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Effect of Applying Organic Fertilizer to Tobacco Leaves on the Quality and Taste of Cigarettes 烟叶施用有机肥对卷烟品质和口感的影响
IF 0.5 4区 医学 Pub Date : 2023-06-01 DOI: 10.1166/jbmb.2023.2278
Wei Wang, Wen-guang Ma, Wenshan Zhao, Tianhua Han, Xianchang Tai, Dezhi Liao
Tobacco production is a significant industry worldwide, and the quality of tobacco leaves is a crucial factor in determining the taste and quality of cigarettes. The use of synthetic fertilizers in tobacco production has been the traditional method for providing nutrients to tobacco plants. However, the use of synthetic fertilizers can have harmful effects on human health and the environment. In recent years, organic fertilizers have emerged as an alternative method that offers numerous benefits, including improved soil quality, enhanced nutrient content in tobacco leaves and reduced harmful chemicals. This paper aims to explore the impact of applying organic fertilizers to tobacco leaves on the quality and taste of cigarettes and to compare the benefits of organic fertilizers with those of synthetic fertilizers. The impact is analyzed by applying organic fertilizers to tobacco leaves on the taste and quality of cigarettes, sensory evaluation tests, and chemical analysis. These sensory evaluation test can provide data on the flavor, aroma, and chemical composition of cigarettes produced with organic and synthetic fertilizers. Then hypothesis testing is conducted to identify the significance of the organic fertilizers in improving the quality and taste of cigarettes produced from tobacco leaves grown with organic fertilizers versus synthetic fertilizers.
烟草生产是世界范围内一个重要的行业,烟叶的质量是决定香烟味道和质量的关键因素。在烟草生产中使用合成肥料一直是为烟草植物提供营养的传统方法。然而,使用合成肥料会对人类健康和环境产生有害影响。近年来,有机肥料已成为一种替代方法,提供了许多好处,包括改善土壤质量、提高烟叶中的营养成分和减少有害化学物质。本文旨在探讨在烟叶上施用有机肥料对卷烟质量和口感的影响,并比较有机肥料和合成肥料的效益。通过对烟叶施用有机肥料、感官评价试验和化学分析,分析了有机肥料对卷烟口感和质量的影响。这些感官评估测试可以提供用有机肥料和合成肥料生产的香烟的风味、香气和化学成分的数据。然后进行假设检验,以确定有机肥料与合成肥料相比在提高用有机肥料种植的烟叶生产的香烟的质量和味道方面的意义。
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引用次数: 0
Robust Wood Sawdust/Microfibrous Cellulose Composite Board Cross-Linked by Phosphoric Acid-Activated Glutaraldehyde 磷酸活化戊二醛交联坚固木屑/微纤维纤维素复合板
IF 0.5 4区 医学 Pub Date : 2023-04-01 DOI: 10.1166/jbmb.2023.2261
Wen Wang, Lei Miao, Dong-chu Chen, M. Zhang
The recycling use of wood sawdust to process composite boards has received much attention in recent years. To avoid the use of chemical adhesives, natural cellulose-based materials were often used as adhesives to combine wood sawdust. Rather than utilizing nanocellulose, the report herein describes a method to prepare a robust composite board that is based on microfibrous cellulose, which is a low-cost commercial product. To effectively cross-link wood sawdust and microfibrous cellulose, phosphoric acid-activated glutaraldehyde was used as catalyst. Compared to its uncross-linked counterpart, the modulus of elasticity and modulus of rupture of the composite board that had been cross-linked by glutaraldehyde and phosphoric acid were significantly strengthened to 3.45±0.06 GPa and 36.5±3.5 MPa, respectively. Moreover, the moisture resistance of the cross-linked composite board was also enhanced. After soaking in water for 24 h, the mass swelling ratio and thickness swelling ratio of cross-linked composite board had only changed 49% and 21%, respectively. These performances even exceeded that of composite board prepared from nanocellulose. The method described in this work may have applications in commercial processing and the recycling of wood sawdust.
