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Bionic functional membranes for separation of oil-in-water emulsions 用于分离水包油型乳液的仿生功能膜
IF 6.8 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-05-01 DOI: 10.1007/s40544-023-0819-6
Chaolang Chen, Ruisong Jiang, Zhiguang Guo

The separation of oil-in-water emulsion is an urgent challenge because its massive production and discharge from daily and industrial activities have caused severe hazards to the ecosystem and serious threats to human health. Membrane technology is considered an outstanding solution strategy for the separation of oil-in-water emulsions due to its unique advantages of low cost, high efficiency, easy operation, and environmental friendliness. However, the membrane is easily fouled by the emulsion oil droplets during the separation process, causing a sharp decline in permeation flux, which greatly inhibits the long-term use of the membrane and largely shortens the membrane’s life. Recently, it was found that endowing the membranes with special wettability e.g., superhydrophilic and superoleophobic can greatly enhance the permeability of the continuous water phase and inhibit the adhesion of oil droplets, thus promoting the separation performance and anti-oil-fouling property of membrane for oily emulsions. In this paper, we review and discuss the recent developments in membranes with special wettability for separating oil-in-water emulsions, including the mechanism analysis of emulsion separation membrane, membrane fouling issues, design strategies, and representative studies for enhancing the membrane’s anti-oil-fouling ability and emulsion separation performance.

水包油型乳液的大量生产和排放给生态系统带来了严重危害,并对人类健康造成了严重威胁,因此水包油型乳液的分离是一项紧迫的挑战。膜技术因其成本低、效率高、操作简便、环境友好等独特优势,被认为是分离水包油型乳液的最佳解决方案。然而,膜在分离过程中很容易被乳状液油滴玷污,导致渗透通量急剧下降,极大地阻碍了膜的长期使用,大大缩短了膜的使用寿命。最近研究发现,赋予膜特殊的润湿性,如超亲水性和超疏水性,可以大大提高连续水相的渗透性,抑制油滴的附着,从而提高油乳剂膜的分离性能和防油污性能。本文回顾并讨论了具有特殊润湿性的水包油乳液分离膜的最新发展,包括乳液分离膜的机理分析、膜堵塞问题、设计策略,以及提高膜抗油堵能力和乳液分离性能的代表性研究。
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引用次数: 0
Experiment and modelling of texture and sliding direction dependence on finger friction behavior 手指摩擦行为与纹理和滑动方向关系的实验和建模
IF 6.8 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-04-15 DOI: 10.1007/s40544-023-0816-9
Yuanzhe Li, Xue Zhou, Pengpeng Bai, Zhonghuan Xiang, Yonggang Meng, Liran Ma, Yu Tian

Humans rely on their fingers to sense and interact with external environment. Understanding the tribological behavior between finger skin and object surface is crucial for various fields, including tactile perception, product appearance design, and electronic skin research. Quantitatively describing finger frictional behavior is always challenging, given the complex structure of the finger. In this study, the texture and sliding direction dependence of finger skin friction was quantified based on explicit mathematic models. The proposed double-layer model of finger skin effectively described the nonlinear elastic response of skin and predicted the scaling-law of effective elastic modulus with contact radius. Additionally, the skin friction model on textured surface considering adhesion and deformation factors was established. It revealed that adhesive term dominated finger friction behavior in daily life, and suggested that object texture size mainly influenced friction-induced vibrations rather than the average friction force. Combined with digital image correlation (DIC) technique, the effect of sliding direction on finger friction was analyzed. It was found that the anisotropy in finger friction was governed by the finger’s ratchet pawl structure, which also contributes to enhanced stick-slip vibrations in the distal sliding direction. The proposed friction models can offer valuable insights into the underlying mechanism of skin friction under various operating conditions, and can provide quantitative guidance for effectively encoding friction into haptics.

