Journal of Environmental Chemical Engineering最新文献

{"title":"Advances and recent applications in high-energy {001} facets of anatase TiO2: A review","authors":"Chaofan Zhao ,&nbsp;Lu Ren ,&nbsp;Yu Shi ,&nbsp;Xinluan Wang ,&nbsp;Wencheng Huang ,&nbsp;Huan Xie","doi":"10.1016/j.jece.2025.115764","DOIUrl":"10.1016/j.jece.2025.115764","url":null,"abstract":"<div><div>Surface control is a crucial influencing factor for the performance of semiconductors, especially TiO₂ photocatalyst. Normally, anatase TiO₂ is accessible with exposed stable {101} facets. Nevertheless, the surface energy of {001} facets with 0.90 J·m⁻² is 2.05 times higher than that of {101} facets. Therefore, anatase TiO₂ with high-energy {001} facets has attracted much attention and been recognized for some special properties. In this review, we profoundly focus on the special {001} facets of anatase TiO₂ from synthesis, unique physicochemical features to recent applications. Here, we provide the detailed surface-controlled growth approaches of F as a capping agent and the F-free route. The morphologies of TiO₂ with {001} facets are presented as single nanocrystals or hierarchically assembled crystals. Particularly, we summarize the physicochemical features of {001} facets, including efficient oxygen site, strong interaction with reactants, excellent photothermocatalytic synergetic effect and unique surface defects. These unique features have promoted the recent applications of {001} facets, which are widely used in VOCs degradation, CH₄ conversion, CO₂ reduction, H₂ production, water oxidation, antibiotic removal, and NO oxidation, etc. Through this review, the research on anatase TiO₂ with {001} facets, and even the surface control of other semiconductor materials can be further inspired.</div></div>","PeriodicalId":15759,"journal":{"name":"Journal of Environmental Chemical Engineering","volume":"13 2","pages":"Article 115764"},"PeriodicalIF":7.4,"publicationDate":"2025-02-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143394416","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Low-water quality and non-communicable disease nexus: Health impacts, mechanisms, and advanced water treatment approaches","authors":"Charles Nshimiyimana ,&nbsp;Nandini Thakur ,&nbsp;Adel I. Alalawy ,&nbsp;Yuanzhang Zheng ,&nbsp;Tareq Kareri ,&nbsp;El-Sayed Salama","doi":"10.1016/j.jece.2025.115744","DOIUrl":"10.1016/j.jece.2025.115744","url":null,"abstract":"<div><div>Water quality is essential to prevent non-communicable diseases (NCDs). Low-water quality induced by contamination from natural and anthropogenic activities can lead to NCDs that affect human health. Previous studies have reported several water- and food-borne diseases. However, the direct and indirect relationships between low-water quality and NCDs must be comprehensively summarized. Thus, this review aims to comprehensively summarize the global impact of low-water quality on NCDs, water pollutants and NCDs interconnection, and potential approaches to improve water quality. Heavy metals, persistent organic pollutants, chemicals, and microplastics from agricultural runoff and leachates contaminate the water sources. These contaminants have been reported to enhance endothelial dysfunction, oxidative stress, reactive oxygen species generation, apoptosis, and DNA damage, which are indirectly linked to NCDs. Methods (such as reverse osmosis, coagulation, flocculation, floatation, and sensor monitoring) could improve water quality and prevent NCDs risk. However, prompt preventive measures at domestic, industrial, and governmental levels are required for cost-effective NCDs prevention. Extensive in vitro research, cohort studies, toxicological evaluations, and multidisciplinary cooperation are also needed to clarify the interconnections between water quality and NCDs.</div></div>","PeriodicalId":15759,"journal":{"name":"Journal of Environmental Chemical Engineering","volume":"13 2","pages":"Article 115744"},"PeriodicalIF":7.4,"publicationDate":"2025-02-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143421514","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Process intensification in hydrothermal liquefaction of biomass: A review","authors":"Shahin Mazhkoo ,&nbsp;Salman Soltanian ,&nbsp;Habeeb O. Odebiyi ,&nbsp;Omid Norouzi ,&nbsp;Mitchell Ubene ,&nbsp;Aneela Hayder ,&nbsp;Omid Pourali ,&nbsp;Rafael M. Santos ,&nbsp;Robert C. Brown ,&nbsp;Animesh Dutta","doi":"10.1016/j.jece.2025.115722","DOIUrl":"10.1016/j.jece.2025.115722","url":null,"abstract":"<div><div>Hydrothermal liquefaction (HTL) presents a promising pathway for converting wet biomass resources into biofuels, offering significant advantages over conventional methods. However, numerous challenges must be addressed for HTL scale-up, including energy provision for the endothermic process, heat and mass transfer limitations, slurry concentration and pumpability challenges, char and coke formation, and continuous phase separation. This review explores key strategies such as autothermal HTL, which improves process efficiency and reduces external energy requirements by coupling exothermic and endothermic reactions within the same reactor, thereby simplifying reactor design and reducing operational costs. Additionally, multistage HTL processes are highlighted for their ability to optimize biocrude quality and yield by fractionating biomass conversion stages, resulting in higher energy returns on investment and better-quality biocrude. Solvothermal HTL and integration techniques for aqueous phase are also discussed. Furthermore, the HTL patent landscape is discussed to provide insights into current technological advancements. This review aims to offer a comprehensive understanding of process intensification in HTL, highlighting innovative solutions to enhance the efficiency and scalability of the process for sustainable biofuel production.