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Understanding and misleading texture perception by rendering vibrational tactile stimuli 通过呈现振动触觉刺激来理解和误导纹理感知
IF 6.8 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2025-11-20 DOI: 10.26599/frict.2025.9441195
Livia Felicetti, Eric Chatelet, Francesco Massi

Among the mechanical stimuli that arise in the tactile interaction between finger and surface during the tactile exploration, stimulating the mechanoreceptors, Friction-Induced Vibrations (FIV) play a fundamental role for discriminating the surface textures. Although it is well known that vibrational tactile stimuli strongly depend on the characteristics of the explored textures, the correlation between the different FIV features (such as amplitude and spectral distribution) with the texture perception and discrimination is still an open field of research. A vibrotactile rendering device has been here used to replicate the FIV measured when exploring isotropic textures. A sensory campaign has been conducted on 10 participants to investigate their ability to discriminate real and rendered isotropic textures, while the reproduced FIV have been manipulated and altered to mislead tactile perception. By swapping the FIV amplitudes measured from real textures, it has been observed that the participants discriminated the samples consistently with the vibration amplitude. The campaign has allowed to correlate the FIV amplitude and their frequency distribution with the perceptual results of the discrimination campaigns on real and mimicked textures.

在触觉探索过程中,手指与表面之间的触觉相互作用产生的机械刺激中,摩擦诱发振动(frictional - induced vibration, FIV)对机械感受器的刺激起着识别表面纹理的重要作用。虽然振动触觉刺激强烈依赖于被探测纹理的特征,但不同FIV特征(如振幅和频谱分布)与纹理感知和识别之间的关系仍然是一个开放的研究领域。在探索各向同性纹理时,振动触觉渲染设备用于复制测量的FIV。我们对10名参与者进行了一项感官运动,以调查他们区分真实和渲染的各向同性纹理的能力,而复制的FIV已被操纵和改变以误导触觉感知。通过交换从真实纹理测量的FIV振幅,观察到参与者与振动振幅一致地区分样品。该运动允许将FIV振幅及其频率分布与真实和模拟纹理的区分运动的感知结果相关联。
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引用次数: 0
A novel PBO/PTFE-PI@M50 tribo-pair system: Achieving superior tribological performance under high-temperature extreme conditions 新型PBO/PTFE-PI@M50摩擦副系统:在高温极端条件下实现卓越的摩擦学性能
IF 6.8 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2025-11-17 DOI: 10.26599/frict.2025.9441193
Xinran Miao, Jiangkun Luo, Zirui Wang, Tianbao Ma

Self-lubricating fabric composites significantly enhance the tribological performance of joint bearings by minimizing friction and wear on both inner and outer rings, thereby substantially extending their operational lifespan. These characteristics make them excellent candidates for bearing liner materials. However, conventional PTFE/Nomex phenolic-based fabric composites exhibit limitations in high-temperature environments, necessitating the development of more thermally stable alternatives. To address this challenge, this study introduced a novel PBO/PTFE polyimide (PI)-based self-lubricating fabric composite and proposed a PBO/PTFE-PI@M50 tribo-pair system suitable for high-temperature working conditions, utilizing M50 bearing steel as the counterpart material. Compared to Nomex fiber-reinforced self-lubricating fabric composites, PBO/PTFE-40PI (fabric composites with resin mass fraction of 40%) demonstrated significantly superior high-strength and high-temperature tribological performance. Notably, even at 300℃, it maintained an elastic modulus of approximately 15 GPa and a tensile strength of around 335 MPa, while achieving a low friction coefficient of 0.023 and an impressively low wear rate of 0.83×10-6mm3/(N·m). The superior properties of PBO/PTFE-PI@M50 tribo-pair system stemmed from the composite's exceptional heat resistance and mechanical stability at high temperatures. Under the combined effects of the 'thermal-mechanical-chemical' interactions, the fiber-reinforced composite material formed a dense, uniform, and strongly stable transfer film on the surface of the M50 steel ring. Detailed analysis revealed that the film's stability primarily arose from the viscoelastic transition of PI and PTFE under high temperature, coupled with their strong tribo-chemical reactions with the steel ring. Given its outstanding performance, the PBO/PTFE-PI@M50 tribo-pair system holds considerable promise for advanced engineering applications.

