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Cover Picture: Compatibility of Molybdenum Disulfide and Magnesium Fluorinated Alkoxyaluminate Electrolytes in Rechargeable Mg Batteries (Batteries & Supercaps 9/2024) 封面图片:二硫化钼和氟化烷氧基铝酸镁电解质在可充电镁电池中的兼容性(电池与超级电容器 9/2024)
IF 5.1 4区 材料科学 Q2 ELECTROCHEMISTRY Pub Date : 2024-09-09 DOI: 10.1002/batt.202480901
Omar Falyouna, Mohd Faizul Idham, Osama Eljamal, Toshihiko Mandai

The Front Cover shows how the sluggish (de)intercalation of Mg2+ in MoS2 cathode materials was overcome by using Mg2+/Li+ dual-salt electrolytes. The simultaneous insertion of Mg2+ and Li+ ions notably boosted the electrochemical performance of MoS2 in rechargeable magnesium batteries allowing the cell to achieve a remarkable initial specific capacity of 100 mAh g−1, almost three times higher than the specific capacity of MoS2 in Mg single-salt electrolytes. More information can be found in the Research Article by O. Falyouna, T. Mandai and co-workers (DOI: 10.1002/batt.202400231).

封面展示了如何通过使用 Mg2+/Li+ 双盐电解质克服 Mg2+ 在 MoS2 阴极材料中缓慢(脱)插殖的问题。Mg2+ 和 Li+ 离子的同时插入显著提高了 MoS2 在可充电镁电池中的电化学性能,使电池的初始比容量达到 100 mAh g-1,几乎是在镁单盐电解质中 MoS2 比容量的三倍。更多信息,请参阅 O. Falyouna、T. Mandai 及其合作者的研究文章(DOI: 10.1002/batt.202400231)。
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引用次数: 0
Glyoxylic-Acetal-Based Gel-Polymer Electrolytes for Lithium-Ion Batteries 用于锂离子电池的乙醛基凝胶聚合物电解质
IF 5.1 4区 材料科学 Q2 ELECTROCHEMISTRY Pub Date : 2024-09-09 DOI: 10.1002/batt.202400453
Christian Leibing, Simon Muench, Juan Luis Gómez Urbano, Ulrich S. Schubert, Andrea Balducci

This work focuses on the combination of two strategies to improve the safety of lithium-ion batteries: The use of a glyoxylic-acetal, 1,1,2,2-tetraethoxyethane, in the solvent blend to reduce the flammability of the liquid electrolyte and further its confinement inside of a methacrylate-based polymer matrix, to prevent electrolyte leakage from the battery cells. Physicochemical characterizations of this novel gel-polymer electrolyte (GPE) confirm its improved thermal properties and suitable ionic conductivity, as well as electrochemical stability window. Tests in LFP and hard carbon half-cells vs. lithium metal show that the combination of glyoxylic-acetal-based electrolyte and the methacrylate-based polymer matrix can promote lithium-ion intercalation and deintercalation with stable capacity values. The application in lithium-ion battery full cells furthermore shows that the GPE can promote a similar performance compared to the respective liquid electrolyte and can therefore make possible the realization of energy storage devices with improved safety characteristics.

这项工作的重点是结合两种策略来提高锂离子电池的安全性:在混合溶剂中使用乙醛--1,1,2,2-四乙氧基乙烷来降低液态电解质的易燃性,并进一步将其封闭在甲基丙烯酸酯基聚合物基质中,以防止电解质从电池单元中泄漏。对这种新型凝胶聚合物电解质(GPE)进行的物理化学表征证实,它具有更好的热性能、合适的离子导电性以及电化学稳定性窗口。锂离子电池和硬碳半电池与锂金属的对比测试表明,乙醛基电解质与甲基丙烯酸酯基聚合物基质的结合可促进锂离子插层和脱插,并具有稳定的容量值。在锂离子电池全电池中的应用进一步表明,与相应的液态电解质相比,乙二醛基电解质能促进类似的性能,因此可以实现具有更好安全特性的储能装置。
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引用次数: 0
Increasing Specific Capacitance by Optimization of the Thickness of Carbon Electrodes 通过优化碳电极厚度提高比电容
IF 5.1 4区 材料科学 Q2 ELECTROCHEMISTRY Pub Date : 2024-09-06 DOI: 10.1002/batt.202400388
Veronika Zahorodna, Denys S. Butenko, Iryna Roslyk, Ivan Baginskyi, Volodymyr Izotov, Oleksiy Gogotsi

