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Genetic types, mineralization styles, and geodynamic drive of uranium deposits in the South China Block 华南地块铀矿床成因类型、成矿样式及地球动力学驱动
IF 8.9 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-12-21 DOI: 10.1016/j.gsf.2025.102241
Jie Yan , Qingfei Wang , Fei Xia , Jiayong Pan , Fujun Zhong , Renyu Zeng , Zhibai Chen , Chaogui Hu , Chengbiao Leng , Mingxing Ling
The South China Block (SCB) is recognized as one of the most significant uranium deposit clusters in the world, characterized by its complex genetic types and geodynamic drives. Based on host rocks, uranium deposits in the SCB can be categorized into three primary types, exhibiting a trend from black shale-related deposits in the west, to granite-related, and ultimately to volcanic-related deposits toward the eastern margin of the SCB. We identify that three types of deposits are primarily distributed within or along margins of ancient crustal domains. Geochronological data reveals large-scale uranium mineralization occurred predominantly during Cretaceous and Paleogene periods. Uranium mineralization was mainly controlled by structures in the extensional setting, developed particularly at subsidiary faults, lithological (unconformity, intrusion contacts) and physicochemical interfaces. Uranium mineralization is dominantly characterized by medium to low ore-forming temperature with pitchblende as the main industrial mineral, and with silicification, carbonatization, hematitization, fluoritization and chloritization as common alteration. Isotopic studies show that sulfur sourced from host rocks, while carbon isotopes distinguish mantle-derived signatures in granite- and volcanic-related deposits from primarily sedimentary organic matter sources in black shale-related deposit. Uranium was mainly contributed by host rocks which are relatively U-fertile geological formations. Magmatic and/or mantle-derived mineralizing agents promote the activation and migration of uranium in host rocks, and accelerate the accumulation of U in ore-forming fluids. Our study suggests that the coupling of shallow and deep-seated energy and conduit system within a crustal extension setting, together with the pre-enrichment of uranium in basement and host rocks, controlled the formation of uranium deposits in the SCB.
华南地块以其复杂的成因类型和地球动力学驱动为特征,是世界上最重要的铀矿床群之一。根据铀矿床的寄主岩类型,可将南海东部铀矿床划分为3种主要类型,呈现出从西部的黑色页岩型铀矿床到东部边缘的花岗岩型铀矿床,最后向东部边缘的火山型铀矿床发展的趋势。我们发现三种类型的矿床主要分布在古地壳域内或沿边缘。地质年代学资料显示,大规模铀矿化主要发生在白垩纪和古近纪。铀矿化主要受伸展构造控制,主要发育于次级断裂、岩性(不整合面、侵入接触面)和物化界面。铀矿化以中低成矿温度为主要特征,以沥青铀矿为主要工业矿物,常见蚀变为硅化、碳化、赤铁矿、氟矿化和绿泥矿化。同位素研究表明,硫来自寄主岩,而碳同位素区分花岗岩和火山相关矿床的幔源特征与黑色页岩相关矿床的主要沉积有机质来源。铀矿主要由含铀量相对丰富的寄主岩贡献。岩浆和(或)幔源矿化剂促进了铀在宿主岩中的活化和迁移,加速了铀在成矿流体中的富集。研究认为,地壳伸展背景下的深、浅能量耦合和管道系统,以及基底和寄主岩中铀的预富集控制了南海铀矿床的形成。
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引用次数: 0
Harnessing LoRa for real-time landslide monitoring and early alerts in Kerala’s terrain 利用LoRa进行喀拉拉邦地形的实时滑坡监测和预警
IF 8.9 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-12-21 DOI: 10.1016/j.gsf.2025.102242
R. Amirthavarshini , A.I. Mohamed Shamil , P.S. Aswin Raaj , G. Kanimozhi
Landslides trigger high loss of life, damage to property and infrastructure, particularly in sensitive terrains like Kerala, India. Real-time monitoring and forecasting remain difficult due to rugged topography and low connectivity in remote terrain. The current work depicts a low-power, long-range IoT framework for monitoring applications utilizing LoRaWAN for data transmission and machine learning for forecasting. Soil moisture, accelerometer–gyroscope (MPU6050), humidity (DHT22), and simulated piezometer sensor nodes periodically store important slope-stability parameters. The sensed data are transmitted across LoRa to a base hub where the site-specific machine learning program analyzes the data in real time. Experimental results reveal soil moisture increasing from 2% to 10%, humidity from 89.8% to 91.5%, pore water pressure from 0.2 kPa to 0.5 kPa, and fluctuating accelerometer during simulated slope failure—variables closely related to landslide initiating factors. Machine learning outcomes reveal the ExtraTrees Classifier obtained 87.0% accuracy and gave the best results relative to different algorithms. The system provides automatic SOS messages to the Geological Survey of India (GSI) and executes site-based alarms for communities at risk. In comparison with the current GSM or satellite-based systems, the presented method provides longer-range communications and reduced energy consumption, along with quicker responses. The work presents a field-applicable and scalable solution for landslide risk management and disaster preparedness applications.
