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Simulation of an Innovative Startup Phase for SOFC Hybrid Systems Based on Recompression Technology: Emulator Test Rig 基于再压缩技术的SOFC混合动力系统创新启动阶段仿真:仿真试验台
Pub Date : 2015-08-01 DOI: 10.1115/1.4031106
U. Damo, M. L. Ferrari, A. Turan, A. Massardo
This paper presents a novel startup approach for solid oxide fuel cell (SOFC) hybrid systems (HSs) based on recompression technology. This startup approach shows a novel method of managing a complete plant to obtain better performance, which is always also a difficult task for equipment manufactures. The research activities were carried out using the HS emulator rig located in Savona (Italy) and developed by the Thermochemical Power Group (TPG) of the University of Genoa. The test rig consists of three integrated technologies: a 100 kWe recuperated microturbine modified for external connections, a high temperature modular vessel necessary to emulate the dimensions of an SOFC stack, and, for air recompression, a turbocharger necessary to increase fuel cell pressure (using part of the recuperator outlet flow) as required for efficiency increase and to manage the cathodic recirculation. It was necessary to develop a theoretical model in order to prevent abnormal plant startup conditions as well as motivated by economic considerations. This transient model of the emulator rig was developed using Matlab®-Simulink® environment to study the time-dependent (including the control system aspects) behavior during the entire system (emulator equipped with the turbocharger) startup condition. The results obtained were able to demonstrate that the HS startup phase can be safely managed with better performance developing a new control logic. In detail, the startup phase reported in this paper shows that all important parameters were always inside acceptable operating zones (surge margin kept above 1.1, turbine outlet temperature (TOT), and fuel flow maintained lower than 918.15 K and 7.7 g/s, respectively).
提出了一种基于再压缩技术的固体氧化物燃料电池(SOFC)混合动力系统启动方法。这种启动方法展示了一种管理完整工厂以获得更好性能的新方法,这也是设备制造商一直面临的难题。研究活动是利用位于萨沃纳(意大利)的HS模拟器进行的,该模拟器由热那亚大学的热化学动力集团(TPG)开发。该试验台由三个集成技术组成:一个用于外部连接的100千瓦回热式微型涡轮机,一个模拟SOFC堆尺寸所需的高温模块化容器,以及一个用于空气再压缩的涡轮增压器,该涡轮增压器需要增加燃料电池压力(使用回热器出口流量的一部分),以提高效率并管理阴极再循环。从经济角度考虑,同时为了防止装置异常启动,有必要建立一个理论模型。利用Matlab®-Simulink®环境开发了仿真平台的瞬态模型,以研究整个系统(配备涡轮增压器的仿真器)启动条件下的时间依赖性(包括控制系统方面)行为。研究结果表明,开发了一种新的控制逻辑,可以对HS启动阶段进行安全管理,并具有更好的性能。从本文报道的启动阶段来看,所有重要参数始终在可接受的工作范围内(喘振裕度保持在1.1以上,涡轮出口温度(TOT)保持在918.15 K以下,燃油流量保持在7.7 g/s以下)。
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引用次数: 4
Triple-Layer Control System for Molten Carbonate Fuel Cell–Gas Turbine Hybrid System 熔融碳酸盐燃料电池-燃气轮机混合系统的三层控制系统
Pub Date : 2015-08-01 DOI: 10.1115/1.4031169
J. Milewski, P. Biczel, M. Kłos
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引用次数: 3
The Effect of Nonuniform Under-Rib Convection on Reactant and Liquid Water Distribution in Proton Exchange Membrane Fuel Cells 非均匀肋下对流对质子交换膜燃料电池中反应物和液态水分布的影响
Pub Date : 2015-08-01 DOI: 10.1115/1.4030514
P. Jithesh, T. Sundararajan, Sarit K. Das
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引用次数: 4
Effect of Rate on Pulsed Laser Deposition of Yttria-Stabilized Zirconia Electrolyte Thin Films for SOFCs 速率对脉冲激光沉积氧化钇稳定氧化锆薄膜的影响
Pub Date : 2015-06-01 DOI: 10.1115/1.4029423
