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Use of lacquer collected from Toxicodendron succedaneum for the Neolithic lacquerware detected in Zhejiang Province of China 中国浙江省发现的新石器时代漆器中,从毒竹中采集的漆器的使用
IF 3.3 2区 综合性期刊 0 ARCHAEOLOGY Pub Date : 2026-01-01 Epub Date: 2025-12-18 DOI: 10.1016/j.culher.2025.12.003
Yoshimi Kamiya , Takayuki Honda , Yoshitaka Nagai , Chuichi Watanabe , Tetsuo Miyakoshi , Ningyuan Wang , Guoping Sun , Leping Jiang , Bin Liu , Shuichi Noshiro , Shinichi Nakamura
Lacquer coatings of lacquerware excavated from four Neolithic sites in Zhejiang Province of eastern China were analyzed with Py-GC/MS analysis. The studied lacquered objects were recovered at the Tianluoshan, Liangzhu-Bianjiashan, Liangzhu-Zhongjiagang, and Kuahuqiao sites. We also carried out radiocarbon dating of seven objects. In 14 of 17 lacquer coating samples, the pyrosis-gas chromatography/mass spectrometry (Py-GC/MS) had the highest intensity in 3-nonylphenol and revealed existence of alkylphenols with 17 carbons in the side chains. These features in the Py-GC/MS results are characteristic of laccol composing the lacquer obtained from Toxicodendron succedaneum. Radiocarbon dating of six studied lacquer coatings and three wooden bodies from these sites ranged from 8000 to 4650 cal BP and indicated that, during the Neolithic period, the lacquer of Toxicodendron succedaneum was used for lacquerware manufacture for nearly 3000 years in eastern China. The obtained results conformed with the present distribution of Toxicodendron succedaneum and T. vernicifluum in China, T. succedaneum in the southern to eastern parts and T. vernicifluum in the central to northeastern parts. This finding, however, disagreed with the traditional understanding about the Neolithic lacquerware manufacture in China that the lacquer from Toxicodendron vernicifluum was solely used for the manufacture.
采用Py-GC/MS分析方法对浙江省4个新石器时代遗址出土的漆器漆膜进行了分析。所研究的漆器分别在天罗山、梁柱-卞家山、梁柱-中家岗和花虎桥遗址出土。我们还对七个物体进行了放射性碳定年。在17个漆膜样品中,有14个样品的热解-气相色谱/质谱(Py-GC/MS)检测结果显示,3-壬基酚中存在17个侧链碳的烷基酚。这些特征都是黄刺藤漆中脂质成分的特征。对这些遗址所研究的6件漆器涂层和3件木器进行放射性碳定年,其时间跨度在8000 ~ 4650 cal BP之间,表明在新石器时代,中国东部地区使用黄纹漆制作漆器已有近3000年的历史。所得结果与中国毒刺和梭子狸的分布现状相吻合,梭子狸分布在南部至东部,梭子狸分布在中部至东北部。然而,这一发现与传统的关于中国新石器时代漆器制造的认识不一致,传统的认识是,毒竹漆仅用于制造。
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引用次数: 0
S. Frutuoso de Montélios, analysis of the monument through new chronological inputs S. Frutuoso de montsamlios,通过新的时间输入对纪念碑进行分析
IF 3.3 2区 综合性期刊 0 ARCHAEOLOGY Pub Date : 2026-01-01 Epub Date: 2026-01-20 DOI: 10.1016/j.culher.2026.01.001
Francisco Andrade , Jorge Sanjurjo-Sánchez , Rebeca Blanco-Rotea , Manuela Martins
The Mausoleum/Chapel of S. Frutuoso de Montélios (Braga, Portugal) is one of the most paradigmatic places for the knowledge of the Portuguese Late Antique and Early Medieval Architecture, unavoidable presence in the Art History studies, which deal with the most ancient references of Christianity in the NW of the Iberian Peninsula. Within the project of Conservation, Valorization and Promotion of the Convent of S. Francisco de Real, led in the archaeological component, by the Archaeological Unit of the University of Minho, it was possible to carry out a detailed study of the building and an analysis of some mortars through Optical Stimulated Luminescence (OSL), crucial to clarifying and validate the historical knowledge that we have of the building. The samples collected from the foundation of the building confirm its Visigoth origins, being an unmissable reference in the northern outskirts of the city of Bracara in Late Antiquity. The dates related to the mausoleum, integrated in the convent, provided very important inputs to one of the most active archaeological debates of the Portuguese archaeology in the 20th century, the association of a set of buildings in the north of Portugal to the Visigoth or Mozarabic fabric and, consequently, the degree of impact of the territorial destabilization in the north of the Douro river.
