首页 > 最新文献

Holzforschung最新文献

英文 中文
Microscopic computed tomography aided finite element modelling as a methodology to estimate hygroexpansion coefficients of wood: a case study on opposite and compression wood in softwood branches 微观计算机断层扫描辅助有限元建模作为一种方法来估计木材的湿膨胀系数:对软木枝上的对生和压缩木材的案例研究
IF 2.4 3区 农林科学 Q2 FORESTRY Pub Date : 2023-08-31 DOI: 10.1515/hf-2023-0014
S. Florisson, M. Hartwig, M. Wohlert, E. Gamstedt
Abstract Microscopic X-ray computed tomography (XµCT) aided finite element (FE) modelling is a popular method in material science to relate material properties to heterogeneous microstructures. Recently, a methodology was developed for the XµCT aided FE modelling of wood, which characterises the process from specimen preparation to estimation of material properties. In the current research, this methodology is tested on branches of Norway spruce (Picea abies (L.) Karst.) to estimate the hygroexpansion coefficients of opposite (OW) and compression wood (CW). These properties are largely unknown and have engineering implications. The study is complemented by measurements of density, moisture content (MC) and elastic moduli. Results showed that the methodology assisted in the design of an integrated process and the identification of bottlenecks. It was seen that the level of detail of the numerical model had a strong influence on the obtained hygroexpansion properties. CW from branches showed higher density and longitudinal shrinkage coefficients, and elastic moduli less affected by MC. These differences are unlikely caused by MC, but more likely by the characteristics of the microstructure.
微观X射线计算机断层扫描(XµCT)辅助有限元(FE)建模是材料科学中将材料性能与非均相微观结构联系起来的一种流行方法。最近,开发了一种用于XµCT辅助木材有限元建模的方法,该方法描述了从试样制备到材料性能估计的过程。在目前的研究中,这种方法在挪威云杉(Picea abies (L.))的分支上进行了测试。)来估算对生木(OW)和压缩木(CW)的湿膨胀系数。这些特性在很大程度上是未知的,具有工程意义。该研究是由密度,水分含量(MC)和弹性模量的测量补充。结果表明,该方法有助于设计集成过程和识别瓶颈。可以看出,数值模型的细节水平对所得的水膨胀特性有很大的影响。枝状连续枝的密度和纵向收缩系数较高,弹性模量受MC的影响较小,这些差异不太可能是MC造成的,而更可能是由微观结构特征造成的。
{"title":"Microscopic computed tomography aided finite element modelling as a methodology to estimate hygroexpansion coefficients of wood: a case study on opposite and compression wood in softwood branches","authors":"S. Florisson, M. Hartwig, M. Wohlert, E. Gamstedt","doi":"10.1515/hf-2023-0014","DOIUrl":"https://doi.org/10.1515/hf-2023-0014","url":null,"abstract":"Abstract Microscopic X-ray computed tomography (XµCT) aided finite element (FE) modelling is a popular method in material science to relate material properties to heterogeneous microstructures. Recently, a methodology was developed for the XµCT aided FE modelling of wood, which characterises the process from specimen preparation to estimation of material properties. In the current research, this methodology is tested on branches of Norway spruce (Picea abies (L.) Karst.) to estimate the hygroexpansion coefficients of opposite (OW) and compression wood (CW). These properties are largely unknown and have engineering implications. The study is complemented by measurements of density, moisture content (MC) and elastic moduli. Results showed that the methodology assisted in the design of an integrated process and the identification of bottlenecks. It was seen that the level of detail of the numerical model had a strong influence on the obtained hygroexpansion properties. CW from branches showed higher density and longitudinal shrinkage coefficients, and elastic moduli less affected by MC. These differences are unlikely caused by MC, but more likely by the characteristics of the microstructure.","PeriodicalId":13083,"journal":{"name":"Holzforschung","volume":" ","pages":""},"PeriodicalIF":2.4,"publicationDate":"2023-08-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48768811","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Planting spacing influences radial variation of basic density and chemical composition of wood from fast growing young Eucalyptus plantations 种植间距影响速生幼桉树人工林木材基本密度和化学成分的径向变化
IF 2.4 3区 农林科学 Q2 FORESTRY Pub Date : 2023-08-04 DOI: 10.1515/hf-2023-0016
E. M. Pimenta, Emilly Gracielly dos Santos Brito, Paola Freitas Gomes, F. Ramalho, G. B. Vidaurre, A. M. Couto, O. Campoe, P. R. Hein
Abstract Planting spacing plays an important role in tree growth and wood formation. Thus, the aim of this study was to determinate how planting spacing and genetic material affect the radial variation of basic density and chemical composition of wood. The sampling of this study was based on 4 clones of Eucalyptus urophylla × Eucalyptus grandis at 5 years of age planted in four spacings (3 × 1, 3 × 2, 3 × 3 and 3 × 4 m). To determine the basic density (BD), extractive (EXT) and lignin (LT) content, wood discs were removed at breast height, which were sectioned in three radial positions (pith, intermediate and sapwood). The results showed that genetic material, planting spacing and radial position affected the values of BD, EXT and LT content. The BD and EXT content tended to increase with increased planting spacing, while the LT content tended to decrease. In relation to the radial variation, the basic density showed an increase in the pith-bark direction, while the EXT content showed a decrease in this direction. For LT, no significant difference was observed in the pith-bark direction. In general, the largest planting spacings promoted the highest rates of variation of the properties studied.