T. Mukai, T. Fujita, S. Tsukui, KEN-ICHI Yoshida, M. Adachi, K. Goretta
Yttria-stabilized zirconia (YSZ) thin films were deposited by pulsed laser deposition (PLD) at laser repetition frequencies of 10–50 Hz. Controlling the laser repetition frequency can achieve high deposition rate of YSZ, but high deposition rate at high laser repetition frequency can adversely affect the crystallinity of the resulting film. In the present work, X-ray diffraction (XRD) of YSZ thin films deposited at 10–50 Hz unexpectedly indicated no significant differences. Well-crystallized YSZ thin films were obtained for all laser repetition frequencies. This result may be due to a sufficient substrate temperature of 1000 K during processing. The oxide-ion conductivity of each thin film was comparable to that of bulk YSZ. Only minor differences in Y2O3 content, residual stress, grain size, and grain-boundary width were observed among the films. We concluded that similar quality YSZ thin films were obtained at all deposition frequencies. Oxide-ion conductivity was affected by the temperature at which the substrate was deposited. The YSZ thin films deposited at 900 K and 1000 K showed similar oxide-ion conductivity and films deposited at 800 K showed lower oxide-ion conductivity. This difference could perhaps be due to narrow grain-boundary width. The YSZ thin film with highest oxide-ion conductivity was fabricated at an intermediate substrate temperature of 900 K with a deposition rate of 86 nm·min−1 at 50 Hz, without additional high-temperature annealing greater than 1273 K. The YSZ growth rates were faster than the rates for other gas-phase methods such as midfrequency and DC sputtering.
采用脉冲激光沉积(PLD)技术,在10 ~ 50 Hz的激光重复频率下沉积钇稳定氧化锆(YSZ)薄膜。控制激光重复频率可以实现YSZ的高沉积速率,但高激光重复频率下的高沉积速率会对所得膜的结晶度产生不利影响。在本工作中,在10-50 Hz下沉积的YSZ薄膜的x射线衍射(XRD)出乎意料地没有显示出显著差异。在所有激光重复频率下均获得结晶良好的YSZ薄膜。这一结果可能是由于加工过程中衬底温度达到1000 K。各薄膜的氧化离子电导率与体YSZ相当。在Y2O3含量、残余应力、晶粒尺寸和晶界宽度等方面,不同薄膜间的差异较小。我们的结论是,在所有的沉积频率下都获得了质量相似的YSZ薄膜。氧化离子电导率受衬底沉积温度的影响。在900 K和1000 K下沉积的YSZ薄膜表现出相似的氧化离子电导率,而在800 K下沉积的薄膜表现出较低的氧化离子电导率。这种差异可能是由于晶界宽度窄。在中间衬底温度为900 K, 50 Hz下沉积速率为86 nm·min - 1的条件下制备了具有最高氧化离子电导率的YSZ薄膜,无需额外进行大于1273 K的高温退火。YSZ的生长速度比其他气相方法(如中频和直流溅射)的生长速度快。
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引用次数: 2
Conceptual Design and Performance Analysis of SOFC/Micro Gas Turbine Hybrid Distributed Energy System SOFC/微型燃气轮机混合分布式能源系统概念设计与性能分析
Pub Date : 2015-06-01 DOI: 10.1115/1.4029395
Zheng Dang, Hua Zhao, G. Xi
A numerical model has been developed for the performance analysis of solid oxide fuel cell (SOFC)/micro gas turbine (MGT) hybrid systems with prereforming of natural gas, in which a quasi two-dimensional model has been built up to simulate the cell electrochemical reaction, heat and mass transfer within tubular SOFC. The developed model can be used not only to predict the overall performance of the SOFC/MGT hybrid system but also to reveal the nonuniform temperature distribution within SOFC unit. The effects of turbine inlet temperature (TIT) and pressure ratio (PR) on the performance of the hybrid system have been investigated. The results show that selecting smaller TIT or PR value will lead to relative higher system efficiency and lower CO2 emission ratio; however, this will raise the risk to destroy SOFC beyond the limitation temperature of electrolyte.
