首页 > 最新文献

International Review of Biophysical Chemistry最新文献

英文 中文
Odour Problems in Potable Water and its Treatment Options: a Review 饮用水中的气味问题及其处理方案综述
Pub Date : 2013-12-31 DOI: 10.15866/IREBIC.V4I6.2460
I. Cho, C. Somerfield, N. Hilal
Odours in potable waters are the major complaint repeated by customers worldwide. Water utilities have justified or ignored them, because, in most cases, the odorous waters satisfy all of the water laws and registration requirements. For customers however, odour is often the primary judgement of water quality. Odour problems are usually caused by Aqueous Organic Matter (AOM). Furthermore, the AOM can be produced as unexpected by-products (e.g. disinfection by-products) during water treatment processes. Hence, eliminating AOM during water treatment is one of the highest priorities in water utilities. Several investigations have been performed for the identification, characterization, treatment options, and treatability of the AOM. Unfortunately, these researchers have proved that the Conventional Potable Water Treatment (CPWT) processes, which consist of coagulation, sedimentation, rapid media filtration and disinfection, are not suitable for reducing the AOM concentration to a level low enough to alleviate odour problems. These researchers have also justified the introduction of advanced or alternative processes such as granular activated carbon bed adsorption, ozonation and membrane filtration for improving AOM removal. The goal of this review is to look at the research which has been done in this area and to find out the best available operations, in terms of AOM reduction, in current CPWT plants for minimizing odour, that can be performed easily and demand minimum budget and modification. For this purpose, options available such as enhanced coagulation, powdered activated carbon adsorption, oxidation and membrane filtration will be investigated and their efficiencies assessed in comparison with the performance of CPWT processes
饮用水的气味是世界各地消费者反复抱怨的主要问题。水务公司已经证明了它们的合理性或忽略了它们,因为在大多数情况下,臭气熏天的水满足了所有的水法和注册要求。然而,对于客户来说,气味往往是对水质的主要判断。气味问题通常是由水性有机物(AOM)引起的。此外,在水处理过程中,AOM可以作为意想不到的副产物(例如消毒副产物)产生。因此,在水处理过程中消除AOM是水务公司的首要任务之一。对AOM的识别、表征、治疗方案和可治疗性进行了几项调查。不幸的是,这些研究人员已经证明,由混凝、沉淀、快速介质过滤和消毒组成的传统饮用水处理(CPWT)工艺不适合将AOM浓度降低到足以缓解气味问题的水平。这些研究人员也证明了引入先进的或替代的工艺,如颗粒活性炭床吸附、臭氧化和膜过滤来改善AOM的去除。本综述的目的是回顾在这一领域所做的研究,并找出在当前CPWT工厂中减少AOM的最佳可行操作,以最大限度地减少气味,这些操作可以很容易地执行,并且需要最少的预算和修改。为此,将研究强化混凝、粉状活性炭吸附、氧化和膜过滤等可用的方法,并与CPWT工艺的性能进行比较,评估其效率
{"title":"Odour Problems in Potable Water and its Treatment Options: a Review","authors":"I. Cho, C. Somerfield, N. Hilal","doi":"10.15866/IREBIC.V4I6.2460","DOIUrl":"https://doi.org/10.15866/IREBIC.V4I6.2460","url":null,"abstract":"Odours in potable waters are the major complaint repeated by customers worldwide. Water utilities have justified or ignored them, because, in most cases, the odorous waters satisfy all of the water laws and registration requirements. For customers however, odour is often the primary judgement of water quality. Odour problems are usually caused by Aqueous Organic Matter (AOM). Furthermore, the AOM can be produced as unexpected by-products (e.g. disinfection by-products) during water treatment processes. Hence, eliminating AOM during water treatment is one of the highest priorities in water utilities. Several investigations have been performed for the identification, characterization, treatment options, and treatability of the AOM. Unfortunately, these researchers have proved that the Conventional Potable Water Treatment (CPWT) processes, which consist of coagulation, sedimentation, rapid media filtration and disinfection, are not suitable for reducing the AOM concentration to a level low enough to alleviate odour problems. These researchers have also justified the introduction of advanced or alternative processes such as granular activated carbon bed adsorption, ozonation and membrane filtration for improving AOM removal. The goal of this review is to look at the research which has been done in this area and to find out the best available operations, in terms of AOM reduction, in current CPWT plants for minimizing odour, that can be performed easily and demand minimum budget and modification. For this purpose, options available such as enhanced coagulation, powdered activated carbon adsorption, oxidation and membrane filtration will be investigated and their efficiencies assessed in comparison with the performance of CPWT processes","PeriodicalId":14377,"journal":{"name":"International Review of Biophysical Chemistry","volume":"16 1","pages":"203-226"},"PeriodicalIF":0.0,"publicationDate":"2013-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80397765","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Assessing the Quality of Gluten Proteins Using Acoustic Waves 利用声波评价面筋蛋白的质量
