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Detection of MTHFR (A1298C) Gene Polymorphism in Women Suffer from Different Types of Abortion in Mosul City 摩苏尔市不同类型流产妇女MTHFR (A1298C)基因多态性检测
Pub Date : 2020-09-01 DOI: 10.33899/edusj.2020.126923.1064
O. Alhassani, Z. Ramadan
Genetic basis of recurrent abortion is poorly understood, Single gene mutations, polygenic, and cytogenetic factors are all found to show association with recurrent abortion. The analysis of single nucleotide polymorphisms in the genes coding for enzymes which responsible for regulatory of metabolic pathways (e.g. methylene tetra hydrofolate reductase), clotting factors (Factor V leiden and prothrombin) and hormones and hormone receptors (progesterone receptor). This study included (85) pregnant women who suffer from problems during pregnancy and the age range was between (25-35) years. The samples were divided into four groups ,the first included pregnant women who suffer from recurrent spontaneous abortion , while the second included pregnant women with missed abortion , the third group included pregnant women with recurrent spontaneous abortion and positive TORCH examination and the final group was considered a control group. The result of the study showed a relationship between cases of pregnancy disorder and genetic mutations of MTHFR gene at the (A1298C) site, the result of the study for a group of women with RSA showed that the distribution of the mutant genotype CC was the highest 40% and the repetitive alleles for this group was 57.5% for mutant allele C and 42.5% for normal allele A. Also the group of missed abortion showed that the distribution of the mutant genotype CC was the highest 40% and the repetitive alleles for this group was 52.5% for mutant allele C and 47.5% for normal allele A. Whereas the group of women with positive TORCH showed that the distribution of heterozygous genotype was the highest 50% and the repetitive alleles for this group was 32.2% for mutant allele C and 67.8% for normal allele A.
复发性流产的遗传基础尚不清楚,单基因突变、多基因及细胞遗传因素均与复发性流产有关。负责代谢途径调节的酶(如亚甲基四氢叶酸还原酶)、凝血因子(因子V leiden和凝血酶原)、激素和激素受体(孕酮受体)编码基因的单核苷酸多态性分析。这项研究包括(85)名怀孕期间出现问题的孕妇,年龄范围在(25-35)岁之间。样本分为四组,第一组为复发性自然流产孕妇,第二组为漏产孕妇,第三组为复发性自然流产且TORCH检查阳性的孕妇,最后一组为对照组。研究结果显示妊娠障碍病例与MTHFR基因(A1298C)位点的基因突变有关。的结果与RSA一群妇女的研究表明,突变体基因型的分布CC最高40%,重复这一群体的等位基因为57.5%,突变等位基因C为42.5%,正常等位基因a稽留流产的小组显示,突变基因型的分布CC最高40%,重复这一群体的等位基因为52.5%,突变等位基因C为47.5%,正常等位基因a而群妇女积极的火炬杂合子基因型的分布最高,为50%,突变等位基因C的重复等位基因占32.2%,正常等位基因A的重复等位基因占67.8%。
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引用次数: 0
Determination of Phenolic Compounds in Leaves for Some Cultivars of Pyrus malus L. and Pyrus communis L. Cultivated in North of Iraq and Identification by Using HPLC and Spectral Characters 伊拉克北部几种梨和梨品种叶片中酚类物质的测定及HPLC和光谱特征鉴别
Pub Date : 2020-09-01 DOI: 10.33899/edusj.2020.127061.1068
M. Shehab, Amer Al-Maathidy
The present work identified (8) cultivars belonging to the species Pyrus malus L. that included ("EarlyGold", "GrannySmith", "Royal Cala", "Red Delicious", "Golden Delicious", "Honey Crisp", "Mcintosh" and Cox") as well as (6) Cultivars of the species Pyrus communis L. namely ("Coneference", Decana", "Bonica", "Alkhatuni","Alothmani" and "William) by using spectral and chemical characteristics. The spectral study showed that different max appeared among all the cultivars of the species, and the result of chemical study identified (7) phenolic compounds in alcoholic extracts of leaves by using High Performance Liquid Chromatography (HPLC) including (Apigenin, Kaempferol, Catichen, Rutin, Luteolin, Quercetin and Coumarin) using (7) standard compounds for comparison among the cultivars. The compounds Apigenin, Kaempferol, Catichen, Leuteolin and Quercetin found in all cultivars of the species Pyrus communis L. while Rutine, Leuteolin, Quercetin and Coumarin found in all cultivars of the species Pyrus malus L. but Kaempferol compound found only in "Early Gold", "Royal Cala" and "Honey Crisp". The cultivar "EarlyGold" showed that lowest concentration of the compound Rutin (1.13) g/g and highest concentration of the compound Quercetin (685.96) g/g. The spectral and chemical characters showed a good taxonomic value in identification and separation the cultivars of the two species. Keyword: Pyrus malus L., Pyrus communis L., Cultivars, North of Iraq, Spectral, Chemical characters. حافتلا فانصأ ضعب قاروأ يف ةيلونيفلا تابكرملا ريدقت Pyrus malus L. ىرثمكلاو Pyrus communis L. قا رعلا لامش يف ةعورزملا مادختساب اهصيخشتو HPLC ةيفيطلا تافصلاو 158 حافتلا فانصأ ضعب قا روأ يف ةيلونيفلا تابكرملا ريدقت Pyrus malus L. ىرثمكلاو