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Impact of salt erosion on mechanical and drying shrinkage performance of cement stabilized macadam 盐侵蚀对水泥稳定碎石路面机械和干燥收缩性能的影响
IF 3.2 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-08-14 DOI: 10.3389/fmats.2024.1453768
Chengbin Wang, Yadi Chen, Baoping An, Qinglin Guo, Yibo Wang
The arch expansion damage of asphalt pavement is a typical disease in desert Gobi and saline-alkali areas, and the reasons for arch expansion are very complex. Exploring the impact of salt solution on the mechanical and drying shrinkage performances of cement-stabilized macadam helps to clarify the causes of the arch expansion damage. To this purpose, this paper designed a salt solution infiltration experiment, using salt solution infiltration to simulate the transmission and accumulation of salts in cement-stabilized macadam, and carried out the compressive and flexural tests of cement-stabilized mortar and cement-stabilized macadam, and measured the drying shrinkage performance of cement-stabilized mortar and macadam. The results show that the type of salt solution has a significant influence on the weight of the cement-stabilized mortar samples, sulfates will cause the samples to lose weight, while chlorides and mixed solutions cause the increase in weight. Chlorides and sulfates lead to the decrease in the strengths of cement-stabilized mortar and macadam. The salt crystallization will lead to the decline of the drying shrinkage strains of cement-stabilized mortar and macadam, which has a positive action for reducing the drying shrinkage deformation. However, under the combined action of chlorides and sulfates, cement-stabilized macadam expands with the moisture loss. This may be one of the important causes of the arch expansion of asphalt pavement in the Gobi area and saline-alkali area.
沥青路面的拱胀破坏是沙漠戈壁和盐碱地区的典型病害,拱胀的原因非常复杂。探讨盐溶液对水泥稳定碎石路面力学性能和干燥收缩性能的影响,有助于弄清拱胀破坏的原因。为此,本文设计了盐溶液渗透实验,利用盐溶液渗透模拟盐分在水泥稳定金刚砂中的传递和积累,并对水泥稳定砂浆和水泥稳定金刚砂进行了抗压和抗折试验,测定了水泥稳定砂浆和金刚砂的干燥收缩性能。结果表明,盐溶液的类型对水泥稳定砂浆样品的重量有很大影响,硫酸盐会导致样品重量减轻,而氯化物和混合溶液则会导致样品重量增加。氯化物和硫酸盐会导致水泥稳定砂浆和金刚砂强度降低。盐的结晶会导致水泥稳定砂浆和金刚砂的干燥收缩应变下降,这对减少干燥收缩变形有积极作用。然而,在氯化物和硫酸盐的共同作用下,水泥稳定的金刚砂会随着水分的流失而膨胀。这可能是戈壁地区和盐碱地区沥青路面拱胀的重要原因之一。
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引用次数: 0
Ferroelastic twin walls for neuromorphic device applications 用于神经形态设备应用的铁弹性孪生壁
IF 3.2 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-08-14 DOI: 10.3389/fmats.2024.1406853
Guangming Lu, Ekhard K. H. Salje
The possibility to use ferroelastic materials as components of neuromorphic devices is discussed. They can be used as local memristors with the advantage that ionic transport is constraint to twin boundaries where ionic diffusion is much faster than in the bulk and does not leak into adjacent domains. It is shown that nano-scale ferroelastic memristors can contain a multitude of domain walls. These domain walls interact by strain fields where the interactions near surfaces are fundamentally different from bulk materials. We show that surface relaxations (∼image forces) are curtailed to short range dipolar interactions which decay as 1/d2 where d is the distance between domain walls. In bigger samples such interactions are long ranging with 1/d. The cross-over regime is typically in the range of some 200–1500 nm using a simple spring interaction model.
