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Principles, design, structure and properties of ceramics for microwave absorption or transmission at high-temperatures 高温微波吸收或传输陶瓷的原理、设计、结构和性能
IF 16.1 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2021-06-21 DOI: 10.1080/09506608.2021.1941716
Daxin Li, D. Jia, Zhihua Yang, Yu Zhou
ABSTRACT The multifunctional metastable SiBOCN system ceramics (including SiBN, SiCN, SiON, SiBC, SiBCN, SiBON, SiBOCN, etc.) are a new type of advanced structure–function integrated materials with unique structure and adjustable dielectric properties for high-temperature applications in thermal protection, communications, precise guidance, and microwave-absorption stealthy. These metastable materials generally require the rational co-design of multiscale structure and chemical composition to achieve desirable dielectric properties which induce interaction with incident electromagnetic wave. Herein, this review presents the latest development of metastable SiBOCN system ceramics, with the intent of summarising key findings, uncovering major trends and providing guidance for future efforts. Major themes in this assessment focus on the main processing routes, basic mechanisms for microwave transmission and absorption, scientific basis for material selection in specific background, principles for multiscale structure design and chemistry optimisation, tunable microwave transparent or absorbing properties, and future challenges and prospects in this active research filed.
多功能亚稳SiBOCN体系陶瓷(包括SiBN、SiCN、SiON、SiBC、SiBCN、SiBON、SiBOCN等)是一种新型的先进结构功能集成材料,具有独特的结构和可调的介电性能,可用于热防护、通信、精确制导和微波吸收隐身等高温领域。这些亚稳材料通常需要合理地协同设计多尺度结构和化学成分,以获得理想的介电性能,从而诱导入射电磁波的相互作用。在此,本文综述了亚稳SiBOCN体系陶瓷的最新进展,旨在总结关键发现,揭示主要趋势,并为未来的努力提供指导。本次评估的主要主题集中在主要的加工路线、微波传输和吸收的基本机制、特定背景下材料选择的科学依据、多尺度结构设计和化学优化的原理、可调的微波透明或吸收性能,以及这一活跃研究领域的未来挑战和前景。
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引用次数: 44
Functional liquid crystalline epoxy networks and composites: from materials design to applications 功能性液晶环氧树脂网络和复合材料:从材料设计到应用
IF 16.1 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2021-06-10 DOI: 10.1080/09506608.2021.1937811
Yuzhan Li, V. Ambrogi, P. Cerruti, Monojoy Goswami, Zhou Yang, M. R. Kessler, Orlando Rios
ABSTRACT Liquid crystalline epoxy networks (LCENs) are a class of materials that combine the useful benefits of both liquid crystals and epoxy networks exhibiting fascinating thermal, mechanical, and stimuli-responsive properties. They have emerged as a new platform for developing functional materials suitable for various applications, such as sensors, actuators, smart coatings and adhesives, tunable optical systems, and soft robotics. This article provides an overview of LCENs and their composites as functional materials, including their synthesis and characterisation, focusing on structure-processing–property relationships. We provide objective analyses on how materials engineers can use these relationships to develop LCENs with desired functionalities for targeted applications. Emerging areas, including advanced manufacturing and multi-functional design of LCENs are covered to show the overall progress in this field. We also survey the forward-looking status of LCEN research in designing novel materials for future technologies.