Pyrus communis L. قا رعلا لامش يف ةعورزملا مادختساب اهصيخشتو HPLC ةيفيطلا تافصلاو باهش دمحم رمع ىنم يديضاعملا دومحم نسحم رماع ةايحلا مولع مسق ةايحلا مولع مسق ةفرصلا مولعلل ةيبرتلا ةيلك ةفرصلا مولعلل ةيبرتلا ةيلك لصوملا ةعماج لصوملا ةعماج muna@uomosul.edu.iq dr.amer@uomosul.edu.iq DOI: 10.33899/edusj.2020.127061.1068 ملاتسلاا لوبقلا 07 / 05 / 2020 09 / 06 / 2020 ةصلاخلا ي ممم ت لامممحلا لمممح لا لممممضت 8 مممصأ ) ان ف ومممنلل ةمممعبات Pyrus$malus$L. مممهو EarlyGold و GrannySmith و RoyalCala و Red$Delicious و Golden$Deliciou و Honey Crisp و Mcintosh و Cox و ) 6 ومممنلل ةمممعبات فانمممصأ ) Pyrus communis L. مممهو Coneference و Decana و Bonica و Alkhatuni و Alothmani و William ةميةايميملاو ةمييييلا اامصلا ماد تساب ) ةومممضلا فامممييملا امممه ب ةمممييييلا ةمممسا دلا رمممهظأ UV Spectrophotometer ةمممم ي مممف لماممم ت اومممجو ةيمممصاصتملاا max ةمممسا دلا مممص و لسعومممنلا فانمممصأ لممميم ل لومممحملا ل تمممسملل 7 ةممميلونسف اممم كرم ) Phenolic compouns وتاما رك ةمةاات ماد تمساب رك فا االاا لامع لةامسلا امي High Performance Liquid Chromatography (HPLC) امعتمممساب 7 مممه مممنما ت دمممقو هفانمممصبا لسمممف ةمممة ااملل ةيمممساي اممم كرم ) اممم كرملا مممص ا فانمممصبا فتتخامممب اهدمممجاوت مممف اممم كرملا Apigenin Kaempferol Catichen Luteolin Quercetin فانمم
利用光谱和化学特征鉴定了梨属品种(“EarlyGold”、“GrannySmith”、“Royal Cala”、“Red Delicious”、“Golden Delicious”、“Honey Crisp”、“Mcintosh”和Cox)和梨属品种(“conefence”、Decana、“Bonica”、“Alkhatuni”、“Alothmani”和“William”)。光谱分析结果表明,各品种间的最大最大比值存在差异;化学分析结果表明,采用高效液相色谱法(HPLC)鉴定出了7种不同品种间的标准化合物,包括芹菜素、山奈酚、菜青素、芦丁、木犀草素、槲皮素和香豆素。芹菜素、山奈酚、菜青素、白犀草素和槲皮素在所有梨属品种中均有发现,芦丁、白犀草素、槲皮素和香豆素在所有梨属品种中均有发现,山奈草酚化合物仅在“早金”、“皇家卡拉”和“蜂蜜脆”中均有发现。品种“早金”中芦丁含量最低(1.13)g/g,槲皮素含量最高(685.96)g/g。光谱和化学性状对两种栽培品种的鉴别和分离具有很好的分类价值。关键词:梨,梨,品种,伊拉克北部,光谱,化学性状حافتلافانصأضعبقاروأيفةيلونيفلاتابكرملاريدقتPyrus马吕斯l .ىرثمكلاوPyrus普通的l .قارعلالامشيفةعورزملامادختساباهصيخشتو高效液相色谱ةيفيطلاتافصلاو158حافتلافانصأضعبقاروأيفةيلونيفلاتابكرملاريدقتPyrus马吕斯l .ىرثمكلاوPyrus普通的l .قارعلالامشيفةعورزملامادختساباهصيخشتو高效液相色谱ةيفيطلاتافصلاوباهشدمحمرمعىنميديضاعملادومحمنسحمرماعةايحلامولعمسقةايحلامولعمسقةفرصلامولعللةيبرتلاةيلكةفرصلامولعللةيبرتلاةيلكلصوملاةعماجلصوملاةعماجmuna@uomosul.edu.iqdr.amer@uomosul.edu.iq DOI: 10.33899 / edusj.2020.127061.1068ملاتسلاالوبقلا07 / 09年05/2020 / 06/2020ةصلاخلايمممتلامممحلالمممحلالممممضت8مممصأ)انفومممنللةمممعباتPyrus马吕斯美元L。مممهوEarlyGoldوGrannySmithوRoyalCalaو红色美味و黄金美元美味و蜂蜜脆و麦金托什و考克斯و)6ومممنللةمممعباتفانمممصأ)Pyrus普通的l .مممهوConeferenceوDecanaوBonicaوAlkhatuniوAlothmaniو威廉ةميةايميملاوةمييييلااامصلامادتساب)ةومممضلافامممييملاامممهبةمممييييلاةمممسادلارمممهظأ紫外分光光度计ةمممميمممفلمامممتاومممجوةيمممصاصتملاا马克斯ةمممسادلامممصولسعومممنلافانمممصألممميمللومممحملالتمممسملل7ةممميلونسفامممكرم)酚醛compounsوتاماركةمةااتمادتمسابركفااالاالامعلةامسلاامي高效液相色谱(HPLC)امعتمممساب7مممهمممنماتدمممقوهفانمممصبالسمممفةمممةاامللةيمممسايامممكرام)مممكرملامممصافانمممصبافتتخامممباهدمممجاوتمممفامممكرملا芹黄素山柰酚Catichen木樨草素槲皮素فانممممصألمممميمجممممفلاممرممممثP.communis l .اممممكرملالسمممملممممف芦丁وLeuteolinو槲皮素و香豆素اماتلافانمصألميمجمفاهمصيتممتP.malus l .ألسملمفبكرملا山柰酚فانصبافدجوو“早期黄金”“皇家爱”و“蜂蜜脆هنممممصلاصممممسمت”EarlyGold”بممممكرمللصممممسكرتلممممقاممممكتتماب芦丁مممملفا1ه13مارغمارغورارامممم)بمكرمللصمسكرتملعألمسامكرمخباامكرملالمةمةااملاب槲皮素ملبو685ه96مارغمارغورارام)هةسودملافانصباةيقبلعحضاولابلاصعةاةلالصعامميتفةمهمةييينصتةميااهةابةيةايميملاوةييييلاااصلارستووصعهلسعونلافانصأةالادلاتااملكلاPyrus马吕斯美元L。Pyrus普通的L .ةمييييلااامصلااارمعلااممفانمصلااهةيةايميملاوحافتلافانصأضعبقاروأيفةيلونيفلاتابكرملاريدقتPyrus马吕斯L .ىرثمكلاوPyrus普通的L。
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引用次数: 0
Modify the rheological properties of Daura asphalt by thermoplastic polyurethane using the microwave technique 采用微波技术对热塑性聚氨酯改性道拉沥青的流变性能进行了研究
Pub Date : 2020-09-01 DOI: 10.33899/edusj.2020.126651.1047
Salam jajo Karash, K. Owaid
There is a growing need to produce asphalt materials with high economic feasibility, that is the production of asphalt materials with rheological properties that differ from the base asphalt (unmodified asphalt), can be used in many fields such as the production of paving asphalt, where it is not appropriate to use ordinary asphalt. This study included the modification of the rheological properties of Daura asphalt by catalytic chemical treatment with thermoplastic polyurethane (Used in the interior parts of cars) using a microwave oven at a power of (360) watts and at different periods of time. As well as treat asphalt samples with the thermoplastic polyurethane in the presence of sulfur. The modified asphalt samples were studied in terms of ductility, penetration, softening point and penetration Index. A sample