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On the effect of polarization relaxation on dielectric breakdown 极化弛豫对介质击穿的影响
IF 3.2 3区 物理与天体物理 Q2 PHYSICS, APPLIED Pub Date : 2024-09-13 DOI: 10.1063/5.0217634
Serge Blonkowski
This article discusses the effect of polarization relaxation on dielectric breakdown. We establish analytical statistical Weibull distributions, taking into account the changing local electric field instead of the usual static field in acceleration models. The time dependence of the local field is expressed using the universal Curie–Von Schweidler law. The derived distribution fits well with various observations on time-to-breakdown statistical distributions. In the case of voltage square pulse alternative stress, the calculated time to breakdown follows a power law with stress frequency, regardless of the field dependence of the acceleration model, consistent with observations. The dielectric lifetime is longer compared to continuous voltage stress, as observed in transistors and integrated capacitors. The analytical expression of the power law exponent depends on the field acceleration model and polarization current. It matches well with the measured values for metal–oxide–semiconductor and metal insulator metal capacitors with different dielectrics. The power law exponent increases with the static dielectric constant. The Weibull shape factor is shown to be lower in the AC mode than in the DC mode, as observed. The AC signal duty factor effect decreases the lifetime in the AC mode. Finally, we demonstrate that the consequence of polarization relaxation also affects the lifetime in the DC mode. The acceleration factor and lifetime projections are close to power laws with the field, regardless of the static field dependence of the acceleration model.
本文讨论了极化弛豫对介质击穿的影响。我们建立了分析统计 Weibull 分布,考虑到了不断变化的局部电场,而不是加速模型中通常的静态电场。局部电场的时间依赖性用通用的居里-冯-施韦德勒定律来表示。推导出的分布与时间-击穿统计分布的各种观测结果非常吻合。在电压方波脉冲替代应力的情况下,无论加速模型的场依赖性如何,计算出的击穿时间与应力频率成幂律关系,这与观测结果一致。与在晶体管和集成电容器中观察到的连续电压应力相比,介质寿命更长。幂律指数的分析表达式取决于场加速模型和极化电流。它与不同电介质的金属氧化物半导体电容器和金属绝缘体金属电容器的测量值非常吻合。幂律指数随静态介电常数的增加而增加。据观察,交流模式下的威布尔形状系数低于直流模式下的威布尔形状系数。交流信号占空比效应降低了交流模式下的寿命。最后,我们证明极化松弛的结果也会影响直流模式下的寿命。加速因子和寿命推算与磁场的幂律接近,与加速模型的静态磁场依赖性无关。
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引用次数: 0
Shock equation of state experiments in MgO up to 1.5 TPa and the effects of optical depth on temperature determination 高达 1.5 TPa 的氧化镁冲击状态方程实验以及光学深度对温度测定的影响
IF 3.2 3区 物理与天体物理 Q2 PHYSICS, APPLIED Pub Date : 2024-09-13 DOI: 10.1063/5.0226765
Zixuan Ye, Raymond F. Smith, Marius Millot, Melissa Sims, Dimitrios Tsapetis, Michael D. Shields, Saransh Singh, Anirudh Hari, June K. Wicks
Laser-driven shock compression enables an experimental study of phase transitions at unprecedented pressures and temperatures. One example is the shock Hugoniot of magnesium oxide (MgO), which crosses the B1–B2-liquid triple point at 400–600 GPa, 10 000–13 000 K (0.86–1.12 eV). MgO is a major component within the mantles of terrestrial planets and has long been a focus of high-pressure research. Here, we combine time-resolved velocimetry and pyrometry measurements with a decaying shock platform to obtain pressure–temperature data on MgO from 300 to 1500 GPa and 9000 to 50 000 K. Pressure–temperature–density Hugoniot data are reported at 1500 GPa. These data represent the near-instantaneous response of an MgO [100] single crystal to shock compression. We report on a prominent temperature anomaly between 400 and 460 GPa, in general agreement with previous shock studies, and draw comparison with equation-of-state models. We provide a detailed analysis of the decaying shock compression platform, including a treatment of a pressure-dependent optical depth near the shock front. We show that if the optical depth of the shocked material is larger than 1 μm, treating the shock front as an optically thick gray body will lead to a noticeable overestimation of the shock temperature.
