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Damage Assessment of Bitumen Refineries Using Simapro (LCA) Inventory Data 基于Simapro (LCA)库存数据的沥青炼油厂损害评估
Pub Date : 2017-02-05 DOI: 10.4172/2157-7463.1000317
Saeed Morsali
Oil refineries are complex facilities. Several processes, such as distillation, vacuum distillation, or steam reforming are required to produce a large variety of oil products such as gasoline, light fuel oil or bitumen. The environmental impacts of oil refineries are assessed using the technique of life cycle assessment (LCA). In this paper, only the material production phase of the bitumen life cycle is considered. To improve the quality of the LCA, a regionalized life cycle inventory (LCI) database for the Oil refineries and commercial LCI databases are used to validate and model unit processes with LCA software.
炼油厂是复杂的设施。几个过程,如蒸馏,真空蒸馏,或蒸汽重整需要生产各种各样的石油产品,如汽油,轻质燃料油或沥青。采用生命周期评价技术对炼油厂的环境影响进行了评价。本文只考虑沥青生命周期中的物质生产阶段。为了提高LCA的质量,我们使用炼油厂区域化生命周期清单(LCI)数据库和商业LCI数据库,利用LCA软件对单元过程进行验证和建模。
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引用次数: 6
An Experimental Study on the Influence of Ethanol and Automotive GasolineBlends 乙醇与汽车混合汽油影响的实验研究
Pub Date : 2017-02-05 DOI: 10.4172/2157-7463.1000318
Aboul Fotouh Tm, O. A. Mazen, I. Ashour
The objective of this work is to investigate the production possibility of high octane environmental ethanol gasoline blends based on Euro specifications. The environmental gasoline is the key element to keep the environment safe and clean. Moreover, it reduces gas emissions after combustion of gasoline. One of the main methods to produce the environmental gasoline is blending gasoline with oxygenated compounds such as ethanol. Ethanol is chosen among other oxygenated compounds as it has a high influence on physico-chemical characteristics of gasoline rather than other oxygenated compounds. In addition, it has a high octane number as well as it is not polluting the environment and clean additive. In the experimental study, the choice of environmental gasolines are based on Euro- 3 specifications for samples without ethanol blend and Euro-5 specifications for samples with ethanol blend; after upgrading. Various blend stocks have been prepared which have reformate, isomerate, full refinery naphtha (FRN), heavy straight run naphtha (HSRN), hydrocracked naphtha, heavy hydrocracked naphtha, coker naphtha and heavy coker naphtha. In this study, ASTM standard methods are performed for spark ignition fuels to characterize its physical and chemical properties. The results show that one has exhibited the optimum specifications of Euro-3 and thus its physico-chemical characteristics are 755.11 Kg/m3 of density, 55.88 of °API and 95 of RON, 88 of MON, 40% by volume of aromatic content and 0.66% by volume of benzene content. Moreover, ASTM distillation curve shows that the volume percentage at 150°C is 83. At the same time, the final boiling point (FBP) and recovery volume percent are 198°C is 96% respectively. While another sample has the poorest physical as well as chemical properties so that it is blended with ethanol to upgrade its characteristics. Therefore, the target is determining the optimum ethanol volume percent to be blended with poorest sample to yield the highest properties of gasoline. These blends are namely as E0, E5, E10, E15, E20. The results indicate that E5 is the optimum one for Euro-5 specifications after upgrading and thus its physico-chemical characteristics are 745.55 Kg/m3 of density, 58 of oAPI, 101 of RON, 98 of MON, 32.65% by volume of aromatic content and 0.47% by volume of benzene content. Moreover, ASTM distillation curve illustrates that the volume percentage at 150°C is 75. At the same time, the final boiling point (FBP) and recovery volume percent are 190°C and 97% respectively. In addition, its Reid vapor pressure equals 8.1 psi and the heat of combustion equals 35 MJ/L. In the final, Blending gasoline with ethanol is an essential issue concerning the production of environmental gasolines.