自润滑织物复合材料通过最大限度地减少内外圈的摩擦和磨损,显着提高关节轴承的摩擦学性能,从而大大延长其使用寿命。这些特性使它们成为轴承衬套材料的优秀候选者。然而,传统的PTFE/Nomex酚醛基织物复合材料在高温环境中表现出局限性,因此需要开发更热稳定的替代品。为了解决这一挑战,本研究引入了一种新型的PBO/PTFE聚酰亚胺(PI)基自润滑织物复合材料,并提出了一种适用于高温工况的PBO/PTFE-PI@M50摩擦副系统,采用M50轴承钢作为对应材料。与Nomex纤维增强自润滑织物复合材料相比,PBO/PTFE-40PI(树脂质量分数为40%的织物复合材料)具有显著的高强高温摩擦学性能。值得注意的是,即使在300℃时,其弹性模量约为15 GPa,抗拉强度约为335 MPa,摩擦系数低至0.023,磨损率低至0.83×10-6mm3/(N·m)。PBO/PTFE-PI@M50摩擦副体系的优异性能源于该复合材料在高温下的优异耐热性和机械稳定性。在“热-机械-化学”相互作用的综合作用下,纤维增强复合材料在M50钢环表面形成致密、均匀、强稳定的转移膜。详细分析表明,薄膜的稳定性主要来自于PI和PTFE在高温下的粘弹性转变,以及它们与钢环的强烈摩擦化学反应。鉴于其出色的性能,PBO/PTFE-PI@M50摩擦副系统在高级工程应用中具有相当大的前景。
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引用次数: 0
Slippery liquid-infused porous surface with layered double hydroxides for enhanced corrosion and wear resistance of TC4 alloys 光滑的液体注入多孔表面,层状双氢氧化物,增强TC4合金的耐腐蚀性和耐磨性
IF 6.8 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2025-11-14 DOI: 10.26599/frict.2025.9441191
Xionggang Chen, Deke Li, Tianqi Wei, Zhiwei Chen, Haidong Wang, Danyan Zhan, Jinxia Huang, Zhiguang Guo

The poor wear performance and susceptibility to pitting corrosion of titanium alloys in practical applications have attracted increasing attention. Layered double hydroxides (LDH) coatings, with two-dimensional structure, have shown great potential in protecting metals from corrosion and wear. However, the dense oxide layer on titanium alloys has hindered the development of LDH on these materials. In this study, a ZnAl LDH coating was fabricated on the surface of TC4 alloy via an in situ growth method. Molybdic acid anions were subsequently incorporated into the LDH interlayer through an ion exchange process. Inspired by biomimetic principles, a UV-grafted PDMS-infused slippery surface was prepared based on the nanoporous structure of ZnAl LDH, resulting in a protective surface with excellent hydrophobicity, corrosion resistance, and wear resistance. The anti-corrosion performance of the surface was evaluated using Tafel polarization and electrochemical impedance spectroscopy (EIS). The results demonstrated excellent corrosion protection for the TC4 substrate, as indicated by a low corrosion current density of 2.34 × 10-7 A/cm². Compared with the bare TC4 alloy, the modified surface exhibited improved improved wear performance, owing to the infused silicone oil and ZnAl LDH nanosheets. This work not only provides valuable insights into the controllable in situ fabrication of LDH coatings but also offers a new strategy for the broader application of TC4 alloys and further research in the field of metal protection.

钛合金在实际应用中磨损性能差、易发生点蚀的问题日益引起人们的关注。层状双氢氧化物(LDH)涂层具有二维结构,在保护金属免受腐蚀和磨损方面显示出巨大的潜力。然而,钛合金表面致密的氧化层阻碍了LDH的发展。本研究采用原位生长法在TC4合金表面制备了ZnAl LDH涂层。钼酸阴离子随后通过离子交换过程并入LDH中间层。受仿生原理的启发,基于ZnAl LDH的纳米孔结构制备了uv接枝pdms注入的光滑表面,从而获得了具有优异疏水性、耐腐蚀性和耐磨性的保护表面。利用Tafel极化和电化学阻抗谱(EIS)对表面的防腐性能进行了评价。结果表明,TC4衬底具有良好的防腐性能,腐蚀电流密度为2.34 × 10-7 a /cm²。与裸露的TC4合金相比,由于注入硅油和ZnAl LDH纳米片,改性后的表面具有更好的耐磨性能。这项工作不仅为LDH涂层的可控原位制备提供了有价值的见解,而且为TC4合金的更广泛应用和进一步研究金属保护领域提供了新的策略。
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引用次数: 0
Simulated and measured characteristics for churning oil flow with a coating surface over a wide range of temperatures 模拟和测量了在宽温度范围内具有涂层表面的搅拌油流的特性
IF 6.8 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2025-11-14 DOI: 10.26599/frict.2025.9441192
Yi Liu, Chunhui Wei, Wei Wu, Le Cheng, Xi Wang, Jun Zhao

