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Enhanced coalbed methane recovery by microwave-induced thermal fracture 通过微波诱导热裂缝提高煤层气回收率
Pub Date : 2024-08-31 DOI: 10.1088/1742-6596/2838/1/012005
Song Wu, Shen Li, Shuxia Yuan, Bintao Guo and Quansen Niu
The investigation on microwave-induced permeabilization and response of coal under microwave heating is of great significance for the industrial application of microwave heating technology instead of traditional heating in coalbed methane mining. Santanghu coal is used as a sample to measure the permeability and porosity of coal samples before and after microwave heating. The fracture changes of coal samples before and after heating are compared to observe the penetration effect of microwaves on coal samples. Based on the technology of directional drilling and continuous tubing technology in petroleum engineering, a technology of increasing the production of coalbed methane by microwave heating in a wide range of coal seams is proposed. The feasibility of this enhanced production method is validated through COMSOL Multiphysics simulations, which model the temperature field distribution within coal seams under various microwave parameters. This approach highlights the potential of microwave technology in coalbed methane recovery. The results show that: (1) the thermal field of coal samples under microwave heating is inhomogeneous. The average length and area of the cracks of the coal samples increased under microwave radiation, and the cracking of the coal samples confirmed the cracking effect of microwaves on the coal samples. (2) With prolonged microwave heating, coal samples exhibit an initial decrease followed by an increase in porosity and permeability, a trend attributed to the expansion of solid particles that occupy and reduce pore spaces. (3) The in-situ microwave heating technique for coalbed methane extraction overcomes the challenges of long-distance microwave transmission loss and methane backflow in transmission pipelines, utilizing continuous pipelines for extensive microwave heating of coal seams. (4) The microwave power and intermittent heating duration have a significant effect on the temperature field distribution of the coal seam, and when the heating duration is 60 days, 1600 W is used to have an effective temperature field distribution while avoiding the waste of heat. When the power is constant at 1600 W, the effective temperature range is wider when the intermittent heating duration is 60 days.
研究微波加热下煤炭的透气性和响应,对于在煤层气开采中以微波加热技术替代传统加热技术的工业应用具有重要意义。以三塘湖煤为样品,测量煤样在微波加热前后的透气性和孔隙度。对比煤样加热前后的断裂变化,观察微波对煤样的穿透效果。以石油工程中的定向钻井技术和连续油管技术为基础,提出了在大范围煤层中通过微波加热提高煤层气产量的技术。通过 COMSOL 多物理场仿真,模拟了不同微波参数下煤层内的温度场分布,验证了这种增产方法的可行性。这种方法凸显了微波技术在煤层气回收中的潜力。结果表明(1) 煤样在微波加热下的热场是不均匀的。煤样裂纹的平均长度和面积在微波辐射下增加,煤样的裂纹证实了微波对煤样的裂纹效应。(2)随着微波加热时间的延长,煤样的孔隙率和透气性先下降后上升,这种趋势归因于固体颗粒的膨胀占据并减少了孔隙空间。(3) 煤层甲烷抽采的原位微波加热技术克服了长距离微波传输损耗和甲烷在传输管道中倒流的难题,利用连续管道对煤层进行大范围微波加热。(4)微波功率和间歇加热时间对煤层的温度场分布有显著影响,当加热时间为 60 天时,采用 1600 W 的微波功率可获得有效的温度场分布,同时避免热量浪费。当功率恒定为 1600 W 时,当间歇加热持续时间为 60 天时,有效温度范围较宽。
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引用次数: 0
Ultrafast reaction kinetic of polyaniline in flexible hydrogel electrodes facilitated by graphene ribbons 石墨烯带促进柔性水凝胶电极中聚苯胺的超快反应动力学
Pub Date : 2024-08-31 DOI: 10.1088/1742-6596/2838/1/012007
Pengfei Gao and Zhuangjun Fan
By loading energy storage active materials on hydrogel which is inherently flexible, the flexibility of electrode materials can be simply realized, thereby achieving the flexibility of energy storage devices. However, the polymer network that constructs the three-dimensional skeleton of the hydrogel is not conductive, which inhibits the redox ability of the active material. If a high speed conductive structure can be added to the colloidal phase, the performance of the flexible electrode material can be greatly improved. Here, we introduce redox graphene ribbons into the polyvinyl alcohol hydrogel loaded with polyaniline. The in situ three-dimensional conductive graphene network greatly enhanced the conductivity of the hydrogel electrode, thus increasing the specific capacitance to as high as 1117 F g−1 at 2 mg cm−2 mass loading, with a retention ratio of 66.96% from 0.5 A g−1 to 20 A g−1. These highlighted properties enable the PRP hydrogel as an electrode for flexible supercapacitors, which provides a promising possibility for the practical application of wearable electronics.