近年来,利用木屑加工复合板受到了广泛关注。为了避免使用化学粘合剂,通常使用天然纤维素基材料作为粘合剂来结合木屑。本文的报告不是利用纳米纤维素,而是描述了一种制备基于微纤维纤维素的坚固复合板的方法,微纤维纤维素是一种低成本的商业产品。为了有效地将木屑和微纤维纤维素交联,采用磷酸活化戊二醛作为催化剂。与未交联的复合板相比,戊二醛和磷酸交联后的复合板的弹性模量和断裂模量分别显著提高到3.45±0.06GPa和36.5±3.5MPa。此外,交联复合板的防潮性也得到了提高。在水中浸泡24小时后,交联复合板的质量膨胀率和厚度膨胀率分别仅变化49%和21%。这些性能甚至超过了由纳米纤维素制备的复合板。本工作中描述的方法可能在商业加工和木屑回收中有应用。
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引用次数: 0
Matrix Solid-Phase Extraction of Nine Pesticide Residues from Vegetables Based on Mesoporous Carbon via an Alternative Sample Preparation Approach 基于介孔碳的基质固相萃取蔬菜中9种农药残留
IF 0.5 4区 医学 Pub Date : 2023-04-01 DOI: 10.1166/jbmb.2023.2263
C. Yuan, Yina You, Yu Wang, Xia Hong, Haining He, X. Lin, Z. Chen
In this work, an n-octadecylamine functionalized mesoporous carbon nanocomposite (ODA-MPC) was synthesized, and its novel application was demonstrated by utilizing it as a sorbent in matrix solid-phase dispersion (MSPD) of nine pesticide residues identified by gas chromatography-mass spectrometer. Here, the protection of the sorbent by the mesoporous fiber membrane enabled it to process complex aqueous matrices and made it advantageous to be used in MSPD. The results confirmed the excellent ability of ODA-MPC to remove matrix interferences and reduce matrix effects compared to the traditional solid phase extraction. In particular, the recoveries were 85.0–95.8% (n = 3) with relative standard deviations less than 5%. Additionally, nine pesticide residues in vegetables and fruit were satisfactorily extracted and detected.
本工作合成了一种正十八胺功能化介孔碳纳米复合材料(ODA-MPC),并将其作为吸附剂在气相色谱-质谱仪鉴定的9种农药残留的基质固相分散体(MSPD)中进行了新的应用。在这里,介孔纤维膜对吸附剂的保护使其能够处理复杂的水性基质,并使其有利于用于MSPD。结果证实,与传统固相萃取相比,ODA-MPC具有良好的去除基质干扰和降低基质效应的能力。特别是,回收率为85.0-95.8%(n=3),相对标准偏差小于5%。此外,对蔬菜和水果中的9种农药残留进行了令人满意的提取和检测。
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引用次数: 0
Structural Characterization of Activated Carbon Prepared from Passion Fruit By-Product for Removal of Cholesterol and Toxic Compound in Liquid Food 百香果副产物活性炭去除液态食品中胆固醇和有毒化合物的结构表征
4区 医学 Pub Date : 2023-04-01 DOI: 10.1166/jbmb.2023.2265
Bo Jie Chen, Liping Yang, Yeying Sun, Shiqian Zhong, Guohuan Liang, Yongjin Sun, Tiemin Jiang, Xia Li, Li Zhou, Hock Eng Khoo
This study aimed to determine the structural characteristics and adsorption capacities of a novel activated carbon prepared from passion fruit by-product. Passion fruit peel was carbonized and structurally modified using phosphoric acid-potassium hydroxide reagent before carbon activation. Industrial-activated carbon was used as a control sample. The surface functional groups and adsorption capacities of the activated carbon samples were determined. The results showed that the chemical-modified activated carbon had anhydride and carboxylic acid as the main functional groups on the carbon surface, together with several conformations of the hydroxyl group. These hydroxyl confirmations were in alkoxy and carboxylate forms but not phenoxy. The peel-based activated carbon had a smoother carbon surface with multiple micropores, whereas the carbon surface of industrial activated carbon was rough with multiple meso- and macropores. The methylene blue adsorption capacity (0.1 mg/mL methylene blue) of the peel-based activated carbon (99.97±0.01%) was comparable to the industrial activated carbon (100.00±0.01%). But the peel-based activated carbon had better cholesterol and albumin adsorption capacities than the industrial activated carbon. Since activated carbon prepared from the fruit peel has better adsorption capacities of cholesterol and other chemicals in liquid foods, it can replace the wood-based activated carbon in food and pharmaceutical applications.