摘要种植间距在树木生长和木材形成中起着重要作用。因此,本研究的目的是确定种植间距和遗传物质如何影响木材基本密度和化学成分的径向变化。本研究以尾叶桉×巨桉4个5年生无性系为材料,按3×1、3×2、3×3和3×4的间距进行取样 m) 。为了测定基本密度(BD)、提取物(EXT)和木质素(LT)的含量,在胸高处去除木盘,将其分为三个径向位置(髓、中间和边材)。结果表明,遗传物质、种植间距和径向位置对BD、EXT和LT含量有影响。BD和EXT含量随着种植间距的增加而增加,而LT含量则趋于减少。与径向变化有关,基本密度在髓皮方向上增加,而EXT含量在该方向上减少。对于LT,在髓皮方向上没有观察到显著差异。一般来说,最大的种植间距促进了所研究性质的最高变化率。
{"title":"Planting spacing influences radial variation of basic density and chemical composition of wood from fast growing young Eucalyptus plantations","authors":"E. M. Pimenta, Emilly Gracielly dos Santos Brito, Paola Freitas Gomes, F. Ramalho, G. B. Vidaurre, A. M. Couto, O. Campoe, P. R. Hein","doi":"10.1515/hf-2023-0016","DOIUrl":"https://doi.org/10.1515/hf-2023-0016","url":null,"abstract":"Abstract Planting spacing plays an important role in tree growth and wood formation. Thus, the aim of this study was to determinate how planting spacing and genetic material affect the radial variation of basic density and chemical composition of wood. The sampling of this study was based on 4 clones of Eucalyptus urophylla × Eucalyptus grandis at 5 years of age planted in four spacings (3 × 1, 3 × 2, 3 × 3 and 3 × 4 m). To determine the basic density (BD), extractive (EXT) and lignin (LT) content, wood discs were removed at breast height, which were sectioned in three radial positions (pith, intermediate and sapwood). The results showed that genetic material, planting spacing and radial position affected the values of BD, EXT and LT content. The BD and EXT content tended to increase with increased planting spacing, while the LT content tended to decrease. In relation to the radial variation, the basic density showed an increase in the pith-bark direction, while the EXT content showed a decrease in this direction. For LT, no significant difference was observed in the pith-bark direction. In general, the largest planting spacings promoted the highest rates of variation of the properties studied.","PeriodicalId":13083,"journal":{"name":"Holzforschung","volume":" ","pages":""},"PeriodicalIF":2.4,"publicationDate":"2023-08-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44352317","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Fit-free analysis of fluorescence lifetime imaging data using chemometrics approach for rapid and nondestructive wood species classification 使用化学计学方法对荧光寿命成像数据进行无拟合分析,实现木材物种的快速无损分类
IF 2.4 3区 农林科学 Q2 FORESTRY Pub Date : 2023-08-04 DOI: 10.1515/hf-2023-0017
Te Ma, T. Inagaki, S. Tsuchikawa
Abstract Conventional fluorescence spectroscopy has been suggested as a valuable tool for classifying wood species rapidly and non-destructively. However, because it is challenging to conduct absolute emission intensity measurements, fluorescence analysis statistics are difficult to obtain. In this study, another dimension of fluorescence, that is, fluorescence lifetime, was further evaluated to address this issue. A time-resolved fluorescence spectroscopic measurement system was first designed, mainly using a streak camera, picosecond pulsed laser at 403 nm, and a spectroscope, to collect the fluorescence time-delay (FTD) profiles and steady-state fluorescence intensity (FI) spectra simultaneously from 15 wood species. For data analysis, principal component analysis was used to “compress” the mean-centered FTD and FI spectra. Then, support vector machine classification analysis was utilized to train the wood species classification model based on their principal component scores. To avoid overfitting, ten-fold cross-validation was used to train the calibration model using 70 % of the total samples, and the remaining 30 % hold-out validation was used to test its reproducibility. The cross-validation accuracies were 100 % (5 softwoods) and 96 % (10 hardwoods), with test-validation accuracies of 96 % and 89 %.
