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Laser absorption correction for hydroxyl planar laser induced fluorescence measurements in a centrally staged combustor at elevated pressures 高压下中央分段燃烧器中羟基平面激光诱导荧光测量的激光吸收校正
IF 3.2 3区 物理与天体物理 Q2 PHYSICS, APPLIED Pub Date : 2024-09-19 DOI: 10.1063/5.0228168
Kexin Ji, Xin Hui, Chao Tao, Xin Xue, Qiang An
Planar laser-induced fluorescence (PLIF) is a crucial spectroscopic technique for measuring minor species [e.g., hydroxyl (OH), methylene (CH), and nitric oxide (NO) radicals] in combustion research, owing to its non-intrusive nature and high sensitivity. However, laser energy attenuation due to absorption poses significant challenges to its application under high-pressure conditions, which may cause asymmetric image intensity distribution along the light propagation direction. An absorption correction method for OH PLIF based on the concept of maximum number density is proposed in the present study. This method offers several key advantages, including simplicity, high accuracy, and versatility, allowing for correcting both time-averaged and instantaneous OH PLIF images. OH PLIF data obtained from a centrally staged combustor at elevated pressures (i.e., 0.3, 0.6, and 1.0 MPa) are utilized to validate the method. Correction for the time-averaged PLIF images achieves a much more symmetric distribution of OH, revealing the overall flame structures that would not have been completely visualized from the original images. The fronts of the pilot and main stage flames have also been recovered from the corrected instantaneous images. This correction algorithm provides an effective way of enhancing data quality for high-cost OH PLIF measurements at pressurized conditions.
平面激光诱导荧光(PLIF)具有非侵入性和高灵敏度的特点,是燃烧研究中测量次要物种(如羟基(OH)、亚甲基(CH)和一氧化氮(NO)自由基)的重要光谱技术。然而,吸收导致的激光能量衰减对其在高压条件下的应用提出了巨大挑战,可能导致沿光传播方向的图像强度分布不对称。本研究提出了一种基于最大数量密度概念的 OH PLIF 吸收校正方法。这种方法具有几个主要优点,包括简单、准确度高和通用性强,既可校正时间平均图像,也可校正瞬时 OH PLIF 图像。从中心分级燃烧器在高压(即 0.3、0.6 和 1.0 兆帕)下获得的 OH PLIF 数据被用来验证该方法。对时间平均 PLIF 图像进行校正后,OH 的分布更加对称,从而揭示了原始图像无法完全显示的整体火焰结构。经过校正的瞬时图像还恢复了先导阶段和主阶段火焰的前沿。这种校正算法为在加压条件下进行高成本 OH PLIF 测量提供了一种提高数据质量的有效方法。
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引用次数: 0
Focus control of a concave–convex ultrasonic gel lens in the radial direction 凹凸超声波凝胶透镜径向聚焦控制
IF 3.2 3区 物理与天体物理 Q2 PHYSICS, APPLIED Pub Date : 2024-09-18 DOI: 10.1063/5.0218754
K. Tagashira, Y. Harada, K. Nakamura, H. Miki, M. Matsukawa, D. Koyama
Optical image stabilization (OIS) systems maintain the three-dimensional focal position of a lens through mechanical actuation systems. This paper examines an optical lens for OIS that utilizes ultrasound vibration to alter the focal position, not only in the depth direction but also in the radial direction. The lens has a simple structure with no mechanical moving parts and consists of an ultrasound transducer divided into four pieces, a glass disk, and a transparent viscoelastic gel film that functions as a lens. The acoustic radiation force generated by the resonant flexural vibration of the glass disk can alter the surface profile of the gel film, allowing for a variable-focus function. The concave and convex lenses can be interchanged using two resonant vibration modes: the standing-wave mode, in which the vibration loop appears at the center, and the traveling-wave mode, in which the vibration node appears at the center. The positions of ultrasound vibrations on the lens can be controlled in a two-dimensional plane by adjusting the driving amplitudes of each channel, thereby achieving focus control in the radial direction. The focusing characteristics of the lens are evaluated through ray-tracing simulation.