山体滑坡会造成巨大的生命损失、财产损失和基础设施破坏,尤其是在印度喀拉拉邦这样的敏感地区。由于崎岖的地形和偏远地区的低连通性,实时监测和预测仍然很困难。目前的工作描述了一个低功耗、远程物联网框架,用于监控应用程序,利用LoRaWAN进行数据传输和机器学习进行预测。土壤湿度、加速度计-陀螺仪(MPU6050)、湿度(DHT22)和模拟的压力计传感器节点定期存储重要的边坡稳定性参数。感知到的数据通过LoRa传输到一个基础集线器,在那里特定站点的机器学习程序实时分析数据。试验结果表明,在模拟边坡破坏过程中,土壤湿度从2%增加到10%,湿度从89.8%增加到91.5%,孔隙水压力从0.2 kPa增加到0.5 kPa,波动加速度计等变量与滑坡发生因素密切相关。机器学习结果显示,ExtraTrees分类器获得了87.0%的准确率,并且相对于不同的算法给出了最好的结果。该系统向印度地质调查局(GSI)提供自动SOS信息,并为处于危险中的社区执行基于现场的警报。与目前的GSM或基于卫星的系统相比,所提出的方法提供了更远距离的通信和更低的能耗,以及更快的响应。这项工作为滑坡风险管理和备灾应用提供了一个适用于现场和可扩展的解决方案。
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引用次数: 0
Transport of colloidal Au-bearing nanoparticles driven by metamorphic decarbonization 变质脱碳驱动胶体含金纳米颗粒的输运
IF 8.9 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-12-21 DOI: 10.1016/j.gsf.2025.102240
Zhenjiang Wang , Shaorui Zhao , Jingbo Li , Yanfei Zhang , Chao Wang , Dan Li , Zhenmin Jin
The genesis of bonanza-style gold deposits, characterized by weight-percent-level Au enrichment, challenges conventional models of chemical transport via aqueous complexes. Through high-pressure experiments (0.5–1.5 GPa, 600–1150 °C) combined with thermodynamic modeling and transmission electron microscopy (TEM) analyses, we demonstrate that CO2-rich fluids generated by metamorphic decarbonization create overpressures exceeding ∼ 200 MPa. This initiates explosive upward migration of sulfide liquids containing Au-Ag nanoparticles (NPs) into porous peridotite at velocities up to 55.9 ± 12.9 μm/h. High-resolution TEM analyses furthermore confirm the mechanical entrainment of Au-Ag NPs within sulfides. Fractal analysis (FD = 1.55–1.62) of dendritic sulfide networks reveals that viscous fingering dominates fluid dynamics. We propose a unified model where gas-driven filter pressing extracts Au-bearing sulfides from subducted slabs, while viscous fingering further facilitates kilometer-scale transport through lithospheric faults. This novel mechanism bridges mantle-derived carbon fluxes with crustal mineralization, offering new insights into the formation of ultrahigh-grade gold deposits.
