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Performance and fire suppression efficiency of potassium salt-modified dry water agents 钾盐改性干水剂的性能及灭火效果
IF 4.2 3区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2026-04-01 Epub Date: 2025-11-24 DOI: 10.1016/j.jlp.2025.105869
Weiyi Ding , Feihao Zhu , Jiaping Zhao , Jun-Cheng Jiang , An-Chi Huang
A novel dry water (DW) fire extinguishing material was developed to enhance the extinguishing efficiency of early-stage oil spill fires. The material is composed of a hydrophobic fumed silica shell and an aqueous core that has been modified with four potassium salts: potassium carbonate (K2CO3), potassium bicarbonate (KHCO3), potassium acetate (CH3COOK), and potassium oxalate (K2C2O4). Bulk density, water retention, fluidity, particle size distribution, and thermogravimetric behaviour were the physical and thermal properties of the modified DW samples that were systematically assessed. Potassium salt-modified DW outperformed unmodified DW in fire suppression experiments conducted on n-heptane pool fires, achieving superior cooling performance and faster flame extinction speed. It is important to note that the shortest extinguishing times were obtained by DW modified with potassium oxalate and potassium carbonate, which were 3 and 4 s, respectively. Within 150 s, all formulations achieved a reduction in core flame temperatures below 200 °C, surpassing the performance of commercial ABC dry powder agents. These results offer an optimistic foundation for the creation of high-efficiency, environmentally friendly fire extinguishing materials that are suitable for oil-related fire situations.
为提高早期溢油火灾的灭火效率,研制了一种新型干水灭火材料。该材料由疏水气相二氧化硅外壳和水芯组成,水芯经碳酸钾(K2CO3)、碳酸氢钾(KHCO3)、醋酸钾(CH3COOK)和草酸钾(K2C2O4)四种钾盐改性。系统评估了改性DW样品的体积密度、保水率、流动性、粒径分布和热重行为。在正庚烷池火灾的灭火实验中,钾盐改性DW比未改性DW具有更好的冷却性能和更快的灭火速度。值得注意的是,草酸钾和碳酸钾改性DW的灭火时间最短,分别为3 s和4 s。在150秒内,所有配方都实现了将核心火焰温度降低到200℃以下,超过了商用ABC干粉剂的性能。这些结果为创造适用于石油相关火灾的高效、环保灭火材料提供了乐观的基础。
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引用次数: 0
Dynamic optimization of hazardous materials vehicle transportation routes based on real-time risk 基于实时风险的危险品车辆运输路线动态优化
IF 4.2 3区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2026-04-01 Epub Date: 2025-11-23 DOI: 10.1016/j.jlp.2025.105864
Zhanzhong Wang, Tingting Li, Meng Yang, Zhihao Wu
—As industrialization continues to advance, the volume of hazardous materials transportation continues to increase. Given the inherent risks associated with hazardous materials, such as flammability and explosiveness, accidents involving hazardous materials vehicles during transportation can have catastrophic consequences. To mitigate the risk of accidents during hazardous materials transportation caused by factors such as road congestion or sudden incidents, this paper proposes a real-time risk-based dynamic optimization model for dangerous materials transportation routes, guiding vehicles to avoid congested or incident-affected sections of the road. A dual-objective initial path planning model for transportation risk and cost is constructed to obtain the optimal driving path for hazardous materials vehicles under static road network conditions. Based on the initial path, vulnerability indicators are applied to evaluate real-time road segment risks, and the optimal path is selected to minimize dynamic risks, thereby achieving dynamic guidance for hazardous materials vehicles. Taking the road network of Changchun City, Jilin Province, China, as an example, this paper verifies that the proposed model can effectively reduce potential risks during transportation and enhance the safety of the road transportation network. This paper provides a dynamic path optimization algorithm to assess risk levels in different regions at different times, achieving dynamic optimization of hazardous materials vehicle routes.
