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Radiance-to-irradiance conversion in the visible and near-infrared bands under clear-sky conditions 晴空条件下可见光和近红外波段的辐射-辐照度转换
IF 1.9 3区 物理与天体物理 Q2 OPTICS Pub Date : 2025-11-27 DOI: 10.1016/j.jqsrt.2025.109777
Xiang Zhong , Baike Xi , Xiquan Dong , Jordann Brendecke , Jake Gristey , Maria Hakuba , Bruce Kindel , Steven Massie , Daniel Feldman , Peter Pilewskie
Accurately partitioning shortwave (SW) radiation into its visible (VIS) and near-infrared (NIR) spectral components is essential for climate models and radiation budget studies, as it governs how the atmosphere absorbs, scatters, and reflects incoming solar energy. In support of NASA’s Libera mission, this study presents a novel method for deriving VIS and NIR irradiances from SW, VIS, and NIR satellite-based radiance measurements under clear-sky conditions by leveraging satellite-based radiance measurements across SW, VIS, and NIR bands. The method centers on a parameterization of the ratio of anisotropic factors, denoted as β (Eq. 3), which varies significantly with solar zenith angle (SZA), viewing zenith angle (VZA), relative azimuth angle (RAA), and aerosol optical depth (AOD). A polynomial regression model is developed to estimate β for different surface types. By combining the regressed β with the radiance ratio of VIS to NIR, which will be directly observed by Libera, the method partitions total SW irradiance into its VIS and NIR components. Validation against MODTRAN6.0 radiative transfer simulations over forest and desert surfaces demonstrates high fidelity, with discrepancies under 3 W m⁻². The approach performs best at backward scattering angles and exhibits more consistent results over vegetated surfaces than over bright, arid terrain. While initial testing is focused on two surface types, the demonstrated sensitivity of β to key atmospheric and geometric parameters indicates strong potential for extension to a wide range of land cover types and atmospheric conditions. Future work will focus on expanding the method to cloudy scenes, improving the regression model, and cross-validating results with alternative radiative transfer tools and in situ measurements.
准确地将短波(SW)辐射划分为可见光(VIS)和近红外(NIR)光谱成分对于气候模型和辐射预算研究至关重要,因为它决定了大气如何吸收、散射和反射入射的太阳能。为了支持NASA的Libera任务,本研究提出了一种新的方法,通过利用基于卫星的SW、VIS和NIR波段的亮度测量,在晴朗的天空条件下,从SW、VIS和NIR卫星的亮度测量中获得VIS和NIR辐照度。该方法的核心是各向异性因子的参数化比率,表示为β (Eq. 3),该系数随太阳天顶角(SZA)、观测天顶角(VZA)、相对方位角(RAA)和气溶胶光学深度(AOD)而显著变化。建立了一个多项式回归模型来估计不同表面类型的β。该方法通过将回归的β与Libera直接观测到的VIS / NIR辐射比相结合,将SW总辐照度划分为VIS和NIR分量。MODTRAN6.0对森林和沙漠表面辐射传输模拟的验证显示出高保真度,差异在3w m⁻²以下。该方法在反向散射角度下表现最好,并且在植被表面上比在明亮的干旱地形上显示出更一致的结果。虽然最初的测试主要集中在两种地表类型,但β对关键大气和几何参数的敏感性表明,它有很强的潜力扩展到广泛的土地覆盖类型和大气条件。未来的工作将侧重于将该方法扩展到多云场景,改进回归模型,并使用替代辐射传输工具和原位测量交叉验证结果。
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引用次数: 0
Polarized infrared radiative transfer in an optically anisotropic medium: A Markov chain solution for remote sensing of atmospheric suspended particles 基于蒙特卡罗的光伏太阳能农场辐射传输模拟:在天气和气候模式中实现快速和准确的参数化
IF 1.9 3区 物理与天体物理 Q2 OPTICS Pub Date : 2025-11-27 DOI: 10.1016/j.jqsrt.2025.109776
Feng Xu , Congcong Qiao , Braxton C. Gosvener , Benting Chen , Lan Gao , Jens Redemann , Anthony B. Davis , Olga V. Kalashnikova , W. Reed Espinosa , Jie Gong , Dong L. Wu , Zhao-Cheng Zeng , Oleg Dubovik
