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Fire Hazard Assessment of New Automotive Battery Materials Using SDS Information 基于SDS信息的新型汽车电池材料火灾危险性评估
Pub Date : 2019-01-01 DOI: 10.3210/fst.38.1
J. Kida, T. Akitsu
This study uses a safety data sheet (SDS), which describes the characteristics and hazards associated with a chemical substance, to determine the hazards associated with battery materials. Furthermore, we investigated whether fires in electric vehicles caused by vehicle-mounted batteries can be predicted using SDSs alone. In addition, we aimed to overcome the limitations associated with fire prediction in electric vehicles using an SDS-based artificial intelligence (AI) method. We found that fires caused by battery material could be accurately predicted using SDSs; however, fires caused by thermal runaway or fires of unknown or artificial origins could not be predicted by SDSs alone. Results demonstrate that when AI is utilized for predicting and extinguishing fires in electric vehicles, it is important to consider the hazards associated with the battery material and also to analyze fires that have occurred in the past along with effective fire extinguishing methods. Although there are limitations at the organizational and developmental stages of information provided to AI, if implemented, it can be applied for predicting fires in electric vehicles and in other devices.
本研究使用安全数据表(SDS),其中描述了与化学物质相关的特性和危害,以确定与电池材料相关的危害。此外,我们还研究了是否可以仅使用sds来预测车载电池引起的电动汽车火灾。此外,我们的目标是利用基于sds的人工智能(AI)方法克服电动汽车火灾预测的局限性。我们发现,使用sds可以准确预测电池材料引起的火灾;然而,由热失控或未知或人为原因引起的火灾无法仅由sds预测。结果表明,当人工智能用于预测和扑灭电动汽车火灾时,重要的是要考虑与电池材料相关的危害,并分析过去发生的火灾以及有效的灭火方法。虽然在提供给人工智能的信息的组织和发展阶段存在限制,但如果实施,它可以应用于预测电动汽车和其他设备的火灾。
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引用次数: 1
Changes and Developments in Hydrogen Energy as Seen in TV Programs 从电视节目看氢能的变化与发展
Pub Date : 2019-01-01 DOI: 10.3210/fst.38.21
J. Kida, T. Akitsu
Hydrogen energy, which has attracted attention in recent years, has the following two major advantages. Hydrogen as a fuel has multiple production methods and does not depend on petroleum. Only water is produced during combustion, and carbon dioxide is not emitted. For these reasons, hydrogen energy is considered as a new energy for the next generation especially in Japan, and both companies and governments are rapidly putting effort into dissemination. However, hydrogen used as a fuel is a flammable gas essentially. Hydrogen also ignites when energy such as static electricity is applied in a state of being mixed with oxygen at a constant concentration. In addition, hydrogen is often marketed and distributed as high-pressure gas in order to reduce its volume. Therefore, when the gas container is heated, the volume of hydrogen contained therein suddenly increases and the container withstands internal pressure. There is a possibility of explosion without breaking. In fact, according to The High Pressure Gas Safety Institute of Japan, 69 accidents have happened involving high pressure hydrogen gas in 2011-2014 [1]. Thus, in order to spread hydrogen energy, it is indispensable to prepare means and regulations for safely handling hydrogen. Herein, changes and developments in hydrogen energy as seen in TV programs about hydrogen energy and fuel cells have been investigated by not only browsing NHK (Nihon Hoso Kyokai)’s program archives but also other database or materials. In addition, by comparing with other TV programs about a famous fire accident in Japan, characteristics of TV programs as will be discussed.
