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Promoting green taxation and sustainable energy transition for low-carbon development 推动绿色税收和可持续能源转型,促进低碳发展
IF 8.5 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-09-11 DOI: 10.1016/j.gsf.2024.101928
Gul Jabeen , Dong Wang , Stefania Pinzón , Cem Işık , Munir Ahmad , Ali Rehman , Muhammad Khalid Anser
Since there is a scientific consensus that the energy sector has brought the planet to the tipping point of climate change, transitioning to sustainable energy sources is inevitable to halt foreseeable climatic adversities. This study looks at how promoting green taxation and sustainable energy transition affected the G7 nations’ goal of low-carbon development between 1994 and 2020. This study used Generalized Least Squares Random Effects Regression and Driscoll-Kraay Standard Errors-based Least Sqaures approaches for empirical analysis. The latter approach accounts for cross-sectional dependence, heteroscedasticity, and autocorrelation to provide robust empirical outcomes. The empirical results are as follows: Firstly, through lowering CO2 intensity and greenhouse gas emissions, the environmental tax revenues have enhanced the condition of the environment. The total tax revenues linked to the environment had a greater overall impact than the tax revenues related to the energy industry. Furthermore, compared to CO2 intensity, both of the environmental tax revenue factors contributed considerably more to greenhouse gas emissions. Second, the sustainable energy transition helped to lower greenhouse gas and CO2 intensity. Among covariates, international trade was supportive of low-carbon development, but industrialization and GDP per capita did the opposite. The panel bootstrap causality revealed a unidirectional causal connection from all independent variables, except foreign direct investment, to CO2 intensity and greenhouse gas emissions. These results demonstrated that the G7 nations’ environmental policies supported their commitment to achieving low-carbon development goals. In this respect, the G7 nations’ environmental emission reduction efforts benefited more from the overall environmental tax revenues. To secure the industrial emissions reduction for a future with net-zero carbon emissions, it is thus advised to continue using policies that price environmental emissions, such as the carbon taxation regulations. Additionally, plans for the sustainable energy transition that includes a quick rise in renewable energy sources in the overall energy mix are successful in lowering environmental emissions. For environmental sustainability and low-carbon development, it is thus advised to divert the taxation burden from renewable energy technologies to the fossil fuel industry to enhance the sustainable energy transition phenomenon for achieving Sustainable Development Goals (especially SDG-7 and SDG-13).
由于科学界已达成共识,即能源行业已将地球带入气候变化的临界点,因此,为阻止可预见的气候逆境,向可持续能源过渡势在必行。本研究探讨了 1994 年至 2020 年间,促进绿色税收和可持续能源转型如何影响七国集团的低碳发展目标。本研究采用广义最小二乘法随机效应回归法和基于标准误差的最小二乘法进行实证分析。后一种方法考虑了横截面依赖性、异方差和自相关性,以提供稳健的实证结果。实证结果如下:首先,通过降低二氧化碳强度和温室气体排放,环境税收改善了环境状况。与环境相关的税收总收入的总体影响大于与能源产业相关的税收收入。此外,与二氧化碳排放强度相比,环境税收因素对温室气体排放的影响要大得多。其次,可持续能源转型有助于降低温室气体和二氧化碳强度。在协变量中,国际贸易支持低碳发展,但工业化和人均国内生产总值则相反。面板自举因果关系显示,除外国直接投资外,所有自变量与二氧化碳强度和温室气体排放之间都存在单向因果关系。这些结果表明,G7 国家的环境政策支持其实现低碳发展目标的承诺。在这方面,G7 国家的环境减排努力从整体环境税收中获益更多。因此,为了确保未来实现碳净零排放的工业减排目标,建议继续使用环境排放定价政策,如碳税法规。此外,可持续能源转型计划,包括在整个能源结构中迅速增加可再生能源,也能成功降低环境排放。因此,为了环境的可持续发展和低碳发展,建议将可再生能源技术的税收负担转移到化石燃料行业,以加强可持续能源转型现象,从而实现可持续发展目标(尤其是可持续发展目标 7 和可持续发展目标 13)。
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引用次数: 0
Formation of high-silica adakites and their relationship with slab break-off: Implications for generating fertile Cu-Au-Mo porphyry systems 高硅方解石的形成及其与板块断裂的关系:对生成肥沃的铜-金-钼斑岩系统的影响
IF 8.5 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-09-10 DOI: 10.1016/j.gsf.2024.101927
Fazilat Yousefi, David R. Lentz