A Markov chain approach is developed to model polarized mid- to long-wave infrared radiative transfer in an optically anisotropic medium. Such a medium contains oriented non-spherical particles with azimuthal randomness. Our model considers variations of temperature, pressure, gas concentration, and particle size distribution in the vertical dimension of the medium and resolves the total and polarized radiation in two-dimensional angular space. It also accounts for emission, scattering, and absorption of the medium, as well as directional and polarized surface emission and reflection. Illustrative simulations are performed using MODIS infrared bands centered at 9.73, 11.03, and 12.02 μm and several standard model atmospheres containing oriented dust or ice spheroids. The results are compared to those obtained for spherical droplets. Our preliminary numerical results demonstrate that while infrared brightness temperature contains information about particle amount, size, and layer height, adding multi-angle and spectro-polarimetry provides further remote sensing sensitivity to type, orientation, and morphology of the non-spherical particles. When reliable a priori information on the atmospheric physical temperature and absorbing gas profiles is available, infrared multi-angle polarimetry is a promising tool to fill the gap of shortwave and microwave remote sensing by resolving micro-meter scale particle properties to which shortwave and microwave frequencies have less sensitivity. Our simulation also reveals that solar radiation exerts a pronounced influence on the top-of-atmosphere brightness temperature when the wavelength approaches the short-wavelength end of the mid-wave infrared (≈3–4 μm).
提出了一种马尔可夫链方法来模拟光学各向异性介质中偏振中长波红外辐射传输。这种介质包含有取向的非球形粒子,具有方位随机性。我们的模型考虑了温度、压力、气体浓度和粒径分布在介质垂直维度上的变化,并在二维角空间上解析了总辐射和极化辐射。它还考虑了介质的发射、散射和吸收,以及定向和极化表面发射和反射。利用以9.73、11.03和12.02 μm为中心的MODIS红外波段和几种含有定向尘埃或冰球的标准模式大气进行了说明性模拟。结果与球形液滴的结果进行了比较。我们的初步数值结果表明,虽然红外亮度温度包含了颗粒数量、大小和层高的信息,但添加多角度和光谱偏振法可以进一步提高对非球形颗粒类型、取向和形态的遥感灵敏度。当有可靠的大气物理温度和吸收气体分布的先验信息时,红外多角度偏振法可以解决微米尺度的粒子特性,填补短波和微波遥感的空白,这是一种很有前途的工具。模拟结果还表明,当太阳辐射波长接近中波红外短波长端(≈3-4 μm)时,对大气顶亮温有显著的影响。
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引用次数: 0
Inter-comparison of different order-scattering models for accurate sensing in dusty conditions 多尘条件下不同阶散射模型的相互比较
IF 1.9 3区 物理与天体物理 Q2 OPTICS Pub Date : 2025-11-21 DOI: 10.1016/j.jqsrt.2025.109760
Safae Nejjari , Amine Ben Daoued , Frédéric Bernardin , Christophe Debain , Philippe Samuel Heritier
One of the major challenges in smart farming is the dust suspension during operations. Optical sensors embedded in agricultural machines and robots become less effective under such conditions, which compromises the accuracy of measurements and consequently the decision-making process. This study represents a comparative analysis of light transmission models under different configurations, from the Beer–Lambert model to different order scattering models, to assess the effectiveness of each model in different scenarios. This comparison is based on the simulation of a transmissiometer system, operating in a homogeneous dusty medium, consisting of suspended mineral dust particles. The evaluation includes the quantification of relative errors between various models across different optical depth values, sensor fields of view, and source divergence angles. Single, Double, Triple, Quadruple, and Multiple Scattering models were also considered in the quantitative comparison, to identify the conditions under which each model provides sufficient accuracy. Additionally, the influence of different scattering phase functions was investigated. The results highlight that the choice of scattering phase function significantly affects the relative errors, especially at angles close to the main propagation axis. The goal of this classification is to determine scenarios where simplified models can be employed for real-time monitoring, as increasing the order of scattering significantly raises the computational cost, making them less suitable for such applications. This classification helps establish a trade-off between physical accuracy and computational efficiency.