Increasing energy density without sacrificing the lifetime, power and cyclability of electrochemical capacitors is a very important goal. However, most efforts are directed toward the improvement of active charge-storing materials, while the design of devices and minimization of the weight/volume of the passive component have received less attention. We propose here a mathematical model of a carbon supercapacitor in organic electrolyte, which establishes a relationship between the specific capacitance of a device, the thickness of its electrodes, and the weight of its passive components (case, external current leads, current collectors, etc.). The model was built based on experimentally obtained dependences and has been validated using experiments with electrodes made of two porous carbon materials. Regardless of the pore size distribution in the specified range of electrode thicknesses, the functional dependence of the electrode's specific capacitance on the thickness is well described within the linear approximation. The developed model enables optimization of the electrode thickness, thus maximizing specific energy density for a chosen carbon electrode material.

在不牺牲电化学电容器的使用寿命、功率和循环性的前提下提高能量密度是一个非常重要的目标。然而,大多数人都在努力改进有源电荷存储材料,而设备设计和最大限度地减少无源元件的重量/体积却较少受到关注。我们在此提出了有机电解质中碳超级电容器的数学模型,该模型确定了设备的比电容、电极厚度和无源元件(外壳、外部电流导线、集流器等)重量之间的关系。该模型是根据实验获得的相关性建立的,并通过使用两种多孔碳材料制成的电极进行实验进行了验证。在指定的电极厚度范围内,无论孔径分布如何,电极的比电容与厚度的函数关系都在线性近似范围内得到了很好的描述。利用所建立的模型可以优化电极厚度,从而最大限度地提高所选碳电极材料的比能量密度。
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引用次数: 0
Automated Robotic Cell Fabrication Technology for Stacked-Type Lithium-Oxygen Batteries 堆叠式锂氧电池的自动机器人电池制造技术
IF 5.1 4区 材料科学 Q2 ELECTROCHEMISTRY Pub Date : 2024-09-06 DOI: 10.1002/batt.202400509
Shoichi Matsuda, Shin Kimura, Misato Takahashi

Rechargeable lithium-oxygen batteries (LOBs) are gaining interest as next-generation energy storage devices due to their superior theoretical energy density. While recent years have seen successful operation of LOBs with high cell-level energy density, the technology for cell fabrication is still in its infancy. This is because the cell fabrication procedure for LOBs is quite different from that of conventional lithium-ion batteries. The study presents a fully automated sequential robotic experimental setup for the fabrication of stacked-type LOB cells. This approach allows for high accuracy and high throughput fabrication of the cells. The developed system enables the fabrication of over 80 cells per day, which is 10 times higher than conventional human-based experiments. In addition, the high alignment accuracy during the electrode stacking and electrolyte injection process results in improved battery performance and reproducibility. The effectiveness of the developed system was also confirmed by investigating a multi-component electrolyte to maximize battery performance. We believe the methodology demonstrated in the present study is beneficial for accelerating the research and development of LOBs.

可充电锂氧电池(LOB)因其超强的理论能量密度而成为下一代储能设备,并受到越来越多的关注。近年来,具有高电池级能量密度的锂氧电池已成功投入使用,但电池制造技术仍处于起步阶段。这是因为 LOB 的电池制造程序与传统的锂离子电池制造程序大不相同。本研究介绍了一种用于制造叠层型 LOB 电池的全自动顺序机器人实验装置。这种方法可实现电池的高精度和高产能制造。所开发的系统每天可制造 80 多个电池,是传统人工实验的 10 倍。此外,电极堆叠和电解液注入过程中的高对准精度也提高了电池性能和可重复性。我们还通过研究多组分电解液来最大限度地提高电池性能,从而证实了所开发系统的有效性。我们相信,本研究中展示的方法有利于加速 LOB 的研究和开发。
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引用次数: 0
The Role and Substitution of Cobalt in the Cobalt-Lean/Free Nickel-Based Layered Transition Metal Oxides for Lithium Ion Batteries 钴在用于锂离子电池的无钴/无镍层状过渡金属氧化物中的作用和替代物
IF 5.1 4区 材料科学 Q2 ELECTROCHEMISTRY Pub Date : 2024-09-04 DOI: 10.1002/batt.202400437
Taifan Yang, Zhenxin Huang, Chengyong Shu, Xiaowei Wang, Zexun Tang, Wei Tang, Kai Zhu, Yuping Wu