——随着工业化进程的不断推进,危险物品运输量不断增加。由于危险材料具有可燃性和爆炸性等固有风险,运输过程中涉及危险材料车辆的事故可能造成灾难性后果。为降低因道路拥堵或突发事件等因素导致危险品运输过程中发生事故的风险,本文提出了一种基于风险的危险品运输路线实时动态优化模型,引导车辆避开拥堵或受事故影响的路段。为了获得静态路网条件下危险品车辆的最优行驶路径,建立了考虑运输风险和成本的双目标初始路径规划模型。在初始路径的基础上,应用脆弱性指标实时评价路段风险,选择最优路径,使动态风险最小化,实现对危险品车辆的动态引导。以吉林省长春市道路网络为例,验证了所提出的模型可以有效降低运输过程中的潜在风险,提高道路运输网络的安全性。本文提出了一种动态路径优化算法,对不同区域、不同时间的危险等级进行评估,实现危险品车辆路径的动态优化。
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引用次数: 0
Research on the variation of CO concentration and temperature in the directional drilling process 定向钻井过程中CO浓度和温度的变化规律研究
IF 4.2 3区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2026-01-01 Epub Date: 2025-08-29 DOI: 10.1016/j.jlp.2025.105772
Furu Kang , Jiahao Song , Jiaxiang Zhang , Chao Pan , Dengke Wang , Zujin Bai , Shixing Fan , Jun Deng
During drilling operations, the drill bit continuously rubs against the coal seam, generating heat and releasing CO gas, which may lead to severe CO poisoning accidents. To address this issue, we construct an experimental monitoring platform to analyze the variations in CO concentration and temperature during coal seam drilling under different drilling feed rates and drilling rig rotational speeds. The results indicate that no CO is produced at the initial stage of drilling. Subsequently, CO concentration increases linearly, accompanied by an increase in the CO generation rate, which leads to an exponential increase in CO concentration. A higher drilling rig rotational speed results in a faster CO generation rate and higher CO concentration. Similarly, a higher drilling feed rate also accelerates the CO generation rate. Specifically, at a drilling rig rotational speed of 990 r/min and a drilling feed rate of 0.5 cm/s, the CO concentration reaches a peak of 29.6 ppm. The temperatures of both the drill bit and coal body initially increase rapidly and then stabilize. Higher drilling rig rotational speeds lead to faster temperature rises in both the drill bit and coal body, causing them to enter the steady growth phase earlier and resulting in higher final temperatures. In contrast, higher drilling feed rates cause the drill bit temperature to rise more rapidly, while the coal body temperature increases at a slower rate. As a result, both temperatures reach the steady growth phase earlier but lead to a lower final temperature. At a drilling rig rotational speed of 990 r/min and a drilling feed rate of 1.5 cm/s, the drill bit and coal body temperatures enter the steady growth phase earliest, at 30 s. At a drilling rig rotational speed of 990 r/min and a drilling feed rate of 0.5 cm/s, the highest temperatures for the drill bit and coal body are reached, 118.2 °C and 68.2 °C, respectively. The temperature rise in both the drill bit and coal body follows a linear relationship with the average CO generation rate. This study provides valuable insights for ensuring safety during coal seam drilling operations.
在钻井作业中,钻头与煤层不断摩擦,产生热量,释放一氧化碳气体,可能导致严重的一氧化碳中毒事故。为此,搭建实验监测平台,分析不同进给速度和钻机转速下煤层钻探过程中CO浓度和温度的变化。结果表明:钻进初期不产生CO;随后,CO浓度线性增加,同时CO生成速率增加,从而导致CO浓度呈指数增长。钻机转速越高,CO生成速率越快,CO浓度越高。同样,较高的钻进进给速率也会加速CO的生成速率。其中,当钻机转速为990 r/min,进给速度为0.5 cm/s时,CO浓度达到峰值29.6 ppm。钻头和煤体温度均呈现先快速升高后趋于稳定的趋势。钻机转速越高,钻头和煤体升温越快,进入稳定生长阶段越早,最终温度也越高。相反,较高的进给速度导致钻头温度上升更快,而煤体温度上升速度较慢。结果,两种温度均较早达到稳定生长阶段,但最终温度较低。当钻机转速为990 r/min,进给速度为1.5 cm/s时,钻头和煤体温度在30 s时最早进入稳定增长阶段。当钻机转速为990 r/min,进给速度为0.5 cm/s时,钻头和煤体的最高温度分别为118.2℃和68.2℃。钻头和煤体的温升均与CO平均生成速率呈线性关系。该研究为确保煤层钻井作业的安全提供了有价值的见解。
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引用次数: 0
Network-aware multi-step hazard prediction using temporal knowledge graphs: A chemical industry case study 基于时序知识图的网络感知多步危害预测:一个化工案例研究
IF 4.2 3区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2026-01-01 Epub Date: 2025-09-03 DOI: 10.1016/j.jlp.2025.105787
Jian Liu , Zhuqing Zhang , Rui Feng
