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First Abu Dhabi 2D/3D Seismic Merge. Fast Track Approach For Seismic Data Integration at Regional Scale in Exploration Studies 首次阿布扎比2D/3D地震合并。勘探研究中区域尺度地震数据集成的快速通道方法
Pub Date : 2018-11-12 DOI: 10.2118/193066-MS
Humberto Parra, M. Caeiro, F. Neves, J. Gomes
One of the main challenges in the execution of regional studies is the integration of large amounts of data coming from different sources and different disciplines. Even within the geophysical domain, integration of thousands of 2D seismic lines and dozens of 3D seismic volumes is a very demanding task. The aim of this paper is to provide a description on the use of fast track methodologies for the integration of 3D and 2D seismic data at country level for regional studies. This approach relies on a pragmatic way of merging seismic, processing data as point sets instead of traces, providing the flexibility of handling seismic information inside the geomodelling and geostatistical domain, where a grid of points can be resampled, reoriented, and ultimately merged into any desired geometry and resolution. The technical challenges include different spatial sampling, grid orientations, frequency contents and event timings. A preconditioning step has been included in the workflow in order to homogenize the data into a common ground, addressing compatibility issues of the different vintages through amplitude scaling, noise reduction and frequency balancing. Merging in a practical approach different 2D/3D seismic data sets into a single volume reduces drastically the amount of time spent in the data analysis and interpretation of geological features at regional scale. In this case of study, the workflow enables a feasible path for merging all seismic data acquired in Abu Dhabi over the past seven decades. The integrated volume helps geophysicists and geologists to carry out better seismic interpretations and perform proper structural analysis and prospect assessments. Finally, the seismic data has been integrated into a unique survey by interpolating the 2D and 3D seismic data to fill the gaps and generating a pseudo 3D survey at country scale. This regional scale single 3D seismic data allows better understanding of the geological and structural trends present in Abu Dhabi. This innovative approach offers a major advantage for regional data integration, expediting subsequent stages of seismic interpretation and description of the geological features at large scale for exploration assessments, prospect generation and 3D reservoir characterization.
执行区域研究的主要挑战之一是整合来自不同来源和不同学科的大量数据。即使在地球物理领域,整合数千条二维地震线和数十个三维地震体也是一项非常艰巨的任务。本文的目的是描述在国家一级用于区域研究的3D和2D地震数据集成的快速通道方法的使用。这种方法依赖于一种实用的地震合并方法,将数据作为点集而不是轨迹处理,在地质建模和地质统计领域内提供处理地震信息的灵活性,其中点网格可以重新采样,重新定向,并最终合并为任何所需的几何形状和分辨率。技术挑战包括不同的空间采样、网格方向、频率内容和事件定时。工作流中包含了预处理步骤,以便将数据均匀化为一个共同点,通过幅度缩放、降噪和频率平衡来解决不同年份的兼容性问题。通过一种实用的方法,将不同的2D/3D地震数据集合并到一个单独的体量中,大大减少了在区域尺度上进行数据分析和解释地质特征所花费的时间。在本案例中,该工作流程为合并过去70年在阿布扎比获得的所有地震数据提供了可行的途径。整合的体积有助于地球物理学家和地质学家进行更好的地震解释,并进行适当的结构分析和前景评估。最后,通过插值二维和三维地震数据,将地震数据整合到一个独特的调查中,以填补空白,并在国家尺度上生成伪三维调查。这种区域尺度的单一三维地震数据可以更好地了解阿布扎比的地质和构造趋势。这种创新的方法为区域数据整合提供了主要优势,加快了后续阶段的地震解释和大规模地质特征描述,用于勘探评估、远景生成和三维储层表征。
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引用次数: 1
Corrosion Management, Field Trial Results of High Pressure Black Bimodal PE100 HDPE Liner in a Super Gigantic Field Provides Innovative Strategy for High Pressure Water Injection Flow Line Internal Corrosion Management 腐蚀管理,超大型油田高压黑色双峰PE100 HDPE尾管现场试验结果为高压注水管线内部腐蚀管理提供了创新策略
Pub Date : 2018-11-12 DOI: 10.2118/192894-MS
Abby Kalio Amabipi, M. Salem, S. P. Grandhe, Tijender Kumar Gupta, M. Awah, J. Schell, T. Compton, N. Herbig
