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Optimizing renewable energy systems for 100 % clean energy target: A comparative study of solar, hydro, pumped hydro, and battery storage technologies 优化可再生能源系统,实现 100% 清洁能源目标:太阳能、水能、抽水蓄能和电池储能技术比较研究
IF 8.9 2区 工程技术 Q1 ENERGY & FUELS Pub Date : 2024-11-15 DOI: 10.1016/j.est.2024.114441
Zainullah Serat
Addressing global environmental concerns and rising energy demand underscores the urgent need for sustainable renewable energy solutions. This study introduces a novel optimization framework for 100 % hybrid renewable energy systems (HRES) tailored for rural electrification, utilizing HOMER software. This study conducts a comprehensive comparative analysis of mono-crystalline silicon (m-Si) and poly-crystalline silicon (p-Si) photovoltaic (PV) technologies, integrated with hydro, pumped hydro storage (PHS), and battery storage systems, from both energy performance and economic perspectives. The study examines three scenarios, m-Si and p-Si PV systems with PHS, m-Si, and p-Si PV systems with battery storage, and a direct comparison of the optimal configurations from these scenarios. The results indicate that the p-Si PV/Hybrid/PHS system, with a capacity of 162 kW PV, 25 kW hydro, and 1525 kWh PHS, is the most cost-effective and energy-efficient solution. This system generates 474,399 kWh annually, with a net present cost (NPC) of US$472,528.54 and a cost of energy (COE) of US$0.101/kWh. Its superior economic performance and minimized excess energy make it the optimal choice for sustainable energy generation in the targeted rural area. Sensitivity analysis further underscores the critical role of solar irradiation and hydro flow rates in cost minimization. These findings highlight the importance of site-specific customization of PV technology and storage solutions, offering actionable insights for the design and implementation of sustainable energy systems in rural and off-grid environments. By providing a detailed optimization framework, this study significantly advances the development of renewable energy solutions, with potential applications in similar settings.
应对全球环境问题和不断增长的能源需求凸显了对可持续可再生能源解决方案的迫切需求。本研究利用 HOMER 软件,为农村电气化量身定制了 100% 混合可再生能源系统 (HRES) 的新型优化框架。本研究从能源性能和经济角度出发,对单晶硅(m-Si)和多晶硅(p-Si)光伏(PV)技术与水力、抽水蓄能(PHS)和电池蓄能系统进行了全面的比较分析。研究考察了三种方案,即带有 PHS 的 m-Si 和 p-Si 光伏系统、带有电池储能的 m-Si 和 p-Si 光伏系统,并对这些方案的最佳配置进行了直接比较。结果表明,光伏容量为 162 千瓦、水力发电容量为 25 千瓦、PHS 容量为 1525 千瓦时的对硅光伏/混合/PHS 系统是最具成本效益和能效的解决方案。该系统年发电量为 474,399 千瓦时,净现值成本 (NPC) 为 472,528.54 美元,能源成本 (COE) 为 0.101 美元/千瓦时。其优越的经济性能和最小化的多余能源使其成为目标农村地区可持续能源发电的最佳选择。敏感性分析进一步强调了太阳辐照度和水流量在成本最小化中的关键作用。这些发现凸显了针对具体地点定制光伏技术和存储解决方案的重要性,为农村和离网环境中可持续能源系统的设计和实施提供了可操作的见解。通过提供详细的优化框架,本研究极大地推动了可再生能源解决方案的发展,并有可能应用于类似环境。
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引用次数: 0
SOH prediction of lithium-ion batteries using a hybrid model approach integrating single particle model and neural networks 利用单颗粒模型和神经网络的混合模型方法预测锂离子电池的 SOH
IF 8.9 2区 工程技术 Q1 ENERGY & FUELS Pub Date : 2024-11-15 DOI: 10.1016/j.est.2024.114579
Di Zhou , Jinlian Liang , Fuxiang Li , Yuxin Cui , Yunxiao Shan , Yanhui Zhang , Minghua Chen , Shu Li
The prediction of battery state of health (SOH) plays a vital role in battery management systems. A fusion model framework was proposed by integrating an improved single-particle model (SPM) with data-driven deep learning algorithms to enhance predictive accuracy and further elucidate the intrinsic mechanisms of battery aging. First, seven electrochemical features were extracted by the improved SPM, which exhibits a significant reduction in computational complexity compared to conventional electrochemical models. The validity of the extracted features was further verified through the utilization of differential voltage analysis (DVA). Second, a hybrid model was constructed which combines temporal convolutional network (TCN) and bidirectional long short-term memory network (BiLSTM). The effectiveness and superiority of the proposed model was demonstrated, with the full electrochemical features, on Oxford University dataset. Finally, experimental measurements were conducted on five different batteries with two different electrode materials combinations to further study SOH estimation across battery types. To address the forecasting challenges arising from data scarcity for a new type of battery, transfer learning was introduced. The results highlight the potential of this fusion framework to achieve more efficient and accurate SOH prediction.