Pub Date : 2013-10-31 DOI: 10.15866/IREBIC.V4I5.1656
H. Elmehdi
The elastic properties of gluten samples were extracted from wheat flours of variable protein content, i.e. strength, were investigated using ultrasound using low frequency (50kHz) longitudinal ultrasonic waves. The objective of the experiments was to use ultrasonic parameter as a tool to assess quality of these samples based on their elastic properties, which is determined from the measured longitudinal ultrasonic velocity. The gluten samples were extracted from a set of 7 flour samples with variable protein content ranging from extra strong to soft wheat flours. The variation in the value of ultrasonic velocity in the 7 samples screened was found to be about 1400 m/s between the soft wheat sample and the extra strong one. The results of these experiments demonstrate that ultrasonic measurements can be used as a powerful technique to classify the strength of flours based on flour protein content (FPC). The sensitivity of ultrasound to protein differences between cultivars show that ultrasound can be considered as a tool that has great potential to be used as a selection tool for breeders and provide quantitative information that complements the information provided by conventional screening tests
采用低频(50kHz)纵向超声波,从不同蛋白含量的小麦粉中提取面筋样品,考察其弹性特性,即强度。实验的目的是利用超声参数作为评估这些样品质量的工具,基于它们的弹性特性,这是由测量的纵向超声速度决定的。麸质样品是从7个不同蛋白质含量的面粉样品中提取的,这些样品的蛋白质含量从特强面粉到软面粉不等。在筛选的7个样品中,软质小麦样品与强质小麦样品之间的超声速度值变化约为1400 m/s。实验结果表明,超声测量可以作为一种基于面粉蛋白含量(FPC)的面粉强度分类的有效技术。超声波对品种间蛋白质差异的敏感性表明,超声波可以被认为是一种有很大潜力的工具,可以作为育种者的选择工具,并提供定量信息,补充传统筛选试验提供的信息
{"title":"Assessing the Quality of Gluten Proteins Using Acoustic Waves","authors":"H. Elmehdi","doi":"10.15866/IREBIC.V4I5.1656","DOIUrl":"https://doi.org/10.15866/IREBIC.V4I5.1656","url":null,"abstract":"The elastic properties of gluten samples were extracted from wheat flours of variable protein content, i.e. strength, were investigated using ultrasound using low frequency (50kHz) longitudinal ultrasonic waves. The objective of the experiments was to use ultrasonic parameter as a tool to assess quality of these samples based on their elastic properties, which is determined from the measured longitudinal ultrasonic velocity. The gluten samples were extracted from a set of 7 flour samples with variable protein content ranging from extra strong to soft wheat flours. The variation in the value of ultrasonic velocity in the 7 samples screened was found to be about 1400 m/s between the soft wheat sample and the extra strong one. The results of these experiments demonstrate that ultrasonic measurements can be used as a powerful technique to classify the strength of flours based on flour protein content (FPC). The sensitivity of ultrasound to protein differences between cultivars show that ultrasound can be considered as a tool that has great potential to be used as a selection tool for breeders and provide quantitative information that complements the information provided by conventional screening tests","PeriodicalId":14377,"journal":{"name":"International Review of Biophysical Chemistry","volume":"31 1","pages":"186-190"},"PeriodicalIF":0.0,"publicationDate":"2013-10-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79970208","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The Effect of Temperature and Ethanol Concentration on Diethyl Ether Production by Using Adsorption–Dehydration Process 温度和乙醇浓度对吸附-脱水法生产乙醚的影响
Pub Date : 2013-10-31 DOI: 10.15866/IREBIC.V4I5.1657
A. Widayat, A. Roesyadi, M. Rachimoellah
The objective of this research is to produce DiEthyl Ether from ethanol broth fermentation by using adsorption - dehydration process with H-zeolite as catalyst. H-zeolite catalyst was synthesized from natural zeolite obtained from District Gunung Kidul, Indonesia. The H-zeolite catalyst was produced with chemical treatment, washing, drying and calcinations processes and then impregnation by using Al /aluminum. The zeolite catalyst was analyzed for its X-ray Diffraction and specific surface area. DiEthyl Ether was produced by adsorption with molecular sieve and then continued by dehydration process. DiEthyl Ether production used a fixed bed reactor with 1/2 in diameter, and ethanol fermentation broth as feed. The operation condition was 140-240oC and atmospheric pressure. The main compounds in the liquid phase of products are diethyl ether, methanol, ethanol and water. The result also showed that the adsorption process can increase purity of ethanol and therefore increase the ethanol conversion. Moreover, increasing operation temperature and ethanol concentration were able to increase the ethanol conversion, while H-zeolite and Alumina catalyst had the same affects in the ethanol conversion