激光驱动的冲击压缩可以在前所未有的压力和温度下对相变进行实验研究。其中一个例子是氧化镁(MgO)的冲击休格尼奥特,它在 400-600 GPa、10 000-13 000 K (0.86-1.12 eV) 时跨越了 B1-B2- 液体三重点。氧化镁是陆地行星外壳中的主要成分,长期以来一直是高压研究的重点。在这里,我们将时间分辨速度测量法和高温测量法测量与衰减冲击平台相结合,获得了氧化镁在 300 至 1500 GPa 和 9000 至 50000 K 的压力-温度数据。这些数据代表了氧化镁 [100] 单晶体对冲击压缩的近乎瞬时响应。我们报告了 400 至 460 GPa 之间的显著温度异常,这与之前的冲击研究基本一致,并与状态方程模型进行了比较。我们对衰减的冲击压缩平台进行了详细分析,包括对冲击前沿附近随压力变化的光学深度的处理。我们表明,如果冲击物质的光学深度大于 1 μm,将冲击前沿视为光学厚灰体将导致对冲击温度的明显高估。
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引用次数: 0
Ablation characteristics of tungsten with ultra-short laser pulses 超短激光脉冲对钨的烧蚀特性
IF 3.2 3区 物理与天体物理 Q2 PHYSICS, APPLIED Pub Date : 2024-09-13 DOI: 10.1063/5.0222073
Steffen Mittelmann, Jan Riedlinger, Benedikt Buchner, Thomas Schwarz-Selinger, Matej Mayer, Georg Pretzler
In approaches to analyze material composition or in processing tasks using ultra-short laser ablation, it is of particular interest how ablated materials are distributed across the solid angle in front of the interaction region. We found that with our sub-10-fs laser in the regime from 1014W/cm2 to 1017W/cm2, the solid angle of the ablation cone decreases significantly along with the laser intensity in a vacuum environment. For this observation, we used ion-beam analysis to investigate the distribution of tungsten collected on silicon catcher plates arranged across the solid angle of the laser-ablation cone. Moreover, we used other post-mortem tools, such as scanning electron microscopy and confocal laser scanning microscopy, to determine the ablation threshold of Fth=468mJ/cm2 of our tungsten samples. Here, clearly, two laser intensity-dependent ablation regimes can be observed in the detection of a crater depth and a ablation cone angle.
在使用超短激光烧蚀来分析材料成分或进行加工任务时,烧蚀材料如何在相互作用区域前的实体角上分布是一个特别令人感兴趣的问题。我们发现,使用 1014W/cm2 到 1017W/cm2 范围内的 10-fs 以下激光,在真空环境中,烧蚀锥的实体角会随着激光强度的增加而显著减小。为此,我们使用离子束分析法研究了在激光烧蚀锥实心角上排列的硅捕捉板上收集的钨的分布情况。此外,我们还使用了扫描电子显微镜和共聚焦激光扫描显微镜等其他死后工具,以确定钨样品的烧蚀阈值 Fth=468mJ/cm2 。很明显,在检测陨石坑深度和烧蚀锥角时,可以观察到两种与激光强度相关的烧蚀机制。
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引用次数: 0
Natural frequency informed finite element modal analysis method for estimating elastic properties of solid materials 用于估算固体材料弹性特性的固有频率信息有限元模态分析方法
IF 3.2 3区 物理与天体物理 Q2 PHYSICS, APPLIED Pub Date : 2024-09-13 DOI: 10.1063/5.0231087
Sanjay Mahat, Roshan Sharma, Hyunjo Jeong, Jingfei Liu
This study proposes a simple yet effective dynamic method that can nondestructively evaluate the elastic properties of homogeneous isotropic solid materials. Like some dynamic methods, such as resonance ultrasound spectrometry and impulse excitation technique, the proposed method consists of two steps: experimentally acquiring the specimen's natural frequencies and numerically calculating the elastic properties. Compared with the existing methods, the proposed method has much lower requirements on all four aspects of experimental operations: specimen preparation, specimen positioning, vibration excitation, and vibration detection. An inverse method based on finite element modal analysis is proposed to calculate the specimen's elastic properties, and it can deliver optimal estimations with high precision and accuracy. The performance of the proposed method was assessed using the well-established sound speed-based dynamic method, i.e., ultrasound pulse-echo testing. Taking a square aluminum specimen as an example, the differences in the measurements of Young's modulus and Poisson's ratio between these two methods are 2.25% and −2.07%, respectively; the differences in the measurements of shear modulus and bulk modulus are 0.01% and −1.46%, respectively. In summary, the proposed method provides a cheaper and experimentally simpler approach to determining the elastic properties of solid materials while maintaining accuracy and reliability similar to the established methods, which typically require sophisticated, costly equipment.