摘要传统的荧光光谱法被认为是一种快速、无损地对木材进行分类的有价值的工具。然而,由于进行绝对发射强度测量具有挑战性,因此很难获得荧光分析统计数据。在这项研究中,进一步评估了荧光的另一个维度,即荧光寿命,以解决这一问题。首先设计了一个时间分辨荧光光谱测量系统,主要使用条纹相机、皮秒脉冲激光403 nm,和分光镜,同时收集15种木材的荧光时间延迟(FTD)谱和稳态荧光强度(FI)谱。对于数据分析,主成分分析用于“压缩”以平均值为中心的FTD和FI光谱。然后,利用支持向量机分类分析,根据木材的主成分得分,训练木材物种分类模型。为了避免过度拟合,使用10倍交叉验证来训练校准模型,使用70 % 总样本的,以及剩余的30个 % 使用保持验证来测试其再现性。交叉验证准确率为100 % (5种软木)和96 % (10种硬木),测试验证精度为96 % 和89 %.
{"title":"Fit-free analysis of fluorescence lifetime imaging data using chemometrics approach for rapid and nondestructive wood species classification","authors":"Te Ma, T. Inagaki, S. Tsuchikawa","doi":"10.1515/hf-2023-0017","DOIUrl":"https://doi.org/10.1515/hf-2023-0017","url":null,"abstract":"Abstract Conventional fluorescence spectroscopy has been suggested as a valuable tool for classifying wood species rapidly and non-destructively. However, because it is challenging to conduct absolute emission intensity measurements, fluorescence analysis statistics are difficult to obtain. In this study, another dimension of fluorescence, that is, fluorescence lifetime, was further evaluated to address this issue. A time-resolved fluorescence spectroscopic measurement system was first designed, mainly using a streak camera, picosecond pulsed laser at 403 nm, and a spectroscope, to collect the fluorescence time-delay (FTD) profiles and steady-state fluorescence intensity (FI) spectra simultaneously from 15 wood species. For data analysis, principal component analysis was used to “compress” the mean-centered FTD and FI spectra. Then, support vector machine classification analysis was utilized to train the wood species classification model based on their principal component scores. To avoid overfitting, ten-fold cross-validation was used to train the calibration model using 70 % of the total samples, and the remaining 30 % hold-out validation was used to test its reproducibility. The cross-validation accuracies were 100 % (5 softwoods) and 96 % (10 hardwoods), with test-validation accuracies of 96 % and 89 %.","PeriodicalId":13083,"journal":{"name":"Holzforschung","volume":" ","pages":""},"PeriodicalIF":2.4,"publicationDate":"2023-08-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47396039","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Improved bleached eucalyptus kraft pulp-based tissue papers incorporating wet-strength resins 含湿强树脂的改进漂白桉木硫酸盐纸浆基薄纸
IF 2.4 3区 农林科学 Q2 FORESTRY Pub Date : 2023-08-03 DOI: 10.1515/hf-2023-0007
Marina Matos, Ana M. M. S. Carta, P. Pinto, D. Evtuguin
Abstract Common tissue paper manufacturing trends aim at partial or total replacement of softwood pulp with hardwood pulp for its production, such as bleached eucalyptus kraft pulp (BEKP), in order to optimize the process and the final product properties such as softness. However, the use of a single type of hardwood fiber results in lower strengths of both wet and dry webs. To maintain necessary strength and desired properties, the incorporation of several additives is often required. In this context, low molecular weight polyethylene glycol (PEG) and different wet strength resins, such as polyamideamine-epichlorohydrin (PAE) and glyoxalated polyacrylamide (GPAM) resins, were combined to achieve an innovated product with improved properties. In particular, wet and dry tensile strength was significantly improved when combining PEG and wet strength resins, especially observed in tissue papers prepared with PAE resin, high-charge cationic agent and bulk applied aqueous PEG solution. Noteworthy that water absorption capacity and softness of tissue paper were not critically affected by PEG incorporation, regardless of application method used (in bulk or by spray).