人类依靠手指来感知外部环境并与之互动。了解手指皮肤与物体表面之间的摩擦行为对触觉感知、产品外观设计和电子皮肤研究等多个领域都至关重要。由于手指结构复杂,定量描述手指摩擦行为始终是一项挑战。本研究基于明确的数学模型对手指皮肤摩擦的纹理和滑动方向依赖性进行了量化。所提出的手指皮肤双层模型有效地描述了皮肤的非线性弹性响应,并预测了有效弹性模量随接触半径的缩放规律。此外,还建立了考虑粘附和变形因素的纹理表面皮肤摩擦模型。结果表明,日常生活中手指摩擦行为中粘附因素占主导地位,并认为物体纹理大小主要影响摩擦引起的振动,而不是平均摩擦力。结合数字图像相关(DIC)技术,分析了滑动方向对手指摩擦力的影响。结果发现,手指摩擦力的各向异性受手指棘轮棘爪结构的支配,这也是远端滑动方向粘滑振动增强的原因。所提出的摩擦模型可为了解各种操作条件下皮肤摩擦的基本机制提供有价值的见解,并可为有效地将摩擦编码到触觉技术中提供定量指导。
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引用次数: 0
Modeling and prediction of tribological properties of copper/aluminum-graphite self-lubricating composites using machine learning algorithms 利用机器学习算法对铜/铝-石墨自润滑复合材料的摩擦学特性进行建模和预测
IF 6.8 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-04-02 DOI: 10.1007/s40544-023-0847-2
Huifeng Ning, Faqiang Chen, Yunfeng Su, Hongbin Li, Hengzhong Fan, Junjie Song, Yongsheng Zhang, Litian Hu

The tribological properties of self-lubricating composites are influenced by many variables and complex mechanisms. Data-driven methods, including machine learning (ML) algorithms, can yield a better comprehensive understanding of complex problems under the influence of multiple parameters, typically for how tribological performances and material properties correlate. Correlation of friction coefficients and wear rates of copper/aluminum-graphite (Cu/Al-graphite) self-lubricating composites with their inherent material properties (composition, lubricant content, particle size, processing process, and interfacial bonding strength) and the variables related to the testing method (normal load, sliding speed, and sliding distance) were analyzed using traditional approaches, followed by modeling and prediction of tribological properties through five different ML algorithms, namely support vector machine (SVM), K-Nearest neighbor (KNN), random forest (RF), eXtreme gradient boosting (XGBoost), and least-squares boosting (LSBoost), based on the tribology experimental data. Results demonstrated that ML models could satisfactorily predict friction coefficient and wear rate from the material properties and testing method variables data. Herein, the LSBoost model based on the integrated learning algorithm presented the best prediction performance for friction coefficients and wear rates, with R2 of 0.9219 and 0.9243, respectively. Feature importance analysis also revealed that the content of graphite and the hardness of the matrix have the greatest influence on the friction coefficients, and the normal load, the content of graphite, and the hardness of the matrix influence the wear rates the most.

自润滑复合材料的摩擦学特性受到许多变量和复杂机制的影响。数据驱动方法,包括机器学习(ML)算法,可以更好地全面了解多参数影响下的复杂问题,特别是摩擦学性能和材料特性之间的关联。铜/铝石墨(Cu/Al-graphite)自润滑复合材料的摩擦系数和磨损率与其固有的材料特性(成分、润滑剂含量、粒度、加工工艺和界面结合强度)以及与测试方法有关的变量(法向载荷、滑动速度和滑动距离)之间的相关性进行了分析、然后根据摩擦学实验数据,通过五种不同的 ML 算法(即支持向量机 (SVM)、K-近邻 (KNN)、随机森林 (RF)、极梯度提升 (XGBoost) 和最小二乘提升 (LSBoost))对摩擦学特性进行建模和预测。结果表明,ML 模型可以从材料属性和测试方法变量数据中预测摩擦系数和磨损率。其中,基于集成学习算法的 LSBoost 模型对摩擦系数和磨损率的预测效果最好,R2 分别为 0.9219 和 0.9243。特征重要性分析还表明,石墨含量和基体硬度对摩擦系数的影响最大,法向载荷、石墨含量和基体硬度对磨损率的影响最大。
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引用次数: 0
A new 3D plastoelastohydrodynamic lubrication model for rough surfaces 粗糙表面的新型三维塑性体流体动力润滑模型
IF 6.8 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-04-02 DOI: 10.1007/s40544-023-0793-z
Shengyu You, Jinyuan Tang, Qiang Wang