The Nickel-based layered transition metal oxide cathode represented by NCM (LiNixCoyMnzO2, x+y+z=1) and NCA (LiNixCoyAlzO2, x+y+z=1) is widely used in the electric vehicle market due to its specific capacity and high working potential, in which Cobalt (Co) plays a huge role in improving the structural stability during the cycle. However, the limited supply of Co, due to its scarcity and the influence of geopolitics, poses a significant constraint on the further advancement of the Nickel-based layered transition metal oxide cathode in the field of energy storage. In this paper, the mechanism of Co in the Nickel-based layered transition metal oxides is reviewed, including its critical role for structural stability such as the inhibition of cationic mixing and the release of lattice oxygen et al. Subsequently, it outlines various strategies to enhance the performance of Co-lean/free materials, such as ion doping, including single-ion doping and multi-ion co-doping, and various surface coating strategies, so as to eliminate the adverse effects of Co loss on materials. Ultimately, this paper offers a glimpse into the promising future of Cobalt-free strategies for high performance of Nickel-based layered transition metal oxides.

以 NCM(LiNixCoyMnzO2,x+ y + z = 1)和 NCA(LiNixCoyAlzO2,x+ y + z = 1)为代表的镍基层状过渡金属氧化物阴极因其比容量和高工作潜能而广泛应用于电动汽车市场,其中钴(Co)在提高循环过程中的结构稳定性方面发挥了巨大作用。然而,由于钴的稀缺性和地缘政治的影响,钴的供应有限,这严重制约了镍基层状过渡金属氧化物阴极在储能领域的进一步发展。本文综述了镍基层状过渡金属氧化物中钴的作用机理,包括钴对结构稳定性的关键作用,如抑制阳离子混合和释放晶格氧等,随后总结了提高无钴材料性能的各种策略,如离子掺杂(包括单离子掺杂和多离子共掺杂)和各种表面涂层策略,以消除钴损耗对材料的不利影响。最终,本文让人们看到了镍基层状过渡金属氧化物高性能化的无钴战略的美好前景。
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引用次数: 0
Advanced Electrolyte Systems with Sultones Additives for High-Voltage Lithium Batteries 用于高压锂电池的含苏尔通添加剂的先进电解质系统
IF 5.1 4区 材料科学 Q2 ELECTROCHEMISTRY Pub Date : 2024-09-04 DOI: 10.1002/batt.202400477
Haojie Wan, Siqi Zhong, Yifan Liu, Yifei Xiong, Ting He, Rong Zeng, Shuang Cai, Jianwen Liu

The new energy market is growing rapidly, lithium batteries (LBs) as the most important source of energy supply in the energy storage and power market, has higher requirements for fast charge and long life, so it is necessary to improve the cell voltage and energy density of LBs. However, LBs with high voltage and high energy density will face serious challenges of electrolyte decomposition and electrode corrosion in high voltage environment. Herein, this review summarizes the effects of a series of sultones as electrolyte additives in high voltage electrolytes. It is found that DTD, ES, 1,3-PS, PES, PCS, MMDS, BDTD, BDTT, DTDph, ODTO, FPS, VES and other sultones have excellent properties on stabilizing SEI/CEI formation, inhibiting gas production, and good high temperature resistance. The preferential oxidation/reduction of sultones can protect the electrolyte from decomposition, and the uniform and dense SEI/CEI can also promote Li+ transport, protect the electrode from corrosion, prevent the growth of lithium dendrites, and promote the insertion and removal of Li+, so as to improve the cycle life of the high-voltage battery. Therefore, sultones are very suitable as high-voltage LBs electrolyte additives to improve the performance of cells. This review can provide theoretical support for the design of high voltage and high energy density LBs electrolyte and selection of additives in the future.