Internal corrosion in high pressure water injection flow lines is a very serious problem in the ADNOC super gigantic onshore fields. This issue has resulted in frequent pipe leaks and water injection flow lines outage which adversely affected oil and gas production due to failure in meeting the required water injection. This paper illustrates successful cost efficient innovative application strategy of the HDPE Liner technology in mitigating internal corrosion problems in water injection flow lines. Innovation centers of some petrochemical companies have now made available "BIMODAL PE100 POLYETHYLENE" materials which are suited for high pressure pipes and able to provide extra flexibility and safety in case of surface scratches in highly deviated flow lines. This paper presents the detailed preparation of the HDPE material, installation, intensive monitoring program, results and integrity challenges of the technology validation in 3km pipeline. A rolling machine reduced the OD of HDPE liner by 7% before drawing into the flow line by a pulling machine, the HDPE OD expands back to full size to give a tight fit in the flow line after sometime. The field trial was initiated in June of 2011 and actual installation completed in two weeks. The Liner conditions were monitored from 2011 through 2017. The flow line section protected with HDPE liner still operates in excellent conditions without any sign of corrosion up till date. This is a technology break through that eliminated internal corrosion threats with huge Opex savings in chemical treatment programs as no chemicals were applied. This Technology is now at the implementation stage in the ADNOC super gigantic onshore field. The paper elaborate on the value added to the company and possible areas of application of the technology for maximum benefits. Finally, this technology has clear impact on the internal corrosion management process that guarantees proper flow line long-life innovative design strategy and provides alternative solutions to conventional flow line designs.
在ADNOC超大型陆上油田中,高压注水管线内部腐蚀是一个非常严重的问题。该问题导致油管频繁泄漏和注水管线中断,由于无法满足注水量要求,对油气生产产生不利影响。本文阐述了HDPE尾管技术在缓解注水管线内部腐蚀问题方面的成功、经济、创新的应用策略。一些石化公司的创新中心现在已经提供了“BIMODAL PE100聚乙烯”材料,这种材料适用于高压管道,并且能够在大斜度流管道的表面划伤情况下提供额外的灵活性和安全性。本文详细介绍了HDPE材料的制备、安装、密集监测方案、3km管道技术验证的结果和完整性挑战。在通过拉拔机将HDPE尾管拉入流水线之前,滚压机将HDPE尾管的外径减小了7%,一段时间后,HDPE尾管的外径会膨胀回最大尺寸,与流水线紧密贴合。现场试验于2011年6月开始,实际安装在两周内完成。从2011年到2017年,对班轮状况进行了监测。采用HDPE尾管保护的管线段至今仍在良好的条件下运行,没有任何腐蚀迹象。这是一项技术突破,消除了内部腐蚀威胁,同时在化学处理方案中节省了大量运营成本,因为无需使用化学物质。该技术目前正处于ADNOC超大型陆上油田的实施阶段。论文详细阐述了该技术为公司带来的附加值和可能的应用领域,以获得最大的效益。最后,该技术对内部腐蚀管理过程有明显的影响,保证了适当的流线长寿命创新设计策略,并为传统的流线设计提供了替代方案。
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引用次数: 0
Permanent Electric Power Supply for Down Hole Devices in Oil and Gas Wells 油气井井下装置用永久电源
Pub Date : 2018-11-12 DOI: 10.2118/193037-MS
Eng Ammar, Mohamed Nabil, M.Hegazy, Gehad
All present time, most of downhole electrical devices operate either retrievable "rechargeable batteries" or permanent electric or fiber cable extend from surface till the bottom associated with high risk and high cost operations. Commonly both retrievable and permanent devices have advantage such as live data and easy communication. However, the disadvantages are temperature limitation, high cost, high risk, and restrictions moreover not suit many other completion scenarios and wells completion types. Most of memory gauges could read with 5 sec rate up to 43 days in temperature range 150 C, and it will reduce to 18 days when temperature increase up to 200 C. even increasing the time by reducing number of decimals for the recorded values. However, memory