S. Frutuoso de montsamlios陵墓/教堂(葡萄牙布拉加)是葡萄牙晚期古董和早期中世纪建筑知识最具代表性的地方之一,在艺术史研究中不可避免地存在,这些研究涉及伊比利亚半岛西北部最古老的基督教参考文献。在由Minho大学考古小组牵头的圣弗朗西斯科德雷亚尔修道院的保护、增值和推广项目中,有可能通过光学激发发光(OSL)对建筑进行详细研究,并对一些砂浆进行分析,这对于澄清和验证我们对建筑的历史知识至关重要。从建筑基础上收集的样本证实了它的西哥特起源,是古代晚期布拉卡拉市北郊不可错过的参考。与修道院有关的陵墓的日期,为20世纪葡萄牙考古学中最活跃的考古辩论之一提供了非常重要的输入,葡萄牙北部的一组建筑与西哥特或莫扎拉布织物的联系,以及因此,杜罗河北部领土不稳定的影响程度。
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引用次数: 0
Hydrophobic interface delaying wet-heat aging of acidified paper by reducing oxidation and acid hydrolysis rates of cellulose 疏水界面通过降低纤维素的氧化率和酸水解率来延缓酸化纸的湿热老化
IF 3.3 2区 综合性期刊 0 ARCHAEOLOGY Pub Date : 2026-01-01 Epub Date: 2025-11-13 DOI: 10.1016/j.culher.2025.10.010
Bei He , Junli Ren , Daodao Hu , Pujun Jin , Huiping Xing , Meiming Zhao
Hydrophilic cellulose derivatives have been widely used in the reinforcement of aged paper documents, but their impact on the durability of treated paper has not received sufficient attention. In this work, hydrophilic cationic cellulose (CMCC) and alkyl ketene dimer grafted cationic cellulose (AKD-g-CMCC) were used for comparative evaluation of anti-aging performance of treated acidified paper. The results indicate that CMCC treatment can more effectively improve the mechanical properties of acidified paper in the initial stage, but its wet-heat aging resistance is inferior to AKD-g-CMCC treatment. This is because hydrophilic CMCC is more prone to moisture absorption and oxidation in humid and heat environments, which further accelerating the oxidation and acid hydrolysis rates of cellulose in its reinforced paper. After AKD grafting, the alkyl chain segments form hydrophobic interfaces, effectively reducing the moisture absorption and oxidation of CMCC in high humidity environments. Moreover, it also strengthens the surface hydrophobicity and reduces air permeability of the treated paper, delaying the oxidation and acid hydrolysis rates of cellulose in acidified paper by blocking the invasion of water and oxygen. Therefore, this study will provide important references for the selection of reinforcement materials for paper documents.