建立了含天然气预成形固体氧化物燃料电池(SOFC)/微型燃气轮机(MGT)混合系统性能分析的数值模型,建立了准二维模型,模拟了管状SOFC内电池的电化学反应、传热和传质过程。所建立的模型不仅可以预测SOFC/MGT混合系统的整体性能,而且可以揭示SOFC单元内部温度分布的不均匀性。研究了涡轮入口温度(TIT)和压力比(PR)对混合动力系统性能的影响。结果表明:选择较小的TIT或PR值可以获得较高的系统效率和较低的CO2排放比;然而,这将增加超过电解质极限温度破坏SOFC的风险。
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引用次数: 4
Effect of the Current Collector on Performance of Anode-Supported Microtubular Solid Oxide Fuel Cells 集流器对阳极支撑微管固体氧化物燃料电池性能的影响
Pub Date : 2015-06-01 DOI: 10.1115/1.4029875
M. Casarin, V. Sglavo
Microtubular anode-supported solid oxide fuel cells (lt-SOFC) were created with ametallic coil embedded in the anode to act as current collector. The electrochemical per-formance was experimentally examined by comparing the power density (PD) oflt-SOFC with embedded coils of different turns per unit length and composition (nickeland palladium). It is shown that an increase in the turns per unit length results in a pro-portional current density increase and in a quadratic increment of PD. Additional per-formance improvement is found for the cell with palladium current collector due to thehigher catalytic activity for hydrogen oxidation. [DOI: 10.1115/1.4029875]Keywords: current collector, anode-supported SOFC, microtubular SOFC, electrochemicalperformance
制备了微管阳极支撑固体氧化物燃料电池(lt-SOFC),金属线圈嵌入阳极作为集流器。通过对比不同匝数单位长度和不同成分(镍和钯)的嵌入式线圈的功率密度(PD),实验考察了其电化学性能。结果表明,单位长度匝数的增加会导致电流密度成比例的增加和PD的二次增量。由于具有更高的氢氧化催化活性,发现具有钯集流器的电池具有额外的性能改进。[DOI: 10.1115/1.4029875]关键词:集流器,阳极负载SOFC,微管SOFC,电化学性能
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引用次数: 6
Independent Analysis of Real-Time, Measured Performance Data From Microcogenerative Fuel Cell Systems Installed in Buildings 安装在建筑物中的微型发电燃料电池系统的实时、测量性能数据的独立分析
Pub Date : 2015-06-01 DOI: 10.1115/1.4007162
H. Dillon, W. Colella
Pacific Northwest National Laboratory (PNNL) is working with industry to independently monitor up to 15 distinct 5 kW-electric (kWe) combined heat and power (CHP) high temperature (HT) proton exchange membrane (PEM) fuel cell systems (FCSs) installed in light commercial buildings. This research paper discusses an evaluation of the first six months of measured performance data acquired at a 1 s sampling rate from real-time monitoring equipment attached to the FCSs at building sites. Engineering performance parameters are independently evaluated. Based on an analysis of the first few months of measured operating data, FCS performance is consistent with manufacturer-stated performance. Initial data indicate that the FCSs have relatively stable performance and a long-term average production of about 4.57 kWe of power. This value is consistent with, but slightly below, the manufacturer's stated rated electric power output of 5 kWe. The measured system net electric efficiency has averaged 33.7%, based on the higher heating value (HHV) of natural gas fuel. This value, also, is consistent with, but slightly below, the manufacturer's stated rated electric efficiency of 36%. The FCSs provide low-grade hot water to the building at a measured average temperature of about 48.4 °C, lower than the manufacturer's stated maximum hot water delivery temperature of 65 °C. The uptime of the systems is also evaluated. System availability can be defined as the quotient of total operating time compared to time since commissioning. The average values for system availability vary between 96.1 and 97.3%, depending on the FCS evaluated in the field. Performance at rated value for electrical efficiency (PRVeff) can be defined as the quotient of the system time operating at or above the rated electric