本研究以h型沸石为催化剂,采用吸附-脱水工艺,从乙醇发酵液中生产乙醚。以印尼基杜尔地区的天然沸石为原料合成了h型沸石催化剂。采用化学处理、洗涤、干燥、煅烧等工艺,再用铝/铝浸渍制备h型沸石催化剂。对分子筛催化剂的x射线衍射和比表面积进行了分析。采用分子筛吸附法制备乙醚,再进行脱水工艺。二乙醚的生产采用直径为1/2的固定床反应器,以乙醇发酵液为饲料。操作条件为140-240℃,常压。产品液相中的主要化合物为乙醚、甲醇、乙醇和水。结果还表明,吸附过程可以提高乙醇纯度,从而提高乙醇转化率。提高操作温度和乙醇浓度均能提高乙醇转化率,h型沸石和氧化铝催化剂对乙醇转化率的影响相同
{"title":"The Effect of Temperature and Ethanol Concentration on Diethyl Ether Production by Using Adsorption–Dehydration Process","authors":"A. Widayat, A. Roesyadi, M. Rachimoellah","doi":"10.15866/IREBIC.V4I5.1657","DOIUrl":"https://doi.org/10.15866/IREBIC.V4I5.1657","url":null,"abstract":"The objective of this research is to produce DiEthyl Ether from ethanol broth fermentation by using adsorption - dehydration process with H-zeolite as catalyst. H-zeolite catalyst was synthesized from natural zeolite obtained from District Gunung Kidul, Indonesia. The H-zeolite catalyst was produced with chemical treatment, washing, drying and calcinations processes and then impregnation by using Al /aluminum. The zeolite catalyst was analyzed for its X-ray Diffraction and specific surface area. DiEthyl Ether was produced by adsorption with molecular sieve and then continued by dehydration process. DiEthyl Ether production used a fixed bed reactor with 1/2 in diameter, and ethanol fermentation broth as feed. The operation condition was 140-240oC and atmospheric pressure. The main compounds in the liquid phase of products are diethyl ether, methanol, ethanol and water. The result also showed that the adsorption process can increase purity of ethanol and therefore increase the ethanol conversion. Moreover, increasing operation temperature and ethanol concentration were able to increase the ethanol conversion, while H-zeolite and Alumina catalyst had the same affects in the ethanol conversion","PeriodicalId":14377,"journal":{"name":"International Review of Biophysical Chemistry","volume":"13 1","pages":"191-196"},"PeriodicalIF":0.0,"publicationDate":"2013-10-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87725823","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Elemental and Molecular Composition of Terminalia Brownii's Bark 黄连树皮的元素和分子组成
Pub Date : 2013-10-31 DOI: 10.15866/IREBIC.V4I5.1654
A. Attaelmanan, H. Omar
Tarminalia Brownii is a plant used for many purposes. It is used as a source of fire wood, for animal fodder or as a traditional medication for a number of diseases. The chemical elements and compounds present in the plant's bark were investigated using a number of analytical techniques, in order to collect more information pertaining to the chemistry of the plant's bark. Powdered air dried bark chips were analyzed for their contents of: dry matter (DM), moisture, crude protein, total Kjeldahl Nitrogen (TKN) and acid detergent fiber (ADF). In addition elemental and molecular compositions were investigated using ICP and FT-IR, while XRF was utilized to determine the crystalline state. The bark samples are found to contain high calcium concentrations (68%) present in the form of calcium and potassium oxalates, Chloropicrin and Diphosphoryl chloride. Only calcium oxalate monohydrate (Whewellite) is present in crystalline form
Tarminalia Brownii是一种用途广泛的植物。它被用作柴火的来源,动物饲料或作为许多疾病的传统药物。为了收集更多有关植物树皮化学成分的信息,研究人员使用了多种分析技术对植物树皮中的化学元素和化合物进行了研究。对风干树皮碎粉的干物质(DM)、水分、粗蛋白质、总凯氏定氮(TKN)和酸性洗涤纤维(ADF)含量进行了分析。此外,利用ICP和FT-IR研究了元素和分子组成,并利用XRF测定了晶体状态。树皮样品被发现含有高浓度的钙(68%),以草酸钙和草酸钾、氯霉素和二磷酸氯的形式存在。只有一水草酸钙(Whewellite)以结晶形式存在
{"title":"Elemental and Molecular Composition of Terminalia Brownii's Bark","authors":"A. Attaelmanan, H. Omar","doi":"10.15866/IREBIC.V4I5.1654","DOIUrl":"https://doi.org/10.15866/IREBIC.V4I5.1654","url":null,"abstract":"Tarminalia Brownii is a plant used for many purposes. It is used as a source of fire wood, for animal fodder or as a traditional medication for a number of diseases. The chemical elements and compounds present in the plant's bark were investigated using a number of analytical techniques, in order to collect more information pertaining to the chemistry of the plant's bark. Powdered air dried bark chips were analyzed for their contents of: dry matter (DM), moisture, crude protein, total Kjeldahl Nitrogen (TKN) and acid detergent fiber (ADF). In addition elemental and molecular compositions were investigated using ICP and FT-IR, while XRF was utilized to determine the crystalline state. The bark samples are found to contain high calcium concentrations (68%) present in the form of calcium and potassium oxalates, Chloropicrin and Diphosphoryl chloride. Only calcium oxalate monohydrate (Whewellite) is present in crystalline form","PeriodicalId":14377,"journal":{"name":"International Review of Biophysical Chemistry","volume":"41 4 1","pages":"157-160"},"PeriodicalIF":0.0,"publicationDate":"2013-10-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79202977","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Ultrafast Spectroscopic Studies on the Interaction of a Potential Food Carcinogen with Biologically Relevant Macromolecules 一种潜在食品致癌物与生物相关大分子相互作用的超快光谱研究
