Random waves on the surface of oil spills on the sea occur due to various factors, including sea breezes, which have a notable influence on the radiative characteristics of the oil spills. Accurately determining the effect of complex sea states on the radiative characteristics of oil spills is crucial for enhancing the accuracy of oil-spill monitoring. This study proposes a modified wave spectrum model incorporating Marangoni effect corrections to model rough oil-spill surfaces in complex sea states. Based on this, a radiative transfer model using the Monte Carlo method was developed to investigate the radiative characteristics of oil-spill and oil-free surfaces under varying wind speeds. The findings demonstrate that the surface roughness of oil spills is significantly lower than that of oil-free surfaces at identical wind speeds. This phenomenon is attributed to the higher viscosity of crude oil compared with that of seawater. Such disparities in the surface roughness leads to distinct variations in the spectral characteristics of reflectance. Neglecting these differences may result in inaccurate results. When employing the ELFOUHAILY wave spectrum model at a wind speed of 3 m/s, the mean relative error in reflectance was recorded as 1.15 %. This error increased with wind speed; at 15 m/s, the error increased to 8.2 %. As the wavelength increased, the reflectance of the oil spills decreased. Significant reflectance peaks were observed at 1760 nm and 1920 nm range. An oil-seawater contrast analysis, coupled with an evaluation of the effects of atmospheric absorption bands, indicated that the 1760 nm band was the most effective for detecting oil spills.
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