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Hybrid materials – a review on co-dispersion, processing, patterning, and properties 杂化材料——共色散、加工、图案和性能综述
IF 16.1 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2020-11-16 DOI: 10.1080/09506608.2019.1653569
K. Lu
ABSTRACT Inorganic and organic hybrids are a class of new materials that are purposely designed and arranged at individual species levels (often at nanoscale) to provide new morphological attributes and properties. This review is intended to offer a systematic discussion and understanding of nanoparticle–polymer hybrid materials. First, integration of nanoparticles and organic matrices is explained from two aspects: mixing of nanoparticles and organic matrix materials and in-situ formation of hybrids; the latter includes both in-situ nanoparticle formation and in-situ polymerisation. Traditional processing techniques for hybrids, such as spin coating and casting, are briefly reviewed followed by more detailed discussion on patterning through self-organisation, laser-induced patterning, and nanoimprint lithographic moulding. The extraordinary potentials of hybrids in existing property improvement and new property creation, including mechanical property, electronic property, optical property, catalytic property, magnetic property, and sensing property are presented. Lastly, opportunities and challenges for future hybrid material development are provided.
无机和有机杂交种是一类新材料,它们被有意地设计和排列在单个物种水平(通常在纳米尺度上),以提供新的形态属性和性能。本文旨在对纳米颗粒-聚合物杂化材料进行系统的讨论和认识。首先,从纳米颗粒与有机基质材料的混合和原位形成杂化体两个方面阐述了纳米颗粒与有机基质的结合;后者包括原位纳米颗粒形成和原位聚合。本文简要回顾了传统的复合材料加工技术,如旋涂和铸造,然后详细讨论了通过自组织、激光诱导图案和纳米压印光刻成型的图案。介绍了混合材料在现有性能改进和新性能创造方面的非凡潜力,包括机械性能、电子性能、光学性能、催化性能、磁性和传感性能。最后,提出了未来混合材料发展的机遇和挑战。
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引用次数: 7
Review of fatigue of bulk structural adhesives and thick adhesive joints 大块结构胶粘剂和厚胶粘剂接头的疲劳研究进展
IF 16.1 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2020-11-12 DOI: 10.1080/09506608.2020.1845110
Peiyuan Zuo, A. P. Vassilopoulos
ABSTRACT Fatigue of structural adhesives has been investigated through joints and a little number of works investigate bulk adhesive behaviour itself. Aerospace and automotive engineering focuses more on joint configuration studies, which are correlated with practical applications. Previous works showed that for thin adhesive joints, material properties measured by bulk adhesive testing and joint testing are similar despite the triaxial stress states developing in the adhesive bondlines. However, with the introduction of structural adhesives in construction industry, thicker bondlines have emerged where the bulk adhesive material dominates the joint behaviour. This review work summarises works on the fatigue of bulk structural adhesives used mainly in the construction industry investigating structural adhesives fatigue behaviour either through experiment on joints or on bulk adhesive specimens. The work focuses on thick adhesive bondlines in joints, and discusses the controversy that is over whether adhesive properties from joints or from bulk material should be used.