with good rheological specification was selected (As7) that are conform with the specifications of Iraqi Roads and Bridges Authority, The selected sample were studied in terms of conducting Marshall tests and comparing them with the original sample in order to demonstrate the possibility of using the modified sample as an paving asphalt. The obtained results showed good specifications in terms of crawl and stability values. An aging test was also conducted on the sample (As7) of the good rheological specifications. Key world: modified-asphalt; thermoplastic polyurethane; rheological properties. ةيجولويرلا صاوخلا ريوحت ناثيروي يلوبلاب ةرودلا تلفسلأ ةرا رحلل عواطملا فيووركياملا ةينقت مادختساب انيزرام وجج ملاس 1 * ديوع دمحا دلاخ ، 2 1 و 2 قا رعلا ،لصوملا ،لصوملا ةعماج ،ةفرصلا مولعلل ةيبرتلا ةيلك ،ءايميكلا مسق Journal of Education and Science (ISSN 1812-125X), Vol: 29, No: 3, 2020 (85-101) 86 ةصلاخلا داوم جاتنلإ ةساملا ةجاحلل اً رظن إ ةيتلفسا داوم جاتنإ يف لثمتت ةيلاع ةيداصتقا ىودج تاذ ةيتلفس حلصت مادختسلال ةريثك تلااجم يف طيلبت تلفسإ جاتنإك ذ و ةيجولوير تافص ةديج تلفسلاا مادختسا بسانملا ريغ نم ثيح ساسلأا .روحملا ريغ هذه تنمضت ةيجولويرلا صاوخلا ريوحت ةسا ردلا لأ تلفس ةرودلا جلاعملاب ايميكلا ة يلوبلا عم ةزفحملا ةيئ ناثيروي ةرا رحلل عواطملا ) ختسملا يف مد تا رايسلل ةيلخادلا ءا زجلاا ( ب فيووركياملا نرف مادختسا ب ( ةقاط 360 بو طاو ) ةينمز تا رتف ةفلتخم ، امك هذه ةجلاعم تمت ناثيروي يلوبلا عم صاوخلا ةرا رحلل عواطملا تيربكلا دوجوب . نمو مت مث ت ةسا رد تانيع فسلاا ةروحملا تل ( ةيجولويرلا صاوخلا ) نم ءا رجإ للاخ تاصوحف ةيذافنلا ، ةلاطتسلااو ، ةنويللا ةجردو .قا رتخلاا ليلدو ا مت نيع رايتخ ة ذ تا ةيجولويرلا تافصاوملا ةديج ( 7 As ) و يتلا ةيقا رعلا روسجلاو قرطلا ةئيه تافصاوم عم قفاوتت ، و نيعلا ةسا رد ة ةراتخملا ب م تا رابتخا ءا رجإ اهتنراقمو لاشرا ةنيعلاب ساسلأا أ نم ةي نيعلا مادختسا ةيناكمإ تابثإ لج ة ةلدعملا طيلبت تلفسأك . ترهظأ تافصاوم اهيلع لوصحلا مت يتلا جئاتنلا ةديج ا رقتسلااو فحزلا ميق ثيح نم ر ةي ، و امك أ ىلع مداقتلا صحف اًضيا يرج جذومنلا ( 7 As ( يذ تافصاوملا .ةديجلا ةيجولويرلا املكلا فملا ت ةيحات تلفسلإا : ةيجولويرلا تافصلا ،ةرا رحلل عواطملا ناثيروي يلوبلا ،روحملا . ةمدقملا لأا فرعي لصت ىتح ةرا رحلا ةجرد ضافخناب دادزت ةجوزل تاذ ةليقث ةلئاس
《塔克拉·塔纳库·拉帕卡·哈拉帕拉贾、马哈拉j和Maharaj[8],《埃斯韦拉》电视插播节目,以及《尼利西亚·卢布·列宁拉·德罗勒》(PVC)·蒂佐,塔卡马拉·塞克特·达德扎布·阿塔特尼拉》。··························································(签名)《和合本》)在《neelatus nnyatob》电视节目中,有一种声音是:“你……”。撒迦利亚人吃撒迦利亚人吃撒迦利亚人吃的撒拉威人吃的撒迦利亚人吃的撒迦利亚人的麦子,我要了一份合身的合影奥恩在《《和合本》(《和合本》)中沉睡,《和合本》(《和合本》)。你们,你们就叫你们不要喝硝基甲苯,因为你们没有使用过氯酮,因为你们没有使用过硝基甲苯,也没有使用过硝基甲苯,你可以看到水底的情景:在沙irini和imanisabab[13]制造电波、灰发式电视、、粉色的、粉色的叔叔的的粉色的粉色、色色的等。《新闻》》(《新闻》)تلفسلإلبحسلاونكمتوeem Kar[15]睡ةساىلع回应taرميلوبلاليدعتريثأتسلأاصاوخ睡我当然رلاbرميلوبلا损伤نيعونمادختسا,ta(نيرياتسنيياداتويبنيرياتسsbثيإو林恩تيسأj (v)金钱p我以EVAريثأتمييقتbeةفلتخم增长ةينزوبسنب)这些不تلايدعتىلعصاوخسلأا我当然رلا不睡لقتلاtaرابتخ弟兄损伤(لثمةيديةجرد,ةيذافنلاةنويللا,ةجوزللاةلاطتسلاا,或者يعونلا向下ىلعاهؤارجإ太يتلا)سلأا我当然رلا损伤和يعيبطلاولدعملا道格bصاوخنأسلأا我当然رلاثكب损伤لضفأتناكلدعملاتلفسلإا叔叔《监测》第29卷,第29卷:0.320世纪80年代(85-101年)hinzo a yamila,, attsala, tatala, at, a, d, d, nuila, nu, h, h, h, h, h, h,马古·胡胡[18]在德姆拉、纳撒罗、尼撒基拉、尼撒拉、尼撒拉、撒母耳、撒母耳、撒母耳、撒母耳、撒母耳、撒母耳、撒母耳、撒母耳、撒母耳、撒母耳、撒母耳、撒母耳、撒母耳、撒母耳、撒母耳、撒母耳、撒母耳、撒母耳下的撒迦德人,向撒母耳撒母耳撒母耳撒母耳撒母耳。这是一个令人兴奋的电视节目。闪烁:拉瓦:耐用(Materials) 1。除了罗得拉电视台和罗得拉·德尼姆拉·德顿姆拉·德德姆拉·德梅特的合唱团(1)。lodg 1 (lodla电视台播放播放播放播放ltla播放的电影,播放的是美国广播公司的电视节目,播放的是美国广播公司的节目。因此,你会感到恐慌。3。艾哈迈拉·蒙伊玛拉·德克尔克4。
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引用次数: 0
The Effect of Nickel and Aluminum Concentration on Cyclic Oxidation Resistance of Mild Steel (AISI 1020) 镍和铝浓度对低碳钢(AISI 1020)抗循环氧化性能的影响
Pub Date : 2020-09-01 DOI: 10.33899/edusj.2020.166256
Y. Salman, Mahmood Hmood, E. E. Ghadeer
Experimental studies have been made to determine the oxidation be heavier of several coatings system on commercial mild steel alloy (AISI 1020). The oxidation kinetics of a single stage coating such as Aluminized and Nickel have been under )1000C( using a thermal cyclic oxidation.The structures were studied using optical microscope to identify a phases. Most coating use to enhance the formation of protective oxid scale, in this research, the results for Nickel coating showed some reduction in resistance of )AISI 1020( alloy and It is found they follow linear rate law, but Aluminized coating using a pack – cementation technique, exhibited the greatest resistance to oxidation, followed parabolic law (protective oxidation behavior). because it has a good ductility and its capability to form a protective oxid Layer )Al2O3(, such Alumina scale is known as thermally and electrically insulator and characterized with slow gowning rate.