亲水纤维素衍生物已被广泛应用于老化纸质文件的加固,但其对处理后纸张耐久性的影响尚未得到足够的重视。本文采用亲水性阳离子纤维素(CMCC)和烷基烯二聚体接枝阳离子纤维素(AKD-g-CMCC)对酸化纸的抗老化性能进行了比较评价。结果表明,CMCC处理能更有效地改善酸化纸初期的力学性能,但其耐湿热老化性能不如AKD-g-CMCC处理。这是因为亲水性CMCC在湿热环境中更容易吸湿和氧化,这进一步加快了其增强纸中纤维素的氧化和酸水解速率。AKD接枝后,烷基链段形成疏水界面,有效降低了CMCC在高湿环境中的吸湿氧化。此外,它还增强了处理后纸张的表面疏水性,降低了纸张的透气性,通过阻止水和氧气的侵入,延缓了酸化纸中纤维素的氧化和酸水解速率。因此,本研究将为纸质文献加固材料的选择提供重要参考。
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引用次数: 0
Advanced antimicrobial strategies for masonry heritage: Mechanisms, applications and prospects 砌体遗产的先进抗菌策略:机制、应用和前景
IF 3.3 2区 综合性期刊 0 ARCHAEOLOGY Pub Date : 2026-01-01 Epub Date: 2026-01-12 DOI: 10.1016/j.culher.2025.12.014
Zhiwei Liu , Ji Zhou , Guoyue Yang , Sheng Xiong
Microbial colonization and biodeterioration pose persistent threats to the integrity and aesthetics of brick and stone cultural heritage. To address these challenges, this review provides a comprehensive synthesis of antimicrobial strategies, ranging from conventional nanomaterials and natural products to emerging frontier approaches such as composite systems, superhydrophobic antimicrobial coatings, ionic liquid-based treatments, and green synthetic formulations. The study systematically integrates diverse antimicrobial mechanisms and emphasizes the translation gap between laboratory efficacy and real-world conservation practice. Special attention is given to multifunctional and environmentally responsive systems, which offer the potential to combine antibacterial activity with self-cleaning, controlled release, and durability enhancement. We further identify critical limitations, such as short-lived efficacy, ecological risks, and challenges in large-scale application—and highlight innovative solutions including encapsulation technologies, material hybridization, and sustainable synthesis routes. The study not only provides theoretical guidance but also proposes technical pathways for the sustainable protection of masonry heritage.
微生物定植和生物退化对砖石文化遗产的完整性和美学构成了持续的威胁。为了应对这些挑战,本综述提供了综合的抗菌策略,从传统的纳米材料和天然产物到新兴的前沿方法,如复合系统、超疏水抗菌涂层、离子液体处理和绿色合成配方。该研究系统地整合了多种抗菌机制,并强调了实验室功效与现实世界保护实践之间的翻译差距。特别关注的是多功能和环境响应系统,它提供了结合抗菌活性与自清洁、控制释放和耐久性增强的潜力。我们进一步指出了关键的限制,如短期疗效、生态风险和大规模应用的挑战,并强调了创新的解决方案,包括封装技术、材料杂交和可持续的合成路线。该研究不仅为砌体遗产的可持续保护提供了理论指导,而且为砌体遗产的可持续保护提供了技术途径。
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引用次数: 0
Understanding architectural heritage: 3D-MELL framework of architectural heritage large language model based on 3D point cloud 理解建筑遗产:基于三维点云的建筑遗产大语言模型3D- mell框架
IF 3.3 2区 综合性期刊 0 ARCHAEOLOGY Pub Date : 2026-01-01 Epub Date: 2025-12-20 DOI: 10.1016/j.culher.2025.12.004
Ming Guo , Li Zhu , Guoli Wang , Xiaoke Shang , Yaru Zhang , Ming Huang , Jiawei Zhao , Yangchao Dong , Yaofeng Wang , Ruoxin Wang , Rongsheng Chen
The swift advancement of artificial intelligence technology indicates that large language models provide significant promise for comprehension and creative endeavors. Point cloud data has emerged as an essential technology resource in urban building, providing extensive information that facilitates many operations. Current research has thoroughly examined the utilization of point cloud data in semantic segmentation and target detection; nevertheless, the perceptual outcomes of these methods are sometimes challenging to implement in scene design directly. This study presents a novel 3D-MELL network architecture designed to enhance the limits of large-scale language modelling in processing 3D data. The architecture employs elements from ancient architectural components as the data source, with each element assigned distinct ID attribute markers and spatial relationship markers. These markers accurately represent the characteristics of the items and their interactions within the 3D environment. The model can be optimized by a distributed training technique to accommodate diverse downstream jobs with particular commands during the fine-tuning phase, demonstrating favorable training metrics and fitting outcomes. This project created a front-end page utilizing HTML and CSS frameworks to represent the chat interface, offering a novel approach to transmitting and developing architectural historical knowledge.
