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Tribological evaluation of thermoplastic polyurethane-based bearing materials under water lubrication: Effect of load, sliding speed, and temperature 水润滑条件下热塑性聚氨酯基轴承材料的摩擦学评估:载荷、滑动速度和温度的影响
IF 6.8 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-05-25 DOI: 10.1007/s40544-023-0856-1
Shaoli Jiang, Janet S. S. Wong, Debashis Puhan, Tian Yuan, Xiuqin Bai, Chengqing Yuan

Polymers are widely used in bearing applications. In the case of water-lubricated stern tube bearings, thermoplastic polyurethane (TPU)-based composites are used due to their excellent wear resistance, corrosion resistance, and tunable mechanical properties. Their tribological performance, however, depends on operating conditions. In this work, TPU was blended with carbon fiber, graphene platelet, and ultra-high molecular weight polyethylene (UHMWPE). Friction tests of TPU based-composites against copper countersurface were carried out in water to mimic the actual operating conditions of the bearing. Most of the resulting contacts were in the boundary lubrication regime, in which friction was attributed to both contact mechanics of asperities as well as water lubrication. Our results show that the viscoelasticity of TPU has a considerable impact on its tribological performance. Water lubrication at 50 °C promotes the softening of polymer surface material during sliding, resulting in higher fluctuation in the coefficient of friction and wear loss. This is attributed to the reduced thermomechanical properties. In addition, Schallamach waviness is observed on worn surface. The tribological properties of TPU are significantly improved by the inclusion of carbon fiber, graphene platelet, and UHMWPE. The formation of graphene transfer-layers and UHMWPE transfer film reduces friction and wear loss, while the inclusion of carbon fiber enhances wear resistance due to improved mechanical properties and load bearing capacity.

聚合物被广泛应用于轴承领域。在水润滑艉轴管轴承中,基于热塑性聚氨酯(TPU)的复合材料因其出色的耐磨性、耐腐蚀性和可调整的机械性能而被广泛使用。不过,它们的摩擦学性能取决于工作条件。在这项研究中,热塑性聚氨酯与碳纤维、石墨烯微粒和超高分子量聚乙烯(UHMWPE)混合。在水中进行了热塑性聚氨酯复合材料与铜表面的摩擦测试,以模拟轴承的实际工作条件。结果显示,大多数接触都处于边界润滑状态,摩擦力可归因于尖角接触力学和水润滑。我们的研究结果表明,热塑性聚氨酯的粘弹性对其摩擦学性能有相当大的影响。50 °C的水润滑促进了滑动过程中聚合物表面材料的软化,导致摩擦系数和磨损损耗的波动增大。这归因于热机械性能的降低。此外,磨损表面还出现了沙拉马赫波纹。加入碳纤维、石墨烯微粒和超高分子量聚乙烯后,热塑性聚氨酯的摩擦学特性得到了显著改善。石墨烯转移层和超高分子量聚乙烯转移膜的形成减少了摩擦和磨损,而碳纤维的加入则提高了机械性能和承载能力,从而增强了耐磨性。
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引用次数: 0
Wear protection assessment of ultralow viscosity lubricants in high-power-density engines: A novel wear prediction algorithm 超低粘度润滑油在高功率密度发动机中的磨损保护评估:新型磨损预测算法
IF 6.8 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-05-25 DOI: 10.1007/s40544-023-0854-3
Javier Blanco-Rodríguez, Jacobo Porteiro, José A. López-Campos, Martí Cortada-García, Silvia Fernández-Castejón

Durability and reliability have been studied for decades through intensive trial-error experimentation. However, there are numerous fields of application where the costs associated with this approach are not acceptable. In lubricated machines with severe dynamic loads, such as high-power-density engines, simulation tools offer clear advantages over intensive testing. Prototypes and multiple scenarios can be cost-effectively simulated to assess different lubricants and engine configurations. The work presented here details the study of wear based on a validated elastohydrodynamic (EHD) simulation model of the connecting rod journal bearing. This model accounts for elastic deformation through a connecting rod finite element model (FEM). In addition, multiple lubricant rheological and tribological dependences, determined by specific experimental tests, are applied in the model through their interaction with the simulation software. Correspondingly, a novel wear algorithm is proposed to predict wear depth over time evolution along a proposed wear cycle based on the typical working ranges of high-performance engines. A final assessment is presented to compare 4 different ultralow-viscosity lubricants in their protective performance under severe conditions. The results show the evolution of the wear load and wear depth over the wear cycle. This evaluation is key to describing a lubricant selection procedure for high-power-density engines.

