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Efficient flexible dye-sensitized solar cells from rear illumination based on different morphologies of titanium dioxide photoanode 基于不同形态二氧化钛光阳极的高效柔性背照式染料敏化太阳能电池
IF 5.1 4区 物理与天体物理 Q2 PHYSICS, CONDENSED MATTER Pub Date : 2024-02-01 DOI: 10.1088/1674-4926/45/2/022801
Zhe He, Gentian Yue, Yueyue Gao, Chen Dong, Furui Tan
The TiO2 with nanoparticles (NPs), nanowires (NWs), nanorods (NRs) and nanotubes (NTs) structures were prepared by using a in-situ hydrothermal technique, and then proposed as a photoanode for flexible dye-sensitized solar cell (FDSSC). The influences of the morphology of TiO2 on the photovoltaic performances of FDSSCs were investigated. Under rear illumination of 100 mW·cm−2, the power conversion efficiencies of FDSSCs achieved 6.96%, 7.36%, 7.65%, and 7.83% with the TiO2 photoanodes of NPs, NWs, NRs, and NTs and PEDOT counter electrode. The FDSSCs based on TiO2 NRs and NTs photoanodes have higher short circuit current densities and power conversion efficiencies than that of the others. The enhanced power conversion efficiency is responsible for their nanotubes and rod-shaped ordered structures, which are more beneficial to transmission of electron and hole in semiconductor compared to the TiO2 nanoparticles and nanowires disordered structure.
利用原位水热技术制备了具有纳米颗粒(NPs)、纳米线(NWs)、纳米棒(NRs)和纳米管(NTs)结构的二氧化钛,并将其作为柔性染料敏化太阳能电池(FDSSC)的光阳极。研究了 TiO2 形貌对 FDSSC 光电性能的影响。在100 mW-cm-2的后照下,NPs、NWs、NRs和NTs的TiO2光阳极与PEDOT对电极的FDSSC功率转换效率分别达到6.96%、7.36%、7.65%和7.83%。与其他光阳极相比,基于 TiO2 NRs 和 NTs 光阳极的 FDSSC 具有更高的短路电流密度和功率转换效率。功率转换效率的提高归功于它们的纳米管和棒状有序结构,与 TiO2 纳米颗粒和纳米线的无序结构相比,它们更有利于电子和空穴在半导体中的传输。
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引用次数: 0
Controllable step-flow growth of GaN on patterned freestanding substrate 图案化独立衬底上氮化镓的可控阶跃流生长
IF 5.1 4区 物理与天体物理 Q2 PHYSICS, CONDENSED MATTER Pub Date : 2024-02-01 DOI: 10.1088/1674-4926/45/2/022501
Peng Wu, Jianping Liu, Lei Hu, Xiaoyu Ren, Aiqin Tian, Wei Zhou, Fan Zhang, Xuan Li, Masao Ikeda, Hui Yang
A new kind of step-flow growth mode is proposed, which adopts sidewall as step source on patterned GaN substrate. The terrace width of steps originated from the sidewall was found to change with the growth temperature and ammonia flux. The growth mechanism is explained and simulated based on step motion model. This work helps better understand the behaviors of step advancement and puts forward a method of precisely modulating atomic steps.
提出了一种新的阶梯流生长模式,即在图案化氮化镓衬底上采用侧壁作为阶梯源。研究发现,源于侧壁的阶梯宽度会随着生长温度和氨通量的变化而变化。基于阶跃运动模型对生长机制进行了解释和模拟。这项研究有助于更好地理解阶跃推进的行为,并提出了一种精确调制原子阶跃的方法。
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引用次数: 0
Two-step growth of β-Ga2O3 on c-plane sapphire using MOCVD for solar-blind photodetector 利用 MOCVD 技术在 c 平面蓝宝石上两步生长β-Ga2O3,用于日盲式光电探测器
IF 5.1 4区 物理与天体物理 Q2 PHYSICS, CONDENSED MATTER Pub Date : 2024-02-01 DOI: 10.1088/1674-4926/45/2/022502
Peipei Ma, Jun Zheng, Xiangquan Liu, Zhi Liu, Yuhua Zuo, Buwen Cheng
In this work, a two-step metal organic chemical vapor deposition (MOCVD) method was applied for growing β-Ga2O3 film on c-plane sapphire. Optimized buffer layer growth temperature (TB) was found at 700 °C and the β-Ga2O3 film with full width at half maximum (FWHM) of 0.66° was achieved. A metal−semiconductor−metal (MSM) solar-blind photodetector (PD) was fabricated based on the β-Ga2O3 film. Ultrahigh responsivity of 1422 A/W @ 254 nm and photo-to-dark current ratio (PDCR) of 106 at 10 V bias were obtained. The detectivity of 2.5 × 1015 Jones proved that the photodetector has outstanding performance in detecting weak signals. Moreover, the photodetector exhibited superior wavelength selectivity with rejection ratio (R250 nm/R400 nm) of 105. These results indicate that the two-step method is a promising approach for preparation of high-quality β-Ga2O3 films for high-performance solar-blind photodetectors.
