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Infrared spectroscopy of quantum materials 量子材料的红外光谱学
IF 2.4 4区 物理与天体物理 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-06-24 DOI: 10.1016/j.cap.2024.06.013
Soonjae Moon , Jungseek Hwang

Infrared spectroscopy is a powerful and versatile experimental technique for studying the electronic response of condensed matter. Infrared spectroscopy measurements in a broad energy region provide invaluable insights on the electronic excitations and collective modes in condensed matter and thus play pivotal roles in establishing current understandings of various classes of condensed matter. Here we discuss the usefulness and importance of infrared spectroscopy to study the physics of quantum materials, which were formerly known as strongly correlated materials. We will describe the basic principles and experimental methods of infrared spectroscopy and discuss how infrared spectroscopy can be utilized to extract quantitative information on the charge dynamics and electronic band structures of quantum materials.

红外光谱学是研究凝聚态物质电子响应的一种功能强大、用途广泛的实验技术。在广阔的能量区域进行的红外光谱测量为研究凝聚态物质中的电子激发和集体模式提供了宝贵的见解,因此在建立当前对各类凝聚态物质的理解方面发挥着举足轻重的作用。在此,我们将讨论红外光谱在研究量子材料物理方面的实用性和重要性,量子材料以前被称为强相关材料。我们将介绍红外光谱学的基本原理和实验方法,并讨论如何利用红外光谱学提取量子材料的电荷动力学和电子能带结构的定量信息。
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引用次数: 0
Strain-insensitive ferromagnetic SrRuO3 thin films with ferrimagnetic CoFe2O4 buffer layer 带有铁磁性 CoFe2O4 缓冲层的应变不敏感铁磁性 SrRuO3 薄膜
IF 2.4 4区 物理与天体物理 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-06-21 DOI: 10.1016/j.cap.2024.06.012
Jung Ehy Hong , Yeong Uk Choi , Hyun Soo Ahn , Bhubnesh Lama , Jong Hun Kim , Tula R. Paudel , Jung-Woo Lee , Jong Hoon Jung

Flexible electronics, such as wearable devices and biosensors, require materials that maintain their properties under mechanical stress. A recent study addresses this by focusing on SrRuO3 (SRO) thin films, which typically suffer reduced coercivity under strain. Herein, we introduce a novel approach by using CoFe2O4 (CFO) as a buffer layer in SRO/CFO/F-mica heterostructures to address this issue. When subjected to a strain of up to ±0.553 %, these heterostructures displayed a mere 11 % variation in saturation magnetic moment and coercive field, significantly outperforming SRO/BaTiO3 configurations, which showed a 95 % reduction in coercivity at only −0.3 % strain. This result demonstrates the effectiveness of the CFO layer in stabilizing the magnetic properties of SRO films against external mechanical deformations. These findings mark a significant advancement in the development of mechanically robust thin films for complex oxide heterostructures in flexible device applications.

柔性电子器件(如可穿戴设备和生物传感器)需要能在机械应力下保持其特性的材料。最近的一项研究通过关注SrRuO3(SRO)薄膜解决了这一问题,这种薄膜在应变下通常会降低矫顽力。在这里,我们介绍了一种新方法,即在 SRO/CFO/F 云母异质结构中使用 CoFe2O4(CFO)作为缓冲层来解决这一问题。当受到高达 ±0.553 % 的应变时,这些异质结构的饱和磁矩和矫顽力场仅有 11 % 的变化,明显优于 SRO/BaTiO3 配置,后者仅在应变为 -0.3 % 时矫顽力就降低了 95 %。这一结果表明了 CFO 层在稳定 SRO 薄膜的磁性能以抵御外部机械变形方面的有效性。这些发现标志着在柔性器件应用中开发具有机械稳定性的复杂氧化物异质结构薄膜方面取得了重大进展。
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引用次数: 0
Infrared spectroscopic study on Nb-ion-irradiated MgB2 thin films 铌离子辐照 MgB2 薄膜的红外光谱研究
IF 2.4 4区 物理与天体物理 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-06-20 DOI: 10.1016/j.cap.2024.06.011
Dzung T. Tran , Tien Le , Hong Gu Lee , Tuson Park , Nguyen The Nghia , Bui Thi Hoa , Duc H. Tran , Won Nam Kang , Jungseek Hwang