几十年来,人们一直在通过大量的试错实验来研究耐久性和可靠性。然而,在许多应用领域中,这种方法的成本是无法接受的。在具有严重动态负载的润滑机器中,例如高功率密度发动机,模拟工具比密集试验具有明显优势。可以经济高效地模拟原型和多种情况,以评估不同的润滑油和发动机配置。本文介绍的工作基于经过验证的连杆轴颈轴承弹性流体力学(EHD)模拟模型,详细介绍了磨损研究。该模型通过连杆有限元模型(FEM)考虑了弹性变形。此外,由特定实验测试确定的多种润滑剂流变学和摩擦学相关性通过与模拟软件的交互作用被应用到模型中。相应地,还提出了一种新的磨损算法,用于预测基于高性能发动机典型工作范围的拟议磨损周期的磨损深度随时间的演变情况。最后的评估对 4 种不同的超低粘度润滑油在恶劣条件下的保护性能进行了比较。结果显示了磨损负荷和磨损深度在磨损周期内的变化情况。该评估是描述高功率密度发动机润滑油选择程序的关键。
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引用次数: 0
Flexible metal–organic frameworks based self-lubricating composite 基于金属有机框架的柔性自润滑复合材料
IF 6.8 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-05-25 DOI: 10.1007/s40544-023-0857-0
Xiao Yang, Yunbo Wang, Weihua Cao, Jinghan Zheng, Changxin Liu, Bingli Fan, Xiaowen Qi

To expand the use of metal–organic frameworks (MOFs) based self-lubricating composite, flexible MOFs MIL-88D has been studied as a nanocontainer for loading lubricant. In this work, the mechanism of oleamine adsorption and desorption by MIL-88D was investigated through molecular simulations and experiments. Molecular simulations showed that the oleamines can be physically adsorbed into open MIL-88Ds with the Fe and O atoms of MIL-88D interacting with oleamine NH2-group. Higher temperature can cause Ole@MIL-88D to release more oleamines, while higher pressure on Ole@MIL-88D caused less oleamines released. Moreover the Ole@MIL-88D was incorporated into epoxy resin (EP) for friction tests. The optimum mass ratio of MIL-88D to EP is 15 wt%, and the EP/Ole@MIL-88D prefers light load and high frequency friction. This work suggests that flexible MOFs can be used as a nanocontainer for loading lubricant, and can be used as a new self-lubricating composite.

为了扩大基于金属有机框架(MOFs)的自润滑复合材料的应用,研究人员将柔性 MOFs MIL-88D 作为装载润滑剂的纳米容器。本研究通过分子模拟和实验研究了油胺在 MIL-88D 中的吸附和解吸机理。分子模拟结果表明,油胺可以通过 MIL-88D 的 Fe 原子和 O 原子与油胺 NH2 基相互作用而被物理吸附到开放的 MIL-88D 中。温度越高,Ole@MIL-88D 释放的油胺越多,而 Ole@MIL-88D 所承受的压力越大,释放的油胺越少。此外,还将 Ole@MIL-88D 加入环氧树脂(EP)中进行摩擦试验。MIL-88D 与 EP 的最佳质量比为 15 wt%,EP/Ole@MIL-88D 更倾向于轻载和高频摩擦。这项工作表明,柔性 MOFs 可用作装载润滑剂的纳米容器,并可用作新型自润滑复合材料。
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引用次数: 0
The effect of electrical current on lubricant film thickness in boundary and mixed lubrication contacts measured with ultrasound 用超声波测量电流对边界和混合润滑接触中润滑油膜厚度的影响
IF 6.8 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-05-23 DOI: 10.1007/s40544-024-0890-7
Julio A. Cao-Romero-Gallegos, Saeid Taghizadeh, Oscar A. Aguilar-Rosas, R. S. Dwyer-Joyce, Leonardo I. Farfan-Cabrera

