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Improved consensus-based current sharing control approach for battery storage in hydrogen production systems 改进的基于共识的制氢系统电池储能电流共享控制方法
IF 8.9 2区 工程技术 Q1 ENERGY & FUELS Pub Date : 2026-02-05 DOI: 10.1016/j.est.2026.120854
Rashid Iqbal , Yancheng Liu , Almas Arshad , Adil Ali Raja , Mudasir Wahab , Qinjin Zhang , Muhammad Yaseen , Syed Awais Ali Shah
With the increasing integration of renewable energy sources, the reliable operation of off-grid DC microgrids, particularly in hydrogen production systems, relies heavily on coordinated energy management and balanced utilization of distributed energy storage units (DESUs). To address these challenges, this paper proposed an improved consensus-based current sharing control approach for DESUs, leveraging a distributed control framework based on multi-agent coordination to ensure accurate current sharing, uniform State of Charge (SoC) distribution, and stable DC bus voltage regulation. A dynamic SoC-based droop control mechanism is developed using the inverse hyperbolic sine function, which inherently incorporates an acceleration factor to enhance the convergence speed and responsiveness of SoC equalization. The control architecture is organized into two functional layers: the primary layer employs an Improved Current Sharing Controller (ICSC) for real-time current allocation and SoC balancing, while the secondary layer integrates a Multi-objective Secondary Controller (MOSC) to suppress voltage deviations caused by droop-based operation and mitigate the effect of line impedance. Additionally, a thorough analysis of small and large signal stability for the proposed control approach is carried out to verify system stability under varying operational scenarios. The effectiveness of the proposed scheme is validated through detailed MATLAB/Simulink simulations and Hardware-in-the-Loop (HIL) experiments. Comparative results confirm that the strategy significantly improves SoC convergence, current sharing accuracy, and dynamic performance compared to conventional approaches, offering a promising solution for efficient and resilient off-grid hydrogen production systems.
随着可再生能源并网程度的不断提高,离网直流微电网的可靠运行,特别是制氢系统的可靠运行,在很大程度上依赖于分布式储能单元(desu)的协调能源管理和平衡利用。为了解决这些挑战,本文提出了一种改进的基于共识的desu电流共享控制方法,利用基于多智能体协调的分布式控制框架来确保精确的电流共享、均匀的荷电状态(SoC)分布和稳定的直流母线电压调节。利用逆双曲正弦函数建立了一种基于SoC的动态下垂控制机制,该机制固有地加入了加速因子,以提高SoC均衡的收敛速度和响应性。控制体系结构分为两个功能层:第一层采用改进的电流共享控制器(ICSC)进行实时电流分配和SoC平衡,第二层集成了多目标辅助控制器(MOSC)来抑制基于下降的操作引起的电压偏差并减轻线阻抗的影响。此外,对所提出的控制方法的小信号和大信号稳定性进行了深入的分析,以验证系统在不同操作场景下的稳定性。通过详细的MATLAB/Simulink仿真和硬件在环(HIL)实验验证了该方案的有效性。对比结果证实,与传统方法相比,该策略显著提高了SoC收敛性、电流共享精度和动态性能,为高效、有弹性的离网制氢系统提供了一种有前景的解决方案。
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引用次数: 0
Thermally-stable composite phase change material enabled by a crosslinking polymer skeleton with aliphatic side chains for thermal management and energy conversion 热稳定的复合相变材料,由具有脂肪侧链的交联聚合物骨架实现,用于热管理和能量转换
IF 8.9 2区 工程技术 Q1 ENERGY & FUELS Pub Date : 2026-02-05 DOI: 10.1016/j.est.2026.120893
Zhubin Yao , Changhong Wang , Jian Cheng , Jiakun Li , Zhenghui Li , Guoqing Zhang , Xiaoqing Yang
Thermal stability and heat storage capacity are both critical performances for composite phase change materials (CPCM) in various applications. However, the pursuit of high stability while maintaining high latent heat remains an arduous challenge owing to the tradeoff between these two key characteristics. Herein, inspired by the comb-like structure of liquid crystalline polymer, we design a functional polymeric skeleton with crosslinking mainchain and aliphatic side chains via in-situ polymerizing docosahexadecyl acrylate monomers in liquid paraffin. The C22 side chains provide an intrinsic latent heat of 102.9 J·g−1. Thus, the proportion of polymeric skeleton can be increased to 55 wt% while guaranteeing a large latent heat of 132.1 J·g−1 of the CPCM. Meanwhile, the high polymer content and its crosslinking mainchain structure endow the CPCM with significantly enhanced thermal stability, including a superior heat tolerance up to 240 °C, a negligible leakage rate of 0.53 wt% and an outstanding shape stability under high operating temperatures. As a result, the obtained CPCM demonstrates great performances in various potential applications, such as an enhanced temperature control ability in thermal management of solar cells and electronic devices, and a high photothermal conversion rate up to 86.5%.
