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Combining in situ elemental and molecular analysis: The Viceroys portraits in Old Goa, India 原位元素分析与分子分析相结合:印度旧果阿的总督画像
IF 3.1 2区 综合性期刊 Q1 Arts and Humanities Pub Date : 2024-06-05 DOI: 10.1016/j.culher.2024.05.012
A.F. Machado , S. Valadas , P. Vandenabeele , A.T. Caldeira , L. Piorro , T. Reis , A. Candeias

The Vice-Roy's Portraits Gallery hosted at the Old Goa Museum of the Archaeological Survey of India in Goa, India, is a unique panel painting collection, spanning from the 16th till the 18th centuries, and representing the Portuguese Viceroys and Governors who administrated the Portuguese provinces in the coastal region of the Indian Ocean. During the Old Goa Revelations project (a collaborative inter-institutional consortium between Evora University HERCULES Lab, Lisbon University Fine Arts Faculty, Archaeological Survey of India and Ghent University), this important collection of panel paintings was examined in-situ using a non-invasive approach with mobile analytical instrumentation. Next to a series of imaging techniques, point analysis has been performed, using both, elemental and molecular spectroscopic methods. On the one hand, handheld X-ray fluorescence analysis and macro X-ray fluorescence imaging was used to obtain the elemental composition and its distribution on pictorial support, while on the other hand mobile Raman spectroscopy was implemented to obtain molecular information. These non-invasive techniques were used to determine the composition of the paint layers and to study the different treatments (e.g. overpainting, changes in compositions, etc.) that the artworks have witnessed since their creation.

位于印度果阿的印度考古调查局旧果阿博物馆(Old Goa Museum of the Archaeological Survey of India)内的副总督肖像画廊(Vice-Roy's Portraits Gallery)是一个独特的板画收藏馆,收藏时间跨度从 16 世纪到 18 世纪,代表了管理印度洋沿岸地区葡萄牙省份的葡萄牙总督和省长。在 "古老果阿的启示 "项目(埃武拉大学 HERCULES 实验室、里斯本大学美术学院、印度考古调查局和根特大学之间的跨机构合作联盟)期间,使用移动分析仪器,以非侵入式方法对这一重要的板画收藏进行了现场研究。除了一系列成像技术外,还使用元素和分子光谱方法进行了点分析。一方面,利用手持式 X 射线荧光分析和宏观 X 射线荧光成像来获取元素组成及其在图像支持物上的分布,另一方面,利用移动拉曼光谱来获取分子信息。这些非侵入性技术用于确定颜料层的成分,并研究艺术品自创作以来所经历的不同处理方式(如覆盖颜料、改变成分等)。
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引用次数: 0
Unraveling the mummy's shroud: A multi-analytical study of a rare painted textile from Roman Egypt 揭开木乃伊裹尸布的神秘面纱:对古埃及罕见彩绘织物的多重分析研究
IF 3.1 2区 综合性期刊 Q1 Arts and Humanities Pub Date : 2024-06-04 DOI: 10.1016/j.culher.2024.05.006
Anna Piccirillo , Paola Buscaglia , Claudia Caliri , Francesco Paolo Romano , Danilo Paolo Pavone , Eva Luna Ravan , Michela Botticelli , Claudia Conti , Maria Catrambone , Costanza Miliani , Ilaria Degano , Alessia Andreotti , Federica Nardella , Marco Samadelli , Alice Paladin , Roberta Genta , Michela Cardinali , Federica Pozzi , Daniela Picchi