电池健康状况(SOH)预测在电池管理系统中发挥着至关重要的作用。通过将改进的单颗粒模型(SPM)与数据驱动的深度学习算法相结合,提出了一种融合模型框架,以提高预测精度并进一步阐明电池老化的内在机制。首先,改进的 SPM 提取了七个电化学特征,与传统电化学模型相比,其计算复杂度显著降低。通过使用差分电压分析法(DVA)进一步验证了所提取特征的有效性。其次,构建了一个混合模型,该模型结合了时序卷积网络(TCN)和双向长短期记忆网络(BiLSTM)。在牛津大学的数据集上,利用完整的电化学特征证明了所提模型的有效性和优越性。最后,对五种不同的电池和两种不同的电极材料组合进行了实验测量,以进一步研究不同类型电池的 SOH 估算。为了应对新型电池数据稀缺所带来的预测挑战,我们引入了迁移学习。结果凸显了这一融合框架在实现更高效、更准确的 SOH 预测方面的潜力。
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引用次数: 0
Modulated synthesis of nickel copper bimetallic compounds by ammonium fluoride-based complex as novel active materials of battery supercapacitor hybrids 用氟化铵络合物调制合成镍铜双金属化合物,作为新型电池超级电容器混合活性材料
IF 8.9 2区 工程技术 Q1 ENERGY & FUELS Pub Date : 2024-11-15 DOI: 10.1016/j.est.2024.114567
Tsung-Rong Kuo , Muhammad Saukani , Dong-Ching Chieh , Yu-Cheng Cao , Pin-Yan Lee , Chutima Kongvarhodom , Sibidou Yougbaré , Hung-Ming Chen , Kuo-Chuan Ho , Lu-Yin Lin
Bimetallic compounds have attracted much attention as efficient active materials of battery supercapacitor hybrid (BSH), owing to their multiple redox states, high electrical conductivity, and simply synthesis process. Nickel-based compounds offer high theoretical capacities, while copper-based compounds provide high electrical conductivity. The energy storage performance can be further enhanced designing favorable morphologies, which can be influenced by the incorporation of structure directing agents (SDAs) such as NH4BF4 and NH4HF2. In this study, nickel and copper bimetallic compounds are synthesized as active materials of BSHs in a novel environment containing metal salts, NH4BF4, NH4HF2, and 2-methylmidozole. The effects of the Cu to Ni ratio on material and electrochemical properties are investigated. To enhance the electrochemical contributions of nickel, which has higher theoretical capacities, the reaction time for copper ions is reduced. The optimal bimetallic (CuNi13) electrode achieves the highest specific capacitance (CF) of 1758.0 F/g, corresponding to a capacity of 791.1C/g at 1 A/g, due to the higher nickel content and smaller sheet sizes. The BSH assembled using the CuNi13 and reduced graphene oxide electrodes demonstrates a maximum energy density of 109.1 Wh/kg at 1071 kW/kg. The CF retention of 85.5% and Coulombic efficiency of 93.6% are also maintained after 10,000 cycles.