热稳定性和蓄热能力是复合相变材料(CPCM)在各种应用中的关键性能。然而,由于这两个关键特性之间的权衡,在保持高潜热的同时追求高稳定性仍然是一项艰巨的挑战。本文以液晶聚合物的梳状结构为灵感,通过在液体石蜡中原位聚合二十二碳十六烷基丙烯酸酯单体,设计了一种具有交联主链和脂肪侧链的功能性聚合物骨架。C22侧链的本征潜热为102.9 J·g−1。因此,聚合物骨架的比例可以增加到55%,同时保证CPCM的大潜热为132.1 J·g−1。同时,高聚合物含量及其交联主链结构使CPCM具有显著增强的热稳定性,包括高达240°C的耐热性,可忽略不计的0.53 wt%的泄漏率以及在高温下出色的形状稳定性。结果表明,所制备的CPCM在太阳能电池和电子器件热管理中的温度控制能力增强,光热转化率高达86.5%,具有良好的应用前景。
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引用次数: 0
Effects of directional magnetic field on the performance and degradation of lithium-ion batteries 定向磁场对锂离子电池性能及退化的影响
IF 8.9 2区 工程技术 Q1 ENERGY & FUELS Pub Date : 2026-02-05 DOI: 10.1016/j.est.2026.120867
Hyunju Ko , Woojoong Kim , Minjun Kang , Sangjun Park , Namwook Kim , Youn Cheol Park , Byeongsu Kang
Lithium-ion batteries are widely used in various applications such as electric vehicles and energy storage systems owing to their high energy density and excellent stability. Accordingly, various studies are actively underway to improve battery life and suppress degradation; however, most have focused on advancing internal materials such as cathodes, anodes, and electrolytes. This approach has limitations, including complex manufacturing processes, increased costs, and difficulty in applying such changes to existing systems in operation. In this study, we propose an external, nonintrusive approach involving the application of an external magnetic field to a battery to overcome these limitations. This method can improve performance through physical stimulation without altering the internal structure of the cell, making it easily applicable to commercial systems. First, we compared the electrochemical characteristics based on the magnetic polarity using a beaker cell. Subsequently, the optimal conditions to a commercial 18,650 lithium-ion battery were applied to analyze and compare the charge/discharge cycle performance with and without application of magnetic field. Additionally, we conducted electrochemical impedance spectroscopy, electrode surface observations, and X-ray photoelectron spectroscopy of the cells after cycling to comprehensively evaluate the effect of the magnetic field on battery degradation. This study demonstrates the feasibility of improving battery life through a simple and practical approach of applying an external magnetic field, and highlights its potential as an alternative technique to enhance the performance of existing battery systems.