Plastoelastohydrodynamic lubrication of rough surfaces (R-PEHL) is a cutting-edge area of research in interface fluid-structure coupling analysis. The existing R-PEHL model calculates the elastic-plastic deformation of rough surface by the Love equation in a semi-infinite space smooth surface, which deviates from the actual surface. Therefore, it is an innovative work to study the exact solution of elastic-plastic deformation of rough surface and its influence on the solution results of R-PEHL model. In this paper, a new contact calculation model of plastoelastohydrodynamic lubrication (PEHL) with three-dimensional (3D) rough surface is proposed by integrating numerical method of EHL and finite element method. The new model eliminates an original error introduced by the assumption of semi-infinite space in contact calculation, providing wide applicability and high accuracy. Under the given rough surfaces and working conditions, the study reveals that: (1) the oil film pressure calculated by the new model is lower than that of the smooth surface in semi-infinite space by 200–800 MPa; (2) the Mises stress of the new model is 2.5%–26.6% higher than that of the smooth surface in semi-infinite space; (3) compared with the semi-infinite space assumption, the rough surface plastic deformation of the new model is increased by 71%–173%, and the local plastic deformation singularity may appear under the semi-infinite space assumption; (4) the plastic deformation caused by the first contact cycle on the rough surface of the new model accounts for 66.7%–92.9% of the total plastic deformation, and the plastic deformation of the semi-infinite space accounts for 50%–83.3%. This study resolves the contradiction between the smooth surface assumption and the rough surface in the existing R-PEHL model, establishing a solid logic foundation for the accurate solution of R-PEHL model.

粗糙表面的塑性流体动力润滑(R-PEHL)是界面流固耦合分析的前沿研究领域。现有的 R-PEHL 模型是在半无限空间光滑表面上通过 Love 方程计算粗糙表面的弹塑性变形,与实际表面存在偏差。因此,研究粗糙表面弹塑性变形的精确解及其对 R-PEHL 模型求解结果的影响是一项创新工作。本文通过整合 EHL 数值方法和有限元方法,提出了一种新的三维(3D)粗糙表面塑性流体动力润滑(PEHL)接触计算模型。新模型消除了接触计算中半无限空间假设带来的原始误差,具有广泛的适用性和较高的精度。在给定的粗糙表面和工作条件下,研究表明(1) 新模型计算的油膜压力比半无限空间的光滑表面低 200-800 MPa;(2) 新模型的米塞斯应力比光滑表面的米塞斯应力高 2.5%-26.6%;(3)与半无限空间假设相比,新模型粗糙表面塑性变形增加了 71%-173%,半无限空间假设下可能出现局部塑性变形奇点;(4)新模型粗糙表面第一次接触循环引起的塑性变形占总塑性变形的 66.7%-92.9%,半无限空间塑性变形占 50%-83.3%。该研究解决了现有 R-PEHL 模型中光滑表面假设与粗糙表面之间的矛盾,为 R-PEHL 模型的精确求解奠定了坚实的逻辑基础。
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引用次数: 0
Analysis of the discrete contact characteristics based on the Greenwood-Williamson model and the localization principle 基于格林伍德-威廉森模型和定位原理的离散接触特性分析
IF 6.8 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-02-02 DOI: 10.1007/s40544-023-0849-0
Anastasiya A. Yakovenko, Irina G. Goryacheva

The contact of a rigid body with nominally flat rough surface and an elastic half-space is considered. To solve the contact problem, the Greenwood-Williamson statistical model and the localization principle are used. The developed contact model allows us to investigate the surface approach and the real contact area with taking into account the asperities interaction. It is shown that the mutual influence of asperities changes not only contact characteristics at the macroscale, but also the contact pressure distribution at the microscale. As follows from the results, the inclusion in the contact model of the effect of the mutual influence of asperities is especially significant for studying the real contact area, as well as the contact characteristics at high applied loads. The results calculated according to the proposed approach are in a good agreement with the experimentally observed effects, i.e., the real contact area saturation and the additional compliance exhaustion.

本研究考虑了具有名义平坦粗糙表面的刚体与弹性半空间的接触问题。为了解决接触问题,使用了格林伍德-威廉姆森统计模型和定位原理。利用所建立的接触模型,我们可以研究表面接近和实际接触面积,同时考虑到非球面的相互作用。结果表明,非晶体的相互影响不仅改变了宏观尺度上的接触特性,也改变了微观尺度上的接触压力分布。从结果可以看出,在接触模型中加入非晶体相互影响的效应对于研究实际接触面积以及高载荷下的接触特性尤为重要。根据提出的方法计算出的结果与实验观察到的效应(即实际接触面积饱和和额外顺应性耗尽)非常吻合。
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引用次数: 0
Role of temperature in tribolayers in fretting wear of γ-TiAl alloy 温度在γ-钛铝合金摩擦磨损摩擦层中的作用
IF 6.8 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-02-02 DOI: 10.1007/s40544-023-0807-x
Yulei Yang, Hongfei Shang, Huiping Pei, Jimin Xu, Yi Liang, Minghui Pan