本研究提出了一种简单而有效的动态方法,可以无损评估均质各向同性固体材料的弹性特性。与共振超声频谱法和脉冲激励技术等一些动态方法一样,所提出的方法包括两个步骤:实验获取试样的固有频率和数值计算弹性特性。与现有方法相比,拟议方法对实验操作的四个方面:试样制备、试样定位、振动激励和振动检测的要求都低得多。本文提出了一种基于有限元模态分析的反演方法来计算试样的弹性特性,该方法可以提供高精度和高准确度的最佳估计值。利用成熟的基于声速的动态方法,即超声脉冲回波测试,对所提出方法的性能进行了评估。以方形铝试样为例,这两种方法测量的杨氏模量和泊松比分别相差 2.25% 和 -2.07%;测量的剪切模量和体积模量分别相差 0.01% 和 -1.46%。总之,所提出的方法为测定固体材料的弹性特性提供了一种成本更低、实验更简单的方法,同时与通常需要复杂、昂贵设备的既定方法相比,保持了相似的准确性和可靠性。
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引用次数: 0
Features of the formation of hot dense plasma in X-pinches on current generators based on low-inductive capacitors 在基于低电感电容器的电流发生器上的 X 形针中形成热密集等离子体的特点
IF 3.2 3区 物理与天体物理 Q2 PHYSICS, APPLIED Pub Date : 2024-09-13 DOI: 10.1063/5.0220763
T. A. Shelkovenko, I. N. Tilikin, A. R. Mingaleev, V. M. Romanova, S. A. Pikuz
The paper presents the results of experimental studies of the operation of hybrid X-pinches on a modified high-current KING generator. The KING generator is a portable pulse current generator based on four low-inductive pulse capacitors. The output assembly of the generator was modified for greater diagnostic access to the load, which led to an increase in the inductance of the entire circuit and an increase in the duration of the current rise. A series of experiments with hybrid X-pinches with Al, Cu, and Mo wires with a diameter of 25 μm was carried out on the modified KING generator (200–260 kA, 220–280 ns, 45 kV). In experiments, it was shown that such a modification of the generator led to the stable formation of bright soft x-ray sources in X-pinches, suitable for use in point-projection radiography with a spatial resolution of about 10–15 μm.