锂离子电池以其高能量密度和优异的稳定性被广泛应用于电动汽车和储能系统等各种应用中。因此,各种研究正在积极进行,以提高电池寿命和抑制退化;然而,大多数都集中在推进内部材料,如阴极、阳极和电解质。这种方法有局限性,包括复杂的制造过程,增加的成本,以及难以将这种变化应用于现有的操作系统。在这项研究中,我们提出了一种外部的、非侵入性的方法,包括对电池施加外部磁场来克服这些限制。这种方法可以通过物理刺激提高性能,而不改变细胞的内部结构,使其易于应用于商业系统。首先,我们用烧杯电池比较了基于磁极性的电化学特性。随后,将最佳条件应用于商用18650锂离子电池,分析和比较在有磁场作用和没有磁场作用时的充放电循环性能。此外,我们还对循环后的电池进行了电化学阻抗谱、电极表面观察和x射线光电子能谱分析,以综合评价磁场对电池退化的影响。本研究证明了通过施加外部磁场的简单实用方法提高电池寿命的可行性,并强调了其作为提高现有电池系统性能的替代技术的潜力。
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引用次数: 0
Mechanistic study of moisture content effects on coal-oxygen adsorption conformational relationship 含水率对煤氧吸附构象关系影响的机理研究
IF 8.9 2区 工程技术 Q1 ENERGY & FUELS Pub Date : 2026-02-05 DOI: 10.1016/j.est.2026.120963
Yanni Zhang , Yunchao Hou , Fanyan Zhai , Dan Yang , Jun Deng
Coal spontaneous combustion is an inherent property of coal, which initial-stage is essentially a cascade transfer process that physical adsorption oxygen activation energy triggers chemical adsorption and oxidation reaction, its dynamic equilibrium process is regulated by the coupling effect of coal-water‑oxygen multiphase interface. Thus it is significant to grasp the impact characteristic of moisture on coal oxygen adsorption for further revealing coal spontaneous combustion mechanism and developing new moisture-regulated inhibition technology. In this research, using low-temperature liquid nitrogen adsorption, the air adsorption calorimetry experimental and molecular dynamics simulation, studied the moisture content affects coal‑oxygen adsorption process. The results show that increasing moisture content, the specific surface area and cumulative pore volume are negatively correlated, positively with the average pore diameter; Grasped heat release law of adsorption coupling at the coal-water‑oxygen multiphase interface. That is, with increasing moisture content, the coal oxygen adsorption capacity, adsorption heat flow and heat release all show a monotonically decreasing trend; Determined moisture content affects coal‑oxygen adsorption microscopic characteristics, i.e., Pore structure level: the spatial occupancy effect of water molecules can change oxygen transport path; Kinetic parameter level: oxygen diffusion coefficient and coal oxygen adsorption interaction energy are negatively correlated with increasing moisture content; Adsorption site level: As moisture content increases, oxygen diffusion resistance increases, prompting adsorption sites to gradually shift toward high-energy adsorption regions. Revealed the conformational mechanism of moisture content affecting coal oxygen adsorption, i.e., water molecules inhibit coal oxygen adsorption by reducing pore space, blocking oxygen transport pathways, and occupying low-energy adsorption sites.
煤自燃是煤的固有性质,其初始阶段本质上是物理吸附氧活化能引发化学吸附氧化反应的级联传递过程,其动态平衡过程受煤-水-氧多相界面耦合作用调控。因此,掌握水分对煤氧吸附的影响特性,对于进一步揭示煤自燃机理,开发新的水分调节抑制技术具有重要意义。本研究采用低温液氮吸附、空气吸附量热法实验和分子动力学模拟,研究了水分含量对煤氧吸附过程的影响。结果表明:增加含水率、比表面积和累积孔隙体积与平均孔径呈负相关,正相关;掌握了煤-水-氧多相界面吸附耦合的放热规律。即随着含水率的增加,煤的吸氧能力、吸附热流和放热均呈单调减小趋势;含水率的确定影响煤对氧吸附的微观特征,即孔隙结构水平:水分子的空间占用效应可以改变氧的运输路径;动力学参数水平:氧扩散系数和煤氧吸附相互作用能与含水率的增加呈负相关;吸附位点水平:随着水分含量的增加,氧气扩散阻力增大,促使吸附位点逐渐向高能吸附区转移。揭示了水分含量影响煤氧吸附的构象机制,即水分子通过缩小孔隙空间、阻断氧运输途径、占据低能吸附位点等方式抑制煤氧吸附。
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引用次数: 0
Quantifying hourly virtual inertia and battery energy storage system requirements for frequency stability in low-inertia power systems 量化小时虚拟惯性和电池储能系统对低惯性电力系统频率稳定性的要求
IF 8.9 2区 工程技术 Q1 ENERGY & FUELS Pub Date : 2026-02-05 DOI: 10.1016/j.est.2026.120853
S. Saha , M. Elliott , T.K. Roy , Amanullah M.T. Oo
The increasing penetration of renewable energy sources has reduced system inertia by displacing conventional synchronous generators, creating challenges for frequency stability in modern power grids. Existing approaches for virtual inertia provision and battery energy storage system (BESS) sizing rely on deterministic and static assumptions and therefore fail to capture the stochastic and time-varying nature of renewable generation, load demand, and operating conditions. To address these shortcomings, this study proposes a stochastic, reliability-constrained optimization framework for the hourly quantification of virtual inertia requirements and corresponding BESS reserves. Uncertainty in renewable generation and load demand is modeled using Monte Carlo simulation, and an empirical cumulative distribution function (ECDF) based assessment is employed to ensure compliance with grid operator-defined frequency nadir and rate-of-change-of-frequency (RoCoF) constraints at a specified reliability level. The proposed framework is validated on a modified IEEE 39-bus test system with 50% renewable energy penetration. The results show strong hourly variation in the required BESS virtual inertia support, expressed in terms of the equivalent inertia constant, which increases from 0.33–0.62 s during high-inertia night-time hours (21:00–05:00) to 3.25–3.76 s during low-inertia solar hours (11:00–15:00) at a 90% reliability level, with a maximum requirement of 3.76 s at 13:00. As the reliability target increases from 50% to 90%, the BESS inertia reserves determined by the proposed framework progressively reduce frequency nadir and RoCoF violations caused by the loss of the largest generating unit, reaching approximately 9% of scenarios at 90% reliability, at the expense of higher reserve requirements and increased capital expenditure. The proposed framework explicitly captures this reliability–cost interaction, thereby quantifying a clear trade-off between frequency reliability and economic performance and providing a reliability-informed framework for balancing frequency security and investment decisions in low-inertia power systems.