</div></div>","PeriodicalId":15759,"journal":{"name":"Journal of Environmental Chemical Engineering","volume":"13 2","pages":"Article 115722"},"PeriodicalIF":7.4,"publicationDate":"2025-02-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143388146","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Valorization of extractible soybean by-products for polymer composite and industrial applications","authors":"Jan Vincent M. Madayag,&nbsp;Marcel Roy B. Domalanta,&nbsp;Reymark D. Maalihan,&nbsp;Eugene B. Caldona","doi":"10.1016/j.jece.2025.115703","DOIUrl":"10.1016/j.jece.2025.115703","url":null,"abstract":"<div><div>Soybean, a versatile global crop, holds significant potential for applications beyond the food industry, extending into sectors such as coatings, corrosion inhibition, composite materials, adhesives, and bioplastics. While extensive research exists on soybean food and feed uses, a comprehensive synthesis of its industrial applications remains limited. This review bridges this gap by examining soybean’s chemical composition, extraction technologies, and emerging industrial uses. We explore how advancements in mechanical, chemical, and enzymatic extraction methods enhance yield and sustainability, comparing their efficiency and environmental impact. Moreover, we discuss innovative applications of soybean derivatives, such as epoxidized and acrylated soybean oils in coatings, isoflavone-rich extracts for corrosion protection, and soybean-based biocomposites and adhesives, highlighting recent developments in each area. The potential of computational approaches (e.g. CROPGRO, machine learning algorithms, and density functional theory) is also reviewed for their ability to optimize the processing and performance of soybean-based materials. Lastly, we identify key challenges, such as improving extraction efficiency, achieving material performance on par with synthetic alternatives, and suggesting pathways for sustainable industrial applications of soybeans. Looking forward, our review aims to guide innovation in soybean-based products, promoting their use as eco-friendly alternatives across diverse industries.</div></div>","PeriodicalId":15759,"journal":{"name":"Journal of Environmental Chemical Engineering","volume":"13 2","pages":"Article 115703"},"PeriodicalIF":7.4,"publicationDate":"2025-02-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143394415","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Cathode materials and novel strategies for improving bioenergy production in microbial electrolysis cell: A review","authors":"Miaomiao Yang ,&nbsp;Shuai Luo ,&nbsp;Rongfang Yuan ,&nbsp;Rongrong Hou ,&nbsp;Beihai Zhou ,&nbsp;Huilun Chen","doi":"10.1016/j.jece.2025.115718","DOIUrl":"10.1016/j.jece.2025.115718","url":null,"abstract":"<div><div>Recovering bioenergy from wastewater by sustainable technologies is crucial to address environmental and energy concerns. Microbial electrolysis cell (MEC) combines electrochemical and microbial metabolic processes and are considered a promising technology. The material properties of cathodes are the primary determinants of production efficiency since they directly participate in the generation of H₂ and byproducts. Previous reviews mainly focused on the production process and mechanism of bioenergy, but little about cathode materials and their optimization. Based on the mechanism of MEC and its coupling technologies, this review comprehensively examines and contrasts the production efficiency of precious metals, carbon-based materials, Ni-based materials, metal-organic frameworks, and biocathodes. Ni-based materials are employed as excellent catalysts or cathode support materials because of their high conductivity, good stability, and low cost. To improve the cathode production efficiency, novel strategies to boost (i) conductivity, (ii) catalysis, (iii) specific surface area, and (iv) H source are discussed. Significantly, electrical conductivity has a greater impact on cathode properties which is attained by constructing layered structures and doping heteroatoms. Finally, we anticipate the future research directions of MEC to address the challenges facing this area.