这项工作的目的是调查生产的可能性高辛烷值环保乙醇汽油混合物的基础上的欧洲规格。环保型汽油是保证环境安全和清洁的关键要素。此外,它减少了汽油燃烧后的气体排放。生产环保型汽油的主要方法之一是将汽油与含氧化合物(如乙醇)混合。与其他含氧化合物相比,乙醇对汽油的物理化学特性影响较大,因此在其他含氧化合物中选择了乙醇。此外,它具有高辛烷值以及不污染环境和清洁添加剂。在实验研究中,环保型汽油的选择是基于欧- 3规范和欧-5规范对无乙醇混合的样品和有乙醇混合的样品;后升级。制备了重整油、异构油、全精油、重直馏油、加氢裂化油、重加氢裂化油、焦化油和重焦化油等不同类型的混合油。在本研究中,采用ASTM标准方法对火花点火燃料进行物理和化学特性表征。结果表明,得到了最佳规格的铕-3,其理化性能为:密度为755.11 Kg/m3, API为55.88,RON为95,MON为88,芳香族含量为40%,苯含量为0.66%。此外,ASTM蒸馏曲线显示,在150°C时的体积百分比为83。同时,终沸点(FBP)和回收率分别为198℃和96%。而另一种样品具有最差的物理和化学性质,因此它与乙醇混合以提高其特性。因此,目标是确定最佳乙醇体积百分比,以混合最差的样品,以产生最高性能的汽油。这些共混物分别为E0、E5、E10、E15、E20。结果表明,改造后的E5为欧5规格的最佳原料,其理化性能为745.55 Kg/m3, oAPI为58 Kg/m3, RON为101 Kg/m3, MON为98 Kg/m3,芳香烃体积含量为32.65%,苯体积含量为0.47%。此外,ASTM蒸馏曲线表明,在150°C时的体积百分比为75。同时,终沸点(FBP)为190℃,回收率为97%。其Reid蒸气压为8.1 psi,燃烧热为35 MJ/L。最后,将汽油与乙醇混合是环保汽油生产的关键问题。
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引用次数: 6
Characterization of Dynamic Pressure Response in Vertical Two Phase Flow 垂直两相流动压力响应特性研究
Pub Date : 2017-02-05 DOI: 10.4172/2157-7463.1000316
J. Agbakwuru, A. Ogunlana, O. Oshagbemi, Rahman Ma, S. Imtiaz
One of the problems encountered in drilling, especially in offshore environments is “kicks”. Kick is a sudden pressure imbalance in the wellbore during drilling operation. When this imbalances in pressure occurs the reservoir pressure has the ability to push the reservoir fluid into the wellbore. This may create a catastrophic event such as blow-out of the drilling rig. Thus, prior detection of the kick situation is critical to prevent any such catastrophic event. Currently, a kick situation is predicted or detected observing the properties of returned drilling mud from the wellbore. This method is not reliable as well as time consuming. The objective of this study is to develop a tool that will enable the prediction and detection of kick situations in managed pressure drilling (MPD). To achieve this goal, a two-phase experiment is conducted in 7.62 cm and 5 m long vertical pipe section. Instead of periodic sampling for kick situations, the newly developed tool enables the continuous monitoring of kick situations.