可再生能源的日益普及取代了传统的同步发电机,减少了系统的惯性,对现代电网的频率稳定性提出了挑战。现有的虚拟惯性供应和电池储能系统(BESS)规模确定方法依赖于确定性和静态假设,因此无法捕捉可再生能源发电、负载需求和运行条件的随机和时变性质。为了解决这些缺点,本研究提出了一个随机的、可靠性约束的优化框架,用于虚拟惯性需求和相应的BESS储备的每小时量化。利用蒙特卡罗模拟对可再生能源发电和负荷需求的不确定性进行建模,并采用基于经验累积分布函数(ECDF)的评估方法,确保在特定可靠性水平下符合电网运营商定义的频率最低点和频率变化率(RoCoF)约束。该框架在可再生能源渗透率为50%的改进的IEEE 39总线测试系统上进行了验证。结果表明,BESS虚拟惯性支撑所需的等效惯性常数具有较强的逐时变化,在90%的可靠性水平下,从高惯性夜间时段(21:00-05:00)的0.33-0.62 s增加到低惯性太阳时段(11:00-15:00)的3.25-3.76 s,最大需求为13:00时的3.76 s。当可靠性目标从50%增加到90%时,由所提出的框架确定的BESS惯性储备逐步减少由最大发电机组损失引起的频率低点和RoCoF违规,在90%可靠性的情况下达到约9%,代价是更高的储备要求和增加的资本支出。所提出的框架明确地捕获了这种可靠性-成本的相互作用,从而量化了频率可靠性和经济性能之间的明确权衡,并为在低惯性电力系统中平衡频率安全和投资决策提供了一个可靠的知情框架。
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引用次数: 0
The uniqueness of Janus: A key element in breakthrough oxygen evolution reaction and oxygen reduction reaction bifunctional electrocatalyst design Janus的独特性:突破析氧反应和氧还原反应双功能电催化剂设计的关键因素
IF 8.9 2区 工程技术 Q1 ENERGY & FUELS Pub Date : 2026-02-05 DOI: 10.1016/j.est.2026.120967
Songshan Gao , Long Lin , Pei Shi , Chaoyang Wang , Xiangyu Guo , Shengli Zhang
The development of efficient, cost-effective, and environmentally friendly electrocatalysts is a fundamental prerequisite for advancing renewable energy storage and conversion technologies. Focusing on bifunctional electrocatalyst systems for the oxygen evolution reaction (OER) and oxygen reduction reaction (ORR), we find that the Janus-type two-dimensional (2D) transition metal chalcogenide SnSSe monolayer offers a unique combination of electronic structure and multiple reactive sites suitable for dual-function catalysis. Based on density functional theory (DFT) calculations, we demonstrate that single-atom modification is an effective strategy to endow the SnSSe substrate with both ORR and OER catalytic capabilities. Among the eighteen configurations doped with transition metals (TM) examined, the Pd-VS, Pd-VSe, Pt-VS, and Pt-VSe@SnSSe systems exhibit superior electrochemical stability and catalytic potential, primarily due to their higher dissolution potentials. Their catalytic excellence is attributed to the simultaneous reduction in overpotentials and enhancement of reaction kinetics, governed by both thermodynamic equilibrium and kinetic reaction pathways. Notably, Pt-VSe@SnSSe shows the most promising performance, achieving theoretical overpotentials of ηORR = 0.43 V and ηOER = 0.40 V, which surpass those of conventional benchmark catalysts Pt(111) and RuO2(110). This superior activity originates from a reconstruction of the electronic structure triggered by changes in the coordination environment. This work not only elucidates the structure–activity relationship of bifunctional catalytic centers but also provides a theoretical foundation for the application of Janus-type two-dimensional materials in metal air batteries and other energy conversion devices.