<div><p>In recent years, the characteristics and sources of fertile adakites has received considerable attention. As well, most recently the geodynamic environment of convergent margins subducting oceanic crust aiding arc formation, evolving to slab rollback, then slab break-off after collision (i.e. late- to post-collisional slab failure (arc-like magmatism) and transpression) has gained more recognition, although their relationship to each other has yet to be explored. The geochemical characteristics imply that adakites/adakite-like, in particular high-silica adakites (HSA), can form by partial melting of subducting hydrothermally altered oceanic crust in convergent plate boundary settings during the terminal stages of subduction, lithosphere thickening, and then failure (all late to post collisional), while the melting of the mantle wedge during subduction-related dehydration creates more typical calc-alkaline basalt-andesite-dacite-rhyolite series (ADR) to form intraoceanic island arc to intracontinental margin arc systems, before the collisional stage. HSAs are characterized by high-silica (SiO<sub>2</sub> > 67 wt.%), Al<sub>2</sub>O<sub>3</sub> > 15 wt.%, Sr > 300 ppm, Y<20 ppm, Yb < 1.8 ppm, and Nb ≤ 10 ppm, and MgO < 3 wt.%, with high Sr/Y (>50), and La/Yb (>10). Some specific geochemical features, such as high Mg# (ave 0.51), Ni (ave 924 ppm), and Cr (ave 36 ppm), in HSAs are typical, in contrast to calc-alkaline arcs, although both groups display similar but less pronounced negative anomalies of Nb, Ta, and Ti in primitive mantle-normalized trace element spider diagram profiles. These unique geochemical features are likely ascribed to the involvement of garnet, hornblende, and titanite either during partial melting of hydrous MORB-like oceanic crust with only minor assimilation and fractional crystallization (AFC) within the mantle and crustal during ascent in a transpressional collisional environment. Hypotheses for origin of HSA derivative from melting in convergent margins from young, hot oceanic plates subducting into the mantle is applicable to only some adakitic systems. The difference in geochemical characteristics of adakites compared to ADR, such as relative higher MgO, Cr, Cu, and Ni, are due to their slab source, as well as interaction of the slab-derived adakitic melts with overlying hot lithospheric mantle; altered oceanic slabs are also relatively rich in siderophile and other chalcophile elements, as well as sulfates and sulfides. HSA magmas related to slab failure have special geochemical properties, such as Sr/Y > 20, Nb/Y > 0.4, Ta/Yb > 0.3, La/Yb > 10, Gd/Yb > 2, and Sm/Yb > 2.5. Slightly higher Nb + Ta is due to high <em>T</em> melting of rutile. Varieties of Nb/Ta compared to silica are also significant in HSA as a result of slab failure (roll back to break-off). High <em>T</em>-<em>P</em> partial melting of the hydrothermally altered oceanic slab produces HSA with quite hig
近年来,肥沃阿达克岩的特征和来源受到了广泛关注。最近,汇聚边俯冲大洋地壳帮助弧的形成、演变为板块后退、碰撞后板块断裂(即碰撞后期至碰撞后板块破坏(弧状岩浆活动)和转位)的地球动力环境也得到了更多的认可,尽管它们之间的关系还有待探讨。地球化学特征表明,在俯冲、岩石圈增厚的末期阶段,在板块交汇边界环境中,俯冲热液蚀变的大洋地壳部分熔化后,可形成吸积岩/类吸积岩,特别是高硅吸积岩(HSA)、而地幔楔在与俯冲有关的脱水过程中的熔化则形成了更典型的钙碱性玄武岩-安山岩-黑云母-流纹岩系列(ADR),从而在碰撞阶段之前形成洋内岛弧至洲内边缘弧系统。HSA的特征是高硅(SiO2 67%)、Al2O3 15%、Sr 300ppm、Y 20ppm、Yb 1.8ppm、Nb ≤ 10ppm、MgO 3%,以及高Sr/Y(50)和La/Yb(10)。一些特殊的地球化学特征,如高 Mg#(平均值 0.51)、Ni(平均值 924 ppm)和 Cr(平均值 36 ppm),在 HSAs 中是典型的,与钙碱性弧形成鲜明对比,尽管这两类弧在原始地幔归一化微量元素蛛网图剖面中显示出类似但不太明显的 Nb、Ta 和 Ti 负异常。这些独特的地球化学特征很可能是由于石榴石、角闪石和榍石的参与,或者是在类水MORB洋壳部分熔融过程中的参与,或者是在换位碰撞环境中上升过程中地幔和地壳内仅有少量同化和部分结晶(AFC)的参与。关于HSA衍生物起源于年轻、炽热的大洋板块向地幔俯冲的汇聚边缘熔融的假设,只适用于某些阿达克特系统。与 ADR 相比,adakites 的地球化学特征有所不同,如相对较高的氧化镁、铬、铜和镍,这是由于它们的板块来源,以及板块衍生的 adakitic 熔体与上覆热岩石圈地幔的相互作用造成的;蚀变的大洋板块也相对富含亲凫元素和其他亲铬元素,以及硫酸盐和硫化物。与板块崩塌有关的 HSA 岩浆具有特殊的地球化学性质,如 Sr/Y >20、Nb/Y >0.4、Ta/Yb >0.3、La/Yb >10、Gd/Yb >2、Sm/Yb >2.5。Nb + Ta 略高是因为金红石的高 T 熔化。与二氧化硅相比,Nb/Ta 的变化在 HSA 中也很明显,这是板坯破坏(回滚到断裂)的结果。热液蚀变的大洋板块的高T-P部分熔化产生了HSA,其中H2O、SO2、HCl的活度相当高,而亲铝金属在较高的fO2(低fH2)条件下仍然不相容;这种情况发生在碰撞晚期至碰撞后的环境中,在这种环境中,俯冲的大洋地壳经历了板块崩塌,导致上涌的岩石圈向系统增加平流热量。在这种板块破裂的情况下,转位和横张在大量肥沃的阿达基岩浆通过俯冲改造的岩石圈和地壳快速置入上地壳中起着重要作用。当氧化板块熔体与俯冲改造岩石圈地幔相互作用时,产生的岩浆保持氧化状态,有可能促成有利于形成斑岩型铜金矿化的特殊条件。
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引用次数: 0
Tectonic controls on ore deposit exhumation and preservation: A case study of the Handan-Xingtai iron-skarn district 构造对矿床出露和保存的控制:邯郸-邢台铁矽卡岩区案例研究
IF 8.5 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-09-10 DOI: 10.1016/j.gsf.2024.101924
