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Fire Safety Research Institute Materials and Products database—A resource to support fire modeling 消防安全研究所材料和产品数据库--支持火灾建模的资源
IF 1.9 4区 工程技术 Q2 Engineering Pub Date : 2024-04-25 DOI: 10.1177/07349041241235566
M. McKinnon, Grayson T. Bellamy
For decades, there has been a need in the fire safety science community for a reliable source of material properties and standard fire test data to accurately represent solid materials in fire models. The project described herein has made advancements in experimental data collection and property determination for a multitude of materials commonly encountered in the built environment for the purpose of making the data easily accessible and to elevate the base knowledge and tools available for all model practitioners and investigators. This article includes a description of the experimental methods, procedures, and estimated uncertainty in the measurements that have been adopted to collect the data necessary to describe common materials in the most advanced comprehensive pyrolysis models. A case study is provided in which all the experiments to characterize polycarbonate are described, analytical procedures and derived properties are presented, and validation of the properties against experimental data is presented.
几十年来,消防安全科学界一直需要一个可靠的材料特性和标准火灾测试数据来源,以便在火灾模型中准确表示固体材料。本文介绍的项目在实验数据收集和属性确定方面取得了进展,适用于建筑环境中常见的多种材料,目的是使数据易于获取,并为所有模型从业人员和研究人员提供更多的基础知识和工具。本文介绍了在最先进的综合热解模型中收集描述常见材料所需的数据所采用的实验方法、程序和测量的估计不确定性。文章提供了一个案例研究,其中描述了表征聚碳酸酯的所有实验,介绍了分析程序和推导性质,并根据实验数据对性质进行了验证。
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引用次数: 0
Thermal degradation of self-contained breathing apparatus facepiece lenses under radiant thermal loads 辐射热负荷下自给式呼吸器面罩镜片的热降解
IF 1.9 4区 工程技术 Q2 Engineering Pub Date : 2024-04-25 DOI: 10.1177/07349041241227921
Richard M. Kesler
The self-contained breathing apparatus is one of the most critical components of the firefighting personal protective ensemble providing protection from potentially toxic gases and products of combustion. Three models of self-contained breathing apparatus facepiece lenses meeting various editions of national standards were exposed to radiant thermal loads of 5, 10, 15, and 20 kW/m2 until thermal degradation resulted in hole formation or the test duration reached 30 min. Thermal damage was documented as time to crazing, bubbling, and hole formation. Temperature was recorded within the facepiece. There were significant differences in times to thermal damage between lenses. The facepiece lens model meeting the 2013 edition of National Fire Protection Association 1981 had significantly longer times to thermal degradation than those meeting older editions of the standard. Maximum temperatures were higher in the facepiece model meeting the 2013 edition of National Fire Protection Association 1981, likely because of the extended time the radiant load was applied.
自给式呼吸器是消防员个人防护装备中最关键的部件之一,可提供对潜在有毒气体和燃烧产物的防护。将符合不同版本国家标准的三种型号的自给式呼吸器面罩镜片暴露在 5、10、15 和 20 kW/m2 的辐射热负荷下,直到热降解导致孔洞形成或测试持续时间达到 30 分钟。热损伤记录为裂纹、气泡和孔洞形成的时间。面罩内的温度被记录下来。不同镜片的热损坏时间存在明显差异。符合美国国家防火协会 1981 年标准 2013 版的面罩镜片型号的热降解时间明显长于符合旧版标准的镜片型号。符合美国国家防火协会 1981 年版 2013 年版标准的面罩型号的最高温度更高,这可能是因为施加辐射负荷的时间更长。
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引用次数: 0
Durability and performance of wood flour/polyethylene composites containing fire retardants after weathering via ASTM D2565 含有阻燃剂的木粉/聚乙烯复合材料经 ASTM D2565 老化后的耐久性和性能
IF 1.9 4区 工程技术 Q2 Engineering Pub Date : 2024-03-29 DOI: 10.1177/07349041241237536
M. Dietenberger, Nicole M. Stark, Charles R. Boardman
Wood–plastic composites are composite materials consisting of wood particles, thermoplastic polymer, and small amounts of other performance additives to increase performance in exterior construction applications such as decking and siding. Three best-performing fire retardants, determined from a previous study, which were brominated, magnesium hydroxide, and ammonium polyphosphate, were selected for this weathering study and more detailed analysis with color analysis, thermogravimetric analysis/differential scanning calorimetry, and the cone calorimeter. With the rapid surface heating condition at cone calorimeter irradiance of 50 kW m−2, modest surface leaching of fire retardant was detected as caused by weathering via increased first peak heat-release rate and reduced time to ignition values. Otherwise, the weathering had minimal effect on the remaining heat-release rate profile, and results confirmed ammonium polyphosphate as top performing fire retardant, even better than Ipe wood, with magnesium hydroxide and brominated slightly worse than Ipe. This suggests that 35% high-density polyethylene content reduced fire retardant bulk leaching.