常见的生活用纸生产趋势是用硬木纸浆部分或全部替代软木纸浆,如漂白桉树硫酸盐纸浆(BEKP),以优化工艺和最终产品的性能,如柔软性。然而,使用单一类型的硬木纤维会导致湿网和干网的强度降低。为了保持必要的强度和所需的性能,通常需要加入几种添加剂。在这种情况下,低分子量聚乙二醇(PEG)和不同的湿强度树脂,如聚酰胺-环氧氯丙烷(PAE)和乙草酸化聚丙烯酰胺(GPAM)树脂结合在一起,获得了性能更好的创新产品。特别是,当PEG与湿强树脂组合时,湿、干拉伸强度显著提高,特别是在PAE树脂、高电荷阳离子剂和大量应用PEG水溶液制备的生活用纸中。值得注意的是,无论使用何种应用方法(散装或喷雾),PEG掺入对纸巾的吸水能力和柔软度都没有严重影响。
{"title":"Improved bleached eucalyptus kraft pulp-based tissue papers incorporating wet-strength resins","authors":"Marina Matos, Ana M. M. S. Carta, P. Pinto, D. Evtuguin","doi":"10.1515/hf-2023-0007","DOIUrl":"https://doi.org/10.1515/hf-2023-0007","url":null,"abstract":"Abstract Common tissue paper manufacturing trends aim at partial or total replacement of softwood pulp with hardwood pulp for its production, such as bleached eucalyptus kraft pulp (BEKP), in order to optimize the process and the final product properties such as softness. However, the use of a single type of hardwood fiber results in lower strengths of both wet and dry webs. To maintain necessary strength and desired properties, the incorporation of several additives is often required. In this context, low molecular weight polyethylene glycol (PEG) and different wet strength resins, such as polyamideamine-epichlorohydrin (PAE) and glyoxalated polyacrylamide (GPAM) resins, were combined to achieve an innovated product with improved properties. In particular, wet and dry tensile strength was significantly improved when combining PEG and wet strength resins, especially observed in tissue papers prepared with PAE resin, high-charge cationic agent and bulk applied aqueous PEG solution. Noteworthy that water absorption capacity and softness of tissue paper were not critically affected by PEG incorporation, regardless of application method used (in bulk or by spray).","PeriodicalId":13083,"journal":{"name":"Holzforschung","volume":" ","pages":""},"PeriodicalIF":2.4,"publicationDate":"2023-08-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45308043","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Frontmatter 头版头条
3区 农林科学 Q2 FORESTRY Pub Date : 2023-08-01 DOI: 10.1515/hf-2023-frontmatter8
{"title":"Frontmatter","authors":"","doi":"10.1515/hf-2023-frontmatter8","DOIUrl":"https://doi.org/10.1515/hf-2023-frontmatter8","url":null,"abstract":"","PeriodicalId":13083,"journal":{"name":"Holzforschung","volume":"28 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136065443","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Site quality impacts tree form, heartwood content and veneer production of plantation-grown Pinus patula 立地质量影响人工林带松的树形、心材含量和单板产量
IF 2.4 3区 农林科学 Q2 FORESTRY Pub Date : 2023-07-27 DOI: 10.1515/hf-2023-0031
J. van der Merwe, Sechaba Madiope, Olwethu Spogter, Hilton Kuisis, J. Potgieter, Oscar Tait, Charles D. Clarke, S. Mansfield
Abstract Plantation forest species were introduced into South Africa due to limited availability of native forests for wood-derived products. Currently, the Mexican pine species, Pinus patula, is the most widely planted softwood species in the country. To study the effect of growth environment on wood and processing properties for the species, sample plots were established in a 20-year rotation covering a wide range of soil geologies and altitudes in Mpumalanga, South Africa. Temperature and seasonal rainfall were also determined for the sample plots. Randomly selected sample trees were harvested from the plots and processed at a plywood plant to determine veneer recovery and quality. Trees grown on sites composed of granite soils, with higher annual maximum temperatures and less rainfall, found in the Highveld region, displayed superior tree size, slenderness, and volume growth, compared to trees grown on dolomite and shale soils common to the Lowveld region. Veneer derived from Lowveld trees had more splits which were largely related to defects. Larger trees also had a greater percentage volumetric heartwood and a smaller live crown, compared to smaller trees. Highveld trees had greater net veneer recovery and produced better quality veneer than trees grown on the Lowveld. In the Mpumalanga forestry region, strong co-relatedness exists between soil geology, altitude, and climate. Although tree form and wood properties were found to differ with varying soil geology and altitude, these differences were primarily related to climate rather than soil properties. These findings highlight the pitfalls associated with neglecting either climate or soil properties when analysing site-specific growing conditions on tree growth and form.