Yannan Wang , Zhiyuan He , Kai Bian , Cunliang Zhao , Lian Chen , Rui Dong , Jin Zhang , Zhaoqun Zhu , Guang Liu

Despite the growing concern regarding post-mineralization thermo-tectonic processes in recent years, the relative roles in exhuming and preserving ore deposits remain highly controversial. This study presents new apatite fission track and (U-Th)/He data from the Xishimen iron skarn deposit in the Handan-Xingtai district, central North China Craton. Apatite fission track dating yielded central ages ranging from 88 ± 18 Ma to 125 ± 9 Ma, with mean confined track lengths varying between 11.9 ± 0.4 μm and 13.3 ± 0.2 μm. Integrated apatite (U-Th)/He dating provided ages of 42.5 ± 0.8 Ma to 48.1 ± 3.3 Ma. Our new data, combined with previous zircon U-Pb and potassium-bearing mineral 40Ar/39Ar ages, revealed three cooling episodes: very rapid cooling (100–140 °C/Ma) at ca. 130–120 Ma, a protracted slow cooling period (0.2–0.4 °C/Ma) at ca. 120–50 Ma, and moderate cooling (0.8–1.0 °C/Ma) since ca. 50 Ma. The initial rapid cooling phase was primarily attributed to post-magmatic thermal equilibration following the shallow emplacement of the Xishimen deposit. The subsequent cooling phases were controlled by uplift and exhumation processes. Our thermal models indicate an estimated total unroofing thickness of < 3 km, which is shallower than the emplacement depth of the ore deposit (3–5 km). This suggests significant potential for mineral exploration. Furthermore, a comprehensive review of preservation mechanisms for various ore deposits underscores the significant role of tectonics in both exhuming and preserving ore bodies.

尽管近年来人们越来越关注成矿后的热构造过程,但对矿床出露和保存的相对作用仍存在很大争议。本研究提供了华北克拉通中部邯郸-邢台地区西石门铁矽卡岩矿床新的磷灰石裂变轨迹和(U-Th)/He数据。磷灰石裂变轨迹测年得出的中心年龄为88±18Ma至125±9Ma,平均封闭轨迹长度为11.9±0.4μm至13.3±0.2μm。磷灰石(U-Th)/He综合测年提供了 42.5 ± 0.8 Ma 至 48.1 ± 3.3 Ma 的年龄。我们的新数据与之前的锆石 U-Pb 和含钾矿物 40Ar/39Ar 年龄相结合,揭示了三个冷却过程:约 130-120 Ma 时的极速冷却(100-140 °C/Ma)、约 130-120 Ma 时的长期冷却(100-140 °C/Ma)、约 130-120 Ma 时的长期冷却(100-140 °C/Ma)。约 130-120 Ma 时的极快速冷却(100-140 °C/Ma),约 120-50 Ma 时的长期缓慢冷却(0.2-0.4 °C/Ma),以及中度冷却(0.2-0.4 °C/Ma)。120-50Ma,以及自约 50Ma 开始的中度冷却(0.8-1.0 °C/Ma)。从大约 50 Ma 开始的中度冷却(0.8-1.0 °C/Ma)。最初的快速冷却阶段主要归因于西石门沉积层浅部置入后的岩浆热平衡。随后的冷却阶段则由隆起和掘起过程控制。我们的热模型表明,估计的总揭露厚度为 3 千米,比矿床的堆积深度(3-5 千米)要浅。这表明这里具有巨大的矿产勘探潜力。此外,对各种矿床保存机制的全面审查强调了构造作用在矿体出露和保存方面的重要作用。
{"title":"Tectonic controls on ore deposit exhumation and preservation: A case study of the Handan-Xingtai iron-skarn district","authors":"Yannan Wang ,&nbsp;Zhiyuan He ,&nbsp;Kai Bian ,&nbsp;Cunliang Zhao ,&nbsp;Lian Chen ,&nbsp;Rui Dong ,&nbsp;Jin Zhang ,&nbsp;Zhaoqun Zhu ,&nbsp;Guang Liu","doi":"10.1016/j.gsf.2024.101924","DOIUrl":"10.1016/j.gsf.2024.101924","url":null,"abstract":"<div><p>Despite the growing concern regarding post-mineralization thermo-tectonic processes in recent years, the relative roles in exhuming and preserving ore deposits remain highly controversial. This study presents new apatite fission track and (U-Th)/He data from the Xishimen iron skarn deposit in the Handan-Xingtai district, central North China Craton. Apatite fission track dating yielded central ages ranging from 88 ± 18 Ma to 125 ± 9 Ma, with mean confined track lengths varying between 11.9 ± 0.4 μm and 13.3 ± 0.2 μm. Integrated apatite (U-Th)/He dating provided ages of 42.5 ± 0.8 Ma to 48.1 ± 3.3 Ma. Our new data, combined with previous zircon U-Pb and potassium-bearing mineral <sup>40</sup>Ar/<sup>39</sup>Ar ages, revealed three cooling episodes: very rapid cooling (100–140 °C/Ma) at ca. 130–120 Ma, a protracted slow cooling period (0.2–0.4 °C/Ma) at ca. 120–50 Ma, and moderate cooling (0.8–1.0 °C/Ma) since ca. 50 Ma. The initial rapid cooling phase was primarily attributed to post-magmatic thermal equilibration following the shallow emplacement of the Xishimen deposit. The subsequent cooling phases were controlled by uplift and exhumation processes. Our thermal models indicate an estimated total unroofing thickness of &lt; 3 km, which is shallower than the emplacement depth of the ore deposit (3–5 km). This suggests significant potential for mineral exploration. Furthermore, a comprehensive review of preservation mechanisms for various ore deposits underscores the significant role of tectonics in both exhuming and preserving ore bodies.