The formation of tribolayers may play significant influences on fretting wear. At elevated temperature, the adhesion among wear debris and the increased diffusion rate facilitate the formation of tribolayers. However, the intensification of oxidation at elevated temperature and the low diffusion rate in oxides may play an adverse role. The present study aims to investigate the role of temperature in tribolayers in fretting wear using a γ-TiAl alloy. Scanning electron microscope, energy dispersive spectrometer, Raman spectrometer, transmission electron microscope and nanoindentation were utilized to investigate the wear debris, tribolayers, and wear scars. The fretting tests showed that, compared with that at room temperature (RT) and 350 °C, significant reduction in wear rate and decrease in the fluctuation of friction coefficient occurred at 550 and 750 °C. It was further revealed that when temperature raised from room temperature (RT) to 750 °C, the oxidation of the wear debris increased slightly and the diffusion coefficients increased prominently, which facilities the formation of well tribo-sintered tribolayers. The well tribo-sintered tribolayers presented homogenous structure, nanocrystalline grains with excellent mechanical properties, and resulted in the improvement in the fretting wear resistance of the γ-TiAl alloy at 550 and 750 °C.

摩擦层的形成可能对摩擦磨损有重大影响。在温度升高时,磨损碎屑之间的粘附力和扩散速度的增加有利于摩擦层的形成。然而,高温下氧化作用的加强和氧化物的低扩散率可能会起到不利作用。本研究旨在使用γ-TiAl 合金研究摩擦层在摩擦磨损中的温度作用。利用扫描电子显微镜、能量色散光谱仪、拉曼光谱仪、透射电子显微镜和纳米压痕法研究了磨损碎片、摩擦层和磨损疤痕。摩擦试验表明,与室温(RT)和 350 ℃ 时相比,550 ℃ 和 750 ℃ 时的磨损率明显降低,摩擦系数的波动也明显减小。研究还发现,当温度从室温(RT)升高到 750 ℃ 时,磨损碎屑的氧化程度略有增加,扩散系数显著提高,这有利于形成良好的摩擦烧结摩擦层。三层烧结摩擦层结构均匀,晶粒呈纳米晶状,具有优异的机械性能,从而提高了γ-TiAl合金在550和750 ℃下的抗摩擦磨损性。
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引用次数: 0
Experimental study on boundary lubricity of superficial area of articular cartilage and synovial fluid 关节软骨表层和滑液边界润滑性实验研究
IF 6.8 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-02-02 DOI: 10.1007/s40544-023-0822-y
Wenxiao Li, Takehiro Morita, Yoshinori Sawae

The boundary lubrication mechanism at the articulating surface of natural synovial joints has been the subject of much discussion in tribology. In this study, to elucidate the lubricating function of the superficial area of articular cartilage and synovial fluid (SF), cartilage specimens were processed with four different treatments: gentle and severe washing with detergent, incubation in NaCl solution, and trypsin digestion to selectively remove certain constituents from the cartilage surface. Subsequently, the frictional characteristics were examined in phosphate-buffered saline (PBS) and SF against glass. Angularly reciprocating sliding tests with a spherical glass probe and square articular cartilage specimens were performed at low contact loads in the mN range to extract the frictional behavior in the superficial area of the cartilage specimens. Meanwhile, the cartilage surface was observed to confirm the effects of treatments on the morphology of the cartilage surface using a fluorescence microscope and water-immersion methods. The coefficient of friction (COF) of the prepared cartilage specimens was varied from 0.05 to over 0.3 in PBS. However, a certain group of cartilage specimens exhibited a low COF of less than 0.1 with limited variation. For the low COF group of specimens, all four treatments increased the COF in PBS to different extents, and fluorescence microscopy revealed that the integrity of the cartilage surface was deteriorated by treatments. This means that the intact cartilage surface had lubricating constituents to maintain low friction, and the removal of such constituents resulted in the loss of the intrinsic boundary lubricity of the cartilage surface. The variation in the COF of the cartilage specimens was suppressed in SF because it had a clear boundary lubrication effect on the cartilage surface. The lubricating effect of SF could be confirmed even after degenerative treatment.