以金富集为特征的富矿型金矿床的成因挑战了传统的通过水络合物进行化学输运的模式。通过高压实验(0.5-1.5 GPa, 600-1150°C),结合热力学模型和透射电镜(TEM)分析,我们证明了变质脱碳产生的富含co2的流体产生超过~ 200 MPa的超压。这引发了含有Au-Ag纳米颗粒(NPs)的硫化液体以55.9±12.9 μm/h的速度向上迁移到多孔橄榄岩中。高分辨率TEM分析进一步证实了Au-Ag NPs在硫化物中的机械夹带。枝状硫化物网络的分形分析(FD = 1.55 ~ 1.62)表明,黏性指指在流体动力学中占主导地位。我们提出了一个统一的模型,即气体驱动的压滤从俯冲板块中提取含金硫化物,而粘性指移进一步促进了通过岩石圈断层的千米尺度运输。这一新的机制将地幔源碳通量与地壳成矿作用联系起来,为超品位金矿床的形成提供了新的认识。
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引用次数: 0
Potassium isotopic evidence for the petrogenesis of Precambrian granitoids and implications for early crustal evolution of the accretionary orogen 前寒武纪花岗岩类岩石成因的钾同位素证据及其对增生造山带早期地壳演化的意义
IF 8.9 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-12-19 DOI: 10.1016/j.gsf.2025.102239
Xinyu Long , Wenliang Xu , Feng Wang , Chenyang Sun , Jie Tang
Stable potassium (K) isotopes are emerging as a novel geochemical tracer for investigating magmatic differentiation and source characteristics. This study presents the K isotopic analyses of Neoarchean–Paleoproterozoic granitoids from the Xing’an Massif, a key microcontinent within the eastern Central Asian Orogenic Belt (CAOB), providing new insights into the granitoid petrogenesis and early crustal evolution of this accretionary orogen. The 2568 Ma peraluminous A-type monzogranite exhibits significantly heavier δ41K values (−0.22‰ to −0.05‰) compared to the range of the upper continental crust. Subduction zones can effectively transfer heavy K isotopic signature to the mantle wedge through slab-derived fluids/melts. The monzogranite could be formed through co-melting and mixing of previously metasomatized mantle materials and recycled supracrustal metapelites, followed by high degree of fractional crystallization in a post-collisional extensional setting. Although both the 1881 Ma monzogranite and 1843 Ma syenogranite share geochemical affinities with adakites, their markedly different K isotopic compositions and distinct geochemical fingerprints point to substantial heterogeneity within their source regions. The 1881 Ma monzogranite shows more pronounced heavy K isotopic enrichment (δ41K = −0.39‰ to −0.18‰) and elevated zircon δ18O values (7.28‰–8.93‰). These features demonstrate the incorporation of mantle components metasomatized by melts of altered oceanic crust (with elevated δ41K values) into the lower crustal source. In contrast, the 1843 Ma syenogranite displays ultrapotassic affinity with lighter K isotopic compositions (δ41K = −0.45‰ to −0.38‰) and strongly negative zircon εHf(t) values (−11.5 to −10.2), indicating a thickened lower crustal source with contributions from ancient supracrustal sediments. Collectively, K isotopic compositions of the ca. 1.8 Ga adakitic granitoids overcome the limitations of traditional geochemical and isotopic proxies in revealing the complex granite petrogenesis, and they potentially provide evidence for a cycle of plate tectonics, from oceanic crust alteration at mid-ocean ridges through slab subduction to continental collision. The onset of plate tectonics promoted remelting of Archean igneous and sedimentary crust, generating abundant peraluminous and potassic granitoids during the late Archean to Paleoproterozoic and driving crustal compositional maturation in this accretionary orogen.
稳定钾同位素作为一种新的地球化学示踪剂,正逐渐成为研究岩浆分异和来源特征的重要手段。本文对中亚造山带东部重要微大陆——兴安地块新太古代-古元古代花岗岩进行了钾同位素分析,为该增生造山带的花岗岩成因和早期地壳演化提供了新的认识。2568 Ma过铝a型二长花岗岩的δ41K值明显高于上陆地壳(- 0.22‰~ - 0.05‰)。俯冲带可以通过板块衍生的流体/熔体有效地将重K同位素特征转移到地幔楔上。二长花岗岩可能是在前交代的地幔物质与再循环的壳上变质岩共融混合后,在碰撞后的伸展环境中发生了高度的分离结晶作用。尽管1881 Ma二长花岗岩和1843 Ma正长花岗岩与埃达岩具有地球化学上的相似性,但它们明显不同的钾同位素组成和不同的地球化学指纹表明它们的来源区域具有明显的非均质性。1881 Ma二长花岗岩重K同位素富集(δ41K = - 0.39‰~ - 0.18‰),锆石δ18O值升高(7.28‰~ 8.93‰)。这些特征表明,变质洋壳(δ41K值升高)熔体交代的地幔成分被纳入下地壳源。而1843 Ma正长花岗岩则表现出较轻的K同位素(δ41K = - 0.45‰~ - 0.38‰)和较强的负锆石εHf(t)值(- 11.5 ~ - 10.2)的超古典亲和性,表明下地壳源区增厚,并有古表壳上沉积物的贡献。总的来说,约1.8 Ga阿达克岩花岗岩的钾同位素组成克服了传统地球化学和同位素指标在揭示复杂花岗岩岩石成因方面的局限性,并可能为板块构造循环提供证据,从洋中脊的洋壳蚀变到板块俯冲再到大陆碰撞。板块构造的发生促进了太古宙火成岩和沉积地壳的重熔,在晚太古宙至古元古代形成了丰富的过铝质和钾质花岗岩,推动了该增生造山带地壳成分的成熟。