通过实验研究,确定了几种涂层体系在商品低碳钢合金(AISI 1020)上的氧化较重。单级涂层(如镀铝和镍)的氧化动力学已低于1000℃(使用热循环氧化)。用光学显微镜对其结构进行了表征。在本研究中,镀镍层对aisi1020合金的抗氧化性能有一定的降低,并遵循线性速率规律,而镀铝层采用包埋胶结技术,表现出最大的抗氧化性能,遵循抛物线规律(保护氧化行为)。因为它具有良好的延展性和形成保护氧化层的能力)Al2O3(,这种氧化铝鳞片被称为热绝缘体和电绝缘体,其特点是生长速度慢。
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引用次数: 0
Effect of Some Biochemical Parameters as Antioxidants in Placenta of infected Pregnant Weman with Toxoplasmosis 弓形虫感染孕妇胎盘抗氧化剂生化指标的影响
Pub Date : 2020-09-01 DOI: 10.33899/edusj.2020.126095.1037
M. I. Ibraheem, L. Mustafa, Ahmed yahya Ismeel
Reregulation of biochemical profile of host as a result of host cells-pathogen interaction may involve in pathogenesis of toxoplasmosis disease. The biochemical parameters in the placenta of Toxoplasma-infected pregnant women and noninfected pregnant women (control group) were investigated The criteria taken into consideration are: Superoxide dismutase (SOD) , Peroxidase (Px) , GlutathioneStransferase (GST) , Lactate dehydrogenase (LDH) , Aryl esterase (AE) , Acetylcholine esterase (AchE) , Vitamin A,C and E As well as placental electrolytes including: Sodium (Na) , Potassium (K) , Chloride (Cl) , Calcium (Ca) , Selenium (Se) , Cupper (Cu) , Zinc (Zn) , Iron (Fe) , Magnesium (Mg) and Manganese (Mn). The results showed: a non-significant increase in the activity of SOD, GST, LDH and AchE during 6-9 months, and activity of AE during 1-3 months, were determined whereas the activity of Px was decreased in all periods of pregnancyA nonsignificant increase in the level of vitamin E and non-significant decrease in levels of vitamin A and C during pregnancy periods in placentae of infected pregnant Were observed. . A significant increase (p≤0.01) in levels of Na and K during 1-3 months and Ca during 3-6 months, whereas the level of Cl decreased during pregnancy periods. A significant increase (p≤0.01) in levels of Seand Mg during 6-9 months and a nonsignificant increase in level of Cu during 1-3 months and 6-9 months, whereas the level of Zn, Fe and Mn significantly decreased in all periods of Pregnancy in placenta infected women.
弓形虫病的发病机制可能与宿主细胞与病原体的相互作用有关。研究弓形虫感染孕妇和未感染孕妇(对照组)胎盘的生化指标,考虑的标准有:超氧化物歧化酶(SOD)、过氧化物酶(Px)、谷胱甘肽转移酶(GST)、乳酸脱氢酶(LDH)、芳基酯酶(AE)、乙酰胆碱酯酶(AchE)、维生素A、C、E以及胎盘电解质包括:钠(Na)、钾(K)、氯(Cl)、钙(Ca)、硒(Se)、铜(Cu)、锌(Zn)、铁(Fe)、镁(Mg)和锰(Mn)。结果表明:6 ~ 9个月期间SOD、GST、LDH、AchE活性无显著升高,1 ~ 3个月期间AE活性无显著升高,而Px活性在妊娠各时期均呈下降趋势;感染孕妇胎盘中维生素E水平无显著升高,维生素a、C水平无显著降低。妊娠1 ~ 3月龄Na、K水平显著升高(p≤0.01),3 ~ 6月龄Ca水平显著升高(p≤0.01),Cl水平下降。胎盘感染孕妇妊娠6 ~ 9月龄硒、镁水平显著升高(p≤0.01),1 ~ 3月龄和6 ~ 9月龄铜水平升高不显著(p≤0.01),而锌、铁、锰水平在妊娠各时期均显著降低。
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引用次数: 1
A study of essential components of three types of Bituminous Materials in Mishraq sulfur Mine Mishraq硫磺矿三种沥青原料的基本成分研究
Pub Date : 2020-09-01 DOI: 10.33899/edusj.2020.126679.1050
Motea Al jbouri, Hala Jasim, thaer abed halo
The chemical constituentisof three types of bituminous materials found in different conditions in Mishraq sulfur Minewas studied. The FTIR spectroscopy showed reduce in the length of hydrocarbon chains from the intensity of paraffinic bands in bitumenous materials of Frasch sulfur Mine (BM) compare with natural bituminous materials (NB) and Bituminous materials which extracted in-depth about 200 m without exposing to Frasch process condition (BB). The percentage of asphaltene in (MB) which increases dramatically is found 63.64% compared with (BB) and (NB) which 37.37% and 14.28% respectively and a similar decrease in percentage petrolene (maltene) . A percentage of n-hexane fraction by silica gel chromatography of petrolene (MB) is 18.49% compared with (BB and N.B) are 25.06 % and 47.05 % respectively while the cyclohexane fractions of petrolene MB are four-time of N.B and three-time of B.B . From all results, we conclude that a reaction has occurred between sulfur and bitumenous materials especially hydrocarbon chains of Aromatics and naphthenic rings in sulfur well during Frasch process which leads to an increase in asphaltene percentage and decrease of petrolene.