gauge stop working when kept for sleeping mode more that 15 sec. This research propose a new strategy, road map and conceptual design with different scenarios that aim to overcome the previous disadvantage through generating electrical power through a special downhole turbine utilizing new concept through wells injection and/or production flow rates. The new recommended turbine either to be installed as a part of the completion as permanent or to be run as retrievable. Moreover, turbine has the ability to generate mandatory power to operate downhole devices fitting any sensors. (eg. memory gauge) The new self power turbine create a new strategy for gas, oil and water wells completion to be more advanced with no need for the rig to change the completion, tubing and/or install cables. Theoretically the research succeeded by mean of installing a turbine to generate constant D/C current that could power up any attached memory gauge. This turbine depend on it is design on two main concepts; the first is how to direct the flow toward the blades and the second is how to maximize the vortex effect to maximize velocity and control turbulence, take in consideration hole accessibility for any operation required.
目前,大多数井下电气设备要么使用可回收的“可充电电池”,要么使用从地面一直延伸到底部的永久性电缆或光纤电缆,这伴随着高风险和高成本的操作。通常,可回收和永久设备都具有实时数据和易于通信等优点。然而,缺点是温度限制、成本高、风险大,而且不适合许多其他完井场景和完井类型。大多数记忆仪表可以在温度范围150℃下以5秒的速度读取长达43天,当温度升高到200℃时,它将减少到18天,甚至通过减少记录值的小数数量来增加时间。然而,当睡眠模式保持超过15秒时,记忆计就会停止工作。本研究提出了一种新的策略、路线图和概念设计,旨在通过利用井注入和/或生产流量的新概念,通过特殊的井下涡轮发电,来克服以前的缺点。新推荐的涡轮机要么作为永久完成的一部分安装,要么作为可回收的运行。此外,涡轮能够产生强制动力,以运行安装任何传感器的井下设备。(如。新型自动力涡轮机为天然气、石油和水井的完井创造了一种新的策略,无需钻机更换完井、油管和/或安装电缆。理论上,这项研究通过安装一个涡轮机来产生恒定的D/C电流,从而为任何附加的记忆仪表供电,从而取得了成功。这台涡轮机取决于它的设计两个主要概念;首先是如何引导气流流向叶片,其次是如何最大化旋涡效应以最大化速度和控制湍流,同时考虑到任何操作所需的孔可达性。
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引用次数: 1
Eye in the Sky: How the Rise of Drones will Transfrom the Oil & Gas Industry 空中之眼:无人机的兴起将如何改变石油和天然气行业
Pub Date : 2018-11-12 DOI: 10.2118/193211-MS
Noorafkan Amir, Mohamed Saeed Al Marar
Commercial use of drones – inspection drones to be specific – in Oil & Gas sector has been on the rise since around 2010. Leading Multinationals and some North American companies managing petroleum assets are among the first to tailor their inspection procedures incorporating the use of inspection drones. This inevitable switch is based on a rationale – safety of inspection personnel including ease of access to hazardous locations. Other factors that incentivize the use of inspection drones include time savings, lower costs, early warnings, improved data collection and sometimes the only viable option to get first hand information about an emergency event. Petroleum industry assets are high-value-long-life assets which are built to process / handle hazardous fluids. Operation & maintenance of these assets is a carefully regulated activity under the dictates of regulatory guidance, codes & standards. These compliance obligations burden the operators of these assets to optimize operations based on reliability centered maintenance philosophy. Consequently, inspection drones have in a very short span of time (5 – 10 years), have succeeded in proving their utility to support the operators and asset managers in meeting responsibilities related to the following: A-1. Operational ResponsibilityA-2. Corporate & Social Responsibility (CSR)A-3. Environmental ResponsibilityA-4. Security Responsibility This paper is an effort to collect and present data signifying the utility of inspection drones for asset management as well as optimized operations – onshore operations related to exploration and production as well as oil transportation.