Pub Date : 2013-10-31 DOI: 10.15866/IREBIC.V4I5.1655
Soma Banerjee, Siddhi Chaudhuri, S. Pal
Benzo[a]pyrene (BP), a potential carcinogen in a class of pyrene derivatives shows interesting photophysics including very sharp vibronic structures in the emission spectrum. A detail spectroscopic study on the close interaction of the carcinogenic molecule with other biologically relevant macromolecules through ultrafast energy/charge transfer reactions is the motive of the present review. Firstly, we present our picosecond resolved studies on the Forster resonance energy transfer (FRET) from various vibronic bands in BP, showing strong dependency on the spectral overlap of an energy acceptor in a confined environment. Our study on the dipolar interactions between BP and different acceptors ethidium (Et), acridine orange (AO) and crystal violet (CV) at the surface of a model anionic micelle reveals the Forster distance (R0) and the rate of energy transfer to be dependent on the individual spectral overlap of the vibronic bands of BP with the absorption spectra of different energy acceptors. The differential behaviour of the vibronic bands is compared with that of different dyes (quantum dots; QDs) in a ‘dye-blend’ (mixture) under FRET to an energy acceptor. Such comparison of the FRET of QDs with that of BP, not only confirms independent nature of dipolar interaction of the vibronic bands with other organic molecules, the use of deconvolution technique in the interpretation of the donor-acceptor (D-A) distance has also been justified. We have also shown that consideration of differential FRET from vibronic bands of BP and from the QDs in the ‘dye-blend’ is equally acceptable in the theoretical frameworks including ‘Infelta-Tachiya’ model and D-A distribution analysis in the nano-environments. While such energy transfer reactions act as “spectroscopic ruler” to measure the distance between two sites on a macromolecule, reactions involving electron transfer (ET)/charge transfer (CT) and reactive oxygen species (ROS) play a pivotal role in carcinogenesis and cancer biochemistry. The review further emphasizes our studies on UVA radiation induced ET reaction as one of the key aspects of BP in the presence of a wide variety of molecules covering organic para-benzoquinone (BQ), biological macromolecules like calf-thymus DNA (CT-DNA), human serum albumin (HSA) protein and inorganic zinc oxide (ZnO) nanorods (NRs). Steady-state and picosecond-resolved fluorescence spectroscopy have been used to monitor such ET reactions. Physical consequences of BP association with CT-DNA have been investigated through temperature-dependent circular dichroism (CD) spectroscopy. The temperature-dependent steady-state, picosecond-resolved fluorescence lifetime and anisotropy studies reveal the effect of temperature on the perturbation of such ET reactions from BP to biological macromolecules, highlighting their temperature-dependent association. Furthermore, the electron donating property of BP has been corroborated by measuring wavelength-dependent photocurrent in a BP-an
苯并[a]芘(BP)是一类芘衍生物中的潜在致癌物,在发射光谱中表现出有趣的光物理现象,包括非常尖锐的振动结构。对致癌分子与其他生物相关大分子通过超快能量/电荷转移反应密切相互作用的详细光谱研究是本综述的动机。首先,我们对BP中不同振动带的福斯特共振能量转移(FRET)进行了皮秒分辨率的研究,显示出在受限环境中能量受体的光谱重叠有很强的依赖性。我们研究了BP与不同受体乙啶(Et)、吖啶橙(AO)和结晶紫(CV)在模型阴离子胶束表面的偶极相互作用,揭示了BP与不同能量受体的吸收光谱的共振带重叠程度决定了BP的福斯特距离(R0)和能量转移速率。比较了不同染料(量子点;在FRET下的“染料混合”(混合物)中的量子点到能量受体。这种量子点的FRET与BP的比较,不仅证实了振动带与其他有机分子的偶极相互作用的独立性,而且在解释供体-受体(D-A)距离时使用反褶积技术也是合理的。我们还表明,在包括“Infelta-Tachiya”模型和纳米环境中的D-A分布分析在内的理论框架中,考虑BP的振动带和“染料-共混物”中的量子点的微分FRET是同样可以接受的。虽然这种能量转移反应是测量大分子上两个位点之间距离的“光谱标尺”,但涉及电子转移(ET)/电荷转移(CT)和活性氧(ROS)的反应在致癌和癌症生物化学中起着关键作用。本文进一步强调了在有机对苯醌(BQ)、小牛胸腺DNA (CT-DNA)、人血清白蛋白(HSA)蛋白和无机氧化锌(ZnO)纳米棒(NRs)等生物大分子存在的情况下,UVA辐射诱导的ET反应是BP的关键方面之一。稳态和皮秒分辨荧光光谱已被用于监测这种ET反应。通过温度依赖性圆二色(CD)光谱研究了BP与CT-DNA关联的物理后果。温度依赖的稳态、皮秒分辨率荧光寿命和各向异性研究揭示了温度对从BP到生物大分子的ET反应的扰动的影响,突出了它们的温度依赖关系。此外,通过测量BP锚定ZnO nr基光器件的波长依赖性光电流,证实了BP的给电子特性,为BP的致癌研究提供了新的物理见解