近年来备受关注的氢能具有以下两大优势。作为燃料的氢有多种生产方法,不依赖于石油。燃烧时只产生水,不排放二氧化碳。由于这些原因,氢能被认为是下一代的新能源,特别是在日本,公司和政府都在迅速努力推广。然而,作为燃料的氢本质上是一种可燃气体。当静电等能量与恒定浓度的氧气混合时,氢气也会被点燃。此外,氢气通常作为高压气体销售和分销,以减少其体积。因此,当气体容器被加热时,其中所含氢气的体积突然增加,容器承受内部压力。有爆炸而不破裂的可能。事实上,根据日本高压气体安全研究所的数据,2011-2014年共发生69起涉及高压氢气的事故[1]。因此,为了推广氢能,必须制定安全处理氢的手段和法规。在此,通过浏览NHK (Nihon Hoso Kyokai)的节目档案和其他数据库或资料,研究了氢能源和燃料电池在电视节目中所看到的变化和发展。此外,通过与其他有关日本著名火灾事故的电视节目的比较,探讨了电视节目的特点。
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引用次数: 1
Case Studies on Predictability in University Chemistry Experiment Accidents 大学化学实验事故可预见性案例研究
Pub Date : 2018-01-01 DOI: 10.3210/FST.37.1
K. Mizuno, Kaori Ueki, T. Akitsu
In this study, we investigated prediction of fire accidents of university’s chemical experiments based on properties or data of chemicals used. By referencing hazardous compounds and their properties in the Fire Service Act in Japan, potentially dangerous operations were picked up from the textbook of General Chemistry Laboratory for undergraduate students in Department of Chemistry, Faculty of Science, University of Science. Moreover, previous examples of fire accidents associated with such hazardous compounds and experimental operations were also searched from some databases. Comparing both facts, we concluded that most of fire accidents are predictable, and some difficult cases (i) required common sense for chemical experiments (implicit knowledge with experience) and (ii) are state-dependent properties of the hazardous compounds, e . g . very reactive nanoparticles. The results will also suggest possibility of AI-aided prediction of fire accidents in the future, the range of data required to be learnt, and remaining technical problems. 3 )] Cl and drop a few mL of water and dissolve well. While cooling the solution in an ice bath, add 6-7 mL of 3 mol/L hydrogen chloride. Care should be taken, since the solution will bubble vigorously. After adding 3 mol/L hydrogen chloride, add about 5 mL of concentrated hydrogen chloride slowly, then heat and condense on a hot plate inside a fume hood until the solution solidifies into green crystals. After it solidifies, let cool, then add a small amount of cold water, then, wash with methanol . Dry well on watch glass. Text
本研究针对高校化学实验中使用的化学物质的性质或数据,探讨了火灾事故的预测方法。参考日本《消防法》中有害化合物及其性质,从理学院化学系本科普通化学实验教材中选取具有潜在危险的操作方法。此外,还从一些数据库中检索了以前与这种危险化合物和实验操作有关的火灾事故的例子。比较这两个事实,我们得出的结论是,大多数火灾事故是可预测的,一些困难的情况下(i)需要化学实验的常识(隐性知识与经验)和(ii)是危险化合物的状态依赖属性,e。g。非常活泼的纳米颗粒。研究结果还将提出未来人工智能辅助预测火灾事故的可能性、需要学习的数据范围以及遗留的技术问题。[3] Cl和滴几毫升水,溶解好。在冰浴中冷却溶液时,加入6- 7ml的3mol /L氯化氢。要小心,因为溶液会剧烈起泡。加入3mol /L氯化氢后,缓慢加入约5ml浓缩氯化氢,然后在通风柜内的热板上加热冷凝,直至溶液凝固成绿色晶体。固化后放凉,再加入少量冷水,然后用甲醇清洗。擦干手表玻璃。文本
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引用次数: 3
Fundamental Study of Gas Toxicity with Respect to Fire Stages 气体毒性的基础研究与火的阶段
Pub Date : 2017-01-01 DOI: 10.3210/FST.36.11
Xuansu Zhao, H. Yoshioka, T. Noguchi, S. Fujimoto, Yutaka Tanaike, T. Hayakawa, Yoshihiro Hase, T. Naruse
Current Building Standard Law of Japan estimates fire toxicity of building material in case of fire by gas toxicity test using mice. Because it is an animal test, some problems are identified such as the impossibility of quantitative analysis, and from ethical viewpoints. Gas analysis method is needed as an alternative. In this research, authors report FTIR (Fourier Transform Infrared Spectroscopy) analysis of gases generated from building materials using gas toxicity test equipment and a tube furnace. The possibility of replacing animal test with FTIR gas analysis test was discussed.