光学图像稳定(OIS)系统通过机械致动系统保持透镜的三维焦点位置。本文研究了一种用于 OIS 的光学透镜,它利用超声波振动来改变焦距位置,不仅在深度方向上,而且在径向方向上也是如此。该透镜结构简单,没有机械运动部件,由分成四块的超声换能器、玻璃圆盘和充当透镜的透明粘弹性凝胶薄膜组成。玻璃盘的共振弯曲振动产生的声辐射力可以改变凝胶膜的表面轮廓,从而实现可变焦距功能。凹透镜和凸透镜可通过两种共振振动模式进行互换:立波模式和行波模式,前者的振动环出现在中心位置,后者的振动节点出现在中心位置。通过调整每个通道的驱动振幅,可在二维平面上控制透镜上超声波振动的位置,从而实现径向聚焦控制。通过光线跟踪模拟评估了透镜的聚焦特性。
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引用次数: 0
Continuum models for meso-scale simulations of HMX (1,3,5,7-tetranitro-1,3,5,7-tetrazocane) guided by molecular dynamics: Pore collapse, shear bands, and hotspot temperature 分子动力学指导下的 HMX(1,3,5,7-tetranitro-1,3,5,7-tetrazocane)中尺度模拟连续模型:孔隙塌陷、剪切带和热点温度
IF 3.2 3区 物理与天体物理 Q2 PHYSICS, APPLIED Pub Date : 2024-09-18 DOI: 10.1063/5.0232413
Yen Thi Nguyen, Chukwudubem Okafor, Puhan Zhao, Oishik Sen, Catalin R. Picu, Tommy Sewell, H. S. Udaykumar
Meso-scale calculations of energy localization and initiation in energetic material microstructures must capture the deformation and collapse of pores and high-temperature shear bands, which lead to hotspots. Because chemical reaction rates depend sensitively on temperature, predictive continuum models need to get the pore-collapse dynamics and resulting hotspot temperatures right; this imposes stringent demands on the fidelity of thermophysical model forms and parameters and on the numerical methods employed to perform high-resolution meso-scale calculations. Here, continuum material models for β-HMX are examined in the context of shock-induced pore collapse, treating predictions from all-atom molecular dynamics (MD) simulations as ground truth. Using atomistics-consistent material properties, we show that the currently available strength models for HMX fail to correctly capture pore collapse and hotspot temperatures. Insights from MD are then employed to advance a Modified Johnson–Cook (M-JC) strength model, which is shown to capture key aspects of the physics of shock-induced localization in HMX. The study culminates in a MD-guided strength model for β-HMX that produces continuum pore-collapse results in better alignment on several aspects with those predicted by MD, including pore-collapse mechanism and rate, shear-band formation in the collapse zone, and temperature, strain, and stress fields in the hotspot zone and the surrounding material. The resulting MD-informed/MD-determined M-JC model should improve the fidelity of meso-scale simulations to predict the detonation initiation of HMX-based energetic materials in microstructure-aware multi-scale frameworks.
