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Tuning Magnetic Properties of Thick CoFeB Film by Interlayer Coupling in Trilayer Structured Thin Films 用三层结构薄膜的层间耦合调谐厚CoFeB薄膜的磁性能
Pub Date : 2018-01-01 DOI: 10.4172/2169-0022.1000437
Anabil Gayen, J. Aroutchelvane, K. Umadevi, P. Alagarsamy
This study deals with tuning magnetic properties of a thick amorphous (a-)Co20Fe60B20 (CoFeB262) film by using interlayer magnetic coupling in trilayer structured films of [CoFeB262 (100 nm)/[Cr,Ta (x nm)]/CoFeB262 (y nm)] with y=2-50, xCr=0.75, 2 and xTa=1, 4. All the films are deposited directly on thermally oxidized Si substrate at ambient temperature using magnetron sputtering. The as-deposited a-CoFeB262 (100 nm) film exhibits magnetic stripe domain and transcritical hysteresis loop due to large effective magnetic anisotropy caused by stress induced during deposition of the films. On the other hand, the shape of magnetic hysteresis (M-H) loops in trilayer films transforms from transcritical to rectangular shaped one with enhanced remanence ratio (MR/MS) of ≥ 75% and single magnetization reversal behavior. This effectively reduces coercivity (HC) and field required to saturate magnetization (HS) in trilayer films. However, the changes in the loop shape and reductions in HC and HS depend strongly on x and y. Magnetic domain images obtained using Kerr microscopy in trilayer films show a rapid switching of large-sized domains along easy-axis and weak ripple domains along hard-axis. In addition, the magnetization reversal behavior along the hard-axis strongly depends on x(Cr,Ta). M-H loops obtained at different temperatures between 30 K and 300 K reveal no change in loop shape for trilayer films with small x and y, while the disappearance of shearing and formation of additional steps at low temperatures are observed for films with large x and y. The observed results are explained on the basis of change in interlayer coupling between CoFeB262 layers with x, y and temperature. Furthermore, these results clearly confirm that the magnetic properties of thick CoFeB262 film with stripe domain can easily be tuned into in-plane magnetization by this simple trilayer structured thin films.
本文研究了在[CoFeB262 (100 nm)/[Cr,Ta (x nm)]/CoFeB262 (y nm)] (y =2-50, xCr=0.75, 2, xTa= 1,4)的三层结构薄膜中,利用层间磁耦合对厚非晶(a-)Co20Fe60B20 (CoFeB262)薄膜的磁性能进行调谐。所有薄膜都是在室温下用磁控溅射直接沉积在热氧化的Si衬底上的。沉积的a-CoFeB262 (100 nm)薄膜由于在沉积过程中应力诱导产生较大的有效磁各向异性,呈现出磁条畴和跨临界磁滞回线。另一方面,三层膜中的磁滞环(M-H)由跨临界形状转变为矩形形状,剩磁比(MR/MS)增强≥75%,具有单磁化反转行为。这有效地降低了三层薄膜的矫顽力(HC)和饱和磁化(HS)所需的场。然而,环路形状的变化以及HC和HS的减少强烈依赖于x和y。利用Kerr显微镜在三层薄膜中获得的磁畴图像显示,大尺寸畴沿易轴和弱纹波畴沿硬轴快速切换。此外,沿硬轴的磁化反转行为强烈依赖于x(Cr,Ta)。在30 K和300 K之间的不同温度下得到的M-H环显示,x和y较小的三层膜的环形状没有变化,而x和y较大的三层膜在低温下观察到剪切消失和附加步骤的形成。观察到的结果是基于CoFeB262层间耦合随x、y和温度的变化。此外,这些结果清楚地证实了这种简单的三层结构薄膜可以很容易地将具有条纹畴的CoFeB262厚膜的磁性调谐到面内磁化。
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引用次数: 3
Silver Vanadium Oxide Nanomaterials: Controlled Synthesis by Hydrothermal Method and Efficient Photocatalytic Degradation of Atrazine and CV Dye 纳米氧化银钒材料:水热法控制合成及其对阿特拉津和CV染料的高效光催化降解
Pub Date : 2017-12-29 DOI: 10.4172/2169-0022.1000407
C. ChiingChang, Janah Shaya, F. Huan-Jung, C. Yi-Kuo, C. Han-ting, Chung‐Shin Lu
Silver vanadium oxides have received remarkable attention in recent years because of their stability, suitable band gaps, and relatively superior photocatalytic abilities. This study synthesizes silver vanadates by the hydrothermal method and investigates their photocatalytic abilities for removing crystal violet (CV) and atrazine pollutants under visible-light irradiation. The as-prepared silver vanadates are characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), and UV-vis diffuse reflectance spectra (DRS). Crystal violet and atrazine could be successfully degraded in the presence of silver vanadate catalyst under visiblelight irradiation. The obtained results show complete degradation of crystal violet after 24 h, and over 97% of atrazine was degraded after 72 h of treatment. Moreover, the as-prepared silver vanadate materials show extremely high catalytic stability and maintain stable activity after three catalytic cycles. The scavenger study indicates that •O2− radicals are the main active species, while •OH and h+ play an assistant role in the degradation of CV and atrazine. Liquid chromatography coupled with electrospray ionization mass spectrometry is applied to the analysis of the samples coming from the photocatalytic degradation of CV and atrazine. Potential degradation pathways for atrazine are evaluated exhibiting two different degradation pathways including dechlorination-hydroxylation, alkylic-oxidationde- alkylation. The N-de-methylation of the CV dye takes place in a stepwise manner with the various N-de-methylated intermediate CV species. The excellent activity and photostability reveal that silver vanadate is a promising visiblelight- responsive photocatalyst for water and wastewater treatment.