Proactive hazard prediction in complex industrial environments like the chemical sector is critical yet challenging due to dynamic, interconnected risks often overlooked by traditional methods. Existing data-driven approaches frequently fall short by failing to model evolving temporal dependencies and multi-step risk propagation across diverse hazard relationships. To overcome these limitations, this study introduces the Temporal Knowledge Graph-Autoregressive Multistep Prediction Model (TKG-AM). Our core innovation lies in representing dynamic, multi-relational hazard data using Temporal Knowledge Graphs (TKGs) and coupling this rich representation with an autoregressive deep learning engine specifically designed for accurate multi-step forecasting, providing crucial lead time for interventions. Validated on extensive hazard records from a chemical industrial park in Ningxia, China, TKG-AM demonstrated strong predictive power, achieving a direct hit rate (Hits@1) of 58.5 % and top-ten accuracy (Hits@10) of 67.3 %. Our analysis revealed the network's small-world properties, facilitating rapid risk diffusion, and identified 75 critical bridging nodes central to information flow. We further analyzed how network topology and specific relationship types impact prediction accuracy, finding, for instance, that inter-community predictions are inherently more challenging. To enhance practical application, we developed a data-driven prediction score threshold enabling risk prioritization (e.g., scores >20 yielding >90 % accuracy). These integrated findings validate TKG-AM as a robust and insightful methodology, offering significant improvements in the efficiency, specificity, and strategic targeting of hazard prevention and differentiated risk management efforts in the chemical industry.
在化工行业等复杂的工业环境中,由于动态的、相互关联的风险往往被传统方法所忽视,因此主动危害预测至关重要,但也具有挑战性。现有的数据驱动方法由于无法对不断变化的时间依赖性和跨不同风险关系的多步骤风险传播进行建模而经常存在不足。为了克服这些局限性,本研究引入了时序知识图-自回归多步预测模型(TKG-AM)。我们的核心创新在于使用时间知识图(TKGs)来表示动态的、多关系的危险数据,并将这种丰富的表示与专门为精确的多步预测设计的自回归深度学习引擎相结合,为干预提供关键的提前期。TKG-AM在中国宁夏某化工园区的大量危害记录中进行了验证,显示出强大的预测能力,直接命中率(Hits@1)达到58.5%,前十名准确率(Hits@10)达到67.3%。我们的分析揭示了网络的小世界特性,促进了风险的快速扩散,并确定了信息流中心的75个关键桥接节点。我们进一步分析了网络拓扑和特定关系类型如何影响预测准确性,发现,例如,社区间的预测本质上更具挑战性。为了加强实际应用,我们开发了一个数据驱动的预测分数阈值,使风险优先级(例如,分数>;20产生>; 90%的准确率)。这些综合研究结果验证了TKG-AM是一种强大而富有洞察力的方法,在化学工业的危害预防和差异化风险管理工作的效率、特异性和战略目标方面提供了重大改进。
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引用次数: 0
Incorporating cybersecurity measures around industrial control systems (ICS) within the petrochemical sector 围绕石化行业的工业控制系统(ICS)采取网络安全措施
IF 4.2 3区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2026-01-01 Epub Date: 2025-09-21 DOI: 10.1016/j.jlp.2025.105803
Lushen Rajaruthnam, Rina Peach
The fast adoption of technologies that enable the Fourth Industrial Revolution (4IR) in the South African industrial sector has been well noted, and is advancing to meet global pressures. Cybersecurity countermeasures to protect and safeguard the expanding interconnected nature of several industrial sectors have not kept pace. The steadfast march toward digitalization and Industrial Internet of Things (IIoT) optimization increases industrial control systems' (ICSs) vulnerabilities, and they become ripe targets for the wicked. This study aimed to identify the current level of the cybersecurity maturity of ICS assets in the South African petrochemical sector and to investigate the root causes of that level of maturity. Extensive research was done into industry best practices, lessons learned, and global governing bodies of knowledge. A target maturity (from NIST 800-xx and IEC 62443-x-x) and possible contributing factors to poor adoption were identified and tested with a population in a cluster of South African petrochemical facilities. The research propositions concurred with the results, showing systemic barriers to adequate ICS cybersecurity adoption. A risk-based approach and a high-level recommendation roadmap were developed to address poor maturity levels. More specific sector studies could be conducted in the future to refine the findings, but this framework and roadmap could be implemented directly as a starting point for an organization's ICS cybersecurity journey.