Magnesium diboride (MgB2) is a two-band superconductor with a high superconducting critical temperature (Tc) of approximately 39 K. Owing to the lack of vortex pinning centers, MgB2 exhibits an abrupt decline in the critical current density (Jc) in an applied magnetic field. Here, we prepared 1 MeV Nb ion-irradiated MgB2 thin-film samples with doses of 3×1013, 7×1013, and 9×1013 ions/cm2. Temperature-dependent magnetization and x-ray diffraction (XRD) measurements were performed to determine the Tc and c-axis lattice constant of each sample. Furthermore, a Fourier transform infrared (FTIR) spectroscopy was performed to obtain the infrared properties of the Nb-ion-irradiated MgB2 thin-film samples. The optical conductivity of each sample in the low-energy region was fitted with two (narrow and broad) Drude modes. We found that the spectral weight redistribution from the low-to high-frequency regions and the broadening of the narrow Drude mode caused by irradiation are closely related to the reduction in Tc.

二硼化镁(MgB2)是一种双带超导体,超导临界温度(Tc)高达约 39 K。由于缺乏涡旋钉中心,MgB2 在外加磁场中的临界电流密度(Jc)会突然下降。在这里,我们制备了 1 MeV Nb 离子辐照 MgB2 薄膜样品,离子剂量分别为 3×1013、7×1013 和 9×1013。通过随温度变化的磁化和 X 射线衍射 (XRD) 测量,确定了每个样品的 Tc 和 c 轴晶格常数。此外,还进行了傅立叶变换红外(FTIR)光谱分析,以获得铌离子辐照 MgB2 薄膜样品的红外特性。用两种(窄和宽)德鲁德模式拟合了每个样品在低能区的光导率。我们发现,辐照造成的光谱重量从低频区到高频区的重新分布和窄德鲁德模式的拓宽与 Tc 的降低密切相关。
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引用次数: 0
Interfacial thermal resistance effect in self-aligned top-gate a-IGZO thin film transistors 自对齐顶栅 a-IGZO 薄膜晶体管中的界面热阻效应
IF 2.4 4区 物理与天体物理 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-06-16 DOI: 10.1016/j.cap.2024.06.008
Junhong Na

This study investigates the interfacial thermal resistance effect, primarily associated with the bottom-gate stack, in self-aligned top-gate amorphous indium gallium zinc oxide (a-IGZO) thin-film transistors (TFTs). We analyze self-heating and heat transfer characteristics across three different a-IGZO TFT configurations: single-gate, dual-gate type 1, and dual-gate type 2. Temperature maps, corresponding to various bias conditions, are acquired using infrared thermal microscopy. The extracted values of thermal resistance reveal a significant disparity between single- and dual-gate configurations. This suggests that the bottom-gate stack in a-IGZO TFTs, including the interfaces, notably impedes heat dissipation. These findings offer crucial insights into the power dissipation aspects of TFT technology, highlighting the importance of interfacial design for thermal management in advanced electronic devices.

本研究调查了自对齐顶栅非晶铟镓锌氧化物(a-IGZO)薄膜晶体管(TFT)中主要与底栅堆叠相关的界面热阻效应。我们分析了三种不同的 a-IGZO TFT 配置(单栅极、双栅极 1 型和双栅极 2 型)的自热和传热特性。我们使用红外热显微镜获取了与各种偏置条件相对应的温度图。提取的热阻值显示,单栅极和双栅极配置之间存在显著差异。这表明,a-IGZO TFT 的底部栅极堆栈(包括界面)明显阻碍了散热。这些发现为 TFT 技术的功率耗散方面提供了重要见解,凸显了界面设计对先进电子设备热管理的重要性。
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引用次数: 0
Piezoelectricity in 2D nanomaterials-crystal structure and polarization direction 二维纳米材料的压电性--晶体结构和极化方向
IF 2.4 4区 物理与天体物理 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-06-14 DOI: 10.1016/j.cap.2024.06.009
Adila Rani , Sang Don Bu