研究了以百香果副产物为原料制备的新型活性炭的结构特性和吸附性能。在碳活化前,用磷酸-氢氧化钾试剂对百香果皮进行炭化和结构改性。以工业活性炭为对照样品。测定了活性炭样品的表面官能团和吸附能力。结果表明,化学改性活性炭表面以酸酐和羧酸为主要官能团,并伴有羟基的几种构象。这些羟基确认为烷氧基和羧酸盐形式,但不是苯氧基。果皮活性炭表面光滑,有多个微孔,而工业活性炭表面粗糙,有多个中孔和大孔。皮基活性炭对亚甲基蓝的吸附量(0.1 mg/mL)为99.97±0.01%,与工业活性炭的吸附量(100.00±0.01%)相当。但皮基活性炭对胆固醇和白蛋白的吸附能力优于工业活性炭。由于果皮制备的活性炭对液态食品中的胆固醇等化学物质有较好的吸附能力,在食品和医药领域可以取代木质活性炭。
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引用次数: 1
Anticancer Effects of Honey Varieties on Human Cells by Studying Some Physical Parameters, Hydrogen Peroxide Content, Catalase, Glucose Oxidase, and Microbial Activities 通过研究蜂蜜的物理参数、过氧化氢含量、过氧化氢酶、葡萄糖氧化酶和微生物活性对人体细胞的抗癌作用
IF 0.5 4区 医学 Pub Date : 2023-04-01 DOI: 10.1166/jbmb.2023.2272
Rasha A. Al-Eisa, A. Ashour, M. Helal, Amani H. Aljahani, Roqayah H. Kadi, Mohannad S Hazzazi, R. Sami
The present work studied the anticancer effects of four honey varieties on human cells by studying some physical parameters, hydrogen peroxide content, catalase, glucose oxidase, and microbial activities. Honey samples were (nigella sativa, moringa, sidr, pumpkin), which were coded as NS, MO, SI, and PU honey, respectively. The tested bacterial isolates Staphylococcus aureus, and Enterococcus faecalis were used for microbial activities. Two types of human cells, breast, and colon adenocarcinoma cell lines were used for anticancer properties. SI Honey samples showed the lowest value for electrical conductivity 3.19 μS cm−1. PU Honey samples recorded the highest value for hydrogen peroxide contents 1582.05 μM, while SI Honey reported a similar trend of 1501.51 μM. The values of catalase enzyme activity ranged from 2.78 U/g in SI Honey to 3.91 U/g in MO Honey. Glucose oxidase activity ranged from 4.12 U/g in NS Honey samples to 10.55 U/g in MO Honey. The highest antibacterial activity was detected by SI Honey with a zone of inhibition value of 14.99 mm against Staphylococcus aureus. PU Honey was the best to inhibit the microbial loud of Enterococcus faecalis 7.93 mm. SI Honey was the most effective against breast adenocarcinoma cells (IC50 66.15 μg/mL), on the same trend MO Honey was the most effective against colon adenocarcinoma cells (IC50 45.13 μg/mL). While NS Honey recorded lower efficiency against both breast and colon adenocarcinoma cancer cells IC50 95.13 μg/mL and IC50 87.66 μg/mL, respectively. The control detected the lowest cytotoxic effects on both breast and colon adenocarcinoma cancer cells IC50 112.33 μg/mL and IC50 203.97 μg/mL, respectively.