木塑复合材料是由木质颗粒、热塑性聚合物和少量其他高性能添加剂组成的复合材料,可提高露台和护墙板等外部建筑应用的性能。本次风化研究选择了之前研究中确定的三种性能最好的阻燃剂(溴化物、氢氧化镁和聚磷酸铵),并通过颜色分析、热重分析/差示扫描量热仪和锥形量热仪进行了更详细的分析。在锥形量热仪辐照度为 50 kW m-2 的快速表面加热条件下,通过增加第一峰值热释放率和减少点火时间值,检测到风化导致的阻燃剂的适度表面沥滤。除此之外,风化对剩余热释放率曲线的影响微乎其微,结果证实聚磷酸铵是性能最好的阻燃剂,甚至优于柚木,氢氧化镁和溴化柚木稍差。这表明,35% 的高密度聚乙烯含量减少了阻燃剂的大量沥滤。
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引用次数: 0
Analysis of fire extinguishing performance and mechanisms in transformer oil pool fires by large-scale compressed nitrogen foam: Impact of different nozzle pressures 大型压缩氮泡沫在变压器油池火灾中的灭火性能和机理分析:不同喷嘴压力的影响
IF 1.9 4区 工程技术 Q2 Engineering Pub Date : 2024-03-26 DOI: 10.1177/07349041241238151
Fengju Shang, Jiaqing Zhang, Taiyun Zhu, Wen Su, Kaiyuan Li, Yanyan Zou, Yi Guo
This article investigates the suppression of transformer oil pool fires using compressed nitrogen aqueous film-forming foam extinguishing agents with varying nozzle pressures (0.1–0.4 MPa), and a comprehensive analysis of fire extinguishing behavior and resistance to re-ignition was conducted. The research findings indicate that at a nozzle pressure of 0.4 MPa, there is a significant enhancement in fire extinguishing efficiency, with a reduction in extinguishing time by 15.0%–29.2%, and an increase in resistance to re-ignition by 32.2%–48.2%, making it the optimal choice. In comparison to the 0.1 MPa condition, the maximum instantaneous emissions of CO and SO2 at 0.4 MPa are only 66.7%. The interaction of various effects, such as atomization, results in a significant enhancement of flame intensification and fire extinguishing effects when compressed nitrogen aqueous film-forming foam is sprayed at high nozzle pressures. The study provides valuable insights for firefighters in the practical use of foam extinguishing agents.
本文研究了使用不同喷嘴压力(0.1-0.4 兆帕)的压缩氮水成膜泡沫灭火剂扑灭变压器油池火灾的情况,并对灭火行为和抗复燃能力进行了综合分析。研究结果表明,喷嘴压力为 0.4 兆帕时,灭火效率显著提高,灭火时间缩短 15.0%-29.2%,抗复燃能力提高 32.2%-48.2%,是最佳选择。与 0.1 MPa 条件相比,0.4 MPa 条件下 CO 和 SO2 的最大瞬时排放量仅为 66.7%。在高喷嘴压力下喷射压缩氮水成膜泡沫时,雾化等各种效应的相互作用导致火焰强化和灭火效果显著增强。这项研究为消防人员实际使用泡沫灭火剂提供了宝贵的启示。
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引用次数: 0
A probabilistic analysis of non-military hangar fire protection systems 非军用机库防火系统的概率分析
IF 1.9 4区 工程技术 Q2 Engineering Pub Date : 2024-03-16 DOI: 10.1177/07349041241231206
John T Wade, Bhushan Lohar, Kari Lippert, Rob Cloutier, Sean Walker, Olabode Olanipekun
The United States Air Force (USAF) dictates policy for foam fire suppression systems in their hangars. In November 2021, the USAF issued a Sundown Policy for Foam Fire Suppression Systems. The National Fire Protection Association’s Standard on Aircraft Hangars, NFPA 409 serves a similar function. This article uses a real-world installation and analysis of the hangar fire protection scheme stipulated in the USAF Sundown Policy as compared to an installation in compliance with NFPA 409. Applying the Poisson process for a zero-inflated probability distribution, the data referenced for the event tree were evaluated and thereafter validated. The analysis shows that the installation of hangar fire protection stipulated in the USAF Sundown Policy achieves a better performance for the fire protection system than an installation in compliance with NFPA 409, insofar as the risk analysis is concerned. Second, the installation of a fire protection system that complies with the requirements of NFPA 409 fails to achieve the basic probabilistic performance promulgated by the International Code Council’s Performance Code (ICCPC). The validation also demonstrated that the scenario involving the accidental discharge of fire foam was significantly more likely to occur compared to that involving only fire occurrences.