双金属化合物作为混合电池超级电容器(BSH)的高效活性材料,因其多重氧化还原态、高导电性和简单的合成工艺而备受关注。镍基化合物具有很高的理论容量,而铜基化合物则具有很高的导电性。通过设计有利的形态可进一步提高储能性能,而加入结构引导剂(SDA)(如 NH4BF4 和 NH4HF2)则可影响储能性能。本研究在含有金属盐、NH4BF4、NH4HF2 和 2-甲基咪唑的新型环境中合成了镍和铜双金属化合物,作为 BSHs 的活性材料。研究了铜镍合金比例对材料和电化学特性的影响。镍的理论容量较高,为了提高镍的电化学贡献,缩短了铜离子的反应时间。由于镍含量较高和薄片尺寸较小,最佳双金属(CuNi13)电极的比电容(CF)最高,达到 1758.0 F/g,相当于 1 A/g 时的电容量 791.1C/g。使用 CuNi13 和还原氧化石墨烯电极组装的 BSH 在 1071 kW/kg 时的最大能量密度为 109.1 Wh/kg。经过 10,000 次循环后,CF 保持率为 85.5%,库仑效率为 93.6%。
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引用次数: 0
A renewable multigeneration system based on biomass gasification and geothermal energy: Techno-economic analysis using neural network and Grey Wolf optimization 基于生物质气化和地热能的可再生多发电系统:利用神经网络和灰狼优化技术进行技术经济分析
IF 8.9 2区 工程技术 Q1 ENERGY & FUELS Pub Date : 2024-11-15 DOI: 10.1016/j.est.2024.114519
Jing Wang , Ali Basem , Hayder Oleiwi Shami , Veyan A. Musa , Pradeep Kumar Singh , Yousef Mohammed Alanazi , Ali Shawabkeh , Husam Rajab , A.S. El-Shafay
Environmental challenges such as climate change, air pollution, and resource depletion are intensifying due to the widespread reliance on fossil fuels for energy. Addressing these problems requires a shift toward cleaner, renewable energy sources that can meet growing energy demands while minimizing environmental impact. This paper provides a comprehensive analysis, combining thermodynamic principles and machine learning, of a novel system that includes a biomass gasifier, PEM electrolyzer, geothermal energy source, thermoelectric generators, and a humidification-dehumidification (HDH) desalination unit. The biomass gasifier converts feedstock into syngas, the primary fuel for a combined power cycle. Hydrogen storage is identified as a key factor in the wider adoption of hydrogen as a clean energy source, with efficient storage methods crucial for its use in fuel cells, transportation, and various industrial applications. Geothermal energy is incorporated to supplement the system's energy needs, enhancing sustainability. Additionally, the Kalina cycle recovers waste heat from the gas turbine to generate extra electricity, further boosting the system's efficiency. Data-driven models are utilized in an integrated system to predict system behavior, enabling real-time optimization and adaptive control, and enhancing performance and resource utilization. The combined thermodynamic and machine learning analysis provides insights into the complex interactions and synergies within the integrated renewable energy system. Results demonstrate the feasibility and potential of such systems to meet energy demands sustainably while minimizing environmental footprint. Elicited optimized results are comprised of two scenarios including essential parameters such as exergy efficiency, Ẇnet (net produced work), and CPsys (cost of products).The optimized point in the first optimization scenario depicts exergy efficiency, Ẇnet, and CPsys of 47.93 %, 5958 kW, and 56.97 $/GJ with the initial parameters. In the second optimization scenario, the optimized point depicts EI, Ẇnet, and CPsys of 0.3996 kg/kWh, 5957.88 kW, and 56.90 $/GJ with the initial parameters. In the third optimization scenario, the optimized point depicts EI, exergy efficiency, and ṁhydrogen of 0.3996 kg/kWh, 47.97 %, and 56.085 kg/h with the initial parameters.