高能材料微结构中能量定位和引发的中尺度计算必须捕捉导致热点的孔隙和高温剪切带的变形和塌缩。由于化学反应速率敏感地取决于温度,因此预测性连续模型必须正确地反映孔隙塌缩动力学和由此产生的热点温度;这对热物理模型形式和参数的保真度以及用于执行高分辨率中尺度计算的数值方法提出了严格的要求。本文以冲击诱导孔隙塌陷为背景,将全原子分子动力学(MD)模拟的预测结果作为基本事实,对β-HMX 的连续材料模型进行了研究。利用原子论一致的材料特性,我们表明目前可用的 HMX 强度模型无法正确捕捉孔隙塌陷和热点温度。然后,我们利用 MD 的洞察力来推进修正约翰逊-库克(M-JC)强度模型,结果表明该模型能够捕捉到 HMX 中冲击诱导定位物理学的关键方面。这项研究最终为 β-HMX 建立了以 MD 为指导的强度模型,该模型产生的连续孔隙塌缩结果在多个方面与 MD 预测的结果更加一致,包括孔隙塌缩机制和速率、塌缩区剪切带的形成,以及热点区和周围材料的温度、应变和应力场。由此产生的 MD 信息/MD 确定的 M-JC 模型应能提高中尺度模拟的保真度,从而在微观结构感知的多尺度框架中预测基于 HMX 的高能材料的起爆。
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引用次数: 0
Optical actinometry for number density measurements in low-pressure plasmas: Advantages, error sources, and method validation 用于测量低压等离子体中数量密度的光学致动测量法:优势、误差源和方法验证
IF 3.2 3区 物理与天体物理 Q2 PHYSICS, APPLIED Pub Date : 2024-09-18 DOI: 10.1063/5.0227576
Nikolay Britun, Michael K. T. Mo, Shih-Nan Hsiao, Fatima J. T. Arellano, Makoto Sekine, Masaru Hori
Number density of plasma-generated atoms or molecules is an important parameter for both fundamental research and applications. It can be measured in a straightforward manner, using vacuum-ultraviolet absorption spectroscopy, which is mainly possible in laboratory conditions as it may require bulky equipment, such as lasers. By contrast, optical actinometry is an alternative approach that only uses spontaneous emission from the plasma. This technique relies on the so-called corona excitation and uses emission line ratios between the gases with unknown and known concentrations (called actinometer in the last case). As a result of using line ratios, the additional density calibration is not required if the excitation cross sections are known. This study discusses Ar-based actinometry in low-pressure (roughly <1 kPa) plasma discharges with an emphasis on multiple line ratios. The work is particularly focused on the method’s applicability, the choice of Ar cross sections, and potential error sources. The influence of the additional excitation mechanisms is analyzed based on both experiments and modeling. The optical transitions for F, O, H, N, and P atoms along with expressions for their number density are presented, not requiring high optical resolution for measurements. For the sake of method validation, it is shown that in low-pressure radiofrequency discharges, a nearly excellent agreement between the actinometry data and the calibrated measurements can be achieved by careful selection of optical transitions.
等离子体产生的原子或分子的数量密度是基础研究和应用的重要参数。它可以用真空紫外吸收光谱法进行直接测量,但由于可能需要激光等笨重的设备,这种方法主要只能在实验室条件下使用。相比之下,光学锕系元素测量法是一种只利用等离子体自发辐射的替代方法。这种技术依赖于所谓的电晕激发,并使用未知浓度气体和已知浓度气体之间的发射线比率(在最后一种情况下称为放线仪)。由于使用了线比,如果已知激发截面,就不需要额外的密度校准。本研究讨论了低压(大约 1 kPa)等离子体放电中基于氩的放电测量法,重点是多线比。这项工作尤其关注该方法的适用性、氩截面的选择以及潜在的误差源。根据实验和建模分析了附加激发机制的影响。在不要求高光学分辨率测量的情况下,介绍了 F、O、H、N 和 P 原子的光学跃迁及其数量密度表达式。为了验证方法,研究表明在低压射频放电中,通过仔细选择光学跃迁,可以实现放电测量数据与校准测量数据之间近乎完美的一致性。
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引用次数: 0
Ultrafast manipulations of nanoscale skyrmioniums 纳米级天铱的超快操作
IF 3.2 3区 物理与天体物理 Q2 PHYSICS, APPLIED Pub Date : 2024-09-18 DOI: 10.1063/5.0227996
H. M. Dong, P. P. Fu, Y. F. Duan, K. Chang
The advancement of next-generation magnetic devices depends on fast manipulating magnetic microstructures at the nanoscale. A universal method is presented for rapid and reliable generating, controlling, and driving nano-scale skyrmioniums, through high-throughput micromagnetic simulations. Ultrafast switches are realized between skyrmionium and skyrmion states and rapidly change their polarities in monolayer magnetic nanodisks by perpendicular magnetic fields. The transition mechanism by alternating magnetic fields differs from that under steady magnetic fields. New skyrmionic textures, such as flower-like and windmill-like skyrmions, are discovered. Moreover, this nanoscale skyrmionium can move rapidly and stably in nanoribbons using weaker spin-polarized currents. Explicit discussions are held regarding the physical mechanisms involved in ultrafast manipulations of skyrmioniums. This work provides further physical insights into the manipulation and application of topological skyrmionic structures for developing low-power consumption and nanostorage devices.