银钒氧化物由于其稳定性、合适的带隙和相对优越的光催化能力,近年来受到了广泛的关注。本文采用水热法合成了钒酸银,并考察了其在可见光照射下对结晶紫(CV)和阿特拉津污染物的光催化去除能力。采用x射线衍射(XRD)、扫描电镜(SEM)、x射线光电子能谱(XPS)和紫外-可见漫反射光谱(DRS)对制备的钒酸银进行了表征。晶体紫和阿特拉津在钒酸银催化剂存在下,在可见光照射下可成功降解。结果表明,结晶紫在处理24 h后完全降解,阿特拉津在处理72 h后降解率达到97%以上。此外,制备的钒酸银材料表现出极高的催化稳定性,在三次催化循环后仍保持稳定的活性。清除剂研究表明,•O2−自由基是主要的活性自由基,而•OH和h+在CV和阿特拉津的降解中起辅助作用。采用液相色谱-电喷雾电离质谱联用技术对光催化降解CV和阿特拉津的样品进行了分析。对阿特拉津的潜在降解途径进行了评估,展示了两种不同的降解途径,包括脱氯-羟基化,烷基-氧化-烷基化。CV染料的n -去甲基化与各种n -去甲基化的中间CV物种以逐步的方式发生。优异的活性和光稳定性表明,钒酸银是一种很有前途的用于水和废水处理的可见光响应光催化剂。
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引用次数: 1
Newly Developed Nickel-Boron Composite Surface Coatings with Pd Particles: Structural, Mechanical and Corrosion Properties 新研制的含Pd粒子的镍硼复合表面涂层:结构、力学和腐蚀性能
Pub Date : 2017-12-21 DOI: 10.4172/2169-0022.1000406
U. Waware, Hamouda Ams, Pradhan Ka
Ni-B and Ni-B-Pd composite coatings have been electrodeposited from an aqueous electrolyte using direct current. The Ni-B composite coating has been observed to be dense, smooth, and shows a globular, cluster of grains type morphology. On the other hand, the Ni-B-Pd composite coating is observed to be porous, highly rough and shows stacked crystal type morphology. The addition of palladium has significantly improved the crystallite size of the coating. From DSC analysis, it is observed that the Ni-B-Pd composite coating is thermodynamically more stable than the Ni-B composite coating. In spite of larger grain size and higher roughness the Ni-B-Pd coating is observed to exhibit higher hardness (≈40% higher) and elastic modulus (≈70% higher) than that of the Ni-B composite coating. Also, it has been observed to possess better protective property (almost three times) than that of the Ni-B composite coating.