本研究采用两步金属有机化学气相沉积(MOCVD)法在 c 平面蓝宝石上生长了 β-Ga2O3 薄膜。最佳缓冲层生长温度(TB)为 700 °C,β-Ga2O3 薄膜的半最大全宽(FWHM)为 0.66°。基于这种 β-Ga2O3 薄膜,制备出了一种金属-半导体-金属(MSM)太阳盲光电探测器(PD)。在 10 V 偏压下,该器件获得了 1422 A/W @ 254 nm 的超高响应率和 106 的光暗电流比 (PDCR)。2.5 × 1015 琼斯的探测率证明了该光电探测器在探测微弱信号方面的卓越性能。此外,该光电探测器还具有出色的波长选择性,抑制比(R250 nm/R400 nm)为 105。这些结果表明,两步法是制备用于高性能日盲光电探测器的高质量 β-Ga2O3 薄膜的一种可行方法。
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引用次数: 0
An advanced theoretical approach to study super-multiperiod superlattices: theory vs experiments 研究超多周期超晶格的先进理论方法:理论与实验
IF 5.1 4区 物理与天体物理 Q2 PHYSICS, CONDENSED MATTER Pub Date : 2024-02-01 DOI: 10.1088/1674-4926/45/2/022701
Alexander Sergeevich Dashkov, Semyon Andreevich Khakhulin, Dmitrii Alekseevich Shapran, Gennadii Fedorovich Glinskii, Nikita Andreevich Kostromin, Alexander Leonidovich Vasiliev, Sergey Nikolayevich Yakunin, Oleg Sergeevich Komkov, Evgeniy Viktorovich Pirogov, Maxim Sergeevich Sobolev, Leonid Ivanovich Goray, Alexei Dmitrievich Bouravleuv
A new theoretical method to study super-multiperiod superlattices has been developed. The method combines the precision of the 8-band kp-method with the flexibility of the shooting method and the Monte Carlo approach. This method was applied to examine the finest quality samples of super-multiperiod Al0.3Ga0.7As/GaAs superlattices grown by molecular beam epitaxy. The express photoreflectance spectroscopy method was utilized to validate the proposed theoretical method. For the first time, the accurate theoretical analysis of the energy band diagram of super-multiperiod superlattices with experimental verification has been conducted. The proposed approach highly accurately determines transition peak positions and enables the calculation of the energy band diagram, transition energies, relaxation rates, and gain estimation. It has achieved a remarkably low 5% error compared to the commonly used method, which typically results in a 25% error, and allowed to recover the superlattice parameters. The retrieved intrinsic parameters of the samples aligned with XRD data and growth parameters. The proposed method also accurately predicted the escape of the second energy level for quantum well thicknesses less than 5 nm, as was observed in photoreflectance experiments. The new designs of THz light-emitting devices operating at room temperature were suggested by the developed method.