下一代磁性器件的发展取决于对纳米级磁性微结构的快速操控。本文提出了一种通用方法,通过高通量微磁模拟,快速可靠地生成、控制和驱动纳米级天鎓。在垂直磁场的作用下,在单层磁性纳米盘中实现了skyrmionium和skyrmion状态之间的超快切换,并迅速改变了它们的极性。交变磁场下的转换机制与稳定磁场下的转换机制不同。研究人员发现了新的天电离纹理,如花朵状天电离和风车状天电离。此外,利用较弱的自旋极化电流,这种纳米尺度的天空离子可以在纳米带中快速稳定地移动。研究人员对超快操纵天鎓的物理机制进行了明确的讨论。这项工作为拓扑天电离结构的操纵和应用提供了进一步的物理见解,有助于开发低功耗和纳米存储设备。
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引用次数: 0
The novel impedance matching device realized by the structure of air-gap ring based on the doping method at microwave frequency 基于掺杂法的气隙环结构在微波频率下实现的新型阻抗匹配器件
IF 3.2 3区 物理与天体物理 Q2 PHYSICS, APPLIED Pub Date : 2024-09-18 DOI: 10.1063/5.0230486
Lin Zhao, Jiaxin Li, Li Pan
The doping method enabled the epsilon-near-zero (ENZ) medium to adjust its permeability effectively. In this study, we theoretically analyze that the gap ring structure formed by the ENZ medium doped with perfect electrical conductor (PEC) can be equivalent to the controllable series reactance. Based on this concept, a universal matching network that can match any complex impedance load by adjusting the gap ring spacing is constructed. We used the above universal matching network to carry out theoretical and simulation calculations on the matching effect of a random-sized stepped waveguide and horn antenna, and the results show that the impedance-matching technology has a good matching effect for different loads. Finally, experimental verification is carried out. Compared with traditional impedance-matching networks, the proposed structure has the characteristics of simplicity, reliability, low loss, high carrying power, low preparation requirements, and good application prospects. This work is a good example of the practicality of ENZ media and also provides a very meaningful idea for the development of new electromagnetic matching devices.
