The growing energy demand in modern buildings, especially those with extensive glazing, underscores the need for energy-efficient solutions. This study explores the potential of magnetron-sputtered TiN mono and multilayer thin films to reduce air conditioning costs and promote sustainable building applications. Coatings were applied to glass substrates of varying thicknesses (4 mm, 6 mm, and 8 mm) and evaluated their optical, thermal, and environmental performance under the hot-dry climate of Vellore, TamilNadu, India. Surface characterization using AFM and FESEM revealed nano-hill structures with increased surface roughness in Ti/TiN multilayers, which enhanced light scattering. UV–VIS-NIR spectroscopy demonstrated that Ti/TiN films effectively blocked ultraviolet (UV) and near-infrared (NiR) radiation while maintaining high visible light transmittance. Spectroscopic ellipsometry highlighted substrate thickness-dependent variations in optical properties. The Ti/TiN film on a 6 mm glass substrate exhibited an optimal combination for low-E applications, balancing high infrared reflectance, visible light transmittance, and low UV penetration. Simulation studies using MATLAB and Design-Builder showed a 12.92% reduction in solar heat gain and improved indoor daylight distribution. Economic analysis indicated substantial reductions in air conditioning loads and electricity costs, with a payback period of 5–7 years. Environmental analysis quantified a significant reduction in carbon emissions, with Ti/TiN film on a 4 mm glass substrate capable of mitigating up to 290 kg CO2/m2 annually. These findings highlight TiN-based coatings as a scalable and cost-effective solution for enhancing energy efficiency, thermal comfort, and sustainability in modern buildings, particularly in regions with hot climatic conditions.
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