本工作通过研究一些物理参数、过氧化氢含量、过氧化氢酶、葡萄糖氧化酶和微生物活性,研究了四个蜂蜜品种对人体细胞的抗癌作用。蜂蜜样品为(nigella sativa、moringa、sidr、南瓜),分别编码为NS、MO、SI和PU蜂蜜。测试的细菌分离株金黄色葡萄球菌和粪肠球菌用于微生物活性。两种类型的人类细胞,乳腺癌和结肠癌细胞系用于抗癌特性。SI蜂蜜样品的电导率最低,为3.19μS cm−1。PU蜂蜜样品的过氧化氢含量最高,为1582.05μM,而SI蜂蜜的过氧化氢含量也有类似的趋势,为1501.51μM。过氧化氢酶活性在SI蜂蜜中为2.78U/g,在MO蜂蜜中为3.91U/g。葡萄糖氧化酶活性在NS蜂蜜样品中为4.12 U/g,在MO蜂蜜中为10.55 U/g。SI Honey检测到最高的抗菌活性,对金黄色葡萄球菌的抑制区为14.99mm。PU蜜糖对粪肠球菌的抑菌效果最好,为7.93mm。SI蜜糖对乳腺腺癌细胞的抑制效果最好(IC50为66.15μg/mL),MO蜜糖对结肠癌细胞的抑制作用最强(IC50 45.13μg/mL。而NS Honey对乳腺癌和结肠癌癌症细胞的有效性较低,IC50分别为95.13μg/mL和87.66μg/mL。对照组对乳腺癌和结肠癌癌症细胞的细胞毒性作用最低,分别为IC50 112.33μg/mL和IC50 203.97μg/mL。
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引用次数: 3
Analysis of Fungal Diversity of Three Samples (dqjq_ck, dqjqcp and dqjp3) from Danquan Distillery 丹泉酒厂3个样品dqjq_ck、dqjqcp和dqjp3真菌多样性分析
IF 0.5 4区 医学 Pub Date : 2023-04-01 DOI: 10.1166/jbmb.2023.2267
Haifeng Wu, Jieli Li, Juntong Zhang, Shiya Wu, Xiaohao Xiang, Zujun Lu, C. Shang
There are fungal communities in fermented grains and high-temperature Daqu of Danquan Baijiu, which had an important effect on Baijiu production. As a saccharifying and fermenting material, to a great extent, Daqu determines Baijiu flavour. However, in high-temperature Daqu “dqjq_ck” and “dqjqcp” (after fermentation for 45 d, 135 d) and fermented grains dqjp3 originated from Danquan distillery, fungal communities remain unclear. Therefore, this study analyzed fungal communities by high-throughput sequencing. Their fungal communities mainly included Ascomycota at phylum level. The most abundant fungal genera were Aspergillus, Issatchenkia and Zygosaccharomyces in dqjq_ck, dqjqcp, dqjp3, respectively. The dominant genera included Aspergillus (96.21%), Thermomyces (2.13%) in dqjq_ck. The dominant genera contained Issatchenkia (48.29%), Millerozyma (14.53%), Thermoascus (12.17%), Aspergillus (8.80%), Hyphopichia (3.28%), Rhizomucor (3.17%), Lichtheimia (2.62%), Thermomyces (2.27%), Monascus (1.37%) in dqjqcp. The dominant genera had Zygosaccharomyces (68.48%), Monascus (15.18%), Aspergillus (6.97%), Cladosporium (1.12%) in dqjp3. The main fungi included Aspergillus, Zygosaccharomyces, Issatchenkia, Monascus, Millerozyma, Thermoascus, Thermomyces, Hyphopichia, Rhizomucor, Lichtheimia and Cladosporium in three samples. The fungal succession of three samples were revealed in three key stages of Danquan Baijiu production. This paper will lay the basis for screening outstanding fungi to enhance Danquan Baijiu quality in near future.