我们开发了一种新的理论方法来研究超多周期超晶格。该方法结合了 8 波段 kp 方法的精确性、射击方法的灵活性和蒙特卡罗方法。该方法被用于研究分子束外延生长的超多周期 Al0.3Ga0.7As/GaAs 超晶格的最优质样品。明示光反射光谱法被用来验证所提出的理论方法。首次对超多期超晶格的能带图进行了精确的理论分析和实验验证。所提出的方法高度精确地确定了跃迁峰位置,并能计算能带图、跃迁能量、弛豫速率和增益估计。与通常会产生 25% 误差的常用方法相比,该方法的误差明显降低到了 5%,而且还能恢复超晶格参数。找回的样品固有参数与 XRD 数据和生长参数一致。所提出的方法还准确预测了量子阱厚度小于 5 纳米时第二能级的逸出,正如光反射实验中所观察到的那样。所开发的方法为在室温下工作的太赫兹发光器件的新设计提供了建议。
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引用次数: 0
Research progress of alkaline earth metal iron-based oxides as anodes for lithium-ion batteries 作为锂离子电池阳极的碱土金属铁基氧化物的研究进展
IF 5.1 4区 物理与天体物理 Q2 PHYSICS, CONDENSED MATTER Pub Date : 2024-02-01 DOI: 10.1088/1674-4926/45/2/021801
Mingyuan Ye, Xiaorui Hao, Jinfeng Zeng, Lin Li, Pengfei Wang, Chenglin Zhang, Li Liu, Fanian Shi, Yuhan Wu
Anode materials are an essential part of lithium-ion batteries (LIBs), which determine the performance and safety of LIBs. Currently, graphite, as the anode material of commercial LIBs, is limited by its low theoretical capacity of 372 mA·h·g−1, thus hindering further development toward high-capacity and large-scale applications. Alkaline earth metal iron-based oxides are considered a promising candidate to replace graphite because of their low preparation cost, good thermal stability, superior stability, and high electrochemical performance. Nonetheless, many issues and challenges remain to be addressed. Herein, we systematically summarize the research progress of alkaline earth metal iron-based oxides as LIB anodes. Meanwhile, the material and structural properties, synthesis methods, electrochemical reaction mechanisms, and improvement strategies are introduced. Finally, existing challenges and future research directions are discussed to accelerate their practical application in commercial LIBs.
负极材料是锂离子电池(LIB)的重要组成部分,决定着锂离子电池的性能和安全性。目前,石墨作为商用锂离子电池的负极材料,其理论容量仅为 372 mA-h-g-1,这限制了其进一步向高容量和大规模应用方向发展。碱土金属铁基氧化物因其制备成本低、热稳定性好、稳定性优越和电化学性能高而被认为是替代石墨的理想候选材料。然而,许多问题和挑战仍有待解决。在此,我们系统地总结了碱土金属铁基氧化物作为 LIB 阳极的研究进展。同时,介绍了材料和结构特性、合成方法、电化学反应机理以及改进策略。最后,讨论了现有的挑战和未来的研究方向,以加速其在商用锂电池中的实际应用。
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引用次数: 0
Enhanced magnetic anisotropy and high hole mobility in magnetic semiconductor Ga1-x-y Fe x Ni y Sb 磁性半导体 Ga1-x-y Fe x Ni y Sb 中增强的磁各向异性和高空穴迁移率
IF 5.1 4区 物理与天体物理 Q2 PHYSICS, CONDENSED MATTER Pub Date : 2024-01-01 DOI: 10.1088/1674-4926/45/1/012101
Zhi Deng, Hailong Wang, Qiqi Wei, Lei Liu, Hongli Sun, Dong Pan, Dahai Wei, Jianhua Zhao
(Ga,Fe)Sb is a promising magnetic semiconductor (MS) for spintronic applications because its Curie temperature (TC) is above 300 K when the Fe concentration is higher than 20%. However, the anisotropy constant Ku of (Ga,Fe)Sb is below 7.6 × 103 erg/cm3 when Fe concentration is lower than 30%, which is one order of magnitude lower than that of (Ga,Mn)As. To address this issue, we grew Ga1-x-yFexNiySb films with almost the same x (≈24%) and different y to characterize their magnetic and electrical transport properties. We found that the magnetic anisotropy of Ga0.76-yFe0.24NiySb can be enhanced by increasing y, in which Ku is negligible at y = 1.7% but increases to 3.8 × 105 erg/cm3 at y = 6.1% (TC = 354 K). In addition, the hole mobility (µ) of Ga1-x-yFexNiySb reaches 31.3 cm2/(V∙s) at x = 23.7%, y = 1.7% (TC = 319 K), which is much higher than the mobility of Ga1-xFexSb at x = 25.2% (µ = 6.2 cm2/(V∙s)). Our results provide useful information for enhancing the magnetic anisotropy and hole mobility of (Ga,Fe)Sb by using Ni co-doping.