智能农业面临的主要挑战之一是操作过程中的粉尘悬浮。在这种条件下,农业机械和机器人中嵌入的光学传感器变得不那么有效,这损害了测量的准确性,从而影响了决策过程。本研究对不同配置下的光传输模型进行了对比分析,从Beer-Lambert模型到不同阶散射模型,以评估每种模型在不同场景下的有效性。这种比较是基于在由悬浮矿物粉尘颗粒组成的均匀粉尘介质中运行的透射仪系统的模拟。评估包括量化不同模型在不同光学深度值、传感器视场和光源发散角之间的相对误差。定量比较中还考虑了单散射、双散射、三散射、四散射和多重散射模型,以确定每种模型提供足够精度的条件。此外,还研究了不同散射相函数的影响。结果表明,散射相函数的选择对相对误差有显著影响,特别是在接近主传播轴的角度。这种分类的目的是确定可以使用简化模型进行实时监测的场景,因为增加散射的顺序会显著提高计算成本,使其不太适合此类应用。这种分类有助于在物理精度和计算效率之间建立一种权衡。
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引用次数: 0
Study of linear depolarization ratios across a wide range of scattering angles for particles of diverse sizes, shapes, and complex refractive indices 不同尺寸、形状和复折射率粒子在大散射角范围内的线性退极化比研究
IF 1.9 3区 物理与天体物理 Q2 OPTICS Pub Date : 2025-11-21 DOI: 10.1016/j.jqsrt.2025.109761
Prakash Gautam , Justin B. Maughan , Hans Moosmüller , Kurt Ehlers , Christopher M. Sorensen
Polarimetry is a valuable technique for remote sensing of atmospheric aerosol particles, with the linear depolarization ratio (LDR) being a key parameter used to characterize particle properties. This study investigates the LDRs of various aerosol particles, including nearly spherical and irregular aluminum oxide (Al2O3), Arizona Road Dust (AZRD), and molybdenum disulfide (MoS2) particles, using both laboratory measurements conducted at a wavelength of 532 nm over a scattering angle range from 0.32° to 177.6° and theoretical model computations for spheroids and Gaussian random spheres. The results demonstrate that the LDR is strongly influenced by particle size, shape, and refractive index, with significant variations across different scattering angles. In the forward-scattering regime, LDR values are small due to scattering being dominated by diffraction, while in the side-scattering regime, LDR increases, peaking around 140° to 160°, before decreasing in the back-scattering regime. This study further explores the relationship between LDR and particle morphology, as well as the impact of the imaginary part of the complex refractive index on LDR, with results showing that higher absorption leads to lower LDRs. Overall, this study contributes to a better understanding of how LDR behaves for different particle types and scattering angles, enhancing our understanding of the optical properties of aerosol particles towards improved polarimetric remote sensing retrievals.
