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On the Desalination of Saline Waters via Batch Adsorption with Spent TeaLeaves 废茶叶批量吸附脱盐的研究
Pub Date : 2017-06-07 DOI: 10.4172/2157-7463.1000326
Kim G, García H, Japhe T, Iyengar R, Llanos Bp, A. Navarro
Desalination is a technology that still needs to take off in scientific research. The current techniques are not appropriate and still demand great investments of money, manpower and space. This study proposes the use of spent tea leaves on the removal of sodium ions from seawater. Although our results do not show a remarkable purification of saltwater (maximum observed adsorption percentage of 8%), but it demonstrates a strong effect of pH, adsorbent mass, salt concentration, presence of other ions and dyes. This indicates that the desalination by using these materials could be tuned and optimized (base-treated GT reached 16% adsorption). Furthermore, column experiments demonstrate that this desalination technique could be taken to automatized systems for the purification of larger water volumes. Instrumental analyses demonstrated that these materials have high heat resistance and appropriate morphological and textural properties, indicating that have appropriate mechanical properties for their use as adsorbents. Lastly, the uptake of sodium ions was improved by the treatment of the tea leaves with diluted acid and bases, indicating their potential as desalinating biomaterials. These results create a new mindset on the desalination as a fertile area that will benefit the society.
海水淡化是一项仍需在科学研究中起步的技术。目前的技术是不合适的,仍然需要大量的资金、人力和空间的投资。本研究提出利用废茶叶去除海水中的钠离子。虽然我们的结果没有显示出对盐水的显著净化(最大观察到的吸附率为8%),但它表明pH值、吸附剂质量、盐浓度、其他离子和染料的存在有很强的影响。这表明使用这些材料的海水淡化是可以调整和优化的(碱处理的GT吸附达到16%)。此外,柱实验表明,这种脱盐技术可以用于自动化系统的净化更大的水量。仪器分析表明,这些材料具有较高的耐热性和适当的形态和织构性能,表明它们具有适当的机械性能作为吸附剂。最后,通过稀释酸和碱处理茶叶,提高了钠离子的吸收,表明它们作为脱盐生物材料的潜力。这些结果创造了一种新的思维方式,将海水淡化作为一个肥沃的地区,将有利于社会。
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引用次数: 5
Nutritional and Bioactive Compounds Evaluation of Pleurotus pulmonarius(Freis) Quell Fruit bodies Grown on Different Wood Logs in Abia State, Nigeria 尼日利亚阿比亚州不同原木上生长的肺侧耳(Pleurotus pulmonarius, Freis) Quell果体的营养和生物活性成分评价
Pub Date : 2017-04-30 DOI: 10.4172/2157-7463.1000325
Nwoko Mc, Onyeizu Ur, Okwulehie Ic, U. Hn
Abstract This study was conducted to determine the nutritional and bioactive compounds composition of Pleurotus pulmonarius fruit bodies cultivated on tree logs of Dacryodes edulis, Mangifera indica and Treculia africana. Pure mycelium culture of P. pulmonarius was aseptically bulked in sorghum grains. Logs were cut into average length of 18 cm with inoculation holes of 3 cm × 15 mm diameter; using High Speed Drill (HSD) of 5 drill bit and allowed to decompose for 8months. During mushroom cultivation, logs were soaked in tap water for 24 hrs and pasteurized at 80°C in an improvised metallic drum (IMD) for 1hour; using cooking gas as heat source and allowed to cool overnight. 10 g of grain based spawn was inserted into 2/3 of each hole by way of inoculation and sealed with sterile polybag for mycelium incubation. Polybags were cut open after spawn run following primordial initiation. Fruit bodies were harvested at maturity, sun-dried ground and packed in airtight container prior to further analysis. Data were analyzed using Analysis of Variance (ANOVA) and mean separation by Duncan Multiple Range Test (DMRT) while levels of significance were determined at 5%. Results indicate that P. pulmonarius fruit bodies harvested from various tree logs were significantly different p<0.05 in their nutritional and bioactive compounds composition. Fruit body samples were rich in protein, carbohydrates, Na, K, and Ca. It was also observed that fruit bodies contained significant amount of Alkaloids, Tannins and Saponins; and could be useful in drug synthesis. Therefore, adopting this technique in oyster mushroom cultivation would lead to more jobs creation and food security; but this must be done with careful regulations to avoid indiscriminate felling of trees.