本文讨论了将铁弹性材料用作神经形态设备元件的可能性。铁弹性材料可用作局部忆阻器,其优势在于离子传输受限于孪生边界,离子扩散速度远快于体态,且不会泄漏到相邻畴中。研究表明,纳米级铁弹性忆阻器可以包含大量畴壁。这些畴壁通过应变场相互作用,其中表面附近的相互作用与块体材料有本质区别。我们的研究表明,表面弛豫(∼图像力)被限制为短程偶极相互作用,其衰减为 1/d2,其中 d 是域壁之间的距离。在较大的样品中,这种相互作用是长程的,衰减为 1/d。使用简单的弹簧相互作用模型,交叉机制通常在大约 200-1500 nm 的范围内。
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引用次数: 0
Study on the strength characteristics and micro-mechanism of modified solidified red mud 改性固化赤泥的强度特性和微观机理研究
IF 3.2 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-08-14 DOI: 10.3389/fmats.2024.1461198
Ziyi Ding, Yu Cheng, Lu Jin, Wentong Wang, Shiying Yan
The residue generated during the production process of alumina, known as red mud, is a type of solid waste. The engineering properties of red mud can be significantly enhanced through the modification and solidification using inorganic materials. This study primarily utilized red mud as the raw material, supplemented with fly ash, lime, and clay, to conduct a solidification experiment of red mud. Orthogonal tests with three factors of two ash ratio (ratio of lime to fly ash), two ash content (total lime and fly ash), and red mud types were designed to study the changes of different ratios and maintenance conditions, etc., on the engineering properties of red mud. In addition, the micro-mechanisms of modified red mud were investigated by means of XRF, XRD, SEM and EDX. The results show that for optimum moisture content, red mud types are the most important influencing factor and for maximum dry density, two ash content is the most important influencing factor. For strength characteristics, the optimum two ash ratio was 1.5:1, the optimum two ash content was 50%, and the optimum red mud types were 70% CRM (red mud made of Chalco Shandong Co., Ltd) mixed with 30% clay. The addition of lime, fly ash, and clay improves the temperature shrinkage coefficient of the red mud. Through the analysis of microscopic composition and structure, it can be seen that goethite (α-FeO(OH)) and magnetite (γ-Fe2O3) in the red mud reacted with the modified materials to generate crystalline aluminosilicate and amorphous hydrated silicate gel, and these products together with the original calcium carbonate (CaCO3), tricalcium aluminate (Ca3Al2O6) and garnet (Ca3TiFeSi3O12) in the red mud which have certain strengths enhance the structural strength of the modified red mud. The optimum ratio obtained from the combined test results was lime: fly ash: CRM = 30:20:50. Therefore, using lime, fly ash and clay as modified materials can greatly enhance the engineering properties of red mud and realise the resourceful use of red mud.
氧化铝生产过程中产生的残渣称为赤泥,是一种固体废物。通过使用无机材料对赤泥进行改性和固化,可以显著提高赤泥的工程特性。本研究主要以赤泥为原料,辅以粉煤灰、石灰和粘土,对赤泥进行固化实验。设计了两灰比(石灰和粉煤灰的比例)、两灰含量(石灰和粉煤灰的总量)和赤泥类型三个因素的正交试验,研究不同比例和养护条件等对赤泥工程性质的变化。此外,还通过 XRF、XRD、SEM 和 EDX 等方法研究了改性赤泥的微观机理。结果表明,对于最佳含水量,赤泥类型是最重要的影响因素;对于最大干密度,二灰含量是最重要的影响因素。在强度特性方面,最佳二灰比为 1.5:1,最佳二灰含量为 50%,最佳赤泥类型为 70%的 CRM(中铝山东有限公司生产的赤泥)与 30%的粘土混合。石灰、粉煤灰和粘土的添加提高了赤泥的温度收缩系数。通过对微观成分和结构的分析,可以看出赤泥中的鹅铁矿(α-FeO(OH))和磁铁矿(γ-Fe2O3)与改性材料反应生成结晶铝硅酸盐和无定形水合硅酸盐凝胶、这些产物与赤泥中原有的具有一定强度的碳酸钙(CaCO3)、铝酸三钙(Ca3Al2O6)和石榴石(Ca3TiFeSi3O12)一起增强了改性赤泥的结构强度。综合试验结果得出的最佳配比为石灰:粉煤灰:CRM=30:20:50。因此,使用石灰、粉煤灰和粘土作为改性材料,可大大提高赤泥的工程性能,实现赤泥的资源化利用。
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引用次数: 0
Advances in the study of AIE polymers AIE 聚合物研究的进展
IF 3.2 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-08-14 DOI: 10.3389/fmats.2024.1446307
Yiran Pei, Leixin Liu, Xinfeng Cao, Jian Zhou, Cuiyun Liu