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引用次数: 0
Multi-task deep transfer learning for complicated seismic dynamic response prediction in slope systems 斜坡系统复杂地震动力响应预测的多任务深度迁移学习
IF 8.9 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-12-13 DOI: 10.1016/j.gsf.2025.102238
Xu Han , Yu Huang , Xiaoyan Jin , Liuyuan Zhao , Chung Yee Kwok
Slope engineering is an uncertain, dynamic, and complex nonlinear spatiotemporal system with time delays. High-fidelity prediction of slope seismic stability has long been a formidable challenge due to the inherent randomness and uncertainty associated with ground motion, geo-material properties, complex topography, etc. Traditional numerical modelling always takes a simplified model by forcedly ignoring those uncertainties, thus failing to replicate precisely the intricate nonlinear interactions between factors that affect slope instability. Notably, the newly emerging deep learning methods have the capability of handling multiple factors with uncertainties. However, these methods heavily rely on extensive and comprehensive sensor data, while arranging sensors at certain important positions is sometimes unachievable. Therefore, we propose a multi-task deep transfer learning (MT-DTL) framework in this study to enhance the prediction accuracy of slope seismic response especially in data-limited conditions. The dynamic response at the locations without sufficient accessible sensor data can be effectively predicted with a newly developed algorithm. To collect the necessary sensor data, we conduct a series of physics experiments with the world’s largest multifunctional shaking table equipment. We demonstrate the efficacy and accuracy of our approach on the shaking-table datasets through comparisons with traditional machine learning (ML) methods. Our findings reveal that the MT-DTL framework can improve the confidence level of prediction results (within 5%) from the highest 86.4% by the optimal traditional ML methods to 92.7%, achieving comparable results with two-thirds fewer data. Additionally, a single response example showed that the trained deep transfer learning model has significantly improved the computational efficiency (0.018 – 0.019 s) compared to the dynamic finite element calculation with GeoStudio (10 min). This highlights its potential for integration into geo-hazards digital twin systems, facilitating rapid risk analysis based on real-time monitoring data.
边坡工程是一个不确定的、动态的、复杂的、具有时滞的非线性时空系统。由于地面运动、地质材料性质、复杂地形等因素的随机性和不确定性,边坡地震稳定性的高保真预测一直是一项艰巨的挑战。传统的数值模拟总是采用简化的模型,强行忽略了这些不确定性因素,从而无法精确地复制影响边坡失稳因素之间复杂的非线性相互作用。值得注意的是,新兴的深度学习方法具有处理多个不确定因素的能力。然而,这些方法严重依赖于广泛而全面的传感器数据,而在某些重要位置布置传感器有时是无法实现的。因此,本研究提出了一个多任务深度迁移学习(MT-DTL)框架,以提高边坡地震反应的预测精度,特别是在数据有限的条件下。本文提出的一种新算法可以有效地预测传感器数据不足位置的动态响应。为了收集必要的传感器数据,我们使用世界上最大的多功能振动台设备进行了一系列物理实验。通过与传统机器学习(ML)方法的比较,我们证明了我们的方法在振动台数据集上的有效性和准确性。我们的研究结果表明,MT-DTL框架可以将预测结果的置信度(5%以内)从最优传统ML方法的最高86.4%提高到92.7%,在减少三分之二数据的情况下获得可比结果。此外,单个响应示例表明,与GeoStudio动态有限元计算(10 min)相比,训练后的深度迁移学习模型的计算效率显著提高(0.018 - 0.019 s)。这突出了它与地质灾害数字孪生系统集成的潜力,促进了基于实时监测数据的快速风险分析。
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引用次数: 0
Fine characterization of micro-nano fractures and analysis of network connectivity: Mechanistic controls on hydrocarbon enrichment in shale reservoirs 微纳裂缝精细表征及网络连通性分析:页岩储层油气富集的机理控制
IF 8.9 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-12-09 DOI: 10.1016/j.gsf.2025.102233
Boyang Wang , Dengfu Yuan , Jingjing Li , Shichao Li , Fei Xiao , Shansi Tian , Mengjing Yin , Jianguo Yang