由于南非原生林的木材衍生产品有限,人工林物种被引入南非。目前,墨西哥松是该国种植最广泛的针叶树种。为了研究生长环境对该树种木材和加工特性的影响,在南非Mpumalanga建立了覆盖广泛土壤地质和海拔的样地,每20年轮作一次。还测定了样地的温度和季节降雨量。从地块中随机选择样本树,并在胶合板工厂进行处理,以确定单板的恢复和质量。与生长在低草原地区常见的白云岩和页岩土壤上的树木相比,生长在花岗岩土壤上的树木,年最高温度更高,降雨量更少,在高草原地区发现的树木,表现出更好的树木大小,细细度和体积生长。来自Lowveld树木的贴面有更多的裂缝,这在很大程度上与缺陷有关。与较小的树木相比,较大的树木也有较大的体积心材百分比和较小的活树冠。高原树木比低地树木有更大的净贴面恢复和更好的贴面质量。在普马兰加森林地区,土壤地质、海拔和气候之间存在很强的相关关系。虽然发现树木形态和木材性质随土壤地质和海拔的不同而不同,但这些差异主要与气候有关,而不是与土壤性质有关。这些发现强调了在分析特定地点的生长条件对树木生长和形态的影响时忽视气候或土壤特性所带来的缺陷。
{"title":"Site quality impacts tree form, heartwood content and veneer production of plantation-grown Pinus patula","authors":"J. van der Merwe, Sechaba Madiope, Olwethu Spogter, Hilton Kuisis, J. Potgieter, Oscar Tait, Charles D. Clarke, S. Mansfield","doi":"10.1515/hf-2023-0031","DOIUrl":"https://doi.org/10.1515/hf-2023-0031","url":null,"abstract":"Abstract Plantation forest species were introduced into South Africa due to limited availability of native forests for wood-derived products. Currently, the Mexican pine species, Pinus patula, is the most widely planted softwood species in the country. To study the effect of growth environment on wood and processing properties for the species, sample plots were established in a 20-year rotation covering a wide range of soil geologies and altitudes in Mpumalanga, South Africa. Temperature and seasonal rainfall were also determined for the sample plots. Randomly selected sample trees were harvested from the plots and processed at a plywood plant to determine veneer recovery and quality. Trees grown on sites composed of granite soils, with higher annual maximum temperatures and less rainfall, found in the Highveld region, displayed superior tree size, slenderness, and volume growth, compared to trees grown on dolomite and shale soils common to the Lowveld region. Veneer derived from Lowveld trees had more splits which were largely related to defects. Larger trees also had a greater percentage volumetric heartwood and a smaller live crown, compared to smaller trees. Highveld trees had greater net veneer recovery and produced better quality veneer than trees grown on the Lowveld. In the Mpumalanga forestry region, strong co-relatedness exists between soil geology, altitude, and climate. Although tree form and wood properties were found to differ with varying soil geology and altitude, these differences were primarily related to climate rather than soil properties. These findings highlight the pitfalls associated with neglecting either climate or soil properties when analysing site-specific growing conditions on tree growth and form.","PeriodicalId":13083,"journal":{"name":"Holzforschung","volume":" ","pages":""},"PeriodicalIF":2.4,"publicationDate":"2023-07-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45534028","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Comparative investigation of chemical and structural properties of charred fir wood samples by Raman and FTIR spectroscopy as well as X-ray-micro-CT technology 利用拉曼光谱和傅里叶红外光谱以及x射线显微ct技术对炭化杉木样品的化学和结构特性进行了对比研究
IF 2.4 3区 农林科学 Q2 FORESTRY Pub Date : 2023-07-24 DOI: 10.1515/hf-2023-0024
D. Ebner, M. Tortora, D. Bedolla, G. Saccomano, L. Vaccari, M. Barbu, J. Grzybek, T. Schnabel
Abstract Wood surface charring is a treatment method commonly employed to enhance weather protection and aesthetic appearance of building exteriors. This study aims to investigate the differences between two wood surface charring processes: the traditional Japanese method known as Yakisugi and an alternative charring technique industrially manufactured with a gas burner. The objective of the study was to assess whether a thicker layer after Yakisugi treatment has any advantages over a thinner layer after the alternative process. Vibrational spectroscopy techniques including UV resonance Raman (UVRR) and Fourier transform infrared (FTIR) spectroscopy, were utilized in conjunction with X-ray-micro-CT analysis. The findings revealed that ATR-FTIR spectroscopy detected the degradation of carbohydrates and changes in lignin within the charred surface, although both processes exhibited similar vibrational contributions. In contrast, UVRR spectroscopy provided insights into the carbonized layers, revealing spectral differences indicating variations in temperature during the charring processes. X-ray micro-CT analysis visually highlighted significant differences in the coal layers, suggesting distinct combustion profiles. Remarkably, the macrostructure of wood treated with Yakisugi remained intact despite a thicker charred layer compared to the alternative charring techniques. However, further investigations are required to assess the weather stability of the alternative charring method for a comprehensive understanding.