日本现行《建筑标准法》采用小鼠气体毒性试验来评估建筑材料火灾时的火灾毒性。由于这是一项动物实验,一些问题被发现,如定量分析的不可能性,从伦理的角度来看。需要气体分析法作为一种替代方法。在这项研究中,作者报告了使用气体毒性测试设备和管式炉对建筑材料产生的气体进行FTIR(傅里叶变换红外光谱)分析。讨论了用FTIR气体分析试验代替动物试验的可能性。
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引用次数: 0
Ferrocene-Containing Emulsion-Based Fire-Extinguishing Agents 二茂铁乳化灭火剂
Pub Date : 2017-01-01 DOI: 10.3210/FST.36.1
Y. Koshiba, Takuya Tomita, H. Ohtani
This paper proposes a novel fire suppressant: a ferrocene-containing oil-in-water (O/W) emulsion. In this study, oil-in-water emulsions containing a surfactant (triton X-100) and ferrocene (0-500 ppm) were prepared and their stabilities and capabilities to extinguish pool fires were investigated. The resulting O/W emulsions exhibited no phase separation for at least one month. Suppression experiments clearly demonstrated that (1) the ferrocene-containing O/W emulsions have a high suppression capability even if the emulsion contained 1.05-wt% n -octane and that (2) the suppression capability is positively correlated with the ferrocene concentration in the 0-500 ppm concentration range.
本文提出了一种新型灭火剂:含二茂铁的水包油乳液。在本研究中,制备了含有表面活性剂(triton X-100)和二茂铁(0-500 ppm)的水包油乳液,并研究了它们的稳定性和扑灭池火的能力。得到的油水乳状液在至少一个月内没有发生相分离。抑制实验清楚地表明:(1)含二茂铁的油水乳状液即使含有1.05-wt%的正辛烷也具有较高的抑制能力;(2)在0-500 ppm浓度范围内,二茂铁的抑制能力与二茂铁的浓度呈正相关。
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引用次数: 1
Self-standing Compartment Fire Tests on Sandwich Panels 夹芯板自立隔间防火试验
Pub Date : 2016-01-01 DOI: 10.3210/FST.35.19
H. Yoshioka, Yoshiki Tanaka, Yuhei Nishio, T. Noguchi, Kyoichi Kobayashi, Y. Ohmiya, M. Kanematsu, Tatsuo Ando, T. Naruse, K. Kagiya, T. Hayakawa
Evaluation of the fire performance of building materials is being conducted in Japan in accordance with ISO 5660-1. There is concern that sandwich panels containing combustible cores can pass certain classification criteria based on this small scale test even though they could be ignited and burn in actual fires including flashover. Within ISO/TC92/SC1, the ISO 13784-1 test addresses the evaluation of self-standing sandwich panels, but it is difficult to be routinely performed. This study proposes an intermediatescale self-standing box test that a) has the same configuration as the ISO/TS17431 box test and b) compares this new proposed test with the ISO 13784-1 test both conducted for the first time in Japan in this program. A correlation between these two test methods (the new box test and ISO 13784-1) is also presented.
日本正在按照ISO 5660-1对建筑材料的防火性能进行评估。人们担心含有可燃芯的夹层板可以通过基于小规模测试的某些分类标准,即使它们可能在包括闪燃在内的实际火灾中被点燃和燃烧。在ISO/TC92/SC1中,ISO 13784-1测试涉及对自立夹层板的评估,但很难常规执行。本研究提出了一种中等规模的自立箱测试,a)与ISO/TS17431箱测试具有相同的配置,b)将新提议的测试与该计划中首次在日本进行的ISO 13784-1测试进行比较。这两种测试方法(新箱试验和ISO 13784-1)之间的相关性也被提出。
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引用次数: 2
Phenomenological Model and Experimental Comparisons on Static Foam Drainage for Fire Fighting Foams 消防泡沫静态泡沫排水的现象学模型及实验比较
Pub Date : 2016-01-01 DOI: 10.3210/FST.35.1
H. Mukunda, C. S. Dixit
This paper is concerned with the development of a phenomenological model for drainage from static foams used in standard fire-foam qualification tests for low expansion ratio commercially available foams. The fact that operational foam heights (30 mm) are much smaller than foam drainage apparatus heights (200 mm) has been the inspiration to determine the height dependence of static drainage. This is done by constructing a model of foam drainage based on momentum flux balance and conducting experiments with an apparatus with foam drainage through a fuel layer. The results show a linear relationship of quarter drainage time with the height consistent with the theoretical expectations. The constants are related to viscosity and liquid film thickness. Microscopic examination on bubble movement and the pictures are used to infer that the bubble size distributions between three commercial foams are not distinctively different and so are the film thicknesses. It is argued that the strong dependence on quarter drainage time on the film thickness can be consistent with the experimental results only if the variation of these thicknesses between different foams is not significantly large. Assuming a constant film thickness, the constants of the relationship between quarter drainage time and height are obtained from the experimental data. The constants derived from the experimental data show dependences in which lower concentration foams have a behavior different from those with higher concentrations beyond known influences of viscosity and surface tension. The need for longer duration drainage as a qualifying measure is argued to be important to correlate with fire extinction behavior.