由于能源普遍依赖化石燃料,气候变化、空气污染和资源枯竭等环境挑战日益严峻。要解决这些问题,就必须转向更清洁的可再生能源,在满足日益增长的能源需求的同时,最大限度地减少对环境的影响。本文结合热力学原理和机器学习,对一个包括生物质气化器、PEM 电解器、地热能源、热电发电机和加湿除湿(HDH)脱盐装置的新型系统进行了全面分析。生物质气化炉将原料转化为合成气,这是联合动力循环的主要燃料。氢气储存被认为是更广泛采用氢气作为清洁能源的关键因素,高效的储存方法对于氢气在燃料电池、运输和各种工业应用中的使用至关重要。地热能可补充系统的能源需求,增强可持续性。此外,卡利纳循环还能回收燃气轮机的废热,产生额外的电力,进一步提高系统效率。数据驱动模型在集成系统中用于预测系统行为,从而实现实时优化和自适应控制,并提高性能和资源利用率。结合热力学和机器学习分析,可以深入了解集成可再生能源系统内部复杂的相互作用和协同效应。研究结果表明,此类系统具有可行性和潜力,可持续满足能源需求,同时最大限度地减少对环境的影响。第一个优化方案的优化点描述了初始参数下的能效、Ẇnet 和 CPsys,分别为 47.93 %、5958 kW 和 56.97 美元/GJ。在第二种优化方案中,优化点的能效比、Ẇnet 和 CPsys 分别为 0.3996 kg/kWh、5957.88 kW 和 56.90 $/GJ。在第三个优化方案中,优化点的 EI、放能效率和ṁhydrogen 分别为 0.3996 kg/kWh、47.97 % 和 56.085 kg/h。
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引用次数: 0
Enhancing the economic efficiency of wind-photovoltaic‑hydrogen complementary power systems via optimizing capacity allocation 通过优化容量分配提高风光互补发电系统的经济效益
IF 8.9 2区 工程技术 Q1 ENERGY & FUELS Pub Date : 2024-11-15 DOI: 10.1016/j.est.2024.114531
Daohong Wei , Mengwei He , Jingjing Zhang , Dong Liu , Md. Apel Mahmud
Renewable energy generation has emerged as an important strategy in achieving dual carbon. However, the inherent randomness and uncontrollability of major new energy resources present significant challenges for the safe and stable operation of power system. Advanced energy storage technologies are essential to enhance the stability of grid-connected power system incorporating wind and solar energy resources. Reasonable allocation of wind power, photovoltaic (PV), and energy storage capacity is the key to ensuring the economy and reliability of power system. To achieve this goal, a mathematical model of the wind-photovoltaic‑hydrogen complementary power system (WPHCPS) is established to achieve economical and reliable system operation. A control algorithm based on the composite grey wolf optimization (GWO) and particle swarm optimization (PSO) is proposed for the maximum power point tracking (MPPT) of PV system as well as capacity allocation of WPHCPS. Finally, a case demonstrating the optimal capacity configuration scheme is quantitatively analyzed, where the load shortage rate and abandonment rate of wind and solar power are considered. The quantified results show that the optimal operating scene is 50 wind turbines, 2521 PV arrays, 25 batteries, 30 electrolytic cells, 38 hydrogen storage tanks, and 54 hydrogen fuel cells, with the total revenue 232,895.9 CNY. The wind and solar abandonment rate and load interruption rate are 0.36 % and 0.21 %, respectively. The methods and results obtained provide a reference for improving the consumption and stability of the complementary power system and achieving sustainable utilization of clean energy.