丹泉白酒的发酵谷物和高温大曲中存在真菌群落,对白酒的生产有重要影响。大曲作为一种糖化和发酵原料,在很大程度上决定了白酒的风味。然而,在高温大曲“dqjq_ck”和“dqjqcp”(发酵45 d、135 d)和丹泉酒厂的发酵粮dqjp3中,真菌群落尚不清楚。因此,本研究通过高通量测序对真菌群落进行分析。在门水平上真菌群落主要包括子囊菌门。dqjq_ck、dqjqcp、dqjp3中真菌属最多的分别是Aspergillus、Issatchenkia和Zygosaccharomyces。dqjq_ck的优势属为曲霉属(96.21%)、温霉菌属(2.13%)。dqjqcp的优势属依次为Issatchenkia(48.29%)、Millerozyma(14.53%)、Thermoascus(12.17%)、Aspergillus(8.80%)、Hyphopichia(3.28%)、rhizzomucor(3.17%)、Lichtheimia(2.62%)、thermoyces(2.27%)、Monascus(1.37%)。dqjp3的优势属依次为Zygosaccharomyces(68.48%)、Monascus(15.18%)、Aspergillus(6.97%)、Cladosporium(1.12%)。3个样品的主要真菌有曲霉、Zygosaccharomyces、Issatchenkia、红曲霉、千霉、热曲霉、热曲霉、菌丝霉、根霉霉、Lichtheimia和枝孢霉。揭示了三个样品在丹泉白酒生产的三个关键阶段的真菌演替。为今后筛选优良菌种,提高丹泉白酒品质奠定基础。
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引用次数: 0
Remote Sensing Monitoring Model of Tobacco Growth and Yield Based on Ecological Process and Carbon Cycle 基于生态过程和碳循环的烟草生长和产量遥感监测模型
IF 0.5 4区 医学 Pub Date : 2023-04-01 DOI: 10.1166/jbmb.2023.2257
Yangming Jiang, Xiaodong Shao, Liping Li, Tuo Wang, Huihui Zhao, Qiuqiang Hou, Xin Du, Fulati Gulimire
Tobacco growth monitoring and yield estimation are very important for tobacco planting control and allocation. However, traditional tobacco yield estimation models have not considered the light energy utilization, carbon cycle, and ecological processes, resulting in the mechanisms poorly explained and the reduced monitoring accuracy. To address these limitations, a tobacco yield remote sensing monitoring model based on ecological process and carbon cycle was proposed. The model couples the Carbon Exchange between Vegetation, Soil, and Atmosphere (CEVSA) ecosystem process model and the global production efficiency model (GLO-PEM), to simulate effective solar radiation and tobacco light energy utilization, stress effects of surface air temperature, water vapour pressure deficit and photosynthetic effective radiation. Then the tobacco gross primary production (GPP), net primary productivity (NPP), tobacco biomass were estimated. Finally, the tobacco yield estimation model based on the correlation between tobacco yield and NPP was proposed. The results showed that there was a significant correlation (correlation= 0.94) between NPP and tobacco leaves weight at 99% confidence level, and the yield estimated by the remote sensing monitoring model was in good agreement with the measured results, with errors of Class I, II, III were 9.644%, 4.316%, and 8.495% respectively. In conclusion, the proposed model can be used to estimate tobacco yield, support decision-making of tobacco planting plan, and strengthen purchasing management.