南非工业部门迅速采用了使第四次工业革命(4IR)成为可能的技术,并正在推进以应对全球压力。保护和维护多个工业部门日益扩大的互联性的网络安全对策没有跟上步伐。数字化和工业物联网(IIoT)优化的稳步发展增加了工业控制系统(ics)的脆弱性,它们成为邪恶分子的成熟目标。本研究旨在确定南非石化行业ICS资产的网络安全成熟度的当前水平,并调查该成熟度水平的根本原因。对行业最佳实践、经验教训和全球知识管理机构进行了广泛的研究。目标成熟度(来自NIST 800-xx和IEC 62443-x-x)和可能导致采用率低的因素被确定并在南非石化设施集群中进行了测试。研究主张与结果一致,显示了充分采用ICS网络安全的系统性障碍。开发了基于风险的方法和高级建议路线图,以解决较差的成熟度级别。未来可以进行更具体的行业研究,以完善研究结果,但该框架和路线图可以直接作为组织ICS网络安全之旅的起点实施。
{"title":"Incorporating cybersecurity measures around industrial control systems (ICS) within the petrochemical sector","authors":"Lushen Rajaruthnam,&nbsp;Rina Peach","doi":"10.1016/j.jlp.2025.105803","DOIUrl":"10.1016/j.jlp.2025.105803","url":null,"abstract":"<div><div>The fast adoption of technologies that enable the Fourth Industrial Revolution (4IR) in the South African industrial sector has been well noted, and is advancing to meet global pressures. Cybersecurity countermeasures to protect and safeguard the expanding interconnected nature of several industrial sectors have not kept pace. The steadfast march toward digitalization and Industrial Internet of Things (IIoT) optimization increases industrial control systems' (ICSs) vulnerabilities, and they become ripe targets for the wicked. This study aimed to identify the current level of the cybersecurity maturity of ICS assets in the South African petrochemical sector and to investigate the root causes of that level of maturity. Extensive research was done into industry best practices, lessons learned, and global governing bodies of knowledge. A target maturity (from NIST 800-xx and IEC 62443-x-x) and possible contributing factors to poor adoption were identified and tested with a population in a cluster of South African petrochemical facilities. The research propositions concurred with the results, showing systemic barriers to adequate ICS cybersecurity adoption. A risk-based approach and a high-level recommendation roadmap were developed to address poor maturity levels. More specific sector studies could be conducted in the future to refine the findings, but this framework and roadmap could be implemented directly as a starting point for an organization's ICS cybersecurity journey.</div></div>","PeriodicalId":16291,"journal":{"name":"Journal of Loss Prevention in The Process Industries","volume":"99 ","pages":"Article 105803"},"PeriodicalIF":4.2,"publicationDate":"2026-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145220588","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Establishing risk tolerance criteria for incident scenarios in LOPA 为LOPA中的事件情景建立风险承受标准
IF 4.2 3区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2026-01-01 Epub Date: 2025-09-16 DOI: 10.1016/j.jlp.2025.105799
Aynur Galeev
Layer of Protection Analysis (LOPA) is widely used in process industries as a semi-quantitative method for assessing risks of incident scenarios and evaluating their tolerability. This paper examines a key challenge in LOPA implementation: defining risk tolerance criteria for individual scenarios. It analyzes several approaches to addressing this challenge, including the direct assignment of risk targets to individual scenarios and the allocation of either individual or societal risk criteria to individual scenarios. The strengths, limitations, and suitable applications of each approach are discussed. The paper provides guidelines for establishing risk tolerance criteria for individual scenarios and calculating scenario frequencies consistent with these criteria. These guidelines combine recommendations extracted and systematized from relevant publications with original contributions.