{"title":"Ultrafast Spectroscopic Studies on the Interaction of a Potential Food Carcinogen with Biologically Relevant Macromolecules","authors":"Soma Banerjee, Siddhi Chaudhuri, S. Pal","doi":"10.15866/IREBIC.V4I5.1655","DOIUrl":"https://doi.org/10.15866/IREBIC.V4I5.1655","url":null,"abstract":"Benzo[a]pyrene (BP), a potential carcinogen in a class of pyrene derivatives shows interesting photophysics including very sharp vibronic structures in the emission spectrum. A detail spectroscopic study on the close interaction of the carcinogenic molecule with other biologically relevant macromolecules through ultrafast energy/charge transfer reactions is the motive of the present review. Firstly, we present our picosecond resolved studies on the Forster resonance energy transfer (FRET) from various vibronic bands in BP, showing strong dependency on the spectral overlap of an energy acceptor in a confined environment. Our study on the dipolar interactions between BP and different acceptors ethidium (Et), acridine orange (AO) and crystal violet (CV) at the surface of a model anionic micelle reveals the Forster distance (R0) and the rate of energy transfer to be dependent on the individual spectral overlap of the vibronic bands of BP with the absorption spectra of different energy acceptors. The differential behaviour of the vibronic bands is compared with that of different dyes (quantum dots; QDs) in a ‘dye-blend’ (mixture) under FRET to an energy acceptor. Such comparison of the FRET of QDs with that of BP, not only confirms independent nature of dipolar interaction of the vibronic bands with other organic molecules, the use of deconvolution technique in the interpretation of the donor-acceptor (D-A) distance has also been justified. We have also shown that consideration of differential FRET from vibronic bands of BP and from the QDs in the ‘dye-blend’ is equally acceptable in the theoretical frameworks including ‘Infelta-Tachiya’ model and D-A distribution analysis in the nano-environments. While such energy transfer reactions act as “spectroscopic ruler” to measure the distance between two sites on a macromolecule, reactions involving electron transfer (ET)/charge transfer (CT) and reactive oxygen species (ROS) play a pivotal role in carcinogenesis and cancer biochemistry. The review further emphasizes our studies on UVA radiation induced ET reaction as one of the key aspects of BP in the presence of a wide variety of molecules covering organic para-benzoquinone (BQ), biological macromolecules like calf-thymus DNA (CT-DNA), human serum albumin (HSA) protein and inorganic zinc oxide (ZnO) nanorods (NRs). Steady-state and picosecond-resolved fluorescence spectroscopy have been used to monitor such ET reactions. Physical consequences of BP association with CT-DNA have been investigated through temperature-dependent circular dichroism (CD) spectroscopy. The temperature-dependent steady-state, picosecond-resolved fluorescence lifetime and anisotropy studies reveal the effect of temperature on the perturbation of such ET reactions from BP to biological macromolecules, highlighting their temperature-dependent association. Furthermore, the electron donating property of BP has been corroborated by measuring wavelength-dependent photocurrent in a BP-an","PeriodicalId":14377,"journal":{"name":"International Review of Biophysical Chemistry","volume":"57 1","pages":"161-185"},"PeriodicalIF":0.0,"publicationDate":"2013-10-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80475973","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Nanofiltration Application for Concentrating Aqueous Waste Stream to Recover Sodium Sulphate 纳滤在废水浓缩回收硫酸钠中的应用
Pub Date : 2013-08-31 DOI: 10.15866/IREBIC.V4I4.1653
R. S. Gawaad, S. Sharma, S. Sambi
Sodium sulphate is one of most important salts of sodium which is mainly used in the manufacture of detergents, Kraft paper, glass, sodium salts, ceramic glazes, pharmaceuticals, dyeing of textile fibers etc. Part of its requirement is met from by-products of manufacturing processes like Aluminium silicate, rayon etc. Presently, evaporation followed by crystallization is the preferred technique for recovery of the salt. This technique becomes uneconomical when the waste water has low concentration of the salt. There is a need to develop new techniques for economical concentration of sodium sulphate. Keeping this in mind efforts were made to test the performance of two commercial CSM membranes Model Nos. NE-1812-70 and RE 1812-50 for concentrating the waste water stream. The results show that waste water stream could be concentrated, at pressure of 25 bar, up to 14.1% at permeate flux of 2.08L-min-1-m-2 with NE-1812-70 membrane compared to 9.29% at permeate flux of 0.62 L-min-1-m-2 with RE 1812-50 membrane
硫酸钠是最重要的钠盐之一,主要用于制造洗涤剂、牛皮纸、玻璃、钠盐、陶瓷釉料、制药、纺织纤维染色等。部分需求由硅酸铝、人造丝等生产过程的副产品来满足。目前,蒸发再结晶是回收盐的首选技术。当废水含盐量较低时,该工艺不经济。有必要开发经济浓缩硫酸钠的新技术。考虑到这一点,我们进行了两种商用CSM膜的性能测试,型号为NE-1812-70和RE 1812-50,用于浓缩废水流。结果表明,在25 bar压力下,NE-1812-70膜在渗透通量为2.08L-min-1-m-2时的废水浓缩率可达14.1%,而RE 1812-50膜在渗透通量为0.62 L-min-1-m-2时的废水浓缩率为9.29%