Gearbox efficiency is essential for the range of new energy vehicles. Most of energy in gearbox is consumed on the load-independent factor, e.g., churning loss, which however, has not been deeply addressed. In this study, load-independent losses are inhibited by oleophobic treatment to the surfaces of a transmission component. A polytetrafluoroethylene (PTFE) coating is prepared by electroless chemical plating. The contact angle (CA) and surface morphology of the coated surfaces are tested to elucidate the loss inhibition mechanism on the oleophobic interface. A visualized test rig for measuring the churning oil flow is built with the function of temperature control at a range of -30℃-80℃. Moving Particle Semi-implicit (MPS) method is used to further investigate the mechanism of oleophobic surface regulation. The oil velocity and pressure distributions, the slip characteristics and flow field around the coated surface are investigated. An analytical flow model is established to demonstrate the flow structure and to quantify the relationship with oil properties and surface characteristics. The results showed that the CA increased from 7.8° to 31.2° when the surface is coated by PTFE. The average reduction of the churning torque test values ranged from 20% to 36% across a wide temperature range of -30℃ to 80℃, with a maximum of 50.7% at 40℃. Simulated slip lengths ranged from 2.9 μm to 16.0 μm at different rotational velocities. The coating reduced the oil velocity and pressure, as well as the viscous shear and differential pressure resistance on the surface of the rotating component. This study thus provides scientific support for the efficiency improvement of gearboxes used in complex engineering.

变速箱效率对新能源汽车的续航里程至关重要。齿轮箱的大部分能量消耗在与负载无关的因素上,如搅拌损耗,但这一问题尚未得到深入解决。在这项研究中,负载无关的损耗被抑制的疏油处理的表面的传输组件。采用化学镀法制备了聚四氟乙烯(PTFE)涂层。测试了涂层表面的接触角和表面形貌,以阐明其在疏油界面上的缓蚀机理。搭建了一个具有-30℃-80℃温度控制功能的搅拌油流可视化测试平台。采用运动粒子半隐式(MPS)方法进一步研究了疏油表面调控的机理。研究了涂层表面油液的速度和压力分布、滑移特性和流场。建立了分析流动模型,以展示流动结构,并量化与油的性质和表面特征的关系。结果表明:表面涂覆PTFE后,CA由7.8°增加到31.2°;在-30 ~ 80℃的宽温度范围内,搅拌扭矩测试值的平均降低幅度为20% ~ 36%,在40℃时最大降低50.7%。不同转速下的滑移长度范围为2.9 ~ 16.0 μm。涂层降低了油的速度和压力,以及旋转部件表面的粘性剪切和压差阻力。为复杂工程中齿轮箱的效率改进提供了科学依据。
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引用次数: 0
Interfacial mechanical and tribochemical effects on friction mechanisms under air or vacuum conditions 在空气或真空条件下对摩擦机制的界面力学和摩擦化学效应
IF 6.8 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2025-10-28 DOI: 10.26599/frict.2025.9441056
Yuting Du, Fuchao Yang, Zhiguang Guo

Friction phenomena are strongly affected by interfacial mechanical and tribochemical effects, which involve major factors such as loads, sliding rates, sliding times, humidity, temperatures, and oxide films. For practical applications at different vacuum levels, friction mechanisms (adhesive wear, abrasive wear, fatigue wear, corrosive wear, and micromotor wear) are highly important for the development of advanced materials with desirable tribological properties to promote vacuum tribology. In this review, in combination with the current understanding of friction‒wear interactions, the tribological phenomena caused by changes in the surfaces of friction pairs that are highly dependent on complex conditions in different vacuum environments are analyzed and summarized. Subsequently, protection strategies for different structural materials are summarized. Finally, this work provides an outlook for designing advanced and sustainable protective materials under different vacuum conditions.

