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Optimization and Modeling of Leaching Parameters Affecting Nickel Dissolution from Lateritic Ore in Eskisehir (Mihaliccik-Yunusemre) Using Box-Behnken Experimental Design 基于Box-Behnken试验设计的Eskisehir (Mihaliccik-Yunusemre)红土矿镍溶出浸出参数优化与建模
Pub Date : 2020-01-01 DOI: 10.37421/jreac.2020.7.263
T. Agacayak, Mohamed T. Ahmed
In this study, optimization and modeling of leaching parameters affecting nickel dissolution from lateritic ore in EskiA…Ÿehir (MihalA„±ccA„±k-Yunusemre) were investigated using Box-Behnken design. Stirring speed (100-400 rpm, temperature (40-80°C), acid concentration (0.1-2 M) and dissolution time (30-180 min) were selected as experimental design parameters. 27 experiments were carried out by Box-Behnken experimental design in Minitab 16.0 program. After leaching experiments, the highest Ni dissolution percentages were obtained as 87.85%. The effective parameters and their interactions in nickel dissolution are described with a mathematical model. The results obtained from the experiments were subjected to ANOVA and multiple regression analysis. The R2 value of the model for nickel dissolution was calculated as 0.980. This showed that the predicted values are in good agreement with the observed values. In addition, three-dimensional response surface and contour graphs of the parameters affecting nickel dissolution efficiency were created and the results were examined.
采用Box-Behnken设计,对影响EskiA…Ÿehir (MihalA“±ccA”±k-Yunusemre)红土矿镍溶出的浸出参数进行了优化和建模研究。实验设计参数为搅拌转速(100-400 rpm)、温度(40-80℃)、酸浓度(0.1-2 M)和溶解时间(30-180 min)。在Minitab 16.0程序中采用Box-Behnken实验设计进行了27次实验。经浸出试验,镍溶出率最高可达87.85%。用数学模型描述了镍溶解的有效参数及其相互作用。对实验结果进行方差分析和多元回归分析。计算镍溶出度模型的R2值为0.980。结果表明,预测值与实测值吻合较好。建立了影响镍溶解效率参数的三维响应面和等值线图,并对结果进行了检验。
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引用次数: 3
Effect of Phytoremediation on PAHs Levels of Agricultural Soil around Mechanic Village Wukari, Nigeria 植物修复对尼日利亚乌卡里机械村农业土壤多环芳烃水平的影响
Pub Date : 2020-01-01 DOI: 10.37421/2380-2391.2020.7.265
Itodo Au, R. Shaato, Wuana Ra, E. Yerima
This study evaluates the PAHs composition in agricultural soils around Mechanic village, Wukari using standard procedures by means of GC-MS. The possible source of the PAHs in the soil was deduced, using the diagnostic ratio analysis for PAH origin. Risk assessment was based on the incremental life cancer risk of PAHs proposed by Provisional Guidance for Quantitative Risk Assessment of the United States Environmental Protection Agency. Effect of phyto-remediation using Zea mays inter-planted with Striga hermonthica (SMV-MS), Zea mays alone (SMV-M), Zea mays inter-planted with Striga hermonthica alongside the application of fertilizer (SMV-MSF) and Zea mays alone alongside fertilizer application (SMV-MF). The result reveals that the PAHs composition based on ring prevalence in agricultural soils around Mechanic village Wukari was in the order Σ5 >Σ6 >Σ4 >Σ3 >Σ2 ring. Dibenz [a,h] anthracene 4.52 μg/kg (39.09%) has the highest percentage abundance but was less than the 100 μg/kg and 700 μg/kg Canadian soil quality guideline for agricultural and commercial layout while acenaphthene 0.111 μg/kg (0.90%) was the least abundant. The source of the PAHs in the soil was basically pyrogenic based on the diagnostic ratio analysis while phytoremediation of the soil using Zea mays inter-planted with Striga hermonthica significantly reduce the PAHs content of the soil.