钻井中遇到的问题之一是“井涌”,特别是在海上环境中。井涌是钻井作业中井筒内突然出现的压力不平衡现象。当这种压力不平衡发生时,储层压力有能力将储层流体推入井筒。这可能会造成灾难性的事件,如钻井平台的井喷。因此,提前发现井涌情况对于防止此类灾难性事件至关重要。目前,通过观察从井筒中返出的钻井泥浆的性质来预测或检测井涌情况。这种方法不可靠,而且耗时。本研究的目的是开发一种工具,能够预测和检测控压钻井(MPD)中的井涌情况。为了实现这一目标,在7.62 cm和5m长的垂直管段中进行了两阶段实验。新开发的工具可以连续监测井涌情况,而不是对井涌情况进行周期性采样。
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引用次数: 1
Investigating and Enhancing Mud Cake Reduction Using Smart Nano ClayBased WBM 智能纳米粘土基WBM对泥饼还原性能的研究与提高
Pub Date : 2017-01-25 DOI: 10.4172/2157-7463.1000315
Asif Zamir, N. A. Siddiqui
Mud cake is the solid particles deposited on the pores of the formation creating a form of barrier when the drilling fluid is forced against the formation under an applied pressure. The mud cake formed along the open hole formation may cause differential pipe sticking and increases torque and drag forces of the drill pipe. This causes drilling operator to stop drilling and perform frequent tripping or over pull to release the stuck pipe. This event may lead to Non-Productive Time (NPT) and increases the operational cost. The aim of this research is to investigate the relationship between Nano Clay based water based mud (WBM) with mud cake thickness and comparing it with the conventional clay based mud (WBM). In this research study, we could only managed to get nano clay between 90 nm to 100 nm. Mud cake thickness, filtrate volume and rheology of the drilling fluids parameters are studied. It was found that the mud cake thickness of Nano-WBM using Nano Clay is half compared to base mud using conventional clay. However, the filtrate collected and the rheological properties show an adverse impact of the drilling fluid performance.
泥浆饼是沉积在地层孔隙上的固体颗粒,当钻井液在施加压力下被迫与地层对抗时,会形成一种屏障。沿着裸眼地层形成的泥饼可能会造成差动钻杆卡钻,增加钻杆的扭矩和阻力。这导致钻井作业人员停止钻井,并进行频繁的起下钻或过拉以释放卡钻。该事件可能导致非生产时间(NPT),并增加运营成本。研究纳米粘土基水基泥浆(WBM)与泥饼厚度的关系,并与常规粘土基泥浆(WBM)进行比较。在这项研究中,我们只能得到90 nm到100 nm之间的纳米粘土。研究了泥饼厚度、滤液体积、钻井液流变性等参数。结果表明,采用纳米粘土制备的纳米基浆的泥饼厚度比采用常规粘土制备的基浆厚度减少了一半。然而,所收集的滤液和流变性能对钻井液性能产生不利影响。
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引用次数: 10
Research and Development for Oil Spill Simulation Backward in Time at East Vietnam Sea 东越海溢油模拟的研究与发展
Pub Date : 2017-01-01 DOI: 10.4172/2157-7463.1000344
Trinh Q Nguyen
The paper is presented the evaluation of the oil spill simulation backward in time with some input data conditions such as the environment factors (from simple to complex conditions) and oil spill data (from one to multifarious). The scientific basis is used the hypothesis of the mathematical basis forward in time, the physical phenomena backward in time (reverse phase) and non-negative requirements. The oil spill process is calculated with important components involved in the simulation such as physical, weathering and oil properties change. The East Vietnam Sea was chosen to apply the study that oil spill incident data was used in the past and especially in 2007 and 2008. The simulation results are considered and determined with concentration and layer thickness of oil spill on sea that they always appear in small areas. This area has a peak concentration value that jumps over nearby surroundings for a short period of time. This time interval depends on the environmental factors that make the input data condition. Hence, the surrounding higher concentrations are predicted oil streaks that could have survived in the past. Finally, the peak concentration area is predicted for the possibility of an oil spill emission source in the past. Besides, this study may still not be optimized so they will continue to be solved in the future.