This article describes a multi-analytical technical study of a rare painted shroud still wrapped around a female Egyptian mummy (MCABo EG 1974) in the collection of the Museo Civico Archeologico of Bologna, Italy. Long stored in the museum's warehouses, these mummified human remains were recently rediscovered within the Bologna Mummy Project (BOmp), an interdisciplinary endeavor promoted by the Museo Civico Archeologico and the Institute for Mummy Studies of Eurac Research, Bolzano, Italy. Dating to the Roman period (1st-2nd century C.E.), as confirmed by radiocarbon dating, this mummy displays a unique series of technical features, including the exceptional finding of a colorful painted shroud still preserved in its original location around the wrapped body, to which it is secured with textile straps and resin. In this context, scientific analysis aimed to deepen our current knowledge of the artistic practices of Roman Egypt through an in-depth study of the painting technique, context of production, and possible provenance of the mummy, while promoting a science-informed, enhanced approach to the preservation of the mummified human remains. This research relied on an integrated analytical protocol based on the combined use of imaging and mapping techniques, non-invasive point analysis, and micro-invasive investigation of minute samples, each carried out at the different partnering institutions. Computed tomography (CT) highlighted varying radio-densities for some of the flesh tones and red decorations. Visible photography and multiband imaging provided information on the nature and distribution of various materials on the surface. Fiber optics reflectance spectroscopy (FORS), X-ray fluorescence (XRF) spectroscopy, and Raman spectroscopy contributed to the characterization of the shroud's color palette along with optical microscopy (OM), scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM/EDS), as well as high-performance liquid chromatography coupled with diode-array detection and mass spectrometry (HPLC/DAD and HPLC/MS). Materials detected include a limited number of mineral pigments and plant-derived dyes such as red lead, red ocher, madder, an unknown yellow dye, Egyptian blue and green, and a carbon-based black. Through access to MOLAB equipment and expertise, macro-XRF (MA-XRF), as well as combined X-ray diffraction (XRD) spot analysis and mapping, enhanced pigment identification. A combination of transmission Fourier-transform infrared (FTIR) spectroscopy with gas chromatography / mass spectrometry (GC/MS) was used to identify the paint binders and any additional organic substances possibly involved in embalming practices and ritual traditions, including animal fat, plant lipid, Pinaceae resin, gum, and beeswax. Mineralogical data gathered by XRD on surface deposits and soil residues collected from within the shroud's inner folds was crucial to put forward hypotheses, in support of the stylistic study of the

本文介绍了对意大利博洛尼亚市政考古博物馆收藏的一具仍包裹着埃及女性木乃伊(MCABo EG 1974)的罕见彩绘裹尸布进行的多重分析技术研究。这些木乃伊遗骸长期存放在博物馆的仓库中,最近在博洛尼亚木乃伊项目(BOmp)中被重新发现,该项目是由博洛尼亚市政考古博物馆和意大利博尔扎诺的欧拉克研究木乃伊研究所共同推动的一项跨学科工作。经放射性碳测年确认,这具木乃伊的年代为罗马时期(公元前 1-2 世纪),它展示了一系列独特的技术特征,其中包括发现了一块色彩斑斓的彩绘裹尸布,该裹尸布仍保存在包裹尸体的原处,并用纺织带和树脂固定。在这种情况下,科学分析的目的是通过深入研究木乃伊的绘画技术、制作背景和可能的来源,加深我们目前对罗马埃及艺术实践的了解,同时促进以科学为依据的、更好的保存木乃伊遗骸的方法。这项研究依赖于一个综合分析方案,该方案基于成像和绘图技术、非侵入性点分析以及对微小样本的微侵入性调查的结合使用,每项工作都在不同的合作机构进行。计算机断层扫描(CT)突出显示了一些肉色和红色装饰的不同放射性密度。可见光摄影和多波段成像提供了有关表面各种材料的性质和分布的信息。光纤反射光谱法 (FORS)、X 射线荧光光谱法 (XRF) 和拉曼光谱法,以及光学显微镜 (OM)、扫描电子显微镜与能量色散 X 射线光谱法 (SEM/EDS)、高效液相色谱法与二极管阵列检测和质谱法 (HPLC/DAD 和 HPLC/MS),都有助于确定裹尸布的色调特征。检测到的材料包括数量有限的矿物颜料和植物染料,如红铅、红赭石、茜草、一种未知的黄色染料、埃及蓝和埃及绿以及一种碳基黑色。通过使用 MOLAB 的设备和专业知识,宏 XRF(MA-XRF)以及 X 射线衍射(XRD)点分析和制图相结合的方法增强了颜料鉴定能力。透射傅立叶变换红外光谱(FTIR)与气相色谱/质谱联用仪(GC/MS)相结合,用于鉴定颜料粘合剂以及可能与防腐做法和仪式传统有关的其他有机物质,包括动物脂肪、植物脂质、松脂、树胶和蜂蜡。通过 XRD 对表面沉积物和从裹尸布内部褶皱中采集的土壤残留物收集的矿物学数据,对于提出裹尸布可能来自上埃及(很可能是西底比斯)的假设至关重要,以支持对裹尸布的风格研究。研究发现,裹尸布和内绷带都是用 OM 亚麻布制作的。经过科学分析和保护处理后,这具木乃伊在 "木乃伊。揭开过去的面纱 "展览,并在 2022 年秋季在博尔扎诺举行的第十届世界木乃伊研究大会上展出。
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引用次数: 0
Digital methods and techniques for reconstructing and visualizing ancient 3D polychromy – An overview 重建和可视化古代三维多色性的数字方法和技术--概述
IF 3.1 2区 综合性期刊 Q1 Arts and Humanities Pub Date : 2024-06-04 DOI: 10.1016/j.culher.2024.05.002
Eliana Siotto, Paolo Cignoni