摘要本研究测定了在毛竹、芒果和非洲木本上栽培的肺侧耳子实体的营养成分和生物活性成分。用无菌方法在高粱籽粒中培养了肺假单胞菌纯菌丝体。原木切割成平均长度为18 cm,接种孔直径为3 cm × 15 mm;使用高速钻头(HSD) 5个钻头,并允许分解8个月。在蘑菇培养过程中,原木在自来水中浸泡24小时,在简易金属桶(IMD)中80°C巴氏消毒1小时;使用烹饪气体作为热源,冷却过夜。用接种法在每孔2/3处插入10 g粒基菌种,用无菌塑料袋密封菌丝孵育。在原始初始化后的产卵运行后,塑料袋被切开。成熟时收获果体,晒干地面,在进一步分析之前装入密封容器。数据分析采用方差分析(ANOVA)和Duncan多元极差检验(DMRT)进行均值分离,显著性水平为5%。结果表明,不同木材采收的肺伪木果体的营养成分和生物活性成分差异显著p<0.05。果体样品富含蛋白质、碳水化合物、Na、K和Ca,同时还含有大量的生物碱、单宁和皂苷;在药物合成中也很有用。因此,在平菇种植中采用这种技术将创造更多的就业机会和粮食安全;但这必须在谨慎的规定下进行,以避免滥伐树木。
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引用次数: 5
Application of a Novel Ultrasonic Technology to Improve Oil Recovery with an Environmental Viewpoint 从环保的角度看超声波技术在提高采收率中的应用
Pub Date : 2017-04-30 DOI: 10.4172/2157-7463.1000323
Hesam Arabzadeh, M. Amani
It is proven by recent studies that sonication has a positive influence over the oil flow within the porous media. Accordingly, the researchers in this paper evaluated the influence of sonication over the oil recovery by means of free fall gravity drainage. Furthermore, the influence of sonication on the oil permeability was assessed in three samples that had different bead size in average. By use of the Hagroot backward method and Matlab simulation, the optimal petrophysical situation for sonication was determined. The authors concluded that sonication positively affects the oil recovery for the non-asphaltenic samples, while it has a reverse effect on the asphaltenic samples because of increasing the viscosity in long-term. Furthermore, it was witnessed that gravity drainage was heightened by increase of beads’ size in the non-asphaltenic sample. Accordingly, this mechanism can be useful in oil recovery by means of gravity drainage, specifically in fracture reservoirs.
近年来的研究证明,超声对多孔介质内的油流有积极的影响。因此,本文采用自由落体重力泄油的方法,评价了超声对采收率的影响。此外,在三个平均粒径不同的样品中,评估了超声对油渗透率的影响。利用Hagroot反求法和Matlab仿真,确定了声波探测的最佳岩石物性条件。结果表明,超声波对非沥青质样品的采收率有积极的影响,而对沥青质样品的采收率则有相反的影响,因为从长期来看,超声波会增加沥青质样品的粘度。在非沥青质样品中,随着颗粒尺寸的增大,重力疏水性增强。因此,该机制可用于重力排水采油,特别是裂缝油藏。
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引用次数: 6
Utilization of Shredded Waste Car Tyres as a Fracture Seal Material (FSM) in Oil and Gas Drilling Operations 废车胎碎作为断裂密封材料在油气钻井作业中的应用
Pub Date : 2017-04-30 DOI: 10.4172/2157-7463.1000322
M. Al-Awad, K. A. Fattah
The drilling operation cost represents 25% of the total oilfield exploitation cost. Drilling fluids represent 15 to 18% of the total cost of well petroleum drilling operations. The main drilling fluids problem is the loss into fractures and vugs. Mitigation of severe lost circulation is a main challenge while drilling in fractured formations where conventional lost circulation materials (LCM) will not cure these losses. Therefore, specialized fracture seal material (FSM) is required when drilling fractured formations. In this study, a promising FSM made from shredded waste car tyres was tested at laboratory for its ability to seal artificially fractured cores under High Temperature High Pressure (HT-HP) conditions similar to wellbore conditions. For this purpose, the conventional 500 ml HT-HP filtration cell was modified to accommodate a fractured core plug of length and diameter equal to 38.1 mm (1.5 inches) instead of the ceramic disc. Moreover, the cell outlet channel located below the fractured plug was increased from 1.0 mm diameter to 5.0 mm to easily allow the passage of the FSM in none effective fracture seal tests. Using the modified HT-HP filtration cell shredded waste car tyres proved its ability to perfectly seal the artificially made fracture in the test core samples at overbalance pressures up to 900 psi and temperatures up to 80°C. The optimum mud composition was fresh water, 7% by weight bentonite, 7% shredded waste car tyres (a mixture ranging between 2.3 mm and less than 0.45 mm granule sizes) in weight bases. In addition to its great ability to seal fractured formation, the shredded waste car tyres material is cheap and locally available in commercial quantities. Additionally, the utilization of waste car tyres in drilling operations and other industrial applications can protect the environment from many hazards.