自2010年左右以来,无人机在石油和天然气领域的商业用途(具体来说是无人机)一直在上升。领先的跨国公司和一些管理石油资产的北美公司是首批使用无人机定制检查程序的公司之一。这种不可避免的切换是基于一个基本原理-检查人员的安全,包括容易进入危险地点。激励使用检查无人机的其他因素包括节省时间、降低成本、早期预警、改进数据收集,有时是获得紧急事件第一手信息的唯一可行选择。石油工业资产是高价值的长寿命资产,用于处理/处理危险流体。这些资产的运营和维护是在监管指导、规范和标准的指导下进行的一项精心监管的活动。这些合规性义务使这些资产的运营商不得不基于以可靠性为中心的维护理念来优化操作。因此,在很短的时间内(5 - 10年),检查无人机已经成功地证明了它们在支持运营商和资产管理公司履行以下相关职责方面的效用:操作ResponsibilityA-2。企业与社会责任(CSR)环境ResponsibilityA-4。本文旨在收集和展示无人机在资产管理和优化作业方面的应用数据,包括与勘探、生产和石油运输相关的陆上作业。
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引用次数: 6
Protecting Offshore Pipelines from External Interference: Dropped and Dragged Anchors. 保护海上管道免受外部干扰:拖曳锚。
Pub Date : 2018-11-12 DOI: 10.2118/193158-MS
R. Bruschi, L. Bartolini
In congested districts of offshore Oil & Gas Industry, merchant ship traffic, offshore operations or fishing activity may interfere with pipelines in service, which rest exposed on the seabed. Despite the shortcomings of existing technology and knowledge, operators' concerns still emerge after yearly surveys that show new pipe damages from external mechanical interference, not to mention a few ruptures occurred in the last decade due to anchor hooking! Therefore, a question arises: do we know enough about the potential threats to offshore pipelines from external, particularly anchor, interference? The scope of this paper is to outline the rationale of pipeline protection works, both at design stage and in service, with focus on open issues influencing decisions on how and due time to intervene across busy offshore districts. In shallow waters and brown fields, e.g. in the Arabian Gulf and Gulf of Mexico, the consequences, not only economic but also safety wise, of a severe interference, might be relevant. The shallower the water depth and busier the area, the more stringent the safety targets. Sometimes, even having met acceptance criteria, backed by competent engineering modelling and use of state-of-the-art tools, field evidences from early operation may lead to rethink of purpose protection works, to be implemented with minimum impact on field operations. Marine pipeline damage prevention and awareness, from both vessel and field operators, is often a unique way to limit risks and unplanned interruptions.