This work explores experimentally the effects of DC electrical currents on lubricant film thickness alteration in lubricated sliding steel contacts in the boundary and mixed regime as measured by ultrasound. The experiments were performed in a two-electrode cell-based pin-on-disk tester instrumented with ultrasonic transducers. Unelectrified and electrified tribological tests were conducted on steel flat-on-flat contacts under various speeds and loads using both a mineral base oil and a gear oil. Film thickness, coefficient of friction (CoF), and electrical contact resistance (ECR) were measured during short experiments (30 s) in unelectrified and electrified (1.5 and 3 A) conditions. The results suggest that film thickness, CoF, and all ECR are altered by passing DC currents through the contact. In particular, film thickness increased and decreased, respectively, by applying electricity at the different speeds and loads tested. These alterations were majorly ascribed to oil viscosity decrease by local heat and surface oxidation caused by electrical discharge and break down at the interface.

这项研究通过实验探索了直流电流在边界和混合状态下对润滑滑动钢触点中润滑油膜厚度变化的影响,并通过超声波进行了测量。实验在配备超声波传感器的双电极针盘测试仪中进行。使用矿物基础油和齿轮油,在不同速度和载荷下对钢制平对平触头进行了无电和有电摩擦学测试。在无电和有电(1.5 A 和 3 A)条件下的短时间实验(30 秒)中,测量了油膜厚度、摩擦系数(CoF)和电接触电阻(ECR)。结果表明,薄膜厚度、CoF 和所有 ECR 都会因通过接触的直流电流而改变。特别是,在测试的不同速度和负载下通电,薄膜厚度分别增加和减少。这些变化主要归因于局部热量和表面氧化引起的油粘度降低,以及界面上的放电和分解。
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引用次数: 0
Boundary-lubricated biomaterials with drug delivery for osteoarthritis treatment 用于骨关节炎治疗的边界润滑生物材料与药物输送
IF 6.8 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-05-23 DOI: 10.1007/s40544-024-0874-7
Junyu Wu, Kaixuan Ren, Jingbo Yin

The good lubrication ability of articular cartilage holds significant importance in our daily lives. Osteoarthritis (OA), the most prevalent degenerative joint disease, causes cartilage damage, increased friction, and inflammation. However, the current clinical treatments for OA exhibit some defects. Recently, the sustained drug release systems with lubricating function have attracted considerable attention for treating OA. This review introduces the lubrication mechanism of cartilage, focusing particularly on the boundary lubrication mechanism. The research progress of boundary-lubricated biomaterials with drug delivery, including microcarriers, hydrogels, and nanoparticles in the treatment of OA by improving inter-articular lubrication and relieving inflammation is discussed and summarized. The efficacy and challenges of boundary-lubricated biomaterials with drug delivery in the treatment of OA are summarized, and the prospects are also discussed.

关节软骨的良好润滑能力对我们的日常生活具有重要意义。骨关节炎(OA)是最常见的关节退行性疾病,会导致软骨损伤、摩擦加剧和炎症。然而,目前临床上治疗 OA 的方法存在一些缺陷。最近,具有润滑功能的药物缓释系统在治疗 OA 方面引起了广泛关注。本综述介绍了软骨的润滑机制,尤其侧重于边界润滑机制。讨论并总结了具有给药功能的边界润滑生物材料(包括微载体、水凝胶和纳米颗粒)在通过改善关节间润滑和缓解炎症来治疗 OA 方面的研究进展。总结了边界润滑生物材料与药物递送在治疗 OA 方面的疗效和挑战,并讨论了其前景。
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引用次数: 0
Screening of low-friction two-dimensional materials from high-throughput calculations using lubricating figure of merit 利用润滑功勋值通过高通量计算筛选低摩擦二维材料
IF 6.8 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-05-23 DOI: 10.1007/s40544-024-0901-8
Kewei Tang, Weihong Qi, Guoliang Ru, Weimin Liu