开发高效、经济、环保的电催化剂是推进可再生能源存储和转换技术的基本前提。通过对析氧反应(OER)和氧还原反应(ORR)的双功能电催化体系的研究,我们发现janus型二维(2D)过渡金属硫族化合物SnSSe单层具有独特的电子结构组合和适合双功能催化的多个反应位点。基于密度泛函理论(DFT)计算,我们证明了单原子修饰是赋予SnSSe底物ORR和OER催化能力的有效策略。在18种掺杂过渡金属(TM)的体系中,Pd-VS、Pd-VSe、Pt-VS和Pt-VSe@SnSSe体系表现出优异的电化学稳定性和催化电位,这主要是由于它们具有较高的溶解电位。它们的优异催化性能归功于同时降低过电位和增强反应动力学,由热力学平衡和动力学反应途径控制。值得注意的是,Pt-VSe@SnSSe表现出最具前景的性能,其理论过电位ηORR = 0.43 V, ηOER = 0.40 V,超过了传统基准催化剂Pt(111)和RuO2(110)。这种优越的活动源于协调环境的变化所引发的电子结构的重建。这项工作不仅阐明了双功能催化中心的构效关系,而且为janus型二维材料在金属空气电池和其他能量转换装置中的应用提供了理论基础。
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引用次数: 0
PINEAPPLE: Physics-informed neuro-evolution algorithm for prognostic parameter inference in lithium-ion battery electrodes 菠萝:用于锂离子电池电极预测参数推断的物理信息神经进化算法
IF 8.9 2区 工程技术 Q1 ENERGY & FUELS Pub Date : 2026-02-05 DOI: 10.1016/j.est.2026.120944
Karkulali Pugalenthi , Jian Cheng Wong , Qizheng Yang , Pao-Hsiung Chiu , My Ha Dao , Nagarajan Raghavan , Chin Chun Ooi
Accurate, real-time, yet non-destructive estimation of internal states in lithium-ion batteries is critical for predicting degradation, optimizing usage strategies, and extending operational lifespan. While physics-based models, such as the single-particle model, utilize fundamental mechanistic insights to link macro-scale measurements (e.g., voltage response) to batteries’ internal electrochemical dynamics, their relatively high computational cost limits real-time diagnostics and continuous inference during battery pack operation. Here, we introduce PINEAPPLE (Physics-Informed Neuro-Evolution Algorithm for Prognostic Parameter inference in Lithium-ion battery Electrodes), a novel framework that integrates physics-informed neural networks (PINNs) with an evolutionary search algorithm to enable rapid, scalable, and interpretable parameter inference with potential for application to next-generation batteries. The meta-learned PINN utilizes fundamental physics principles to achieve accurate zero-shot prediction of electrode behavior with test errors below 0.1% while maintaining an order-of-magnitude speed-up over conventional solvers. PINEAPPLE demonstrates robust parameter inference solely from voltage–time discharge curves across multiple batteries from the open-source CALCE repository, recovering the evolution of key internal state parameters such as Li-ion diffusion coefficients across usage cycles. Notably, the inferred cycle-dependent evolution of these parameters exhibit consistent trends across different batteries without any customized degradation physics-embedded heuristic, highlighting the effective regularizing effect and robustness that can be conferred through incorporation of fundamental physics in PINEAPPLE. By enabling computationally efficient, real-time parameter estimation, PINEAPPLE offers a promising route towards the non-destructive, physics-based characterization of inter-cell and intra-cell variability of battery modules and battery packs, thereby unlocking new opportunities for downstream on-the-fly needs in next-generation battery management systems such as individual cell-scale state-of-health diagnostics.