可再生能源发电已成为实现 "双碳 "的重要战略。然而,主要新能源固有的随机性和不可控性给电力系统的安全稳定运行带来了巨大挑战。先进的储能技术对于提高包含风能和太阳能资源的并网电力系统的稳定性至关重要。合理分配风电、光伏和储能容量是确保电力系统经济性和可靠性的关键。为实现这一目标,本文建立了风光互补发电系统(WPHCPS)的数学模型,以实现系统运行的经济性和可靠性。提出了一种基于灰狼优化(GWO)和粒子群优化(PSO)的控制算法,用于光伏系统的最大功率点跟踪(MPPT)以及 WPHCPS 的容量分配。最后,定量分析了最优容量配置方案的示范案例,其中考虑了风能和太阳能发电的负荷短缺率和弃电率。量化结果表明,最佳运行场景为 50 台风力发电机、2521 个光伏阵列、25 个蓄电池、30 个电解槽、38 个储氢罐和 54 个氢燃料电池,总收益为 232895.9 元人民币。风能和太阳能弃风率和负荷中断率分别为 0.36 % 和 0.21 %。所得出的方法和结果为提高互补电力系统的消纳和稳定性,实现清洁能源的可持续利用提供了参考。
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引用次数: 0
Chemical reduction-induced defect-rich and synergistic effects of reduced graphene oxide based Cu-doped NiO nanocomposite (RGO@Cu-NiO NCs) decorated on woven carbon fiber for supercapacitor device and their charge storage mechanism 编织碳纤维上装饰的还原氧化石墨烯基铜掺杂氧化镍纳米复合材料 (RGO@Cu-NiO NCs) 化学还原诱导的富缺陷和协同效应及其用于超级电容器器件的电荷存储机制
IF 8.9 2区 工程技术 Q1 ENERGY & FUELS Pub Date : 2024-11-15 DOI: 10.1016/j.est.2024.114578
Fouzia Mashkoor , Mohd Shoeb , Javed Alam Khan , Mohammed Ashraf Gondal , Changyoon Jeong
In today's technological landscape, energy storage devices such as batteries and supercapacitors play a critical role, with hybrid variants attracting significant attention. This study focuses on synthesizing a ternary nanocomposite material composed of reduced graphene oxide adorned Cu-doped NiO (RGO@Cu-NiO NC) for high-performance supercapacitor device applications. Unlike most research that analyzes NiO-based nanocomposites in alkaline electrolytes, our study explores RGO@Cu-NiO NCs coated on woven carbon fiber in Na2SO4 electrolyte, revealing a more dominant surface reaction mechanism. Electrochemical analysis unveiled that the specific capacitances of RGO@Cu-NiO NCs surpass those of Cu-doped NiO NPs by 1.14 times and those of pristine NiO nanoparticles (NPs) by 1.28 times, showcasing a remarkable enhancement in performance. Additionally, the study investigated the charge storage mechanism, providing intriguing insights into the capacity contribution from RGO@Cu-NiO NC to the overall capacitance. The outstanding performance of RGO@Cu-NiO NCs is attributed to incorporating RGO sheets and enhancing charge-storage capacity through facilitated conductive networks. Impressively, the material retained 94 % capacity even after 10,000 cycles. Furthermore, a symmetric supercapacitor device (SSD) based on RGO@Cu-NiO NCs demonstrated a notable specific capacitance of 261.25 F/g at 1.5 A/g, along with 43.54 Wh/kg energy density at 750 W/kg power density, and retained ~96 % capacitance after 10,000 cycles. These findings establish RGO@Cu-NiO nanocomposites as auspicious materials for advanced supercapacitor applications.