Two-dimensional materials are excellent lubricants with inherent advantages. However, superlubricity has been reported for only a few of these materials. Unfortunately, other promising two-dimentional (2D) materials with different physical properties cannot be discovered or applied in production; thus, energy consumption can be greatly reduced. Here, we carry out high-throughput calculations for 1,475 2D materials and screen for low-friction materials. To set a standard, we propose, for the first time, a geometry-independent lubricating figure of merit based on the conditions for stick-slip transition and our theory of Moiré friction. For the efficient calculation of this figure of merit, an innovative approach was developed based on an improved registry index model. Through calculations, 340 materials were found to have a figure of merit lower than 10−3. Eventually, a small set of 21 materials with a figure of merit lower than 10−4 were screened out. These materials can provide diverse choices for various applications. In addition, the efficient computational approach demonstrated in this work can be used to study other stacking-dependent properties.

二维材料是极佳的润滑剂,具有与生俱来的优势。然而,目前仅有少数此类材料具有超润滑性。遗憾的是,具有不同物理性质的其他有前途的二维(2D)材料尚未被发现或应用于生产;因此,能耗可以大大降低。在此,我们对 1475 种二维材料进行了高通量计算,并筛选出了低摩擦材料。为了树立一个标准,我们根据粘滑过渡的条件和莫伊里摩擦理论,首次提出了与几何形状无关的润滑功绩值。为了有效计算这一优点系数,我们在改进的登记指数模型基础上开发了一种创新方法。通过计算,发现有 340 种材料的摩擦系数低于 10-3。最终,筛选出 21 种优越性低于 10-4 的材料。这些材料可为各种应用提供多种选择。此外,这项工作中展示的高效计算方法还可用于研究其他依赖堆叠的特性。
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引用次数: 0
Topology optimization of AISI 4140 steel with surface texture filled by multi-solid lubricants for enhancing tribological properties 采用多固体润滑剂填充表面纹理的 AISI 4140 钢的拓扑优化,以提高摩擦学性能
IF 6.8 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-05-07 DOI: 10.1007/s40544-024-0863-x
Qipeng Huang, Chaohua Wu, Xiaoliang Shi, Kaipeng Zhang

Wind power gears will be excessively worn due to lubrication failure during operation. Herein, the tribological properties of rubbing pairs are improved by filling solid lubricants into surface texture. In texture design, three types of topological textures (Circle (C), Hexagon (H) and Circle/Hexagon (CH)) were obtained by cell topology optimization, and then three cases with 20%, 30%, and 40% density were designed for each texture. Next, SnAgCu and TiC were deposited in texture of AISI 4140 steel (AS) to obtain 9 kinds of self-lubricating surfaces. Among them, AS with 30% CH density (AS-CH30) exhibits excellent mechanical and tribological properties. Compared with AS-C and AS-H, the maximum equivalent stress of AS-CH was decreased by 10.86% and 5.37%, respectively. Friction coefficient and wear rate of AS-CH30 were 79.68% and 78% lower than those of AS. The excellent tribological performances of AS-CH30 can be attributed to the synergistic effect of topological surface and solid lubricants. Topological surface can not only reduce fluctuation of equivalent stress, but also promote the stored lubricants to be easily transferred at the contact interface to form a 200 nm lubricating film containing solid lubricants (mainly), oxides and wear debris.

风电齿轮在运行过程中会因润滑失效而过度磨损。在这里,通过在表面纹理中填充固体润滑剂来改善摩擦副的摩擦学特性。在纹理设计中,通过单元拓扑优化获得了三种拓扑纹理(圆形(C)、六角形(H)和圆形/六角形(CH)),然后为每种纹理设计了 20%、30% 和 40% 密度的三种情况。接着,在 AISI 4140 钢(AS)的纹理中沉积 SnAgCu 和 TiC,得到 9 种自润滑表面。其中,CH 密度为 30% 的 AS(AS-CH30)具有优异的机械性能和摩擦学性能。与 AS-C 和 AS-H 相比,AS-CH 的最大等效应力分别降低了 10.86% 和 5.37%。AS-CH30 的摩擦系数和磨损率分别比 AS 低 79.68% 和 78%。AS-CH30 的优异摩擦学性能可归因于拓扑表面和固体润滑剂的协同作用。拓扑表面不仅能减少等效应力的波动,还能促进储存的润滑剂在接触界面上轻松转移,形成一层含有固体润滑剂(主要是)、氧化物和磨损碎屑的 200 nm 润滑膜。
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引用次数: 0
Anisotropic tribology and electrification properties of sliding-mode triboelectric nanogenerator with groove textures 具有凹槽纹理的滑动模式三电纳米发电机的各向异性摩擦学和电气化特性
IF 6.8 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-05-07 DOI: 10.1007/s40544-024-0861-z
Weixu Yang, Jieyang Wang, Xiaoli Wang, Ping Chen