准确、实时、无损地估计锂离子电池的内部状态对于预测电池退化、优化使用策略和延长使用寿命至关重要。虽然基于物理的模型,如单粒子模型,利用基本的机械洞察力将宏观测量(如电压响应)与电池内部电化学动力学联系起来,但它们相对较高的计算成本限制了电池组运行期间的实时诊断和连续推断。在这里,我们介绍了菠萝(用于锂离子电池电极预测参数推断的物理信息神经进化算法),这是一个将物理信息神经网络(pinn)与进化搜索算法集成在一起的新框架,可以实现快速、可扩展和可解释的参数推断,具有应用于下一代电池的潜力。元学习的PINN利用基本物理原理,实现了对电极行为的精确零射击预测,测试误差低于0.1%,同时保持了比传统求解器的数量级加速。菠萝仅从来自开源CALCE存储库的多个电池的电压-时间放电曲线中进行了鲁棒的参数推断,恢复了锂离子扩散系数等关键内部状态参数在使用周期中的演变。值得注意的是,这些参数的循环依赖演化在不同的电池中表现出一致的趋势,没有任何定制的退化物理嵌入的启发,突出了有效的正则化效果和鲁棒性,可以通过将基础物理结合到菠萝中。通过实现高效的计算、实时参数估计,PINEAPPLE为电池模块和电池组的细胞间和细胞内可变性的非破坏性、基于物理的表征提供了一条有前途的途径,从而为下一代电池管理系统(如单个细胞规模的健康状态诊断)的下游动态需求提供了新的机会。
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引用次数: 0
Hybrid Co(II) coordination polymer/CNT/GO electrodes for high energy asymmetric supercapacitor Co(II)配位聚合物/碳纳米管/氧化石墨烯复合电极用于高能非对称超级电容器
IF 8.9 2区 工程技术 Q1 ENERGY & FUELS Pub Date : 2026-02-05 DOI: 10.1016/j.est.2026.120709
Arif Ali, Khusboo Kumari, Anupama Joy, Fatma Parween, Mst Shubnur Sultana, Ganesh Chandra Nayak
Two-dimensional (2D) coordination polymers (CPs) have attracted significant attention in electrochemical energy storage because their layered architectures promote strong interfacial interactions with 1D and 2D carbon materials. Nevertheless, CPs often suffer from limited specific capacitance and poor structural stability. Integrating conductive carbon components can effectively overcome these drawbacks by leveraging synergistic effects to enhance overall charge storage capability. Herein, we report the solvothermal synthesis of a Co(II)-based coordination polymer, [Co(PDA)(H₂O)] (namely, MCo). The structure of MCo was elucidated by single-crystal X-ray diffraction (SC-XRD), revealing an hcb-type underlying net topology. Composite materials were subsequently fabricated by integrating MCo with multi-walled carbon nanotubes (MWCNTs) and graphene oxide (GO), designated as MCo/CNT and MCo/GO, respectively. The morphology and chemical composition of the resulting composites were characterized by FESEM, HR-TEM, and XPS analysis. Electrochemical analysis of symmetric supercapacitor (SSC) and asymmetric supercapacitor (ASC) devices showed that the ASC device has better specific capacitance (Sp.CP.). The specific capacitance of MCo, MCo/CNT 100, and MCo/GO 20 was calculated to be 14.54, 287.13, and 373.12 F g−1 at 0.5 A g−1 current density, respectively. The energy density and power density of MCo/GO 20 were calculated to be 132.6 Wh kg−1 and 400 W kg−1 at 0.5 A g−1. The ASC device retained 68% capacitance after completion of 10,000 cycles of charging-discharging, demonstrating good cyclic stability. Furthermore, power-law analysis indicated a predominantly electric double-layer capacitance (EDLC) behavior with b-values ranging between 0.5 and 1. For practical demonstration, the ASC device successfully powered red, multicolor disco, and white LEDs, maintaining illumination for 120 s after a charging of 60 s. Additionally, an ASC flexible MCo/GO 20 device under PVA/KOH gel electrolyte showed sp. cp. of 461.03 F g−1 and energy density of 164.02 Wh kg−1 at a current density of 0.5 A g−1 with a capacitance retention of 87% at a current density of 6 A g−1, after 5000th charge-discharge cycles. These results highlight the potential of MCo/GO 20 composites as a promising electrode material for next-generation supercapacitor application.