(Ga,Fe)Sb是一种很有前途的自旋电子应用磁性半导体(MS),因为当铁元素浓度高于20%时,它的居里温度(TC)高于300 K。然而,当铁元素浓度低于 30% 时,(Ga,Fe)Sb 的各向异性常数 Ku 低于 7.6 × 103 erg/cm3,比 (Ga,Mn)As 低一个数量级。为了解决这个问题,我们生长了几乎相同 x(≈24%)和不同 y 的 Ga1-x-yFexNiySb 薄膜,以表征它们的磁性和电传输特性。我们发现,Ga0.76-yFe0.24NiySb 的磁各向异性可随着 y 的增加而增强,其中在 y = 1.7% 时,Ku 可忽略不计,但在 y = 6.1% 时(TC = 354 K),Ku 增加到 3.8 × 105 erg/cm3。此外,Ga1-x-yFexNiySb 的空穴迁移率(µ)在 x = 23.7%、y = 1.7%(TC = 319 K)时达到 31.3 cm2/(V∙s),远高于 Ga1-xFexSb 在 x = 25.2%(µ = 6.2 cm2/(V∙s))时的迁移率。我们的研究结果为通过掺杂镍来提高(Ga,Fe)Sb 的磁各向异性和空穴迁移率提供了有用的信息。
{"title":"Enhanced magnetic anisotropy and high hole mobility in magnetic semiconductor Ga1-x-y Fe x Ni y Sb","authors":"Zhi Deng, Hailong Wang, Qiqi Wei, Lei Liu, Hongli Sun, Dong Pan, Dahai Wei, Jianhua Zhao","doi":"10.1088/1674-4926/45/1/012101","DOIUrl":"https://doi.org/10.1088/1674-4926/45/1/012101","url":null,"abstract":"(Ga,Fe)Sb is a promising magnetic semiconductor (MS) for spintronic applications because its Curie temperature (<italic toggle=\"yes\">T</italic>\u0000<sub>C</sub>) is above 300 K when the Fe concentration is higher than 20%. However, the anisotropy constant <italic toggle=\"yes\">K</italic>\u0000<sub>u</sub> of (Ga,Fe)Sb is below 7.6 × 10<sup>3</sup> erg/cm<sup>3</sup> when Fe concentration is lower than 30%, which is one order of magnitude lower than that of (Ga,Mn)As. To address this issue, we grew Ga<sub>1-<italic toggle=\"yes\">x</italic>-<italic toggle=\"yes\">y</italic>\u0000</sub>Fe<sub>\u0000<italic toggle=\"yes\">x</italic>\u0000</sub>Ni<sub>\u0000<italic toggle=\"yes\">y</italic>\u0000</sub>Sb films with almost the same <italic toggle=\"yes\">x</italic> (≈24%) and different <italic toggle=\"yes\">y</italic> to characterize their magnetic and electrical transport properties. We found that the magnetic anisotropy of Ga<sub>0.76-<italic toggle=\"yes\">y</italic>\u0000</sub>Fe<sub>0.24</sub>Ni<sub>\u0000<italic toggle=\"yes\">y</italic>\u0000</sub>Sb can be enhanced by increasing <italic toggle=\"yes\">y</italic>, in which <italic toggle=\"yes\">K</italic>\u0000<sub>u</sub> is negligible at <italic toggle=\"yes\">y</italic> = 1.7% but increases to 3.8 × 10<sup>5</sup> erg/cm<sup>3</sup> at <italic toggle=\"yes\">y</italic> = 6.1% (<italic toggle=\"yes\">T</italic>\u0000<sub>C</sub> = 354 K). In addition, the hole mobility (<italic toggle=\"yes\">µ</italic>) of Ga<sub>1-<italic toggle=\"yes\">x</italic>-<italic toggle=\"yes\">y</italic>\u0000</sub>Fe<sub>\u0000<italic toggle=\"yes\">x</italic>\u0000</sub>Ni<sub>\u0000<italic toggle=\"yes\">y</italic>\u0000</sub>Sb reaches 31.3 cm<sup>2</sup>/(V∙s) at <italic toggle=\"yes\">x</italic> = 23.7%, <italic toggle=\"yes\">y</italic> = 1.7% (<italic toggle=\"yes\">T</italic>\u0000<sub>C</sub> = 319 K), which is much higher than the mobility of Ga<sub>1-<italic toggle=\"yes\">x</italic>\u0000</sub>Fe<sub>\u0000<italic toggle=\"yes\">x</italic>\u0000</sub>Sb at <italic toggle=\"yes\">x</italic> = 25.2% (<italic