Micro-nano fractures serve as the bridge connecting nanopores and macro-fractures. The unclear understanding of their developmental characteristics and controlling factors significantly hinders the large-scale, efficient development of continental shale oil. To address this, this study employs the entropy weight method to establish an evaluation model for fracture development strength that comprehensively considers fracture number, average width, areal density, and areal porosity. Additionally, topology is introduced to evaluate fracture connectivity. The research clarifies the differences in micro-nano fracture developmental characteristics and primary controlling factors among different lithofacies and elucidates the impact of micro-nano fracture development on pore structure and hydrocarbon accumulation in Gulong shale. The results indicate that the HQS (high-organic laminated felsic shale) lithofacies exhibits high micro-nano fracture development strength and connectivity, yielding the highest comprehensive evaluation index. The HCS (high-organic laminated mixed shale) shows high development strength but low connectivity, resulting in a secondary comprehensive evaluation index. Higher organic matter content correlates with greater fracture development strength; clay mineral content controls the characteristics of nano-fracture development; felsic mineral content positively influences fracture connectivity. The development of micro-nano fractures not only enhances macropore content and average pore size but also effectively connects pores of various scales, increasing the effectiveness of the pore-fracture system. Lithofacies with low fracture connectivity (primarily HCS) exhibit more complex pore structures. Shale oil in such lithofacies mainly accumulates via a self-sealing model, making it difficult to form complex fracture networks during hydraulic fracturing and hindering efficient development. Conversely, the HQS lithofacies demonstrates optimal pore-fracture connectivity, favorable oil content, and represents the most favorable lithofacies for Gulong shale oil development. These findings contribute to the optimization of sweet-spot intervals for shale oil exploration in the study area.
微纳裂缝是连接纳米孔和宏观裂缝的桥梁。对陆相页岩油的发育特征和控制因素认识不清,严重阻碍了陆相页岩油的大规模高效开发。针对这一问题,本文采用熵权法建立了综合考虑裂缝数、平均宽度、面密度、面孔隙度的裂缝发育强度评价模型。此外,还引入了拓扑学来评估裂缝连通性。研究明确了不同岩相间微纳裂缝发育特征的差异及主控因素,阐明了微纳裂缝发育对古龙页岩孔隙结构和油气成藏的影响。结果表明,HQS(高有机质层状长英质页岩)岩相具有较高的微纳裂缝发育强度和连通性,综合评价指标最高。高有机质层状混合页岩发育强度高,但连通性低,形成二级综合评价指标。有机质含量越高,裂缝发育强度越大;黏土矿物含量控制着纳米裂缝发育特征;长硅矿物含量正影响裂缝连通性。微纳裂缝的发育不仅提高了大孔隙含量和平均孔径,而且有效连接了不同尺度的孔隙,提高了孔隙-裂缝系统的有效性。裂缝连通性低的岩相(主要是HCS)孔隙结构更为复杂。该岩相页岩油主要以自封闭模式聚集,水力压裂时难以形成复杂的裂缝网络,阻碍了高效开发。相反,HQS岩相孔缝连通性最佳,含油量有利,是古龙页岩油开发的最有利岩相。研究结果为研究区页岩油甜点层段的优选提供了理论依据。
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引用次数: 0
Probabilistic quantification of global drought risk amplification from temperature-enhanced evapotranspiration under climate change 气候变化下温度增强蒸散发对全球干旱风险放大的概率量化
IF 8.9 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-12-08 DOI: 10.1016/j.gsf.2025.102235
Akinwale T. Ogunrinde , Paul Adigun , Xian Xue , Koji Dairaku , Sabab Ali Shah , Ifeoluwa S. Adawa
Droughts pose escalating threats to global water security, agriculture, and socioeconomic stability amid anthropogenic climate change, with projections indicating an increase in frequency, duration, and severity driven by altered precipitation patterns and amplified evaporative demand. This study introduces a probabilistic framework to quantify drought risk amplification, employing the Risk Ratio (RR) methodology integrated with extreme value theory and non-parametric inference. Utilizing multi-model ensemble (MME) from the Coupled Model Intercomparison Project Phase 6 (CMIP6) under Shared Socioeconomic Pathways (SSP2-4.5 and SSP5-8.5), we evaluate changes in drought characteristics—duration, frequency, and severity — via the Standardized Precipitation Evapotranspiration Index (SPEI) at 3- and 12-month timescales for near-future (NF) and far-future (FF) periods. Our analyses reveal pervasive global intensification, with over 90% of land grids exhibiting positive severity shifts under SSP5-8.5 in the FF, attributed to atmospheric evaporative demand, which accounts for approximately 44% of the trends in SPEI. Threshold-stratified RR assessments reveal nonlinear escalations at higher percentiles (P90 vs. P75), compressing the return periods of extreme events by 20%–30% under high-emission scenarios. Regional hotspots, including the Amazon basin, sub-Saharan Africa, southwestern North America, and Central Asian drylands, exhibit frequency risks that are 4-fold or more amplified, signaling transitions to chronic water stress and potential ecosystem tipping points. These findings underscore the dominance of thermodynamic drivers in drought dynamics, advocating for emissions mitigation to curtail risks by 15%–25% under moderate pathways. By addressing uncertainties in non-stationary regimes, this framework provides adaptive strategies for resilient water management, offering policymakers critical insights to mitigate cascading impacts on global food security and biodiversity in a warming world.
在人为气候变化的背景下,干旱对全球水安全、农业和社会经济稳定构成的威胁不断升级,预测表明,由于降水模式的改变和蒸发需求的扩大,干旱的频率、持续时间和严重程度都会增加。本文采用风险比(RR)方法,结合极值理论和非参数推理,提出了干旱风险放大量化的概率框架。利用共享社会经济路径(SSP2-4.5和SSP5-8.5)下的耦合模式比对项目第6阶段(CMIP6)的多模式集成(MME),通过标准化降水蒸散指数(SPEI)在近未来(NF)和远未来(FF)时期的3个月和12个月时间尺度上评估了干旱特征的变化——持续时间、频率和严重程度。我们的分析揭示了普遍的全球强化,超过90%的陆地网格在FF的SSP5-8.5下表现出正的严重变化,这归因于大气蒸发需求,这占SPEI趋势的约44%。阈值分层RR评估显示,在高排放情景下,较高百分位数(P90 vs P75)的非线性上升,将极端事件的重现期压缩了20%-30%。包括亚马逊盆地、撒哈拉以南非洲、北美西南部和中亚旱地在内的区域热点地区,呈现出4倍或更多的频率风险,标志着向慢性水压力和潜在生态系统临界点的转变。这些发现强调了干旱动力学中热力学驱动因素的主导地位,主张在适度途径下减少排放,将风险降低15%-25%。通过解决非平稳机制中的不确定性,该框架为弹性水管理提供了适应性战略,为政策制定者提供了关键见解,以减轻全球变暖对全球粮食安全和生物多样性的连锁影响。
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引用次数: 0
First observation of coexisting crystalline and amorphous mineral phases in the Bhawad LL6 chondrite: Evidence from Micro-Raman spectroscopic studies 在Bhawad LL6球粒陨石中首次观察到共存的晶体和非晶矿物相:来自微拉曼光谱研究的证据
IF 8.9 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-12-08 DOI: 10.1016/j.gsf.2025.102236
Bhaskar J. Saikia , G. Parthasarathy , Binoy K. Saikia , Puja Bordoloi , Rashmi R. Borah
We report here for the first time the detailed spectroscopic investigations on Bhawad meteorite using micro-Raman spectroscopic and high-resolution transmission electron microscopy (HR-TEM) investigation of the Bhawad LL6 ordinary chondrite, focusing on its mineralogical composition and carbonaceous phases. Raman spectroscopy reveals crystalline silicates including olivine, pyroxene, and plagioclase, along with accessory chromite containing ≤20% of Al. Carbonaceous material exhibits broad ID (∼1336 cm−1) and IG (∼1587 cm−1) bands with an ID/IG ratio of ∼1.04, indicative of disordered graphite and nanocrystalline carbon, reflecting shock-induced metamorphism. High-pressure TiO2 polymorphs are identified by characteristic Raman modes at 146, 394, 446, and 610 cm−1. HR-TEM imaging confirms the presence of nanocrystalline TiO2 particles embedded within amorphous carbonaceous matrices, demonstrating the coexistence of crystalline and amorphous phases. The Raman spectra of the Bhawad meteorite reveal the presence of high-temperature plagioclase phases, characterized by these distinct vibrational features. This observation indicates possible quenching of the melts having feldspar components, representing the complex thermal and shock metamorphic history of the meteorite. This coexistence of crystalline and amorphous phases highlights the complex thermal and shock history of the Bhawad meteorite, revealing insights into phase transitions and structural order–disorder phase transition induced by impact processes.