二维配位聚合物(CPs)由于其层状结构促进了与一维和二维碳材料的强界面相互作用,在电化学储能领域受到了广泛的关注。然而,CPs通常存在比电容有限和结构稳定性差的问题。集成导电碳组件可以有效地克服这些缺点,利用协同效应来提高整体电荷存储能力。本文报道了一种Co(II)基配位聚合物[Co(PDA)(H₂O)]的溶剂热合成方法。用单晶x射线衍射(SC-XRD)分析了MCo的结构,发现其底层为hcb型网状结构。随后,将MCo与多壁碳纳米管(MWCNTs)和氧化石墨烯(GO)结合,分别称为MCo/CNT和MCo/GO,制备复合材料。通过FESEM、HR-TEM和XPS对复合材料的形貌和化学成分进行了表征。对对称超级电容器(SSC)和非对称超级电容器(ASC)器件的电化学分析表明,ASC器件具有更好的比电容(Sp.CP.)。在0.5 A g−1电流密度下,MCo、MCo/ cnt100和MCo/GO 20的比电容分别为14.54、287.13和373.12 F g−1。在0.5 A g−1时,MCo/GO 20的能量密度和功率密度分别为132.6 Wh kg−1和400 W kg−1。在完成10,000次 充放电循环后,ASC器件保持了68%的电容,表现出良好的循环稳定性。此外,幂律分析表明,双电层电容(EDLC)主要表现为b值在0.5 ~ 1之间。作为实际演示,ASC设备成功地为红色、多色迪斯科和白色led供电,在充电60 秒后保持120 秒的照明。此外,在PVA/KOH凝胶电解质下,ASC柔性MCo/GO 20器件在0.5 a g−1电流密度下的sp. cp值为461.03 F g−1,能量密度为164.02 Wh kg−1,在6 a g−1电流密度下,经过5000次充放电循环后的电容保持率为87%。这些结果突出了MCo/GO 20复合材料作为下一代超级电容器电极材料的潜力。
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引用次数: 0
Assessing the arbitrage of integrating a molten salt thermal energy storage (TES) into a coal-fired combined heat and power (CHP) plant 评估将熔盐热储能(TES)集成到燃煤热电联产(CHP)电厂的套利
IF 8.9 2区 工程技术 Q1 ENERGY & FUELS Pub Date : 2026-02-05 DOI: 10.1016/j.est.2026.120817
Congyu Wang , Luyun Wang , Fangfang Chen , Hongmei Cao , Lin Gao , Shuang Tian , Wei Wang , Qie Sun
The integration of molten salt thermal energy storage (TES) into coal-fired power plants has been increasingly recognized as an effective approach for operational flexibility enhancement. However, limited research has focused on the arbitrage of the molten salt TES-integrated combined heat and power (CHP) plant in electricity markets. This study fills the research gap by developing an operational optimization model for a molten salt TES-integrated CHP plant, which maximizes its profit by considering real-time electricity prices and heating loads. Results show that integrating an 800 MWh molten salt TES into a 330 MW CHP plant can improve the plant's annual profit from 67.5 to 83.7 million RMB, primarily through capitalizing on peak-valley electricity price differences and expanding industrial heating capacity. Moreover, the TES integration can gain greater economic benefits in heating seasons compared to summer months. The net present value (NPV) of this TES integration is 62.7 million RMB, and the payback period is 10.0 years. Furthermore, the sensitivity analysis indicates that, compared to the baseline capacity of 800 MWh, a 40% decrease in the total energy storage capacity would improve the NPV up to 83.0 million RMB and shorten the payback period to 7.1 years. In addition, when the electricity prices rise by +60% from the baseline, the NPV of the TES integration would increase to 177.3 million RMB, representing an increase of 182%. This study provides insights to the planning and operation of molten salt TES and its integration in CHP plants.