偏振法是遥感大气气溶胶粒子的一项有价值的技术,线性去极化比(LDR)是表征气溶胶粒子特性的关键参数。本文研究了各种气溶胶颗粒的LDRs,包括近球形和不规则的氧化铝(Al2O3),亚利桑那道路粉尘(AZRD)和二硫化钼(MoS2)颗粒,使用波长为532 nm,散射角范围为0.32°至177.6°的实验室测量和球形和高斯随机球体的理论模型计算。结果表明,LDR受颗粒大小、形状和折射率的影响较大,且在不同散射角度下变化显著。在前向散射区,由于散射以衍射为主,LDR值很小,而在侧向散射区,LDR值增加,在140°~ 160°左右达到峰值,后向散射区LDR值下降。本研究进一步探讨了LDR与粒子形态的关系,以及复折射率虚部对LDR的影响,结果表明吸收越高,LDR越低。总的来说,本研究有助于更好地理解LDR在不同颗粒类型和散射角度下的行为,增强我们对气溶胶颗粒光学特性的理解,从而改进偏振遥感检索。
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引用次数: 0
The dynamic characteristics of non-diffracting skyrmionic beams under tight focusing configurations 紧密聚焦条件下非绕射天电子束的动态特性
IF 1.9 3区 物理与天体物理 Q2 OPTICS Pub Date : 2025-11-20 DOI: 10.1016/j.jqsrt.2025.109756
Guoxia Han, Yihan Tian, Ke Hu, Feiyang Zhang, Maoda Jing, Guangyi Wang, Qihui Zhao, Li Zhao
Optical skyrmions stand out by virtue of their non-trivial topological structures and have attracted considerable interest of many researchers in recent years. However, the significant potential of non-diffracting skyrmionic beams for optical trapping and manipulation remains largely overlooked. In this work, the tight focusing properties of non-diffracting skyrmionic beams are investigated and the dynamic characteristics of the topological fields under tight focusing conditions are first explored. The topological properties of skyrmionic beams in Bessel modes under tight focusing conditions are studied systematically based on the Richards -Wolf vector diffraction theory. We theoretically demonstrate that a transformation of the phase difference is exhibited for skyrmionic beams through tight focusing process, while the skyrmion number remains unchanged in the central region. Furthermore, a comprehensive numerical analysis of the force and torque on Rayleigh particles exerted by the tightly focused skyrmionic beams is performed and the influence of skyrmion numbers and transverse components of the wave-vector on the trapping behaviors is conducted. The multi-particles can be captured in the tightly focused skyrmionic beams by adjusting these parameters. Our findings in this work allow a deeper exploration of skyrmions in applications, and provide essential theoretical support for its utilization in particle manipulation and sorting.
光学天幕以其非平凡的拓扑结构而引人注目,近年来引起了许多研究者的极大兴趣。然而,非衍射天空电子束在光学捕获和操纵方面的巨大潜力在很大程度上被忽视了。本文研究了非绕射天电子束的紧聚焦特性,并首次探讨了紧聚焦条件下拓扑场的动态特性。基于Richards -Wolf矢量衍射理论,系统地研究了紧密聚焦条件下贝塞尔模式下天空粒子束的拓扑特性。我们从理论上证明了在紧密聚焦过程中,天子光束的相位差发生了变化,而中心区域的天子数保持不变。在此基础上,对紧密聚焦的skyronic光束对Rayleigh粒子施加的力和扭矩进行了全面的数值分析,并对skyronic数和波矢量的横向分量对捕获行为的影响进行了研究。通过调整这些参数,可以在紧密聚焦的天粒子束中捕获多粒子。我们的研究结果允许对skyrmions在应用中的更深入探索,并为其在粒子操纵和分选中的应用提供重要的理论支持。
{"title":"The dynamic characteristics of non-diffracting skyrmionic beams under tight focusing configurations","authors":"Guoxia Han,&nbsp;Yihan Tian,&nbsp;Ke Hu,&nbsp;Feiyang Zhang,&nbsp;Maoda Jing,&nbsp;Guangyi Wang,&nbsp;Qihui Zhao,&nbsp;Li Zhao","doi":"10.1016/j.jqsrt.2025.109756","DOIUrl":"10.1016/j.jqsrt.2025.109756","url":null,"abstract":"<div><div>Optical skyrmions stand out by virtue of their non-trivial topological structures and have attracted considerable interest of many researchers in recent years. However, the significant potential of non-diffracting skyrmionic beams for optical trapping and manipulation remains largely overlooked. In this work, the tight focusing properties of non-diffracting skyrmionic beams are investigated and the dynamic characteristics of the topological fields under tight focusing conditions are first explored. The topological properties of skyrmionic beams in Bessel modes under tight focusing conditions are studied systematically based on the Richards -Wolf vector diffraction theory. We theoretically demonstrate that a transformation of the phase difference is exhibited for skyrmionic beams through tight focusing process, while the skyrmion number remains unchanged in the central region. Furthermore, a comprehensive numerical analysis of the force and torque on Rayleigh particles exerted by the tightly focused skyrmionic beams is performed and the influence of skyrmion numbers and transverse components of the wave-vector on the trapping behaviors is conducted. The multi-particles can be captured in the tightly focused skyrmionic beams by adjusting these parameters. Our findings in this work allow a deeper exploration of skyrmions in applications, and provide essential theoretical support for its utilization in particle manipulation and sorting.</div></div>","PeriodicalId":16935,"journal":{"name":"Journal of Quantitative Spectroscopy & Radiative Transfer","volume":"350 ","pages":"Article 109756"},"PeriodicalIF":1.9,"publicationDate":"2025-11-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145559877","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