天然滑膜关节铰接面的边界润滑机制一直是摩擦学中讨论的主题。在这项研究中,为了阐明关节软骨表层区域和滑液(SF)的润滑功能,对软骨标本进行了四种不同的处理:用洗涤剂进行轻度和重度清洗、在氯化钠溶液中培养、胰蛋白酶消化以选择性地去除软骨表面的某些成分。随后,在磷酸盐缓冲盐水(PBS)和 SF 对玻璃中检测了摩擦特性。用球形玻璃探针和方形关节软骨试样在 mN 范围内的低接触载荷下进行角往复滑动测试,以提取软骨试样表层区域的摩擦行为。同时,使用荧光显微镜和水浸法观察软骨表面,以确认处理对软骨表面形态的影响。制备的软骨试样在 PBS 中的摩擦系数(COF)从 0.05 到 0.3 以上不等。然而,有一组软骨试样的摩擦系数较低,小于 0.1,且变化有限。对于低 COF 组标本,所有四种处理方法都在不同程度上增加了 PBS 中的 COF,荧光显微镜显示软骨表面的完整性因处理方法而恶化。这说明完整的软骨表面具有维持低摩擦的润滑成分,而去除这些成分会导致软骨表面内在边界润滑性的丧失。由于 SF 对软骨表面具有明显的边界润滑作用,因此软骨试样的 COF 变化在 SF 中受到抑制。SF 的润滑效果即使在退化处理后也能得到证实。
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引用次数: 0
Friction and wear performance of polyether ether ketone (PEEK) polymers in three lubrication regimes 聚醚醚酮 (PEEK) 聚合物在三种润滑条件下的摩擦和磨损性能
IF 6.8 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-02-02 DOI: 10.1007/s40544-023-0780-4
Davide Massocchi, Nora Lecis, Marco Lattuada, Davide Scaglia, Steven Chatterton, Paolo Pennacchi

This experimental study investigates the friction and wear of three coatings commonly used in industrial applications, particularly in hydrodynamic bearings. The three materials under investigation were Babbitt, polyether ether ketone (PEEK) reinforced with 15% carbon fibers, and PEEK reinforced with 20% carbon fibers. The first polymer material was extruded, while the other was produced by fused deposition modelling (FDM). The materials were subjected to sliding tests in a pin-on-disc configuration, with a steel ball serving as the counter surface. The tests were conducted at room temperature, with a load of 10 N and under three different lubrication conditions: dry, grease, and oil. The linear speed was set at 0.3 m/s for the dry and semi-solid lubrication tests, while for the oil tests, the speed was set at 0.25 m/s. The greases used had consistency grades of NGLI 000 and NGLI 2. An ISO VG 68 circulation oil was used for the oil lubrication tests. Additionally, thermodynamic analyses were performed under the most severe conditions (i.e., dry) to investigate the steel-Babbitt and steel-PEEK contact.

本实验研究调查了工业应用中常用的三种涂层的摩擦和磨损情况,尤其是在流体动力轴承中。研究的三种材料分别是巴比特、用 15% 碳纤维增强的聚醚醚酮 (PEEK) 和用 20% 碳纤维增强的 PEEK。第一种聚合物材料是挤压成型的,而另一种是通过熔融沉积成型(FDM)生产的。这些材料在针盘配置下进行滑动测试,钢球作为反面。测试在室温下进行,载荷为 10 N,并在三种不同的润滑条件下进行:干润滑、油脂润滑和油润滑。干润滑和半固体润滑试验的线速度设定为 0.3 米/秒,而油润滑试验的线速度设定为 0.25 米/秒。所用润滑脂的稠度等级为 NGLI 000 和 NGLI 2,油润滑试验使用的是 ISO VG 68 循环油。此外,还在最苛刻的条件下(即干燥)进行了热力学分析,以研究钢-巴比特和钢-PEEK 的接触情况。
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引用次数: 0
Oil-soluble polymer brushes-functionalized nanoMOFs for highly efficient friction and wear reduction 油溶性聚合物刷功能化纳米MOF,可高效减少摩擦和磨损
IF 6.8 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-01-10 DOI: 10.1007/s40544-023-0823-x
Jianxi Liu, Yong Qian, Dongshen Li, Wei Wu, Mengchen Zhang, Jie Yan, Bin Li, Feng Zhou
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引用次数: 0
Prediction of ball-on-plate friction and wear by ANN with data-driven optimization 通过数据驱动优化的 ANN 预测球-板摩擦和磨损
IF 6.8 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-01-10 DOI: 10.1007/s40544-023-0803-1
Alexander Kovalev, Yu Tian, Yonggang Meng
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引用次数: 0
期刊
Friction
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