将熔盐储热系统(TES)集成到燃煤电厂中,已被越来越多地认为是提高运行灵活性的有效途径。然而,关于熔盐tes集成热电联产(CHP)电厂在电力市场上的套利研究有限。本研究通过建立熔盐tes集成热电联产电厂的运行优化模型来填补研究空白,该模型考虑实时电价和热负荷,使其利润最大化。结果表明,将一个800兆瓦时的熔盐TES并入一个330兆瓦的热电联产电厂,主要通过利用峰谷电价差异和扩大工业供热能力,可以将电厂的年利润从6750万元提高到8370万元。此外,与夏季相比,TES集成可以在采暖季节获得更大的经济效益。本次TES整合的净现值(NPV)为6270万元,投资回收期为10年。敏感性分析表明,与800兆瓦时的基线容量相比,总储能容量减少40%可使净现值提高8300万元,投资回收期缩短至7.1年。此外,当电价较基线上涨+60%时,TES整合的净现值将增加到1.773亿元,增长182%。本研究为熔盐TES的规划和运行及其在热电联产电厂的整合提供了见解。
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引用次数: 0
State of health estimation for battery modules based on multimodal expansion force-voltage features 基于多模态膨胀力-电压特征的电池模块健康状态估计
IF 8.9 2区 工程技术 Q1 ENERGY & FUELS Pub Date : 2026-02-05 DOI: 10.1016/j.est.2026.120961
Lili Gong , Dan Yang , Qing Xu , Kai Sun , Di Hu , Tao Li , Peng Tan
Accurate estimation of the state of health (SOH) of lithium-ion battery modules is essential for the timely monitoring of aging and the prevention of sudden performance declines. Since single electrochemical features often fail to comprehensively capture the internal inconsistencies and aging dynamics within battery modules, a novel SOH estimation framework integrating multimodal features from voltage and expansion force is herein proposed. Degradation tests are conducted on battery modules under varying initial preload forces, with expansion force and voltage data synchronously acquired during cyclic aging. Multimodal feature factors are derived directly from the expansion-voltage profiles to construct a combined feature set that reflects the overall aging behavior of the modules. By integrating Bayesian optimization (BO) with a long short-term memory (LSTM) network, a robust SOH estimation model is established using six multimodal expansion force-voltage features as inputs. The experimental results show that the maximum relative error of the proposed method is within 1.1%. This multimodal framework establishes a more comprehensive and robust feature set, providing a highly resilient solution for module health management.
准确估计锂离子电池模块的健康状态(SOH)对于及时监测老化和防止性能突然下降至关重要。针对单一电化学特征往往无法全面捕捉电池模块内部不一致性和老化动态的问题,提出了一种基于电压和膨胀力的多模态特征的SOH估计框架。对电池模块进行不同初始预紧力下的退化试验,同步获取循环老化过程中的膨胀力和电压数据。多模态特征因子直接从扩展电压曲线中导出,以构建反映模块整体老化行为的组合特征集。将贝叶斯优化(BO)与长短期记忆(LSTM)网络相结合,以6个多模态膨胀力-电压特征为输入,建立了稳健的SOH估计模型。实验结果表明,该方法的最大相对误差在1.1%以内。此多模式框架建立了更全面、更健壮的功能集,为模块运行状况管理提供了高度弹性的解决方案。
{"title":"State of health estimation for battery modules based on multimodal expansion force-voltage features","authors":"Lili Gong ,&nbsp;Dan Yang ,&nbsp;Qing Xu ,&nbsp;Kai Sun ,&nbsp;Di Hu ,&nbsp;Tao Li ,&nbsp;Peng Tan","doi":"10.1016/j.est.2026.120961","DOIUrl":"10.1016/j.est.2026.120961","url":null,"abstract":"<div><div>Accurate estimation of the state of health (SOH) of lithium-ion battery modules is essential for the timely monitoring of aging and the prevention of sudden performance declines. Since single electrochemical features often fail to comprehensively capture the internal inconsistencies and aging dynamics within battery modules, a novel SOH estimation framework integrating multimodal features from voltage and expansion force is herein proposed. Degradation tests are conducted on battery modules under varying initial preload forces, with expansion force and voltage data synchronously acquired during cyclic aging. Multimodal feature factors are derived directly from the expansion-voltage profiles to construct a combined feature set that reflects the overall aging behavior of the modules. By integrating Bayesian optimization (BO) with a long short-term memory (LSTM) network, a robust SOH estimation model is established using six multimodal expansion force-voltage features as inputs. The experimental results show that the maximum relative error of the proposed method is within 1.1%. This multimodal framework establishes a more comprehensive and robust feature set, providing a highly resilient solution for module health management.</div></div>","PeriodicalId":15942,"journal":{"name":"Journal of energy storage","volume":"153 ","pages":"Article 120961"},"PeriodicalIF":8.9,"publicationDate":"2026-02-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146191759","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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Journal of energy storage
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