Aggregation-induced emission (AIE) can exhibit different properties in different situations, such as non-emission and highly fluorescent in the dissolved state of the molecule and in the aggregate or solid state, respectively. This property of AIE is distinguished from aggregation-induced quenching (ACQ) or even the opposite. Combining the AIE phenomenon with different polymers yields different polymers with corresponding AIE properties. In this paper, the mechanism, synthesis, branching and application of AIE in the fields of optoelectronic functional materials, sensors, biology, and environment are reviewed. It is hoped that this review will stimulate more research on molecular aggregates and promote further cross-fertilisation and greater development in the disciplines of materials, chemistry and biomedicine.
聚集诱导发射(AIE)在不同的情况下会表现出不同的性质,例如在分子溶解状态和聚集状态或固体状态下分别表现为不发射和高荧光。AIE 的这种特性有别于聚集诱导淬灭(ACQ),甚至相反。将 AIE 现象与不同的聚合物相结合,可以得到具有相应 AIE 特性的不同聚合物。本文综述了 AIE 的机理、合成、分支以及在光电功能材料、传感器、生物和环境领域的应用。希望这篇综述能激发更多关于分子聚合体的研究,促进材料、化学和生物医学学科的进一步交叉融合和更大发展。
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引用次数: 0
A review on the auxetic mechanical metamaterials and their applications in the field of applied engineering 辅助机械超材料及其在应用工程领域的应用综述
IF 3.2 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-08-06 DOI: 10.3389/fmats.2024.1453905
Volha Siniauskaya, Hao Wang, Yadong Liu, Yuhang Chen, Michael Zhuravkov, Yongtao Lyu
Metamaterials are artificially created materials or structures with properties not found in nature. They encompass electromagnetic, acoustic, and mechanical metamaterials, which are particularly significant in applied engineering. Mechanical metamaterials exhibit unique mechanical properties such as vanishing shear modulus, negative Poisson’s ratio, negative compressibility, etc. This paper reviews the most commonly used mechanical metamaterials and discusses their applications in the field of applied engineering, specifically in vibration isolation, energy absorption, and vibration reduction. The prospects for future developments in this field are also presented.
超材料是人工制造的材料或结构,具有自然界所没有的特性。超材料包括电磁超材料、声学超材料和机械超材料,它们在应用工程中尤为重要。机械超材料具有独特的机械特性,如剪切模量消失、负泊松比、负可压缩性等。本文回顾了最常用的机械超材料,并讨论了它们在应用工程领域的应用,特别是在隔振、吸能和减振方面的应用。本文还介绍了该领域的未来发展前景。
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引用次数: 0
Research on mechanical properties of steel-polypropylene fiber concrete and application of beam structure 钢-聚丙烯纤维混凝土力学性能研究及在梁结构中的应用
IF 3.2 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-08-06 DOI: 10.3389/fmats.2024.1440466
Jiuyang Li, Jingwei Luo, Li Chen, Xinmei Fan, Yuepeng Zhu, Xiaoyu Wang, Jingpeng Guo
Concrete faces the difficulties of low tensile strength and poor crack resistance in building structures. In order to remedy this deficiency. In this paper, steel-polypropylene hybrid fiber reinforced concrete (SPFRC) was prepared by adding steel fiber (SF) and three kinds of polypropylene fiber (PF) to C50-grade concrete. The mechanical properties and microstructure of SPFRC were studied with different fiber combinations and content, obtaining the best hybrid combination. Based on this, the bending resistance and cracking of SPFRC beam members were investigated. The results demonstrate that the addition of fiber improves the compressive strength of ordinary concrete by 0.16% ∼ 17.69%, the splitting tensile strength by 15.18% ∼ 47.45%, and the bending strength by 3.54% ∼ 26.77%. Compared with single-fiber concrete, the hybrid fiber can achieve better internal microstructure, which further enhances the mechanical properties of the material. Hybrid fibers overlap within concrete beams, effectively redistributing stress and inhibiting the formation and propagation of cracks. For the three types of SPFRC beams, the cracking load is increased by 14.29% ∼ 28.57% compared with PC beam, the ultimate bearing capacity is increased by 9.68% ∼ 19.35%. The optimal dosage is determined as 1.0% SF, 0.6% Embossed polypropylene fiber (PBF). It provides reference for the application of SPFRC in flexural members.