摩擦现象受到界面力学和摩擦化学效应的强烈影响,其中包括载荷、滑动速率、滑动时间、湿度、温度和氧化膜等主要因素。在不同真空水平下的实际应用中,摩擦机制(粘着磨损、磨料磨损、疲劳磨损、腐蚀磨损和微电机磨损)对于开发具有理想摩擦学性能的先进材料以促进真空摩擦学的发展非常重要。本文结合目前对摩擦磨损相互作用的认识,对不同真空环境下高度依赖于复杂条件的摩擦副表面变化引起的摩擦学现象进行了分析和总结。随后,总结了不同结构材料的防护策略。最后,展望了在不同真空条件下设计先进、可持续的防护材料的前景。
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引用次数: 0
Role of friction in tribofilm formation: Tribochemical evolution of proteins under AFM single-asperity friction 摩擦在摩擦膜形成中的作用:AFM单粗糙摩擦下蛋白质的摩擦化学演化
IF 6.8 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2025-10-28 DOI: 10.26599/frict.2025.9441073
Jiachen Chen, Heng Liu, Yu Yan

Recent studies have indicated that tribochemical reaction layers form on metal-on-metal-bearing surfaces, which may play a significant role in the performance and longevity of artificial joints. The purpose of this study was to determine the role of friction in the formation of tribofilms, and an in situ atomic force microscopy single-asperity sliding setup was used to perform in situ microscopic friction experiments to control the contact area and load. Time-of-flight secondary ion mass spectrometry and Raman spectroscopy were also employed to investigate changes in the composition and structure of the proteins at different sliding cycles. The results revealed that the proteins first unfolded under shear and then underwent chain breakage, dehydrogenation, and desulfurization over time as friction progressed. Finally, the carbonaceous fragments did not show graphitization trends under only shear stress.

近年来的研究表明,金属与金属接触面形成的摩擦化学反应层可能对人工关节的性能和寿命起重要作用。本研究的目的是确定摩擦在摩擦膜形成中的作用,并使用原位原子力显微镜单轴滑动装置进行原位微观摩擦实验,以控制接触面积和载荷。利用飞行时间二次离子质谱法和拉曼光谱法研究了不同滑动周期下蛋白质的组成和结构变化。结果表明,随着摩擦的增加,蛋白质首先在剪切下展开,然后随着时间的推移发生链断裂、脱氢和脱硫。最后,仅在剪切应力下,碳质碎屑未表现出石墨化趋势。
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引用次数: 0
Synergistic effect between h-BN and MoS2 for excellent lubrication of solid lubricant coating for high-temperature, open-air-system applications 氢氮化硼和二硫化钼之间的协同作用为高温露天系统应用的固体润滑剂涂层提供了良好的润滑
IF 6.8 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2025-10-28 DOI: 10.26599/frict.2025.9441067
Wenjuan Huai, Tianyi Han, Qingyuan Yu, Chenhui Zhang

High-temperature solid lubricant coatings with decent lubrication performance are essential in critical processes of metal forming and aerospace. However, their preparation is formidably challenging due to the harsh working conditions. Here, we successfully developed a solid lubricant coating via a facile and eco-friendly approach by casting a homogeneous mixture of molybdenum disulfide (MoS2) and hexagonal boron nitride (h-BN) as lubricants, silicate as the binder, and water as the solvent onto a titanium alloy substrate. This solid lubricant coating exhibited excellent and stable tribological properties with a very low coefficient of friction (COF) of 0.080 at 1,000 °C, yet in an open-air atmosphere. This superior lubrication behavior is attributed to the synergistic effect between the base lubricants h-BN and MoS2, contributing to the formation of a coating for both lubrication and lubricant protection against oxidation at 1,000 °C in an open-air environment. This work largely extends the operation temperature range of the crucial lubricant MoS2 in an open-air atmosphere and further sheds valuable light on the design of high-temperature solid lubricants via the synergistic effect between base lubricants.