美国空军(USAF)规定了机库泡沫灭火系统的政策。2021 年 11 月,美国空军发布了《泡沫灭火系统日落政策》。美国国家防火协会的飞机库标准 NFPA 409 也具有类似功能。本文采用实际安装情况,分析了美国空军 "日落政策 "规定的机库防火方案与符合 NFPA 409 标准的安装情况的比较。应用零膨胀概率分布的泊松过程,对事件树的参考数据进行了评估和验证。分析表明,就风险分析而言,美国空军 "日落政策 "中规定的机库防火装置比符合 NFPA 409 标准的防火系统具有更好的性能。其次,安装符合 NFPA 409 要求的防火系统无法达到国际规范委员会性能规范 (ICCPC) 颁布的基本概率性能。验证结果还表明,与仅涉及火灾发生的情况相比,涉及消防泡沫意外喷射的情况发生的可能性要大得多。
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引用次数: 0
Experimental and numerical investigation of a single-tree fire 单树火灾的实验和数值研究
IF 1.9 4区 工程技术 Q2 Engineering Pub Date : 2024-02-05 DOI: 10.1177/07349041231218967
Gilbert Accary, Joseph Darido, Dominique Morvan, Leo Schneider, Benjamin Betting, Nicolas Frangieh, Sofiane Meradji, Albert Simeoni
The physics and the dynamics of static fires were studied numerically and experimentally by burning single Douglas fir trees. The mass loss rate was recorded, as well as the radiative heat flux and temperature at different positions. The numerical simulations were carried out using a fully physical CFD code (FireStar3D), and two levels of description were considered: in the first one, the vegetation was represented using a single fuel-type; in the second, four fuel-types were considered. The numerical results were compared to the experimental data for fuel moisture content of 14% and 50%. The results clearly show the advantage of considering several fuel-types to represent the tree; nevertheless, compared to the experiments, faster tree burning dynamics is obtained by simulation. The role played by the ignition process was also analysed numerically, highlighting the sensitivity of the tree burning dynamics to the ignition protocol.
通过燃烧单棵花旗松,对静态火灾的物理和动力学进行了数值和实验研究。记录了质量损失率以及不同位置的辐射热通量和温度。数值模拟使用完全物理的 CFD 代码(FireStar3D)进行,并考虑了两个层次的描述:第一个层次使用单一燃料类型表示植被;第二个层次考虑了四种燃料类型。数值结果与燃料含水量为 14% 和 50% 的实验数据进行了比较。结果清楚地表明,考虑几种燃料类型来表示树木是有优势的;然而,与实验相比,模拟得到的树木燃烧动态更快。此外,还对点火过程所起的作用进行了数值分析,突出了树木燃烧动力学对点火方案的敏感性。
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引用次数: 0
Toward improved thermal exposure classes for structural firefighters 改进结构消防员的热暴露等级
IF 1.9 4区 工程技术 Q2 Engineering Pub Date : 2024-01-18 DOI: 10.1177/07349041231222852
C. Weinschenk, Holli Knight, John W Regan
In the early 1970s, there was an initial effort to quantify the conditions under which firefighters are expected to perform. Harvey Utech led this endeavor by defining three levels of thermal exposure—routine, ordinary, and emergency—which were characterized by combining a range of air temperatures and radiative heat fluxes. In the last half-century, there has been a concerted scientific effort to further understand the conditions to which firefighters are exposed during structural firefighting. Research has been conducted on the resiliency of turnout gear and facepiece lenses, the thermal conditions observed during a structure fire, and the impact of firefighter tactics such as ventilation and suppression. The authors synthesize the results from these research areas to update the original thermal classifications to six categories of exposure—routine, Ordinary I, Ordinary II, Emergency I, Emergency II, and Emergency III—which are more representative of the operating environment and protective equipment thresholds that firefighters should be aware of during firefighting operations and tactical decision-making.