用直流电沉积了Ni-B和Ni-B- pd复合镀层。Ni-B复合镀层致密、光滑,呈球状、颗粒簇状。另一方面,Ni-B-Pd复合镀层具有多孔性、高度粗糙性和叠层晶体型形貌。钯的加入显著改善了涂层的晶粒尺寸。DSC分析表明,Ni-B- pd复合镀层的热稳定性优于Ni-B复合镀层。尽管Ni-B- pd涂层的晶粒尺寸更大,粗糙度更高,但其硬度和弹性模量均比Ni-B复合涂层高约40%和约70%。此外,它还具有比Ni-B复合涂层更好的防护性能(几乎是Ni-B复合涂层的三倍)。
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引用次数: 0
Dilemma between Physics and ISO Elastic Indentation Modulus 物理和ISO弹性压痕模量之间的困境
Pub Date : 2017-12-21 DOI: 10.4172/2169-0022.1000402
G. Kaupp
This paper challenges the ISO standard 14577 that determines the elastic indentation modulus by violating the first energy law, and omitting easily detected phase change onsets as well as initial surface effects under load. The double iteration for incorrect fitting indentation modulus to Hook's law Young's modulus of a standard with up to 11 free parameters must be cancelled and discontinued. The iterative evaluation of the elastic modulus Er-ISO can by far not be reproduced by iteration-free direct calculation of Er, when using the underlying formulas for S, hc, Ahc, and ε. For cubic aluminium the divergence amounts to a factor of 3.5 or 3.1, respectively (both smaller for the non-iterated calculations). Every interpretation of indentation moduli as single unidirectional "Young's moduli" is false. They are mixtures from all directions and include shear moduli. The three different packing diagrams of body centered cubic α-iron exemplify the mixture of three independent Young's moduli (and thus also three shear moduli) even in this simple but already anisotropic case. More linear moduli ensue in lower symmetry crystals as exemplified with α-quartz. The first physical indentation modulus is deduced by removal of the physical errors of Er-ISO, or after indenter compliance correction EISO. Ephys does no longer violate the energy law. Five face-dependent elastic indentation moduli of α-quartz at the obsolete Er-ISO level and two tensional Hook-law Young's moduli are compared with all of its six resonance ultrasound spectroscopy (RUS) evaluated Young's moduli, and with the bulk modulus. The dilemma between ISO and physics is particularly detrimental, as EISO is used for the calculation of very frequently applied mechanical parameters. These propagate the errors into failure risks of falsely calculated materials with severe violation of the basic energy law and other physical laws for daily life. Difficulties with the urgent settlement by new ISO standards are discussed. First suggestions for the use of Ephys, or Sphys, or eventually measured bulk modulus K are made. This should be urgently evaluated and discussed. *Corresponding author: Gerd Kaupp, University of Oldenburg, Diekweg 15, D-26188 Edewecht, Germany, Tel: 4944868386; Fax: 4486920704; E-mail: gerd.kaupp@uni-oldenburg.de Received October 28, 2017; Accepted December 11, 2017; Published December 21, 2017 Citation: Kaupp G (2017) Dilemma between Physics and ISO Elastic Indentation Modulus. J Material Sci Eng 6: 402. doi: 10.4172/2169-0022.1000402 Copyright: © 2017 Kaupp G. This is an open-access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.
本文挑战了ISO 14577标准,该标准通过违反第一能量定律来确定弹性压痕模量,并且忽略了易于检测的相变开始以及载荷下的初始表面效应。有多达11个自由参数的标准的胡克定律杨氏模量与压痕模量拟合不正确的双迭代必须取消和停止。当使用S、hc、Ahc和ε的基础公式时,弹性模量Er- iso的迭代计算到目前为止还不能通过无迭代直接计算Er来重现。对于立方铝,散度分别为3.5或3.1倍(对于非迭代计算,两者都较小)。将缩进模量解释为单一单向的“杨氏模量”都是错误的。它们是来自各个方向的混合物,包括剪切模量。体心立方α-铁的三种不同的堆积图举例说明了三个独立的杨氏模量(因此也是三个剪切模量)的混合,即使在这个简单但已经各向异性的情况下。α-石英的对称性越低,线性模量越大。第一个物理压痕模量是通过去除Er-ISO的物理误差,或在压痕柔度校正EISO后推导出来的。埃弗斯不再违反能源法。将α-石英在过时的Er-ISO水平上的5个面相关弹性压痕模量和2个张拉Hook-law杨氏模量与其所有6个共振超声光谱(RUS)评估的杨氏模量进行了比较,并与体模量进行了比较。在ISO和物理学之间的困境是特别有害的,因为EISO用于计算非常频繁应用的机械参数。这些将误差传播为错误计算的材料的失效风险,严重违反了日常生活中的基本能量定律和其他物理定律。讨论了新ISO标准紧急解决的困难。提出了使用Ephys或Sphys或最终测量体积模量K的第一个建议。这一点应紧急加以评价和讨论。*通讯作者:Gerd Kaupp, University of Oldenburg, Diekweg 15, D-26188 edeweht, Germany, Tel: 4944868386;传真:4486920704;邮箱:gerd.kaupp@uni-oldenburg.de 2017年10月28日收到;2017年12月11日录用;引用本文:Kaupp G(2017)物理与ISO弹性压痕模量之间的困境。[J] .材料工程学报,6(6):444 - 444。版权:©2017 Kaupp G.这是一篇根据知识共享署名许可条款发布的开放获取文章,允许在任何媒体上不受限制地使用、分发和复制,前提是注明原作者和来源。
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引用次数: 5
The Effect of Cu on the Decomposition of Al-Zn-Mg-(Cu) Alloys Cu对Al-Zn-Mg-(Cu)合金分解的影响
Pub Date : 2017-12-21 DOI: 10.4172/2169-0022.1000404
J. Lamb, Sanders Jr. Th
A series of experimental Al-Zn-Mg-(Cu) alloys with a semi-constant Zn:Mg ratio were produced via hot rolling. The effects of Cu in these alloys on the activation energy for precipitation, the response to natural aging, the size of the precipitate free zone, and the corrosion resistance were investigated.
