Porphyry deposits are the largest source of metals (e.g., Cu, Mo, and Au) worldwide, yet it remains unclear whether the ore-forming magmas are anomalously enriched in metals. Numerous studies have suggested that the magmas responsible for ore formation are enriched in metals. However, recent research on melt inclusion (MI) has put forward the proposition that these magmas may not actually be particularly enriched in metals. In this study, we report the metal contents of MIs in quartz and feldspar phenocrysts from four fertile and three barren Miocene post-collisional porphyries in Tibet. Three main types of isolated MIs were identified: glassy, crystalline, and melt–fluid inclusions. TIMA scanning reveals that the crystalline minerals are primarily quartz, orthoclase and albite, occupying >70 %–90 % of the MIs with minimal fluid modification. By comparing the compositions of MIs and whole-rock samples, it is evident that fertile and barren porphyritic magmas have undergone different magmatic evolution processes. The fertile porphyries exhibit anomalously high metal contents (highest Cu contents of 236–1333 ppm), whereas the barren porphyries have highest Cu contents of <100 ppm. Petrographic observations and modeling suggest that the high Cu concentrations cannot be attributed to magmatic evolution. Notebly, the Cu and Cu/Mo values in the Jiama, Bangpu and Zhunuo porphyries follow coherent trends with a distinct “down-up-down” pattern, which is not observed in barren porphyries. These findings indicate that metals were efficiently extracted from the melts into the exsolved fluids during ore formation. We propose that the initial metal enrichment in the melts and the efficiency of metal extraction are key controlling factors in porphyry mineralization.
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