通过在本身具有柔性的水凝胶上负载储能活性材料,可以简单地实现电极材料的柔性,从而实现储能设备的柔性。然而,构建水凝胶三维骨架的聚合物网络并不导电,这就抑制了活性材料的氧化还原能力。如果能在胶体相中加入高速导电结构,就能大大提高柔性电极材料的性能。在这里,我们将氧化还原石墨烯带引入负载聚苯胺的聚乙烯醇水凝胶中。原位三维导电石墨烯网络极大地增强了水凝胶电极的导电性,因此在 2 mg cm-2 质量负载条件下,比电容高达 1117 F g-1,从 0.5 A g-1 到 20 A g-1 的保持率为 66.96%。这些突出特性使 PRP 水凝胶成为柔性超级电容器的电极,为可穿戴电子设备的实际应用提供了可能。
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引用次数: 0
Preparation and performance study of organic small molecule photovoltaic donor materials in solar cells 太阳能电池中有机小分子光伏供体材料的制备和性能研究
Pub Date : 2024-08-31 DOI: 10.1088/1742-6596/2838/1/012006
Ping Xiong, Ning Fu and Yifan Zhang
In this study, PDPAT-BDT-BT was used as a donor material, combined with PC61BM and PC71BM as acceptor materials, to prepare a hybrid thin film for organic solar cells. In photovoltaic performance tests, this film shows advantages and good characteristics. The experimental results show that the PDPAT-BDT-BT polymer shows good performance in terms of thermal stability, optical properties, and electrochemical properties. It also shows better photovoltaic performance in the hybrid system with PC71BM, which lays a good foundation for its potential application in organic solar cells.
本研究以 PDPAT-BDT-BT 为给体材料,结合 PC61BM 和 PC71BM 为受体材料,制备了一种用于有机太阳能电池的混合薄膜。在光伏性能测试中,该薄膜显示出优势和良好特性。实验结果表明,PDPAT-BDT-BT 聚合物在热稳定性、光学性能和电化学性能方面都表现出良好的性能。在与 PC71BM 的混合体系中,它还显示出更好的光伏性能,这为其在有机太阳能电池中的潜在应用奠定了良好的基础。
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引用次数: 0
Controllable Oil Adsorption from water Using Hydrophobic (Paraffin/Stearic Acid)/CoFe2O4 Magnetized Fibril Wax 利用疏水性(石蜡/硬脂酸)/CoFe2O4 磁化纤维蜡对水中油类进行可控吸附
Pub Date : 2024-08-31 DOI: 10.1088/1742-6596/2830/1/012005
M. M. Ghobashy
The development of efficient oil-water separation techniques is critical for mitigating environmental pollution from industrial oily wastewater. This study synthesized a hydrophobic and oleophilic (paraffin/stearic acid) (Par/St)/CoFe2O4 magnetized fibril wax for controllable adsorption and removal of waste engine oil from water. Structural and morphological characterization confirmed the successful incorporation of 30 wt% CoFe2O4 nanoparticles into the Par/St wax matrix with fibril morphology. Structural and morphological characterization using TEM, UV-Vis, FTIR, XRD, and SEM consistently confirmed the successful integration of CoFe2O4 nanoparticles into the Par/St wax matrix, forming fibrils with a high surface area. The oleophilic fibril demonstrated rapid adsorption and excellent removal efficiency of 99% for waste engine oil within 30 seconds. The fibrils could be magnetically guided for oil collection, ensuring reusable and eco-friendly oil remediation. This work introduces a novel solution for controllable oil spill clean-up and oily wastewater treatment.