efficiency and the time since commissioning. The PRVeff varies between 5.6% and 31.6%, depending on the FCS field unit evaluated. Performance at rated value for electrical power (PRVp) can be defined as the quotient of the system time operating at or above the rated electric power and the time since commissioning. PRVp varies between 6.5% and 16.2%. Performance at rated value for electrical efficiency and power (PRVt) can be defined as the quotient of the system time operating at or above both the rated electric efficiency and the electric power output compared to the time since commissioning. PRVt varies between 0.2% and 1.4%. Optimization to determine the manufacturer rating required to achieve PRVt greater than 80% has been performed based on the collected data. For example, for FCS Unit 130 to achieve a PRVt of 95%, it would have to be down-rated to an electrical power output of 3.2 kWe and an electrical efficiency of 29%. The use of PRV as an assessment metric for FCSs has been developed and reported for the first time in this paper. For FCS Unit 130, a maximum decline in electric power output of approximately 18% was observed over a 500 h period in Jan. 2012.
太平洋西北国家实验室(PNNL)正在与工业界合作,独立监测安装在轻型商业建筑中的多达15个不同的5千瓦电(kWe)热电联产(CHP)高温(HT)质子交换膜(PEM)燃料电池系统(FCSs)。本研究论文讨论了前六个月的测量性能数据的评估,这些数据以1秒的采样率从建筑工地的fcs附带的实时监测设备中获得。工程性能参数独立评估。根据对前几个月测量运行数据的分析,FCS的性能与制造商声明的性能一致。初步数据表明,fcs具有相对稳定的性能,长期平均发电量约为4.57千瓦时。该值与制造商规定的5千瓦时的额定输出功率一致,但略低于此值。基于天然气燃料较高的热值(HHV),实测系统净电效率平均为33.7%。这个值,也,是一致的,但略低于制造商所声明的额定电效率36%。FCSs为建筑提供低品位热水,平均测量温度约为48.4℃,低于制造商规定的最高热水输送温度65℃。还评估了系统的正常运行时间。系统可用性可以定义为总运行时间与自调试以来的时间之比。系统可用性的平均值在96.1和97.3%之间变化,这取决于在现场评估的FCS。额定电效率(PRVeff)下的性能可以定义为系统在额定电效率或高于额定电效率下运行的时间与调试以来的时间之商。根据评估的FCS现场单元,PRVeff在5.6%至31.6%之间变化。额定功率下的性能(PRVp)可以定义为系统在额定功率或高于额定功率下运行的时间与调试以来的时间之商。PRVp在6.5%到16.2%之间。电效率和功率额定值下的性能(PRVt)可以定义为系统在额定电效率和输出电功率下或高于额定电效率的运行时间与调试以来的时间之商。PRVt在0.2%到1.4%之间变化。根据收集的数据进行了优化,以确定实现PRVt大于80%所需的制造商评级。例如,为了使FCS Unit 130达到95%的PRVt,它必须将额定功率降低到3.2 kWe,电气效率为29%。本文首次提出并报道了利用PRV作为fcs评估指标的方法。2012年1月,FCS 130机组在500小时的时间内,电力输出最大降幅约为18%。
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引用次数: 1
SOFC Stack Model for Integration Into a Hybrid System: Stack Response to Control Variables 集成到混合系统的SOFC堆栈模型:控制变量的堆栈响应
Pub Date : 2015-06-01 DOI: 10.1115/1.4029877
Michael M. Whiston, M. Bilec, L. Schaefer
Due to the tight coupling of physical processes inside solid oxide fuel cells (SOFCs), efficient control of these devices depends largely on the proper pairing of controlled and manipulated variables. The present study investigates the uncontrolled, dynamic behavior of an SOFC stack that is intended for use in a hybrid SOFC-gas turbine (GT) system. A numerical fuel cell model is developed based on charge, species mass, energy, and momentum balances, and an equivalent circuit is used to combine the fuel cell's irreversibilities. The model is then verified on electrochemical, mass, and thermal timescales. The open-loop response of the average positive electrode-electrolyte-negative electrode (PEN) temperature, fuel utilization, and SOFC power to step changes in the inlet fuel flow rate, current density, and inlet air flow rate is simulated on different timescales. Results indicate that manipulating the current density is the quickest and most efficient way to change the SOFC power. Meanwhile, manipulating the fuel flow is found to be the most efficient way to change the fuel utilization. In future work, it is recommended that such control strategies be further analyzed and compared in the context of a complete SOFC-GT system model.