本文介绍了在改进型大电流 KING 发生器上运行混合 X 针的实验研究结果。KING 发生器是一种基于四个低电感脉冲电容器的便携式脉冲电流发生器。对该发生器的输出组件进行了改装,以便对负载进行更多的诊断,从而增加了整个电路的电感量,并延长了电流上升的持续时间。在改装后的 KING 发生器(200-260 kA、220-280 ns、45 kV)上,使用直径为 25 μm 的铝线、铜线和钼线混合 X 针进行了一系列实验。实验表明,对发生器进行这样的改装,可以在 X 针中稳定地形成明亮的软 X 射线源,适用于空间分辨率约为 10-15 μm 的点投影射线照相术。
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引用次数: 0
Effects of irradiation damage on the hardness and elastic properties of quaternary and high entropy transition metal diborides 辐照损伤对四元和高熵过渡金属二硼化物硬度和弹性特性的影响
IF 3.2 3区 物理与天体物理 Q2 PHYSICS, APPLIED Pub Date : 2024-09-11 DOI: 10.1063/5.0206224
Amey Khanolkar, Amit Datye, Yan Zhang, Cody A. Dennett, Weiming Guo, Yang Liu, William J. Weber, Hua-Tay Lin, Yanwen Zhang
Multi-principal component transition metal (TM) diborides represent a class of high-entropy ceramics (HECs) that have received considerable interest in recent years owing to their promising properties for extreme environment applications that include thermal/ environmental barriers, hypersonic vehicles, turbine engines, and next-generation nuclear reactors. While the addition of chemical disorder through the random distribution of TM elements on the cation sublattice has offered opportunities to tailor elastic stiffness and hardness, the effects of irradiation-induced structural damage on the physical properties of these complex materials have remained largely unexplored. To this end, changes in the hardness and elastic moduli of a high-entropy TM diboride (Hf0.2Nb0.2Ta0.2Ti0.2Zr0.2)B2 and three of its quaternary subsets following irradiation with 10 MeV gold (Au) ions to fluences of up to 6 × 1015 Au cm−2 are investigated at the micrometer and sub-micrometer length-scales via the dispersion of laser-generated surface acoustic waves (SAW) and nanoindentation, respectively. The nanoindentation measurements show that the TM diborides exhibit an initial increase in hardness following irradiation with energetic Au ions, with a subsequent decrease in hardness following further irradiation. One quaternary composition, (Hf1/3Ta1/3Ti1/3)B2, exhibits a notable exception to the trend and continues to exhibit an increase in hardness with ion irradiation fluence. Although differences in the absolute values of the effective elastic moduli obtained from the measured SAW dispersion and nanoindentation are observed (and attributed to microstructural variations at the measurement length-scale), both techniques yield similar trends in the form of an initial reduction and subsequent saturation in the elastic modulus with increasing ion irradiation fluence. The quaternary TM diboride (Hf1/3Ta1/3Ti1/3)B2 again exhibits a departure from this trend. The high-entropy TM diboride (Hf0.2Nb0.2Ta0.2Ti0.2Zr0.2)B2 exhibits the greatest recovery in hardness and modulus when irradiated to high ion fluences following initial changes at low fluence, indicating superior resistance to radiation-induced damage over its quaternary counterparts. Opportunities for designing HECs with superior hardness and modulus for enhanced radiation resistance (compared to their single constituent counterparts) by tailoring chemical disorder and bond character in the lattice are discussed.