The digital technologies employed in archaeology since the 1990s have progressively and experimentally been utilized over the last two decades to document and re-present the ancient polychromy of Greek and Roman marble artworks. Given that this remains a developing field of investigation and application, this study offers, for the first time, a systematic review of the endeavours undertaken thus far in implementing information technology for the documentation, analysis, reconstruction, visualization, and presentation of ancient polychromy. This overview is supported by a literature review and existing implementations, organized into methods and techniques employed for 3D colour preservation, analysis, and reconstruction, as well as those used for the visualization and dissemination of findings. The goal is to identify gaps and provide intriguing insights for future research concerning the use of digital technologies as an essential tool in the stages of documenting and disseminating ancient polychromy in architecture and archaeological artefacts. This, in turn, aims to encourage data sharing, contribute to the dissemination of science-based knowledge and resolve substantial barriers associated with the long-term retention of digital data.

自 20 世纪 90 年代以来,考古学中使用的数字技术在过去二十年中被逐步和试验性地用 于记录和重新展示古代希腊和罗马大理石艺术品的多色性。鉴于这仍然是一个不断发展的调查和应用领域,本研究首次对迄今为止在记录、分析、重建、可视化和展示古代多色性方面采用信息技术所做的努力进行了系统回顾。文献综述和现有实施方案为这一概述提供了支持,分为三维色彩保存、分析和重建所使用的方法和技术,以及可视化和传播研究成果所使用的方法和技术。目的是找出差距,并为今后的研究提供引人入胜的见解,将数字技术作为记录和传播古代建筑和考古文物多色性的重要工具。这反过来又旨在鼓励数据共享,促进科学知识的传播,并解决与长期保存数字数据有关的重大障碍。
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引用次数: 0
Deep learning-based automated tile defect detection system for Portuguese cultural heritage buildings 基于深度学习的葡萄牙文化遗产建筑瓷砖缺陷自动检测系统
IF 3.1 2区 综合性期刊 Q1 Arts and Humanities Pub Date : 2024-05-31 DOI: 10.1016/j.culher.2024.05.009
Narges Karimi, Mayank Mishra, Paulo B. Lourenço

A prominent feature in Portuguese historic architecture is Portugal’s azulejos or tiles that cover cultural heritage buildings with colorful patterns. However, tiles are prone to deterioration due to the quality of masonry materials, exposure over time, and natural and human factors. A careful approach is necessary to detect and assess tile damage in time to conserve cultural heritage. Deep learning (DL) methods are applied to detect deterioration and damage by automating vision-based monitoring. This study uses the You Only Look Once (YOLO), method to detect deterioration in tiles automatically. To obtain the initial dataset, over 5000 images of damage were collected, including cracks, craters, glaze detachment, and tile lacunae, as well as images with no defects. Additionally, a MobileNet model was used for binary classification of damaged and intact tiles to compare classification and detection approaches. Through the fine-tuning of hyperparameters and updating the dataset, an overall accuracy of over 72% for YOLO (multiple classification) and 97% accuracy for binary classification was achieved, demonstrating the adequacy of the tool for real-world applications.

葡萄牙历史建筑的一个显著特点是葡萄牙的天蓝色瓷砖(azulejos),这些瓷砖用五颜六色的图案覆盖着文化遗产建筑。然而,由于砖石材料的质量、长期暴露以及自然和人为因素,瓦片很容易老化。要及时发现和评估瓦片损坏情况,保护文化遗产,就必须采取谨慎的方法。深度学习(DL)方法可通过基于视觉的自动监测来检测老化和损坏情况。本研究使用 "只看一次"(YOLO)方法自动检测瓦片的老化情况。为了获得初始数据集,收集了 5000 多张损坏图像,包括裂缝、凹坑、釉面脱落和瓦片裂缝,以及无缺陷的图像。此外,还使用 MobileNet 模型对受损和完好的瓷砖进行二元分类,以比较分类和检测方法。通过微调超参数和更新数据集,YOLO(多重分类)的总体准确率超过 72%,二元分类的准确率达到 97%,证明了该工具在实际应用中的充分性。
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引用次数: 0
The death and the (digital) re-birth of a god – 3D virtual refitting of the Palaikastro Kouros 神的死亡与(数字)重生--帕拉伊卡斯特罗-库罗斯号的三维虚拟改装
IF 3.1 2区 综合性期刊 Q1 Arts and Humanities Pub Date : 2024-05-31 DOI: 10.1016/j.culher.2024.05.011
Sorin Hermon , Rahaf Orabi , Valentina Vassallo , Martina Polig , Joseph Alexander MacGillivray , Jan Driessen