摘要:结构胶粘剂的疲劳已经通过接头进行了研究,少量工作研究了本体胶粘剂本身的行为。航空航天和汽车工程更多地关注与实际应用相关的联合构型研究。先前的工作表明,对于薄胶接接头,尽管胶接线中存在三轴应力状态,但通过本体胶接试验和接头试验测量的材料性能是相似的。然而,随着结构粘合剂在建筑行业的引入,出现了较厚的粘合线,其中大块粘合剂材料主导了接缝行为。这项综述工作总结了主要用于建筑行业的散装结构粘合剂的疲劳工作,通过对接缝或散装粘合剂样品的实验来研究结构粘合剂疲劳行为。这项工作的重点是接缝中的厚粘合线,并讨论了关于是否应该使用接缝或散装材料的粘合性能的争议。
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引用次数: 29
Calcia–magnesia–alumina–silicate (CMAS) attack mechanisms and roadmap towards Sandphobic thermal and environmental barrier coatings 钙镁铝硅酸盐(CMAS)的攻击机理和疏沙热环境屏障涂层的发展方向
IF 16.1 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2020-10-29 DOI: 10.1080/09506608.2020.1824414
A. Nieto, R. Agrawal, L. Bravo, Clara Hofmeister-Mock, M. Pepi, A. Ghoshal
ABSTRACT This review critically examines the current understanding of calcia–magnesia–alumina–silicate (CMAS) degradation mechanisms and mitigation approaches in thermal and environmental barrier coatings. First, the review introduces case studies of field returned engine components exposed to CMAS attack, followed by fundamental aspects of CMAS-induced degradation. Understanding CMAS adhesion, infiltration, spallation mechanics, and thermochemical attack mechanisms is crucial to designing materials approaches to mitigate CMAS attack. CMAS mitigation strategies have focused on reactive approaches aimed at crystallising molten CMAS at the earliest stage possible to inhibit infiltration. Promising approaches are presented, starting with fundamental reaction kinetics studies, followed by the effects of microstructure in actual coatings systems. Salient results on coating systems tested in various burner rigs and a full engine test are presented to benchmark the success of various mitigation strategies. Lastly, several key future research areas are presented in order to provide a roadmap towards ‘sandphobic’ thermal and environmental barrier systems.
本文综述了目前对钙镁铝硅酸盐(CMAS)在热和环境屏障涂层中的降解机制和缓解方法的理解。首先,该综述介绍了受到CMAS攻击的现场返回发动机部件的案例研究,然后介绍了CMAS引起的退化的基本方面。了解CMAS的粘附、渗透、剥落力学和热化学攻击机制对于设计减轻CMAS攻击的材料方法至关重要。CMAS减缓战略侧重于反应性方法,旨在尽早使熔融的CMAS结晶,以抑制渗透。提出了有前途的方法,从基本的反应动力学研究开始,然后是实际涂层系统中微观结构的影响。在各种燃烧器平台和全发动机测试中,涂层系统的显著结果被提出,以基准各种缓解策略的成功。最后,提出了几个关键的未来研究领域,以便为“疏沙”热和环境屏障系统提供路线图。
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引用次数: 37
Electrophoretic deposition of carbon nanotubes: recent progress and remaining challenges 碳纳米管的电泳沉积:最近的进展和仍然存在的挑战
IF 16.1 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2020-10-13 DOI: 10.1080/09506608.2020.1831299
M. A. U. Rehman, M. A. U. Rehman, Qian Chen, A. Braem, M. Shaffer, A. Boccaccini
ABSTRACT Electrophoretic deposition (EPD) is a powerful technique to assemble carbon nanotube (CNT) coatings and composite films with controlled architectures. This comprehensive review of the EPD of CNTs and CNT-containing composites focuses on achievements within the last 15 years and ongoing challenges. Stable CNT suspensions are a pre-requisite for successful EPD and have been prepared by a variety of strategies, discussed here. The resulting film microstructure is determined by the initial feedstock, the suspension, and the EPD approach applied, as well as a variety of EPD processing parameters. Nanocomposites can be prepared via co-deposition, sequential deposition, or post-deposition treatments, to introduce metallic, ceramic or polymeric phases. There are numerous potential applications for both homogeneous and patterned CNT films, including as structural reinforcements for composites, as field emission, energy storage and conversion devices, as well as in biomedical applications. The advantages and disadvantages of EPD processing in these contexts are discussed.