多主成分过渡金属(TM)二硼化物是一类高熵陶瓷(HECs),由于其在极端环境应用(包括热/环境屏障、高超音速飞行器、涡轮发动机和下一代核反应堆)中具有良好的性能,近年来受到了广泛关注。虽然通过阳离子亚晶格上 TM 元素的随机分布增加化学无序性为定制弹性刚度和硬度提供了机会,但辐照引起的结构损伤对这些复杂材料物理性质的影响在很大程度上仍未得到探索。为此,我们通过激光产生的表面声波(SAW)色散和纳米压痕测量,分别研究了高熵 TM 二硼化物(Hf0.2Nb0.2Ta0.2Ti0.2Zr0.2)B2 及其三个四元子集在 10 MeV 金(Au)离子以高达 6 × 1015 Au cm-2 的通量辐照后在微米和亚微米长度尺度上的硬度和弹性模量变化。纳米压痕测量结果表明,TM 二硼化物在受到高能金离子辐照后,最初的硬度会有所提高,而在进一步辐照后,硬度会随之降低。其中一种四元成分 (Hf1/3Ta1/3Ti1/3)B2 的趋势明显例外,其硬度继续随着离子辐照通量的增加而增加。虽然通过测量声表面波色散和纳米压痕获得的有效弹性模量的绝对值存在差异(并归因于测量长度尺度上的微观结构变化),但这两种技术都得出了类似的趋势,即随着离子辐照通量的增加,弹性模量最初降低,随后达到饱和。四元 TM 二硼化物(Hf1/3Ta1/3Ti1/3)B2 再次偏离了这一趋势。高熵 TM 二硼化物(Hf0.2Nb0.2Ta0.2Ti0.2Zr0.2)B2 在低辐照度下发生初始变化后,辐照到高离子辐照度时硬度和模量的恢复程度最大,这表明它比四元TM 二硼化物具有更强的抗辐射损伤能力。本文讨论了通过调整晶格中的化学无序性和键特性,设计出具有更高硬度和模量以增强抗辐射能力(与单一成分的同类产品相比)的 HECs 的可能性。
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引用次数: 0
Permittivity enhancement of Al2O3/ZrO2 dielectrics with the incorporation of Pt nanoparticles 掺入铂纳米粒子后 Al2O3/ZrO2 介电材料的脆度增强
IF 3.2 3区 物理与天体物理 Q2 PHYSICS, APPLIED Pub Date : 2024-09-10 DOI: 10.1063/5.0218456
Bao Zhu, Ze Shang, Chenyan Wang, Xiaohan Wu, David Wei Zhang
Al2O3/ZrO2 (A/Z) layers with embedded Pt nanoparticles (Pt-nps) at the interface of A/Z have been used to create a dielectric film with an enhanced permittivity. The Pt-nps and dielectrics are both grown by the atomic layer deposition process, which is complementary metal–oxide–semiconductor compatible. In order to control the thickness ratio of Pt-nps in the overall dielectrics more easily, the thickness of the ZrO2 layer is changed from 12 to 30 nm with a fixed thickness of 12 nm for Al2O3 and constant growth cycles of 70 for Pt-nps. The results show that the introduction of Pt-nps is beneficial to the enhancement of the dielectric permittivity. As the thickness of ZrO2 is 30 nm, the capacitance density increases from 2.5 to 5.1 fF/μm2 with the addition of Pt-nps, i.e., a doubling of the capacitance density achieved. Additionally, the leakage current at 2 V increases from 1.1 × 10−8 to 1.5 × 10−7 A/cm2. Furthermore, the dielectric breakdown field decreases from 5.4 to 2.7 MV/cm. The electric field distribution simulation and charging–discharging test imply that interfacial polarization is built at the interface of Pt-nps and the dielectric films, which contributes to the dielectric permittivity enhancement, and local electric field increasing in the affinity of Pt-nps gives rise to the deterioration of the leakage current and breakdown electric field.