A unique anthropomorphic statue, representing a young man standing tall ca. 50 cm. and primarily made of ivory and with gold decorative elements, was discovered heavily fragmented and burnt during the extensive excavations at the Bronze Age site of Palaikastro in Crete, Greece in 1987, 1988 and 1990. Through a painstaking restoration process of nearly a decade long, the statue was brought back to its original shape from ca. 200 recovered fragments and it is now exhibited in the Siteia Archaeological Museum in East Crete. The statue and the remaining fragments that the conservators were not able to refit on the statue were recently 3D documented by means of a high-precision optical scanner, resulting in the virtual re-positioning of many remaining fragments, correction of the statue's right foot orientation and its overall posture, and a better understanding of its assembly technique. This article presents these results and the digital processes that lead to them.

1987 年、1988 年和 1990 年,在希腊克里特岛 Palaikastro 青铜时代遗址进行大规模发掘时,发现了一尊独特的拟人雕像,雕像表现的是一个身高约 50 厘米的年轻人,主要由象牙制成,并带有金色装饰元素。经过近十年的艰苦修复,雕像从约 200 块碎片中恢复了原貌,现陈列在东克里特岛 Siteia 考古博物馆。最近,利用高精度光学扫描仪对雕像和保护人员未能重新安装在雕像上的剩余碎片进行了三维记录,从而对许多剩余碎片进行了虚拟重新定位,纠正了雕像右脚的方向和整体姿态,并更好地了解了雕像的组装技术。这篇文章介绍了这些成果以及促成这些成果的数字化过程。
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引用次数: 0
Improving access: Multi-analytical survey of the Norwegian Sea trade archive to establish storage conditions, digitisation priorities and conservation treatments 提高利用率:对挪威海贸易档案进行多重分析调查,以确定储存条件、数字化优先事项和保存处理方法
IF 3.1 2区 综合性期刊 Q1 Arts and Humanities Pub Date : 2024-05-30 DOI: 10.1016/j.culher.2024.05.001
Ekaterina Pasnak , Jasna Malešič , Sílvia O. Sequeira

The Norwegian Sea Trade Archive (NST Archive) from the University of Bergen Library, Norway, is part of the UNESCO documentary heritage and contains unique documentation of the activity of companies that traded in stock fish in Norway and Europe (16th-20th century). The archive consists primarily of bound paper manuscripts written mostly in brown ink. We have surveyed this collection using a multi-analytical approach focused on the material characterization and condition of the paper carrier and inks. Our main aim was to support decision-making on establishing storage conditions, digitisation priorities, and type and extent of conservation treatments necessary to make the collection accessible.

After a first visual examination to detect and quantify damages, for the paper support analysis we measured surface pH, paper thickness and water absorbency. Additionally, on a quarter of all tested materials, we performed a SurveNIR analysis, providing information regarding paper pulp type, lignin, protein and rosin content, degree of polymerization, and mechanical properties. The archival material was grouped into three periods characterising the three milestones in paper production: handmade gelatine-sized rag papers, machine-made rag papers with gelatine and rosin sizing, and papers made from processed wood pulp.

Regarding the manuscripts’ inks, we used iron and copper tests to determine the presence of Fe2, Cu2+ and Cu+ions, respectively. For the visual characterization and condition rating of the inks, we used the protocols described by the Netherlands Institute for Cultural Heritage. The variety of ink colours and thickness of the inked lines encountered in each document was noted down. Thus specific tendencies present in each historical period became apparent. Results of the solubility of ink in water and alcohol significantly narrowed treatment options.