保护层分析(LOPA)作为一种半定量的方法,广泛应用于过程工业中,用于评估事件情景的风险和评估其容忍度。本文研究了LOPA实现中的一个关键挑战:为单个场景定义风险承受标准。它分析了应对这一挑战的几种方法,包括将风险目标直接分配给个别情景,以及将个人或社会风险标准分配给个别情景。讨论了每种方法的优点、局限性和适合的应用。本文提供了为个别情景建立风险承受标准和计算与这些标准一致的情景频率的指导方针。这些指南结合了从相关出版物中提取并系统化的建议和原始贡献。
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引用次数: 0
Study on the scope of impact of consequences of leakage of hydrogen blended with natural gas pipeline 天然气混氢管道泄漏后果影响范围的研究
IF 4.2 3区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2026-01-01 Epub Date: 2025-09-29 DOI: 10.1016/j.jlp.2025.105810
Jun Li , Ding Li , Xuting Du , Zengfeng Jin , Xin Xin
In the context of low-carbon energy transition, Hydrogen blended with natural gas (HBNG) technology has attracted much attention due to its carbon reduction potential, but its leakage risk poses higher requirements for safety control. This study aims to analyze the impact of the consequences of HBNG pipeline leakage. The PHAST software is used to analyze the consequences of leakage accidents with its characteristics, and the role of three factors, namely, hydrogen blending ratio, leakage hole diameter and ambient wind speed, on the range of influence of jet thermal radiation and explosion overpressure is investigated by constructing a physical model and applying numerical simulation, combining the flame cone model and the TNT-equivalent method. The results show that the influence range of jet fire radiation increases with the increase of leakage hole diameter and ambient wind speed, but decreases with the increase of hydrogen blending ratio; the influence range of explosion overpressure increases with the increase of leakage hole diameter, decreases with the increase of ambient wind speed, and increases first and then decreases with the increase of hydrogen blending ratio. Based on this result, the corresponding hazardous and safety zones are delineated. This study can provide some technical support for the development of safety measures for jet fire and explosion accidents caused by HBNG leakage.
在低碳能源转型背景下,天然气混氢技术因其减碳潜力备受关注,但其泄漏风险对安全控制提出了更高的要求。本研究旨在分析HBNG管道泄漏后果的影响。利用PHAST软件分析泄漏事故的后果及其特点,结合火焰锥模型和tnt等效法,通过构建物理模型并应用数值模拟的方法,研究了氢气掺合比、泄漏孔直径和环境风速三个因素对射流热辐射和爆炸超压影响范围的作用。结果表明:射流火辐射的影响范围随着泄漏孔直径和环境风速的增大而增大,但随着掺氢比的增大而减小;爆炸超压的影响范围随泄漏孔直径的增大而增大,随环境风速的增大而减小,随掺氢比的增大先增大后减小。在此基础上,划定了相应的危险区和安全区。该研究可为HBNG泄漏射流火灾爆炸事故安全措施的制定提供一定的技术支持。
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引用次数: 0
Scenario-based resilience framework for gas compressor stations under fire and explosion hazards 火灾和爆炸危险下燃气压缩站的情景复原框架
IF 4.2 3区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2026-01-01 Epub Date: 2025-09-25 DOI: 10.1016/j.jlp.2025.105809
Amir Aminshokravi, Gholamreza Heravi, Behnood Rahbari, Mohadese Elahi
Gas compressor stations are pivotal nodes in gas transmission networks; therefore, assessment of their resilience against fire and explosion hazards is crucial for improving process safety. While traditional process safety risk assessments identify potential hazards, a critical gap exists in quantifying the dynamic resilience of these plants following major incidents. This study presents a novel approach in the field of process safety by introducing an integrated framework to model and quantify the resilience of gas compressor stations against fire and explosion. The methodology combines HAZID-based hazard identification with modelling the consequences of fires and explosions using PHAST software. To move beyond static consequence metrics, a time-dependent Resilience Loss (RL) index is proposed, which captures both functional degradation and the recovery process, a key component of loss prevention. A case study of the Dorahan Gas Compressor Station demonstrates the framework’s application. Results illustrate that the most vulnerable sections of gas compressor stations that lead to the most severe resilience degradation are turbocompressors and the type of flange connections. Finally, a sensitivity analysis proves the impact of increasing repair crew sizes in reducing logistical delay and recovery time. The approach introduces a novel tool for process safety decision-making and the capability to use risk-informed approaches to improve the resilience of gas compressor stations.