钻井作业成本占油田开发总成本的25%。钻井液成本占油井钻井作业总成本的15%至18%。钻井液的主要问题是流失到裂缝和空隙中。在裂缝地层钻井时,减少严重的井漏是主要挑战,常规的井漏材料(LCM)无法消除这些井漏。因此,在压裂地层钻井时,需要使用专用的压裂密封材料(FSM)。在这项研究中,研究人员在实验室测试了一种由废弃汽车轮胎碎片制成的FSM,该FSM具有在类似于井筒条件的高温高压(HT-HP)条件下密封人工压裂岩心的能力。为此,对传统的500ml HT-HP过滤池进行了改进,以容纳长度和直径为38.1 mm(1.5英寸)的压裂芯塞,而不是陶瓷盘。此外,位于裂缝塞下方的储液池出口通道直径从1.0 mm增加到5.0 mm,以便在无有效裂缝密封测试中允许FSM通过。使用改进的HT-HP过滤单元,废弃汽车轮胎碎片在高达900 psi的超平衡压力和高达80°C的温度下,能够完美地密封测试岩心样品中人为制造的裂缝。最佳泥浆组成为淡水、7%的膨润土、7%的废汽车轮胎碎(颗粒大小在2.3毫米到小于0.45毫米之间的混合物)。除了具有密封裂缝地层的强大能力外,废汽车轮胎碎片材料价格便宜,在当地可以大量商用。此外,在钻井作业和其他工业应用中利用废旧汽车轮胎可以保护环境免受许多危害。
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引用次数: 8
Bioremoval of Heavy Metals from Effluent of Port Harcourt Refinery UsingPluerotus ostreatus 哈科特港炼油厂废水中重金属的生物去除研究
Pub Date : 2017-04-25 DOI: 10.4172/2157-7463.1000324
Stanley Ho, Ihennacho Cm, Stanley Cn
The presence of heavy metals in refinery effluent has the potential to pose significant risks to human health and the environment. However, the conventional heavy metal removal has limitations hence the need to introduce alternative treatments. Recently, there have been considerable interests in bio-adsorption of heavy metal using fungus. In the present study, the effectiveness of iron, zinc, lead, nickel, cadmium and chromium removal from refinery effluent was evaluated using living white rot fungus (spawn) viz., Pleurotus ostreatus. The fungus was amended with sawdust and rice bran. Physiochemical analysis of the effluent on day zero indicated the presence of Iron (0.775 mg/L), Zinc (0.750 mg/L), Lead (0.031 mg/L), Nickel (0.188 mg/L), Chromium (0.025 mg/L) and Cadmium (0.054 mg/L). P. ostreatus bioremoved the metals under study at pH 7.6, Temperature at 26.8°C and contact time 60 days with substrate (sawdust mixed with rice bran). Throughout the research, the percentage of removal was found to increase with increasing contact time. The heavy metals were determined using an atomic absorption spectrophotometer. Sawdust mixed with rice bran colonized with P. ostreatus spawn could be utilized as an excellent biosorbent thus exhibiting efficiency for Iron 80%, Zinc 99%, Lead 94%, Nickel 99%. Chromium 93%, and Cadmium 96% respectively. The analysis of variance of the five variables: lead, iron, nickel, cadmium and chromium showed that there was no significant difference at P<0.05 with the exception of iron. It was observed that P. ostreatus is efficient in bioremoving heavy metals as the levels of remaining heavy metals in the refinery effluent were below the limit of detection (<0.001 mg/L). This validates P. ostreatus as a potential bio-sorbent and can be employed in treatment of environments polluted with effluent containing high levels of lead, zinc, iron, nickel, cadmium and chromium.