开发高效的油水分离技术对于减轻工业含油废水造成的环境污染至关重要。本研究合成了一种疏水性和亲油性(石蜡/硬脂酸)(Par/St)/CoFe2O4 磁化纤维蜡,用于可控吸附和去除水中的废机油。结构和形态表征证实,30 wt% 的 CoFe2O4 纳米颗粒成功地融入了具有纤维形态的 Par/St 蜡基质中。利用 TEM、UV-Vis、FTIR、XRD 和 SEM 进行的结构和形态表征一致证实,CoFe2O4 纳米粒子成功地融入了 Par/St 蜡基质,形成了具有高表面积的纤维。这种亲油纤维具有快速吸附能力,在 30 秒内对废机油的去除率高达 99%。纤维可通过磁力引导进行油收集,确保可重复使用和环保的油修复。这项研究为可控溢油清理和含油废水处理提供了一种新的解决方案。
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引用次数: 0
Decarbonizing natural gas infrastructure: blending hydrogen for sustainable energy 天然气基础设施的去碳化:为可持续能源混合氢气
Pub Date : 2024-08-31 DOI: 10.1088/1742-6596/2830/1/012007
Z I Tawfik, S T El-Sheltawy and A R Abdelghany
The paper explores the potential of hydrogen as a clean energy carrier and its integration into existing natural gas systems to reduce carbon intensity. It highlights the need for infrastructure impact studies and significant investment to realize the vision of green hydrogen. It also discusses the properties of hydrogen compared to natural gas, its production methods, and the potential for blending hydrogen into existing natural gas pipelines. Additionally, it provides insights into Egypt’s energy sector and its efforts to embrace renewable energy. It concludes by summarizing notable studies and projects related to hydrogen-natural gas blending. The blending of hydrogen into natural gas systems is an important and achievable first step towards full conversion to 100% hydrogen. The paper presents a compilation of hydrogen blending projects from different countries, showcasing the collaborative efforts and advancements in integrating hydrogen into existing energy systems.
本文探讨了氢气作为清洁能源载体的潜力,以及将其融入现有天然气系统以降低碳强度的问题。它强调了进行基础设施影响研究和大量投资以实现绿色氢能愿景的必要性。报告还讨论了氢气与天然气相比的特性、生产方法以及将氢气掺入现有天然气管道的潜力。此外,报告还深入探讨了埃及的能源行业及其在利用可再生能源方面所做的努力。报告最后总结了与氢气-天然气混合相关的著名研究和项目。在天然气系统中掺入氢气是向完全转化为 100% 氢气迈出的重要且可实现的第一步。本文汇编了不同国家的氢气混合项目,展示了将氢气融入现有能源系统的合作努力和进展。
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引用次数: 0
Anti-corrosive properties of vermiculite-enhanced waterborne epoxy resins with two-dimensional exfoliation 二维剥离蛭石增强型水性环氧树脂的抗腐蚀性能
Pub Date : 2024-08-31 DOI: 10.1088/1742-6596/2838/1/012008
Zhiyuan Li, Lisha Ren, Tong Wei and Zhuangjun Fan
Although waterborne epoxy resin coatings are widely used in the field of anti-corrosion, micropores and micro defects in their coatings are the key factors restricting their further development. The exfoliated vermiculite was stripped by a physical one-step stripping method, with good water dispersion and dense lamellar structure. As the nano-filler, it can effectively fill the micro defects in the coating, make the coating structure more compact, and effectively prevent the intrusion of corrosive media. When exfoliated vermiculite was added at 1%, two orders of magnitude increased the electrochemical impedance modulus to 2.276×106 Ω cm2 and the corrosion current was correspondingly reduced to 1.186×10−8 A cm−2, showing excellent corrosion resistance. Adding 1% exfoliated vermiculite creates a “labyrinth effect” in the coating that extends the penetration path of the corrosion particles, thus effectively preventing corrosion of the underlying metal substrate. This enables the coating to better cope with harsh corrosive environments and provides a viable idea for coating protection.