Materials that produce electric charges in response to a mechanical load are known as piezoelectric materials. Materials with a lattice structure devoid of centosymmetry exhibit piezoelectric activity. These days, non-centrosymmetric 2D nanomaterials have been used in many possible applications and have attracted a lot of attention as piezoelectric materials. The crystal structure, crystal nonsymmetry, and nonzero electronic bandgap energy values of two-dimensional nanomaterials have a significant influence on their piezoelectric capabilities. For example, it was discovered that the symmetry of certain mono- or few-layered 2D nanomaterials differed from that of their bulk counterparts. Piezoelectricity is found at the atomic thickness level in many 2D monolayer materials with structurally broken symmetry, but it gradually vanishes with increasing thickness. Secondly, there is a strong correlation between this piezoelectric action and the polarization direction. In this sense, improving the piezoelectric capabilities in 2D mono, few, and multilayer nanomaterials requires a deeper comprehension of the crystal structure and direction of polarization. Based on theoretical and experimental findings, the crystal structure and direction of polarization of various 2D nanomaterials will be the main topics of this review. We will also discuss recent developments and applications of various 2D nanomaterials.

在机械负载作用下产生电荷的材料被称为压电材料。具有非中心对称晶格结构的材料具有压电活性。如今,非中心对称二维纳米材料已被广泛应用,并作为压电材料引起了广泛关注。二维纳米材料的晶体结构、晶体非对称性和非零电子带隙能值对其压电能力有重要影响。例如,人们发现某些单层或少层二维纳米材料的对称性与其块体材料的对称性不同。在许多具有结构断裂对称性的二维单层材料中,压电性在原子厚度水平上被发现,但随着厚度的增加,压电性逐渐消失。其次,这种压电作用与极化方向有很强的相关性。从这个意义上讲,要提高二维单层、少层和多层纳米材料的压电能力,就必须深入理解晶体结构和极化方向。基于理论和实验研究结果,本综述将以各种二维纳米材料的晶体结构和极化方向为主题。我们还将讨论各种二维纳米材料的最新发展和应用。
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引用次数: 0
Optimization of metal-insulated-semiconductor field-effect-transistor for the formation of two-dimensional electron gas in dopant-free systems 在无掺杂剂系统中优化金属绝缘半导体场效应晶体管以形成二维电子气
IF 2.4 4区 物理与天体物理 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-06-13 DOI: 10.1016/j.cap.2024.06.007
Do-Hoon Kim , Hyeon-Sik Jang , Changki Hong , Minky Seo , Hoonkyung Lee , Sang-Jin Lee , Nojoon Myoung , Donghun Lee , Seok-Kyun Son , Young Tea Chun

We developed a geometry of metal-insulated-semiconductor field-effect-transistor for the formation of two-dimensional electron gas (2DEG) in dopant-free GaAs/AlGaAs heterostructures in which the conduction band can be modulated by external electric field. We showed two different kinds of device processes: for simple device fabrication and for the uniform 2DEG. We optimized the process of ohmic contacts and the gate geometry for the high quality 2DEG in a triangular quantum well formed at the GaAs/AlGaAs heterointerface. We use these two types of devices to perform a direct comparison of the magneto-transport properties at a low temperature (1.2 K) to get a relationship between the induced carrier density and external electric field. By using our developed fabrication process, the tunability of a high-quality 2DEG was obtained with a carrier density ranging from 0.8 to 2.3 × 1011 cm−2, for which the corresponding mobility ranged 1.5 to 3.3 × 106 cm2 V−1 s−1. Also, we demonstrated that the 2DEG is well established with a suitable depth, 120 nm below the surface (near the GaAs/AlGaAs heterointerface) which is calculated by the capacitance model.

我们开发了一种金属绝缘半导体场效应晶体管的几何结构,用于在无掺杂剂的砷化镓/砷化镓异质结构中形成二维电子气(2DEG),其中的导带可通过外部电场进行调制。我们展示了两种不同的器件工艺:简单器件制造工艺和均匀二维电子气制造工艺。我们优化了欧姆接触工艺和栅极几何形状,以便在砷化镓/砷化镓异质面形成的三角形量子阱中实现高质量的二维电子元件。我们利用这两种器件直接比较了低温(1.2 K)下的磁传输特性,从而得出了诱导载流子密度与外部电场之间的关系。通过使用我们开发的制造工艺,获得了载流子密度范围为 0.8 至 2.3 × 1011 cm-2 的高质量 2DEG 的可调谐性,其相应的迁移率范围为 1.5 至 3.3 × 106 cm2 V-1 s-1。此外,我们还证明,根据电容模型的计算,2DEG 在表面以下 120 nm 处(GaAs/AlGaAs 异质界面附近)具有合适的深度。
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引用次数: 0
Facile fabrication of microstructured superhydrophilic and superhydrophobic STS316L 轻松制造微结构超亲水和超疏水 STS316L
IF 2.4 4区 物理与天体物理 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-06-13 DOI: 10.1016/j.cap.2024.06.006
Je-Un Jeong, Jothi Prakash Chakrapani Gunarasan, Jeong-Won Lee