烟草生长监测和产量估算对烟草种植控制和分配具有重要意义。然而,传统的烟草产量估算模型没有考虑光能利用、碳循环和生态过程,导致其机制解释不足,监测精度降低。针对这些局限性,提出了一种基于生态过程和碳循环的烟草产量遥感监测模型。该模型将植被、土壤和大气之间的碳交换(CEVSA)生态系统过程模型和全球生产效率模型(GLO-PEM)相结合,以模拟有效的太阳辐射和烟草光能利用、地表气温的胁迫效应、水蒸气压力不足和光合有效辐射。然后估算了烟草初级生产总值(GPP)、净初级生产力(NPP)和烟草生物量。最后,提出了基于烟草产量与NPP相关性的烟草产量估算模型。结果表明,在99%置信水平下,NPP与烟叶重量之间存在显著相关性(相关系数=0.94),遥感监测模型估算的产量与实测结果吻合较好,Ⅰ、Ⅱ、Ⅲ类误差分别为9.644%、4.316%和8.495%。总之,该模型可用于估算烟草产量,支持烟草种植计划的决策,加强采购管理。
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引用次数: 0
Study on Distribution Characteristics of Mineral Nutrients in Fritillaria hubeiensis 湖北贝母矿质养分分布特征的研究
IF 0.5 4区 医学 Pub Date : 2023-04-01 DOI: 10.1166/jbmb.2023.2266
W. Cheng, Xingyuan Luo, Li Jiang, Jie Guo, Lihong Zhang, Kangfei Xiao, Juan Hong
The contents and correlation of various mineral elements in soil and roots, stems and leaves of Fritillaria hubeiensis were analyzed and evaluated to supply basis for diagnosis of soil mineral nutrition and rational fertilization of Fritillaria hubeiensis. The contents of Phosphorus, potassium, calcium, magnesium, iron, zinc, manganese and copper were tested by the inductively coupled plasma, and the results were analyzed by SPSS11.5 software. The total contents of manganese, phosphorus, potassium, calcium and magnesium in soil and roots, leaves and stems of Fritillaria hubeiensis were different with different cultivation bases. The order of Fe and Cu contents was root > leaf > stem. The distribution of Zn showed a trend of “root > stem > leaf.” Between potassium content of soil and root, it was a significant positive correlation. But there was a significant negative correlation between Zinc content of soil and root. The total contents of calcium and iron were positively correlated between roots and stems. The total contents of Phosphorus, potassium, magnesium and copper were positively correlated among stems and leaves, while the contents of Mn were positively correlated. Therefore, Fritillaria hubeiensis mainly regulates the amount of mineral nutrients through selective absorption.
分析评价了湖北贝母土壤和根、茎、叶中各种矿质元素的含量及其相关性,为贝母土壤矿质营养诊断和合理施肥提供依据。采用电感耦合等离子体测定磷、钾、钙、镁、铁、锌、锰、铜的含量,并采用SPSS11.5软件对结果进行分析。湖北贝母土壤及根、叶、茎中锰、磷、钾、钙、镁的总含量随栽培基地的不同而不同。铁和铜的含量顺序为根>叶>茎。锌的分布呈“根>茎>叶”的趋势。土壤钾含量与根系钾含量呈极显著正相关。土壤锌含量与根系锌含量呈显著负相关。根和茎的总钙和总铁含量呈显著正相关。茎叶间磷、钾、镁、铜总含量呈显著正相关,锰含量呈显著正相关。因此,湖北贝母主要通过选择性吸收来调节矿质营养素的量。
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引用次数: 0
Quantitative Trait Loci Mapping of Grain Lipid Content in Rice Variety ‘Goudang 3’ Using Genome Re-Sequencing 利用基因组重测序技术对水稻品种狗当3号籽粒脂质含量的定量性状定位
IF 0.5 4区 医学 Pub Date : 2023-04-01 DOI: 10.1166/jbmb.2023.2256
Wuhua Long, Xue Jiang, Chaoxin Wu, Zu-Jun Li, Xian Wu, Zhongni Wang, Qiang Peng, Susong Zhu
Fat is the third largest substance in rice seeds, and its content has a great impact on rice cooking, taste and storage qualities. However, few genes related to seed fat content have been cloned, which seriously restricts the application of fat traits in high-quality rice breeding. ‘Goudang 3’ is a representative aromatic rice landrace of Guizhou He, a characteristic rice species resource in Guizhou Province, China. It has the advantages of high fat content, rich flavor, soft and glutinous taste, etc. In this work, to address this issue, from a high-fat content rice variety, Goudang 3, and a low-fat content rice variety, Huazhan, a 148 recombinant inbred lines (RILs) population were derived. A high-density genetic map with 4063 Bin Markers covering 12 chromosomes were constructed through simplified genotyping-by-sequencing (GBS) technology. In combination with fat content, a brown rice fat content quantitative trait loci (QTL) qCFC3 was mapped within the 492 kb interval on chromosome 3. The qCFC3 was consistent with the previous reporting site, and no cloned fat content-related genes have been reported. LOC_Os03g13630 was identified. In conclusion, these QTL and candidate gene can be used for improving rice quality and can lay a foundation for further cloning and functional analysis.