N2-broadening coefficients and their temperature exponents for ethylene lines: A semi-empirical approach for (exo)planetary studies 乙烯谱线的n2 -展宽系数及其温度指数:外行星研究的半经验方法
IF 1.9 3区 物理与天体物理 Q2 OPTICS Pub Date : 2025-11-19 DOI: 10.1016/j.jqsrt.2025.109758
Sarah Clavier , Michael Rey , Jeanna Buldyreva
Nitrogen-broadening coefficients for ethylene absorption lines in the ν7 band are computed theoretically to fill in the enormous gaps existing in available experimental data. A semi-empirical method relying on the Anderson theory is employed for this purpose, with the model parameters adjusted on some rare room-temperature measurements and used further for calculations in extended temperature ranges. The spectroscopically active molecule C2H4 is rigorously treated as an asymmetric top, and its energy levels and wavefunctions are accurately computed by a quantum-chemistry methodology based on ab initio potential energy surfaces. Theoretical broadening values are obtained for the temperature range 100–1000 K relevant to studies of planetary and exoplanetary atmospheres. These values are further analyzed by the traditional power law to get the associated temperature-dependence exponents. Comparisons of the computed theoretical results with previous measurements and calculations are provided at a low temperature of 173 K to validate the theoretical method chosen. Since the power law describes perfectly the considered temperature range, the sets of reference-temperature broadening coefficients and their temperature exponents can be safely used for higher temperatures where semi-classical approaches applicability only grows. These data are provided for the quantum numbers 0J47, K26 and the three P-, Q-, R-branches of the ν7 band, i.e. represent the most comprehensive up-to-date description of N2-broadened ethylene linewidths suitable for integration into spectroscopic databases and high-temperature simulations of (exo)planetary atmospheres.
从理论上计算了ν7波段乙烯吸收谱线的氮展宽系数,以填补现有实验数据中存在的巨大空白。为此,采用了一种基于安德森理论的半经验方法,在一些罕见的室温测量上调整模型参数,并进一步用于扩大温度范围的计算。对具有光谱活性的分子C2H4进行了严格的非对称顶处理,并采用基于从头算势能面的量子化学方法精确计算了其能级和波函数。得到了与行星和系外行星大气研究有关的100 - 1000k温度范围的理论展宽值。利用传统幂律法对这些值进行进一步分析,得到相应的温度依赖指数。在173 K的低温条件下,将计算的理论结果与以往的测量和计算结果进行了比较,以验证所选择的理论方法。由于幂律完美地描述了所考虑的温度范围,参考温度展宽系数集合及其温度指数可以安全地用于更高的温度,而半经典方法的适用性只会增加。这些数据是为量子数0≤J≤47,K≤26和ν7波段的三个P-, Q-, r -分支提供的,即代表了最新最全面的n2加宽乙烯线宽描述,适合集成到光谱数据库和(外)行星大气的高温模拟中。
{"title":"N2-broadening coefficients and their temperature exponents for ethylene lines: A semi-empirical approach for (exo)planetary studies","authors":"Sarah Clavier ,&nbsp;Michael Rey ,&nbsp;Jeanna Buldyreva","doi":"10.1016/j.jqsrt.2025.109758","DOIUrl":"10.1016/j.jqsrt.2025.109758","url":null,"abstract":"<div><div>Nitrogen-broadening coefficients for ethylene absorption lines in the <span><math><msub><mrow><mi>ν</mi></mrow><mrow><mn>7</mn></mrow></msub></math></span> band are computed theoretically to fill in the enormous gaps existing in available experimental data. A semi-empirical method relying on the Anderson theory is employed for this purpose, with the model parameters adjusted on some rare room-temperature measurements and used further for calculations in extended temperature ranges. The spectroscopically active molecule C<span><math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math></span>H<span><math><msub><mrow></mrow><mrow><mn>4</mn></mrow></msub></math></span> is rigorously treated as an asymmetric top, and its energy levels and wavefunctions are accurately computed by a quantum-chemistry