混凝土在建筑结构中面临着抗拉强度低和抗裂性能差的难题。为了弥补这一不足。本文在 C50 级混凝土中加入钢纤维(SF)和三种聚丙烯纤维(PF),制备了钢-聚丙烯混合纤维增强混凝土(SPFRC)。研究了不同纤维组合和含量下 SPFRC 的力学性能和微观结构,获得了最佳混合组合。在此基础上,研究了 SPFRC 梁构件的抗弯强度和开裂情况。结果表明,添加纤维后,普通混凝土的抗压强度提高了 0.16% ~ 17.69%,劈裂抗拉强度提高了 15.18% ~ 47.45%,抗弯强度提高了 3.54% ~ 26.77%。与单纤维混凝土相比,混合纤维能获得更好的内部微观结构,从而进一步提高材料的力学性能。混合纤维在混凝土梁内重叠,可有效地重新分配应力,抑制裂缝的形成和扩展。与 PC 梁相比,三种 SPFRC 梁的开裂荷载增加了 14.29% ~ 28.57%,极限承载力增加了 9.68% ~ 19.35%。最佳掺量确定为 1.0% SF,0.6% 压花聚丙烯纤维(PBF)。它为 SPFRC 在抗弯构件中的应用提供了参考。
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引用次数: 0
Preparation and property study of sawdust-modified cement mortar 锯末改性水泥砂浆的制备和性能研究
IF 3.2 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-08-06 DOI: 10.3389/fmats.2024.1457167
Yu Cheng, Jiatao Liu, Wentong Wang, Lu Jin, Shiying Yan
Sawdust, a solid waste generated during stone processing, poses a serious threat to the environment with its untreated accumulation. This paper first analyzes the chemical composition and physical properties of sawdust, and discusses its mechanism of action in cement mortar. By systematically optimizing the blending ratio and modification method of sawdust, the sawdust-modified cement mortar with excellent performance was prepared. This study evaluates the key performance indicators of sawdust-modified cement mortar, such as compressive strength, flexural strength, and durability, through a series of experiments. The experimental results indicate that the incorporation of an appropriate amount of sawdust significantly enhances the mechanical properties of cement mortar, while also improving its durability, particularly in terms of freeze-thaw resistance. Microstructural analysis reveals the mechanism by which sawdust improves the pore structure of cement mortar; the active components in the sawdust react with the hydration products of cement, resulting in the formation of crystalline structures with higher strength.Therefore, the use of sawdust as a modifier in cement mortar can improve its mechanical properties and durability, while simultaneously reducing the accumulation of solid waste and promoting the sustainable development of building materials.