炼油厂废水中重金属的存在有可能对人类健康和环境构成重大风险。然而,传统的重金属去除方法存在局限性,因此需要引入替代方法。近年来,利用真菌对重金属进行生物吸附的研究引起了广泛的关注。本研究利用白腐菌(菌种)平菇(Pleurotus ostreatus)对炼油厂废水中铁、锌、铅、镍、镉和铬的去除效果进行了评价。用木屑和米糠对真菌进行了改性。第0天的废水理化分析表明,存在铁(0.775 mg/L)、锌(0.750 mg/L)、铅(0.031 mg/L)、镍(0.188 mg/L)、铬(0.025 mg/L)和镉(0.054 mg/L)。在pH 7.6、温度26.8℃、与底物(木屑与米糠混合)接触60天的条件下,P. ostreatus生物去除所研究的金属。在整个研究过程中,发现去除百分比随着接触时间的增加而增加。用原子吸收分光光度计测定重金属。木屑与米糠混合可作为一种优良的生物吸附剂,对铁、锌、铅、镍的吸附效率分别为80%、99%、94%和99%。铬93%,镉96%。对铅、铁、镍、镉、铬5个变量进行方差分析,除铁外,差异均无统计学意义(P<0.05)。结果表明,在炼化废水中残留重金属低于检测限(<0.001 mg/L)的情况下,P. ostreatus对重金属的生物去除效果良好。这证实了P. ostreatus是一种潜在的生物吸附剂,可用于处理含有高浓度铅、锌、铁、镍、镉和铬的废水污染的环境。
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引用次数: 5
Recovery of Phase Transferee Catalysts from Waste-water by Adsorption onZeolite 沸石吸附法回收废水中相转移催化剂
Pub Date : 2017-04-07 DOI: 10.4172/2157-7463.1000320
N. El-Mehbad
The interaction between zeolite and phase transfer catalysts PTC (cationic surfactants) is of great interest. In this paper, study the influence of various physical and chemical parameters. On the adsorption of PTC on zeolite is compared according their efficiency on removal PTC at constant conditions. The optimum conditions are studied to removal PTC. Thermodynamic of adsorption are calculated to suggest the mechanism of adsorption. The effects of different conditions are studied to investigate degree of removal PTC. Furthermore, the effect of hydrophilic and hydrophobic of PTC on efficiency of adsorption on zeolite is discussed according to thermodynamic adsorption parameters. A dsorption isotherm is studied according Frumkin isotherm. The mechanism of adsorption suggested with respect micellization processes and adsorption at solution/air interface. Furthermore, cross sectional area of phase transfer catalyst affect on degree of its adsorption. The results confirm the effect of pH and chemical structures of PTC efficiency of adsorption by zeolite.