摘要木材表面炭化是提高建筑外观耐候性和美观性的常用处理方法。本研究旨在研究两种木材表面炭化工艺之间的差异:日本传统的Yakisugi方法和工业上使用燃气燃烧器制造的替代炭化技术。该研究的目的是评估Yakisugi处理后的较厚层是否比替代工艺后的较薄层有任何优势。振动光谱技术,包括紫外共振拉曼(UVRR)和傅里叶变换红外(FTIR)光谱,与X射线微CT分析结合使用。研究结果表明,ATR-FTIR光谱检测到烧焦表面内碳水化合物的降解和木质素的变化,尽管这两个过程都表现出相似的振动贡献。相比之下,UVRR光谱提供了对碳化层的深入了解,揭示了表明碳化过程中温度变化的光谱差异。X射线显微CT分析直观地突出了煤层的显著差异,表明了不同的燃烧剖面。值得注意的是,与其他炭化技术相比,尽管烧焦层更厚,但用烧木处理的木材的宏观结构仍然完好无损。然而,为了全面了解替代炭化方法的天气稳定性,还需要进行进一步的调查。
{"title":"Comparative investigation of chemical and structural properties of charred fir wood samples by Raman and FTIR spectroscopy as well as X-ray-micro-CT technology","authors":"D. Ebner, M. Tortora, D. Bedolla, G. Saccomano, L. Vaccari, M. Barbu, J. Grzybek, T. Schnabel","doi":"10.1515/hf-2023-0024","DOIUrl":"https://doi.org/10.1515/hf-2023-0024","url":null,"abstract":"Abstract Wood surface charring is a treatment method commonly employed to enhance weather protection and aesthetic appearance of building exteriors. This study aims to investigate the differences between two wood surface charring processes: the traditional Japanese method known as Yakisugi and an alternative charring technique industrially manufactured with a gas burner. The objective of the study was to assess whether a thicker layer after Yakisugi treatment has any advantages over a thinner layer after the alternative process. Vibrational spectroscopy techniques including UV resonance Raman (UVRR) and Fourier transform infrared (FTIR) spectroscopy, were utilized in conjunction with X-ray-micro-CT analysis. The findings revealed that ATR-FTIR spectroscopy detected the degradation of carbohydrates and changes in lignin within the charred surface, although both processes exhibited similar vibrational contributions. In contrast, UVRR spectroscopy provided insights into the carbonized layers, revealing spectral differences indicating variations in temperature during the charring processes. X-ray micro-CT analysis visually highlighted significant differences in the coal layers, suggesting distinct combustion profiles. Remarkably, the macrostructure of wood treated with Yakisugi remained intact despite a thicker charred layer compared to the alternative charring techniques. However, further investigations are required to assess the weather stability of the alternative charring method for a comprehensive understanding.","PeriodicalId":13083,"journal":{"name":"Holzforschung","volume":" ","pages":""},"PeriodicalIF":2.4,"publicationDate":"2023-07-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44029533","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Swelling behavior of thermally modified timber from a cellular and chemical perspective 从细胞和化学角度看热改性木材的膨胀行为
IF 2.4 3区 农林科学 Q2 FORESTRY Pub Date : 2023-07-17 DOI: 10.1515/hf-2023-0033
Yufa Gao, Yongdong Zhou, Zongying Fu, J. Van den Bulcke, J. Van Acker
Abstract Thermally modified timber (TMT) reduces hygroscopicity, increases dimensional stability, and decay resistance. Although there is a substantial amount of research on heat-treated wood, investigations on the sensitivity of cell wall swelling behavior to water variation are limited. Therefore, this study focused on the swelling behavior of TMT from cellular and chemical perspectives. The effects of heat treatment on the hygroscopicity and swelling behavior of the wood cell walls were studied using dynamic vapor sorption and confocal laser scanning microscopy. Changes in the chemical composition and cellulose crystallinity were studied using attenuated total reflectance Fourier transform infrared spectroscopy (ATR-FTIR) and X-ray diffraction. The results revealed that the hygroscopic swelling of latewood significantly decreased with increasing treatment temperature, reducing the anisotropy of the wood cell swelling. The hygroscopicity of wood was reduced by heat treatment, and a clear decrease in hysteresis was observed at elevated treatment temperatures. The FTIR spectra indicated that both hemicellulose and lignin were degraded. The crystallinity and lateral size of the cellulose increased after heat treatment. Similar changes in the chemical composition and crystallinity of cellulose were observed in the latewood and earlywood.
