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Absorption spectroscopy of AlO including photodissociation 含光解作用的AlO吸收光谱
IF 2.3 3区 物理与天体物理 Q2 OPTICS Pub Date : 2024-12-25 DOI: 10.1016/j.jqsrt.2024.109335
Tianrui Bai, Lynette Edline Momo Jeulefack, Songfeng Li, Jie Cheng, Shuidong Dai, Linhua Liu, Fei Li
Photodissociation of AlO may be important for the aluminium chemistry in various astrophysical regions. The photodissociation cross sections and rates of AlO were investigated over the temperature range from 0 to 15000 K in this work. Firstly, the state-resolved cross sections at the wavelength of 50 − 5000 nm for transitions from the ground and first excited states were calculated using ab initio potential energy curves and transition dipole moments. The temperature-dependent cross sections were then obtained by assuming a Boltzmann distribution to describe the population of the initial state. Several common radiation fields (interstellar, solar and blackbody radiation field) were selected as the radiation fields, and then the photodissociation rates in different radiation fields were obtained. The photodissociation rates in all studied radiation fields exhibit a positive correlation with increasing temperature. This finding indicates that the total photodissociation rates are sensitive to the temperature. In addition, the photodissociation rates in the solar radiation field are higher than those in the interstellar radiation fields, indicating that photodissociation rate is associated with the type of radiation field in which the molecule is exposed. The calculated photodissociation cross sections and rates of AlO are useful to investigate the chemical evolution of the aluminum element in the interstellar environment.
光解作用对不同天体物理区域的铝化学可能具有重要意义。在0 ~ 15000 K的温度范围内,研究了AlO的光解截面和速率。首先,利用从头算势能曲线和跃迁偶极矩计算了从基态和第一激发态跃迁的50 ~ 5000 nm波长处的态分辨截面。然后,通过假设玻尔兹曼分布来描述初始状态的总体,获得了与温度相关的截面。选取几种常见的辐射场(星际辐射场、太阳辐射场和黑体辐射场)作为辐射场,得到不同辐射场下的光解速率。在所研究的所有辐射场中,光解速率均与温度的升高呈正相关。这一发现表明总光解速率对温度敏感。此外,在太阳辐射场中的光解速率高于星际辐射场中的光解速率,说明光解速率与分子所暴露的辐射场类型有关。计算得到的光解截面和光解速率对研究铝元素在星际环境中的化学演化具有重要意义。
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引用次数: 0
Deep sub-wavelength scale focusing of heat flux radiated by magneto-optical nanoemitters in the presence of an external magnetic-field 外磁场存在下磁光纳米发射器辐射热流的深亚波长尺度聚焦
IF 2.3 3区 物理与天体物理 Q2 OPTICS Pub Date : 2024-12-24 DOI: 10.1016/j.jqsrt.2024.109322
Louis Rihouey, Philippe Ben-Abdallah, Riccardo Messina
We introduce a theoretical framework to describe the heat flux radiated in the near-field regime by a set of magneto-optical thermal nanoemitters close to a substrate in the presence of an external magnetic field. Then, we investigate the particular case of a single emitter and we demonstrate that the external field can induce both an amplification of the heat exchanged between emittter and substrate and a focusing of the Poynting field at the substrate interface at deep sub-wavelength scale. These effects open up promising perspectives for the development of heat-assisted magnetic-recording technology.