液晶环氧树脂网络(LCENs)是一类结合了液晶和环氧树脂网络的有用优点的材料,具有迷人的热、机械和刺激响应性能。它们已经成为开发适用于各种应用的功能材料的新平台,例如传感器,执行器,智能涂层和粘合剂,可调光学系统和软机器人。本文综述了LCENs及其复合材料作为功能材料的研究进展,包括它们的合成和表征,重点介绍了结构-加工-性能关系。我们就材料工程师如何利用这些关系开发具有目标应用所需功能的LCENs提供了客观的分析。包括先进制造和多功能设计在内的新兴领域,展示了该领域的总体进展。我们还调查了len研究在为未来技术设计新材料方面的前瞻性地位。
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引用次数: 6
Metal hybrids processed by high-pressure torsion: synthesis, microstructure, mechanical properties and developing trends 高压扭转加工金属杂化材料的合成、微观结构、力学性能及发展趋势
IF 16.1 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2021-06-01 DOI: 10.1080/09506608.2021.1922807
D. Hernández-Escobar, M. Kawasaki, C. Boehlert
ABSTRACT The tradeoff between strength and ductility has long been identified as the ‘Achilles’ heel’ of the mechanical properties in engineering applications. Metal hybrids processed by severe plastic deformation (SPD) have gained significant attention in recent years, as they have shown potential for enhancing strength and ductility simultaneously through different heterostructured designs. Among SPD processes, high-pressure torsion (HPT) is considered the most effective in grain refinement and offers excellent versatility for synthesising new materials with a wide variety of experimental setups and processing parameters. This review article describes the current state-of-the-art of metal hybrids processed by HPT, characterised by heterogeneous microstructures (i.e. nanoscale and/or microscale), through a comprehensive study of their synthesis-microstructure-property relationships. The potential of HPT-processed hybrids is highlighted and discussed along with their limitations. Suggestions are provided with the aim to advance current research trends towards future application in high-impact technologies, including the biomedical and microelectronic industries.
长期以来,强度和延性之间的权衡一直被认为是工程应用中机械性能的“阿喀琉斯之踵”。强塑性变形(SPD)处理的金属杂化材料近年来备受关注,因为它们显示出通过不同的异质结构设计同时提高强度和延性的潜力。在SPD工艺中,高压扭转(HPT)被认为是最有效的晶粒细化方法,并为合成具有各种实验设置和加工参数的新材料提供了出色的多功能性。本文通过对其合成-微观结构-性能关系的综合研究,介绍了目前HPT加工的具有非均相微观结构(即纳米级和/或微尺度)的金属杂化材料的最新进展。hpt加工的混合动力的潜力被突出和讨论,以及它们的局限性。提出了一些建议,旨在推动当前的研究趋势,以实现未来在高影响力技术中的应用,包括生物医学和微电子工业。
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引用次数: 8
Defect phases – thermodynamics and impact on material properties 缺陷相——热力学和对材料性能的影响
IF 16.1 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2021-05-26 DOI: 10.1080/09506608.2021.1930734
S. Korte-Kerzel, T. Hickel, L. Huber, D. Raabe, S. Sandlöbes-Haut, M. Todorova, J. Neugebauer
ABSTRACT Two approaches in materials physics have proven immensely successful in alloy design: First, thermodynamic and kinetic descriptions for tailoring and processing alloys to achieve a desired microstructure. Second, crystal defect manipulation to control strength, formability and corrosion resistance. However, to date, the two concepts remain essentially decoupled. A bridge is needed between these powerful approaches to achieve a single conceptual framework. Considering defects and their thermodynamic state holistically as ‘defect phases’, provides a future materials design strategy by jointly treating the thermodynamic stability of both, the local crystalline structure and the distribution of elements at defects. Here, we suggest that these concepts are naturally linked by defect phase diagrams describing the coexistence and transitions of defect phases. Construction of these defect phase diagrams will require new quantitative descriptors. We believe such a framework will enable a paradigm shift in the description and design of future engineering materials.