人工智能技术的迅速发展表明,大型语言模型为理解和创造性努力提供了重要的希望。点云数据已经成为城市建设中必不可少的技术资源,它提供了广泛的信息,方便了许多操作。目前的研究已经深入探讨了点云数据在语义分割和目标检测中的应用;然而,这些方法的感知结果有时很难直接应用于场景设计中。本研究提出了一种新颖的3D- mell网络架构,旨在增强大规模语言建模在处理3D数据中的局限性。该体系结构采用古代建筑构件中的元素作为数据源,并为每个元素分配了不同的ID属性标记和空间关系标记。这些标记准确地代表了物品的特征以及它们在3D环境中的相互作用。该模型可以通过分布式训练技术进行优化,以适应在微调阶段具有特定命令的不同下游作业,从而显示出良好的训练指标和拟合结果。该项目创建了一个前端页面,利用HTML和CSS框架来表示聊天界面,提供了一种传输和开发建筑历史知识的新方法。
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引用次数: 0
Exploring the classification of painted pottery artifacts from different cultural sites in Northwest China by using LIBS technology combined with machine learning 利用LIBS技术结合机器学习对西北地区不同文化遗址彩陶文物进行分类研究
IF 3.3 2区 综合性期刊 0 ARCHAEOLOGY Pub Date : 2026-01-01 Epub Date: 2025-12-21 DOI: 10.1016/j.culher.2025.11.017
Yingna Chen , Duixiong Sun , Guoding Zhang , Xuetao Bai , Maogen Su , Marek Sikorski , Chenzhong Dong
Painted potterys, as a significant aspect of material culture, provides valuable insights into ancient societies and is essential for studying the evolution of civilizations. Traditional identification methods for the age of painted pottery artifacts often rely on excavation sites and decorative features, depending on expert experience, which introduces the risk of subjective misjudgment. To complement these approaches, this study proposes an auxiliary technique using Laser-Induced Breakdown Spectroscopy (LIBS) and machine learning. We analyzed pottery from six Neolithic to Bronze Age sites (c. 3300–600 B.C.). Hierarchical clustering evaluated chemical similarities, while Convolutional Neural Networks (CNN), Deep Neural Networks (DNN), and Light Gradient Boosting Machine (LightGBM) models were employed for classification. The optimal model achieved 98 % accuracy. The LIME interpreter further identified significant elemental features for each culture, enhancing objectivity. This research demonstrates that LIBS with machine learning serves as a valuable complement to traditional expertise, mitigating subjective risks and providing a reliable analytical aid for pottery classifications.
彩陶作为物质文化的一个重要方面,为研究古代社会提供了宝贵的见解,对研究文明的演变至关重要。传统的彩陶器物年代鉴定方法往往依赖于发掘地点和装饰特征,依赖于专家经验,这就引入了主观误判的风险。为了补充这些方法,本研究提出了一种使用激光诱导击穿光谱(LIBS)和机器学习的辅助技术。我们分析了六个新石器时代至青铜时代遗址(公元前3300-600年)的陶器。分层聚类评估化学相似性,同时使用卷积神经网络(CNN)、深度神经网络(DNN)和光梯度增强机(LightGBM)模型进行分类。最优模型的准确率达到98%。LIME解释器进一步确定了每种文化的重要元素特征,增强了客观性。这项研究表明,带有机器学习的LIBS可以作为传统专业知识的有价值的补充,降低主观风险,并为陶器分类提供可靠的分析辅助。
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引用次数: 0
Microblasting of powdered lignocellulosic particles: Cleaning of a wooden joint cover of a medieval coffered ceiling 粉末状木质纤维素颗粒的微爆破:中世纪格子天花板的木制接合覆盖物的清洗
IF 3.3 2区 综合性期刊 0 ARCHAEOLOGY Pub Date : 2026-01-01 Epub Date: 2026-01-02 DOI: 10.1016/j.culher.2025.12.012
Anna Nualart-Torroja , Àfrica Pitarch Martí , Iris Bautista-Morenilla , Manuel Ángel Iglesias-Campos
Mechanical methods used for cleaning unpolychromed wooden heritage in conservation-restoration rely on procedures that entail pressure and friction, potentially leading to erosion or material loss on the treated surface. In addition, certain methods, such as the use of sponges or erasers, very often leave residues that could affect the long-term conservation of wood due to their chemical composition.