采用气相色谱-质谱联用技术,对乌卡里梅克克村周边农业土壤中多环芳烃的组成进行了标准测定。利用多环芳烃来源诊断率分析,推断了土壤中多环芳烃的可能来源。风险评估依据美国环境保护署《定量风险评估临时指南》提出的多环芳烃终生致癌增量风险。间作玉米(SMV-MS)、单独间作玉米(SMV-M)、间作玉米(SMV-MSF)和单独间作玉米(SMV-MF)的植物修复效果结果表明:以环流行度为基础的机械村周边农业土壤多环芳烃组成依次为Σ5 >Σ6 >Σ4 >Σ3 >Σ2环。二苯并[a,h]蒽4.52 μg/kg(39.09%)丰度最高,但低于加拿大农业和商业布局土壤质量指标100 μg/kg和700 μg/kg,苊0.111 μg/kg(0.90%)丰度最低。诊断比分析表明,土壤中多环芳烃的来源基本为热原源,而玉米间种金刺草对土壤进行植物修复后,土壤中多环芳烃含量显著降低。
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引用次数: 2
Editorial Note on Climate Change 关于气候变化的社论说明
Pub Date : 2020-01-01 DOI: 10.37421/2380-2391.2020.7.284
C. Mounica
Environmental change is currently essentially difficult to overlook. The temperature arrived at a record-breaking 90 degrees in Anchorage this late spring and an uncommon 108 degrees in Paris
目前,环境变化基本上是难以忽视的。今年春末,安克雷奇的气温达到了破纪录的90华氏度,巴黎则达到了罕见的108华氏度
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引用次数: 0
Editorial Note on Fluid Dynamics of Disease Transmission 疾病传播的流体动力学编者按
Pub Date : 2020-01-01 DOI: 10.37421/2380-2391.2020.7.286
C. Mounica
The unfurling COVID sickness 2019 (COVID-19) pandemic and the new episodes of serious intense respiratory disorder (SARS), center east respiratory condition (MERS), and exceptionally pathogenic flu, for example, H5N1 and H1N1, just as rising anti-infection obstruction, show that we live in a period of recently arising and reappearing irresistible illnesses that influence billions around the world.
2019年冠状病毒病(COVID-19)大流行和新发作的严重急性呼吸系统疾病(SARS)、中东呼吸综合征(MERS)以及H5N1和H1N1等异常致病性流感,以及不断上升的抗感染障碍,表明我们生活在一个最近出现和再次出现的不可抗拒疾病的时代,这些疾病影响着全球数十亿人。
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引用次数: 0
How to Find a Journal’s Aims and Scope for Your Research 如何为你的研究找到期刊的目标和范围
Pub Date : 2020-01-01 DOI: 10.37421/2380-2391.2020.7.268
Mounica Chinthala
When choosing a journal to submit your article to, it’s important to make sure it’s the right fit. To help with this, every journal on Environmental Analytical Chemistry Online has an aims and scope statement. This is a powerful resource that you can use to choose the best journal for your research.
在选择要投稿的期刊时,确保它是合适的是很重要的。为了做到这一点,环境分析化学在线上的每个期刊都有一个目标和范围声明。这是一个强大的资源,你可以用它来为你的研究选择最好的期刊。
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引用次数: 0
Occurrence and Remediation of Polychlorinated Biphenyls in Soil from Jos, Plateau State, Nigeria 尼日利亚乔斯高原州土壤中多氯联苯的发生与修复
Pub Date : 2020-01-01 DOI: 10.37421/2380-2391.2020.7.277
E. Ibrahim, Sa John, S. GushitJohn, Dalen Mb, Gube-Ibrahim Ma
Investigation into occurrence and Remediation of Polychlorinated biphenyls in soil from Jos, Plateau State Nigeria was carried out. The polychlorinated biphenyls in the soil was extracted with 40ml hexane-acetone mixture (1:1) in ultrasonic bath for 30 minutes and cleaned with column chromatography packed with silica gel. The polychlorinated biphenyls were quantified using Agilent 6975 Gas chromatography Mass Spectrophotometer with the following results: PCB 18 (0.71), PCB 20 (0.37), PCB 28 (0.38), PCB 29 (0.38), PCB 44 (0.42), PCB 52 (0.66), PCB 101 (0.61), PCB 105 (0.17), PCB 137 (0.64), PCB 142 (0.33), PCB 153 (0.42), PCB 170 (0.13) and PCB 180 (0.21) all in mg/kg. Remediation with Moringa seed results in the followings; PCB 20 (0.28), PCB 28 (0.28), PCB 29 (0.28), PCB 52 (0.30), PCB 101 (0.18), PCB 143 (0.91) while the other congeners were completely removed. The Moringa seed powder results completely removed the PCBs sake PCB 44. The effectiveness of the powder as compared with the seed in the removal of the PCBs might be attributed to the increased surface area of the seed powder providing for better interaction with the contaminated soil. Whereas the results from the use of activated carbon only removed PCB 105 completely and reduced the concentrations of other congeners as follows: PCB 18 (0.04), PCB 20 (0.011), PCB 28 (0.019), PCB 29 (0.019), PCB 44 (0.021), PCB 52 (0.33), PCB 101 (0.031), PCB137 (0.032), PCB 142 (0.017), PCB 153 (0.021), PCB 170 (0.007) and PCB 180 (0.011) all in mg/kg. The result suggests that Moringa seed powder could possibly serve as an excellent means of remediation for Polychlorinated biphenyls in contaminated soil.