在当今的技术领域,电池和超级电容器等储能设备发挥着至关重要的作用,其中混合变体备受关注。本研究的重点是合成一种由还原氧化石墨烯和掺铜氧化镍(RGO@Cu-NiO NC)组成的三元纳米复合材料,用于高性能超级电容器设备的应用。与大多数分析碱性电解质中氧化镍基纳米复合材料的研究不同,我们的研究探讨了在 Na2SO4 电解质中涂覆在碳纤维编织物上的 RGO@Cu-NiO NC,揭示了一种更主要的表面反应机制。电化学分析表明,RGO@Cu-NiO NCs 的比电容是掺铜 NiO NPs 的 1.14 倍,是原始 NiO 纳米粒子(NPs)的 1.28 倍,性能显著提高。此外,研究还探讨了电荷存储机制,为 RGO@Cu-NiO NC 对整体电容的容量贡献提供了有趣的见解。RGO@Cu-NiO NCs 的出色性能归功于加入了 RGO 片,并通过促进导电网络提高了电荷存储容量。令人印象深刻的是,这种材料在经过 10,000 次循环后仍能保持 94% 的容量。此外,基于 RGO@Cu-NiO NCs 的对称超级电容器器件 (SSD) 在 1.5 A/g 的条件下显示出 261.25 F/g 的显著比电容,在 750 W/kg 的功率密度条件下显示出 43.54 Wh/kg 的能量密度,并在 10,000 次循环后保持了约 96% 的电容。这些发现使 RGO@Cu-NiO 纳米复合材料成为先进超级电容器应用的理想材料。
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引用次数: 0
Erratum to “Tailoring the interfacial surfaces of ultrathin Cu-doped MoS2/activated carbon for high performance electrochemical energy storage” [J. Energy Storage 102 (2024) 114173] 对 "为高性能电化学储能定制超薄铜掺杂 MoS2/ 活性碳的界面 "的勘误 [J. Energy Storage 102 (2024) 114173]
IF 8.9 2区 工程技术 Q1 ENERGY & FUELS Pub Date : 2024-11-15 DOI: 10.1016/j.est.2024.114535
Kamarajar Prakash , Shanmugasundaram Kamalakannan , Jayaram Archana , Mani Navaneethan , Santhanakrishnan Harish
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引用次数: 0
Harnessing sustainable energy: Synthesizing a trinary chalcogenide semiconductor BaS:Sb2S3:CuS for enhanced performance in supercapacitor devices and electro-catalysis 利用可持续能源:合成三元共卤化物半导体 BaS:Sb2S3:CuS,提高超级电容器设备和电催化性能
IF 8.9 2区 工程技术 Q1 ENERGY & FUELS Pub Date : 2024-11-15 DOI: 10.1016/j.est.2024.114527
Shaan Bibi Jaffri , Khuram Shahzad Ahmad , Jehad S. Al-Hawadi , Harsh Panchal , Ram K. Gupta , Ghulam Abbas Ashraf , Mohammad K. Okla
The BaS:Sb2S3:CuS trinary chalcogenide is synthesized with a diethyldithiocarbamate ligand as a chelating substance in order to increase the effectiveness of charge storage devices and operate as an energy generation catalyst. The sustainably produced BaS:Sb2S3:CuS semiconductor showed good photo-activity because of its light absorption, with an energy band gap of 2.57 eV. The BaS:Sb2S3:CuS electrochemical performance was evaluated using a traditional three-electrode setup. With a specific power density of 8161 W kg−1 and a specific capacitance of up to 958.91 F g−1, BaS:Sb2S3:CuS has shown to be a great electrode material for energy storage applications. The same series resistance (Rs) of 2.02 Ω further supported this remarkable electrochemical performance. Through electro-catalysis, the electrode produced an OER overpotential and a corresponding Tafel slope of 419 mV and 186 mV/dec. On the other hand, the Tafel slope and overpotential for HER activity were 321 mV/dec and 154 mV, respectively.