{"title":"Nanofiltration Application for Concentrating Aqueous Waste Stream to Recover Sodium Sulphate","authors":"R. S. Gawaad, S. Sharma, S. Sambi","doi":"10.15866/IREBIC.V4I4.1653","DOIUrl":"https://doi.org/10.15866/IREBIC.V4I4.1653","url":null,"abstract":"Sodium sulphate is one of most important salts of sodium which is mainly used in the manufacture of detergents, Kraft paper, glass, sodium salts, ceramic glazes, pharmaceuticals, dyeing of textile fibers etc. Part of its requirement is met from by-products of manufacturing processes like Aluminium silicate, rayon etc. Presently, evaporation followed by crystallization is the preferred technique for recovery of the salt. This technique becomes uneconomical when the waste water has low concentration of the salt. There is a need to develop new techniques for economical concentration of sodium sulphate. Keeping this in mind efforts were made to test the performance of two commercial CSM membranes Model Nos. NE-1812-70 and RE 1812-50 for concentrating the waste water stream. The results show that waste water stream could be concentrated, at pressure of 25 bar, up to 14.1% at permeate flux of 2.08L-min-1-m-2 with NE-1812-70 membrane compared to 9.29% at permeate flux of 0.62 L-min-1-m-2 with RE 1812-50 membrane","PeriodicalId":14377,"journal":{"name":"International Review of Biophysical Chemistry","volume":"70 1","pages":"152-156"},"PeriodicalIF":0.0,"publicationDate":"2013-08-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89129453","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Thermodynamic Properties and Electron Transfer of the Interaction Between Pyropheophorbide a Methyl Ester and Copper: the Nature of Binding Forces 卟啉甲酯与铜相互作用的热力学性质和电子转移:结合力的性质
Pub Date : 2013-08-31 DOI: 10.15866/IREBIC.V4I4.1652
S. Al-Omari
Pyropheophorbide methyl ester (PPME) is clinically used as antitumor drug. Understanding of the strong interaction between PPME and Cu2+ could contribute to understand its pharmacodynamics and pharmacokinetics. The interaction between PPME and Cu2+ was investigated using fluorescence and UV-vis techniques. The binding constants of Cu2+ with PPME were determined at different temperatures depending on the fluorescence quenching results. Furthermore, the thermodynamic functions of standard enthalpy (ΔH0) and standard entropy (ΔS0) for the binding reaction were determined according to the van’t Hoff equation, which indicated that electron transfer, electrostatic, and hydrophobic interactions are important driving forces for PPME-Cu2+ association
焦磷酯甲酯(PPME)是临床上常用的抗肿瘤药物。了解PPME与Cu2+之间的强相互作用有助于了解其药效学和药代动力学。利用荧光和紫外-可见技术研究了PPME与Cu2+的相互作用。根据荧光猝灭结果测定了不同温度下Cu2+与PPME的结合常数。此外,根据van 't Hoff方程确定了结合反应的标准焓(ΔH0)和标准熵(ΔS0)热力学函数,表明电子转移、静电和疏水相互作用是PPME-Cu2+缔合的重要驱动力
{"title":"Thermodynamic Properties and Electron Transfer of the Interaction Between Pyropheophorbide a Methyl Ester and Copper: the Nature of Binding Forces","authors":"S. Al-Omari","doi":"10.15866/IREBIC.V4I4.1652","DOIUrl":"https://doi.org/10.15866/IREBIC.V4I4.1652","url":null,"abstract":"Pyropheophorbide methyl ester (PPME) is clinically used as antitumor drug. Understanding of the strong interaction between PPME and Cu2+ could contribute to understand its pharmacodynamics and pharmacokinetics. The interaction between PPME and Cu2+ was investigated using fluorescence and UV-vis techniques. The binding constants of Cu2+ with PPME were determined at different temperatures depending on the fluorescence quenching results. Furthermore, the thermodynamic functions of standard enthalpy (ΔH0) and standard entropy (ΔS0) for the binding reaction were determined according to the van’t Hoff equation, which indicated that electron transfer, electrostatic, and hydrophobic interactions are important driving forces for PPME-Cu2+ association","PeriodicalId":14377,"journal":{"name":"International Review of Biophysical Chemistry","volume":"82 1","pages":"143-151"},"PeriodicalIF":0.0,"publicationDate":"2013-08-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88933886","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Novel Approach for Mass Detection in a Mammographic Computer-Aided System 乳腺x线摄影计算机辅助系统中质量检测的新方法
Pub Date : 2013-08-31 DOI: 10.15866/IREBIC.V4I4.1650
A. Melouah, H. Merouani