采用热轧法制备了半恒定Zn:Mg比的Al-Zn-Mg-(Cu)合金。研究了Cu含量对合金的析出活化能、自然时效响应、无析出区大小和耐蚀性的影响。
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引用次数: 1
An Electrical Model for Off-Plane Nano Needle Array Electrodes in Intracellular Signal Measurement in Biological Environments 非平面纳米针阵列电极在生物环境下细胞内信号测量中的电学模型
Pub Date : 2017-12-20 DOI: 10.4172/2169-0022.1000405
N. Mehmood, A. Hariz
Electrical signals emanating from biological cells can convey clinical information on the functionality thereof. However, measurement of such small signals caused primarily by ionic activity inside the cell, known as action potential, poses a great challenge to biomedical scientists. The electrical signals of the biological cells result from exchange of ions through the cell membrane. The characteristics of action potentials may reveal a great deal of information about the causes and symptoms of abnormal cell behaviour. Hence, it is imperative to capture high quality action potentials through the use of nano-sensors from within the cell. Recently, developments in silicon nanowires (SiNW) fabrication techniques have demonstrated a great potential for them to be used as nano-electrodes. Largescale assembly and integration of addressable complementary silicon nanowires arrays have been demonstrated for multiplexed biosensor arrays. The fabrication process resulted in a high-yield, high performance devices arrays for chemical and biological detection. In this paper, we seek to model the electrical interface that is responsible for recording the biological signals. We present electrical equivalent circuits that model the boundary between the biological cell and the nanowire electrode. Impedance measurement curves of nanowires for various sizes of length and diameter have also been presented and discussed. The impedance graphs show a hyperbolic dependence of resistance on length and diameter of nanowires. This non-linear behaviour may be mitigated in software algorithms when interpreting the measured cell signals.
从生物细胞发出的电信号可以传递关于其功能的临床信息。然而,测量这种主要由细胞内离子活性引起的小信号,即动作电位,对生物医学科学家来说是一个巨大的挑战。生物细胞的电信号是离子通过细胞膜交换而产生的。动作电位的特征可以揭示有关异常细胞行为的原因和症状的大量信息。因此,通过使用纳米传感器从细胞内捕获高质量的动作电位是必要的。近年来,硅纳米线(SiNW)制造技术的发展显示出其作为纳米电极的巨大潜力。大规模组装和集成可寻址互补硅纳米线阵列已经证明了多路生物传感器阵列。该制造工艺产生了用于化学和生物检测的高产、高性能器件阵列。在本文中,我们试图对负责记录生物信号的电接口进行建模。我们提出了模拟生物细胞和纳米线电极之间边界的等效电路。给出并讨论了不同长度和直径纳米线的阻抗测量曲线。阻抗图显示电阻与纳米线的长度和直径呈双曲线关系。在解释被测量的细胞信号时,这种非线性行为可以在软件算法中得到缓解。
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引用次数: 0
Synthesis and Evaluation of Olivine Nanosheets from Layered Ammonium Iron Phosphate Monohydrate 层状一水磷酸铁铵橄榄石纳米片的合成与评价
Pub Date : 2017-12-10 DOI: 10.4172/2169-0022.1000403
Masakazu Togo, A. Nakahira
The synthesis of novel microstructured LiFePO4 with advantageous nanosheets for Li ion conductivity was attempted. Using layered NH4FePO4•H2O as raw material, LiFePO4 nanosheet was synthesized by the hydrothermal process in LiCl solution. Prepared NH4FePO4•H2O was several tens micrometer sized sheet with about 200 nm in thickness. As Li ion resource, various LiCl solution like deionized water, ethanol, and ethylene glycol were prepared through subsequent hydrothermal process and the effect of a kind of solvents for LiCl solution on the microstructure of products treated by the hydrothermal process was investigated for LiFePO4 nanosheets synthesis. The products of LiFePO4 nanosheet were characterized by XRD, SEM, TEM, FT-IR and ICP. Regardless of a kind of solvents, LiFePO4 nanosheet was composed of arranged nano-blocks, although the size and morphology of nano-blocks was different in each solvent.