The aim of this work is to assess the feasibility of using microblasting with powdered lignocellulosic particles for cleaning unpolychromed wood on a heritage artwork. The investigation aims to evaluate the advantages and drawbacks of this technique as a sensitive and sustainable alternative to the most common techniques used by conservator-restorers for unpolychromed wood cleaning. The cleaning results of microblasting of lignocellulosic particles are qualitatively compared to those achieved by traditional dry-cleaning techniques on wood.
This study is based on previous research that examined the effects of this technique on non-heritage wooden samples using hazelnut and almond shells, cork and pure cellulose powdered particles. The investigation aimed to assess potential morphological surface changes and to determine the degree of cleaning qualitatively without causing damage to the wood surface. Additionally, the study allowed the development of a cleaning protocol by selecting the specific particle size, and by adjusting pressure, angle, distance and time to surface soiling characteristics and wood typology according to the limited bibliographic references available.
From these results, tests were conducted on the back side of a wooden joint cover dating back to between the 14th and 16th centuries from one of the ceilings of the Monastery of Santa María de Pedralbes. The joint cover was weakened and affected by fungi and woodworm after centuries of outdoor climate exposure.
To evaluate the cleaning efficiency and the resulting effects on wood, the surface was analysed by digital optical microscopy and scanning electron microscopy before and after cleaning. Star diagrams were also made to assess the fulfilment of the cleaning criteria selected for the study.
Results indicate that when the technique is applied properly, an appropriate cleaning level can be achieved without compromising the fragile treated surface and with negligible presence of residues. Therefore, this approach emerges as a promising and environmentally friendly technique, respectful to the integrity of the heritage wooden artworks.
在保护修复中,用于清洁非彩色木材遗产的机械方法依赖于需要压力和摩擦的程序,可能导致处理表面的侵蚀或材料损失。此外,某些方法,例如使用海绵或橡皮擦,由于其化学成分,往往会留下可能影响木材长期保存的残留物。这项工作的目的是评估使用粉末状木质纤维素颗粒的微爆破清理文物艺术品上的非彩色木材的可行性。调查的目的是评估这种技术的优点和缺点,作为一种敏感的和可持续的替代最常用的技术,由保护-修复用于非多色木材清洁。木质纤维素颗粒的微爆破清洗结果与传统的木材干洗技术进行了定性比较。这项研究基于先前的研究,该研究检验了这种技术对使用榛子和杏仁壳、软木和纯纤维素粉末颗粒的非遗产木制样品的影响。该调查旨在评估潜在的形态学表面变化,并定性地确定清洁程度,而不会对木材表面造成损害。此外,该研究允许通过选择特定粒径,并根据有限的参考书目调整压力、角度、距离和时间来确定表面污染特征和木材类型,从而制定清洁方案。根据这些结果,对一个木制接头盖的背面进行了测试,该接头盖可以追溯到14世纪到16世纪之间,来自圣塔修道院María de Pedralbes的一个天花板。经过几个世纪的户外气候暴露,接缝覆盖被真菌和木蠕虫削弱并受到影响。为了评估清洁效率和对木材的影响,在清洁前后用数码光学显微镜和扫描电子显微镜对木材表面进行了分析。还制作了星图,以评估为研究选择的清洁标准的实现情况。结果表明,当该技术应用得当时,可以达到适当的清洁水平,而不会损害易碎的处理表面,并且残留物可以忽略不计。因此,这种方法作为一种有前途的环保技术出现,尊重传统木制艺术品的完整性。
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引用次数: 0
Experimental artistic research on the basis of the galvanography technique by Franz von Kobell (1840) 基于科贝尔电印技术的实验艺术研究(1840)
IF 3.3 2区 综合性期刊 0 ARCHAEOLOGY Pub Date : 2026-01-01 Epub Date: 2025-11-20 DOI: 10.1016/j.culher.2025.10.022
Valentina Ljubic Tobisch , Anna Artaker , Martin Klobassa , Wolfgang Kautek
Technical and methodological aspects of the production of galvanographs, a printing technique from the 1840s, were investigated both in a techno-historical and experimental manner. This new graphic technique was invented by Franz von Kobell in Munich. The businessman and owner of the paper shop Theyer & Hardtmuth, Franz Theyer, further developed and optimized the technique in the first Austrian laboratory for electrotyping in Vienna. The presented investigations support a better and more accurate identification of galvanographically generated printing plates and prints. The historical printing plates examined showed the use of various conventional graphic techniques and tools in combination with galvanography. Traces of a dry needle, wooden spatulas, roulettes and various burins indicated the use of mixed techniques. Experiments conducted showed that viscosity, heterogeneity, layer thickness and composition of the paints influenced the electrodeposited copper layer. The best results were achieved with a conductive powder layer over the paint, with graphite proving to be superior to silver.