The enhancement of the wettability characteristics in stainless steel holds substantial significance for the application of inhibitor coatings. Investigating a s surface design along with assessing the influences of roughness, surface topography, and chemical heterogeneity on wettability has been a primary focus. In this context, the manipulation of stainless steel surface properties has gained significant attention, specifically for the purpose of fine-tuning wettability. Despite this, uncomplicated surface treatment techniques for stainless steels remain insufficiently established. This study presents a simple etching and oxidation approach for tuning the wettability of stainless steel (STS316L). Through etching and oxidation of STS316L, a superhydrophilic wetting state was achieved (contact angle ∼ 2°). Subsequent application of a monolayer coating led to the reversal of wettability from superhydrophilic to superhydrophobic (contact angle ∼ 168°). Additionally, the proposed methodology for STS316L surface treatment opens up broad expansion possibilities for the applications of superhydrophobic surfaces.

提高不锈钢的润湿性对抑制剂涂层的应用具有重要意义。研究表面设计以及评估粗糙度、表面形貌和化学异质性对润湿性的影响一直是研究的重点。在这种情况下,对不锈钢表面特性的处理,特别是为了微调润湿性而进行的处理,已经获得了极大的关注。尽管如此,简单的不锈钢表面处理技术仍然不够成熟。本研究介绍了一种调整不锈钢(STS316L)润湿性的简单蚀刻和氧化方法。通过对 STS316L 进行蚀刻和氧化,实现了超亲水润湿状态(接触角 ∼ 2°)。随后的单层涂层使润湿性从超亲水状态逆转为超疏水状态(接触角 ∼ 168°)。此外,所提出的 STS316L 表面处理方法为超疏水性表面的应用开辟了广阔的发展空间。
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引用次数: 0
Energy transfer of Er3+-Nd3+ co-doped in tellurite glass via energy level match 通过能级匹配实现碲玻璃中掺杂 Er3+-Nd3+ 的能量转移
IF 2.4 4区 物理与天体物理 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-06-11 DOI: 10.1016/j.cap.2024.06.005
Qun Wang, Changyuan Xu, Fengjiao Zhao, Hongming Yin

Er3+/Nd3+ co-doped tellurate glass was prepared by melt quenching method. The relationship between the energy levels of two rare earth ions was studied by absorption spectra and excitation spectra. At 379/407/488 nm excitation, visible light, near-infrared (NIR) emission spectra, and fluorescence attenuation curves were measured. The NIR emission spectrum and fluorescence lifetime show that Er3+ can transfer energy to Nd3+, thus enhancing the NIR emission of Nd3+ in tellurate glass. In the co-doped sample, under excitation of 379/407/488 nm, the NIR emission of Nd3+ has a concentration quenching point related to Er3+, and the optimal co-doped concentration is 1mol% ErF3. At 365/451 nm excitation, NIR emission was not enhanced and no energy transfer occurred. In contrast to the energy transfer between conventional Er3+-Nd3+ co-doped glasses, this paper investigates the effect of matching the higher Er3+ energy levels with adjacent Nd3+ levels on the energy transfer. The energy transfer process of Er3+-Nd3+ co-doped glasses is studied in the energy level diagram.