尽管水性环氧树脂涂料在防腐领域应用广泛,但其涂层中的微孔和微缺陷是制约其进一步发展的关键因素。采用物理一步剥离法剥离的剥离蛭石具有良好的水分散性和致密的片状结构。作为纳米填料,它能有效填补涂层中的微小缺陷,使涂层结构更加致密,有效防止腐蚀性介质的侵入。当剥离蛭石的添加量为 1%时,电化学阻抗模量提高了两个数量级,达到 2.276×106 Ω cm2,腐蚀电流也相应降低到 1.186×10-8 A cm-2,显示出优异的耐腐蚀性能。添加 1%的剥落蛭石可在涂层中产生 "迷宫效应",延长腐蚀粒子的穿透路径,从而有效防止底层金属基材的腐蚀。这使涂层能够更好地应对恶劣的腐蚀环境,为涂层保护提供了一种可行的思路。
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引用次数: 0
Modification of Nanyang crude oil by a functional magnetically responsive flow modifier in synergy with magnetic field 功能性磁响应流动改性剂与磁场协同作用对南阳原油进行改性
Pub Date : 2024-08-31 DOI: 10.1088/1742-6596/2838/1/012001
Feng Yan, Jionghao Li, Qifu Li, Yunchen Wang, Chaofei Nie, Fan Xiao and Bohong San
Nanyang crude oil is classified as high wax crude oil. It has severe wax deposition and poor low-temperature fluidity, which pose a major risk to the safety of pipeline transportation of wax-containing crude oil. A large-size polymer-coated magnetic nanosphere was created by dispersion polymerization employing methyl methacrylate, nano-iron oxide, tetraethoxysilane, and dodecyltriethoxysilane as raw materials to address the aforementioned issues.Ethylene-vinyl acetate copolymer was compounded to provide a useful magnetic response flow modifier.Using FTIR and ESEM, the polymer grafted on the iron oxide nanosphere’s surface was shown. After evaluating the functional magnetic response flow modifier’s impact on the yield stress and viscosity of a Nanyang crude oil, the effect of the magnetic field was introduced to analyze the functional magnetic response flow modifier’s synergistic effect on viscosity and yield stress. The results show that the functional magnetic response flow modifier may greatly lower yield stress and viscosity when compared to the EVA pour point depressant. Additionally, applying an alternating magnetic field could amplify the functional magnetic response flow modifier’s beneficial effects on Nanyang crude oil.
南阳原油属于高蜡原油。其蜡沉积严重,低温流动性差,对含蜡原油的管道运输安全构成重大威胁。为了解决上述问题,我们以甲基丙烯酸甲酯、纳米氧化铁、四乙氧基硅烷和十二烷基三乙氧基硅烷为原料,通过分散聚合制造出了大尺寸聚合物包覆磁性纳米球。在评估了功能性磁响应流动改性剂对南阳原油屈服应力和粘度的影响后,引入磁场效应分析功能性磁响应流动改性剂对粘度和屈服应力的协同效应。结果表明,与 EVA 降凝剂相比,功能性磁响应流动改性剂可大大降低屈服应力和粘度。此外,应用交变磁场可以放大功能磁响应流动改性剂对南阳原油的有利影响。
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引用次数: 0
Corrosion Resistance Improvement of Mild Steel 提高低碳钢的抗腐蚀能力
Pub Date : 2024-08-31 DOI: 10.1088/1742-6596/2830/1/012002
M Sheashea, B Zagloul, M Zorainy, I Naeem and M Gobara
Corrosion’s devastating consequences have become a big issue all over the world. One of the corrosion damage aspects are related to decontamination solutions which are essential for rapid degradation of toxic agents. The decontamination solutions should be non-corrosive to avoid deterioration of steel container. Decontamination solutions comprising have high chlorinating activity so they have a corrosive effect on mild which are used in fabrication of storage tanks. In this case, using inhibitors is one of the most effective strategies to limit the rate of corrosion. This work describes the effect of different compounds; (zinc chromate, cinnamaldehyde, sodium tripolyphosphate, zinc ortho-phosphate, ammonium molybdate and thiourea) on the rate of corrosion of mild steel within dichloroisocyanuric acid decontamination solution. Meanwhile, these inhibitors should not affect active chlorine content which is responsible for the decontamination process. By using kelthoff and AquaChec® methods for measuring active chlorine, it was found that only zinc chromate passed the tests. For measuring electrochemical behaviour of mild steel in decontamination solutions, different techniques were used. Zinc chromate inhibition on mild steel in a 0.5% dichloroisocyanuric acid solution at different temperatures (298–313 K) were studied utilising electrochemical impedance spectroscopy, weight loss, and potentiodynamic polarisation. The results reveal that zinc chromate is an excellent mild steel corrosion inhibitor in dichloroisocyanuric acid, with an inhibition efficacy of 96% at a concentration of 0.005 M. Finally, surface morphology of mild was also investigated using SEM.