本文尝试合成一种新型的微结构LiFePO4,并对锂离子电导率具有有利的纳米片。以层状NH4FePO4•H2O为原料,在LiCl溶液中采用水热法制备了LiFePO4纳米片。制备的NH4FePO4•H2O为几十微米大小的薄片,厚度约为200 nm。以去离子水、乙醇、乙二醇等多种LiCl溶液作为锂离子资源,通过后续水热法制备LiCl溶液,研究了一种LiCl溶液溶剂对水热法制备LiFePO4纳米片产物微观结构的影响。采用XRD、SEM、TEM、FT-IR和ICP对LiFePO4纳米片进行了表征。无论哪种溶剂,LiFePO4纳米片都是由排列的纳米块组成的,尽管在每种溶剂中纳米块的大小和形态不同。
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引用次数: 0
Fatigue Resistance Study of Quenched and Tempered High-Strength Steel Submitted to Low Intensity Shot Peening Treatments with Different Types of Shots 不同类型丸剂低强度喷丸强化调质高强钢的抗疲劳性能研究
Pub Date : 2017-12-07 DOI: 10.4172/2169-0022.1000401
E. Segurado, Belzunce Fj, I. FernándezPariente
The aim of this research is to study the fatigue life enhancement produced in quenched and tempered AISI4340 steel with a tensile strength of 2000 MPa after being submitted to shot peening surface treatments. These treatments generate compressive residual stress fields in a superficial layer of the material at the same time as inducing some kind of damage on the surface. Different kind of projectiles were chosen to perform the treatment (ceramic and steel shots), studying the way these affected the fatigue life of the specimens. The surface topography of the samples was analysed using a roughness tester and by means of scanning electron microscopy (SEM). The compressive residual stress profile induced by these treatments was measured using X-ray diffraction (XRD) plus electro-polishing. The fatigue behaviour of the treated samples was subsequently studied by means of 4-point rotating bending tests and their fracture surfaces were analysed using SEM. The best fatigue performance was obtained after shot peening with ceramic beads under 8A Almen intensity. The main difference in relation to the treatment performed under the same intensity but using steel cut wire shots was the much lower surface damage induced by the impacts with the ceramic shots compared with the cut wire projectiles, which in turn is justified by the greater geometric perfection and hardness of the former. Furthermore, fatigue specimens shot peened with ceramic beads under 8A intensity always gave rise to internal fatigue crack initiation, which took place outside the zone subjected to residual compressive stresses. Moreover, fatigue initiation was always linked to the presence of hard and rigid alumina inclusions, which acted as microstructural stress concentrators.
本研究的目的是研究抗拉强度为2000 MPa的AISI4340钢经喷丸强化表面处理后的调质疲劳寿命的提高。这些处理在材料的表层产生压缩残余应力场,同时在表面引起某种损伤。选择不同类型的弹丸(陶瓷弹丸和钢弹丸)进行处理,研究其对试样疲劳寿命的影响。用粗糙度仪和扫描电子显微镜对试样的表面形貌进行了分析。利用x射线衍射仪(XRD)和电抛光仪测量了这些处理引起的压缩残余应力分布。随后,采用四点旋转弯曲试验研究了处理后试样的疲劳行为,并用扫描电镜对其断口进行了分析。在8A Almen强度下,用陶瓷珠喷丸强化后,其疲劳性能最好。在相同强度下使用钢丝切割弹进行处理的主要区别是,陶瓷弹与钢丝切割弹相比,其表面损伤要小得多,这反过来又证明了前者具有更高的几何完美性和硬度。此外,在8A强度下,陶瓷珠喷丸疲劳试样总是在残余压应力作用区外产生内部疲劳裂纹。此外,疲劳启动总是与硬刚体氧化铝夹杂物的存在有关,这些夹杂物起着微结构应力集中剂的作用。
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引用次数: 1
Effect of Heat Treatment of Cu-Al-Be Shape Memory Alloy on Microstructure, Shape Memory Effect and Hardness Cu-Al-Be形状记忆合金热处理对组织、形状记忆效应和硬度的影响
Pub Date : 2017-12-02 DOI: 10.4172/2169-0022.1000398
J. Al-haidary, A. M. Mustafa, A. A. Hamza
Cu-13Al-0.545Be shape memory alloy are heat treatment at different temperature and time. The microstructure of alloy after heat treatment at 850°C, 650°C and aging at 150°C ,450°C and 550°C for 2, 4 and 6 h study by optical microscope and X-ray diffraction. Bending test is use to show effect of heat treatment on super-elastic and shape memory effect. Micro hardness test used to show effect of heat treatment on micro hardness .shape memory effect increase at heat treatment 650°C and aging at 150°C, while at 450°C and 550°C will decrease because precipitate formation rate rises with increase in temperature and time. The hardness and precipitates in the alloy increases with increasing ageing duration. Higher ageing temperature avoids the imperfection by moving and filling the empty space thereby hardens the alloy.