</p></div>","PeriodicalId":12711,"journal":{"name":"Geoscience frontiers","volume":"15 6","pages":"Article 101924"},"PeriodicalIF":8.5,"publicationDate":"2024-09-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1674987124001488/pdfft?md5=40fe852d394f5c2affe439b4dbbc38c4&pid=1-s2.0-S1674987124001488-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142256607","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A first-principles molecular dynamics study of molecular hydrogen diffusion in Fe-free olivine 无铁橄榄石中分子氢扩散的第一原理分子动力学研究
IF 8.9 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-09-07 DOI: 10.1016/j.gsf.2024.101926
Haibo Liu, Baohua Zhang, Hongzhan Fei, Lei Liu
Molecular hydrogen (H2) may be an important form of water in nominally anhydrous minerals in the Earth’s mantle and plays a critical role in mantle water cycle, but the transport properties of H2 remain unclear. Here, the diffusion of H2 in Fe-free olivine lattice is investigated at pressures of 1–13 GPa and temperatures of 1300–1900 K by first-principles molecular dynamics. The activation energy and activation volume for H2 diffusion in Fe-free olivine are determined to be 55 ± 8 kJ/mol and 3.6 ± 0.2 cm3/mol, respectively. H2 diffusion in Fe-free olivine is faster than H+ by 1–4 orders of magnitude and therefore it is more favorable for hydrogen transportation under upper mantle conditions. H2 can be carried to the mantle transition zone by subducting slabs without releasing to the surrounding mantle. The upper mantle may act as a lid, preventing the releasing of H2 produced in the deep mantle to the surface.
分子氢(H2)可能是地幔中名义上无水矿物中水的一种重要形式,在地幔水循环中起着关键作用,但 H2 的传输特性仍不清楚。本文通过第一原理分子动力学研究了在压力为 1-13 GPa、温度为 1300-1900 K 的条件下 H2 在无铁橄榄石晶格中的扩散。无铁橄榄石中 H2 扩散的活化能和活化体积分别为 55 ± 8 kJ/mol 和 3.6 ± 0.2 cm3/mol。H2在无铁橄榄石中的扩散速度比H+快1-4个数量级,因此在上地幔条件下更有利于氢的运输。H2可被俯冲板块带到地幔过渡带,而不会释放到周围的地幔中。上地幔可以起到盖子的作用,防止深地幔中产生的H2释放到地表。
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引用次数: 0
The effect of antigorite dehydration on velocity structure and water migration in subduction zones 反橄榄岩脱水对俯冲带速度结构和水迁移的影响
IF 8.9 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-09-02 DOI: 10.1016/j.gsf.2024.101923
Huan Zeng, Maining Ma, Yongbing Li, Jialei Zhang, Hao Guan, Xiao Li
The water migration in subduction zones, primarily driven by the phase transition in hydrous minerals, can give rise to hydrated regions with reduced velocity. A fundamental element in comprehending and deciphering these low-velocity zones revolves around acquiring insights into the stability and elasticity of relevant hydrous minerals. As one of the main water carriers in shallow areas, antigorite can dehydrate to form talc, forsterite, and fluid (talc–bearing peridotites) in deep areas of subduction zones, and then the talc thus serves as one of the minerals that can bring water to the deep Earth. Here, the elasticity of talc up to 24 GPa and forsterite up to 12 GPa are calculated by using the first principles method. The result supposes that the talc structure transforming from talc I to talc II is at a pressure between 6 GPa and 8 GPa, impacting the trend of elastic wave velocity in response to pressure. Furthermore, the elastic wave velocity of forsterite can be significantly affected by iron concentration. Meanwhile, a variation velocity model with antigorite consumption and talc content is set up for talc-bearing serpentinized peridotite based on the elastic properties of talc and forsterite in this study, and antigorite in Wang et al. (2022). The results of our model demonstrate a decrease in the low-velocity anomaly in subduction zones, particularly in deep regions or areas with higher initial serpentinization degrees. The results also suggest that the mode of antigorite dehydration can diminish the estimation of water content transported to depths of subduction zones, such as the Mariana Trench and Northern Japan subduction zones. The mode of antigorite dehydration thus provides a useful tool for constraining the composition, seismic velocity structure, and water migration in subduction zones.