本文首次利用微拉曼光谱和高分辨率透射电镜(hrtem)对Bhawad LL6普通球粒陨石进行了详细的光谱研究,重点研究了其矿物组成和碳质相。拉曼光谱显示,晶体硅酸盐包括橄榄石、辉石和斜长石,以及含铝量≤20%的铬铁矿。碳质材料显示出宽ID (~ 1336 cm−1)和IG (~ 1587 cm−1)波段,ID/IG比值为~ 1.04,表明无序石墨和纳米晶碳,反映了冲击诱发的变质作用。在146、394、446和610 cm−1处,通过特征拉曼模式鉴定出了高压TiO2多晶。HR-TEM成像证实了纳米晶TiO2颗粒嵌入在非晶碳质基体中,证明了晶相和非晶相共存。Bhawad陨石的拉曼光谱揭示了高温斜长石相的存在,其特征是这些明显的振动特征。这一观察结果表明,含有长石成分的熔体可能被淬火,代表了陨石复杂的热变质和冲击变质历史。这种晶体和非晶相的共存突出了Bhawad陨石复杂的热历史和冲击历史,揭示了由撞击过程引起的相变和结构有序-无序相变的见解。
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引用次数: 0
Physics-informed dictionary learning of time-varying 3D settlements from sparse monitoring data and 2D numerical models with consideration of complex stratigraphy 基于稀疏监测数据和考虑复杂地层的二维数值模型的时变三维沉降的物理字典学习
IF 8.9 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-12-02 DOI: 10.1016/j.gsf.2025.102222
Dan-Ni Zhang , Hua-Ming Tian , Yu Wang , Chao Shi , Kostas Senetakis
Digital twins of geotechnical structures replicate their physical counterparts, such as underground spaces developed from land reclamations. These spaces often exhibit intricate three-dimensional (3D) stratigraphic distributions, including irregular and interbedded soil layers. Developing a virtual 3D model, such as finite element model (FEM), with complex stratigraphy poses significant computational challenges due to the necessity for numerous stratum voxels, high-resolution meshing, and prohibitive analysis times. Incorporating field settlement data for model updating escalates the computational burden, as repeated evaluations of 3D FEM models are required for each model updating. To address this challenge, this study develops a novel approach for efficiently predicting time-varying 3D settlement from two-dimensional (2D) numerical models with sparsely measured monitoring data. Settlements from 2D FEM analyses, which account for complex stratigraphy, are compiled within a dictionary learning framework and combined with limited monitoring data to estimate time-varying settlements at multiple 2D cross-sections. The 2D settlements are then utilized to reconstruct high-resolution 3D settlements through 3D compressive sampling (3D-CS), eliminating a need for additional numerical model evaluations when integrating new monitoring data. The proposed approach is illustrated using a reclamation project in Hong Kong, China.