沸石与相转移催化剂PTC(阳离子表面活性剂)之间的相互作用引起了人们的极大兴趣。本文研究了各种理化参数的影响。比较了两种分子筛在一定条件下对PTC的吸附效果。研究了去除PTC的最佳工艺条件。计算了吸附热力学,提出了吸附机理。研究了不同条件对PTC去除率的影响。根据热力学吸附参数,讨论了PTC的亲疏水性对沸石吸附效率的影响。根据弗鲁姆金等温线研究了吸附等温线。从胶束过程和液/气界面吸附两方面提出了吸附机理。此外,相转移催化剂的横截面积对其吸附程度也有影响。结果证实了pH和化学结构对沸石吸附PTC效率的影响。
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引用次数: 0
Biodiesel production from waste vegetable oil (Sunflower) obtained from fried chicken and plantain 从炸鸡和车前草中提取的废植物油(向日葵)生产生物柴油
Pub Date : 2017-03-28 DOI: 10.4172/2157-7463.1000321
Benard A Udehab
Waste sunflower oil sourced from fried chicken and plantain was used for biodiesel production in this study. During the transesterification process, 161 ml of ethanol containing 96% (v/v) was added to 250 ml of waste sunflower oil using NaOH as the catalyst at different concentrations (2.0% to 4.0%) and temperatures (45°C, 60°C, 70°C and 85°C). Biodiesel yield of 88.6% was obtained at the temperature of 70°C in 3.0% NaOH. Viscosity test at room temperature and specific gravity evaluation recorded 2.81 cm2s-1 and 0.912 Kg/m3 respectively. The high energy density obtained from waste sunflower biodiesel blend is comparable with the hydrocarbon-based fossil fuel, an indication for smooth engine runs. This means that waste sunflower oil could be a veritable material for energy production as the alternative to greenhouse issues of fossil fuel diesel blend.
本研究利用从炸鸡和车前草中提取的废弃葵花籽油生产生物柴油。在酯交换过程中,以NaOH为催化剂,在不同浓度(2.0% ~ 4.0%)和温度(45℃、60℃、70℃、85℃)下,将浓度为96% (v/v)的乙醇161 ml加入到250 ml废葵花籽油中。在70℃、3.0% NaOH条件下,生物柴油的产率为88.6%。室温粘度测试和比重评估分别为2.81 cm2s-1和0.912 Kg/m3。从废弃向日葵生物柴油混合物中获得的高能量密度与碳氢化合物基化石燃料相当,这表明发动机运行平稳。这意味着废弃的葵花籽油可以成为名副其实的能源生产材料,作为化石燃料柴油混合物温室问题的替代品。
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引用次数: 7
An Improved Film Thickness Model for Annular Flow Pressure GradientEstimation in Vertical Gas Wells 垂直气井环空流动压力梯度估算的改进气膜厚度模型
Pub Date : 2017-02-28 DOI: 10.4172/2157-7463.1000314
Rahman Ma, Jacqueline Stevens, J. Pardy, D. Wheeler
The presence of liquids in natural gas wells increases the pressure loss within the well due to differences in density of the pressure head. In gas, well annular flow, liquid may be present in entrained droplets as well as in the liquid film. Several models have been proposed to predict liquid film thickness in pipes with vertical two-phase annular flow. Earlier models are based limited range of experimental data. The earlier models also require exhaustive iterative procedure to estimate liquid film thickness. On the other hand, the proposed modified film thickness model in this study was developed from a wide range of experimental data. The experimental data covers conditions of superficial liquid velocities ranging from 0.6 to 38.8 cm/s; superficial gas velocities ranging from 13.4 to 110.6 m/s; and diameters ranging from 12 to 51 mm. The proposed model is compared with the available experimental data in the literature. Model predictions are in good agreement with the available experimental data set. The modified film thickness model helps accurate estimation of pressure gradient in vertical annular flow, which in turn is beneficial to the natural gas production industry as it further develops the understanding of production mechanics.