本文研究了一种用于低膨胀比市售泡沫标准防火泡沫定性试验的静态泡沫排水的现象学模型的发展。操作泡沫高度(30毫米)远小于泡沫排水装置高度(200毫米),这一事实为确定静态排水的高度依赖性提供了灵感。建立了基于动量通量平衡的泡沫排水模型,并在燃料层泡沫排水装置上进行了实验。结果表明,四分之一排水时间与高度呈线性关系,符合理论预期。这些常数与粘度和液膜厚度有关。通过对气泡运动和图片的显微检查,可以推断出三种商品泡沫之间的气泡大小分布没有明显差异,膜厚也没有明显差异。本文认为,只有在不同泡沫之间的膜厚变化不是很大的情况下,四分之一排水时间对膜厚的依赖性才与实验结果一致。假设膜厚一定,由实验数据得到四分之一排水时间与高度的关系常数。从实验数据得出的常数表明,在已知的粘度和表面张力影响之外,低浓度泡沫的行为不同于高浓度泡沫的行为。需要更长时间的排水作为一种合格的措施,被认为是重要的与灭火行为相关联。
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引用次数: 0
Experimental Study on Car Fire with Respect to Urban Fire Spreading 汽车火灾在城市火灾蔓延中的实验研究
Pub Date : 2015-09-04 DOI: 10.3210/FST.37.17
H. Yoshioka, T. Iwami, Shuichi Takeya
In case of urban large fire spreading in a highly crowded areas of Japan, roads are usually considered to be effective in blocking the fire spreading between the buildings, together with parks, vacant spaces, rivers, and railway tracks, etc. However, especially when there is a car in a narrow road between two adjacent buildings, then it could be possible that fire spreading will be even accelerated by the burning car on a road, rather than the situation where a road will block the fire spreading. Both domestically in Japan and internationally, there have been many car fire researches based on experiments, but so far, most of them have been discussing the fire behavior of automobiles themselves, and not so many have been focusing on the car fire with respect to fire spreading between the buildings in case of urban fire spread, under the circumstances such as major earthquake or extremely high wind. Therefore, in this research, authors firstly conducted the full-scale fire experiment, where car is ignited by fire from the opening in a building façade, and observed how car is ignited by radiation and convection and then how fire is propagated in that car, and also incident heal fluxes were measured at surrounding places of the ignited car. Furthermore secondly, simple calculation model was proposed based on this car fire experiment, which was then applied to the parametric study for predicting the occurrence time of fire spreading to the adjacent building from the building of fire origin, with and without a car located between the two buildings. It was found that generally there was not great difference in time to fire spreading between the buildings dependent on the existence of car. But in an extreme situation where the distance between the two buildings is large, and also car is located quite close to the adjacent building (instead of the building of fire origin), there was a difference in calculation results dependent on the existence of a car, more specifically, the existence of car induced the occurrence of fire spreading between the buildings.
在日本,如果在人口密集的地区发生城市大火,道路以及公园、空地、河流和铁路轨道等通常被认为能有效地阻止火灾在建筑物之间蔓延。但是,特别是当两个相邻建筑物之间的狭窄道路上有一辆汽车时,那么道路上燃烧的汽车甚至有可能加速火势的蔓延,而不是道路阻挡火势蔓延的情况。无论是日本国内还是国际上,都有很多基于实验的汽车火灾研究,但迄今为止,大多数研究都是在讨论汽车本身的火灾行为,而很少有人关注在城市火灾蔓延的情况下,在大地震或大风等情况下,汽车火灾在建筑物之间的火灾蔓延。因此,在本研究中,作者首先进行了全尺寸的火灾实验,在建筑立面的开口处进行火灾引燃汽车的实验,观察了辐射和对流如何引燃汽车,然后火灾如何在汽车中传播,并测量了被引燃汽车周围的入射通量。其次,在本次汽车火灾实验的基础上,提出了简单的计算模型,并将其应用于预测火灾发生时间的参数化研究,以预测火灾发生时两建筑之间是否有汽车的情况。研究发现,一般情况下,由于汽车的存在,火灾在建筑物之间的蔓延时间差异不大。但在两个建筑物之间距离较大,且汽车距离相邻建筑物(而不是起火建筑物)相当近的极端情况下,由于汽车的存在导致了计算结果的差异,更具体地说,汽车的存在导致了建筑物之间火灾蔓延的发生。
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引用次数: 0
A Tractable Solution for Engineering Calculations on Buoyancy Dominated Turbulent Non-Premixed Flames 浮力主导湍流非预混火焰工程计算的一种易于处理的解决方案
Pub Date : 2015-01-01 DOI: 10.3210/FST.34.1
H. Dong, J. Garo, B. Magnognou, Hui-Ying Wang
The modelling of molecular species and smoke concentrations in turbulent buoyant intermediate free pool and enclosure fires is described. The numerical model solves the time-dependent reactive flow, Navier-Stokes equations, coupled with submodels for soot formation and thermal radiation transfer. A comparison is performed, and differences are discussed between the values of the temperature, velocity, carbon monoxide and smoke concentrations in the fire from the current study and the literature. The current modeling indicates that CO generation is relatively independent of position in the overfire region, and is correlated solely as a function of mixture fraction. No link between the soot concentration and the mixture fraction is found, which suggests that soot formation in the fires is fundamentally controlled by the transient phenomena. For a free pool-like fire, the computed peak temperature, velocity and CO concentration differ from the experimental values by less than 15%. The soot volume fraction differs significantly from the experimental data only in the fuel-lean, thermal plume region.