新能源市场发展迅速,锂电池(LBs)作为储能和动力市场最重要的能源供应来源,对快速充电和长寿命有更高的要求,因此必须提高锂电池的电芯电压和能量密度。然而,具有高电压和高能量密度的枸杞电池在高压环境下将面临电解质分解和电极腐蚀的严峻挑战。本综述总结了一系列舒通酮作为电解质添加剂在高压电解质中的作用。研究发现,DTD、ES、1,3-PS、PES、PCS、MMDS、BDTD、BDTT、DTDph、ODTO、FPS、VES 和其他舒他酮在稳定 SEI/CEI 形成、抑制气体产生和良好的耐高温性方面具有优异的性能。磺内酯的优先氧化/还原性可以保护电解液不被分解,均匀致密的 SEI/CEI 还可以促进 Li+ 的传输,保护电极不受腐蚀,防止锂枝晶的生长,促进 Li+ 的插入和移出,从而提高高压电池的循环寿命。本综述可为未来高电压、高能量密度锂电池电解液的设计和添加剂的选择提供理论支持。
{"title":"Advanced Electrolyte Systems with Sultones Additives for High-Voltage Lithium Batteries","authors":"Haojie Wan,&nbsp;Siqi Zhong,&nbsp;Yifan Liu,&nbsp;Yifei Xiong,&nbsp;Ting He,&nbsp;Rong Zeng,&nbsp;Shuang Cai,&nbsp;Jianwen Liu","doi":"10.1002/batt.202400477","DOIUrl":"10.1002/batt.202400477","url":null,"abstract":"<p>The new energy market is growing rapidly, lithium batteries (LBs) as the most important source of energy supply in the energy storage and power market, has higher requirements for fast charge and long life, so it is necessary to improve the cell voltage and energy density of LBs. However, LBs with high voltage and high energy density will face serious challenges of electrolyte decomposition and electrode corrosion in high voltage environment. Herein, this review summarizes the effects of a series of sultones as electrolyte additives in high voltage electrolytes. It is found that DTD, ES, 1,3-PS, PES, PCS, MMDS, BDTD, BDTT, DTDph, ODTO, FPS, VES and other sultones have excellent properties on stabilizing SEI/CEI formation, inhibiting gas production, and good high temperature resistance. The preferential oxidation/reduction of sultones can protect the electrolyte from decomposition, and the uniform and dense SEI/CEI can also promote Li<sup>+</sup> transport, protect the electrode from corrosion, prevent the growth of lithium dendrites, and promote the insertion and removal of Li<sup>+</sup>, so as to improve the cycle life of the high-voltage battery. Therefore, sultones are very suitable as high-voltage LBs electrolyte additives to improve the performance of cells. This review can provide theoretical support for the design of high voltage and high energy density LBs electrolyte and selection of additives in the future.</p>","PeriodicalId":132,"journal":{"name":"Batteries & Supercaps","volume":"7 12","pages":""},"PeriodicalIF":5.1,"publicationDate":"2024-09-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142224131","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Zinc-Triazolate Metal-Organic Framework Assisted Synthesis of Germanium Nanoparticles Encapsulated in Nitrogen-Doped Carbon as Anode Materials for Lithium-Ion Batteries 锌-三唑烷金属有机框架辅助合成掺氮碳中封装的锗纳米颗粒作为锂离子电池的负极材料
IF 5.1 4区 材料科学 Q2 ELECTROCHEMISTRY Pub Date : 2024-09-04 DOI: 10.1002/batt.202400442
Zhuo Wang, Xue Bai, Jiabao Dong, Kexin Zhang, Bin Zhao, Xiaoli Dong

Germanium (Ge) is demonstrated to be prospective as a lithium-ion battery anode material, yet the cycling stability is undermined by substantial volume fluctuations, restricting its viability for practical applications. Here, we present a facile Zn-based metal−organic framework (MOF) engaged route to produce Ge nanoparticles in situ encapsulated in nitrogen-doped mesoporous carbon (denoted as Ge@N-C) as an anode material. This method uses a zinc-triazolate MOF (MET-6) and commercial GeO2 as the hybrid carbon and Ge precursors. After a heating treatment, the Ge@N-C composite is readily obtained along with the simultaneous thermal decomposition of MET-6 and the reduction of GeO2. Benefiting from the mesoporous structure and high electrical conductivity of N−C, along with the strong interaction between Ge and N−C, the obtained Ge@N-C electrode exhibits a significant reversible charge capacity of 1012.8 mAh g−1 after 150 cycles at 0.1 A g−1, and excellent rate capability. Furthermore, a reversible charge capacity of 521.1 mAh g−1 can be maintained at 5.0 A g−1 after 1000 cycles.