X-ray images of the breast must be carefully evaluated to identify early signs of cancerous growth. Mass lesion detection is a challenging task, and in order to help radiologists in their identification, computer aided systems have been introduced. The purpose of this paper is to present a novel approach for mass detection in a mammographic computer-aided system. The proposed approach is based on the intensity specification to segment the image and to put into evidence the suspicious parts. The detection process tries to get progressively close to the suspicious region through different ranges of scales. Although different algorithms have been proposed for such task, most of them are application dependent. The suggested approach begins with a pre-processing step followed by sequence of: segmentation, features extraction and classification. This approach is particular for two reasons:  first, a new segmentation strategy based on competition scenario is suggested; secondly, detection is performed from the coarsest segmentation to the finest segmentation using a binary tree classifier. The proposed method was applied to a series of images from the Digital Database for Screening. Preliminary results are promising; a large study using more cases is currently in progress
乳房的x光图像必须仔细评估,以确定癌症生长的早期迹象。肿块病变检测是一项具有挑战性的任务,为了帮助放射科医生进行识别,计算机辅助系统已经被引入。本文的目的是提出一种在乳腺x线摄影计算机辅助系统中进行肿块检测的新方法。该方法基于强度规范对图像进行分割,并对可疑部分进行证据化。检测过程试图通过不同的尺度范围逐步接近可疑区域。尽管针对此类任务提出了不同的算法,但大多数算法都与应用程序相关。建议的方法从预处理步骤开始,然后是:分割,特征提取和分类。该方法的独特之处在于:首先,提出了一种新的基于竞争情景的细分策略;其次,使用二叉树分类器从最粗分割到最细分割进行检测。将该方法应用于来自数字数据库的一系列图像进行筛选。初步结果令人鼓舞;一项使用更多病例的大型研究目前正在进行中
{"title":"Novel Approach for Mass Detection in a Mammographic Computer-Aided System","authors":"A. Melouah, H. Merouani","doi":"10.15866/IREBIC.V4I4.1650","DOIUrl":"https://doi.org/10.15866/IREBIC.V4I4.1650","url":null,"abstract":"X-ray images of the breast must be carefully evaluated to identify early signs of cancerous growth. Mass lesion detection is a challenging task, and in order to help radiologists in their identification, computer aided systems have been introduced. The purpose of this paper is to present a novel approach for mass detection in a mammographic computer-aided system. The proposed approach is based on the intensity specification to segment the image and to put into evidence the suspicious parts. The detection process tries to get progressively close to the suspicious region through different ranges of scales. Although different algorithms have been proposed for such task, most of them are application dependent. The suggested approach begins with a pre-processing step followed by sequence of: segmentation, features extraction and classification. This approach is particular for two reasons:  first, a new segmentation strategy based on competition scenario is suggested; secondly, detection is performed from the coarsest segmentation to the finest segmentation using a binary tree classifier. The proposed method was applied to a series of images from the Digital Database for Screening. Preliminary results are promising; a large study using more cases is currently in progress","PeriodicalId":14377,"journal":{"name":"International Review of Biophysical Chemistry","volume":"67 1","pages":"131-138"},"PeriodicalIF":0.0,"publicationDate":"2013-08-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81203258","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Mathematical Models for Mixing Time of Some Additive Free Calcium Soap Lubricating Greases 无钙皂类润滑脂混合时间的数学模型
Pub Date : 2013-06-30 DOI: 10.15866/IREBIC.V4I3.1646
A. Sterpu, I. Niță, A. Neagu, A. Dumitru, Sibel Geacai
Mixing is among the most common processes in chemical, biochemical, pharmaceutical, polymer, mineral, food, and wastewater treatment industries [1]. Several examples of greases mixing processes can be found in the literature [2]-[5]. Four greases were prepared with different concentration of calcium soap: 5%, 10%, 15% and 20% in paraffin oil. The preparation formulas for these four greases and manufacture method were presented in a recent work [6]. The aim of this study was to find a mathematical model for the mixing time of some additive-free lubricating greases. The mathematical modeling consisted on finding an accurate equation linking the mixing time (tm) and the Reynolds number (Re) at different soap concentrations and temperatures. The mixing experiments were carried out in a laboratory autoclave equipped with an anchor impeller, without baffles, at 8 speed ratio, from 100 to 800 rpm. The models resulted from the tm variation versus Re are power function type tm = a x Reb, where the coefficients a and b are functions of soap concentration in base oil and the processing temperature
混合是化学、生化、制药、聚合物、矿物、食品和废水处理行业中最常见的过程之一。润滑脂混合过程的几个例子可以在文献[2]-[5]中找到。在石蜡油中添加5%、10%、15%和20%的钙皂,制备了4种润滑脂。本文介绍了这四种润滑脂的制备配方和制备方法。本研究的目的是建立一些无添加剂润滑脂混合时间的数学模型。数学建模的目的是找到在不同肥皂浓度和温度下混合时间(tm)和雷诺数(Re)之间的精确方程。混合实验在装有锚式叶轮的实验室高压釜中进行,无挡板,转速比为8,转速为100 ~ 800 rpm。tm随Re变化的模型为幂函数型tm = a x Reb,其中系数a和b是基础油中肥皂浓度和加工温度的函数