气体压缩站是输气网络中的关键节点;因此,评估其对火灾和爆炸危险的恢复能力对于提高工艺安全性至关重要。虽然传统的过程安全风险评估识别潜在的危害,但在量化这些工厂在重大事件后的动态恢复能力方面存在严重差距。本研究通过引入一个集成框架来模拟和量化气体压缩站对火灾和爆炸的弹性,为过程安全领域提供了一种新的方法。该方法将基于hazid的危险识别与使用PHAST软件对火灾和爆炸后果进行建模相结合。为了超越静态后果度量,提出了一个时间相关的弹性损失(RL)指数,该指数可以捕获功能退化和恢复过程,这是损失预防的关键组成部分。以Dorahan燃气压缩站为例,说明了该框架的应用。结果表明,气压站中最容易导致回弹退化最严重的部位是涡轮压气机和法兰连接类型。最后,通过敏感性分析证明了增加维修队伍规模对减少后勤延误和恢复时间的影响。该方法引入了一种用于过程安全决策的新工具,并能够使用风险知情方法来提高气体压缩站的弹性。
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引用次数: 0
A novel integrated multi-source heterogeneous uncertainty fusion framework for reducing the complexity of uncertainty characterization in domino effect risk assessment 一种新型集成多源异构不确定性融合框架,降低了多米诺效应风险评估中不确定性表征的复杂性
IF 4.2 3区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2026-01-01 Epub Date: 2025-09-23 DOI: 10.1016/j.jlp.2025.105804
Hongrui Jiang, Long Ding, Jie Ji, Jiping Zhu
The risk assessment result of domino accidents in chemical industry can be influenced by uncertainty, and the multi-source heterogeneous data fusion makes the uncertainty analysis, especially the characterization, complex and difficult. This paper proposed an integrated framework of uncertainty analysis considering multi-source heterogeneous data, and provided different characterization methods for common multi-source heterogeneous data types in order to reduce the complexity of uncertainty analysis. In order to deal with the influence of expert cognitive bias on fuzzy information, the interval type-2 fuzzy set suitable for domino accidents in chemical industry was established based on questionnaire data. The proposed framework was applied to a real tank farm to obtain the intervals and the corresponding probability envelopes of time to failure and escalation probability, and the most likely accident scenario. Compared with the competitive method, the superiority of the proposed method was verified. The sensitivity analysis of inherent safety design parameter was carried out to obtain the priority of the material, size and storage of LNG storage tank considering the fire-induced domino risk. The integrated framework can reduce the complexity of uncertainty analysis of chemical domino accident risk assessment and provide reference information for decision makers to control domino effect.