摘要材料物理学中的两种方法在合金设计中取得了巨大成功:首先,热力学和动力学描述,用于定制和加工合金以获得所需的微观结构。其次,对晶体缺陷进行处理,以控制强度、成形性和耐腐蚀性。然而,到目前为止,这两个概念基本上是脱钩的。需要在这些强大的方法之间架起一座桥梁,以实现单一的概念框架。将缺陷及其热力学状态整体视为“缺陷相”,通过联合处理两者的热力学稳定性、局部晶体结构和缺陷处元素的分布,提供了未来的材料设计策略。在这里,我们建议这些概念通过描述缺陷相共存和转变的缺陷相图自然地联系起来。构建这些缺陷相图将需要新的定量描述符。我们相信,这样的框架将使未来工程材料的描述和设计发生范式转变。
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引用次数: 20
Multifunctional applications of biochar beyond carbon storage 生物炭在碳储存之外的多功能应用
IF 16.1 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2021-05-07 DOI: 10.1080/09506608.2021.1922047
N. Bolan, Son A. Hoang, Jingzi Beiyuan, Souradeep Gupta, D. Hou, A. Karakoti, S. Joseph, Sungyup Jung, Ki-Hyun Kim, M. Kirkham, H. Kua, Manoj Kumar, E. Kwon, Y. Ok, V. Perera, J. Rinklebe, S. Shaheen, B. Sarkar, A. Sarmah, Bhupinder Singh, Gurwinder Singh, Daniel C W Tsang, Kumar Vikrant, M. Vithanage, A. Vinu, Hailong Wang, H. Wijesekara, Yubo Yan, S. A. Younis, L. Zwieten
ABSTRACT Biochar is produced as a charred material with high surface area and abundant functional groups by pyrolysis, which refers to the process of thermochemical decomposition of organic material at elevated temperatures in the absence of oxygen. The carbon component in biochar is relatively stable, and, hence, biochar was originally proposed as a soil amendment to store carbon in the soil. Biochar has multifunctional values that include the use of it for the following purposes: soil amendment to improve soil health, nutrient and microbial carrier, immobilising agent for remediation of toxic metals and organic contaminants in soil and water, catalyst for industrial applications, porous material for mitigating greenhouse gas emissions and odorous compounds, and feed supplement to improve animal health and nutrient intake efficiency and, thus, productivity. This article provides for the first time an overview of the multifunctional values and unintended consequences of biochar applications.
摘要生物炭是指在无氧条件下,有机材料在高温下发生热化学分解的过程,是一种具有高表面积和丰富官能团的烧焦材料。生物炭中的碳成分相对稳定,因此,生物炭最初被认为是一种将碳储存在土壤中的土壤改良剂。生物炭具有多功能价值,包括将其用于以下目的:改善土壤健康的土壤改良剂、营养和微生物载体、修复土壤和水中有毒金属和有机污染物的固定剂、工业应用催化剂、减少温室气体排放的多孔材料和气味化合物,以及饲料补充,以提高动物健康和营养摄入效率,从而提高生产力。本文首次概述了生物炭应用的多功能价值和意外后果。
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引用次数: 214
Piezoelectric polymers: theory, challenges and opportunities 压电聚合物:理论、挑战与机遇
IF 16.1 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2021-04-30 DOI: 10.1080/09506608.2021.1915935
Michael Smith, S. Kar‐Narayan
ABSTRACT Piezoelectric materials can directly transduce electrical and mechanical energy, making them attractive for applications such as sensors, actuators and energy harvesting devices. While often associated with ceramic materials, piezoelectric behaviour is also observed in many polymers. The flexibility, ease of processing and biocompatibility of piezoelectric polymers mean that they are often preferable for certain applications, despite their lower piezoelectric coefficients. This review will cover some theoretical and practical concepts of piezoelectricity in polymers, such as the symmetry requirements, the underlying mechanism and the necessary materials processing. A brief review of the applications of piezoelectric polymers is also presented. One of the main motivations of this review is to discuss the challenges and open questions in the field in an effort to highlight potential future research directions.