对Cu-13Al-0.545Be形状记忆合金进行不同温度和时间的热处理。通过光学显微镜和x射线衍射研究了850℃、650℃热处理和150℃、450℃、550℃时效2、4、6 h后合金的显微组织。采用弯曲试验来考察热处理对超弹性和形状记忆效应的影响。显微硬度试验显示热处理对显微硬度的影响。形状记忆效应在650℃热处理和150℃时效时增强,而在450℃和550℃时由于析出速率随温度和时间的增加而增大而减弱。随着时效时间的延长,合金的硬度和析出相增加。较高的时效温度通过移动和填充空白空间来避免缺陷,从而使合金硬化。
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引用次数: 6
Nanofibers for High Efficiency Filtration 纳米纤维用于高效过滤
Pub Date : 2017-12-02 DOI: 10.4172/2169-0022.1000399
Prakash Khude
Nanofiber is a broad phrase generally referring to a fibre with a diameter less than 1 micron. While glass fibres have existed in the sub-micron range for some time and polymeric meltblown fibres are just beginning to break the micron barrier, sub-half-micron diameters have been used for air filtration in commercial, industrial and defence applications for more than twenty years. They have been shown to deliver improved filter life, increased contaminate holding capacity and enhanced filtration efficiency. Small fibres in the sub-micron range, in comparison with larger ones, are well known to provide higher filter efficiency at the same pressure drop in the interception and inertial impaction stages of the filtration process. In particular, nanofibers provide marked increases in filtration efficiency at relatively small (and in some cases immeasurable) decreases in permeability. Nanofiber filter media have enabled new levels of filtration performance in several diverse applications with a broad range of environments and contaminants. While nano fibre size lead to a higher pressure drop, interception and inertial impaction efficiencies will increase faster, and therefore more than compensating for the rise in pressure drop. Thus, in the particle size of interest, i.e. from sub-micron upwards, better filter efficiency can be achieved at the same pressure drop, or conversely, the same filter efficiency at a lower pressure drop can be achieved with nanofibres. This paper will discuss a process for making nanofibers, as well as the benefits, limitations, construction, and applications of filters using nanofiber media.
纳米纤维是一个广义的短语,一般指直径小于1微米的纤维。虽然玻璃纤维在亚微米范围内已经存在了一段时间,聚合物熔喷纤维刚刚开始打破微米的障碍,但在商业,工业和国防应用中,半微米以下直径的空气过滤已经使用了二十多年。它们已被证明提供改进的过滤器寿命,增加污染物持有能力和提高过滤效率。众所周知,在过滤过程的拦截和惯性冲击阶段,与较大的纤维相比,亚微米范围内的小纤维在相同的压降下提供更高的过滤效率。特别是,纳米纤维在渗透率相对较小(在某些情况下无法测量)的降低下,过滤效率显著提高。纳米纤维过滤介质在多种环境和污染物的不同应用中实现了新的过滤性能水平。虽然纳米纤维的尺寸会导致更高的压降,但拦截和惯性冲击效率会提高得更快,因此可以弥补压降的增加。因此,对于感兴趣的粒径,即从亚微米以上,可以在相同的压降下获得更好的过滤效率,或者相反,纳米纤维可以在更低的压降下获得相同的过滤效率。本文将讨论纳米纤维的制备工艺,以及纳米纤维滤料的优点、局限性、结构和应用。
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引用次数: 5
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