General tendencies of paper and ink degradation based on differences in papermaking were observed. Surface pH measurement, SurveNIR pH, rosin and protein concentration data showed that most rag papers were of poor to fair quality (pH ≤ 6.0 and low protein content (< 5 %)). Rosin-sized papers dated after 1840 had a lower pH (from 3.3 ± 0.2 to 5.0 ± 0.2) compared to gelatine-sized ones. Based on the obtained results, the overall condition of all the papers is good – slightly damaged but stable. The inks are not severely corroded, and there is no loss of text, although 20 % of the collection does show signs of iron-gall ink (IGI) corrosion. A limited number of documents, mostly before 1800, would require local antioxidative treatment. Due to the low pH of all the papers and the detection of ink corrosion, the collection should be stored in a cool environment, with low relative humidity.

After the survey, digitisation priorities were also established.

挪威卑尔根大学图书馆的挪威海贸易档案(NST 档案)是联合国教科文组织文献遗产的一部分,其中包含有关挪威和欧洲(16-20 世纪)鱼类贸易公司活动的独特文献。该档案主要由装订成册的纸质手稿组成,大部分用棕色墨水书写。我们采用多重分析方法对该藏品进行了调查,重点是纸质载体和墨水的材料特征和状况。我们的主要目的是为决策提供支持,以确定保存条件、数字化的优先次序以及保存处理的类型和程度,从而使藏品能够被利用。在进行了首次目视检查以检测和量化损坏情况后,我们对纸张支撑物进行了分析,测量了表面 pH 值、纸张厚度和吸水性。此外,我们还对四分之一的检测材料进行了 SurveNIR 分析,提供了有关纸浆类型、木质素、蛋白质和松香含量、聚合度和机械性能的信息。我们将档案材料分为三个时期,分别代表纸张生产的三个里程碑:手工制作的明胶大小的破布纸、使用明胶和松香施胶的机器制作的破布纸,以及使用加工过的木浆制作的纸张。对于油墨的目测特征和状况评级,我们采用了荷兰文化遗产研究所(Netherlands Institute for Cultural Heritage)描述的规程。每份文献中的墨色种类和墨线粗细都被记录下来。因此,每个历史时期的特定趋势都很明显。墨水在水和酒精中的溶解度结果大大缩小了处理方案的选择范围,并根据造纸工艺的不同观察到纸张和墨水降解的一般趋势。表面 pH 值测量、SurveNIR pH 值、松香和蛋白质浓度数据表明,大多数碎布纸张的质量较差或一般(pH 值≤ 6.0,蛋白质含量较低(< 5 %))。与明胶纸相比,1840 年以后的松香纸 pH 值较低(从 3.3 ± 0.2 到 5.0 ± 0.2)。根据所得结果,所有纸张的整体状况良好--略有损坏,但很稳定。油墨没有受到严重腐蚀,文字也没有丢失,但有 20% 的藏品出现了铁球油墨 (IGI) 腐蚀的迹象。少数文件需要进行局部抗氧化处理,其中大部分是 1800 年以前的文件。由于所有纸张的 pH 值都很低,而且还发现了油墨腐蚀,因此藏品应存放在相对湿度较低的阴凉环境中。
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引用次数: 0
A combined approach of SFM-MVS photogrammetry and reflectance transformation imaging to enhance 3D reconstructions 将 SFM-MVS 摄影测量与反射变换成像相结合,增强三维重建效果
IF 3.1 2区 综合性期刊 Q1 Arts and Humanities Pub Date : 2024-05-30 DOI: 10.1016/j.culher.2024.05.008
María Mercedes Morita , Daniel Alejando Loaiza Carvajal , Ivana Leticia González Bagur , Gabriel Mario Bilmes

One of the problems that arises when applying 3D Structure from Motion and Multi-View-Stereo photogrammetry to certain heritage objects characterized by minimal surface features and monochrome textures is that the obtained 3D models have low quality and accuracy. Within such scenarios, the smallest lengths that can be measured on it with high accuracy is usually one or more orders of magnitude worse than the maximum resolution of the input photographs. Additionally, when contrasted with outputs from scanning systems, these reconstructions tend to exhibit relatively lower quality. This article presents a simple approach wherein the incorporation of normal maps acquired through Reflectance Transformation Imaging technique improves the quality and accuracy of 3D photogrammetric reconstructions (mesh + texture). This enhancement also surpasses the capabilities of some commercial structured light scanning systems and reaches values that are in the order of magnitude of the maximum resolution of the photographs used.