我们引入了一个理论框架来描述在存在外部磁场的情况下,一组靠近衬底的磁光热纳米发射器在近场状态下辐射的热流。然后,我们研究了单发射器的特殊情况,我们证明了外场可以诱导发射器和衬底之间的热交换放大和衬底界面在深亚波长尺度上的坡印亭场聚焦。这些效应为热辅助磁记录技术的发展开辟了广阔的前景。
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引用次数: 0
Updating the carbon dioxide line list in HITEMP 更新HITEMP中的二氧化碳行列表
IF 2.3 3区 物理与天体物理 Q2 OPTICS Pub Date : 2024-12-24 DOI: 10.1016/j.jqsrt.2024.109324
Robert J. Hargreaves, Iouli E. Gordon, Xinchuan Huang, Geoffrey C. Toon, Laurence S. Rothman
An updated carbon dioxide line list for the HITEMP spectroscopic database is presented. This line list covers the 0–17697 cm−1 (>565 nm) spectral range and is built upon the AI-3000K semi-empirical line list for 12C16O2, 13C16O2, 16O12C18O, and 16O12C17O (Huang et al., 2023), combined with HITRAN2020 data, additional isotopologues, and further improvements described in this work. In order to make the line list practical for applications, over 36 billion individual transitions of the original AI-3000K line list have been separated into “strong” and “weak”. “Strong” transitions were adapted directly, while the weak transitions were then combined into so-called “effective” lines. The latter can accurately account for the intensity contribution of underlying weak AI-3000K transitions while reducing the database by over two orders of magnitude (to 326 million). In addition, pressure broadening parameters have been revised for this work to improve applicability at high temperatures. The line list has been added to HITEMP and is suitable for modeling the spectrum of carbon dioxide at temperatures up to 3000 K.
提出了HITEMP光谱数据库中最新的二氧化碳谱线表。该谱线列表涵盖0-17697 cm−1 (>565 nm)光谱范围,基于AI-3000K 12C16O2、13C16O2、16O12C18O和16O12C17O的半经验谱线列表(Huang et al., 2023),结合HITRAN2020数据、额外的同位素以及本工作中描述的进一步改进。为了使线路列表在实际应用中更加实用,原始AI-3000K线路列表中超过360亿个单独的过渡被分为“强”和“弱”。“强”的过渡被直接改编,而弱的过渡则被组合成所谓的“有效”的线条。后者可以准确地解释潜在的弱AI-3000K转换的强度贡献,同时将数据库减少两个数量级以上(至~ 3.26亿)。此外,还对压力展宽参数进行了修订,以提高在高温下的适用性。该线列表已添加到HITEMP,适用于模拟温度高达3000k的二氧化碳光谱。
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引用次数: 0
Statistical simulation of the angular distribution of reflected solar radiation in optically anisotropic ice-crystal clouds: Horizontally oriented particles 光学各向异性冰晶云中反射太阳辐射角分布的统计模拟:水平取向粒子
IF 2.3 3区 物理与天体物理 Q2 OPTICS Pub Date : 2024-12-22 DOI: 10.1016/j.jqsrt.2024.109327
Tatiana Zhuravleva
The results of statistical modeling of the angular characteristics of reflected solar radiation in the atmosphere containing a layer of ice crystal clouds with anisotropy caused by the orientation of particles in space are presented. Numerical experiments are carried out using (1) original algorithm of the Monte Carlo method for calculating characteristics of unpolarized solar radiation taking into account the multiple scattering, reflection from the underlying surface, and attenuation by aerosol particles and due to molecular scattering and (2) optical model of anisotropic medium, composed of horizontally oriented hexagonal plates or Parry columns (visible range), developed previously in Institute of Atmospheric Optics, Siberian Branch, Russian Academy of Sciences, Tomsk, Russia. We discuss the patterns of formation of reflected solar radiation without taking into account the aerosol-molecular component of the atmosphere and surface reflection; these simulation results make it possible to identify the specific features of radiative transfer, caused exclusively by the effects of anisotropy of ice-crystal clouds. The factors that determine the influence of the surface reflection and aerosol attenuation on halo phenomena are described. It is shown that, as the surface albedo increases, the near-isotropic radiation field is formed outside the main halo lines and the intensity of different halo lines decreases down to the level when these lines or their components become almost invisible against the background of the contribution formed by surface-reflected radiation. Our radiation code is to be used for a research into the optical phenomena, observed from the Earth's surface and space, and, in particular, for an additional study of scattering by oriented ice crystals near the specular reflection direction (solar glint).