对米什拉克硫磺矿在不同条件下发现的三种沥青材料的化学成分进行了研究。FTIR光谱分析表明,与天然沥青材料(NB)和未暴露于Frasch工艺条件下提取深度约200 m的沥青材料(BB)相比,Frasch硫矿(BM)沥青材料的烷烃链长度减少。沥青质在(MB)中的含量显著增加,为63.64%,而(BB)和(NB)的沥青质含量分别为37.37%和14.28%,汽油(maltene)的沥青质含量也有类似下降。经硅胶层析得到的石油天然气(MB)正己烷馏分为18.49%,而(BB和N.B)的正己烷馏分分别为25.06%和47.05%,而石油天然气(MB)的环己烷馏分是N.B的4倍和B.B的3倍。综上所述,硫井中硫与沥青物质特别是芳烃链和环烷环发生了反应,导致沥青质含量增加,汽油含量降低。
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引用次数: 0
Study Boundary Problem with Integral condition for Fractional Differential Equations 研究分数阶微分方程具有积分条件的边界问题
Pub Date : 2020-09-01 DOI: 10.33899/edusj.2020.126471.1038
Nawal Aziz Abdulkader, N. Adnan
Many years ago there was a great interest in studying the existence of positive solutions for fractional differential equations. Many researchers have considered the existence of positive solutions of non-linear differential equations of non-integer order with integral boundary value conditions using fixed point theorems. G.wang et al.(2012) investigated the following fractional differential equations DW(t) + f(t,W(t)) = 0, 0 < t < 1 with integral boundary value condition W(0) = W(0) = 0 , W (1) = λ∫ W(s)ds 1 0 were 2 < α ≤ 3 λ is a positive number (0 < λ < 2), Dis the standard fractional derivative equation of Caputo who obtained his results by means of Guo-krosnosel'skii theorem in a cone also A.Cabada et at. (2013) established the following non-linear fractional differential equation with integral boundary value conditions DW(t) + f(t,W(t)) = 0 , 0 < t < 1 W(0) = W(0) = 0 ,W(1) = λ ∫ W(s)ds , were 2 < α ≤ 3 , λ > 0 , λ ≠ α , 1 0 Dis Riemann –Liovuville standard fractional derivative. and f is a continuous function. The results were based on Guo-krasnosel'skii fixed point theorem in a cone . In this paper we investigate the existent results of a positive solution for the integral boundary value conditions of the following system of equations: D h(t) + k(t, h(t)) = 0 , t ∈ (0,1) h(0) = h(0) = h(0) = 0 , h(1) = δ∫ h(n)dn 1 0 where 3< β ≤ 4 , δ is a positive number , δ ≠ 3 , D denotes Caputo standard derivative and k is a continuous function.Our work based on Banach's and Schauder's theorem. Keyword: Fractional Differential Equation, Integral boundary value Conditions, Schauder's theorem, Green function. 1.Introduction In the last few decades, fractional order calculus has been of the most rapidly developing areas of mathematical analysis. In fact, a natural phenomenon may depend not only on the time instant but also on the previous time history, which can be successfully modeled by fractional calculus. Also fractional differential equations Study boundary problem with Integral condition for Fractional Differential Equations 239 play an important role because of their application in various fields of science such as mathematics, physics, mechanism, economics, engineering and biological sciences etc.(see[1-4]). Integral boundary conditions have several applications in real-life problem such as population dynamics, underground water flow, and blood flow problems. For a detailed description of the integral boundary conditions, we refer in this study to some recent papers [5,6,7]. Our establishment is the existence of positive solutions of the integral boundary conditions of the following fractional differential equation:D h(t) + k(t, h(t)) = 0 , 0 < t < 1 (1) h(0) = h(0) = h(0) = 0 , h(1) = δ ∫ h(n)dn 1 0 (2) where 3 < β ≤ 4 , 0 < δ < 3 , D denotes Caputo standard derivative and k: [0,1] × [0,∞) → [0,∞) is a continuous function. Firstly we obtain the exact expression of the Green's function related to the liner equation Dh(t) + g(t) = 0 , 0 < t < 1 (
许多年前,人们对研究分数阶微分方程正解的存在性产生了极大的兴趣。许多研究者利用不动点定理研究了具有整边值条件的非整数阶非线性微分方程正解的存在性。g.w wang et al.(2012)研究了分数阶微分方程DW(t) + f(t,W(t)) = 0, 0 < t < 1,积分边值条件W(0) = W(0) = 0, W(1) = λ∫W(s),当2 < α≤3 λ为正数(0 < λ < 2)时,得到分数阶微分方程,并给出了Caputo的标准分数阶微分方程,Caputo利用锥上的Guo-krosnosel’skii定理得到了结果。(2013)建立了具有积分边值条件的非线性分数阶微分方程DW(t) + f(t,W(t)) = 0, 0 < t < 1 W(0) = W(0) = 0,W(1) = λ∫W(s)ds,分别为2 < α≤3,λ > 0, λ≠α, 1 0 Dis Riemann -Liovuville标准分数阶导数。f是一个连续函数。结果基于锥上的Guo-krasnosel不动点定理。本文研究了下列方程组积分边值条件的正解的存在性结果:D h(t) + k(t, h(t)) = 0, t∈(0,1)h(0) = h(0) = h(0) = 0, h(1) = δ∫h(n) dn10,其中3< β≤4,δ为正数,δ≠3,D为Caputo标准导数,k为连续函数。我们的研究基于巴拿赫定理和绍德定理。关键词:分数阶微分方程,积分边值条件,Schauder定理,Green函数。1.在过去的几十年里,分数阶微积分已经成为数学分析中发展最快的领域之一。事实上,一种自然现象可能不仅依赖于时间瞬间,而且还依赖于以前的时间历史,这可以通过分数微积分成功地建模。分数阶微分方程的积分条件边界问题在数学、物理、机械、经济、工程和生物科学等科学领域有着重要的应用(参见[1-4])。积分边界条件在人口动态、地下水流动和血流问题等现实问题中有许多应用。对于积分边界条件的详细描述,我们在本研究中参考了最近的一些论文[5,6,7]。我们建立了以下分数阶微分方程积分边界条件的正解的存在性:D h(t) + k(t, h(t)) = 0,0 < t < 1 (1) h(0) = h(0) = 0, h(1) = δ∫h(n)dn 1 0(2)其中3 < β≤4,0 < δ < 3, D表示Caputo标准导数,k: [0,1] ×[0,∞)→[0,∞)是连续函数。首先,我们得到了线性方程Dh(t) + g(t) = 0,0 < t < 1(3)对应的积分条件h(0) = h(0) = h(0) = 0, h(1) = δ∫h(ρ)dρ 10的格林函数的精确表达式。2.本文给出了分数阶微积分定理中的一些定义、记号、引理和定理。定义2.1。[1]函数J:[0,∞)→R的Capote导数分数阶α定义为:DJ(t) = 1 Γ(ρ−α)∫Jρ(c) (t−c)1+α−n t