脂肪是稻米种子中的第三大物质,其含量对稻米的蒸煮、口感和贮藏品质有很大影响。然而,与种子脂肪含量相关的基因很少被克隆,这严重限制了脂肪性状在优质水稻育种中的应用沟当3’是贵州河具有代表性的香米地方品种,是贵州省特有的水稻品种资源。它具有脂肪含量高、风味浓郁、口感软糯等优点。为了解决这一问题,本工作从高脂肪含量的水稻品种狗当3号和低脂肪含量的稻米品种华占中衍生出148个重组自交系群体。采用简化基因分型测序技术(GBS)构建了覆盖12条染色体的4063个Bin标记的高密度遗传图谱。结合脂肪含量,在3号染色体492kb的区间内定位了糙米脂肪含量定量性状基因座(QTL)qCFC3。qCFC3与之前的报道位点一致,并且尚未报道克隆的脂肪含量相关基因。LOC_Os03g13630已识别。总之,这些QTL和候选基因可用于改善稻米品质,为进一步的克隆和功能分析奠定基础。
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引用次数: 0
Deacidification of Acidic Oil Catalyzed by Sulfonated Mesoporous Silica for Biodiesel Production: Optimization, Kinetic, and Enhancement by Using Calcined Kaolin 磺化介孔二氧化硅催化酸性油脱酸制备生物柴油:煅烧高岭土的优化、动力学和强化
IF 0.5 4区 医学 Pub Date : 2023-04-01 DOI: 10.1166/jbmb.2023.2262
Huiqin Chen, Deguang Zhong, Youheng Ma, L. Cui, Zijun Xiao, Wei Lu
Acidified oil is characterized as high acid value. Hence, deacidification is indispensable in biodiesel production from acidic oil. Heterogeneous catalysts have many advantages over homogeneous counterparts in deacidification of acidic oil. Therefore, in the present work, sulfonated mesoporous silica (SMS) was prepared and characterized, followed by the systematical investigation on the effect of reaction variables on the deacidification rate (DR). Furthermore, response surface methodology (RSM) was employed to optimize the reaction parameters. Results showed that the optimal studied reaction variables for the deacidification process were as follows: reaction temperature 65 °C, methanol to oleic acid ratio 35:1, catalyst loading of 2%, in which, deacidification rate of 97.78% could be achieved. DR of 62.52% could still be obtained after catalyst had been used for four consecutive cycles. Finally, significant enhancement of DR could be achieved by using calcined kaolin to assist the deacidification of acidified oil with high water content, indicating that there is great potential in deacidification of acidic oil catalyzed by SMS with the assistance of calcined kaolin for biodiesel production.
酸化油的特点是酸值高。因此,在酸性油生产生物柴油的过程中,脱酸是必不可少的。在酸性油的脱酸过程中,非均相催化剂比均相催化剂具有许多优点。因此,本工作制备并表征了磺化介孔二氧化硅(SMS),然后系统研究了反应变量对脱酸速率(DR)的影响。此外,采用响应面法对反应参数进行了优化。结果表明,脱酸工艺的最佳反应条件为:反应温度65°C,甲醇与油酸的比例35:1,催化剂用量2%,脱酸率可达97.78%。在催化剂已经连续使用四个循环之后,仍然可以获得62.52%的DR。最后,使用煅烧高岭土辅助高含水量酸化油的脱酸可以显著提高DR,表明煅烧高岭土辅助SMS催化酸性油脱酸生产生物柴油具有巨大的潜力。
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引用次数: 0
期刊
Journal of Biobased Materials and Bioenergy
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
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