锯末是石材加工过程中产生的一种固体废物,未经处理的堆积会对环境造成严重威胁。本文首先分析了锯末的化学成分和物理性质,并探讨了锯末在水泥砂浆中的作用机理。通过系统优化锯末的掺入比例和改性方法,制备出性能优异的锯末改性水泥砂浆。本研究通过一系列实验对锯末改性水泥砂浆的抗压强度、抗折强度和耐久性等主要性能指标进行了评价。实验结果表明,掺入适量锯末可显著提高水泥砂浆的力学性能,同时还能改善其耐久性,尤其是抗冻融性。微观结构分析揭示了锯末改善水泥砂浆孔隙结构的机理;锯末中的活性成分与水泥的水化产物发生反应,形成强度更高的结晶结构。因此,在水泥砂浆中使用锯末作为改性剂,可以改善水泥砂浆的力学性能和耐久性,同时减少固体废弃物的积累,促进建筑材料的可持续发展。
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引用次数: 0
Reviewing the progress of corrosion fatigue research on marine structures 海洋结构腐蚀疲劳研究进展回顾
IF 3.2 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-08-05 DOI: 10.3389/fmats.2024.1399292
Yuefu Yang, Chaohe Chen, Yifeng Zhuang, Zhijia Suo
This paper reviews the state-of-the-art progress of research into corrosion fatigue on marine structures, both theoretical and experimental. This includes corrosion fatigue life prediction models/methods, load–environment interaction/coupling test methods, accelerated corrosion methods in corrosion fatigue testing, fatigue crack measurement, and corrosion fatigue life assessment in the whole life period. To date, some theoretical models and methods for predicting the corrosion fatigue life of metallic materials or structures have been proposed and applied. Meanwhile, load–environment interaction/coupling testing on metallic material specimens has been maturely developed and widely applied. Some newly developed corrosion fatigue theoretical and experimental methods, based on data-driven machine learning and at-sea monitoring, have received preliminary application. This review of accelerated corrosion methods, fatigue crack measurement methods, and corrosion fatigue life assessment for marine structures in the whole-life period has been undertaken by extensive reference to relevant studies conducted worldwide. Challenges and recommendations for further developing and improving corrosion fatigue assessment methods and test techniques are also reported and discussed.
本文从理论和实验两方面回顾了海洋结构腐蚀疲劳研究的最新进展。其中包括腐蚀疲劳寿命预测模型/方法、载荷-环境相互作用/耦合试验方法、腐蚀疲劳试验中的加速腐蚀方法、疲劳裂纹测量以及全寿命期腐蚀疲劳寿命评估。迄今为止,已经提出并应用了一些预测金属材料或结构腐蚀疲劳寿命的理论模型和方法。同时,在金属材料试样上进行载荷-环境相互作用/耦合测试也已发展成熟并得到广泛应用。一些新开发的基于数据驱动的机器学习和海上监测的腐蚀疲劳理论和实验方法已得到初步应用。本综述对加速腐蚀方法、疲劳裂纹测量方法以及全寿命期海洋结构腐蚀疲劳寿命评估进行了综述,并广泛参考了世界各地开展的相关研究。此外,还报告和讨论了进一步开发和改进腐蚀疲劳评估方法和测试技术的挑战和建议。
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引用次数: 0
Mesoscopic numerical simulation of chloride diffusion behavior in cracked recycled aggregate concrete 裂缝再生骨料混凝土中氯离子扩散行为的介观数值模拟
IF 3.2 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-08-05 DOI: 10.3389/fmats.2024.1441220
Jing Liu
The cracking of recycled aggregate concrete (RAC) is well known to promotes the chloride diffusion, accelerates the corrosion of reinforcement embedded in RAC. To reveal the mechanism of chloride diffusion in RAC under cracking, a multiphase mesoscopic model for chloride diffusion in RAC was proposed. It should be noted that RAC is regarded as eight-phase composite materials consisting of coarse aggregate, reinforcement, new and old mortar, new and old interface transition zones (ITZ), cracks, and damage zones. The effects of the width and depth of cracks and damage zones on chloride diffusion behavior in RAC after cracking were further investigated. The numerical simulation results show that the damage zones accelerate the chloride diffusion and exacerbates the accumulation effect of chloride at the crack tip. Compared to the crack depth, the crack width of RAC has a small effect on chloride diffusion behavior, especially, the crack width is less than 50 µm. More importantly, the chloride diffusion streamline generated by numerical simulation reveals the mechanism of cracks promoting chloride diffusion. The research in this paper provides new insights into the durability design of RAC by revealing the diffusion behavior of chloride ions in RAC.