高温固体润滑剂涂层具有良好的润滑性能,是金属成形和航空航天等关键工艺中必不可少的。然而,由于恶劣的工作条件,他们的准备工作非常具有挑战性。在这里,我们通过简单和环保的方法成功开发了固体润滑剂涂层,将二硫化钼(MoS2)和六方氮化硼(h-BN)的均匀混合物作为润滑剂,硅酸盐作为粘合剂,水作为溶剂浇铸到钛合金基体上。该固体润滑涂层在1000°C时具有非常低的摩擦系数(COF)(0.080),且在露天环境中具有优异而稳定的摩擦学性能。这种优异的润滑性能是由于基础润滑剂h-BN和MoS2之间的协同作用,有助于形成一层既润滑又抗氧化的涂层,在1000°C的露天环境中。这项工作在很大程度上扩展了关键润滑剂MoS2在露天环境中的工作温度范围,并通过基础润滑剂之间的协同效应进一步为高温固体润滑剂的设计提供了有价值的启示。
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引用次数: 0
Robust low friction mechanism of HNT–PVPA composite coating based on microviscosity regulation 基于微粘度调节的HNT-PVPA复合涂层鲁棒低摩擦机理研究
IF 6.8 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2025-10-28 DOI: 10.26599/frict.2025.9441084
Caixia Zhang, Ruishen Wang, Lihui Wang, Weihao Liang, Qiang Cheng, Yanhong Cheng, Congbin Yang, Zhifeng Liu

Reducing the coefficient of friction is a critical method for improving the service life and enhancing the efficiency of artificial implants. Maintaining a robust low-friction effect is essential for optimal artificial implant performance. This work utilizes the mechanism of the interaction between the interfacial charge and microviscosity to design a composite coating for titanium alloys modified with halloysite nanotubes/poly(vinylphosphonic acid) (PVPA). Compared with that of the pure PVPA coating, the coefficient of friction of the composite coating-polytetrafluoroethylene (PTFE) system stabilized at a low-friction state of approximately 0.008, with a 13.40% improvement in the load-bearing capacity. This low-friction state is maintained over a wide range of speeds and for extended periods. Furthermore, the study reveals that the electrical property differences between the inner and outer walls of halloysite nanotubes induce specific aggregation of anions and cations. These ions increase the microviscosity around the tube wall by forming hydrogen bonds with water molecules and attracting water molecules to form hydronium cations, contributing to the low-friction mechanism. The halloysite nanotube/PVPA composite coatings also enhance the toughness of the coating in the body fluid environment by stabilizing the crosslinked core region against perturbations from multivalent cations. The results provide a new approach for achieving low-friction composite polymer coatings with improved frictional properties in biotribology.

降低摩擦系数是提高人工种植体使用寿命和效率的关键方法。维持一个强大的低摩擦效果是必不可少的最佳人工种植性能。本工作利用界面电荷与微粘度之间的相互作用机制,设计了一种高岭土纳米管/聚乙烯基膦酸(PVPA)改性钛合金的复合涂层。与纯PVPA涂层相比,复合涂层-聚四氟乙烯(PTFE)体系的摩擦系数稳定在约0.008的低摩擦状态,承载能力提高13.40%。这种低摩擦状态可以在大范围的速度和较长的时间内保持。此外,研究还揭示了高岭土纳米管内外壁的电学性质差异诱导了阴离子和阳离子的特异性聚集。这些离子通过与水分子形成氢键,并吸引水分子形成水合氢离子,从而增加管壁周围的微粘度,有助于实现低摩擦机制。高岭土纳米管/PVPA复合涂层还通过稳定交联核心区以抵抗多价阳离子的扰动,提高了涂层在体液环境中的韧性。研究结果为生物摩擦学领域实现具有良好摩擦性能的低摩擦复合聚合物涂层提供了新的途径。
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引用次数: 0
A 2.5D peridynamic model for turnout rail crack propagation under wheel rolling contact action 车轮滚动接触作用下道岔钢轨裂纹扩展的2.5维动力学模型
IF 6.8 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2025-10-17 DOI: 10.26599/frict.2025.9441072
Xiaochuan Ma, Xianghe Wang, Linya Liu, Weibin Yin, Yajie Wang, Qi Zeng

Based on the ordinary state-based peridynamics (OSB PD) theory, a 2.5-dimensional (2.5D) PD model for rail crack propagation in railway turnouts was proposed. First, a two-dimensional (2D) model for rail crack propagation in railway turnouts was constructed, with two types of 2.5D additional constraints for crack opening and cross section proposed on the basis of the 2D model. The 2.5D PD model for rail crack propagation in railway turnouts could thus be established. A fatigue crack propagation experiment was subsequently carried out on the U71Mn turnout rail material. The bond fatigue failure condition of the turnout rail material was established on the basis of the experimental results. Finally, the accuracy of the structural deformation and bond fatigue failure conditions was verified. The simulation results for rail crack propagation were compared with field observations and then analyzed in detail. These results show that the proposed 2.5D PD model can be used to accurately simulate the characteristics and rules for rail crack propagation in railway turnouts.