锗(Ge)作为锂离子电池负极材料具有广阔的发展前景,但其循环稳定性因体积大幅波动而受到影响,限制了其在实际应用中的可行性。在此,我们提出了一种简便的锌基金属有机框架(MOF)参与路线,以原位生产封装在掺氮介孔碳(Ge@N-C)中的 Ge 纳米粒子,作为负极材料。该方法使用三唑锌MOF(MET-6)和商用GeO2作为碳和Ge的混合前驱体。加热处理后,随着 MET-6 的热分解和 GeO2 的还原,很容易得到 Ge@N-C 复合材料。得益于 N-C 的介孔结构和高导电性,以及 Ge 与 N-C 之间的强相互作用,所获得的 Ge@N-C 电极在 0.1 A g-1 的条件下循环 150 次后,显示出 1012.8 mAh g-1 的显著可逆电荷容量和优异的速率能力。此外,在 5.0 A g-1 条件下循环 1000 次后,可保持 521.1 mAh g-1 的可逆充电容量。
{"title":"Zinc-Triazolate Metal-Organic Framework Assisted Synthesis of Germanium Nanoparticles Encapsulated in Nitrogen-Doped Carbon as Anode Materials for Lithium-Ion Batteries","authors":"Zhuo Wang,&nbsp;Xue Bai,&nbsp;Jiabao Dong,&nbsp;Kexin Zhang,&nbsp;Bin Zhao,&nbsp;Xiaoli Dong","doi":"10.1002/batt.202400442","DOIUrl":"10.1002/batt.202400442","url":null,"abstract":"<p>Germanium (Ge) is demonstrated to be prospective as a lithium-ion battery anode material, yet the cycling stability is undermined by substantial volume fluctuations, restricting its viability for practical applications. Here, we present a facile Zn-based metal−organic framework (MOF) engaged route to produce Ge nanoparticles in situ encapsulated in nitrogen-doped mesoporous carbon (denoted as Ge@N-C) as an anode material. This method uses a zinc-triazolate MOF (MET-6) and commercial GeO<sub>2</sub> as the hybrid carbon and Ge precursors. After a heating treatment, the Ge@N-C composite is readily obtained along with the simultaneous thermal decomposition of MET-6 and the reduction of GeO<sub>2</sub>. Benefiting from the mesoporous structure and high electrical conductivity of N−C, along with the strong interaction between Ge and N−C, the obtained Ge@N-C electrode exhibits a significant reversible charge capacity of 1012.8 mAh g<sup>−1</sup> after 150 cycles at 0.1 A g<sup>−1</sup>, and excellent rate capability. Furthermore, a reversible charge capacity of 521.1 mAh g<sup>−1</sup> can be maintained at 5.0 A g<sup>−1</sup> after 1000 cycles.</p>","PeriodicalId":132,"journal":{"name":"Batteries & Supercaps","volume":"7 12","pages":""},"PeriodicalIF":5.1,"publicationDate":"2024-09-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142224132","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Corrosion Study of Current Collectors for Magnesium Batteries 镁电池集流体的腐蚀研究
IF 5.1 4区 材料科学 Q2 ELECTROCHEMISTRY Pub Date : 2024-09-04 DOI: 10.1002/batt.202400392
Laurin Rademacher, Joachim Häcker, Dr. J. Alberto Blázquez, Dr. Maryam Nojabaee, Prof. K. Andreas Friedrich

For rechargeable magnesium batteries, chlorine-containing electrolytes are used because chlorine species reduce the energy barrier for the intercalation process at the cathode. However, these species can cause corrosion of the cathode-side current collectors during polarization. In this study, carbon-coated aluminum and Nickel metal substrates, as well as a graphite foil, were investigated using Linear Sweep Voltammetry, Chronoamperometry, and Electrochemical Impedance Spectroscopy to evaluate their potential as current collectors in APC electrolyte. The graphite-based current collector withstood corrosive environments at polarization potentials up to 2 V, displaying passivating behavior comparable to platinum in Chronoamperometry measurements. During Electrochemical Impedance Spectroscopy measurements, the graphite foil exhibited exceptionally high polarization resistance of at least 4.5 MΩ cm2. Combined with its low areal density of 5 mg/cm−2, this makes it an excellent current collector material for rechargeable magnesium batteries with chlorine-containing electrolytes. In contrast, Al foil are instable towards corrosion – despite protective coatings.