压电材料可以直接转换电能和机械能,这使其在传感器、致动器和能量采集设备等应用中具有吸引力。虽然通常与陶瓷材料有关,但在许多聚合物中也观察到压电行为。压电聚合物的灵活性、易加工性和生物相容性意味着,尽管其压电系数较低,但它们通常更适合某些应用。这篇综述将涵盖聚合物压电性的一些理论和实践概念,如对称性要求、潜在机制和必要的材料加工。文中还简要介绍了压电聚合物的应用。这篇综述的主要动机之一是讨论该领域的挑战和悬而未决的问题,以突出未来潜在的研究方向。
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引用次数: 78
Advances in the development of biobased epoxy resins: insight into more sustainable materials and future applications 生物基环氧树脂的发展进展:洞察更可持续的材料和未来的应用
IF 16.1 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2021-04-28 DOI: 10.1080/09506608.2021.1915936
F. Gonçalves, Marta Santos, T. Cernadas, P. Ferreira, P. Alves
ABSTRACT The urgent need to replace fossil resource-based products is considerably increasing in the past few years, resulting in the search for more sustainable materials, with the aim of reducing the wastes from polymer pollution, solving economic and environmental issues. This is even more relevant in industrial fields, where toxic compounds are the basis of their polymeric formulations. Herein is reported the most relevant advances of epoxy resins (ERs) in the past decade, with great emphasis on the replacement of bisphenol A (BPA), leading to the production of renewable-based ERs with good properties. The synthesis of ERs based on renewable sources, such as vegetable oils, phenolic compounds, sugars and the outcome in the material’s structure is explored within this review. Emphasis is also given to the use of new biobased curing agents and biofillers to enhance the biocharacter of the ERs.
近年来,人们越来越迫切地需要替代化石资源产品,从而寻求更可持续的材料,以减少聚合物污染产生的废物,解决经济和环境问题。这在工业领域更为重要,因为有毒化合物是其聚合物配方的基础。本文介绍了近十年来环氧树脂(ERs)的最新进展,重点介绍了双酚A (BPA)的替代,从而生产出性能良好的可再生环氧树脂。本文综述了基于可再生资源,如植物油、酚类化合物、糖的合成及其对材料结构的影响。重点介绍了新型生物基固化剂和生物填料的应用,以提高其生物特性。
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引用次数: 26
Recent progress in photocatalytic degradation of chlorinated phenols and reduction of heavy metal ions in water by TiO2-based catalysts 二氧化钛基催化剂光催化降解氯代苯酚及水中重金属离子研究进展
IF 16.1 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2021-02-28 DOI: 10.1080/09506608.2021.1891368
Ayoola Shoneye, Jang Sen Chang, M. Chong, Junwang Tang
ABSTRACT Among the various semiconductor photocatalysts reported so far, TiO2 is still the most promising material for real applications because of its excellent chemical and thermal stability, non-toxicity, low cost and highly oxidising photogenerated holes. This review summarises the recent progress (mainly over the last five years) in photocatalytic oxidation of non-biodegradable organic pollutants (chlorophenols) and reduction of toxic heavy metal ions in aqueous solution. The review details the recently developed strategies for improving the performance of TiO2-based photocatalysts, with particular respect to the visible light activity, charge separation efficiency, stability, separability and adsorption capacity for the remediation of the aforementioned categories of water contaminants, as these factors heavily affect the practical application of this technology. Next, the underlying semiconductor photocatalytic mechanisms have been thoroughly addressed experimentally and theoretically, together with the proposed defect engineering to improve the photocatalytic performance. Finally, the prospect of TiO2 photocatalysis was discussed.
摘要在迄今为止报道的各种半导体光催化剂中,TiO2仍然是最有前途的实际应用材料,因为它具有优异的化学和热稳定性、无毒性、低成本和高度氧化的光生空穴。本文综述了光催化氧化不可生物降解的有机污染物(氯酚)和减少水溶液中有毒重金属离子的最新进展(主要是在过去五年中)。综述详细介绍了最近开发的提高TiO2基光催化剂性能的策略,特别是在可见光活性、电荷分离效率、稳定性、可分离性和吸附能力方面,用于修复上述类别的水污染物,因为这些因素严重影响该技术的实际应用。接下来,已经从实验和理论上彻底解决了潜在的半导体光催化机制,并提出了改进光催化性能的缺陷工程。最后对TiO2光催化的前景进行了展望。
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引用次数: 40
Computational modelling of process–structure–property–performance relationships in metal additive manufacturing: a review 金属增材制造中工艺-结构-性能-性能关系的计算建模:综述
IF 16.1 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2021-01-24 DOI: 10.1080/09506608.2020.1868889
S. M. Hashemi, S. Parvizi, Haniyeh Baghbanijavid, Alvin T. L. Tan, M. Nematollahi, A. Ramazani, N. Fang, M. Elahinia
ABSTRACT In the current review, an exceptional view on the multi-scale integrated computational modelling and data-driven methods in the Additive manufacturing (AM) of metallic materials in the framework of integrated computational materials engineering (ICME) is discussed. In the first part of the review, process simulation (P-S linkage), structure modelling (S-P linkage), property simulation (S-P linkage), and integrated modelling (PSP and PSPP linkages) are elaborated considering different physical phenomena (multi-physics) in AM and at micro/meso/macro scales (multi-scale modelling). The second part provides an extensive discussion of a data-driven framework, which involves extracting existing data from databases and texts, data pre-processing, high throughput screening, and, therefore, database construction. A data-driven workflow that integrates statistical methods, including ML, artificial intelligence (AI), and neural network (NN) models, has great potential for completing PSPP linkages. This review paper provides an insight for both academic and industrial researchers, working on the AM of metallic materials.