在 Al2O3/ZrO2(A/Z)层的界面上嵌入铂纳米粒子(Pt-nps),用于制造具有增强介电常数的介电薄膜。Pt-nps 和介质都是通过原子层沉积工艺生长的,这种工艺与互补金属氧化物半导体兼容。为了更容易地控制 Pt-nps 在整个电介质中的厚度比,ZrO2 层的厚度从 12 纳米变为 30 纳米,而 Al2O3 的厚度固定为 12 纳米,Pt-nps 的生长周期则恒定为 70 个周期。结果表明,引入 Pt-nps 有利于提高介电常数。当 ZrO2 的厚度为 30 nm 时,加入 Pt-nps 后,电容密度从 2.5 fF/μm2 增加到 5.1 fF/μm2,即电容密度增加了一倍。此外,2 V 时的漏电流从 1.1 × 10-8 增至 1.5 × 10-7 A/cm2。此外,介电击穿场从 5.4 MV/cm 减小到 2.7 MV/cm。电场分布模拟和充放电测试表明,Pt-nps 与介质薄膜的界面上形成了界面极化,这有助于介电常数的提高,而 Pt-nps 亲和的局部电场的增加导致了漏电流和击穿电场的恶化。
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引用次数: 0
Minimization of detent force in PMLSM by end magnetic regulating module with free topologies 通过自由拓扑结构的端磁调节模块最大限度降低 PMLSM 中的棘爪力
IF 3.2 3区 物理与天体物理 Q2 PHYSICS, APPLIED Pub Date : 2024-09-10 DOI: 10.1063/5.0232229
Xiaozhuo Xu, Kai Hua, Haichao Feng, Siyuan Jiang, Yunji Zhao
In this paper, a novel method for suppressing the detent force of permanent magnet linear synchronous motors is proposed. First, the end force is adjusted to offset the cogging force while the cogging force remains unchanged. On the other hand, the proposed method can arbitrarily change the shape of the end magnetic regulating module (EMRM), thus allowing the end force to obtain a wider adjustment range, which is different from the conventional limited shape optimization. More interestingly, compared to the traditional approach for suppressing the end force, which is to suppress the end force to the lowest level, the proposed method does not necessarily suppress the end force to the lowest level, but rather adjusts it to a reasonable level, so that it can offset the cogging force. This leads to the fact that the optimized end magnetic regulating module is effective in adjusting the end force and may even increase the end force, which is different from the conventional idea of suppressing the detent force. Next, the optimal EMRM's topologies are solved using the optimization algorithm, which replaces the traditional low-dimensional single-direction optimization and performs multi-direction global search. Finally, the prototype with optimal EMRM's topology and the testing platform are established and the experimental results validate the effectiveness of the proposed method.
本文提出了一种抑制永磁直线同步电机棘爪力的新方法。首先,在齿槽力保持不变的情况下,调整端面力以抵消齿槽力。另一方面,所提出的方法可以任意改变端磁调节模块(EMRM)的形状,从而使端力获得更宽的调节范围,这与传统的有限形状优化不同。更有趣的是,与传统的抑制末端力的方法--将末端力抑制到最低水平--相比,所提出的方法并不一定将末端力抑制到最低水平,而是将其调整到一个合理的水平,使其能够抵消齿槽力。这就导致优化后的端面磁调节模块能有效调节端面力,甚至可能增加端面力,这与传统的抑制棘爪力的思路不同。接下来,使用优化算法求解最佳电磁调节器拓扑结构,该算法取代了传统的低维单方向优化,而是执行多方向全局搜索。最后,建立了具有最优 EMRM 拓扑结构的原型和测试平台,实验结果验证了所提方法的有效性。
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引用次数: 0
Magnetic tunnel junctions with superlattice barriers 具有超晶格势垒的磁隧道结
IF 3.2 3区 物理与天体物理 Q2 PHYSICS, APPLIED Pub Date : 2024-09-10 DOI: 10.1063/5.0228748
Jing-Ci Su, Shih-Hung Cheng, Sin-You Huang, Wen-Jeng Hsueh
The urgent demand for high-performance emerging memory, propelled by artificial intelligence in internet of things (AIoT) and machine learning advancements, spotlights spin-transfer torque magnetic random-access memory as a prime candidate for practical application. However, magnetic tunnel junctions (MTJs) with a single-crystalline MgO barrier, which are central to magnetic random-access memory (MRAM), suffer from significant drawbacks: insufficient endurance due to breakdown and high writing power requirements. A superlattice barrier-based MTJ (SL-MTJ) is proposed to overcome the limitation. We first fabricated the MTJ using an SL barrier while examining the magnetoresistance and resistance-area product. Lower writing power can be achieved in SL-MTJs compared to MgO-MTJs. Our study may provide a new route to the development of MRAM technologies.