methodology based on <em>ab initio</em> potential energy surfaces. Theoretical broadening values are obtained for the temperature range 100–1000 K relevant to studies of planetary and exoplanetary atmospheres. These values are further analyzed by the traditional power law to get the associated temperature-dependence exponents. Comparisons of the computed theoretical results with previous measurements and calculations are provided at a low temperature of 173 K to validate the theoretical method chosen. Since the power law describes perfectly the considered temperature range, the sets of reference-temperature broadening coefficients and their temperature exponents can be safely used for higher temperatures where semi-classical approaches applicability only grows. These data are provided for the quantum numbers <span><math><mrow><mn>0</mn><mo>≤</mo><mi>J</mi><mo>≤</mo><mn>47</mn></mrow></math></span>, <span><math><mrow><mi>K</mi><mo>≤</mo><mn>26</mn></mrow></math></span> and the three <span><math><mi>P</mi></math></span>-, <span><math><mi>Q</mi></math></span>-, <span><math><mi>R</mi></math></span>-branches of the <span><math><msub><mrow><mi>ν</mi></mrow><mrow><mn>7</mn></mrow></msub></math></span> band, i.e. represent the most comprehensive up-to-date description of N<span><math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math></span>-broadened ethylene linewidths suitable for integration into spectroscopic databases and high-temperature simulations of (exo)planetary atmospheres.</div></div>","PeriodicalId":16935,"journal":{"name":"Journal of Quantitative Spectroscopy & Radiative Transfer","volume":"350 ","pages":"Article 109758"},"PeriodicalIF":1.9,"publicationDate":"2025-11-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145559886","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The predictive power of the calculated line lists of carbon monoxide 计算出的一氧化碳线表的预测能力
IF 1.9 3区 物理与天体物理 Q2 OPTICS Pub Date : 2025-11-19 DOI: 10.1016/j.jqsrt.2025.109759
E.S. Medvedev, V.G. Ushakov
The ability of our semi-empirical irregular dipole-moment functions (2022) and (2025) to predict the intensities of the yet unobserved lines, as well as to describe the observed ones not used in the fitting, is demonstrated by comparison with recent measurements in the 0-0, 1-0, 3-0, and 7-0 bands.
我们的半经验不规则偶极矩函数(2022)和(2025)预测尚未观测到的谱线强度的能力,以及描述未用于拟合的观测谱线的能力,通过与最近在0-0、1-0、3-0和7-0波段的测量结果进行比较来证明。
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引用次数: 0
Modeling and analysis of high-resolution H212CO spectra in the range 4450-5000 cm-1 4450-5000 cm-1高分辨率H212CO光谱建模与分析
IF 1.9 3区 物理与天体物理 Q2 OPTICS Pub Date : 2025-11-19 DOI: 10.1016/j.jqsrt.2025.109757
A.A. Rodina , A.V. Nikitin , A.E. Protasevich , L. Manceron , M. Rey , Vl.G. Tyuterev
This study presents modeling and analysis of the line positions and intensities of H₂CO in the 4450–5000 cm⁻¹ spectral region, recorded at a low temperature (160–166 K) at various pressures using a high-resolution Fourier transform spectrometer. The calculations are based on a series of numerical block-diagonalization procedures applied to the nuclear-motion Hamiltonian, which was constructed from our ab initio potential energy and dipole moment surfaces, resulting in a new effective model for successive rovibrational polyads. Over 4600 assigned transitions were included in the empirical optimization of the model parameters using observed line positions. The fitting process for line intensities involved about 3300 transitions. The root-mean-square (RMS) deviation for line positions in the studied range is 0.00094 cm-1, while the RMS deviation for the line intensities is 10.18 %. New theoretical predictions for the isotopic species H213C16O, H212C18O, for the band origins are reported. The improved line list contains 25,725 transitions, including both experimentally measured and calculated lines. Validations of the new list are discussed, using comparisons of the transmittance simulation versus our high-resolution experimental spectra at T = 160–166 K and of cross-section simulations at T = 296 K versus medium-resolution PNNL observations.