</div></div>","PeriodicalId":15759,"journal":{"name":"Journal of Environmental Chemical Engineering","volume":"13 2","pages":"Article 115718"},"PeriodicalIF":7.4,"publicationDate":"2025-02-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143326385","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Development of strategies for persulfate activation with cerium-based catalysts for environmental applications: A review","authors":"Vu-Anh Le ,&nbsp;Hieu Trung Nguyen ,&nbsp;Thi-Dieu-Hien Vo ,&nbsp;Ya-Fen Wang ,&nbsp;Sheng-Jie You","doi":"10.1016/j.jece.2025.115699","DOIUrl":"10.1016/j.jece.2025.115699","url":null,"abstract":"<div><div>Advanced oxidation processes utilizing sulfate radicals have attracted growing interest in recent years as a clean and efficient method for breaking down organic pollutants. Cerium is widely recognized for its reversible redox reaction involving Ce(III) and Ce(IV) species. This distinctive characteristic enhances the breakdown of organic pollutants by persulfate, a chemical that contains sulfate radical species, through the release of oxygen and the formation of oxygen vacancies within its structure. Multiple strategies have been employed to improve the effectiveness of persulfate activation and the degradation of organic compounds. This review uniquely focuses on cerium-based catalysts, addressing their underexplored potential in persulfate activation. It offers a comprehensive summary of design strategies, elucidates the synergistic mechanisms between Ce ions, support materials, and persulfate, and systematically evaluates their applications. Economical feasibility was also analyzed as well as providing actionable recommendations to advance catalysts research and implementation in environmental treatment.</div></div>","PeriodicalId":15759,"journal":{"name":"Journal of Environmental Chemical Engineering","volume":"13 2","pages":"Article 115699"},"PeriodicalIF":7.4,"publicationDate":"2025-02-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143326384","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Recent study on biodegradable hydrogels for agriculture application: A review","authors":"Wan Amirah Najwa Wan Anuar ,&nbsp;Ros Azlinawati Ramli ,&nbsp;Marwa M. El-Sayed ,&nbsp;Sudhir G. Warkar","doi":"10.1016/j.jece.2025.115679","DOIUrl":"10.1016/j.jece.2025.115679","url":null,"abstract":"<div><div>Biodegradability and eco-friendliness are the most importance topic to consider in the development of new products. Commercial hydrogels for agriculture applications are made from fully synthetic polymers, which is non-biodegradable and harmful to environment. The utilization of polysaccharide in hydrogels production has sparked the rise of biodegradable hydrogels (BHs). However, using it alone results in poor mechanical properties and very fast degradation. Therefore, combining it with other materials as a composite is necessary. This article reviewed the development of BHs in the last 5 years. Classifications, materials resources, preparation methods, biodegradability of BHs, seeds germination and plant growth performance are critically investigated. Fundamental concepts such as definitions and application methods of BHs are described. Finally, important conclusions and outlook have been mentioned at the end of this article.</div></div>","PeriodicalId":15759,"journal":{"name":"Journal of Environmental Chemical Engineering","volume":"13 2","pages":"Article 115679"},"PeriodicalIF":7.4,"publicationDate":"2025-02-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143326392","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Theoretical insights into the factors affecting the electrochemical performance of solid oxide electrolysis cells for CO2 reduction","authors":"Azeem Mustafa ,&nbsp;Yong Shuai ,&nbsp;Zhijiang Wang ,&nbsp;Guene Lougou Bachirou ,&nbsp;Mummad Rafique ,&nbsp;Samia Razzaq ,&nbsp;Muhamamd Ammad Nasir ,&nbsp;Wei Wang ,&nbsp;Enkhbayar Shagdar","doi":"10.1016/j.jece.2025.115696","DOIUrl":"10.1016/j.jece.2025.115696","url":null,"abstract":"<div><div>To mitigate the most severe impacts of climate change, a fundamental transformation of our energy system from fossil fuels to low-carbon energy sources is imperative and essential for a sustainable future. Among the various conversion technologies, carbon dioxide (CO₂) electrolysis is a promising approach for converting CO₂ to energy-dense chemicals. However, the low-temperature CO₂ electrolysis process is hindered by several challenges, including low energy efficiencies, poor selectivities, low catalytic activity, and stability, ultimately impacting its commercial viability. This has driven the development of high-temperature CO₂ electrolysis in solid oxide electrolysis cells (SOECs), which offers enhanced carbon-oxygen bond activation, higher current densities, and improved energy efficiencies, making it a more viable alternative to low-temperature electrolysis. The present work provides a comprehensive investigation of the CO₂ electrolysis process using SOEC, including a closer examination of the thermodynamic favorability of the process. We have reported novel insights into the critical roles of cathode, anode and electrolyte materials, revealing the opportunities for their enhancement and optimization. Additionally, the pressing issue of electrode degradation and reactivation strategies, as well as the degradation phenomena in the SOEC stack is discussed. Economic analysis is also incorporated to outline the techno-economic feasibility of this technology. Finally, future perspectives are included to highlight the important future considerations and provide a roadmap for this rapidly growing technology. By integrating these key aspects, the present work offers a more complete understanding of CO₂ electrolysis in SOECs and identifies opportunities for future research and development.