摘要在当前的综述中,讨论了在集成计算材料工程(ICME)框架下,金属材料增材制造(AM)中的多尺度集成计算建模和数据驱动方法的特殊观点。在综述的第一部分中,考虑到AM和微/中/宏观尺度上的不同物理现象(多物理)(多尺度建模),详细阐述了过程模拟(P-S连杆)、结构建模(S-P连杆)、性能模拟(S-P杆)和集成建模(PSP和PSPP连杆)。第二部分对数据驱动框架进行了广泛的讨论,包括从数据库和文本中提取现有数据、数据预处理、高通量筛选,以及数据库构建。数据驱动的工作流集成了统计方法,包括ML、人工智能(AI)和神经网络(NN)模型,在完成PSPP链接方面具有巨大潜力。这篇综述论文为研究金属材料AM的学术和工业研究人员提供了一个见解。
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引用次数: 41
A critical review of corrosion characteristics of additively manufactured stainless steels 增材制造不锈钢的腐蚀特性综述
IF 16.1 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2020-12-17 DOI: 10.1080/09506608.2020.1855381
M. Laleh, A. Hughes, W. Xu, I. Gibson, M. Tan
ABSTRACT Additive manufacturing (AM) is associated with a sequence of rapid heating and cooling cycles along with large temperature gradients, developing complex thermal histories which have direct influence on resultant microstructures. Such a dynamic and far-from-equilibrium process leads to distinct microstructural features that are expected to cause changes in the corrosion characteristics of AM stainless steels. Currently such changes are not well understood, consequently inconsistencies and disagreements are frequently found in the literature on the corrosion behaviour of AM stainless steels. This paper performs a critical review of corrosion characteristics of AM stainless steels by assessing the effects of their unique microstructural features on corrosion behaviour, with particular focus on new corrosion phenomena and selected critical forms of localised corrosion including pitting corrosion, erosion-corrosion, intergranular corrosion, fatigue corrosion, and stress corrosion cracking. Discussion on the mechanisms of these corrosion phenomena and behaviour, as well as major influencing factors, are undertaken, leading to recommendations and suggestions for future development of AM stainless steels for various corrosive conditions.
摘要:增材制造(AM)与一系列快速加热和冷却循环以及大的温度梯度有关,产生复杂的热历史,直接影响最终的微观结构。这种动态且远离平衡的过程会导致不同的微观结构特征,预计这些特征会导致AM不锈钢腐蚀特性的变化。目前,这种变化还没有得到很好的理解,因此在AM不锈钢腐蚀行为的文献中经常发现不一致和分歧。本文通过评估AM不锈钢独特的微观结构特征对腐蚀行为的影响,对其腐蚀特性进行了批判性综述,特别关注新的腐蚀现象和局部腐蚀的选定关键形式,包括点蚀、侵蚀腐蚀、晶间腐蚀、疲劳腐蚀,以及应力腐蚀开裂。对这些腐蚀现象和行为的机理以及主要影响因素进行了讨论,为AM不锈钢在各种腐蚀条件下的未来发展提出了建议和建议。
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引用次数: 33
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International Materials Reviews
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