20 世纪 70 年代初,人们开始努力量化消防员的工作条件。哈维-乌泰奇(Harvey Utech)领导了这项工作,他定义了三个级别的热暴露--常规、普通和紧急--这些级别的特点是结合了一系列空气温度和辐射热通量。在过去的半个世纪中,科学界一直致力于进一步了解消防员在结构性火灾扑救过程中的暴露条件。对消防员的防护装备和面罩镜片的弹性、结构火灾中观察到的热条件以及消防员战术(如通风和压制)的影响进行了研究。作者综合了这些研究领域的成果,将最初的热分类更新为六类暴露--常规、普通 I、普通 II、紧急 I、紧急 II 和紧急 III--这六类暴露更能代表消防员在灭火行动和战术决策中应注意的操作环境和防护装备阈值。
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引用次数: 0
Block it and rock it: Smoke suppressants that form a protective layer in PA 6.6 阻挡它,震撼它:在 PA 6.6 中形成保护层的烟雾抑制剂
IF 1.9 4区 工程技术 Q2 Engineering Pub Date : 2024-01-13 DOI: 10.1177/07349041231220250
S. M. Goller, B. Schartel, Simone Krüger
To ensure fire safety, polymers are filled with flame retardants and smoke suppressants. To meet the highest requirements, it is essential to understand the decomposition of those polymeric materials. This study reveals interactions between polymer, smoke suppressants, and flame retardants, and discusses their impact on the materials’ flame retardancy, smoke emission, smoke toxicity, and particle emission in conventional loadings to provide deeper general understanding. Low melting oxide glass, melem, spherical silica, sepiolite, melamine polyphosphate, and boehmite in an aluminum diethylphosphinate flame-retarded polyamide 6.6 were investigated. All smoke suppressants improve the protective layer and act as an adjuvant. Silica and melem performed best under forced flaming conditions. Spherical silica reduces the peak of heat release rate by 39% and the total heat evolved by 14%, whereas 10 wt% melem lowers the total smoke production by 41%. Melem alters the mode of action of aluminum diethylphosphinate from gas to more condensed phase activity. This change reduces flame inhibition and hence smoke toxicity, but further improves the protective layer due to charring reactions in the decomposition mechanism. In addition, the sizes of the smoke particles decrease because of the prolonged time in the pyrolytic zone. This study highlights that interactions between polymer, flame retardants, and smoke suppressants can significantly determine the smoking and burning behavior.