将三维运动结构和多视角立体摄影测量技术应用于某些表面特征极少、纹理为单色的文物时,会出现一个问题,即获得的三维模型质量和精度都很低。在这种情况下,能够高精度测量的最小长度通常比输入照片的最大分辨率差一个或多个数量级。此外,与扫描系统的输出结果相比,这些重建结果的质量也相对较低。本文介绍了一种简单的方法,即结合通过反射变换成像技术获取的法线图,提高三维摄影测量重建(网格+纹理)的质量和精度。这种改进还超越了某些商用结构光扫描系统的能力,达到了所使用照片最大分辨率的数量级。
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引用次数: 0
Potential of synchrotron X-ray diffraction computed tomography (XRDCT) for a 3D non-destructive and/or non-invasive characterisation of cultural heritage geomaterials (CHG) 同步辐射 X 射线衍射计算机断层扫描(XRDCT)在文化遗产地质材料(CHG)三维非破坏性和/或非侵入性表征方面的潜力
IF 3.1 2区 综合性期刊 Q1 Arts and Humanities Pub Date : 2024-05-29 DOI: 10.1016/j.culher.2024.04.006
Elena Possenti , Maria Catrambone , Chiara Colombo , Marco Cantaluppi , Marco Merlini , Gavin B.M. Vaughan , Marco di Michiel , Nicoletta Marinoni

The present work describes the high potential of the recently developed synchrotron X-ray diffraction computed tomography (XRDCT) for 3D mapping of crystalline and amorphous phases in Geomaterials of Cultural Heritage (CHG). The paper critically discusses the promising results and limitations of XRDCT in Cultural Heritage applications. XRDCT has been applied herein to diverse CHG materials, spanning from archaeological ceramics, and stone conservation treatments to meteorites, at a microscale. Although these materials are very complex systems from a chemical, mineralogical and microstructural point of view, this innovative technique proves effective capability to access the real spatial distribution and semi-quantification of crystallographic phases within materials in a totally non-destructive and/or non-invasive way.

本论文介绍了最近开发的同步辐射 X 射线衍射计算机断层成像技术(XRDCT)在三维绘制文化遗产(CHG)地质材料中的晶体和非晶体相方面的巨大潜力。本文批判性地讨论了 XRDCT 在文化遗产应用中的良好效果和局限性。本文将 XRDCT 应用于各种文化遗产材料,从考古陶瓷、石材保护处理到陨石的微观层面。尽管从化学、矿物学和微观结构的角度来看,这些材料都是非常复杂的系统,但这一创新技术以完全无损和/或非侵入性的方式,证明了它能够有效地获取材料内部结晶相的真实空间分布和半定量化。
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引用次数: 0
Calcium hydroxide, magnesium hydroxide, silicon dioxide nanoparticles and their combinations as consolidants for lime mortars and gypsum plasters 氢氧化钙、氢氧化镁、二氧化硅纳米颗粒及其组合作为石灰砂浆和石膏抹灰的固化剂
IF 3.1 2区 综合性期刊 Q1 Arts and Humanities Pub Date : 2024-05-24 DOI: 10.1016/j.culher.2024.05.004
Ana Martínez-Arredondo , Victoria E. García-Vera , David Navarro-Moreno , Antonio J. Tenza-Abril , Marcos Lanzón

This paper studies the effectiveness of four consolidation treatments based on nanoparticles suspensions: calcium hydroxide (Ca-NP), magnesium hydroxide (Mg-NP), a treatment combining calcium hydroxide and magnesium hydroxide (Ca/Mg-NP), and a treatment consisting of calcium hydroxide and silicon dioxide (Ca/Si-NP) that were both applied separately. The suspensions were sprayed on gypsum plasters and lime renders which are common substrates in historical constructions and show a high degree of similarity with the treatments. The consolidation efficiency was evaluated using non-destructive techniques, such as peeling test, Shore-D hardness, water flow using Karsten tube and water vapour permeability tests. In addition, TEM images and XRD tests demonstrated the formation of a new C-S-H cementing phase when Ca/Si-NPs were combined due to a reaction between Ca(OH)2 with SiO2. Colour tests (CIE-L*a*b*) showed the consolidants did not produce major colour alterations, although the Ca-NP treatment caused a slight lightness increase. The strengthening effect was greater in lime mortars and water flow was moderately reduced in all treatments, except in mortars coated with Ca/Mg-NP. Finally, the chemical nature of the treatments is similar to the substrates, and they did not significantly alter the water vapour permeability of the studied materials.