以二乙基二硫代氨基甲酸酯配体为螯合剂合成了 BaS:Sb2S3:CuS 三元共卤化物,以提高电荷存储设备的效率,并用作能源生成催化剂。可持续制备的 BaS:Sb2S3:CuS 半导体具有良好的光吸收活性,能带隙为 2.57 eV。采用传统的三电极设置对 BaS:Sb2S3:CuS 的电化学性能进行了评估。BaS:Sb2S3:CuS 的比功率密度为 8161 W kg-1,比电容高达 958.91 F g-1,是一种非常适合储能应用的电极材料。2.02 Ω的相同串联电阻(Rs)进一步支持了这一卓越的电化学性能。通过电催化,该电极产生了 419 mV 和 186 mV/dec 的 OER 过电位和相应的 Tafel 斜坡。另一方面,HER 活性的塔菲尔斜率和过电位分别为 321 mV/dec 和 154 mV。
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引用次数: 0
Pre‑carbonization for regulating sucrose-based hard carbon pore structure as high plateau capacity sodium-ion battery anode 调节蔗糖基硬质碳孔隙结构的预碳化技术,用作高原容量钠离子电池阳极
IF 8.9 2区 工程技术 Q1 ENERGY & FUELS Pub Date : 2024-11-15 DOI: 10.1016/j.est.2024.114590
Yuanting Yan , Ge Chen , Wenjing Liu , Meizhen Qu , Zhengwei Xie , Feng Wang
Although hard carbon still suffers from low initial coulombic efficiency and a controversial sodium storage mechanism, it is widely explored and utilized as an anode material for sodium-ion batteries due to its affordability and accessibility. This work used pre‑carbonization to construct sufficient reaction time of volatile reactive molecules released from matrix in the carbon interlayers, hence optimizing the structure of the nanopore and the graphite microcrystal inside the sucrose-based hard carbon. The sucrose-based hard carbon after pre‑carbonization treatment has an expanded carbon layer spacing, an appropriate micro-mesopore ratio, and a distinct closed pore structure. The result provides evidence that the low-voltage plateau region capacity is related to two Na+ storage behaviors: intercalation between carbon layers and pore-filling in nanopores. Further larger interlayer distances, lower micro-mesoporous ratios, and closed pores are favorable for sodium storage in the low-voltage plateau region which is assisting to improve the initial coulombic efficiency. In comparison to previously published studies, the pre‑carbonized hard carbon at 450 °C with a heating rate of 3 °C/min exhibits an impressive plateau capacity of 277 mAh g−1, increasing the contribution of the plateau capacity from 54 % to 63 %, while also enhancing cycling and rate performance. Furthermore, it has a significant initial coulombic efficiency (ICE) of 85 % and a noteworthy reversible specific capacity of 374 mAh g−1 at a current density of 20 mA g−1, which is noticeably better than the biomass hard carbon documented in the literature. Achieving a sustained low-voltage plateau capacity through microstructure modulation is crucial for producing hard carbon with both high specific capacity and rewarding ICE. This study presents a novel approach for the preparation sucrose based hard carbon of high plateau capacity and is expected to contribute significantly to the development of high energy density sodium-ion battery energy storage systems.