热改性木材(TMT)降低吸湿性,增加尺寸稳定性和抗腐性。虽然有大量的研究对热处理木材,研究的敏感性的细胞壁膨胀行为对水的变化是有限的。因此,本研究主要从细胞和化学角度研究TMT的溶胀行为。采用动态蒸汽吸附和激光共聚焦扫描显微镜研究了热处理对木材细胞壁吸湿性和溶胀性的影响。利用衰减全反射傅里叶变换红外光谱(ATR-FTIR)和x射线衍射研究了纤维素化学成分和结晶度的变化。结果表明:随着处理温度的升高,红木的吸湿性溶胀显著降低,降低了木材细胞溶胀的各向异性;热处理降低了木材的吸湿性,并且在升高的处理温度下观察到迟滞明显减少。红外光谱分析表明,半纤维素和木质素均被降解。热处理后纤维素的结晶度和横向尺寸增大。在晚木和早木中,纤维素的化学成分和结晶度也发生了类似的变化。
{"title":"Swelling behavior of thermally modified timber from a cellular and chemical perspective","authors":"Yufa Gao, Yongdong Zhou, Zongying Fu, J. Van den Bulcke, J. Van Acker","doi":"10.1515/hf-2023-0033","DOIUrl":"https://doi.org/10.1515/hf-2023-0033","url":null,"abstract":"Abstract Thermally modified timber (TMT) reduces hygroscopicity, increases dimensional stability, and decay resistance. Although there is a substantial amount of research on heat-treated wood, investigations on the sensitivity of cell wall swelling behavior to water variation are limited. Therefore, this study focused on the swelling behavior of TMT from cellular and chemical perspectives. The effects of heat treatment on the hygroscopicity and swelling behavior of the wood cell walls were studied using dynamic vapor sorption and confocal laser scanning microscopy. Changes in the chemical composition and cellulose crystallinity were studied using attenuated total reflectance Fourier transform infrared spectroscopy (ATR-FTIR) and X-ray diffraction. The results revealed that the hygroscopic swelling of latewood significantly decreased with increasing treatment temperature, reducing the anisotropy of the wood cell swelling. The hygroscopicity of wood was reduced by heat treatment, and a clear decrease in hysteresis was observed at elevated treatment temperatures. The FTIR spectra indicated that both hemicellulose and lignin were degraded. The crystallinity and lateral size of the cellulose increased after heat treatment. Similar changes in the chemical composition and crystallinity of cellulose were observed in the latewood and earlywood.","PeriodicalId":13083,"journal":{"name":"Holzforschung","volume":" ","pages":""},"PeriodicalIF":2.4,"publicationDate":"2023-07-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48587440","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Antifungal properties of lauric arginate (LAE) treated wood 月桂酸酯(LAE)处理木材的抗真菌性能
IF 2.4 3区 农林科学 Q2 FORESTRY Pub Date : 2023-07-10 DOI: 10.1515/hf-2023-0013
Courage Alorbu, Joshua Carey, A. McDonald, Li-Juan Cai
Abstract This study investigated the efficacy of lauric arginate (LAE) as a potential preservative against wood deteriorating fungi. First, the antifungal properties of LAE against two brown rot fungi, Gloeophyllum trabeum (G.t.) and Rhodonia placenta (R.p.), and two white rot fungi, Trametes versicolor (T.v.) and Irpex lacteus (I.l.) were examined using malt-agar media as substrate. Then the biological resistance of LAE-treated wood specimens (10, 20, and 25 % LAE solutions) was tested following American Wood Protection Association (AWPA) E10 soil-block test procedures. The in vitro study showed LAE actively inhibited the growth of all the fungi tested compared to growth in control plates but there were no considerable changes observed in the morphology of fungi hyphae. Wood impregnated with LAE showed increased weight percent gain as a function of treatment concentration. Characterization of LAE-treated wood on a thermogravimetric analyzer showed LAE shifted the thermal degradation temperatures to lower stages but did not significantly improve the thermal stability of the treated specimen. LAE in wood significantly suppressed fungus growth, leading to decreased mass loss but it also leached out from wood specimens during fungi exposure.
摘要本研究探讨了月桂精氨酸(LAE)作为木材变质真菌的潜在防腐剂的防腐效果。首先,以麦芽-琼脂培养基为底物,研究了LAE对两种褐腐真菌Gloeophyllum trabeum (g.t.)和Rhodonia胎盘(r.p.)以及两种白腐真菌Trametes versicolor (t.v.)和Irpex lacteus (i.l.)的抑菌性能。然后按照美国木材保护协会(AWPA) E10土块试验程序测试LAE处理的木材样品(10、20和25 % LAE溶液)的生物抗性。体外研究表明,与对照板相比,LAE对所有真菌的生长都有抑制作用,但真菌菌丝形态没有明显变化。LAE浸渍木材的增重率随处理浓度的增加而增加。用热重分析仪对LAE处理过的木材进行表征,结果表明LAE将热降解温度转移到较低的阶段,但并没有显著改善处理过的木材的热稳定性。木材中的LAE显著抑制真菌生长,导致质量损失减少,但在真菌暴露过程中也会从木材样品中浸出。
{"title":"Antifungal properties of lauric arginate (LAE) treated wood","authors":"Courage Alorbu, Joshua Carey, A. McDonald, Li-Juan Cai","doi":"10.1515/hf-2023-0013","DOIUrl":"https://doi.org/10.1515/hf-2023-0013","url":null,"abstract":"Abstract This study investigated the efficacy of lauric arginate (LAE) as a potential preservative against wood deteriorating fungi. First, the antifungal properties of LAE against two brown rot fungi, Gloeophyllum trabeum (G.t.) and Rhodonia placenta (R.p.), and two white rot fungi, Trametes versicolor (T.v.) and Irpex lacteus (I.l.) were examined using malt-agar media as substrate. Then the biological resistance of LAE-treated wood specimens (10, 20, and 25 % LAE solutions) was tested following American Wood Protection Association (AWPA) E10 