岩土工程结构的数字双胞胎复制了它们的物理对应物,例如从土地复垦中开发的地下空间。这些空间通常呈现复杂的三维(3D)地层分布,包括不规则和互层的土层。由于需要大量的地层体素、高分辨率网格划分和令人望而却步的分析时间,开发具有复杂地层的虚拟3D模型(如有限元模型(FEM))带来了巨大的计算挑战。采用现场沉降数据进行模型更新会增加计算量,因为每次更新模型都需要对三维有限元模型进行重复评估。为了解决这一挑战,本研究开发了一种新的方法,可以通过稀疏测量的监测数据从二维(2D)数值模型有效地预测时变的3D沉降。二维有限元沉降分析解释了复杂的地层,在字典学习框架内编制,并结合有限的监测数据来估计多个二维截面上随时间变化的沉降。然后利用2D沉降,通过3D压缩采样(3D- cs)重建高分辨率3D沉降,在整合新的监测数据时无需额外的数值模型评估。以中国香港的一个填海工程为例,说明建议的方法。
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引用次数: 0
Fast production of large lithologic maps using lithologic sample generation strategies based on 3D spatial positioning 利用基于三维空间定位的岩性样品生成策略快速生成大型岩性图
IF 8.9 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-12-02 DOI: 10.1016/j.gsf.2025.102217
Tao Zhang , Zhifang Zhao , Min Zeng , Haiying Yang
The acquisition of spatiotemporal information for lithological mapping with timeliness, accuracy, and high precision is crucial for mineral resource exploration and geological hazard prevention. However, large-scale lithological mapping remains severely constrained by the limitations of visual interpretation in obtaining representative samples from remote sensing data and error propagation during sample collection based on existing geological maps. To address this, we propose a three-dimensional spatial dual-positioning sample generation methodology (SG-3DSD) using Sentinel-2 (S2) and Landsat 8 (L8) data on the Google Earth Engine (GEE) platform, enabling automated generation of 11 lithological class samples across the Beishan region of Gansu Province, China (covering approximately 6,000 km2). First, boundary association rules were established to reconstruct 1:200,000-scale geological maps, mitigating data acquisition biases and cartographic compilation errors. Second, principal component analysis (PCA) was performed on seven S2 spectral bands, with the first three principal components (capturing > 98% information variance) constituting a 3D feature space for localized clustering. Concurrently, four L8 bands were selected through lithological spectral curve analysis to implement band ratio (BR) transformations for secondary positioning. Finally, a two-step refinement strategy was implemented to filter high-confidence samples across 11 lithological classes, balancing intraclass feature consistency and sample purity. Applying SG-3DSD-derived samples to multiple machine learning models revealed that (1) the Stacking ensemble model demonstrated superior lithological discrimination capability compared to conventional algorithms, achieving peak accuracy of 94.15% and mean F1-score of 93.87%; (2) integrating topographic data (especially Elevation) enhanced lithological positioning accuracy by 4.43% ± 1.13%; (3) PCA and BR transformations effectively enhanced lithological separability, particularly at lithological boundary zones; (4) while SG-3DSD enables efficient large-scale sample generation, it is advisable to avoid using excessively large training samples for regional-scale mapping. This methodology mitigates the weighting dependence on geological maps during sample selection and dilutes inherent cartographic error propagation, providing a novel paradigm for large-scale lithological mapping with broad application potential.
及时、准确、高精度地获取岩性填图的时空信息,对矿产资源勘查和地质灾害防治至关重要。然而,大规模的岩性填图仍然受到遥感数据中获得代表性样品的目视解释的局限性和基于现有地质图的样品采集过程中的误差传播的严重制约。为了解决这个问题,我们提出了一种三维空间双定位样本生成方法(SG-3DSD),利用谷歌地球引擎(GEE)平台上的Sentinel-2 (S2)和Landsat 8 (L8)数据,在中国甘肃省北山地区(面积约6000平方公里)自动生成11个岩性类样本。首先,建立边界关联规则,重构1:20万比例尺地质图,减少数据采集偏差和制图编制误差;其次,对7个S2光谱波段进行主成分分析(PCA),其中前3个主成分(捕获98%的信息方差)构成三维特征空间进行局部聚类;同时,通过岩性光谱曲线分析,选择4个L8波段,进行波段比变换,进行二次定位。最后,采用两步优化策略过滤11个岩性类别的高置信度样本,平衡类内特征一致性和样本纯度。将sg - 3dsd衍生样本应用于多个机器学习模型表明:(1)与传统算法相比,叠加系综模型具有更强的岩性识别能力,峰值精度为94.15%,平均f1分数为93.87%;(2)整合地形数据(尤其是高程数据)可使岩性定位精度提高4.43%±1.13%;(3) PCA和BR变换有效增强了岩性可分性,特别是在岩性边界带;(4) SG-3DSD虽然能够高效地生成大尺度样本,但在区域比例尺制图时,建议避免使用过大的训练样本。该方法减轻了样本选择过程中对地质图的权重依赖,淡化了固有的制图误差传播,为大规模岩性填图提供了一种新的范例,具有广阔的应用潜力。
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Geoscience frontiers
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