{"title":"Mathematical Models for Mixing Time of Some Additive Free Calcium Soap Lubricating Greases","authors":"A. Sterpu, I. Niță, A. Neagu, A. Dumitru, Sibel Geacai","doi":"10.15866/IREBIC.V4I3.1646","DOIUrl":"https://doi.org/10.15866/IREBIC.V4I3.1646","url":null,"abstract":"Mixing is among the most common processes in chemical, biochemical, pharmaceutical, polymer, mineral, food, and wastewater treatment industries [1]. Several examples of greases mixing processes can be found in the literature [2]-[5]. Four greases were prepared with different concentration of calcium soap: 5%, 10%, 15% and 20% in paraffin oil. The preparation formulas for these four greases and manufacture method were presented in a recent work [6]. The aim of this study was to find a mathematical model for the mixing time of some additive-free lubricating greases. The mathematical modeling consisted on finding an accurate equation linking the mixing time (tm) and the Reynolds number (Re) at different soap concentrations and temperatures. The mixing experiments were carried out in a laboratory autoclave equipped with an anchor impeller, without baffles, at 8 speed ratio, from 100 to 800 rpm. The models resulted from the tm variation versus Re are power function type tm = a x Reb, where the coefficients a and b are functions of soap concentration in base oil and the processing temperature","PeriodicalId":14377,"journal":{"name":"International Review of Biophysical Chemistry","volume":"6 1","pages":"109-112"},"PeriodicalIF":0.0,"publicationDate":"2013-06-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74458711","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Proposal of Simulation-Based Management of Biological or Chemical Incidents as a Smart Solution 基于仿真的生化事件管理智能解决方案的提出
Pub Date : 2013-06-30 DOI: 10.15866/IREBIC.V4I3.1647
V. Bureš, P. Čech, T. Otcenásková
Management of biological or chemical incidents represents a challenging and demanding issue since it consists of several complex activities and important decisions. In case of accidents in agricultural or industrial mills or plants these decisions have to be made by personnel who are usually not primarily trained for such situations. From the technological perspective, various approaches or principles have been already applied and intended for computer-based support of biological or chemical incidents management. However, few of them incorporate principles of smart solutions which can make decisions even more precise and appropriate. This paper presents model utilizable for the management of biological or chemical incidents created in the multi-agent NetLogo environment and outlines possibilities of its extension by smart solution elements. Furthermore, together with the description of the simulation model, its parameterization is explained, and areas for further research are depicted
生物或化学事件的管理是一个具有挑战性和要求很高的问题,因为它包括若干复杂的活动和重要的决定。在农业或工业工厂发生事故的情况下,这些决定必须由通常没有受过此类培训的人员做出。从技术角度来看,已经应用和打算采用各种方法或原则,以计算机为基础支助生物或化学事件管理。然而,它们很少包含智能解决方案的原则,这些原则可以使决策更加精确和适当。本文提出了在多智能体NetLogo环境中创建的用于生物或化学事件管理的模型,并概述了通过智能解决方案元素扩展该模型的可能性。在此基础上,结合仿真模型的描述,对模型的参数化进行了说明,并指出了有待进一步研究的领域
{"title":"Proposal of Simulation-Based Management of Biological or Chemical Incidents as a Smart Solution","authors":"V. Bureš, P. Čech, T. Otcenásková","doi":"10.15866/IREBIC.V4I3.1647","DOIUrl":"https://doi.org/10.15866/IREBIC.V4I3.1647","url":null,"abstract":"Management of biological or chemical incidents represents a challenging and demanding issue since it consists of several complex activities and important decisions. In case of accidents in agricultural or industrial mills or plants these decisions have to be made by personnel who are usually not primarily trained for such situations. From the technological perspective, various approaches or principles have been already applied and intended for computer-based support of biological or chemical incidents management. However, few of them incorporate principles of smart solutions which can make decisions even more precise and appropriate. This paper presents model utilizable for the management of biological or chemical incidents created in the multi-agent NetLogo environment and outlines possibilities of its extension by smart solution elements. Furthermore, together with the description of the simulation model, its parameterization is explained, and areas for further research are depicted","PeriodicalId":14377,"journal":{"name":"International Review of Biophysical Chemistry","volume":"54 1","pages":"113-118"},"PeriodicalIF":0.0,"publicationDate":"2013-06-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80750175","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
期刊
International Review of Biophysical Chemistry
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1