在海上油气行业拥挤的地区,商船交通、海上作业或捕鱼活动可能会干扰在役管道,这些管道暴露在海底。尽管现有技术和知识存在缺陷,但每年的调查显示,外部机械干扰导致新的管道损坏,更不用说在过去十年中由于锚钩而发生的一些破裂,运营商仍然感到担忧!因此,一个问题出现了:我们是否足够了解外部,特别是锚点干扰对海上管道的潜在威胁?本文的范围是概述管道保护工程的基本原理,包括设计阶段和服务阶段,重点是影响繁忙的海上地区如何和适当时间干预决策的开放性问题。在浅水和棕地,例如在阿拉伯湾和墨西哥湾,严重干扰的后果,不仅是经济上的,而且是安全上的,可能是相关的。水深越浅,区域越繁忙,安全指标越严格。有时,即使达到了验收标准,在有能力的工程建模和使用最先进工具的支持下,早期作业的现场证据也可能导致重新考虑目的保护工程,以便在对现场作业影响最小的情况下实施。船舶和现场作业人员对海上管道损坏的预防和意识通常是限制风险和意外中断的独特方法。
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引用次数: 2
Innovative Geophysical Hazard Survey for Jack-Up Rig Approach and Operating in Hazardous Area of Shallow Seabed Due to Gas Pockets or Entrapped Gas and Tower Integrity Update and Conclusion. A Case Study 自升式钻井平台在浅海底气穴或困气危险区域接近和作业的创新地球物理危害调查及塔架完整性更新与结论。案例研究
Pub Date : 2018-11-12 DOI: 10.2118/193091-MS
Y. Goraya, Rajeev Nair, A. Al-Neaimi, A. Alfelasi, Franciscus Johannes Kleef, Bader Al-Dhafari, M. El-Sayed, Fazeel Akram, I. Al-Hosani
During a routine tower maintenance visit, gas bubbles were observed at sea bed. The challenge now was to identify the source of the gas leak and identify areas where gas had accumulated. The observed gas seep, escaped from the seabed to the water column and was in the vicinity of the TWR-2 platform as confirmed during a diving survey. A geophysical survey was initiated to understand if gas had accumulated in the subsurface and whether it was safe to approach the site with a rig to kill the well.
在例行的塔维护访问中,在海底观察到气泡。现在的挑战是确定气体泄漏的来源和确定气体积聚的区域。观测到的气体从海底渗漏到水柱,并在TWR-2平台附近,这在潜水调查中得到了证实。一项地球物理调查开始了,以了解天然气是否在地下积聚,以及用钻机接近现场压井是否安全。
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引用次数: 0
Piping Motion Solutions-Ball Joint Technology 管道运动解决方案-球接头技术
Pub Date : 2018-11-12 DOI: 10.2118/192676-MS
Arlene Chase
Inform and educate oil and gas pipe engineers of the safe and reliable solutions to pipe motion at high pressures. Expansion joints for Axial and Offset technology pipe systems. Ball joint designs in the offset and scissor installations for Offshore, Onshore, Production, Development and Distribution pipe systems. Axial and Offset Pipe system technology and what are the advantages? How are expansion joints installed? What is a ball joint and how do they work? How to model expansion joints in a pipe stress program? Ball joints are not new. Barco Ball joints have been around since 1908. The designs were developed to ensure steam could reach the front of a train from the boiler in the back across each car connection. The Steam piping made the passenger cars warm and comfortable. Today, Ball Joints provide a method of absorbing pipe movement for applications ranging to high pressures, steam and hot water pipe expansion, tank and building settlement, seismic isolation, wave motion compensation on oil platforms, barges, FPSO and drilling ships, solar panel movement, oil well riser expansion and safety relief valve escape piping.