本文给出了在含有冰晶云层的大气中反射太阳辐射的角特性的统计模拟结果,这些冰晶云层是由粒子在空间中的取向引起的。数值实验采用(1)考虑多重散射、下垫面反射、气溶胶粒子衰减和分子散射等因素的原始蒙特卡罗方法计算非偏振太阳辐射特性;(2)大气光学研究所开发的由水平取向六角形板或Parry柱(可见范围)组成的各向异性介质光学模型。俄罗斯科学院西伯利亚分院,托木斯克,俄罗斯。我们讨论了反射太阳辐射的形成模式,而不考虑大气的气溶胶分子成分和表面反射;这些模拟结果使我们能够确定完全由冰晶云的各向异性影响引起的辐射传输的具体特征。描述了决定表面反射和气溶胶衰减对光晕现象影响的因素。结果表明,随着地表反照率的增加,在主光晕线外形成近各向同性辐射场,不同光晕线的强度降低到在地表反射辐射贡献背景下这些光晕线或其组成部分几乎不可见的水平。我们的辐射代码将用于研究从地球表面和空间观测到的光学现象,特别是用于在镜面反射方向(太阳闪烁)附近定向冰晶散射的额外研究。
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引用次数: 0
Using convolutional neural networks to predict the optical properties of coated black carbon 利用卷积神经网络预测涂覆黑碳的光学性质
IF 2.3 3区 物理与天体物理 Q2 OPTICS Pub Date : 2024-12-22 DOI: 10.1016/j.jqsrt.2024.109326
Zhenhai Qin, Jinhong Wu, Haihui Wang, Yongming Zhang, Qixing Zhang
Black carbon (BC) is a type of light absorbing substances in atmosphere, which has a significant impact on regional and global radiation balance. When evaluating the climatic effects of BC, the complex morphology of BC poses a challenge for large-scale climate models to proceed with the calculations. In this study, we developed a deep convolutional neural network (CNN) that combines residual links with one-dimensional multi-scale dilated convolutions. Using the multiple sphere T-matrix (MSTM), the extinction efficiency (Qext), absorption efficiency (Qabs), scattering efficiency (Qsca), and asymmetry factor (g) for coated BC were evaluated under different fractal dimensions, monomer radii, refractive indices, and incident wavelengths, by considering the volume fraction of thinly coated BC and thickly coated BC in the range from 20 % to 60 % and 2 % to 10 %, respectively. The optical properties of small particles were then treated as the training set to train the CNN, and the trained CNN was used to output the optical properties of large particles. By comparing the Qext, Qabs, Qsca, and g predicted by the CNN with those obtained from the MSTM, we found that the CNN has superior predictive capabilities for the optical properties of coated BC, and the newly established CNN exhibited broad applicability in predicting the optical properties of coated BC. Although relative deviations are observed in predicting the optical properties of small particles using the CNN, the errors for large particle predictions are essentially <1 %, with the mean absolute errors and root mean square errors being lower than 0.029 and 0.043, respectively. This study demonstrates that the CNN has great potential for further development. Future research should focus on how to use less data to predict more accurate results for the range of computational parameters for BC.
黑碳是大气中的一种吸光物质,对区域和全球的辐射平衡有着重要的影响。在评估BC的气候效应时,BC复杂的形态给大尺度气候模式的计算带来了挑战。在这项研究中,我们开发了一种将残差链接与一维多尺度扩张卷积相结合的深度卷积神经网络(CNN)。利用多球t矩阵(MSTM),考虑薄层和厚层BC的体积分数分别在20% ~ 60%和2% ~ 10%范围内,在不同分形维数、单体半径、折射率和入射波长条件下,对涂层BC的消光效率(Qext)、吸收效率(Qabs)、散射效率(Qsca)和不对称系数(g)进行了评价。然后将小颗粒的光学性质作为训练集来训练CNN,用训练好的CNN输出大颗粒的光学性质。通过将CNN预测的Qext、Qabs、Qsca和g与MSTM的预测结果进行比较,我们发现CNN对涂层BC的光学性质具有更好的预测能力,并且新建立的CNN在预测涂层BC的光学性质方面具有广泛的适用性。虽然使用CNN预测小粒子的光学性质存在相对偏差,但对大粒子的预测误差基本为1%,平均绝对误差和均方根误差分别小于0.029和0.043。本研究表明,CNN具有很大的发展潜力。未来的研究应侧重于如何使用更少的数据来预测更准确的BC计算参数范围的结果。
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引用次数: 0
An effective computational method and analysis of scattering characteristics for sea surface foam layer 海面泡沫层散射特性的有效计算方法及分析
IF 2.3 3区 物理与天体物理 Q2 OPTICS Pub Date : 2024-12-21 DOI: 10.1016/j.jqsrt.2024.109332
Yue Zhang, Xiaoxiao Yu, Peng Gao, Chunlin Huang, Qixiang Chen, Yuan Yuan, Shikui Dong, Kaifeng Lin
The optical properties of oceanic foam are crucial for satellite remote sensing inversion and target identification, with the volume scattering properties of foam layers significantly influencing the directionality of light scattering, making them a focal point in sea surface scattering research. To achieve efficient computation and analysis of the volume scattering properties of foam layers, this paper establishes a large-scale foam aggregate light scattering model based on geometric optics theory. An efficient algorithm for the foam volume scattering phase function was developed using GPU acceleration, and its convergence and acceleration performance were analyzed and evaluated. Furthermore, the influences of various factors, including different fractal models, particle numbers, random orientations of fractal structures, and asymmetric geometries, on the average volume scattering properties of the foam multi-spherical aggregates were analyzed. The results indicate that the influences of the fractal structures, particle numbers, and orientations of fractal structures on the average scattering properties is minimal, with correlation coefficients exceeding 0.99. This study provides an efficient algorithm for obtaining the average volume scattering phase function of foam, offering strong support for further research on sea surface scattering characteristics involving foam layers.