描述了湍流浮力中间自由池和围栏火灾中分子种类和烟雾浓度的模型。该数值模型求解了随时间变化的反应流、Navier-Stokes方程以及烟尘形成和热辐射传递子模型。进行了比较,并讨论了当前研究和文献中火灾中的温度、速度、一氧化碳和烟雾浓度的值之间的差异。目前的模型表明,CO的生成相对独立于过火区域的位置,而仅与混合物分数相关。煤烟浓度与混合分数之间没有联系,说明火灾中煤烟的形成基本上受瞬态现象控制。对于自由池状火灾,计算得到的峰值温度、速度和CO浓度与实验值相差小于15%。烟灰体积分数仅在燃料稀薄、热羽流区域与实验数据有显著差异。
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引用次数: 0
Façade Tests on Fire Propagation along Combustible Exterior Wall Systems 可燃外墙系统火焰传播的立面试验
Pub Date : 2014-01-01 DOI: 10.3210/FST.33.1
H. Yoshioka, Yuhei Nishio, M. Tamura, Masahi Yoshida, T. Noguchi, Y. Ohmiya, M. Kanematsu, Tatsuo Ando, Kouji Koura, T. Tomatsu, Yasuji Ozaki
With regard to fire protection for exterior walls of a building, only fire-resistive performance is considered, according to the current building standard law of Japan. In previous authors' studies, a new test method for evaluation of fire propagation along combustible cladding was proposed using primarily test specimens of facade walls with exterior thermal insulation without vent layers. In this paper, newly made results of facade fire tests also with other specimens of combustible facades, such as sandwich panels, photovoltaic sheets, combustible coating materials, and exterior insulation with vent layer, are discussed.
对于建筑外墙的防火,根据日本现行的建筑标准法,只考虑耐火性能。在之前的研究中,作者提出了一种新的测试方法来评估沿可燃覆层的火灾传播,主要使用无通风口的外保温立面墙的测试样本。本文讨论了对夹心板、光伏板、可燃涂层材料、带通风口的外保温材料等可燃外墙的最新测试结果。
{"title":"Façade Tests on Fire Propagation along Combustible Exterior Wall Systems","authors":"H. Yoshioka, Yuhei Nishio, M. Tamura, Masahi Yoshida, T. Noguchi, Y. Ohmiya, M. Kanematsu, Tatsuo Ando, Kouji Koura, T. Tomatsu, Yasuji Ozaki","doi":"10.3210/FST.33.1","DOIUrl":"https://doi.org/10.3210/FST.33.1","url":null,"abstract":"With regard to fire protection for exterior walls of a building, only fire-resistive performance is considered, according to the current building standard law of Japan. In previous authors' studies, a new test method for evaluation of fire propagation along combustible cladding was proposed using primarily test specimens of facade walls with exterior thermal insulation without vent layers. In this paper, newly made results of facade fire tests also with other specimens of combustible facades, such as sandwich panels, photovoltaic sheets, combustible coating materials, and exterior insulation with vent layer, are discussed.","PeriodicalId":12289,"journal":{"name":"Fire Science and Technology","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2014-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"90342995","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 16
期刊
Fire Science and Technology
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