告知和教育石油和天然气管道工程师在高压下管道运动的安全可靠的解决方案。轴向和偏置技术管道系统的膨胀接头。用于海上、陆上、生产、开发和分配管道系统的偏置式和剪式安装中的球接头设计。轴向和偏置管道系统技术有哪些优势?伸缩缝如何安装?什么是球形接头,它们是如何工作的?如何在管道应力程序中模拟伸缩缝?球形接头并不新鲜。巴可球接头自1908年以来一直存在。这些设计是为了确保蒸汽可以从后面的锅炉通过每节车厢连接到达火车的前部。蒸汽管道使乘用车温暖舒适。如今,球接头为各种应用提供了一种吸收管道运动的方法,包括高压、蒸汽和热水管道膨胀、储罐和建筑沉降、地震隔离、石油平台、驳船、FPSO和钻井船的波浪运动补偿、太阳能电池板运动、油井隔水管膨胀和安全阀泄放管道。
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引用次数: 0
Technology Demonstration Journey in ADNOC R&D – A Case Study ADNOC研发中的技术示范之旅-案例研究
Pub Date : 2018-11-12 DOI: 10.2118/192633-MS
Ibrahim Khan, Yasser Al Wahedi, Vaithilingam Balasubramanian, M. Tsapatsis, Frank Geuzobroek, Adel Saif Al Nasr, Khadija Al Daghar
This paper explains the process work flow steps starting from the proof of concept of a new research technology up to the field demonstration considering a live example. We discuss the stages that are employed in ADNOC R&TD technology management process in assessing proposals, supervising projects progress, steering projects towards technology maturity. The example under study pertains to a research project which was awarded to Khalifa University (KU). The project attempts at solving high SO2 emissions from old Sulfur Recovery Units (SRUs) in ADNOC Gas Processing. The subject project is research work involving development of a mixed metal oxide, highly selective regenerable adsorbent possessing high adsorption capacity of 6 to 8 mmol/g. We follow the progress of the new technology via the various steps of ADNOC R&D technology management process.
本文通过实例说明了从一项新研究技术的概念验证到现场演示的过程工作流程步骤。我们讨论了在ADNOC研发技术管理过程中评估提案、监督项目进度、引导项目走向技术成熟所采用的阶段。正在研究的例子与授予哈利法大学(KU)的研究项目有关。该项目试图解决ADNOC天然气处理中旧硫回收装置(sru)的高二氧化硫排放问题。本课题为研究开发一种具有6 ~ 8 mmol/g高吸附容量的混合金属氧化物高选择性可再生吸附剂。我们通过ADNOC研发技术管理流程的各个步骤跟踪新技术的进展。
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引用次数: 0
Low Cost CO2 Capture: Dream or Reality? 低成本二氧化碳捕获:梦想还是现实?
Pub Date : 2018-11-12 DOI: 10.2118/192726-MS
A. S. E. Nasr, F. Geuzebroek, Prachi Singh
Carbon capture and Storage is one of the major pathways to reduce carbon dioxide emission. Over the years, the success of this technology has been relatively limited. Reasons for this include lack of acceptance of storage, but also a lack of economic feasibility. In many cases, projects need to be funded through subsidies or are justified on the basis of use for enhanced oil recovery. Meanwhile an enormous effort has been placed into lowering the cost of capture. Many R&D programs have set the target to reduce cost from typically 50 $/ton to 25 $/ton, while even now this kind of reductions have not been realized, to the contrary there has been an increase in reported cost. This paper addresses the background of the situation. It gives a literature overview of different technologies and the associated cost. A cost analysis is made of the different components in a CO2 capture plant. Comparison is made for the different technologies for post, pre- and oxy-combustion. The reasons for the high cost is analyzed and it is shown that no silver bullets exist. Several smart technologies are currently in development and the latest insights are given in how these technologies can reduce cost. A few studies are given that show why these technologies could not fulfill the initial expectations. The results show that there is a tendency that advantages of technology solutions are often off-set by disadvantages that are not foreseen at the early Research stages, often because the new systems are more complicated than the state-of-the-art. This includes engineering cost for mitigate these dis advantages. An example is the use of smart solvents with phase change involved. This process may lead to lower OPEX due to lower energy consumption, but cost is increased by the higher cost for doing the separation or for keeping the solvents from leaving the solvent.