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引用次数: 1
Comparative Anatomical Study for the Cultivars of Morus L. Species cultivated in North of Iraq 伊拉克北部桑属栽培品种的比较解剖学研究
Pub Date : 2020-09-01 DOI: 10.33899/edusj.2020.127117.1075
Raad Hammad Al-Badrany, Aamer Al-mathidy
The current study involved a comparative anatomical study for the cultivars belonging to the species Morus L. cultivated in north of Iraq that included 14 cultivars of 6 species: M. alba L. (ʽBeautiful Dayʼ, ʽBig Whiteʼ, ʽReaseʼ, ʽGreeceʼ, ʽPearlʼ, ʽBorder Sweetʼ and ʽPendulaʼ); M. latifolia Poir (ʽKokuso Koreanʼ); M. rubra L. (ʽAmarahʼ); M. nigra L. (ʽShamiʼ); M. macroura Miq (ʽKing Whiteʼ); ʽDwarfʼ and M. hybrid (ʽTiceʼ and ʽWellingtonʼ). The anatomical study included (blade leaf, midrib and venation system) in addition to nonliving components (crystals) in the mesophyll of the blade leaf. The result of the anatomical characteristics of (blade thickness, cuticle, epidermis cell, thickness and layers of palisade and spongy tissue, thickness and shape of arc vascular curve, number and dimension of vessles in the midrib and the shape of idioblast in cystolith). In addition to the venation system of the leaf which found the Brochidodromous type in all cultivars excepted ʽBigWhiteʼ and ʽPendulaʼ cultivars of species M. alba and ʽKokuso Koreanʼ cultivars of species M. latifolia founded from Craspedromous type. Certainly they have importance taxonomic value in the separation and identification among the cultivars of the species studied belong to the genus Morus L. Keyword: Anatomical Study, Cultivars, Morus, North of Iraq ةنراقم ةيحيرشت ةسا رد عاونأ فانصلأ سنجلا Morus L. قا رعلا لامش يف ةعورزملا ينا ردبلا دومحم دمح دعر 1 * ، يديضاعملا دومحم نسحم رماع 2 1 و 2 سق ةايحلا مولع م ، ةفرصلا مولعلل ةيبرتلا ةيلك قا رعلا ،لصوملا ،لصوملا ةعماج ، ةصلاخلا فة لا لاوةنا اافةصص ةةنراقم ةيحيرشت ةسا رد يلاحلا ثحبلا نمضت Morus L. يةتلاو قا رةعلا لامةا يةف ةةعورزملا فمةضت 14 ةل دوعت اففص 6 اافصصاب :يهو لاونأ ʽBeautiful Dayʼ و ʽBig Whiteʼ و ʽReaseʼ و ʽGreeceʼ و ʽPearlʼ و ʽBorder Sweetʼ و ʽPendulaʼ لوفلل M. alba L. و ʽKokuso Koreanʼ لوةفلل M. latifolia Poir و ʽAmarahʼ لوةفلل M. rubra L. و ʽShamiʼ لوةفلل M. nigra L. و ʽKing Whiteʼ و ʽDwarfʼ لوةفلل M. macroura Miq و ʽTiceʼ و ʽWellingtonʼ Journal of Education and Science (ISSN 1812-125X), Vol: 29, No: 3, 2020 (178-195) 179 لوفلل M. hybrid دقف لما ةةيحلا رةهل اةنوتملا نةع نةضف ،اةههف قرةعتلا ماظن ،يطسولا اهقرع ،ةقرولا لصن( ةيحيرشتلا ةسا ردلا ةرةةشبلا اةة ن ،ةةةمد ا ،ةةةقرولا لةةصن دمةةس( ةةةل ةيحيرةةشتلا افةةصلا تاةةتن رةةه ا هاا ا روةةلولا( اةةههف داةةمعلا يةةسفلا اةةقبق دمةةس ، ةةةةي وصا ددةةةع ،يتاةةةعولا دوةةةقلا لتةةةاو دمةةةس ،ي ففةةةسصاو ةةةةقلعملا ا روةةةلولل يجراةةةقلا لزةةة لا لتةةةاو ،يطةةةسولا قرةةةعلا يةةةف اةةةهرطقو Idioblast لوةفلا رةه ا قا رو ا يةف قرةعتلا ماةظن نةع نةضف ا Brochidodromous نهففةصلا ادةع اافةص ا اةيمج يةف ʽBig Whiteʼ و ʽPendulaʼ لوةةةةةفلل M. alba فةةةةةصلاو ʽKokuso Koreanʼ لوةةةةةفلل M. latifolia ةةةةةناك إ لوةةةةةفلا نةةةةةم Craspedromous يهو هةسوردملا اافص ا صيقشتو لزع يف اهمادقتسا نتم ةيفيفصت ةيمها ا ،اافصأ ،ةيحيرشت ةسا رد :ةيحاتفملا املكلا Morus ، هقا رعلا لاما ةمدقملا ف لا يمتفي Morus L. اعلا ىلا ةيتوتلا ةلت Moraceae مضت يتلاو 73 و فج 1000 ققافملا يف رشتفت لون يتاوتةسصا ة صا هباو ةيتاوتس و