化工行业多米诺骨牌事故风险评估结果会受到不确定性的影响,多源异构数据的融合使得不确定性分析,特别是不确定性表征变得复杂和困难。本文提出了考虑多源异构数据的不确定性分析集成框架,并针对常见的多源异构数据类型提供了不同的表征方法,以降低不确定性分析的复杂性。为了处理专家认知偏差对模糊信息的影响,在问卷调查数据的基础上,建立了适用于化工多米诺骨牌事故的区间2型模糊集。将该框架应用于实际油库,得到了故障时间间隔和相应的概率包络线、升级概率,以及最可能发生的事故情景。通过与竞争方法的比较,验证了该方法的优越性。对固有安全设计参数进行敏感性分析,得到考虑火灾多米诺骨牌风险的LNG储罐材料、尺寸和储罐的优先级。该综合框架可降低化学多米诺事故风险评估不确定性分析的复杂性,为决策者控制多米诺效应提供参考信息。
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引用次数: 0
Enhancing atomization and fire-Suppression efficiency of perfluorohexanone using swirl nozzles across a range of injection pressures 在一定喷射压力范围内使用旋流喷嘴增强全氟己酮的雾化和灭火效率
IF 4.2 3区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2026-01-01 Epub Date: 2025-09-19 DOI: 10.1016/j.jlp.2025.105802
Zhilei Yu , Guohui Li , Hongzhang Jia , Haibin Dong , Junchao Zhao , Heping Zhang
This study investigates the atomization, diffusion, and fire suppression performance of perfluorohexanone, discharged through a swirl nozzle in a 1 m3 sealed chamber, aiming to enhance the total flooding efficiency of this environmentally friendly Halon alternative. For the first time, the coupling effect of swirl nozzle geometry and injection pressure on droplet size distribution, vapor diffusion, and suppression effectiveness is systematically analyzed through combined experiments and computational fluid dynamics (CFD) simulations. Increasing the injection pressure from 0.3 to 0.5 MPa reduced D90 and D50 by 22 % and 29 %, respectively, which accelerated vaporization and improved the cooling rate. Correspondingly, the average chamber temperature declined from 25 °C to 7.2 °C, achieving a 49 % cooling efficiency improvement. Fire suppression time for upper-layer flames was reduced by 47 %, and the total flooding concentration was achieved within 3.3s, with CFD predictions closely matching experimental data. Lower nozzle heights improved suppression of near-ground flames, whereas higher positions enhanced coverage and atomization in upper layers. These results provide quantitative guidance for optimizing the design and deployment of perfluorohexanone total flooding systems in confined environments.
本研究研究了全氟己酮的雾化、扩散和灭火性能,通过旋流喷嘴在1 m3密封腔室中排放,旨在提高这种环保替代品的总驱油效率。通过实验与计算流体动力学(CFD)模拟相结合,首次系统分析了旋流喷嘴几何形状和喷射压力对液滴尺寸分布、蒸汽扩散和抑制效果的耦合效应。将喷射压力从0.3 MPa提高到0.5 MPa, D90和D50分别降低22%和29%,加速了汽化,提高了冷却速度。相应的,平均腔温从25°C下降到7.2°C,冷却效率提高49%。上层火焰的灭火时间缩短了47%,总淹没浓度在3.3s以内,CFD预测与实验数据基本吻合。较低的喷嘴高度改善了近地火焰的抑制,而较高的位置增强了上层的覆盖和雾化。这些结果为密闭环境下全氟己酮全驱体系的优化设计和部署提供了定量指导。
{"title":"Enhancing atomization and fire-Suppression efficiency of perfluorohexanone using swirl nozzles across a range of injection pressures","authors":"Zhilei Yu ,&nbsp;Guohui Li ,&nbsp;Hongzhang Jia ,&nbsp;Haibin Dong ,&nbsp;Junchao Zhao ,&nbsp;Heping Zhang","doi":"10.1016/j.jlp.2025.105802","DOIUrl":"10.1016/j.jlp.2025.105802","url":null,"abstract":"<div><div>This study investigates the atomization, diffusion, and fire suppression performance of perfluorohexanone, discharged through a swirl nozzle in a 1 m<sup>3</sup> sealed chamber, aiming to enhance the total flooding efficiency of this environmentally friendly Halon alternative. For the first time, the coupling effect of swirl nozzle geometry and injection pressure on droplet size distribution, vapor diffusion, and suppression effectiveness is systematically analyzed through combined experiments and computational fluid dynamics (CFD) simulations. Increasing the injection pressure from 0.3 to 0.5 MPa reduced D90 and D50 by 22 % and 29 %, respectively, which accelerated vaporization and improved the cooling rate. Correspondingly, the average chamber temperature declined from 25 °C to 7.2 °C, achieving a 49 % cooling efficiency improvement. Fire suppression time for upper-layer flames was reduced by 47 %, and the total flooding concentration was achieved within 3.3s, with CFD predictions closely matching experimental data. Lower nozzle heights improved suppression of near-ground flames, whereas higher positions enhanced coverage and atomization in upper layers. These results provide quantitative guidance for optimizing the design and deployment of perfluorohexanone total flooding systems in confined environments.</div></div>","PeriodicalId":16291,"journal":{"name":"Journal of Loss Prevention in The Process Industries","volume":"99 ","pages":"Article 105802"},"PeriodicalIF":4.2,"publicationDate":"2026-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145155222","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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Journal of Loss Prevention in The Process Industries
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