水在俯冲带中的迁移主要是由含水矿物的相变驱动的,这种迁移会产生速度降低的水合区域。理解和解读这些低速区的一个基本要素是深入了解相关含水矿物的稳定性和弹性。作为浅层地区的主要水载体之一,安氏闪长岩在俯冲带深部地区可以脱水形成滑石、闪长岩和流体(含滑石的橄榄岩),然后滑石就成为可以将水带到地球深部的矿物之一。在此,我们利用第一原理方法计算了滑石最高达 24 GPa 的弹性和绿柱石最高达 12 GPa 的弹性。结果推测,滑石结构从滑石 I 转变为滑石 II 的压力介于 6 GPa 和 8 GPa 之间,这影响了弹性波速随压力变化的趋势。此外,铁的浓度也会极大地影响闪石的弹性波速。同时,根据本研究中滑石和绿柱石的弹性特性,以及 Wang 等人(2022 年)中绿柱石的弹性特性,为含滑石的蛇纹石化橄榄岩建立了一个带有锑橄榄石消耗量和滑石含量的变化速度模型。我们的模型结果表明,俯冲带的低速异常有所减少,尤其是在深部地区或初始蛇绿岩化程度较高的地区。结果还表明,锑锭岩脱水模式会降低对潜没带(如马里亚纳海沟和日本北部潜没带)深处水含量的估算。因此,锑橄榄岩脱水模式为约束俯冲带的成分、地震速度结构和水迁移提供了有用的工具。
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引用次数: 0
Spatio-temporal analysis of Permian-Cretaceous magmatic activities in the Tengchong block: Implications for tectono-magmatic evolution 腾冲地块二叠纪-白垩纪岩浆活动的时空分析:构造岩浆演化的意义
IF 8.5 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-08-31 DOI: 10.1016/j.gsf.2024.101920
Xinkun Yang , Zhenjie Zhang , Yuanzhi Zhou , Jie Yang

Understanding the tectono-magmatic evolution history of the Tengchong block is crucial for elucidating the formation of the Eastern Tethys tectonic domain. However, the correlation and evolution of the Tengchong block with the Sibumasu and Lhasa blocks is controversial during the Permian and Cretaceous. This study explores the information contained within magmatic rocks using big data and spatio-temporal analysis, providing quantitative constraints for the discussion of the tectono-magmatic evolution of the Tengchong block. To more accurately assess true magma activities and reduce errors caused by preservation and sampling processes, we utilized local singularity analysis to obtain the singularity index time-series. Correlation analysis of zircon ages and εHf(t) (correlation coefficient ≥ 0.5) values indicates that the Tengchong block is more similar to the Sibumasu block. Results from time-lagged cross-correlation analysis indicate that the Tengchong block and Sibumasu block exhibit a shorter lag in magmatic activities (3 Myr). Wavelet analysis reveals similar periods of collision-related magmatic activities (57 Myr and 43 Myr). Integrating evidence from paleontology and ophiolite belts, we propose that the Tengchong block co-evolved more closely with the Sibumasu block than with the Lhasa block, suggesting similar tectonic processes during the Early Permian to Early Cretaceous. Approximately 250–236 Ma, in the western Tengchong block, partial melting of the lower crust occurs due to crustal thickening. Around 219–213 Ma and 198–180 Ma, after the Tengchong block collided with the Eurasian continent, the subduction of the Meso-Tethys Ocean commenced. Around 130–111 Ma, the overall tectonic feature was a scissor-like closure of the Meso-Tethys Ocean from north to south.

