties of the surrounding gas and the distribution of the boundary layer. The temporal characteristics of the Nu and Sh numbers generally stabilize after a period of rapid decline. This study provides a theoretical basis for understanding the evaporation mechanisms of LNG droplets.

液滴的蒸发特性是准确描述移动的液化天然气(LNG)液滴以及由于强烈的热量、质量传递和动量交换而不断变化的环境的一个基本问题。本研究开发了一种改进的液滴蒸发模型,用于研究单个自由下落的液化天然气液滴在各种环境条件下的蒸发行为。所提出的模型捕捉了液滴界面,并使用流体体积法计算了通过蒸汽浓度梯度的传质速率,同时集成了一个平滑函数。对单个自由下落的液化天然气液滴进行了蒸发实验,以捕捉蒸发过程。结果表明,忽略单个自由下落液化天然气液滴的斯特凡流的影响是可以接受的。这项研究还考察了不同环境条件对蒸发特性的影响。结果表明,液滴直径的变化主要受环境温度的影响,因为环境温度会影响周围气体的热特性和边界层的分布。Nu 和 Sh 数值的时间特征一般在快速下降一段时间后趋于稳定。这项研究为理解液化天然气液滴的蒸发机理提供了理论依据。
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引用次数: 0
Tough epoxy resin systems for cryogenic applications 用于低温应用的坚韧环氧树脂系统
IF 1.8 3区 工程技术 Q3 PHYSICS, APPLIED Pub Date : 2024-08-21 DOI: 10.1016/j.cryogenics.2024.103923
Pascal B. Studer, Alain Schwegler, Theo A. Tervoort

This work presents the development of new epoxy systems that combine high fracture toughness at cryogenic temperatures (

) with a slow curing reaction (long pot life) and a glass transition temperature between
and
, ensuring good mechanical performance at room temperature. This was achieved by incorporating varying amounts and types of short-chain alkylamines into epoxy networks based on bisphenol A diglycidyl ether (DGEBA) crosslinked with metaphenylene diamine (MPD). This modification enhanced the cryogenic fracture toughness of the base system, DGEBA crosslinked with MPD, from 2 to
. It has been suggested that the significantly improved cryogenic fracture toughness in systems with flexible aliphatic chain extenders might result from nano- or micro-phase separation, but X-ray scattering and dynamic mechanical spectroscopy did not provide conclusive evidence for this hypothesis.

The required slow curing reaction was achieved by using a sterically hindered alkylamine (2-heptylamine) as chain extender, which increased the pot life more than twofold, resulting in resin formulations that combine a high cryogenic fracture toughness, a low viscosity and a long processing window at room temperature.

这项工作介绍了新型环氧系统的开发情况,该系统兼具低温下的高断裂韧性()、缓慢的固化反应(较长的固化寿命)以及介于和之间的玻璃化转变温度,可确保在室温下具有良好的机械性能。通过将不同数量和类型的短链烷基胺掺入以双酚 A 二缩水甘油醚(DGEBA)为基础、与偏苯二胺(MPD)交联的环氧网络中,实现了这一目标。 这种改性将基础体系(DGEBA 与 MPD 交联)的低温断裂韧性从 2 提高到了...。有人认为,在具有柔性脂肪族链延伸剂的体系中,低温断裂韧性的显著提高可能是由于纳米或微相位分离造成的,但 X 射线散射和动态机械光谱并没有为这一假设提供确凿的证据。通过使用立体受阻的烷基胺(2-庚胺)作为扩链剂,实现了所需的缓慢固化反应,从而将罐装寿命延长了两倍多,使树脂配方兼具高低温断裂韧性、低粘度和室温下长加工窗口的特点。
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引用次数: 0
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Cryogenics
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