为确保防火安全,聚合物中添加了阻燃剂和烟雾抑制剂。为了达到最高要求,了解这些聚合物材料的分解过程至关重要。本研究揭示了聚合物、抑烟剂和阻燃剂之间的相互作用,并讨论了它们在常规负载下对材料的阻燃性、烟雾排放、烟雾毒性和颗粒排放的影响,以提供更深入的总体认识。研究了二乙基膦酸铝阻燃聚酰胺 6.6 中的低熔点氧化物玻璃、melem、球形二氧化硅、sepiolite、三聚氰胺聚磷酸盐和沸石。所有抑烟剂都能改善保护层并起到辅助作用。在强制燃烧条件下,二氧化硅和melem 的性能最佳。球形二氧化硅可将热释放率峰值降低 39%,总热量降低 14%,而 10 wt%的 Melem 可将总烟雾产生量降低 41%。Melem 改变了二乙基膦酸铝的作用模式,使其从气相活性转变为更多的凝聚相活性。这种变化降低了火焰抑制作用,从而降低了烟雾毒性,但由于分解机制中的炭化反应,进一步改善了保护层。此外,由于在热解区的时间延长,烟雾颗粒的大小也会减小。这项研究表明,聚合物、阻燃剂和烟雾抑制剂之间的相互作用可在很大程度上决定烟雾和燃烧行为。
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引用次数: 0
An assessment of recent thermal radiation model performance for propane gas fire experiments 丙烷气火实验热辐射模型最新性能评估
IF 1.9 4区 工程技术 Q2 Engineering Pub Date : 2024-01-13 DOI: 10.1177/07349041231222010
Michael Chong Vui San, Mohd Zahirasri Mohd Tohir, M. Spearpoint, S. Saadon, A. R. Abu Talib
In this article, the performance of five radiation models is investigated, including one conventional radiation model, that is, single-point source model, as well as four recently developed models, that is, a weighted multipoint source model, a cuboid flame model, a multicuboid flame model and a multicylinder flame model. The models are assessed in terms of the height of a target above flame base, the horizontal distance of target from flame source, heat release rate and size of burner. The estimations of the theoretical models are compared with propane-based experimental data with heat release rate ranging from 100 to 300 kW and assessed through numerical and graphical analysis. From the results obtained, the single-point source model outperformed the recently developed radiation models in estimating radiant heat received by an object located at a distance from the fire source, albeit it does exhibit some sensitivity to modifications in input parameters.
本文研究了五种辐射模型的性能,包括一种传统辐射模型,即单点源模型,以及四种最新开发的模型,即加权多点源模型、立方体火焰模型、多立方体火焰模型和多圆柱体火焰模型。这些模型根据目标在火焰底部上方的高度、目标与火焰源的水平距离、热释放率和燃烧器的大小进行评估。理论模型的估计值与基于丙烷的实验数据进行了比较,实验数据的热释放率从 100 千瓦到 300 千瓦不等,并通过数值和图形分析进行了评估。从获得的结果来看,单点源模型在估算距离火源较远的物体所接收的辐射热方面优于最近开发的辐射模型,尽管它对输入参数的修改表现出一定的敏感性。
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引用次数: 0
Radiative ignition properties of food grains and surface temperatures at ignition 粮食的辐射点火特性和点火时的表面温度
IF 1.9 4区 工程技术 Q2 Engineering Pub Date : 2024-01-02 DOI: 10.1177/07349041231220840
A.B.C. Oguaka, Natalia Flores-Quiroz, Richard Walls
Fire safety of food grains in storage, transport and processing facilities requires knowledge of their ignition properties some of which have been determined in this study. Cowpea, lentils, millet, soybean, unshelled peanut, flax (linseed), sunflower, shelled peanut and sesame, at 10% moisture content were studied. A cone calorimeter heater was used to impose radiative heat fluxes of 25, 35 and 47.5 kW/m2 on the food grains to determine the time to piloted ignition concurrently with the surface temperature at ignition ( Ts,ig). Ignition temperatures ( Tig) were calculated from experimentally determined critical heat fluxes. The thermal response parameter and thermal inertia ([Formula: see text]) essential for the characterization of the ignition of the food grains were also calculated. Thermal response parameter appears to be best suited for distinguishing the ignitability of the food grains. Ignition temperatures range between 239°C and 305°C, while thermal response parameter varies between 261 and 565 kWs0.5/m2. Small particle-sized grains showed higher ignitability.
粮食在储存、运输和加工设施中的防火安全要求了解其燃烧特性,本研究已确定了其中一些特性。研究了含水量为 10% 的豇豆、扁豆、小米、大豆、去壳花生、亚麻(亚麻籽)、葵花籽、去壳花生和芝麻。使用锥形量热计加热器对粮食施加 25、35 和 47.5 kW/m2 的辐射热流量,以确定引燃时间和点火时的表面温度 ( Ts,ig)。点火温度 ( Tig) 是根据实验确定的临界热通量计算得出的。此外,还计算了对确定食物颗粒点火特性至关重要的热反应参数和热惯性([公式:见正文])。热反应参数似乎最适合用来区分粮食的可燃性。点燃温度在 239°C 至 305°C 之间,而热反应参数在 261 至 565 kWs0.5/m2 之间。小颗粒大小的谷物显示出更高的可燃性。
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引用次数: 0
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Journal of Fire Sciences
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