众所周知,再生骨料混凝土(RAC)的开裂会促进氯离子的扩散,加速 RAC 中预埋钢筋的腐蚀。为揭示开裂情况下氯离子在 RAC 中的扩散机理,提出了氯离子在 RAC 中扩散的多相介观模型。需要指出的是,RAC 被视为由粗骨料、钢筋、新旧砂浆、新旧界面过渡区(ITZ)、裂缝和损伤区组成的八相复合材料。进一步研究了裂缝和损伤区的宽度和深度对开裂后 RAC 中氯离子扩散行为的影响。数值模拟结果表明,损伤区加速了氯化物的扩散,加剧了氯化物在裂缝尖端的累积效应。与裂纹深度相比,RAC 的裂纹宽度对氯化物扩散行为的影响较小,尤其是裂纹宽度小于 50 µm。更重要的是,数值模拟产生的氯化物扩散流线揭示了裂纹促进氯化物扩散的机理。本文的研究通过揭示氯离子在 RAC 中的扩散行为,为 RAC 的耐久性设计提供了新的见解。
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引用次数: 0
Design and performance evaluation of a compact radiation absorber for 5G applications 面向 5G 应用的紧凑型辐射吸收器的设计与性能评估
IF 3.2 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-07-31 DOI: 10.3389/fmats.2024.1428912
Imran Khan, Asma Alshehri, Pi-Chung Wang, Ibrahim A. Hameed
Introduction: The emergence of electromagnetic wave pollution as a new form of pollution in human society is attributed to the advancements in communication technology and the electronic information business. In addition to harming priceless electronic equipment, these electromagnetic radiation and interference issues brought on by electrical and electronic devices have a major negative influence on human productivity and wellbeing. The secret to getting rid of electromagnetic radiation interference (EMI) and improving performance is electromagnetic shielding technology. Metamaterial absorber is a type of metamaterial that absorb EMI radiation. The benefits of metamaterial absorbers include their lightweight, simple construction, and excellent absorptivity.Methods: This paper proposes a novel metamaterial absorber for EMI radiation absorption. It consists of dielectric layers, metamaterial shielding layer and transmission line. The reflection of radiation is reduced by miniaturization of metamaterials.Results and Discussion: Simulation results show that the proposed design has better performance as compared to existing methods. The operating frequency range is from 23.1 to 28.3 GHz. The values of S21 with and without shielding are −5 dB and −0.05 dB, and the shielding effectiveness is 10.10 dB and a maximum of 12.63 dB.
引言电磁波污染作为一种新的污染形式出现在人类社会,其原因在于通信技术和电子信息业务的发展。这些电气和电子设备带来的电磁辐射和干扰问题除了会损害无价的电子设备外,还会对人类的生产力和福祉产生重大的负面影响。消除电磁辐射干扰(EMI)和提高性能的秘诀就是电磁屏蔽技术。超材料吸收器是一种能吸收 EMI 辐射的超材料。超材料吸波材料的优点是重量轻、结构简单、吸波性能优异:本文提出了一种用于吸收 EMI 辐射的新型超材料吸收器。它由介电层、超材料屏蔽层和传输线组成。结果与讨论:仿真结果表明,本文提出的超材料吸收器具有良好的电磁干扰辐射吸收能力:仿真结果表明,与现有方法相比,拟议设计具有更好的性能。工作频率范围为 23.1 至 28.3 千兆赫。有屏蔽和无屏蔽的 S21 值分别为 -5 dB 和 -0.05 dB,屏蔽效果为 10.10 dB,最大值为 12.63 dB。
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引用次数: 0
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