从技术历史和实验的角度研究了19世纪40年代的一种印刷技术——电镀法的生产技术和方法。这种新的图形技术是由慕尼黑的弗朗茨·冯·科贝尔发明的。商人兼纸张店老板弗朗茨·特耶尔在维也纳的第一个奥地利实验室里进一步发展和优化了这项技术。提出的调查支持更好和更准确地识别电镀锌产生的印版和印刷品。历史上的印版显示了各种传统的图形技术和工具与电版画的结合使用。干针、木铲、轮盘和各种烧伤痕迹表明使用了混合技术。实验结果表明,涂料的粘度、非均质性、层厚和成分对电沉积铜层有影响。最好的结果是在涂料上涂上导电粉末层,石墨被证明优于银。
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引用次数: 0
Corrigendum to “Lac Dye Colours: A Review of the Origin, History and Identification Techniques in Textiles” [Journal of Cultural Heritage 75 (2025) 307-325] “紫胶染料:纺织品的起源、历史和鉴定技术回顾”的勘误表[文化遗产杂志75 (2025)307-325]
IF 3.3 2区 综合性期刊 0 ARCHAEOLOGY Pub Date : 2025-11-01 Epub Date: 2025-09-24 DOI: 10.1016/j.culher.2025.09.010
Mila Crippa , Dominique Cardon , Diego Tamburini , Takumasa Kondo , Paula Nabais
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引用次数: 0
A CityGML ADE for modeling Buddhist statues in 3D with semantic information 一个CityGML ADE,用于用语义信息对佛像进行三维建模
IF 3.3 2区 综合性期刊 0 ARCHAEOLOGY Pub Date : 2025-11-01 Epub Date: 2025-09-25 DOI: 10.1016/j.culher.2025.09.001
Yuehan Pan , Miaole Hou , Su Yang , Huabiao Li , Songze Wei , Hongchao Fan
Aiming to support intraoperative and quantitative analysis on 3D Buddhist models, this paper presents a new mechanism of integrating semantic and attribute information within 3D geometries of Buddhist statues using the CityGML Application Domain Extension (ADE). For this purpose, a framework is designed for the process of ADE development which includes the definition of component Thesaurus, the establishment of semantic structure, the development of logic and physical models. By deploying this framework, the ADE is developed to model Buddhist statues in any type with semantic and attribute information, because with this ADE it is possible to decompose a statue into small meaningful component and record semantic and attribute information with the geometries. The ADE is tested by interactively selecting and visualizing one component of a Buddhist statue and validate that capability of modelling. 3D Buddhist statues modeled using this ADE can then support automatic analysis and calculations. Hence, this research work is one of the fundaments for the digitalization in the domain of culture heritage.
为了支持三维佛像模型的术中分析和定量分析,本文提出了一种利用CityGML应用领域扩展(Application Domain Extension, ADE)将佛像三维几何图形中的语义和属性信息整合的新机制。为此,设计了ADE开发过程的框架,包括组件词库的定义、语义结构的建立、逻辑模型和物理模型的开发。通过部署这个框架,可以开发ADE来使用语义和属性信息对任何类型的佛像进行建模,因为有了这个ADE,就可以将佛像分解成有意义的小组件,并用几何图形记录语义和属性信息。通过交互式选择和可视化佛像的一个组件来测试ADE,并验证该建模能力。使用此ADE建模的3D佛像可以支持自动分析和计算。因此,这项研究工作是文化遗产领域数字化的基础之一。
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引用次数: 0
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Journal of Cultural Heritage
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