摘要电泳沉积(EPD)是一种组装具有可控结构的碳纳米管(CNT)涂层和复合膜的强大技术。这篇关于碳纳米管和含碳纳米管复合材料的EPD的全面综述侧重于过去15年的成就和持续的挑战。稳定的CNT悬浮液是成功EPD的先决条件,并且已经通过多种策略制备,本文对此进行了讨论。所得薄膜微观结构由初始原料、悬浮液和所应用的EPD方法以及各种EPD工艺参数决定。纳米复合材料可以通过共沉积、顺序沉积或沉积后处理来制备,以引入金属、陶瓷或聚合物相。均匀的和图案化的CNT膜都有许多潜在的应用,包括作为复合材料的结构增强体,作为场发射、能量存储和转换器件,以及在生物医学应用中。讨论了EPD处理在这些背景下的优点和缺点。
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引用次数: 49
Confinement effects on compressive and ballistic performance of ceramics: a review 约束效应对陶瓷压缩和弹道性能的影响
IF 16.1 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2020-10-13 DOI: 10.1080/09506608.2020.1830665
Rui Zhang, B. Han, T. Lu
ABSTRACT Ceramic materials have been extensively used as armour materials for nearly 50 years and continue to attract great interest in the field of defense technology. As confinement is crucial for ceramics to achieve enhanced performance, it has become indispensable in ceramic armour systems. This review aims to explore the effects of a wide variety of confinement on ceramic performance, so as to provide scientific insights for further exploration and development of ceramic materials and ceramic-based armour systems for both researchers and engineers. This work first characterises multiaxial compressive experiments of ceramics, explores confinement-induced brittle to ductile transition, and presents pressure-dependent micromechanical and phenomenological constitutive models. Subsequently, the change of fracture mode under compression and the reduction of damage extent under projectile impact are separately discussed. Enhancement in ballistic performance by confining and prestressing ceramics is also introduced, with corresponding physical mechanisms explored. Last but not least, insights into future opportunities and challenges are presented.
陶瓷材料作为装甲材料已被广泛应用了近50年,并在国防技术领域继续引起人们的极大兴趣。由于约束是提高陶瓷性能的关键,因此约束在陶瓷装甲系统中已成为必不可少的。本文旨在探讨各种约束对陶瓷性能的影响,从而为研究人员和工程师进一步探索和开发陶瓷材料和陶瓷装甲系统提供科学见解。这项工作首先对陶瓷的多轴压缩实验进行了表征,探索了禁锢诱导的脆性到韧性的转变,并提出了与压力相关的微观力学和现象学本构模型。在此基础上,分别讨论了压缩作用下断裂模式的变化和弹丸冲击作用下损伤程度的减小。还介绍了围压和预应力陶瓷对弹道性能的提高,并探讨了相应的物理机制。最后,对未来的机遇和挑战提出了见解。
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引用次数: 25
Copper-based alloys for structural high-heat-flux applications: a review of development, properties, and performance of Cu-rich Cu–Cr–Nb alloys 用于结构高热通量应用的铜基合金:富铜Cu–Cr–Nb合金的发展、性能和性能综述
IF 16.1 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2020-10-08 DOI: 10.1080/09506608.2020.1821485
Robert P. Minneci, E. Lass, J. Bunn, H. Choo, C. Rawn
ABSTRACT This review examines the development and current state of Cu-rich Cu–Cr–Nb alloys commonly referred to as GRCop or Glenn Research copper alloys with emphasis on Cu–8Cr–4Nb (at%), or GRCop-84, and Cu–4Cr–2Nb, or GRCop-42. Recent additive manufacturing efforts have increased interest in GRCop alloys, and full-scale hardware has been fabricated using AM techniques and practical hot-fire tests have been conducted, but structure–property relationships are still under development. The development, processing, and current microstructure-property relationships of GRCop alloys are reviewed along with comparisons to similar high-heat-flux Cu alloys including NARloy-Z, GlidCop Al-15, AMZIRC, Cu–1Cr–0.1Zr, and Cu–0.9Cr. The review concludes with an assessment of future prospects for GRCop alloys and overview of advantages provided by additive manufacturing.
