Hydrogel is an ideal material for replacing natural articular cartilage. However, their inadequate mechanical properties, such as severe dynamic damage, restricted its application in the field of joint replacement. Herein, based on Schiff base bond (dialdehyde starch (DS) with acrylamide (AM)) and metal coordination bond (Fe3+ with DS), we designed a self-healing bio-lubricant hydrogel coating (DS/AM/Fe3+). Moreover, the nano-composite metal-organic framework (ZIF-8) was applied to the DS/AM/Fe3+ hydrogels to improve its mechanical properties. The 1000ppmZIF-8/DS/AM/Fe3+ hydrogel coatings show excellent tribological properties and corrosion resistance, with wear rate reduced by 32.94%, friction coefficient reduced to 0.104, corrosion inhibition efficiency up to 79.63%, and active antibacterial and biological activity. The designed hydrogel provides potential applications for artificial joint replacement.
{"title":"A self-healing bio-lubricating hydrogel coating synergistically enhanced with ZIF-8 nanoparticles, exhibiting corrosion resistance, antibacterial properties, and wear resistance","authors":"Yanan Li, Qianqian Wang, Rujiang Wang, Xiaozheng Hou, Sheng Han, Xin Zhao, Chenchen Wang","doi":"10.26599/frict.2025.9441181","DOIUrl":"https://doi.org/10.26599/frict.2025.9441181","url":null,"abstract":"<p>Hydrogel is an ideal material for replacing natural articular cartilage. However, their inadequate mechanical properties, such as severe dynamic damage, restricted its application in the field of joint replacement. Herein, based on Schiff base bond (dialdehyde starch (DS) with acrylamide (AM)) and metal coordination bond (Fe<sup>3+</sup> with DS), we designed a self-healing bio-lubricant hydrogel coating (DS/AM/Fe<sup>3+</sup>). Moreover, the nano-composite metal-organic framework (ZIF-8) was applied to the DS/AM/Fe<sup>3+</sup> hydrogels to improve its mechanical properties. The 1000ppmZIF-8/DS/AM/Fe<sup>3+</sup> hydrogel coatings show excellent tribological properties and corrosion resistance, with wear rate reduced by 32.94%, friction coefficient reduced to 0.104, corrosion inhibition efficiency up to 79.63%, and active antibacterial and biological activity. The designed hydrogel provides potential applications for artificial joint replacement.</p>","PeriodicalId":12442,"journal":{"name":"Friction","volume":"1 1","pages":""},"PeriodicalIF":6.8,"publicationDate":"2025-09-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145183115","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Superelastic NiTi alloys produced through laser powder bed fusion (LPBF) hold great promise in advancing wear-resistant transmission devices for aerospace and related applications. However, limited research on their wear behavior and strategies for enhancing wear resistance raises concerns about their future application prospects. In this study, a straightforward yet highly effective pre-strain treatment method is introduced, resulting in a nearly twofold improvement in the wear resistance of LPBF-fabricated NiTi alloys. This method prunes microstructure characteristics, influences the martensitic transformation process that improves cyclic compression superelasticity and transforms the distribution characteristics of adhesion stress acting on the indenter during wear processes, thereby effectively enhancing wear resistance. Additionally, the present study proposes an analytical model that establishes a link between superelastic metal cyclic compression characteristics and wear behaviors, providing insight into the wear characteristics, especially for adhesive wear patterns of superelastic metals including LPBF-fabricated NiTi alloys through analysis of cyclic compression curve. This research contributes to the fundamental understanding of wear resistance mechanisms in superelastic engineering materials and opens avenues for further optimization in related applications.
{"title":"Improving the superelastic wear resistance of laser powder bed fusing (LPBF) Ni-rich NiTi alloys by mechanical training","authors":"Qingquan Zhang, Weikang Sun, Yuting Liu, Zhenglei Yu, Shijie Hao, Lishan Cui, Luquan Ren, Zhihui Zhang","doi":"10.26599/frict.2025.9441064","DOIUrl":"https://doi.org/10.26599/frict.2025.9441064","url":null,"abstract":" <p>Superelastic NiTi alloys produced through laser powder bed fusion (LPBF) hold great promise in advancing wear-resistant transmission devices for aerospace and related applications. However, limited research on their wear behavior and strategies for enhancing wear resistance raises concerns about their future application prospects. In this study, a straightforward yet highly effective pre-strain treatment method is introduced, resulting in a nearly twofold improvement in the wear resistance of LPBF-fabricated NiTi alloys. This method prunes microstructure characteristics, influences the martensitic transformation process that improves cyclic compression superelasticity and transforms the distribution characteristics of adhesion stress acting on the indenter during wear processes, thereby effectively enhancing wear resistance. Additionally, the present study proposes an analytical model that establishes a link between superelastic metal cyclic compression characteristics and wear behaviors, providing insight into the wear characteristics, especially for adhesive wear patterns of superelastic metals including LPBF-fabricated NiTi alloys through analysis of cyclic compression curve. This research contributes to the fundamental understanding of wear resistance mechanisms in superelastic engineering materials and opens avenues for further optimization in related applications.</p> ","PeriodicalId":12442,"journal":{"name":"Friction","volume":"23 1","pages":""},"PeriodicalIF":6.8,"publicationDate":"2025-09-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145068168","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-09-12DOI: 10.26599/frict.2025.9441176
Weiye Li, Li Chen, Bin Zhang
Rubber is widely used as a crucial sealing material in aerospace, petrochemical, and automotive industries to prevent contaminants from entering enclosures and lubricants from leaking. However, severe wear and friction occur during sliding motion, which are major causes of seal failure and significantly impact the safety and service life of equipment. To enhance the wear resistance of rubber surfaces, diamond-like carbon (DLC) coatings have been extensively studied due to their low friction coefficient, high hardness, excellent wear resistance, and chemical inertness. The hardness, elasticity, and adhesion of the coating can be effectively controlled by adjusting deposition parameters. This allows the film to accommodate the deformation of the soft rubber substrate, preventing delamination while avoiding thermal degradation or damage to the rubber. Additionally, the chemical composition of carbon-based films, primarily consisting of carbon and hydrogen, exhibits good compatibility with rubber, ensuring strong interfacial adhesion.