海洋泡沫的光学特性对卫星遥感反演和目标识别至关重要,泡沫层的体积散射特性对光散射的方向性有重要影响,是海洋表面散射研究的重点。为了实现对泡沫层体积散射特性的高效计算和分析,本文基于几何光学理论建立了大尺度泡沫聚集体光散射模型。提出了一种基于GPU加速的泡沫体积散射相函数的高效算法,并对其收敛性和加速性能进行了分析和评价。分析了不同分形模型、颗粒数、分形结构随机取向、几何形状不对称等因素对泡沫多球形聚集体平均体积散射性能的影响。结果表明:分形结构、颗粒数和分形结构取向对平均散射特性的影响最小,相关系数均大于0.99;本研究提供了一种获取泡沫平均体积散射相函数的有效算法,为进一步研究涉及泡沫层的海面散射特性提供了有力支持。
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引用次数: 0
Near field radiative heat transfer in twisted bilayer graphene grating structures based on magnetic modulation 基于磁调制的扭曲双层石墨烯光栅结构的近场辐射传热
IF 2.3 3区 物理与天体物理 Q2 OPTICS Pub Date : 2024-12-21 DOI: 10.1016/j.jqsrt.2024.109328
J.X. Wang, Z.G. Xu, F.Q. Zhang
Graphene grating structures have potential in enhancing near-field radiative heat transfer because of their anisotropic properties and single-layer graphene grating structures have shown excellent capability for thermal modulation in magnetic fields. In this study, a theoretical model for the near-field radiative heat transfer under the influence of a magnetic field in twisted bilayer graphene grating structures is proposed, in which there exists a rotation angle between bilayer graphene gratings. The emitter and absorber are mirror images of each other. The combined effect of the magnetic field and graphene chemical potentials on modulating near-field radiative heat transfer is investigated. The effect of the graphene grating filling factor on the surface state and the near-field radiative heat transfer is discussed. By manipulating the rotation angle of the graphene gratings, the magnetic field enhances thermal modulation. The hyperbolic and elliptic surface plasmon polaritons of the graphene gratings undergo topological transitions as the rotation angle increases.