摘要本文综述了富铜Cu–Cr–Nb合金(通常称为GRCop或Glenn Research铜合金)的发展和现状,重点介绍了Cu–8Cr–4Nb(at%)、GRCop-84和Cu–4Cr–2Nb或GRCop-42。最近的增材制造工作增加了人们对GRCop合金的兴趣,已经使用AM技术制造了全尺寸的硬件,并进行了实际的防火测试,但结构-性能关系仍在开发中。综述了GRCop合金的发展、加工和目前的微观结构-性能关系,并与类似的高热通量铜合金(包括NARloy-Z、GlidCop Al-15、AMZIRC、Cu–1Cr–0.1Zr和Cu–0.9Cr)进行了比较。最后,对GRCop合金未来的前景进行了评估,并概述了增材制造的优势。
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引用次数: 47
Selection, processing, properties and applications of ultra-high temperature ceramic matrix composites, UHTCMCs – a review 超高温陶瓷基复合材料的选择、加工、性能及应用综述
IF 16.1 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2020-10-02 DOI: 10.1080/09506608.2019.1652006
J. Binner, M. Porter, B. Baker, J. Zou, V. Venkatachalam, Virtudes Rubio Diaz, A. D’Angiò, P. Ramanujam, Tailin Zhang, T. Murthy
ABSTRACT Composites are, in general, a rapidly evolving and growing technical field with a very wide range of applications across the aerospace, defence, energy, medical and transport sectors as a result of their superior mechanical and physical properties. Ultra-high temperature ceramic matrix composites, UHTCMCs, are a new subfield within the wider grouping of CMCs that offer applications in rocket and hypersonic vehicle components, particularly nozzles, leading edges and engine components. The design and development of structural materials for use in oxidising and rapid heating environments at temperatures above 1600°C is therefore of both great scientific and engineering importance. UHTC materials are typically considered to be the carbides, nitrides, and borides of the transition metals, but the Group IV compounds (Zr, Hf & Ti) plus TaC are generally considered to be the main focus of research due to the superior melting temperatures and stable high-melting temperature oxide that forms in situ. This review presents the selection, processing, properties, applications, outlook and future directions of UHTCMCs.
总的来说,复合材料是一个快速发展和发展的技术领域,由于其优越的机械和物理性能,在航空航天、国防、能源、医疗和运输领域有着非常广泛的应用。超高温陶瓷基复合材料(uhtcmc)是一种新型的复合材料,主要应用于火箭和高超声速飞行器部件,特别是喷嘴、前缘和发动机部件。因此,在1600°C以上的氧化和快速加热环境中使用的结构材料的设计和开发具有重大的科学和工程重要性。UHTC材料通常被认为是过渡金属的碳化物、氮化物和硼化物,但IV族化合物(Zr、Hf和Ti)加上TaC通常被认为是研究的主要焦点,因为它具有优越的熔化温度和原位形成的稳定的高温氧化物。本文综述了超高温cmc的选择、加工、性能、应用、前景及未来发展方向。
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引用次数: 170
Cryomilling as environmentally friendly synthesis route to prepare nanomaterials 冷冻研磨作为制备纳米材料的环保合成途径
IF 16.1 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2020-09-30 DOI: 10.1080/09506608.2020.1825175
N. K. Katiyar, K. Biswas, C. Tiwary
ABSTRACT The milling of materials at cryogenic temperature has gained importance both in academic as well as the industrial community in the last two decades, primarily because of distinct advantages of this technique as compared to milling at room temperature; environmental friendly nature, cost-effectiveness, rapid grain refinement, less contamination, and large scale production capability of various nanomaterials. Scientifically, milling at cryo-temperature exhibits several distinct material related phenomena; suppression of recovery and recrystallisation, predominant fracture over cold welding, significantly low oxidation, and contamination, leading to rapid grain refinement. Cryomilling has extensively been used to obtain finer scale powder of spices for the preservation of aroma, medicines for effective dissolution, or amorphisation. It has been considered an environmentally friendly process as it utilises benign liquid nitrogen or argon without discharging any toxic entity. The present review is intended to provide various scientific as well as technological aspects of cryomilling, environmental impact, and future direction.