本研究采用高分辨率傅立叶变换光谱仪,对4450-5000 cm⁻¹光谱区(在低温(160-166 K)下不同压力下记录的H₂CO的谱线位置和强度进行建模和分析。计算是基于一系列数值块对角化程序,应用于核运动哈密顿量,它是由我们从头开始的势能和偶极矩曲面构建的,从而得到一个新的连续旋转振动多边形的有效模型。超过4600个指定的过渡被包括在使用观测线位置的模型参数的经验优化中。线强度的拟合过程涉及约3300次转换。研究范围内线位置的均方根偏差为0.00094 cm-1,线强度的均方根偏差为10.18%。报道了新理论预测的H213C16O、H212C18O同位素对带起源的影响。改进的线表包含25,725个跃迁,包括实验测量和计算的线。通过比较透射率模拟与160-166 K时的高分辨率实验光谱,以及296 K时的截面模拟与中分辨率PNNL观测结果,讨论了新列表的有效性。
{"title":"Modeling and analysis of high-resolution H212CO spectra in the range 4450-5000 cm-1","authors":"A.A. Rodina ,&nbsp;A.V. Nikitin ,&nbsp;A.E. Protasevich ,&nbsp;L. Manceron ,&nbsp;M. Rey ,&nbsp;Vl.G. Tyuterev","doi":"10.1016/j.jqsrt.2025.109757","DOIUrl":"10.1016/j.jqsrt.2025.109757","url":null,"abstract":"<div><div>This study presents modeling and analysis of the line positions and intensities of H₂CO in the 4450–5000 cm⁻¹ spectral region, recorded at a low temperature (160–166 K) at various pressures using a high-resolution Fourier transform spectrometer. The calculations are based on a series of numerical block-diagonalization procedures applied to the nuclear-motion Hamiltonian, which was constructed from our <em>ab initio</em> potential energy and dipole moment surfaces, resulting in a new effective model for successive rovibrational polyads. Over 4600 assigned transitions were included in the empirical optimization of the model parameters using observed line positions. The fitting process for line intensities involved about 3300 transitions. The root-mean-square (RMS) deviation for line positions in the studied range is 0.00094 cm<sup>-1</sup>, while the RMS deviation for the line intensities is 10.18 %. New theoretical predictions for the isotopic species H<sub>2</sub><sup>13</sup>C<sup>16</sup>O, H<sub>2</sub><sup>12</sup>C<sup>18</sup>O, for the band origins are reported. The improved line list contains 25,725 transitions, including both experimentally measured and calculated lines. Validations of the new list are discussed, using comparisons of the transmittance simulation versus our high-resolution experimental spectra at <em>T</em> = 160–166 K and of cross-section simulations at <em>T</em> = 296 K versus medium-resolution PNNL observations.</div></div>","PeriodicalId":16935,"journal":{"name":"Journal of Quantitative Spectroscopy & Radiative Transfer","volume":"350 ","pages":"Article 109757"},"PeriodicalIF":1.9,"publicationDate":"2025-11-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145559884","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Experimental and semi-empirical studies of the fine and the hyperfine structure of even-parity configuration system of atomic lutetium 镥原子偶宇称组态系统精细与超精细结构的实验与半经验研究
IF 1.9 3区 物理与天体物理 Q2 OPTICS Pub Date : 2025-11-18 DOI: 10.1016/j.jqsrt.2025.109755
M. Klempka , M. Elantkowska , B. Furmann , J. Ruczkowski , P. Głowacki , S. Mieloch , D. Stefańska
The paper presents the results of the fine structure (fs) and the hyperfine structure (hfs) analysis of even-parity configuration levels of neutral lutetium (Lu I). The experimental results, obtained within this study using laser-induced fluorescence (LIF) spectroscopy or Fourier transform spectra, led to determination of the hfs constants for 17 levels, 5 of them evaluated for the first time. Using these new values, along with all the data available in the literature, we performed a semi-empirical parametric study of the fs and the hfs for the system of 147 even-parity configurations. A mean error of ΔE=5.7 cm−1 for 174 energy levels was obtained. A very good consistency between the calculated and measured values was achieved for magnetic dipole constants (A); for electric quadrupole constants (B) the respective agreement was only slightly worse. For unknown electronic levels, predicted values of the level energies, Landé gJ factors and the hfs constants are presented.