石墨烯光栅结构的各向异性使其在增强近场辐射换热方面具有潜力,单层石墨烯光栅结构在磁场中表现出优异的热调制能力。在本研究中,提出了一种在磁场影响下的双层石墨烯光栅结构的近场辐射传热理论模型,其中双层石墨烯光栅之间存在一个旋转角。发射器和吸收体是彼此的镜像。研究了磁场和石墨烯化学势对近场辐射传热调制的联合效应。讨论了石墨烯光栅填充系数对表面态和近场辐射传热的影响。通过控制石墨烯光栅的旋转角度,磁场增强了热调制。石墨烯光栅的双曲和椭圆表面等离子激元极化子随着旋转角度的增加而发生拓扑跃迁。
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引用次数: 0
Polarization Analysis of Enceladus’ Surface 土卫二表面的偏振分析
IF 2.3 3区 物理与天体物理 Q2 OPTICS Pub Date : 2024-12-21 DOI: 10.1016/j.jqsrt.2024.109331
Claudia D. Morello, Robert A. West, Matthew J. Berg
Enceladus, the sixth largest moon of Saturn, is known to be a geologically active icy body. Observations by NASA's Cassini spacecraft show that Enceladus has cryovolcanoes on its south pole as well as a global subsurface ocean hidden beneath its frozen crust. Photographs from NASA's Cassini Spacecraft during flybys of Enceladus document Enceladus's surface and the cryovolcano plumes. It is known that larger particles ejected from the cryovolcanoes deposit on the surface, while smaller particles escape into Saturn's E-ring. Cassini observations of the sunlight scattered by the plume particles on the surface may provide information about the plume composition and potentially the dynamics of the ocean below. This work presents Enceladus’ disk-averaged degree of linear polarization (DoLP), which has yet to be analyzed, and compares it to spherical, spheroidal, cylindrical, and hexagonal ice particles simulated by light scattering codes ADDA and T-Matrix using a multiple-scattering approximation. The Pearson correlation coefficient is used to quantify the fit of each morphology to the surface polarization data in the GRN (569 nm) and MT2 (727 nm) wavelength filters. The polarization of Enceladus’ surface implies the particles are likely non-spherical, and possibly occur in a narrow size distribution near a mean of two microns in radius.
土卫二是土星的第六大卫星,是一个地质活跃的冰体。美国宇航局卡西尼号宇宙飞船的观测表明,土卫二的南极有冰火山,在其冰冻的地壳下隐藏着一个全球性的地下海洋。美国宇航局卡西尼号飞船在飞越土卫二时拍摄的照片记录了土卫二的表面和冰冻火山羽流。众所周知,从冰火山喷出的较大颗粒沉积在土星表面,而较小的颗粒则逃逸到土星的e环中。卡西尼号对表面羽流粒子散射的阳光的观测可能会提供羽流组成和下面海洋动态的潜在信息。本文介绍了土卫二的圆盘平均线极化度(DoLP),并将其与用多重散射近似的光散射代码ADDA和T-Matrix模拟的球形、球形、圆柱形和六边形冰粒进行了比较。Pearson相关系数用于量化GRN(569 nm)和MT2(727 nm)波长滤波器中每种形貌与表面极化数据的拟合。土卫二表面的极化表明,这些粒子很可能是非球形的,并且可能以接近平均半径2微米的狭窄尺寸分布。
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引用次数: 0
T-matrix representation of optical scattering response: Suggestion for a data format 光散射响应的t矩阵表示:对数据格式的建议
IF 2.3 3区 物理与天体物理 Q2 OPTICS Pub Date : 2024-12-19 DOI: 10.1016/j.jqsrt.2024.109310
Nigar Asadova, Karim Achouri, Kristian Arjas, Baptiste Auguié, Roland Aydin, Alexandre Baron, Dominik Beutel, Bernd Bodermann, Kaoutar Boussaoud, Sven Burger, Minseok Choi, Krzysztof M. Czajkowski, Andrey B. Evlyukhin, Atefeh Fazel-Najafabadi, Ivan Fernandez-Corbaton, Puneet Garg, David Globosits, Ulrich Hohenester, Hongyoon Kim, Seokwoo Kim, Philippe Lalanne, Eric C. Le Ru, Jörg Meyer, Jungho Mun, Lorenzo Pattelli, Lukas Pflug, Carsten Rockstuhl, Junsuk Rho, Stefan Rotter, Brian Stout, Päivi Törmä, Jorge Olmos Trigo, Frank Tristram, Nikolaos L. Tsitsas, Renaud Vallée, Kevin Vynck, Thomas Weiss, Peter Wiecha, Thomas Wriedt, Vassilios Yannopapas, Maxim A. Yurkin, Grigorios P. Zouros
The transition matrix, frequently abbreviated as T-matrix, contains the complete information in a linear approximation of how a spatially localized object scatters an incident field. The T-matrix is used to study the scattering response of an isolated object and describes the optical response of complex photonic materials made from ensembles of individual objects. T-matrices of certain common structures, potentially, have been repeatedly calculated all over the world again and again. This is not necessary and constitutes a major challenge for various reasons. First, the resources spent on their computation represent an unsustainable financial and ecological burden. Second, with the onset of machine learning, data is the gold of our era, and it should be freely available to everybody to address novel scientific challenges. Finally, the possibility of reproducing simulations could tremendously improve if the considered T-matrices could be shared. To address these challenges, we found it important to agree on a common data format for T-matrices and to enable their collection from different sources and distribution. This document aims to develop the specifications for storing T-matrices and associated metadata. The specifications should allow maximum freedom to accommodate as many use cases as possible without introducing any ambiguity in the stored data. The common format will assist in setting up a public database of T-matrices.