了解腾冲块体的构造-岩浆演化史对于阐明东特提斯构造域的形成至关重要。然而,在二叠纪和白垩纪,腾冲地块与西双版纳和拉萨地块的相关性和演化却存在争议。本研究利用大数据和时空分析,探索岩浆岩所蕴含的信息,为探讨腾冲块体的构造-岩浆演化提供定量约束。为了更准确地评估岩浆活动的真实情况,减少保存和取样过程造成的误差,我们利用局部奇异性分析获得了奇异性指数时间序列。锆石年龄与εHf(t)(相关系数≥0.5)值的相关分析表明,腾冲块体与西布玛苏块体更为相似。时滞交叉相关分析结果表明,腾冲块体和西布玛苏块体的岩浆活动滞后时间较短(3 Myr)。小波分析显示,与碰撞有关的岩浆活动期相似(57 Myr 和 43 Myr)。综合古生物学和蛇绿岩带的证据,我们认为腾冲块体与西双版纳块体的共同演化比与拉萨块体的共同演化更为密切,这表明早二叠世至早白垩世的构造过程相似。大约在250-236Ma,腾冲西部地块由于地壳增厚,下地壳发生部分融化。约 219-213 Ma 和 198-180 Ma,腾冲地块与欧亚大陆碰撞后,中特提斯洋开始俯冲。在 130-111 Ma 前后,中特提斯洋的总体构造特征是自北向南呈剪刀状闭合。
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引用次数: 0
Evaluation of gas content in organic-rich shale: A review of the history, current status, and future directions 富含有机质页岩中气体含量的评估:历史、现状和未来方向回顾
IF 8.5 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-08-31 DOI: 10.1016/j.gsf.2024.101921
Haikuan Nie , Wei Dang , Qin Zhang , Jinchuan Zhang , Pei Li , Shaohua Zhang , Jianghui Ding , Qian Chen , Yubo Feng , Xin Zhang

Shale gas is being hailed as the green energy of the future due to high heating value, low carbon emissions, and large reserves. Gas content of shale is a key parameter for evaluating the shale gas potential and screening for the shale gas sweet spots. Although the concept of gas content has been well defined, obtaining a reliable gas content data still remains a challenge. A significant barrier is the method for evaluating the gas content. In this paper, we provide a review of the long-established and recently developed gas content evaluation methods. In the first part of this review article, the history of gas content evaluation methods is summarized since 1910s, relied on published and unpublished literatures as well as our own experiences. Then, the fundamental contents and concepts involved in gas content evaluation are introduced to provide a clear theoretical foundation for the methods. In the third part, eleven evaluation methods, including four direct methods and seven indirect methods, are systematically reviewed. In each method, its application to evaluating the gas content is presented, the key advances are highlighted, and the advantages and limitations are discussed. Finally, future directions are discussed to promote creative thinking across disciplines to develop new methods or improve current methods for evaluating the gas content more accurately and efficiently.

页岩气因热值高、碳排放量低、储量大而被誉为未来的绿色能源。页岩的含气量是评估页岩气潜力和筛选页岩气甜点的关键参数。虽然含气量的概念已经得到了很好的定义,但获取可靠的含气量数据仍然是一项挑战。一个重要的障碍就是含气量的评估方法。在本文中,我们将对历史悠久和最新开发的含气量评估方法进行综述。在综述文章的第一部分,我们根据已发表和未发表的文献以及自身的经验,总结了自 1910 年代以来气体含量评估方法的历史。然后,介绍了气体含量评价所涉及的基本内容和概念,为这些方法提供了清晰的理论基础。第三部分系统回顾了 11 种评价方法,包括 4 种直接方法和 7 种间接方法。每种方法都介绍了其在含气量评价中的应用,强调了主要进展,并讨论了其优势和局限性。最后,讨论了未来的发展方向,以促进跨学科的创造性思维,开发新方法或改进现有方法,从而更准确、更高效地评估气体含量。
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引用次数: 0
Earth’s tectonic and plate boundary evolution over 1.8 billion years 18 亿年来地球构造和板块边界的演变
IF 8.5 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-08-31 DOI: 10.1016/j.gsf.2024.101922
Xianzhi Cao , Alan S. Collins , Sergei Pisarevsky , Nicolas Flament , Sanzhong Li , Derrick Hasterok , R. Dietmar Müller

Understanding the intricate relationships between the solid Earth and its surface systems in deep time necessitates comprehensive full-plate tectonic reconstructions that include evolving plate boundaries and oceanic plates. In particular, a tectonic reconstruction that spans multiple supercontinent cycles is important to understand the long-term evolution of Earth’s interior, surface environments and mineral resources. Here, we present a new full-plate tectonic reconstruction from 1.8 Ga to present that combines and refines three published models: one full-plate tectonic model spanning 1 Ga to present and two continental-drift models focused on the late Paleoproterozoic to Mesoproterozoic eras. Our model is constrained by geological and geophysical data, and presented as a relative plate motion model in a paleomagnetic reference frame. The model encompasses three supercontinents, Nuna (Columbia), Rodinia, and Gondwana/Pangea, and more than two complete supercontinent cycles, covering ∼40% of the Earth’s history. Our refinements to the base models are focused on times before 1.0 Ga, with minor changes for the Neoproterozoic. For times between 1.8 Ga and 1.0 Ga, the root mean square speeds for all plates generally range between 4 cm/yr and 7 cm/yr (despite short-term fast motion around 1.1 Ga), which are kinematically consistent with post-Pangean plate tectonic constraints. The time span of the existence of Nuna is updated to between 1.6 Ga (1.65 Ga in the base model) and 1.46 Ga based on geological and paleomagnetic data. We follow the base models to leave Amazonia/West Africa separate from Nuna (as well as Western Australia, which only collides with the remnants of Nuna after initial break-up), and South China/India separate from Rodinia. Contrary to the concept of a “boring billion”, our model reveals a dynamic geological history between 1.8 Ga and 0.8 Ga, characterized by supercontinent assembly and breakup, and continuous accretion events. The model is publicly accessible, providing a framework for future refinements and facilitating deep time studies of Earth’s system. We suggest that the model can serve as a valuable working hypothesis, laying the groundwork for future hypothesis testing.