由于固体氧化物燃料电池(sofc)内部物理过程的紧密耦合,这些设备的有效控制在很大程度上取决于被控变量和被控变量的适当配对。本研究研究了用于混合SOFC-燃气轮机(GT)系统的SOFC堆的不受控动态行为。建立了基于电荷、物质质量、能量和动量平衡的燃料电池数值模型,并使用等效电路将燃料电池的不可逆性结合起来。然后在电化学、质量和热时间尺度上验证了该模型。模拟了不同时间尺度下正极-电解质-负极(PEN)平均温度、燃料利用率和SOFC功率对进口燃油流量、电流密度和进口空气流量阶跃变化的开环响应。结果表明,控制电流密度是改变SOFC功率最快、最有效的方法。同时,对燃油流量进行控制是改变燃油利用率的最有效方法。在未来的工作中,建议在完整的SOFC-GT系统模型的背景下进一步分析和比较这些控制策略。
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引用次数: 5
Energy System and Thermoeconomic Analysis of Combined Heat and Power High Temperature Proton Exchange Membrane Fuel Cell Systems for Light Commercial Buildings 轻型商业建筑热电联产高温质子交换膜燃料电池系统的能量系统及热经济分析
Pub Date : 2015-06-01 DOI: 10.1115/1.4007273
W. Colella, S. Pilli
The United States (U.S.) Department of Energy (DOE)’s Pacific Northwest National Laboratory (PNNL) is spearheading a program with industry to deploy and independently monitor five kilowatt-electric (kWe) combined heat and power (CHP) fuel cell systems (FCSs) in light commercial buildings. This publication discusses results from PNNL’s research efforts to independently evaluate manufacturer-stated engineering, economic, and environmental performance of these CHP FCSs at installation sites. The analysis was done by developing parameters for economic comparison of CHP installations. Key thermodynamic terms are first defined, followed by an economic analysis using both a standard accounting approach and a management accounting approach. Key economic and environmental performance parameters are evaluated, including (1) the average per unit cost of the CHP FCSs per unit of power, (2) the average per unit cost of the CHP FCSs per unit of energy, (3) the change in greenhouse gas (GHG) and air pollution emissions with a switch from conventional power plants and furnaces to CHP FCSs; (4) the change in GHG mitigation costs from the switch; and (5) the change in human health costs related to air pollution. From the power perspective, the average per unit cost per unit of electrical power is estimated to span amore » range from $15–19,000/ kilowatt-electric (kWe) (depending on site-specific changes in installation, fuel, and other costs), while the average per unit cost of electrical and heat recovery power varies between $7,000 and $9,000/kW. From the energy perspective, the average per unit cost per unit of electrical energy ranges from $0.38 to $0.46/kilowatt-hour-electric (kWhe), while the average per unit cost per unit of electrical and heat recovery energy varies from $0.18 to $0.23/kWh. These values are calculated from engineering