本文提出了在环境因素(从简单条件到复杂条件)和溢油数据(从单一条件到多种条件)的输入条件下,对溢油模拟进行逆向时间评价的方法。科学基础是采用数学基础的时间正向假说,物理现象的时间反向假说(逆相)和非负性要求。对溢油过程进行了物理、风化和油性变化等重要因素的计算。选择东越南海作为研究对象,运用了以往特别是2007年和2008年的溢油事件数据。模拟结果考虑和决定于海面溢油浓度和层厚,溢油总是出现在小范围内。这个区域有一个峰值浓度值,在短时间内跳过附近的环境。这个时间间隔取决于造成输入数据条件的环境因素。因此,周围较高的浓度被预测为过去可能存在的油纹。最后,对过去可能发生溢油排放源的峰值集中区进行了预测。此外,本研究可能还没有得到优化,因此这些问题将在未来继续解决。
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引用次数: 2
Source Rock Evaluation in The Lake Chad Area of the Bornu Basin, Nigeria 尼日利亚Bornu盆地乍得湖地区烃源岩评价
Pub Date : 2017-01-01 DOI: 10.4172/2157-7463.1000346
O. Sunday, A. Adeyinka, O. S. Ojo
Source rock evaluation of the Lake Chad area of the Bornu Basin which contains a comparatively thicker sedimentary succession based on interpreted seismic and gravity data was undertaken in this study. A total of twenty-nine shale samples from three wells (Kutchali-1, Faltu-1 and Herwa-1) were analysed to arrive at the bulk geochemical properties, organic matter particles and vitrinite reflectance (VR) data of the strata penetrated by the wells. The Lake Chad area appears to contain the main ingredients required to make a rich source rock with over 96% of the total organic carbon (TOC) values being in the range of 0.63-2.88 wt% and over 95% having Tmax greater than 435°C in most of the sampled intervals. The variation of Tmax and VR with depth in the wells reveals irregular decreases or subtle decreasing trends that are suggestive of cooling in the basin’s thermal history probably as a result of uplift and erosion. The uplift could have been caused by epeirogenic movement or by folding related to the Santonian inversion witnessed by the West African Rift Subsystem. In terms of hydrocarbon generation potential, most of the samples have HI values greater than 50 mgHC/g TOC, but generally less than 200 mgHC/g TOC. These HI values suggest dominance of Type III with less Type II Kerogen; thus, a predominantly predominantly gas prone area. A study of some bulk geochemical parameters (TOC, Tmax and HI) of the three study wells has revealed that the succession penetrated by one of them (Faltu-1 well) contains several potential gas source intervals and two potential oil source intervals with the latter probably lying between 2500 m and 3000 m depth.
基于地震和重力解释资料,对沉积层序较厚的Bornu盆地乍得湖地区进行了烃源岩评价。对3口井(Kutchali-1、Faltu-1和Herwa-1)的29个页岩样品进行了分析,得到了地层的总体地球化学性质、有机质颗粒和镜质体反射率(VR)数据。乍得湖地区似乎包含了形成丰富烃源岩所需的主要成分,96%以上的总有机碳(TOC)值在0.63-2.88 wt%之间,95%以上的Tmax在大多数采样区间大于435°C。Tmax和VR随井深的变化显示出不规则的减小或微妙的减小趋势,表明盆地热历史可能由于隆升和侵蚀而冷却。隆起可能是由造陆运动引起的,也可能是由与西非裂谷子系统所见证的圣东反转有关的褶皱引起的。在生烃潜力方面,大多数样品的HI值大于50 mgHC/g TOC,但一般小于200 mgHC/g TOC。这些HI值表明III型干酪根占优势,II型干酪根较少;因此,一个主要是天然气易发地区。通过对3口井整体地球化学参数(TOC、Tmax和HI)的研究表明,其中1口井(Faltu-1井)所穿透的层序包含多个潜在气源层段和2个潜在油源层段,后者可能位于2500 ~ 3000 m深度之间。
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引用次数: 4
A Prospective analysis on Minimization of Mechanical Friction of Fuel Engine using Chemical Reagents 利用化学试剂减少燃油发动机机械摩擦的前瞻性分析
Pub Date : 2017-01-01 DOI: 10.4172/2157-7463.1000341
Shaheen Shah, Nasirul Islam, S. Hossain, Ābu Henā, N. Jamil, S. Chowdhury, A. Al-Hossain
Chemical reagents such as Lithium base grease, Calcium base grease, Aluminum base grease which are reduced the mechanical friction and increase the performance of machines with adding various additives molybdenum disulphide (MoS2), Graphite, Boron Nitrite. Dropping point is an indicator of heat resistance of the grease. The dropping point indicates the upper temperature limit at which grease retains its structure. If, failure the grease against high temperature then occurs friction and increase load. When load is increase then the fuel engine does not give the satisfy output. The paper estimated the dropping point of those grease. A.S.T.M standard D-566 used for estimated dropping of the greases. The dropping point of Lithium base grease, Calcium base grease, Aluminum base grease are estimated 195°C, 95°C, and 110°C respectively. The dropping point of mixed base grease i.e., Calcium 50% + Lithium 50%, Lithium 50% + Aluminum 50% and Calcium 50% +Aluminum 50% are 140°C, 158°C and 152°C respectively. The dropping of mixed base grease is higher than the individuals of the greases. The use of the calcium base grease also act is a water and repellant and corrosion protective. This paper represents that Aluminum 50% + Calcium 50% mixed base grease is showing the best performance against high temperature with protects the corrosion.