由于压力头密度的差异,天然气井中液体的存在增加了井内的压力损失。在气井环空流动中,液体可以存在于夹带的液滴中,也可以存在于液膜中。提出了几种预测垂直两相环流管道液膜厚度的模型。早期的模型是基于有限范围的实验数据。早期的模型还需要穷举迭代过程来估计液膜厚度。另一方面,本文提出的修正膜厚模型是在广泛的实验数据基础上建立起来的。实验数据涵盖了液体表面速度为0.6 ~ 38.8 cm/s的条件;表面气速范围为13.4 ~ 110.6 m/s;直径从12毫米到51毫米不等。将所提出的模型与文献中已有的实验数据进行了比较。模型预测与现有的实验数据集很好地吻合。修正后的气膜厚度模型有助于准确估计垂向环空流体的压力梯度,从而进一步加深对生产机理的认识,有利于天然气生产行业的发展。
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引用次数: 2
Improving Recovery Through Surfactant Desorption on An Oil Wet LimestoneReservoir 表面活性剂解吸提高含油石灰石油藏采收率
Pub Date : 2017-02-28 DOI: 10.4172/2157-7463.1000319
Prince Mja
The current paper investigates on reducing surfactant adsorption after its application onto limestone surface by Ethelene Oxide (EO) conjugated with Sodium Dodecyl Sulphonate (SDS) to improve oil recovery. SDS has been treated with EO as a nonionic surfactant with low critical micelle concentration to increase its hydrophilic nature that leads to desorb itself from oil wet surfaces like limestone reservoirs after altering wettability. Although, surfactant has a great impact on Oil recovery, adsorption makes them ineffective. It’s been a great concern for petroleum industry during enhanced oil recovery operations. This study focuses on finding a mechanism to reduce SDS adsorption on an oil wet limestone core sample and altering its wettability through EO at different concentrations. Critical Micelle Concentration (CMC) of SDS was found at 500 ppm by conductivity test was chosen to reduce interfacial tension between oil and brine composition. Due to surface charge variation SDS was observed to adsorb onto limestone surface through core analysis. It has been flooded after water under core flooding operations, which shows near to field observations. For reducing this effect, EO was introduced with different concentrations to alter the hydrophilic properties of SDS. Being limestone oil wet surface, which leads SDS to adsorb onto its surface. Since, SDS would adhere onto the inner layers of core lead to alter wettability by recovering crude. The recovery of crude from a limestone core has been carried in two ways. Firstly, SDS was treated to get adsorb onto the core surface and secondly desorption of SDS by enhancing its hydrophilic nature through EO. By its application, the recovery of oil has been improved by reduction in adsorption of SDS successfully have been reported.
本文研究了环氧乙烷(EO)与十二烷基磺酸钠(SDS)偶联后在石灰石表面减少表面活性剂吸附以提高采收率的方法。SDS作为一种临界胶束浓度较低的非离子表面活性剂,经EO处理后可提高其亲水性,从而在改变润湿性后从石灰石储层等油湿表面解吸。表面活性剂虽然对采收率有很大的影响,但吸附作用使其失效。在提高石油采收率的过程中,它一直是石油工业非常关注的问题。本研究的重点是寻找一种减少SDS在油湿石灰岩岩心样品上吸附的机制,并通过不同浓度的EO改变其润湿性。电导率测试发现SDS的临界胶束浓度(CMC)为500 ppm时,可降低油盐组分之间的界面张力。通过岩心分析发现,由于表面电荷的变化,SDS吸附在石灰石表面。在岩心注水作业后被淹,这与现场观测结果接近。为了减少这种影响,引入不同浓度的EO来改变SDS的亲水性。由于石灰石表面油湿,导致SDS吸附在其表面。因为SDS会附着在岩心导联的内层上,通过回收原油来改变润湿性。从石灰岩岩心中回收原油有两种方法。首先对SDS进行吸附处理,使其吸附在岩心表面,然后通过EO增强SDS的亲水性进行脱附。通过它的应用,成功地减少了SDS的吸附,提高了油的采收率。
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引用次数: 0
Energy Efficient Enhancement and Initial Cost Saving Mechanisms for Petrochemical Manufacturing Industrial Applications 石油化工制造工业应用的能源效率提升和初始成本节约机制
Pub Date : 2017-02-20 DOI: 10.4172/2157-7463.1000E131
B. Prabhu, N. Balakumar
Energy plays a major role in all the petro-chemical industrial applications because it involves the initial cost. All the petro chemical industry produces a large volume and intermediary organic chemicals as well as large volume of plastics. Energy efficient enhancement is a significant way to decrease these cost and to increase the expectable earnings. Majority of opportunities are available at industrial plants in the USA petro chemical industry to decrease energy consumption in a cost effective manner.
能源在所有石油化工工业应用中起着重要作用,因为它涉及到初始成本。所有的石油化工工业生产大量的中间有机化学品和大量的塑料。提高能源效率是降低这些成本和增加预期收益的重要途径。在美国石油化工行业,大多数工厂都有机会以具有成本效益的方式减少能源消耗。
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引用次数: 1
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Journal of Petroleum & Environmental Biotechnology
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