摘要在过去的二十年里,在低温下研磨材料在学术界和工业界都获得了重要地位,主要是因为与室温下研磨相比,这种技术具有明显的优势;环境友好的性质、成本效益、快速晶粒细化、污染少以及各种纳米材料的大规模生产能力。从科学角度讲,低温铣削表现出几种不同的材料相关现象;抑制恢复和再结晶,与冷焊相比主要断裂,显著降低氧化和污染,导致快速晶粒细化。冷冻研磨已被广泛用于获得用于保存香气的更精细的香料粉末、用于有效溶解或非晶化的药物。它被认为是一种环境友好的工艺,因为它使用良性液氮或氩气,而不会排放任何有毒物质。本综述旨在提供冷冻铣削的各种科学和技术方面、环境影响和未来方向。
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引用次数: 21
Directional recrystallisation processing: a review 定向再结晶工艺综述
IF 16.1 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2020-09-17 DOI: 10.1080/09506608.2020.1819688
Chao Yang, I. Baker
ABSTRACT Directional recrystallisation processing is a solid-state process in which a specimen traverses a sharp hot zone and one or a few grains grow as they pass through the hot zone. The mechanism can be either a primary recrystallisation or secondary recrystallisation process, or a combination of both. The mechanism can be either primary recrystallisation or secondary recrystallisation process, or a combination of both. Directional recrystallisation was invented more than 80 years ago to achieve columnar grain structures or single crystals that have enhanced mechanical properties. This review discusses the effects of both processing parameters, including the temperature gradient, hot-zone velocity, and annealing temperature, and microstructural parameters, including stored energy, grain size, initial texture, solutes, and both soluble and insoluble particles, on the resulting microstructures. The results of simulations of directional recrystallisation, including Monte Carlo simulations, Front-Tracking methods, and phase-field simulations, are also reviewed. Finally, the effects of directional recrystallisation on material properties are discussed.
摘要定向再结晶工艺是一种固态工艺,试样穿过一个尖锐的热区,一个或几个晶粒在穿过热区时生长。该机制可以是一次再结晶或二次再结晶过程,也可以是二者的组合。其机制可以是一次再结晶或二次再结晶过程,也可以是二者的结合。定向再结晶是80多年前发明的,目的是获得具有增强机械性能的柱状晶粒结构或单晶。这篇综述讨论了两个工艺参数(包括温度梯度、热区速度和退火温度)和微观结构参数(包括储能、晶粒尺寸、初始织构、溶质以及可溶性和不溶性颗粒)对所得微观结构的影响。还回顾了定向再结晶的模拟结果,包括蒙特卡罗模拟、前沿跟踪方法和相场模拟。最后,讨论了定向再结晶对材料性能的影响。
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引用次数: 7
Artificial intelligence-enabled smart mechanical metamaterials: advent and future trends 人工智能驱动的智能机械超材料:出现和未来趋势
IF 16.1 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2020-09-08 DOI: 10.1080/09506608.2020.1815394
Pengcheng Jiao, A. Alavi
ABSTRACT Mechanical metamaterials have opened an exciting venue for control and manipulation of architected structures in recent years. Research in the area of mechanical metamaterials has covered many of their fabrication, mechanism characterisation and application aspects. More recently, however, a paradigm shift has emerged to an exciting research direction towards designing, optimising and characterising mechanical metamaterials using artificial intelligence (AI) techniques. This new line of research aims at addressing the difficulties in mechanical metamaterials (i.e. design, analysis, fabrication and industrial application). This review article discusses the advent and development of mechanical metamaterials, and the future trends of applying AI to obtain smart mechanical metamaterials with programmable mechanical response. We explain why architected materials and structures have prominent advantages, what are the main challenges in the mechanical metamaterial research domain, and how to surpass the limit of mechanical metamaterials via the AI techniques. We finally envision the potential research avenues and emerging trends for using the AI-enabled mechanical metamaterials for future innovations.
近年来,机械超材料为建筑结构的控制和操纵开辟了一个令人兴奋的领域。机械超材料领域的研究涵盖了其制造、机理表征和应用等诸多方面。然而,最近,一个令人兴奋的研究方向出现了范式转变,即使用人工智能(AI)技术设计、优化和表征机械超材料。这一新的研究方向旨在解决机械超材料(即设计、分析、制造和工业应用)中的困难。本文综述了机械超材料的出现和发展,以及应用人工智能获得具有可编程机械响应的智能机械超材料的未来趋势。我们解释了为什么建筑材料和结构具有突出的优势,机械超材料研究领域的主要挑战是什么,以及如何通过人工智能技术超越机械超材料的极限。我们最后设想了使用人工智能支持的机械超材料进行未来创新的潜在研究途径和新兴趋势。
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引用次数: 52
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