Hydration‐induced heating in cemented tailings backfill (CTB) can deteriorate the thermal environment of underground working areas. To support thermal management, the influence of placement volume on the spatiotemporal evolution of the CTB temperature field and its coupled multiphysics processes was investigated. An integrated micro–macro experimental program was conducted to analyze the spatiotemporal evolution of hydration parameters for CTB with different volumes, and to develop a temperature-field model incorporating volume effects. A coupled thermos-chemical-hydraulic-electrical (T-C-H-E) mechanism was then proposed. In-situ monitoring was undertaken to validate the model and assess environmental impact. The results indicate that volume effects significantly reshape the temperature field; both peak temperature and time-to-peak increase with volume. Specifically, the largest sample (CTB40) exhibited a peak temperature 6.9 ℃ higher than the smallest sample (CTB10). Peak temperature at different locations exhibits a power-law relationship with characteristic length (T = Tenv + aLcb), and the spatial profile is approximately Gaussian. Microstructural tests indicate greater formation of hydration products with increasing volume, with enrichment in the center and lower region. The hydration product content in the central region is 1.73 times that of the surrounding areas. Temperature is strongly and positively correlated with hydration product yield, confirming spatial non-uniformity driven by volume effects. The proposed T-C-H-E mechanism captures this spatiotemporal coupling. In-situ validation reports that the error of the temperature field calculation model was less than 10 %, and the backfill increases the ambient temperature by approximately 4–5 ℃. These findings provide practical guidance for controlling backfill heat release and improving the mine thermal environment.
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