掺杂方法使ε-近零(ENZ)介质能够有效调节其磁导率。在本研究中,我们从理论上分析了掺杂完美电导体(PEC)的 ENZ 介质形成的间隙环结构可以等效为可控串联电抗。基于这一概念,我们构建了一个通用匹配网络,它可以通过调整间隙环间距来匹配任何复杂阻抗负载。我们利用上述通用匹配网络对随机大小的阶梯波导和喇叭天线的匹配效果进行了理论和仿真计算,结果表明该阻抗匹配技术对不同负载具有良好的匹配效果。最后,还进行了实验验证。与传统的阻抗匹配网络相比,所提出的结构具有简单、可靠、低损耗、高承载功率、低准备要求和良好的应用前景等特点。这项工作很好地证明了 ENZ 介质的实用性,同时也为新型电磁匹配器件的开发提供了一个非常有意义的思路。
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引用次数: 0
Multicaloric response tuned by electric field in cylindrical MnAs/PZT magnetoelectric composite 通过电场调节圆柱形 MnAs/PZT 磁电复合材料的多磁响应
IF 3.2 3区 物理与天体物理 Q2 PHYSICS, APPLIED Pub Date : 2024-09-17 DOI: 10.1063/5.0231720
Abdulkarim A. Amirov, Maksim A. Koliushenkov, Abdula A. Mukhuchev, Dibir M. Yusupov, Valeriya V. Govorina, Dmitriy S. Neznakhin, Gennady A. Govor, Akhmed M. Aliev
The possibility observation of the electric field controlled multicaloric response through quasi-isostatic compression as a result of the converse piezoelectric effect was demonstrated on the cylindrical type magnetoelectric composite MnAs/PZT. It was shown that an electric voltage of 100 V corresponding to an electric field of E ∼0.3 kV/mm applied to the walls of the piezoelectric component PZT of the MnAs/PZT composite contributes to an increase in the maximum adiabatic temperature change by 0.2 K in the temperature range of the magnetostructural phase transition of MnAs ∼317 K at a magnetic field change of 1.8 T. Numerical analysis using the finite element method has shown that an electric field voltage of 100 V is capable of creating a quasi-isostatic mechanical stress in the region inside a cylindrical PZT tube of ∼3 MPa. Moreover, in the region of weak pressures up to 10 MPa, the contribution to the total adiabatic temperature change from piezo-mechanical compression linearly depends on the electrical voltage that can be used for control by magnetic and caloric properties of multicaloric materials.
在圆柱型磁电复合材料 MnAs/PZT 上观察到了通过准等静压产生的反向压电效应来实现电场控制多磁性响应的可能性。研究表明,在 MnAs/PZT 复合材料的压电元件 PZT 的壁上施加 100 V 的电压(对应于 E ∼ 0.3 kV/mm 的电场),可使最大绝热温度变化增加 0.使用有限元法进行的数值分析表明,100 V 的电场电压能够在圆柱形 PZT 管内部区域产生 ∼3 MPa 的准等静压机械应力。此外,在高达 10 兆帕的微弱压力区域,压电机械压缩对总绝热温度变化的贡献与电场电压成线性关系,可用于控制多热体材料的磁性和热量特性。
{"title":"Multicaloric response tuned by electric field in cylindrical MnAs/PZT magnetoelectric composite","authors":"Abdulkarim A. Amirov, Maksim A. Koliushenkov, Abdula A. Mukhuchev, Dibir M. Yusupov, Valeriya V. Govorina, Dmitriy S. Neznakhin, Gennady A. Govor, Akhmed M. Aliev","doi":"10.1063/5.0231720","DOIUrl":"https://doi.org/10.1063/5.0231720","url":null,"abstract":"The possibility observation of the electric field controlled multicaloric response through quasi-isostatic compression as a result of the converse piezoelectric effect was demonstrated on the cylindrical type magnetoelectric composite MnAs/PZT. It was shown that an electric voltage of 100 V corresponding to an electric field of E ∼0.3 kV/mm applied to the walls of the piezoelectric component PZT of the MnAs/PZT composite contributes to an increase in the maximum adiabatic temperature change by 0.2 K in the temperature range of the magnetostructural phase transition of MnAs ∼317 K at a magnetic field change of 1.8 T. Numerical analysis using the finite element method has shown that an electric field voltage of 100 V is capable of creating a quasi-isostatic mechanical stress in the region inside a cylindrical PZT tube of ∼3 MPa. Moreover, in the region of weak pressures up to 10 MPa, the contribution to the total adiabatic temperature change from piezo-mechanical compression linearly depends on the electrical voltage that can be used for control by magnetic and caloric properties of multicaloric materials.","PeriodicalId":15088,"journal":{"name":"Journal of Applied Physics","volume":"21 1","pages":""},"PeriodicalIF":3.2,"publicationDate":"2024-09-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142260291","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Performance optimization for magnetoelectric antennas based on a multi-field coupling analysis model 基于多场耦合分析模型的磁电天线性能优化