本文介绍了中性镥偶宇称组态能级的精细结构(fs)和超精细结构(hfs)分析结果。本研究利用激光诱导荧光(LIF)光谱或傅立叶变换光谱获得的实验结果,确定了17个能级的hfs常数,其中5个是首次评估。使用这些新值,以及文献中所有可用的数据,我们对147个偶宇称配置的系统的fs和hfs进行了半经验参数研究。174个能级的平均误差为ΔE=5.7 cm−1。磁偶极常数(A)的计算值与实测值具有很好的一致性;对于电四极常数(B),各自的一致性略差。对于未知能级,给出了能级能、land gJ因子和hfs常数的预测值。
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引用次数: 0
Graph-enhanced residual attention networks for high-resolution reconstruction in VSHDOM 面向VSHDOM高分辨率重建的图增强剩余注意网络
IF 1.9 3区 物理与天体物理 Q2 OPTICS Pub Date : 2025-11-14 DOI: 10.1016/j.jqsrt.2025.109754
Qianwen Wang, Sixu Pu, Ruoxi Peng, Biao Zhang, Jian Li, Chuanlong Xu
The Vector Spherical Harmonics Discrete Ordinate Method (VSHDOM) is an efficient deterministic solver for three-dimensional atmospheric radiative transfer. However, it still suffers from significant computational time and memory demands when applied to high spatial resolution cloud fields. Hence, this study proposes a super-resolution reconstruction approach based on a Graph-Enhanced Residual Attention Network (GRAN). The key innovation of this method lies in its ability to directly reconstruct high-resolution outputs from the low-resolution results produced by VSHDOM, thereby generating images that are comparable to high-resolution reference solutions while avoiding the heavy computational cost associated with explicitly solving the radiative transfer equation (RTE) at high resolutions. Results show that a 3D flux field with a resolution of 37 × 37 × 26 can be super-resolved to 370 × 370 × 26 in only 0.39 s, with a reconstruction error of <3.7 %. In contrast, a single VSHDOM iteration under the same computational setup takes approximately 12 min. Beyond RTE flux reconstruction, GRAN is also capable of performing super-resolution reconstruction for synthesized Stokes images, achieving a maximum absolute error of <0.01 compared to the benchmark.
矢量球谐离散纵坐标法(VSHDOM)是三维大气辐射传输的一种有效的确定性求解方法。然而,当应用于高空间分辨率云场时,它仍然存在显著的计算时间和内存需求。因此,本研究提出了一种基于图增强剩余注意网络(GRAN)的超分辨率重建方法。该方法的关键创新之处在于,它能够直接从VSHDOM产生的低分辨率结果中重建高分辨率输出,从而生成与高分辨率参考解决方案相当的图像,同时避免了在高分辨率下显式求解辐射传递方程(RTE)所带来的沉重计算成本。结果表明,分辨率为37 × 37 × 26的三维通量场在0.39 s内可超分辨到370 × 370 × 26,重建误差为3.7%。相比之下,在相同的计算设置下,单个VSHDOM迭代大约需要12分钟。除了RTE通量重建之外,GRAN还能够对合成Stokes图像进行超分辨率重建,与基准相比,最大绝对误差为<;0.01。
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引用次数: 0
期刊
Journal of Quantitative Spectroscopy & Radiative Transfer
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