对尼日利亚高原州乔斯市土壤中多氯联苯的发生及修复进行了调查。用40ml正己烷-丙酮混合物(1:1)在超声浴中提取土壤中的多氯联苯30分钟,用硅胶填充柱层析法清洗。采用Agilent 6975气相色谱质谱仪对多氯联苯进行定量分析,结果为:PCB 18(0.71)、PCB 20(0.37)、PCB 28(0.38)、PCB 29(0.38)、PCB 44(0.42)、PCB 52(0.66)、PCB 101(0.61)、PCB 105(0.17)、PCB 137(0.64)、PCB 142(0.33)、PCB 153(0.42)、PCB 170(0.13)、PCB 180(0.21),单位均为mg/kg。辣木籽修复效果如下;PCB 20 (0.28), PCB 28 (0.28), PCB 29 (0.28), PCB 52 (0.30), PCB 101 (0.18), PCB 143(0.91),而其他同系物则被完全删除。辣木籽粉的检测结果完全去除了多氯联苯。与种子相比,粉末在去除多氯联苯方面的有效性可能归因于种子粉末的表面积增加,从而更好地与受污染的土壤相互作用。而使用活性炭的结果仅完全去除了PCB 105,并降低了其他同系物的浓度:PCB 18 (0.04), PCB 20 (0.011), PCB 28 (0.019), PCB 29 (0.019), PCB 44 (0.021), PCB 52 (0.33), PCB 101 (0.031), PCB137 (0.032), PCB 142 (0.017), PCB 153 (0.021), PCB 170(0.007)和PCB 180(0.011),均为mg/kg。结果表明,辣木籽粉有可能作为修复土壤中多氯联苯的优良手段。
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引用次数: 1
Editorial Note on Environmental Pollution 环境污染社论
Pub Date : 2020-01-01 DOI: 10.37421/2380-2391.2020.7.274
C. Mounica
Environmental pollution is arriving at stressing extents around the world. Urbanization and industrialization alongside economic development have led to increase in energy consumption and waste discharges.
世界各地的环境污染都达到了令人紧张的程度。随着经济的发展,城市化和工业化导致了能源消耗和废物排放的增加。
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引用次数: 0
Editorial Note on Environmental Organic Chemistry: How Might We Avoid Regrettable Substitution 环境有机化学:我们如何避免令人遗憾的替代
Pub Date : 2020-01-01 DOI: 10.37421/2380-2391.2020.7.275
C. Mounica
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引用次数: 0
Source Estimation of Oil Spill Accident in Flood Situation using Gas Chromatography Olfactometry (GC-O) 用气相色谱-嗅觉法估算洪水溢油事故来源
Pub Date : 2020-01-01 DOI: 10.5985/jec.30.29
Koga Yuki, Ide Kaito, Matsumoto Misato, Higuchi Taiki, Ichiba Masayoshi, Ueno Daisuke
Oil spill accident from steel mill was caused by flood in August 2019 in Saga Prefecture, Japan. Since “ oil odor prob-lem ” was happened in disaster area, the source estimation of oil odor was conducted using sensory evaluation and Gas Chromatography-Olfactometry (GC-O). By the sensory evaluation, the odor in disaster area was assigned as “ odor of oil and sewage ” . To know in detail of the oil odor, environmental samples (oil absorption sheets) were collected and sensory compared with several fuel oils. As the result of evaluation, oil odor in 7 days after accident consisted of diesel oil (with / or kerosene) instead of spilled oil from steel mill. This result suggested that those fuel oils were also spilled from various sources (heating fuel for house and agriculture) around this disaster are during this flood. On the other hand, the oil absorption sheets in 12 days after accident did not showed odor of those fuel oils, and it showed weak odor of spilled oil from steel mill. It could be due to that these fuel oils spilled were evaporated within a few days under the summer weather, but spilled oil from steel mill which had heavier property was kept in environment.
2019年8月,日本佐贺县发生了因洪水导致的钢铁厂溢油事故。针对灾区发生的“油臭问题”,采用感官评价和气相色谱-嗅觉(GC-O)相结合的方法对油臭源进行了估计。通过感官评价,确定灾区气味为“油污气味”。为了详细了解油的气味,收集了环境样品(吸油片),并与几种燃料油进行了感官比较。经评价,事故发生后7天内的油味主要是柴油(含/或煤油),而不是炼钢厂的溢油。这一结果表明,这些燃料油也是在这次洪水期间从灾难周围的各种来源(房屋和农业的取暖燃料)泄漏的。另一方面,事故发生后12天的吸油片没有这些燃料油的气味,并且有轻微的钢厂溢油气味。这可能是由于这些泄漏的燃料油在夏季的天气下在几天内就蒸发了,但从属性较重的钢铁厂泄漏的油被保存在环境中。
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引用次数: 1
The Therapeutic Development for COVID-19 COVID-19治疗进展
Pub Date : 2020-01-01 DOI: 10.37421/2380-2391.2020.7.272
Shihori Tanabe
The importance of environmental chemistry has been increasing in the era of industrial advancement. It is also one of the critical issues to consider the chemical compounds and nano-particle chemistry in the environment. The current coronavirus disease 2019 (COVID-19) situation in all over the world has facilitated the development of anti-viral drugs
在工业进步的时代,环境化学的重要性与日俱增。考虑环境中的化合物和纳米粒子化学也是关键问题之一。当前,全球新型冠状病毒病(COVID-19)疫情为抗病毒药物的研发提供了便利
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引用次数: 2
期刊
Journal of environmental analytical chemistry
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