Sliding-mode triboelectric nanogenerator (S-TENG) is based on the coupling of triboelectrification and electrostatic induction, converting electrical energy from sliding motion. Introducing micro-textures into the sliding surface, and adjusting the angle between the texture and sliding direction (direction angle) may achieve performance anisotropy, which provides novel ideas for optimizing the tribology and electrification performance of S-TENG. To guide the performance optimization based on the anisotropy, in this paper, groove micro-textures were fabricated on the surface of S-TENG, and anisotropic tribology and electrification performance were obtained through changing the direction angle. Based on the surface analysis and after-cleaning tests, the mechanism of the anisotropy was explained. It is shown that the anisotropy of friction coefficient can be attributed to the changes of texture edge induced resistance and groove captured wear debris, while the voltage anisotropy is due to the variations of debris accumulated on the sliding interface and the resulting charge neutralization. Among the selected 0°–90° direction angles, S-TENG at angle of 90° exhibits relatively small stable friction coefficient and high open-circuit voltage, and thus it is recommended for the performance optimization. The open-circuit voltage is not directly associated with the friction coefficient, but closely related to the wear debris accumulated on the sliding interface. This study presents a simple and convenient method to optimize the performance of S-TENG, and help understand the correlation between its tribology and electrical performance.

滑动模式三电纳米发电机(S-TENG)基于三电和静电感应的耦合,从滑动运动中转换电能。在滑动表面引入微纹理,并调整纹理与滑动方向的夹角(方向角)可实现性能各向异性,这为优化 S-TENG 的摩擦学和电气化性能提供了新思路。为了指导基于各向异性的性能优化,本文在 S-TENG 表面制作了沟槽微纹理,并通过改变方向角获得了各向异性的摩擦学和电气化性能。基于表面分析和清洁后测试,解释了各向异性的机理。结果表明,摩擦系数的各向异性可归因于纹理边缘诱导电阻和沟槽捕获的磨损碎片的变化,而电压的各向异性则是由于滑动界面上积累的碎片的变化以及由此产生的电荷中和。在所选的 0°-90° 方向角中,90° 角的 S-TENG 显示出相对较小的稳定摩擦系数和较高的开路电压,因此推荐用于性能优化。开路电压与摩擦系数没有直接关系,但与滑动界面上积累的磨损碎片密切相关。本研究提出了一种简单方便的方法来优化 S-TENG 的性能,并有助于理解其摩擦学与电气性能之间的相关性。
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引用次数: 0
Tribological properties of Al-GNP composites at elevated temperature 高温下 Al-GNP 复合材料的摩擦学特性
IF 6.8 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-05-01 DOI: 10.1007/s40544-023-0839-2

Abstract

Lighter and more powerful next generation vehicles and other rotary machinery demand bearings to operate in harsher conditions for higher efficiency, and the continuous development of advanced low-wear and friction materials is thus becoming even more important to meet these requirements. New aluminium composites reinforced with high performance lubricate phases such as graphene nanoplatelets (GNPs) are very promising and have been vigorously investigated. By maintaining a low coefficient of friction (COF) and offering great strength against wear due to their self-lubricating capability, the solid lubricant like GNPs protect the bearing surface from wear damage and prevent change in metallurgical properties during temperature fluctuations. This paper first studies the high-temperature tribological performance of aluminium matrix composites reinforced with GNP, consolidated via powder metallurgy, then elucidates their tribological mechanism. We report that the best tribological performance is achieved by the composite containing 2.0 wt% GNP, with an extraordinarily low COF of 0.09 and a specific wear rate of 3.5×10−2 mm3·N−1·m−1, which represent 75% and 40% reduction respectively, against the plain aluminium consolidated under identical conditions. The in-track and out-of-track Raman analysis have confirmed the role of GNPs in creating a tribofilm on the counterpart surface which contributed to the excellent performance.