IF 3.2 3区 物理与天体物理 Q2 PHYSICS, APPLIED Pub Date : 2024-09-17 DOI: 10.1063/5.0231433
Yue Mao, Qiyuan Jiao, Yang Shi
This paper presents a multi-field coupling model for magnetoelectric (ME) antennas, encompassing a ME film, electrode layers, and a substrate featuring a cavity structure. This model accounts for the nonlinear magnetoelastic coupling within the radiation layer and employs a combined DC and AC simulation methodology to capture the antenna's radiation mechanism. Leveraging this multi-field coupling model, performance differences between the ME antenna and an ideal ME composite film are analyzed. By exploring optimization schemes based on multi-physics fields, electrode materials, and structural design, the ME antenna's radiation performance is significantly enhanced. The findings demonstrate that the complete antenna structure, with its increased thickness and cavity design, exhibits a lower resonance frequency and a higher converse ME (CME) coefficient compared to the ideal ME film. The optimal CME effect is achieved under proper external stimuli, leading to a broader 3 dB bandwidth. Expanding the cavity dimensions enhances the CME coefficient by 42% and reduces the resonance frequency due to decreased acoustic wave loss. Adopting electrode materials with higher acoustic impedance elevates the CME coefficient, yet narrows the bandwidth. Conversely, using silver (Ag) electrodes promotes a broader bandwidth. Additionally, ME antenna arrays are designed to broaden the bandwidth by 300%.
本文介绍了磁电(ME)天线的多场耦合模型,包括磁电薄膜、电极层和具有空腔结构的基板。该模型考虑了辐射层内的非线性磁弹性耦合,并采用直流和交流相结合的仿真方法来捕捉天线的辐射机制。利用这一多场耦合模型,分析了 ME 天线与理想 ME 复合薄膜之间的性能差异。通过探索基于多物理场、电极材料和结构设计的优化方案,ME 天线的辐射性能显著提高。研究结果表明,与理想的 ME 薄膜相比,增加了厚度和腔体设计的完整天线结构具有更低的谐振频率和更高的反向 ME(CME)系数。在适当的外部刺激下,CME 效果达到最佳,从而获得更宽的 3 dB 带宽。扩大腔体尺寸可将 CME 系数提高 42%,并由于声波损耗的减少而降低共振频率。采用声阻抗较高的电极材料可提高 CME 系数,但会缩小带宽。相反,使用银(Ag)电极则可提高带宽。此外,ME 天线阵列的设计可将带宽拓宽 300%。
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引用次数: 0
An innovative approach to control the Hf/Ti ratio in monolayers grown via atomic partial layer deposition 控制通过原子部分层沉积生长的单层中 Hf/Ti 比率的创新方法
IF 3.2 3区 物理与天体物理 Q2 PHYSICS, APPLIED Pub Date : 2024-09-17 DOI: 10.1063/5.0225744
M. I. Pérez-Valverde, E. López-Luna, E. Martínez-Guerra, J. G. R. Hernández-Arteaga, M. A. Vidal
The Hf/Ti ratio was precisely controlled at monolayer thickness using atomic partial layer deposition (APLD). HfxTi1−xO2 films with varying Hf concentrations were deposited by adjusting the pulse time of Hf precursors within a single atomic layer. Characterization using x-ray reflectivity, x-ray photoelectron spectroscopy, and spectroscopic ellipsometry confirmed the presence of Hf, Ti, and O in the films. Increasing the Hf content caused the binding energies of the O 1s peak to shift to higher values, indicating a chemical environment change from TiO2-like to HfO2-like. A higher Hf content also increased the relative atomic percentages of Hf, Ti, and O, altering the film properties. The mass density and optical properties were notably sensitive to changes in the Hf/Ti ratio at monolayer thickness. The potential of APLD to reduce dimensionality through precise control of both thickness and composition renders it especially appropriate for applications requiring highly specific material properties.