采用熔融淬火法制备了 Er3+/Nd3+ 共掺杂碲酸玻璃。通过吸收光谱和激发光谱研究了两种稀土离子能级之间的关系。在 379/407/488 nm 激发波长下,测量了可见光、近红外发射光谱和荧光衰减曲线。近红外发射光谱和荧光寿命表明,Er3+ 可以将能量转移给 Nd3+,从而增强碲化镉玻璃中 Nd3+ 的近红外发射。在共掺杂样品中,在 379/407/488 nm 的激发下,Nd3+ 的近红外发射有一个与 Er3+ 有关的浓度淬灭点,最佳共掺杂浓度为 1mol% ErF3。在 365/451 纳米激发下,近红外发射没有增强,也没有发生能量转移。与传统的 Er3+-Nd3+ 共掺玻璃之间的能量传递不同,本文研究了较高的 Er3+ 能级与相邻的 Nd3+ 能级相匹配对能量传递的影响。通过能级图研究了 Er3+-Nd3+ 共掺玻璃的能量传递过程。
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引用次数: 0
Back-focal plane scanning spectroscopy for investigating the optical dispersion of large-area two-dimensional photonic crystal fabricated by capillary force lithography 用于研究毛细力光刻法制造的大面积二维光子晶体光色散的背焦平面扫描光谱仪
IF 2.4 4区 物理与天体物理 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-06-08 DOI: 10.1016/j.cap.2024.06.001
Changwon Seo , Jae-Eon Shim , Chanseul Kim , Eunji Lee , Gwan Hyun Choi , Pil Jin Yoo , Gi-Ra Yi , Jeongyong Kim , Teun-Teun Kim

In this article, we introduce our custom-built back-focal plane (BFP) scanning spectroscopy to explore an angle-resolved optical dispersion in two-dimensional (2D) photonic crystal (PhC) constructed with hexagonal lattice of nano-scaled dielectric rods. We fabricated a uniformly large-area photonic crystal measuring 1 cm by 0.5 cm, featuring a polymer-based hexagonal lattice on a gold layer, using capillary force lithography. This precision enables the effective confinement of photonic modes, leading to enhanced optical interactions. We successfully map out the angle-resolved reflectance spectra by directly scanning BFP, revealing the structure's angle dependent optical response and providing insights into its iso-frequency contours. Our approach simplifies the exploration of advanced optical materials, highlighting the role of precise fabrication and measurement techniques in understanding and utilizing the optical properties of structured materials for various technological applications.

在这篇文章中,我们介绍了定制的后焦平面(BFP)扫描光谱仪,用于探索二维(2D)光子晶体(PhC)中的角度分辨光色散,该晶体由纳米级电介质棒的六边形晶格构成。我们利用毛细力光刻技术制作了一个 1 厘米 x 0.5 厘米的均匀大面积光子晶体,其特点是在金层上形成了基于聚合物的六边形晶格。这种精确度实现了光子模式的有效约束,从而增强了光学相互作用。通过直接扫描 BFP,我们成功绘制出了角度分辨反射光谱图,揭示了该结构与角度相关的光学响应,并深入了解了其等频轮廓。我们的方法简化了对先进光学材料的探索,凸显了精确制造和测量技术在理解和利用结构材料的光学特性实现各种技术应用方面的作用。
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引用次数: 0
Characteristics of inductively coupled plasma radio-frequency ion source of ion implanters for high number density dopant generation 离子注入机的电感耦合等离子射频离子源在生成高数目密度掺杂剂方面的特性
IF 2.4 4区 物理与天体物理 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-06-06 DOI: 10.1016/j.cap.2024.06.004
Jong Jin Hwang , Choong-Mo Ryu , Hyo Jun Sim , Ho-Jun Lee , Seung Jae Moon

In this study, we developed an inductively coupled plasma ion source that can be applied to implanters in semiconductor production. We employed an infrared camera and thermocouples to assess the temperature properties of the ion source operated at temperatures below 500 °C. This reduced temperature is expected to facilitate the adoption of various materials as the ion source. Ion densities of the direct current ion source measured using a double Langmuir probe were found to range from 1.66 × 1016 to 5.06 × 1016 m−3 within an input power range of 682–895 W. In contrast, the ion densities of a radio-frequency ion source ranged from 7.86 × 1016–9.58 × 1016 m−3 within an input power range of 700–900 W. This proposed ion source can serve as a next-generation solution because of its low operating temperature and high ion density.

在这项研究中,我们开发了一种电感耦合等离子体离子源,可用于半导体生产中的植入器。我们使用红外摄像机和热电偶来评估离子源在低于 500 °C 的温度下工作的温度特性。温度的降低将有助于采用各种材料作为离子源。在输入功率为 682-895 W 的范围内,使用双朗缪尔探针测量的直流电离子源的离子密度为 1.66 × 1016 至 5.06 × 1016 m-3。
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引用次数: 0
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Current Applied Physics
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