碳捕获与封存是减少二氧化碳排放的主要途径之一。多年来,这项技术的成功一直相对有限。造成这种情况的原因包括缺乏对储存的接受,但也缺乏经济可行性。在许多情况下,项目需要通过补贴来提供资金,或者根据提高石油采收率的使用来证明其合理性。与此同时,为了降低捕获成本,人们付出了巨大的努力。许多研发项目已经设定了将成本从通常的50美元/吨降低到25美元/吨的目标,而即使是现在,这种降低也没有实现,相反,报告的成本有所增加。本文阐述了这一情况的背景。它给出了不同技术和相关成本的文献综述。对二氧化碳捕集厂的不同组成部分进行了成本分析。对后燃烧、前燃烧和全氧燃烧的不同技术进行了比较。分析了成本高的原因,指出没有解决问题的灵丹妙药。一些智能技术目前正在开发中,并给出了这些技术如何降低成本的最新见解。一些研究表明,为什么这些技术不能满足最初的期望。结果表明,有一种趋势,即技术解决方案的优势往往被早期研究阶段无法预见的劣势所抵消,这通常是因为新系统比最先进的系统更复杂。这包括减轻这些缺点的工程成本。一个例子是使用涉及相变的智能溶剂。由于能耗较低,该工艺可能会降低运营成本,但由于分离或防止溶剂离开溶剂的成本较高,成本也随之增加。
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引用次数: 0
Feasibility Study of Carbon Dioxide Methanation: Assessment of Various Supported Nickel Catalyst 二氧化碳甲烷化的可行性研究:不同负载镍催化剂的评价
Pub Date : 2018-11-12 DOI: 10.2118/193294-MS
N. Berahim, A. Seman, M. G. M. Noh
Carbon dioxide (CO2) management is vital for ensuring the economic and environment viability for monetization of high CO2 gas field. Apart from the great technical challenge in separating high concentration of CO2 in gas field economically, the management of separated CO2 is a fine balance between the sink-in value by sequestration and creation of value via conversion to product, constrained by the thermodynamic challenge in breaking the stable CO2 molecule. Conversion to methane is one the exploratory idea due to ease of integration to current product line-up of PETRONAS. Catalytic conversion of CO2 to methane are reported here over various supported nickel base catalyst, namely ZrO2, La2O3, and Al2O3 at temperature ranging from 300 to 400°C under atmospheric pressure. The catalysts with fixed Ni loadings were prepared by wet impregnation technique, characterized and their performances were evaluated in a parallel reactor under Sabatier-based CO2 conversion. Reaction temperature and GHSV were taken into account as two important parameters with fixed H2/CO2 molar ratio. Experimental results indicate that among all catalysts, Ni/Al2O3 give the highest CO2 conversion of 74% and high CH4 selectivity of 99% at temperature of 380°C and GHSV 10000 h-1. This asserted Ni supported on Al2O3 as a potential catalyst for CO2 conversion and promising methanation performance over a low cost catalyst.
二氧化碳(CO2)管理对于确保高二氧化碳气田货币化的经济和环境可行性至关重要。除了从经济上分离气田高浓度二氧化碳的巨大技术挑战外,分离后的二氧化碳的管理是在封存的吸收价值和转化为产品的价值创造之间的微妙平衡,受到破坏稳定的二氧化碳分子的热力学挑战的约束。转化为甲烷是一个探索性的想法,因为易于整合到马来西亚国家石油公司目前的产品线。本文报道了不同负载型镍基催化剂(ZrO2、La2O3和Al2O3)在300 ~ 400℃的常压下催化CO2转化为甲烷。采用湿浸渍法制备了固定负载Ni的催化剂,并在Sabatier-based CO2转化的平行反应器中对其进行了表征和性能评价。反应温度和GHSV是固定H2/CO2摩尔比的两个重要参数。实验结果表明,在380℃、10000 h-1 GHSV条件下,Ni/Al2O3催化剂的CO2转化率最高,达到74%,CH4选择性最高,达到99%。这表明,与低成本的催化剂相比,氧化铝负载的Ni是一种潜在的二氧化碳转化催化剂,具有良好的甲烷化性能。
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引用次数: 1
期刊
Day 1 Mon, November 12, 2018
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