要了解固体地球及其表面系统在深部时间的复杂关系,就必须进行全面的全板块构造重建,其中包括不断演变的板块边界和大洋板块。特别是,跨越多个超大陆周期的构造重建对于了解地球内部、地表环境和矿产资源的长期演化非常重要。在这里,我们提出了一个从 1.8 Ga 到现在的新的全板块构造重建,它结合并完善了三个已发表的模型:一个跨越 1 Ga 到现在的全板块构造模型和两个侧重于晚古生代到中古生代的大陆漂移模型。我们的模型受到地质和地球物理数据的制约,是在古地磁参考框架下的相对板块运动模型。该模型包括三个超大陆,即努纳大陆(哥伦比亚)、罗迪尼亚大陆和冈瓦纳/泛大陆,以及两个以上完整的超大陆周期,涵盖了地球历史的 40%。我们对基本模型的改进主要集中在 1.0 Ga 之前,对新近纪略有改动。在 1.8 Ga 到 1.0 Ga 之间,所有板块的均方根速度一般在 4 cm/yr 到 7 cm/yr 之间(尽管在 1.1 Ga 附近有短期的快速运动),这在运动学上与后泛大陆板块构造的约束相一致。根据地质和古地磁数据,努纳存在的时间跨度更新为 1.6 Ga(基础模型为 1.65 Ga)和 1.46 Ga 之间。我们沿用了基础模型,将亚马孙/西非从努纳星分离出来(以及西澳大利亚,它只是在最初解体后才与努纳星的残余部分相撞),并将华南/印度从罗迪尼亚分离出来。与 "无聊的十亿 "概念相反,我们的模型揭示了 1.8 Ga 到 0.8 Ga 之间的动态地质历史,其特点是超大陆的组装和解体,以及持续的增生事件。该模型可公开访问,为未来的改进提供了一个框架,并促进了对地球系统的深时研究。我们认为该模型可以作为一个有价值的工作假设,为未来的假设检验奠定基础。
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引用次数: 0
Multifaceted natural resources and green energy transformation for sustainable industrial development 多元自然资源和绿色能源转型促进可持续工业发展
IF 8.5 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-08-24 DOI: 10.1016/j.gsf.2024.101919
Desire Wade Atchike , Munir Ahmad , Qingyu Zhang

Climate change is the most phenomenal challenge to humanity, and its roots are intervened with unsustainable industrialization, exercising overexploitation of natural resources. Therefore, the departure from non-renewable to renewables has become inevitable, though thought-provoking. In this respect, we explore how green energy transformation moderates the impacts of multifaceted natural resources on sustainable industrial development in the presence of other covariates involving technological progress, financial development, and economic progress. We compiled data from Group of Seven (G-7) members over the 1995−2018 period and applied panel quantile regression (PQREG) to capture the effects across varying levels of quantiles of sustainable industrial development. Results revealed a positive role of natural gas rents, while coal, forest, and total natural resource rents contributed adverse implications for sustainable industrial development. However, the green energy transformation proved to be the game changer because it not only directly induced sustainable industrial development improvement but also turned the unfavorable effects of coal, forest, and total natural resources into favorable ones by interacting with those multifaceted natural resources. Technological, financial, and economic progress supported sustainable industrial development in G-7 nations, particularly in members with existing middle and upper scales of sustainable industrial development. These findings are robust enough when subjected to different estimation tools. In light of these outcomes, the interaction between green energy transformation and natural resource policy is inevitably critical to attaining natural resource efficiency for sustainable industrial development. Therefore, it is imperative to establish a close policy coordination between advancing green energy technology and allocating natural resource revenue to achieve sustainable development goals (SDGs), with a particular emphasis on SDG-7 and SDG-13.