在人工智能物联网(AIoT)和机器学习进步的推动下,对高性能新兴存储器的迫切需求凸显了自旋转移力矩磁随机存取存储器在实际应用中的首要候选。然而,作为磁性随机存取存储器(MRAM)核心的单晶氧化镁势垒磁隧道结(MTJ)存在明显缺陷:因击穿而导致的耐久性不足以及高写入功率要求。我们提出了一种基于超晶格势垒的 MTJ(SL-MTJ)来克服这一限制。我们首先使用超晶格势垒制造了 MTJ,同时研究了磁阻和电阻-面积乘积。与氧化镁 MTJ 相比,SL-MTJ 的写入功率更低。我们的研究可能会为 MRAM 技术的发展提供一条新的途径。
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引用次数: 0
Theoretical prediction of chalcogen-based Janus monolayers for self-powered optoelectronic devices 用于自供电光电设备的基于铬化砷的 Janus 单层膜的理论预测
IF 3.2 3区 物理与天体物理 Q2 PHYSICS, APPLIED Pub Date : 2024-09-09 DOI: 10.1063/5.0223915
Yuxuan Sun, Naizhang Sun, Wenlin Zhou, Han Ye
Exploring potential two-dimensional monolayers with large photogalvanic effect (PGE) has been of great importance for developing self-powered optoelectronic devices. In this paper, we systematically investigate the generation of PGE photocurrent in chalcogen-based Janus XYZ monolayers (X/Y/Z = S, Se, Te; X ≠ Y ≠ Z) based on non-equilibrium Green's function formalism with density functional theory. The optimized Janus SSeTe, SeSTe, and TeSeS monolayers in the rectangular phase are shown stable and, respectively, possess 1.54, 1.49, and 1.74 eV indirect bandgaps. Illuminated by linearly polarized light, the PGE photocurrent without bias voltage can be collected in both armchair and zigzag directions. Unlike common Janus 2D materials with C3v symmetry, the photocurrent peak values of Janus XYZ monolayers do not come up with certain polarization angles, while the relations can be fitted by Iph = α sin(2θ) + β cos(2θ) + γ at each photon energy. Meanwhile, the maximum photoresponses of Janus SSeTe, SeSTe, and TeSeS monolayers are 2.02, 3.33, and 4.42 a20/photon, respectively. The relatively large PGE photocurrents and complicated polarization relations result from the lower symmetry of Janus XYZ monolayers. Moreover, the specific polarization angles for maximum photoresponses at each photon energy and the ratio between two transport directions are demonstrated, reflecting the anisotropy. Our results theoretically predict a potential Janus monolayer family for self-powered optoelectronic applications.
探索具有大光电效应(PGE)的潜在二维单层对于开发自供电光电器件具有重要意义。在本文中,我们基于密度泛函理论的非平衡格林函数形式主义,系统地研究了基于砷化镓的 Janus XYZ 单层(X/Y/Z = S、Se、Te;X≠Y≠Z)中 PGE 光电流的产生。优化后的矩形相 Janus SSeTe、SeSTe 和 TeSeS 单层显示稳定,分别具有 1.54、1.49 和 1.74 eV 的间接带隙。在线性偏振光的照射下,PGE 光电流无需偏置电压即可在扶手和之字形方向上收集。与具有 C3v 对称性的普通 Janus 2D 材料不同,Janus XYZ 单层材料的光电流峰值并不随特定偏振角的变化而变化,在每种光子能量下,其关系可以用 Iph = α sin(2θ) + β cos(2θ) + γ 来拟合。同时,Janus SSeTe、SeSTe 和 TeSeS 单层的最大光响应分别为 2.02、3.33 和 4.42 a20/光子。相对较大的 PGE 光电流和复杂的偏振关系是由 Janus XYZ 单层的较低对称性造成的。此外,我们还证明了每个光子能量下最大光响应的特定偏振角以及两个传输方向之间的比率,这反映了各向异性。我们的研究结果从理论上预测了自供电光电应用的潜在 Janus 单层系列。
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引用次数: 0
期刊
Journal of Applied Physics
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