尽管硬碳仍然存在初始库仑效率低和钠存储机制存在争议等问题,但由于其价格低廉、易于获得,它作为钠离子电池的负极材料得到了广泛的开发和利用。这项研究利用预碳化技术,使从基质中释放的挥发性反应分子在碳夹层中形成足够的反应时间,从而优化了蔗糖基硬碳内部的纳米孔和石墨微晶结构。经过预碳化处理后的蔗糖基硬碳具有扩大的碳层间距、适当的微介孔比例和明显的封闭孔结构。结果证明,低电压高原区的容量与两种 Na+ 储存行为有关:碳层间的插层和纳米孔隙中的孔隙填充。此外,较大的层间距离、较低的微多孔比和封闭的孔隙有利于钠在低电压高原区的储存,这有助于提高初始库仑效率。与之前发表的研究相比,在 450 °C 下以 3 °C/min 的升温速率预碳化的硬碳显示出 277 mAh g-1 的惊人高原容量,将高原容量的贡献率从 54% 提高到 63%,同时还提高了循环和速率性能。此外,它的初始库仑效率(ICE)高达 85%,电流密度为 20 mA g-1 时的可逆比容量为 374 mAh g-1,明显优于文献记载的生物质硬碳。通过微观结构调控实现持续的低电压高原容量,对于生产高比容量和高回报 ICE 的硬质碳至关重要。本研究提出了一种制备高平台容量蔗糖基硬质碳的新方法,有望为高能量密度钠离子电池储能系统的开发做出重大贡献。
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引用次数: 0
Predicting batteries second-life state-of-health with first-life data and on-board voltage measurements using support vector regression 使用支持向量回归法,利用第一生命周期数据和车载电压测量值预测电池第二生命周期的健康状况
IF 8.9 2区 工程技术 Q1 ENERGY & FUELS Pub Date : 2024-11-15 DOI: 10.1016/j.est.2024.114554
Shymaa Mohammed Jameel , J.M. Altmemi , Ahmed A. Oglah , Mohammad A. Abbas , Ahmad H. Sabry
Electric vehicle (EV) batteries experience significant degradation during their primary use. While reaching End-of-Life (EOL) for EVs, these batteries hold the potential for a “Second-life” in less demanding applications. However, accurate estimation for State-of-Health (SoH) remains a challenging task as it requires extensive monitoring communications in Second-life settings. This study proposes a novel data-efficient approach to predicting Second-life SoH with minimal Second-life measurements and readily available first-life data. This work introduces a Support Vector Regression (SVR) model trained on first-life features to estimate discharge capacity in the Second-life. Only terminal voltage measurements (TIECVD and TIEDVD) during Second-life operation are utilized to predict SoH. Unlike existing methods involving broad Second-life monitoring, this approach focuses on energy delivery as an indicator of the battery's ability to power continuous operation, reducing complexity and data acquisition costs. To validate the proposed technique, we conducted experiments using Lithium-ion batteries with NASA's dataset including three different battery models. The results of using the SVR model achieved a Root Mean Square Error (RMSE) between actual and predicted SoH data ranging from 0.0012 to 0.0158, signifying its effectiveness over various battery types. This innovative SoH prediction method using first-life data and minimal Second-life measurements clears the way for better predicting the Remaining Useful Life (RUL) in Second-life EV batteries.
电动汽车(EV)电池在其主要使用过程中会出现严重退化。虽然电动汽车的电池寿命已到终点(EOL),但这些电池在要求不高的应用中仍有 "第二寿命 "的潜力。然而,对电池健康状况(SoH)的准确估计仍然是一项具有挑战性的任务,因为这需要在 "第二寿命 "环境中进行广泛的监控通信。本研究提出了一种新颖的数据高效方法,利用最少的 "第二生命期 "测量数据和随时可用的 "第一生命期 "数据来预测 "第二生命期 "的健康状况。这项工作引入了一个支持向量回归(SVR)模型,该模型根据第一生命周期的特征进行训练,以估算第二生命周期的放电容量。仅利用第二生命周期运行期间的端电压测量值(TIECVD 和 TIEDVD)来预测 SoH。与涉及广泛的第二寿命监测的现有方法不同,这种方法侧重于将能量输送作为电池持续运行能力的指标,从而降低了复杂性和数据采集成本。为了验证所提出的技术,我们使用锂离子电池和 NASA 的数据集(包括三种不同的电池模型)进行了实验。使用 SVR 模型的结果表明,实际 SoH 数据与预测 SoH 数据之间的均方根误差(RMSE)在 0.0012 到 0.0158 之间,这表明它对各种类型的电池都很有效。这种创新的 SoH 预测方法使用了第一生命周期数据和最少的第二生命周期测量数据,为更好地预测第二生命周期电动汽车电池的剩余使用寿命 (RUL) 开辟了道路。
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Journal of energy storage
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