本文研究了四种基于纳米颗粒悬浮液的加固处理方法的效果:氢氧化钙(Ca-NP)、氢氧化镁(Mg-NP)、氢氧化钙和氢氧化镁的混合处理方法(Ca/Mg-NP)以及氢氧化钙和二氧化硅的混合处理方法(Ca/Si-NP),这两种处理方法都是单独使用的。悬浮液被喷洒在石膏抹灰和石灰灰泥上,这些都是历史建筑中常见的基材,与处理方法有很高的相似度。使用非破坏性技术对固结效率进行了评估,如剥离测试、邵氏硬度、使用卡斯滕管的水流量和水蒸气渗透性测试。此外,TEM 图像和 XRD 测试表明,由于 Ca(OH)2 与 SiO2 发生反应,Ca/Si-NPs 结合后形成了新的 C-S-H 胶结相。颜色测试(CIE-L*a*b*)表明,尽管 Ca-NP 处理会导致轻微的亮度增加,但固化剂不会产生重大的颜色变化。石灰砂浆的加固效果更大,除涂覆了 Ca/Mg-NP 的砂浆外,所有处理方法都会适度降低水流量。最后,处理方法的化学性质与基材相似,它们不会显著改变所研究材料的水蒸气渗透性。
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引用次数: 0
Retentive bio-based chemical gel for removing glues from water-sensitive wooden artworks 用于去除对水敏感的木制艺术品上的胶水的生物基化学凝胶
IF 3.1 2区 综合性期刊 Q1 Arts and Humanities Pub Date : 2024-05-24 DOI: 10.1016/j.culher.2024.05.005
Chaehoon Lee , Giacomo Fiocco , Barbara Vigani , Teresa Recca , Silvia Rossi , Maurizio Licchelli , Marco Malagodi , Maduka L. Weththimuni , Francesca Volpi

Aged animal glues degrade and weaken over time, resulting in flakes and cracks on the material employed by wooden manufacturers and luthiers. Because of this deterioration, conservators and restorers remove aged water-soluble glues with a water swab, smoothing enough to clean them mechanically and putting on new reversible glues. However, it raises the question of whether a water swab can control moisture delivery while removing glue from wood, a hygroscopic and water-sensitive material.

This study formulated a chemically crosslinked film-forming hydrogel based on sodium alginate (SA) with (3-Glycidoxypropyl)trimethoxysilane (GPTMS) and calcium chloride, named as CA-GPTMS to construct a retentive gel. Synthesized gel materials were characterized using several methods: liquid state NMR, FTIR-ATR, and SEM-EDS analyses were involved in examining the cross-linking process, while moisture and mechanical properties were examined to understand its suitability for the cleaning application process. The strategies for applying the CA-GPTMS gel on wood surface were to selectively soften the glue and to remove it as well as leave no residues on the wood surface. The cleaning process was investigated by using different techniques, i.e., stereomicroscopy, reflection-FTIR, and SEM-EDS. Compared to traditional rigid Agar gel, the CA-GPTMS gel appeared successfully resistant to destruction and was suitable for application on highly water-sensitive surfaces.

随着时间的推移,老化的动物胶会变质和变弱,导致木制品制造商和制琴师使用的材料出现剥落和裂缝。由于这种劣化现象,保护人员和修复人员会用水拭子去除老化的水溶性胶水,用机械方法使其平滑清洁,然后涂上新的可逆性胶水。本研究以海藻酸钠(SA)为基础,用(3-缩水甘油氧丙基)三甲氧基硅烷(GPTMS)和氯化钙配制了一种化学交联成膜水凝胶,并命名为 CA-GPTMS,以构建一种保持性凝胶。合成的凝胶材料采用多种方法进行表征:液态核磁共振、傅立叶变换红外-原子吸收光谱和扫描电子显微镜-电子显微镜分析用于检查交联过程,而水分和机械性能则用于了解其在清洁应用过程中的适用性。在木材表面涂抹 CA-GPTMS 凝胶的策略是选择性地软化胶水,去除胶水,同时不在木材表面留下残留物。研究人员使用不同的技术,即立体显微镜、反射-傅立叶变换红外光谱和扫描电镜-电子显微镜,对清洁过程进行了研究。与传统的硬质琼脂凝胶相比,CA-GPTMS 凝胶具有成功的抗破坏性,适合应用于对水高度敏感的表面。
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