本研究对栽培于伊拉克北部的桑属6种14个栽培品种进行了比较解剖学研究:M. alba L. (Beautiful Day’、Big White’、Rease’、greek’、Pearl’、Border Sweet’和Pendula’);M. latifolia Poir(韩国);M. rubra L. (;;);M. nigra L.(沙米);M. macoura Miq (King White);“矮人”和“混血”(“Tice”和“惠灵顿”)。解剖研究包括(叶片、中脉和脉系统)以及叶片叶肉中的无生命成分(晶体)。解剖特征(叶片厚度、角质层、表皮细胞、栅栏和海绵组织的厚度和层数、圆弧维管曲线的厚度和形状、中脉维管的数量和尺寸、囊体中异母细胞的形状)的结果。除了在所有品种中都发现了Brochidodromous类型的叶片脉系,但在M. alba的BigWhite '和Pendula '品种和在M. latifolia的Kokuso Korean '品种中发现了Craspedromous类型。当然,它们对桑树属植物品种的分离鉴定具有重要的分类学价值。解剖研究,栽培品种,桑葚;伊拉克北部ةنراقمةيحيرشتةساردعاونأفانصلأسنجلا桑属l .قارعلالامشيفةعورزملايناردبلادومحمدمحدعر1 *،يديضاعملادومحمنسحمرماع2 1وسقةايحلامولعم،ةفرصلامولعللةيبرتلاةيلكقارعلا،لصوملا،لصوملاةعماج،ةصلاخلافةلالاوةنااافةصصةةنراقمةيحيرشتةسارديلاحلاثحبلانمضت桑属l .يةتلاوقارةعلالامةايةفةةعورزملافمةضت14ةلدوعتاففص6اافصصاب:يهولاونأʽ美丽的日子ʼوʽ白色ʼوʽ原因ʼوʽ希腊ʼوʽ珍珠ʼوʽ边境甜ʼوʽ翻车机ʼلوفللm·阿尔·l·وKokuso Korean ' لوةفلل M. latifolia Poir Amarah ' لوةفلل M. rubra L. Shami ' لوةفلل M. nigra L. King White ' Dwarf ' لوةفلل M. macoura Miq Tice ' Wellington ' Journal of Education and Science (ISSN 1812-125X), Vol . 29, No:3.2020年(178 - 195)179年لوفللm .混合دقفلماةةيحلارةهلاةنوتملانةعنةضف،اةههفقرةعتلاماظن،يطسولااهقرع،ةقرولالصن(ةيحيرشتلاةساردلاةرةةشبلااةةن،ةةةمدا،ةةةقرولالةةصندمةةس(ةةةلةيحيرةةشتلاافةةصلاتاةةتنرةةهاهاااروةةلولا(اةةههفداةةمعلايةةسفلااةةقبقدمةةس،ةةةةيوصاددةةةع،يتاةةةعولادوةةةقلالتةةةاودمةةةس،يففةةةسصاوةةةةقلعملااروةةةلولليجراةةةقلالزةةةلالتةةةاو،يطةةةسولاقرةةةعلايةةةفاةةةهرطقو异形细胞لوةفلارةهاقاروايةفقرةعتلاماةظننةعنةضفاBrochidodromousنهففةصلاادةعاافةصااةيمجيةفʽ白色ʼوʽ翻车机ʼلوةةةةةفللm . albaفةةةةةصلاوʽKokuso韩国ʼلوةةةةةفللm . latifoliaةةةةةناكإلوةةةةةفلانةةةةةمCraspedromousيهوهةسوردملااافصاصيقشتولزعيفاهمادقتسانتمةيفيفصتةيمهاا،اافصأ،ةيحيرشتةسارد:ةيحاتفملااملكلا桑属،هقارعلالاماةمدقملافلايمتفي桑属l .اعلاىلاةيتوتلاةلت桑科مضتيتلاو73وفج1000ققافملايفرشتفتلونيتاوتةسصاةصاهباوةيتاوتسوفلالاونأومفترااالتشبنتسملايتافثواداحأ،ةرمعمارهاووبرتيفةفلتقموتيةفدةهجلتشبرهزاةيضماحلابرتلاpH(6。
{"title":"Comparative Anatomical Study for the Cultivars of Morus L. Species cultivated in North of Iraq","authors":"Raad Hammad Al-Badrany, Aamer Al-mathidy","doi":"10.33899/edusj.2020.127117.1075","DOIUrl":"https://doi.org/10.33899/edusj.2020.127117.1075","url":null,"abstract":"The current study involved a comparative anatomical study for the cultivars belonging to the species Morus L. cultivated in north of Iraq that included 14 cultivars of 6 species: M. alba L. (ʽBeautiful Dayʼ, ʽBig Whiteʼ, ʽReaseʼ, ʽGreeceʼ, ʽPearlʼ, ʽBorder Sweetʼ and ʽPendulaʼ); M. latifolia Poir (ʽKokuso Koreanʼ); M. rubra L. (ʽAmarahʼ); M. nigra L. (ʽShamiʼ); M. macroura Miq (ʽKing Whiteʼ); ʽDwarfʼ and M. hybrid (ʽTiceʼ and ʽWellingtonʼ). The anatomical study included (blade leaf, midrib and venation system) in addition to nonliving components (crystals) in the mesophyll of the blade leaf. The result of the anatomical characteristics of (blade thickness, cuticle, epidermis cell, thickness and layers of palisade and spongy tissue, thickness and shape of arc vascular curve, number and dimension of vessles in the midrib and the shape of idioblast in cystolith). In addition to the venation system of the leaf which found the Brochidodromous type in all cultivars excepted ʽBigWhiteʼ and ʽPendulaʼ cultivars of species M. alba and ʽKokuso Koreanʼ cultivars of species M. latifolia founded from Craspedromous type. Certainly they have importance taxonomic value in the separation and identification among the cultivars of the species studied belong to the genus Morus L. Keyword: Anatomical Study, Cultivars, Morus, North of Iraq ةنراقم ةيحيرشت ةسا رد عاونأ فانصلأ سنجلا Morus L. قا رعلا لامش يف ةعورزملا ينا ردبلا دومحم دمح دعر 1 * ، يديضاعملا دومحم نسحم رماع 2 1 و 2 سق ةايحلا مولع م ، ةفرصلا مولعلل ةيبرتلا ةيلك قا رعلا ،لصوملا ،لصوملا ةعماج ، ةصلاخلا فة لا لاوةنا اافةصص ةةنراقم ةيحيرشت ةسا رد يلاحلا ثحبلا نمضت Morus L. يةتلاو قا رةعلا لامةا يةف ةةعورزملا فمةضت 14 ةل دوعت اففص 6 اافصصاب :يهو لاونأ ʽBeautiful Dayʼ و ʽBig Whiteʼ و ʽReaseʼ و ʽGreeceʼ و ʽPearlʼ و ʽBorder Sweetʼ و ʽPendulaʼ لوفلل M. alba L. و ʽKokuso Koreanʼ لوةفلل M. latifolia Poir و ʽAmarahʼ لوةفلل M. rubra L. و ʽShamiʼ لوةفلل M. nigra L. و ʽKing Whiteʼ و ʽDwarfʼ لوةفلل M. macroura Miq و ʽTiceʼ و ʽWellingtonʼ Journal of Education and Science (ISSN 1812-125X), Vol: 29, No: 3, 2020 (178-195) 179 لوفلل M. hybrid دقف لما ةةيحلا رةهل اةنوتملا نةع نةضف ،اةههف قرةعتلا ماظن ،يطسولا اهقرع ،ةقرولا لصن( ةيحيرشتلا ةسا ردلا ةرةةشبلا اةة ن ،ةةةمد ا ،ةةةقرولا لةةصن دمةةس( ةةةل ةيحيرةةشتلا افةةصلا تاةةتن رةةه ا هاا ا روةةلولا( اةةههف داةةمعلا يةةسفلا اةةقبق دمةةس ، ةةةةي وصا ددةةةع ،يتاةةةعولا دوةةةقلا لتةةةاو دمةةةس ،ي ففةةةسصاو ةةةةقلعملا ا روةةةلولل يجراةةةقلا لزةةة لا لتةةةاو ،يطةةةسولا قرةةةعلا يةةةف اةةةهرطقو Idioblast