转移矩阵,通常缩写为t矩阵,包含了空间局部物体如何散射入射场的线性近似的完整信息。t矩阵用于研究孤立物体的散射响应,描述了由单个物体组成的复杂光子材料的光学响应。某些常见结构的t矩阵,可能已经在世界范围内一次又一次地被反复计算。这是不必要的,并且由于各种原因构成了一个重大挑战。首先,用于计算的资源构成了不可持续的财政和生态负担。其次,随着机器学习的出现,数据是我们这个时代的黄金,它应该免费提供给每个人,以应对新的科学挑战。最后,如果所考虑的t矩阵可以共享,那么再现模拟的可能性将大大提高。为了应对这些挑战,我们认为重要的是就t矩阵的通用数据格式达成一致,并使它们能够从不同的来源和分布中收集。本文档旨在开发存储t矩阵和相关元数据的规范。规范应该允许最大限度的自由来容纳尽可能多的用例,而不会在存储的数据中引入任何歧义。共同格式将有助于建立t矩阵的公共数据库。
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引用次数: 0
Pyramid-structured VO2-based thin films with large emissivity tunability for thermochromic radiators 用于热致变色散热器的具有大发射率可调性的金字塔结构vo2基薄膜
IF 2.3 3区 物理与天体物理 Q2 OPTICS Pub Date : 2024-12-18 DOI: 10.1016/j.jqsrt.2024.109325
Yifan Sun, Guoliang Chen, Qingze Chen, Haoyang Fu, Benzhi Min, Zhengwei Tao, Tongtong Yue, Junming Zhao, Jun Qiu
Structure-engineering has proven successful in enhancing the thermochromic properties of VO2-based film for smart thermal management under dynamic thermal loads. However, traditional multilayer structures based on interlayer interference and grating structures based on resonance effect exhibit certain wavelength selectivity, thereby hindering broadband absorption. This limitation constrains the improvement of high temperature integrated emissivity (εH), posing great challenges for achieving greater average emissivity tunability (Δε=εH-εL). In this work, we propose a VO2-based 3D pyramid structured film by combining the multilayer structure with the grating structure, achieving an unprecedented high emissivity tunability Δε reaching 0.68. Based on the Magneto-polaron (MP) resonance effect, high absorption over a wide spectral range at high temperature is achieved, with εH of 0.954. Through optimizing the VO2 thickness δ to 30 nm and tilt angle β to 80° respectively, we achieve optimal thermochromic performance of the film. Compared with conventional multilayer and grating regimes, the pyramid textured structure proposed in this work demonstrates a larger design space, which can be a reference for the design and optimization of spacecraft thermal control skin.
结构工程已被证明成功地提高了vo2基薄膜的热致变色性能,以实现动态热负荷下的智能热管理。然而,传统的基于层间干涉的多层结构和基于共振效应的光栅结构具有一定的波长选择性,从而阻碍了宽带吸收。这一限制限制了高温综合发射率(εH)的提高,对实现更高的平均发射率可调性(Δε=εH-εL)提出了很大的挑战。在这项工作中,我们提出了一种基于vo2的三维金字塔结构薄膜,将多层结构与光栅结构相结合,实现了前所未有的高发射率可调性Δε,达到0.68。基于磁极化子(MP)共振效应,在高温下实现了宽光谱范围内的高吸收,εH为0.954。通过优化VO2厚度δ ~ 30 nm和倾角β ~ 80°,获得了薄膜的最佳热致变色性能。与传统的多层和光栅结构相比,本文提出的金字塔结构具有更大的设计空间,可为航天器热控蒙皮的设计和优化提供参考。
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Journal of Quantitative Spectroscopy & Radiative Transfer
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