化学试剂,如锂基润滑脂、钙基润滑脂、铝基润滑脂等,通过添加各种二硫化钼(MoS2)、石墨、亚硝酸盐硼等添加剂来减少机械摩擦,提高机器性能。滴点是润滑脂耐热性的指标。滴点表示油脂保持其结构的温度上限。如果润滑脂在高温下失效,则会发生摩擦并增加负载。当负荷增加时,燃油发动机不能提供满意的输出。这张纸估计了那些油脂的落点。a.s.t.m.标准D-566用于估计润滑脂的下降。锂基润滑脂、钙基润滑脂、铝基润滑脂的滴点估计分别为195℃、95℃和110℃。钙50% +锂50%、锂50% +铝50%和钙50% +铝50%混合基础脂滴点分别为140℃、158℃和152℃。混合基润滑脂的滴度高于单个润滑脂。使用的钙基润滑脂还起着防水和防腐蚀的作用。研究表明,铝50% +钙50%混合基润滑脂具有较好的耐高温性能和抗腐蚀性能。
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引用次数: 1
Limiting Key Drilling Parameters to Avoid or Mitigate Mud Losses in the Hartha Formation, Rumaila Field, Iraq 限制关键钻井参数以避免或减少伊拉克鲁迈拉油田Hartha地层的泥浆损失
Pub Date : 2017-01-01 DOI: 10.4172/2157-7463.1000345
A. T. Al-Hameedi, H. Alkinani, S. Dunn-Norman, R. Flori, Steven Hilgedick, A. Amer
Wells drilled in Rumaila field are highly susceptible to lost circulation problems when drilling through the Hartha formation. This paper presents an extended statistical work and sensitivity analysis models of lost circulation events in more than 100 wells drilled in Rumaila field. Lost circulation data are extracted from daily drilling reports, final reports, and technical reports. The volume loss model is conducted to predict the mud losses in the Hartha formation. Observations that are made from the volume loss model are ECD, MW, and Yp have a significant impact on lost circulation respectively; however, SPM, RPM, and ROP have a minor effect on the mud losses. Equivalent circulation density model is obtained to estimate ECD in the Hartha zone, and from this model can be deduced that MW, ROP, and Q have a significant impact on ECD respectively; nevertheless, RPM and Yp have a minor impact on the ECD. The rate of penetration model is made to estimate ROP in the Hatha zone. It is concluded that WOB, RPM, and SPM have a significant impact on the ROP respectively. Due to the lack of published studies for the Hartha formation, this work can serve as a practical resource for drilling through this formation.