气候变化是人类面临的最大挑战,其根源在于不可持续的工业化和对自然资源的过度开发。因此,从不可再生能源到可再生能源的转变已成为不可避免的趋势,尽管这一转变发人深省。为此,我们探讨了在技术进步、金融发展和经济进步等其他协变量存在的情况下,绿色能源转型如何调节多元自然资源对工业可持续发展的影响。我们汇编了七国集团(G-7)成员国 1995-2018 年期间的数据,并应用面板量化回归(PQREG)来捕捉不同量化水平的可持续工业发展的影响。结果显示,天然气租金发挥了积极作用,而煤炭、森林和自然资源总租金则对工业可持续发展产生了不利影响。然而,事实证明绿色能源转型改变了游戏规则,因为它不仅直接促使工业可持续发展得到改善,而且通过与煤炭、森林和自然资源总量等多方面的相互作用,将这些不利影响转化为有利影响。技术、金融和经济进步支持了七国集团国家的可持续工业发展,尤其是在可持续工业发展水平处于中上游的国家。这些发现在使用不同的估算工具时都非常可靠。鉴于这些结果,绿色能源转型与自然资源政策之间的互动对于实现自然资源效率以促进可持续工业发展必然至关重要。因此,为实现可持续发展目标(SDGs),特别是 SDG-7 和 SDG-13 目标,必须在推进绿色能源技术与自然资源收入分配之间建立密切的政策协调。
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引用次数: 0
Constraints on the spin-state transition of siderite from laboratory-based Raman spectroscopy and electrical conductivity under high temperature and high pressure 从实验室拉曼光谱和高温高压下的导电性看菱铁矿自旋态转变的制约因素
IF 8.9 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-08-24 DOI: 10.1016/j.gsf.2024.101918
Xinyu Zhang, Lidong Dai, Haiying Hu, Meiling Hong, Chuang Li
The vibrational and electrical transport properties of natural siderite are systematically investigated by means of Raman spectroscopy and alternating current impedance spectroscopy under conditions of 0.6–55.6 GPa, 298–873 K and different hydrostatic environments using a diamond anvil cell (DAC). Upon non-hydrostatic compression, all of these observable characteristic variations of siderite including the appearance of three absolutely new Raman peaks (’, ′ and ′), the disappearance of Raman peaks (, and ) and the discontinuity in the pressure-dependent electrical conductivity can provide robust evidence of electronic spin transitions of Fe from high-spin to mixed-spin to low-spin states at the respective pressures of 42.5 GPa and 48.5 GPa. As far as hydrostatic condition, the electronic spin states from high-spin to mixed-spin to low-spin states occurred at the higher pressures of 45.7 GPa and 50.4 GPa, respectively, which implied the highly sensitive hydrostaticity of electronic spin transition pressures. Upon decompression, the reverse electronic spin transitions from low-spin to mixed-spin to high-spin states were detected at the respective pressures of 47.2 GPa and 28.7 GPa under non-hydrostatic condition, and as well as at the pressures of 49.4 GPa and 25.1 GPa under hydrostatic condition, respectively. The huge pressure hysteresis of 13.8 GPa and 20.6 GPa for the electronic spin state transition was revealed under non-hydrostatic and hydrostatic environments, respectively. In order to explore the effect of temperature on the electronic spin transition, a series of electrical conductivity experiments on siderite were performed over the temperature range of 323–873 K under conditions of three typical pressures of 47.7, 49.8 and 51.6 GPa. Furthermore, the functional relationships between the temperature and pressure describing the high-spin to mixed-spin to low-spin transitions for siderite were successfully established: (GPa) = 39.318 + 0.015 (K) and (GPa) = 41.277 + 0.018 (K), respectively. In conclusion, our acquired phase diagram of the electronic spin transition on siderite is beneficial to deep insight into the electronic spin behavior for those of iron-bearing carbonate minerals under high-temperature and high-pressure conditions.
在 0.6-55.6 GPa、298-873 K 和不同的静水环境条件下,使用金刚石砧电池 (DAC) 通过拉曼光谱和交流阻抗光谱系统地研究了天然菱铁矿的振动和电传输特性。在非静水压力下,菱铁矿的所有这些可观察到的特征变化,包括三个全新拉曼峰('、′和′)的出现、拉曼峰(、和)的消失以及随压力变化的电导率的不连续性,都能有力地证明在 42.5 GPa 和 48.5 GPa 的压力下,铁的电子自旋从高自旋态到混合自旋态再到低自旋态的转变。在静水压条件下,从高自旋态到混合自旋态再到低自旋态的电子自旋态分别发生在较高的压力(45.7 GPa 和 50.4 GPa)下,这意味着电子自旋转变压力具有高度敏感的静水压性。减压时,在非静压条件下,分别在 47.2 GPa 和 28.7 GPa 的压力下,以及在静压条件下,分别在 49.4 GPa 和 25.1 GPa 的压力下,检测到了从低自旋态到混合自旋态再到高自旋态的反向电子自旋跃迁。在非静水和静水环境下,电子自旋态转变的巨大压力滞后分别为 13.8 GPa 和 20.6 GPa。为了探索温度对电子自旋态转变的影响,在 323-873 K 的温度范围内,在 47.7、49.8 和 51.6 GPa 三个典型压力条件下,对菱铁矿进行了一系列电导率实验。此外,还成功建立了描述菱铁矿从高自旋到混合自旋再到低自旋转变的温度和压力之间的函数关系:(GPa) = 39.318 + 0.015 (K) 和 (GPa) = 41.277 + 0.018 (K)。总之,我们获得的菱铁矿电子自旋转变相图有助于深入了解高温高压条件下含铁碳酸盐矿物的电子自旋行为。
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