soil-block test procedures. The in vitro study showed LAE actively inhibited the growth of all the fungi tested compared to growth in control plates but there were no considerable changes observed in the morphology of fungi hyphae. Wood impregnated with LAE showed increased weight percent gain as a function of treatment concentration. Characterization of LAE-treated wood on a thermogravimetric analyzer showed LAE shifted the thermal degradation temperatures to lower stages but did not significantly improve the thermal stability of the treated specimen. LAE in wood significantly suppressed fungus growth, leading to decreased mass loss but it also leached out from wood specimens during fungi exposure.","PeriodicalId":13083,"journal":{"name":"Holzforschung","volume":"77 1","pages":"640 - 647"},"PeriodicalIF":2.4,"publicationDate":"2023-07-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42810028","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Natural durability and fungal diversity of five wood species in a field-test site in Jeongseon, Korea 韩国旌善地区5种木材的自然耐久性和真菌多样性
IF 2.4 3区 农林科学 Q2 FORESTRY Pub Date : 2023-07-10 DOI: 10.1515/hf-2023-0034
Sae-Min Yoon, Min-ji Kim, W. Hwang, Hyun-Mi Lee, Yonggun Park, Dong-Won Son, Yeong-Suk Kim, Yong-Seok Choi
Abstract Climate change from global warming raises the risk of wood decay. Knowing the inherent durability period of wood is crucial for long-term use. Hence, the natural durability of five important Korean wood species (Larix kaempferi, Pinus densiflora, Quercus rubra, Quercus variabilis, and Quercus serrata) was evaluated. In addition, the fungal diversity isolated from each wood stake was investigated to compare and analyze the differences in natural durability. The natural durability of the five wood species was determined to be highest in Larix kaempferi and Quercus serrata, followed by Quercus variabilis, Quercus rubra, and Pinus densiflora. Overall, 306 fungal isolates were collected, including 16 species of Ascomycota, 22 species of Basidiomycota, 15 species of Zygomycota, and eight unidentified species, which dominate different positions of the wood stake. Less Basidiomycota diversity was observed in the two wood species with high durability. In addition, the isolation of not only Basidiomycota but also Ascomycota and Zygomycota could affect wood deterioration and explain the association with wood durability. These findings are expected to be useful in improving the durability of useful wood in Korea in an era of climate change, where the risk of wood decay is increasing.
摘要全球变暖引起的气候变化增加了木材腐烂的风险。了解木材固有的耐用性对于长期使用至关重要。因此,对五种重要的韩国木材(山奈落叶松、赤松、红栎、栓皮栎和锯齿栎)的自然耐久性进行了评估。此外,还对从每个木桩中分离出的真菌多样性进行了调查,以比较和分析天然耐久性的差异。五种木材的自然耐久性最高的是山奈落叶松和锯齿栎,其次是栓皮栎、红栎和赤松。总共收集了306个真菌分离株,包括16种子囊菌门、22种担子菌门、15种接合菌门和8个未鉴定的物种,它们在木桩的不同位置占主导地位。在具有高耐久性的两种木材中观察到较少的担子菌门多样性。此外,不仅担子菌门的分离,而且子囊菌门和结霉菌门的分离都可能影响木材的劣化,并解释其与木材耐久性的关系。在气候变化时代,木材腐烂的风险正在增加,这些发现有望有助于提高韩国有用木材的耐用性。
{"title":"Natural durability and fungal diversity of five wood species in a field-test site in Jeongseon, Korea","authors":"Sae-Min Yoon, Min-ji Kim, W. Hwang, Hyun-Mi Lee, Yonggun Park, Dong-Won Son, Yeong-Suk Kim, Yong-Seok Choi","doi":"10.1515/hf-2023-0034","DOIUrl":"https://doi.org/10.1515/hf-2023-0034","url":null,"abstract":"Abstract Climate change from global warming raises the risk of wood decay. Knowing the inherent durability period of wood is crucial for long-term use. Hence, the natural durability of five important Korean wood species (Larix kaempferi, Pinus densiflora, Quercus rubra, Quercus variabilis, and Quercus serrata) was evaluated. In addition, the fungal diversity isolated from each wood stake was investigated to compare and analyze the differences in natural durability. The natural durability of the five wood species was determined to be highest in Larix kaempferi and Quercus serrata, followed by Quercus variabilis, Quercus rubra, and Pinus densiflora. Overall, 306 fungal isolates were collected, including 16 species of Ascomycota, 22 species of Basidiomycota, 15 species of Zygomycota, and eight unidentified species, which dominate different positions of the wood stake. Less Basidiomycota diversity was observed in the two wood species with high durability. In addition, the isolation of not only Basidiomycota but also Ascomycota and Zygomycota could affect wood deterioration and explain the association with wood durability. These findings are expected to be useful in improving the durability of useful wood in Korea in an era of climate change, where the risk of wood decay is increasing.","PeriodicalId":13083,"journal":{"name":"Holzforschung","volume":"77 1","pages":"577 - 584"},"PeriodicalIF":2.4,"publicationDate":"2023-07-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42427753","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Holzforschung
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1