基于普通状态周动力理论,提出了钢轨裂纹扩展的2.5维(2.5D)周动力模型。首先,建立了道岔中钢轨裂纹扩展的二维模型,并在此基础上提出了裂纹张开和截面的两种2.5D附加约束。由此可以建立钢轨裂纹扩展的2.5D PD模型。随后对U71Mn道岔钢轨材料进行了疲劳裂纹扩展试验。在试验结果的基础上,建立了道岔钢轨材料粘结疲劳破坏条件。最后,验证了结构变形和粘结层疲劳破坏条件的准确性。将钢轨裂纹扩展的模拟结果与现场观测结果进行了比较,并进行了详细分析。结果表明,所建立的2.5D PD模型能够较准确地模拟道岔裂纹扩展的特征和规律。
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引用次数: 0
N-doped carbon dots based nano-composite coatings with ultra-low coefficient of friction and superior corrosion resistance 氮掺杂碳点基纳米复合涂层具有超低摩擦系数和优异的耐腐蚀性能
IF 6.8 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2025-10-15 DOI: 10.26599/frict.2025.9441187
Guangkai Jin, Shenghua Xue, Bokun Zhao, Yixin Wang, Shujuan Liu, Qian Ye, Feng Zhou

Carbon dots (CDs) are widely recognized for their superior adsorption and film-forming capabilities on metallic surfaces, making them effective as liquid lubricant additives and corrosion inhibitors. However, their applications in solid lubricating and organic anti-corrosion coatings have been less reported. In this study, nitrogen-doped CDs (N-CDs) with a polymer-carbon core hybrid structure are synthesized via a facile aldol condensation of acetaldehyde and urea. The incorporation of these N-CDs as additives into waterborne epoxy (WEP) coatings enhances interfacial compatibility, resulting in remarkable improvements in lubricating performance and corrosion resistance. Compared to the pure WEP coating, the N-CDs based nano-composite coating (WEP(PDMS)@N-CDs) demonstrates a dramatic reduction in the coefficient of friction from 0.760 to 0.049, representing a 93.6% decrease. Additionally, the WEP(PDMS)@N-CDs coating exhibits exceptional corrosion resistance, as evidenced by a stable low-frequency impedance modulus of │z│0.01 Hz=3.5×107 Ω cm2. These improvements are primarily attributed to the abundant polymer branched chains on the N-CDs surface, which effectively increase the cross-linking density of the WEP polymer. The resulting WEP(PDMS)@N-CDs coating not only facilitates dynamic repair during friction but also enhances the barrier effect of the coating, leading to significantly improved anti-wear and corrosion resistance.

碳点(cd)因其在金属表面的优异吸附和成膜能力而被广泛认可,使其成为有效的液体润滑剂添加剂和缓蚀剂。然而,它们在固体润滑和有机防腐涂层中的应用报道较少。在这项研究中,氮掺杂CDs (N-CDs)具有聚合物-碳核心杂化结构,通过乙醛和尿素的易醛缩合合成。将这些N-CDs作为添加剂加入水性环氧树脂(WEP)涂层中,增强了界面相容性,从而显著改善了润滑性能和耐腐蚀性。与纯WEP涂层相比,N-CDs基纳米复合涂层(WEP(PDMS)@N-CDs)的摩擦系数从0.760降低到0.049,降低了93.6%。此外,WEP(PDMS)@N-CDs涂层表现出优异的耐腐蚀性,其稳定的低频阻抗模量为│z│0.01 Hz=3.5×107 Ω cm2。这些改进主要归功于N-CDs表面丰富的聚合物支链,有效地增加了WEP聚合物的交联密度。所得WEP(PDMS)@N-CDs涂层不仅有利于摩擦过程中的动态修复,还增强了涂层的阻隔效应,从而显著提高了抗磨性和耐腐蚀性。
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引用次数: 0
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