摘要 重量更轻、功率更大的下一代汽车和其他旋转机械要求轴承在更恶劣的条件下工作以提高效率,因此,不断开发先进的低磨损和摩擦材料对于满足这些要求变得更加重要。用石墨烯纳米颗粒(GNPs)等高性能润滑相增强的新型铝复合材料前景非常广阔,并已得到大力研究。通过保持较低的摩擦系数(COF),并通过其自润滑能力提供强大的抗磨损强度,GNPs 等固体润滑剂可保护轴承表面免受磨损,并防止在温度波动时发生冶金性能变化。本文首先研究了通过粉末冶金法固结的 GNP 增强铝基复合材料的高温摩擦学性能,然后阐明了其摩擦学机理。我们发现,含 2.0 wt% GNP 的复合材料具有最佳的摩擦学性能,其 COF 值为 0.09,比磨损率为 3.5×10-2 mm3-N-1-m-1,与相同条件下固结的普通铝相比,分别降低了 75% 和 40%。轨内和轨外拉曼分析证实了 GNPs 在对应表面形成三膜的作用,这有助于实现优异的性能。
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引用次数: 0
Core-rim structured MXene@SiO2 composites as oil-based additives for enhanced tribological properties 作为油基添加剂的芯环结构 MXene@SiO2 复合材料可增强摩擦学性能
IF 6.8 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-05-01 DOI: 10.1007/s40544-023-0840-9
Yuhong Cui, Shenghua Xue, Tiantian Wang, Shujuan Liu, Qian Ye, Feng Zhou, Weimin Liu

Herein, we have prepared SiO2 particles uploaded MXene nanosheets via in-situ hydrolysis of tetraetholothosilicate. Due to the large number of groups at the edges of MXene, SiO2 grows at the edges first, forming MXene@SiO2 composites with a unique core-rim structure. The tribological properties of MXene@SiO2 as lubricating additive in 500 SN are evaluated by SRV-5. The results show that MXene@SiO2 can reduce the friction coefficient of 500 SN from 0.572 to 0.108, the wear volume is reduced by 73.7%, and the load capacity is increased to 800 N. The superior lubricity of MXene@SiO2 is attributed to the synergistic effect of MXene and SiO2. The rolling friction caused by SiO2 not only improves the bearing capacity but also increases the interlayer distance of MXene, avoiding accumulation and making it more prone to interlayer slip. MXene@SiO2 is adsorbed on the friction interface to form a physical adsorption film and isolate the friction pair. In addition, the high temperature and high load induce the tribochemical reaction and form a chemical protection film during in the friction process. Ultimately, the presence of these protective films results in MXene@SiO2 having good lubricating properties.

在这里,我们通过原位水解四乙醇基硅酸盐制备了上载 MXene 纳米片的 SiO2 颗粒。由于 MXene 边缘有大量基团,SiO2 首先在边缘生长,从而形成了具有独特核心-边缘结构的 MXene@SiO2 复合材料。用 SRV-5 评估了 MXene@SiO2 作为润滑添加剂在 500 SN 中的摩擦学性能。结果表明,MXene@SiO2 可将 500 SN 的摩擦系数从 0.572 降至 0.108,磨损量减少了 73.7%,承载能力提高到 800 N。SiO2 造成的滚动摩擦不仅提高了轴承的承载能力,还增加了 MXene 的层间距离,避免了堆积,使其更容易发生层间滑移。MXene@SiO2 吸附在摩擦界面上形成物理吸附膜,隔离了摩擦副。此外,高温和高负荷会诱发摩擦化学反应,在摩擦过程中形成化学保护膜。这些保护膜的存在最终使 MXene@SiO2 具有良好的润滑性能。
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引用次数: 0
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