</div></div>","PeriodicalId":15759,"journal":{"name":"Journal of Environmental Chemical Engineering","volume":"13 2","pages":"Article 115696"},"PeriodicalIF":7.4,"publicationDate":"2025-02-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143357337","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"The comprehensive review of catalysts for catalytic oxidation of volatile organic compounds","authors":"Jingjing Yi ,&nbsp;Jiadong Liu ,&nbsp;Bo Gao ,&nbsp;Longli Bo ,&nbsp;Li Cao ,&nbsp;Mika Sillanpää","doi":"10.1016/j.jece.2025.115691","DOIUrl":"10.1016/j.jece.2025.115691","url":null,"abstract":"<div><div>Volatile organic compounds (VOCs) are an important factor contributing to air pollution and have received significant attention due to their toxicity and severe impact on the environment and human health. Catalytic oxidation technology has been widely recognized as an effective end-of-pipe control method for VOCs, which has been extensively studied in recent years to enhance catalyst activity, stability, and economic benefits. So, this review focuses on summarizing noble metal catalysts, non-noble metal and composite catalysts used in VOCs catalytic oxidation; analyzing factors influencing their catalytic activity and improvement methods; objectively evaluating the catalytic performance and key parameters of these catalysts; discussing the catalytic oxidation mechanism. Based on this comprehensive review, the development routes and strategies of catalysts preparing for VOC catalytic oxidation will be more explicit, while their application scenarios and parameters will be clearer.</div></div>","PeriodicalId":15759,"journal":{"name":"Journal of Environmental Chemical Engineering","volume":"13 2","pages":"Article 115691"},"PeriodicalIF":7.4,"publicationDate":"2025-02-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143357338","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Exploring the impact of Nickel on ceria doped Cobalt catalysts for low-temperature catalytic combustion of methane","authors":"Mirza Belal Beg ,&nbsp;Labeeb Ali ,&nbsp;Suryamol Nambyaruveettil ,&nbsp;Florence H. Vermeire ,&nbsp;Mohammednoor Altarawneh","doi":"10.1016/j.jece.2024.115017","DOIUrl":"10.1016/j.jece.2024.115017","url":null,"abstract":"<div><div>Reducing methane emissions through complete catalytic oxidation at lower temperatures, using efficient and cost-effective catalysts, holds an importance in various industrial and environmental applications. In this study, we developed a series of bimetallic catalysts by incorporating nickel into ceria-doped cobalt oxide at varying loadings. These catalysts were thoroughly characterized to understand the impact of nickel incorporation on the catalytic performance, and subsequently tested for their efficiency in methane oxidation. To gain a comprehensive understanding of the catalysts' properties, a range of characterization techniques was employed, including X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FT-IR), scanning electron microscopy with energy-dispersive spectroscopy (SEM-EDS), nitrogen adsorption-desorption (BET), Raman spectroscopy, hydrogen temperature-programmed reduction (H₂-TPR), and oxygen temperature-programmed desorption (O₂-TPD). These methods provided insights into the physicochemical properties of the catalysts and the influence of nickel on their catalytic activity. The catalysts' performance in complete methane oxidation was evaluated in the range of 200–600°C. Water vapour (1.5 vol%) was introduced into the feed stream to study the impact of water vapour on the catalytic performance. Among the catalysts tested, the 15Co15NiCe catalyst exhibited the highest activity, achieving a <em>T</em>₅₀ value at 389°C. The characterization results revealed that the optimal incorporation of nickel led to an increase in active surface oxygen species, the creation of lattice defects, an enlarged surface area, and enhanced reducibility, all of which contributed to an improved catalytic performance. Kinetic analysis showed that the calculated activation energy aligned with the observed methane oxidation activity trends. Furthermore, the best-performing catalyst demonstrated an exceptional stability over extended reaction times, with stability tests conducted over 12 hours revealing minimal variation in conversion efficiency. Post-reaction characterization of the spent catalyst using thermogravimetric analysis (TGA) and temperature-programmed oxidation (TPO) provided insights into the slight variations observed during the stability tests. The findings from this study pave the way for the development of low-temperature catalytic processes pretinent to catalytic oxidation of methane.</div></div>","PeriodicalId":15759,"journal":{"name":"Journal of Environmental Chemical Engineering","volume":"13 1","pages":"Article 115017"},"PeriodicalIF":7.4,"publicationDate":"2025-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143181250","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}