利用原子局部层沉积(APLD)技术精确控制了单层厚度的铪/钛比。通过调整单原子层中 Hf 前驱体的脉冲时间,沉积出了不同 Hf 浓度的 HfxTi1-xO2 薄膜。利用 X 射线反射率、X 射线光电子能谱和光谱椭偏仪进行的表征证实了薄膜中 Hf、Ti 和 O 的存在。增加 Hf 含量会导致 O 1s 峰的结合能向更高值移动,表明化学环境从类似 TiO2 转变为类似 HfO2。较高的 Hf 含量还增加了 Hf、Ti 和 O 的相对原子百分比,从而改变了薄膜的性质。在单层厚度下,质量密度和光学特性对 Hf/Ti 比率的变化非常敏感。APLD 具有通过精确控制厚度和成分来降低尺寸的潜力,因此特别适用于需要高度特定材料特性的应用。
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引用次数: 0
An electro-thermal finite element method (FEM) model for local hotspot kinetics in Cu(In, Ga)Se2 thin-film solar modules 铜铟镓硒薄膜太阳能模块局部热点动力学的电热有限元法 (FEM) 模型
IF 3.2 3区 物理与天体物理 Q2 PHYSICS, APPLIED Pub Date : 2024-09-17 DOI: 10.1063/5.0222051
Suheir Nofal, Timon S. Vaas, Uwe Rau, Bart E. Pieters
Partial shading can significantly impair the efficiency of thin-film solar cells. When exposed to partial shading, cells within the array tend to become reverse biased, leading to thermal runaway events and the emergence of hotspots. In Cu(In,Ga)Se2 (CIGS) solar cells such hotspots are also associated with so-called worm-like defects. Both theoretical and experimental studies have shown that in CIGS, a positive-feedback loop leads to instability and thermal runaway events. However, we observe an inconsistency between published simulation results and recently published experimental work. In a recent experimental study, it was shown that under certain conditions, a hotspot develops within 1ms, showing signs of melting of the CIGS in an area with a 5μm radius. However, in published simulation results, the time for such high temperatures to develop is in the order of seconds, a discrepancy of three orders of magnitude. In this work, we argue that this discrepancy is explained by the size of the seed defect, demonstrating that the origin of these experimentally observed, fast-developing hotspots is likely microscopic defects. To this end, we developed an electro-thermal finite element model, with very high temporal and spatial resolution. We demonstrate that, assuming a seed defect with a 10nm radius, we can reproduce the experimental results with respect to the size of the defect and the time it took to develop.
局部遮光会严重影响薄膜太阳能电池的效率。在部分遮光的情况下,阵列中的电池容易出现反向偏置,导致热失控事件和热点的出现。在铜铟镓硒(CIGS)太阳能电池中,这种热点也与所谓的蠕虫状缺陷有关。理论和实验研究都表明,在 CIGS 中,正反馈回路会导致不稳定和热失控事件。然而,我们注意到已公布的模拟结果与最近公布的实验结果不一致。最近的一项实验研究表明,在特定条件下,1 毫秒内会出现一个热点,在半径为 5 微米的区域内显示出 CIGS 的熔化迹象。然而,在已公布的模拟结果中,出现这种高温的时间约为几秒,相差三个数量级。在这项工作中,我们认为这种差异可以用种子缺陷的大小来解释,证明这些实验观测到的快速发展热点的起源很可能是微观缺陷。为此,我们开发了一个具有极高时空分辨率的电热有限元模型。我们证明,假设种子缺陷的半径为 10 纳米,我们就能在缺陷大小和形成时间方面重现实验结果。
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引用次数: 0
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Journal of Applied Physics
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