对于可充电镁电池,使用含氯电解质是因为氯能降低阴极插层过程的能量障碍。然而,这些物种会在极化过程中导致阴极集流器腐蚀。在这项研究中,我们使用线性扫描伏安法、慢性阻抗测量法和电化学阻抗光谱法对碳涂层铝和镍金属基板以及石墨箔进行了研究,以评估它们在 APC 电解液中作为电流收集器的潜力。石墨基集流体在极化电位高达 2 V 的情况下可承受腐蚀环境,在 Chronoamperometry 测量中显示出与铂相当的钝化性能。在电化学阻抗谱测量中,石墨箔表现出极高的极化电阻,至少达到 4.5 MΩ cm2。石墨箔的平均密度仅为 5 毫克/厘米-2,因此是使用含氯电解质的可充电镁电池的极佳集流材料。相比之下,尽管铝箔上有保护涂层,但仍容易受到腐蚀。
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引用次数: 0
Graphite Co-Intercalation Chemistry in Sodium-Ion Batteries 钠离子电池中的石墨共钙化化学
IF 5.1 4区 材料科学 Q2 ELECTROCHEMISTRY Pub Date : 2024-09-04 DOI: 10.1002/batt.202400521
Dr. Linlong Lyu, Dr. Yuyang Yi, Prof. Zheng-Long Xu

Lithium ion intercalation chemistry in graphite underpins commercial lithium-ion batteries since 1991. In exploring the potential of cost-effective graphite anodes in alternative battery systems, the conventional intercalation chemistry falls short for Na ions, which exhibited minimal capacity and thermodynamic unfavourability in sodium ion batteries (SIBs). The introduction of an alternative intercalation chemistry involving solvated-Na-ion co-intercalation gives a rebirth to graphite anodes. The co-intercalation chemistry allows appreciable Na ion storage capacities and extraordinary rate capabilities. The fundamental differences between intercalation and co-intercalation chemistries have attracted extensive investigation over the past decade for high-power SIBs. Herein, we focus on the state-of-the-art advances on the co-intercalation chemistry in the SIBs for the purpose of enriching insights into graphite intercalation chemistry. Following our introducing the thermodynamic features of co-intercalation reactions, we will illuminate the electrochemical properties and mechanic issues of co-intercalated graphite, finalized by the perspective challenges and potential resolutions.

自 1991 年以来,石墨中的锂离子插层化学一直是商用锂离子电池的基础。在探索具有成本效益的石墨负极在替代电池系统中的潜力时,传统的插层化学在钠离子电池(SIBs)中表现出最小容量和热力学上的不利性,而对 Na 离子而言则存在不足。溶解态 Na 离子共插层化学的引入为石墨阳极带来了新生。共掺杂化学可实现可观的 Na 离子存储容量和非凡的速率能力。在过去十年中,插层化学与共插层化学之间的根本区别吸引了人们对大功率 SIB 的广泛研究。在此,我们重点介绍 SIB 中共闰化学的最新进展,以丰富对石墨插层化学的认识。在介绍共插层反应的热力学特征之后,我们将阐明共插层石墨的电化学特性和力学问题,最后提出面临的挑战和可能的解决方案。
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引用次数: 0
A Trio of Revelations: Weakly Solvating Modulation in Aqueous Electrolytes for Zinc Metal Batteries 三重启示:锌金属电池水性电解质中的弱溶解调制
IF 5.1 4区 材料科学 Q2 ELECTROCHEMISTRY Pub Date : 2024-09-03 DOI: 10.1002/batt.202400483
Zhenrui Wu, Jian Liu

The emerging concept of weakly solvating electrolytes in multivalent ion aqueous batteries has garnered attention due to their enhanced kinetic performance at a low cost. This article aims to dissect the concept of “weakly solvating electrolyte” into three revelations, i. e., ion solvation, hydrogen bonding strength, and ionic interactions. It is revealed that a weakly interacting solvent must satisfy the requirements of having a solvation strength weaker than water molecules, as well as disrupting rather than strengthening hydrogen bonding within them. Moreover, electrolyte chemistry requires balancing multiple factors, and one weakly interacting solvent can exhibit varying effects with different anions of zinc salts. This study offers quantitative descriptors to the concept of weak solvation, particularly for aqueous electrolytes, and provides insights for future electrolyte advancements for multivalent ion batteries.

多价离子水电池中新出现的弱溶解电解质概念因其低成本、更高的动力学性能而备受关注。本文旨在将 "弱溶解电解质 "的概念剖析为三个启示,即离子溶解、氢键强度和离子相互作用。文章揭示了弱相互作用溶剂必须满足以下要求:溶解强度弱于水分子的离子相互作用,以及破坏而不是加强水分子内部的氢键。此外,电解质化学需要平衡多种因素,同样的弱相互作用溶剂会随着锌盐阴离子的变化而表现出不同的效果。这项研究为弱溶解的概念提供了定量描述,尤其是对水性电解质而言,并为未来多价离子电池电解质的发展提供了启示。
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引用次数: 0
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