لوةفلا رةه ا قا رو ا يةف قرةعتلا ماةظن نةع نةضف ا Brochidodromous نهففةصلا ادةع اافةص ا اةيمج يةف ʽBig Whiteʼ و ʽPendulaʼ لوةةةةةفلل M. alba فةةةةةصلاو ʽKokuso Koreanʼ لوةةةةةفلل M. latifolia ةةةةةناك إ لوةةةةةفلا نةةةةةم Craspedromous يهو هةسوردملا اافص ا صيقشتو لزع يف اهمادقتسا نتم ةيفيفصت ةيمها ا ،اافصأ ،ةيحيرشت ةسا رد :ةيحاتفملا املكلا Morus ، هقا رعلا لاما ةمدقملا ف لا يمتفي Morus L. اعلا ىلا ةيتوتلا ةلت Moraceae مضت يتلاو 73 و فج 1000 ققافملا يف رشتفت لون يتاوتةسصا ة صا هباو ةيتاوتس و ","PeriodicalId":15610,"journal":{"name":"Journal of Education Science","volume":"2 1","pages":"178-195"},"PeriodicalIF":0.0,"publicationDate":"2020-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"90562441","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Time decay of pulse current in capillary glow discharge 毛细管辉光放电中脉冲电流的时间衰减
Pub Date : 2020-09-01 DOI: 10.33899/edusj.2020.126339.1032
M. Ahmed
A high voltage pulse generator was development and implemented. This generator has the capacity to generate a sequence of pulses with a varying pulse height from 0 to 5 kV, and changes the pulse width in ms range. This generator has been tested and used to study the pulse glow discharge in argon by using the capillary tube under pressure 0.3 to 0.5 torr. This study has succeeded to establish the nature of discharge relaxation (plasma relaxation) when a high voltage pulse causes a breakdown in the gas (converts to conducting case).The current decays when the obtained voltage pulse is switched off. The electronic switching is a successful tool which can be used to generate high voltage pulses with flexibility that help to adjust an adjustable peak height voltage pulse, pulse duration and pulse width. The plasma returns to a neutral status when the current decay time is less than plasma relaxation time. This mean that if plasma decays time is more than relaxation time the plasma will transit from pulse glow discharge to continuous discharge. In this study the currentvoltage characteristics in relation to different gas pressures were in the abnormal glow discharge regime.
研制并实现了高压脉冲发生器。该发生器具有产生一系列脉冲的能力,脉冲高度从0到5kv不等,脉冲宽度在ms范围内变化。该发生器已在0.3 ~ 0.5 torr压力下的毛细管氩气中进行了脉冲辉光放电实验。本研究成功地建立了当高压脉冲导致气体击穿(转化为导电情况)时放电弛豫(等离子体弛豫)的性质。当获得的电压脉冲关闭时,电流衰减。电子开关是一种成功的工具,它可以灵活地产生高压脉冲,有助于调整可调的峰值高度、电压脉冲、脉冲持续时间和脉冲宽度。当电流衰减时间小于等离子体弛豫时间时,等离子体恢复到中性状态。这意味着如果等离子体衰减时间大于弛豫时间,等离子体将从脉冲辉光放电过渡到连续放电。在本研究中,不同气体压力下的电流电压特性处于异常辉光放电状态。
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引用次数: 0
Spectrophotometric Determination of Aminophenol Isomers Via Oxidative Coupling Reaction with 4-Aminoantipyrine 4-氨基安替比林氧化偶联分光光度法测定氨基酚异构体
Pub Date : 2020-09-01 DOI: 10.33899/edusj.2020.126543.1041
R. Al-Luhaiby, Mohammed S. Al-Enizzi
A spectrophotometric method has been developed for the determination of aminophenol isomers (o-aminophenol, m-aminophenol and p-aminophenol). The method is based on oxidative coupling reaction of these compounds with 4-aminoantipyrine (4-AAP) in the presence of cupper sulphate as oxidizing agent in alkaine medium forming a reddish brown colour. The products show maximum absorption at 440 nm, 480 nm and 445 nm for o-aminophenol, m-aminophenol and p-aminophenol respectively. The molar absorptivities are 8.632×10 ,9.33×10 and 9.1449 ×10 l.mol.cm for concentrations obeyed Beer’s law in the range 1-20, 1-24 and 1-7 μg.ml for the above compounds respectively. The average recovery was ranged between 98.38% and 101.01% with relative standard deviation < 1.6 for all the studied compounds. The 4-AAP products were formed in the ratio of 1:2 aminophenol isomers : 4-AAP. The stability constant of the products was 7.4 ×10, 3.27×10 and 9.94×10 l.mol for o-aminophenol, m-aminophenol and p-aminophenol products respectively indicating the good stability of these products.
建立了一种测定氨基酚异构体(邻氨基酚、间氨基酚和对氨基酚)的分光光度法。该方法是基于这些化合物与4-氨基安替比林(4-AAP)在硫酸铜作为氧化剂的存在下,在碱介质中氧化偶联反应,形成红棕色。产物对邻氨基酚、间氨基酚和对氨基酚的最大吸收波长分别为440 nm、480 nm和445 nm。在1-20、1-24和1-7 μg浓度范围内,摩尔吸光度分别为8.632×10、9.33×10和9.1449 ×10 l.mol.cm。以上化合物分别为Ml。加样回收率在98.38% ~ 101.01%之间,相对标准偏差< 1.6。氨基苯酚同分异构体与4-AAP的比例为1:2。邻氨基酚、间氨基酚和对氨基酚的稳定常数分别为7.4 ×10、3.27×10和9.94×10 l.mol,表明产品具有良好的稳定性。
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引用次数: 0
期刊
Journal of Education Science
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