腐蚀的破坏性后果已成为全世界的一个大问题。腐蚀破坏的其中一个方面与去污溶液有关,而去污溶液对于快速降解毒剂至关重要。去污溶液应该是非腐蚀性的,以避免钢制容器的腐蚀。去污溶液包括具有高氯化活性的溶液,因此会对用于制造储罐的低碳钢产生腐蚀作用。在这种情况下,使用抑制剂是限制腐蚀速度的最有效策略之一。本研究介绍了不同化合物(铬酸锌、肉桂醛、三聚磷酸钠、正磷酸锌、钼酸铵和硫脲)对二氯异氰尿酸去污溶液中低碳钢腐蚀速度的影响。同时,这些抑制剂不应影响起净化作用的活性氯含量。通过使用 kelthoff 和 AquaChec® 方法测量活性氯,发现只有铬酸锌通过了测试。为了测量低碳钢在去污溶液中的电化学行为,使用了不同的技术。利用电化学阻抗光谱法、失重法和电位极化法研究了 0.5% 二氯异氰尿酸溶液在不同温度(298-313 K)下铬酸锌对低碳钢的抑制作用。结果表明,铬酸锌在二氯异氰尿酸中是一种极好的低碳钢缓蚀剂,浓度为 0.005 M 时的缓蚀效果高达 96%。
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引用次数: 0
Peer Review Statement 同行评审声明
Pub Date : 2024-08-31 DOI: 10.1088/1742-6596/2838/1/011002
All papers published in this volume have been reviewed through processes administered by the Editors. Reviews were conducted by expert referees to the professional and scientific standards expected of a proceedings journal published by IOP Publishing. • Type of peer review: Single Anonymous • Conference submission management system: Morressier • Number of submissions received: 86 • Number of submissions sent for review: 74 • Number of submissions accepted: 45 • Acceptance Rate (Submissions Accepted / Submissions Received × 100): 52.3 • Average number of reviews per paper: 3 • Total number of reviewers involved: 10 • Contact person for queries: Name: Xuexia Email: xx.ye@keoaeic.org Affiliation: AEIC Academic Exchange Information Centre
本卷中发表的所有论文均已通过编辑部的审核。审稿专家按照 IOP 出版社出版的论文集期刊应有的专业和科学标准进行审稿。- 同行评审类型:单一匿名 - 会议投稿管理系统:收到的投稿数量:86 - 送审稿件数量:74 - 接受的投稿数量:45 - 接受率 (接受的投稿数量 / 收到的投稿数量 × 100):52.3 - 每篇论文的平均评审次数:3 - 参与评审的总人数:1010 - 询问联系人:姓名:Xuexia Email: xx.ye@keoaeic.org Affiliation:AEIC 学术交流信息中心
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引用次数: 0
Deep Reinforcement Learning-based Collaborative Multi-UAV Coverage Path Planning 基于深度强化学习的协作式多无人机覆盖路径规划
Pub Date : 2024-08-01 DOI: 10.1088/1742-6596/2833/1/012017
Boquan Zhang, Tian Jing, Xiang Lin, Yanru Cui, Yifan Zhu, Zhi Zhu
The coverage path planning problem has gained significant attention in research due to its wide applicability and practical value in various fields such as logistics and distribution, smart homes, and unmanned vehicles. This paper focuses on studying the coverage path planning problem under multi-UAV collaboration to maximize the coverage of the mission area within a given time. To address this problem, we propose a multi-objective optimization model and reformulate it with the framework of Decentralized Partially Observable Markov Decision Process (Dec-POMDP). We then employ a multi-agent deep reinforcement learning (MADRL) method to solve the problem. Specifically, we introduce the ε—Multi-Agent Twin Delayed Deep Deterministic Policy Gradient (ε—MADT3), which incorporates an exploration coefficient based on MATD3. This coefficient gradually decays with the number of iterations, allowing for a balance between exploration and exploitation. Numerous simulation results demonstrate that ε—MADT3 outperforms the baseline algorithm in terms of coverage rate and number of collisions.
覆盖路径规划问题因其在物流配送、智能家居、无人车等多个领域的广泛适用性和实用价值而备受研究关注。本文重点研究多无人机协作下的覆盖路径规划问题,以在给定时间内最大化任务区域的覆盖范围。为了解决这个问题,我们提出了一个多目标优化模型,并用分散式部分可观测马尔可夫决策过程(Dec-POMDP)框架对其进行了重新表述。然后,我们采用多代理深度强化学习(MADRL)方法来解决这个问题。具体来说,我们引入了ε-多代理双延迟深度确定性策略梯度(ε-MADT3),其中包含一个基于 MATD3 的探索系数。该系数随着迭代次数的增加而逐渐减小,从而在探索和利用之间取得平衡。大量模拟结果表明,ε-MADT3 在覆盖率和碰撞次数方面都优于基准算法。
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引用次数: 0
期刊
Journal of Physics: Conference Series
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