and economic performance data provided by the manufacturer (not independently measured data). The GHG emissions were estimated to decrease by one-third by shifting from a conventional energy system to a CHP FCS system. The GHG mitigation costs were also proportional to the changes in the GHG gas emissions. Human health costs were estimated to decrease significantly with a switch from a conventional system to a CHP FCS system.« less
美国(U.S.)美国能源部(DOE)的西北太平洋国家实验室(PNNL)正在与工业界一起开展一项计划,在轻型商业建筑中部署和独立监测5千瓦电(kWe)热电联产(CHP)燃料电池系统(FCSs)。本出版物讨论了PNNL的研究成果,以独立评估制造商在安装地点声明的这些热电联产燃料电池的工程、经济和环境性能。分析是通过为热电联产装置的经济比较制定参数来完成的。首先定义关键热力学术语,然后使用标准会计方法和管理会计方法进行经济分析。主要的经济和环境性能参数进行了评估,包括(1)每单位功率的热电联产燃料电池的平均单位成本,(2)每单位能量的热电联产燃料电池的平均单位成本,(3)温室气体(GHG)和空气污染排放的变化从传统发电厂和熔炉切换到热电联产燃料电池;(4)转换后温室气体减缓成本的变化;(5)与空气污染有关的人类健康成本的变化。从电力的角度来看,每单位电力的平均每单位成本估计在每千瓦电15 - 19 000美元之间(取决于具体地点安装、燃料和其他费用的变化),而电力和热回收电力的平均每单位成本在每千瓦7 000至9 000美元之间。从能源角度看,每单位电能的平均成本为0.38美元至0.46美元/千瓦时电,而每单位电能和热回收能的平均成本为0.18美元至0.23美元/千瓦时。这些值是根据制造商提供的工程和经济性能数据计算出来的(不是独立测量的数据)。据估计,从传统能源系统转向热电联产FCS系统,温室气体排放量将减少三分之一。温室气体缓解成本也与温室气体排放的变化成正比。据估计,从传统系统切换到热电联产FCS系统后,人类健康成本将显著降低。«少
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引用次数: 8
Fault Diagnosis of Solid Oxide Fuel Cell Based on a Supervised Self-Organization Map Model 基于监督自组织映射模型的固体氧化物燃料电池故障诊断
Pub Date : 2015-06-01 DOI: 10.1115/1.4029070
Xiao Juan Wu, Hongtan Liu
Too high stack temperature and insufficient reactant gas flow may lead to severe and irreversible damages in a real solid oxide fuel cell (SOFC) power system. Thus, fault monitoring and diagnosis technology is indispensable to improve the SOFC system reliability. A supervised self-organization map (SOM) model is proposed to diagnose the faults of the SOFC system in this paper. Using the supervised SOM model, the multidimensional testing data of the SOFC is mapped into a two-dimensional map, and the different region in the out map is represented for one fault mode. The method is evaluated using the data obtained from an SOFC mathematical model, and the results show that the supervised SOM analysis contributes on a very efficient way to the faults diagnosis of the SOFC system.
在固体氧化物燃料电池(SOFC)电力系统中,过高的堆温和不足的反应物气体流量会导致严重的、不可逆的损坏。因此,故障监测与诊断技术是提高SOFC系统可靠性不可或缺的技术。提出了一种用于SOFC系统故障诊断的监督自组织映射(SOM)模型。利用有监督SOM模型,将SOFC的多维测试数据映射成二维图,并将出图中的不同区域表示为一种故障模式。利用SOFC数学模型的数据对该方法进行了评价,结果表明,监督SOM分析是SOFC系统故障诊断的有效方法。
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引用次数: 13
期刊
Journal of Fuel Cell Science and Technology
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