Rumaila油田的井在钻穿Hartha地层时极易出现漏失问题。本文介绍了鲁迈拉油田100多口井漏失事件的扩展统计工作和敏感性分析模型。漏失数据从每日钻井报告、最终报告和技术报告中提取。采用体积损失模型对Hartha地层的泥浆损失进行预测。根据体积损失模型的观察结果,ECD、MW和Yp分别对井漏有显著影响;然而,SPM、RPM和ROP对泥浆漏失的影响较小。建立了等效循环密度模型,估算了Hartha区块的ECD,并推导出MW、ROP和Q分别对ECD有显著影响;然而,RPM和Yp对ECD的影响很小。建立了渗透速率模型来估计Hatha区的ROP。结果表明,钻压、RPM和SPM分别对ROP有显著影响。由于缺乏针对Hartha地层的公开研究,这项工作可以作为钻穿该地层的实用资源。
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引用次数: 7
Effect of Pump Schedule on Fracture Geometry and Shape during Frac Packing Job 压裂充填作业中泵送进度对裂缝几何形状的影响
Pub Date : 2017-01-01 DOI: 10.4172/2157-7463.1000342
E. Khair
Recently, Frac packing was investigated to improve the economic returns of the reservoirs through the reduction of formation damage and controlling sanding from unconsolidated formation. The technique is applied for high permeability formations, in which the well production rate is affect by fracture conductivity rather than fracture length; therefore, short fat fracture with a good slurry concentration is required. The optimization of these parameters is the major factor for successful job; the optimization can be achieved through the combination of reservoir model with fracture model and tip screen-out (TSO) concept. On the basis of the formation characteristics, fracture length and conductivity with in-situ stress the effect of pump schedule was addressed for Tip Screen Out fracture through a well in Fula oilfield in Sudan. 3D fracture simulation software (FRACPRO PT) was used with TSO concept to address the effect of pump rate and proppant concentration on the obtained fracture. The study presented the proppant distribution is highly affected by the injection rate, and an injection rate of 3.5 was selected to avoid sanding as a result of bad proppant distribution. Also, it was observed that the fracture geometry is affected by pump rate and proppant concentration.
近年来,人们研究了压裂充填技术,通过减少地层损害和控制松散地层出砂来提高储层的经济效益。该技术适用于高渗透地层,在这些地层中,影响油井产量的是裂缝导流能力而不是裂缝长度;因此,需要短断口和良好的料浆浓度。这些参数的优化是作业成功的主要因素;通过将储层模型与裂缝模型和尖端筛出(TSO)概念相结合来实现优化。根据苏丹富拉油田一口井的地层特征、裂缝长度、导流能力和地应力,研究了泵注时间对Tip Screen Out裂缝的影响,采用三维裂缝模拟软件FRACPRO PT,结合TSO概念,分析了泵注速率和支撑剂浓度对裂缝的影响。研究表明,支撑剂的分布受注入速度的影响较大,为避免因支撑剂分布不良而导致出砂,选择注入速度为3.5。此外,还观察到裂缝的几何形状受泵速和支撑剂浓度的影响。
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引用次数: 3
Investigating Effect of SiO2 Nanoparticle and Sodium-Dodecyl-Sulfate Surfactant on Surface Properties: Wettability Alteration and IFT Reduction 二氧化硅纳米颗粒和十二烷基硫酸钠表面活性剂对表面性质的影响:润湿性改变和IFT降低
Pub Date : 2017-01-01 DOI: 10.4172/2157-7463.1000349
S. EhsanEshraghi, Y. Kazemzadeh, M. Qahramanpour, A. Kazemi
Interfacial-Tension (IFT)/contact angle measurements and several core-floods are performed to characterize the as-prepared samples and evaluate the efficacy of silica nanoparticles (NPs) and SDS surfactant in Enhanced-Oil-Recovery (EOR). NPs decreases the oil/solution IFT more than the surfactant solution and much more than reservoir brine. The optimum concentration of silica NPs in surfactant solution is determined to achieve in highest IFT reduction. Also, contact angle measurements unraveled the vital role of the synthesized NPs hydrophilic nature in altering the wettability to strongly water-wet. Consecutive core flood examinations corroborated the significant improvement of the surfactant performance in EOR by the NPs.
通过界面张力(IFT)/接触角测量和几次岩心驱油来表征制备的样品,并评估二氧化硅纳米颗粒(NPs)和SDS表面活性剂在提高采收率(EOR)中的效果。NPs比表面活性剂溶液更能降低油/溶液的IFT,比储层盐水更能降低IFT。确定了表面活性剂溶液中二氧化硅纳米粒子的最佳浓度,以实现最高的IFT还原。此外,接触角测量揭示了合成的NPs的亲水性在将润湿性改变为强水润湿性方面的重要作用。连续岩心注水测试证实了NPs显著改善了表面活性剂在提高采收率中的性能。
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引用次数: 10
期刊
Journal of Petroleum & Environmental Biotechnology
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