toggle=\"yes\">µ</italic> = 6.2 cm<sup>2</sup>/(V∙s)). Our results provide useful information for enhancing the magnetic anisotropy and hole mobility of (Ga,Fe)Sb by using Ni co-doping.","PeriodicalId":17038,"journal":{"name":"Journal of Semiconductors","volume":"72 1","pages":""},"PeriodicalIF":5.1,"publicationDate":"2024-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139510045","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A 24−30 GHz 8-element dual-polarized 5G FR2 phased-array transceiver IC with 20.8-dBm TX OP1dB and 4.1-dB RX NFin 65-nm CMOS 一款 24-30 GHz 8 元双极化 5G FR2 相控阵收发器集成电路,在 65-nm CMOS 中具有 20.8-dBm TX OP1dB 和 4.1-dB RX NF
IF 5.1 4区 物理与天体物理 Q2 PHYSICS, CONDENSED MATTER Pub Date : 2024-01-01 DOI: 10.1088/1674-4926/45/1/012201
Yongran Yi, Dixian Zhao, Jiajun Zhang, Peng Gu, Chenyu Xu, Yuan Chai, Huiqi Liu, Xiaohu You
This article presents an 8-element dual-polarized phased-array transceiver (TRX) front-end IC for millimeter-wave (mm-Wave) 5G new radio (NR). Power enhancement technologies for power amplifiers (PA) in mm-Wave 5G phased-array TRX are discussed. A four-stage wideband high-power class-AB PA with distributed-active-transformer (DAT) power combining and multi-stage second-harmonic traps is proposed, ensuring the mitigated amplitude-to-phase (AM-PM) distortions across wide carrier frequencies without degrading transmitting (TX) power, gain and efficiency. TX and receiving (RX) switching is achieved by a matching network co-designed on-chip T/R switch. In each TRX element, 6-bit 360° phase shifting and 6-bit 31.5-dB gain tuning are respectively achieved by the digital-controlled vector-modulated phase shifter (VMPS) and differential attenuator (ATT). Fabricated in 65-nm bulk complementary metal oxide semiconductor (CMOS), the proposed TRX demonstrates the measured peak TX/RX gains of 25.5/21.3 dB, covering the 24−29.5 GHz band. The measured peak TX OP1dB and power-added efficiency (PAE) are 20.8 dBm and 21.1%, respectively. The measured minimum RX NF is 4.1 dB. The TRX achieves an output power of 11.0−12.4 dBm and error vector magnitude (EVM) of 5% with 400-MHz 5G NR FR2 OFDM 64-QAM signals across 24−29.5 GHz, covering 3GPP 5G NR FR2 operating bands of n257, n258, and n261.
本文介绍了一种用于毫米波(mm-Wave)5G 新无线电(NR)的 8 元双极化相控阵收发器(TRX)前端集成电路。讨论了毫米波 5G 相控阵 TRX 中功率放大器 (PA) 的功率增强技术。提出了一种具有分布式有源变压器(DAT)功率组合和多级二次谐波捕获器的四级宽带大功率 AB 类功率放大器,确保在不降低发射(TX)功率、增益和效率的情况下,减轻宽载波频率上的幅相失真(AM-PM)。发送(TX)和接收(RX)开关通过片上共同设计的 T/R 开关匹配网络实现。在每个 TRX 元件中,数字控制的矢量调制移相器 (VMPS) 和差分衰减器 (ATT) 分别实现了 6 位 360° 相移和 6 位 31.5 dB 增益调整。拟议的 TRX 采用 65 纳米体互补金属氧化物半导体(CMOS)制造,实测峰值 TX/RX 增益分别为 25.5/21.3 dB,覆盖 24-29.5 GHz 频段。测得的峰值 TX OP1dB 和功率附加效率(PAE)分别为 20.8 dBm 和 21.1%。测得的最小 RX NF 为 4.1 dB。TRX 在 24-29.5 GHz 400-MHz 5G NR FR2 OFDM 64-QAM 信号下实现了 11.0-12.4 dBm 的输出功率和 5% 的误差矢量幅度 (EVM),覆盖了 n257、n258 和 n261 的 3GPP 5G NR FR2 工作频段。
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引用次数: 0
Bidirectional rectifier with gate voltage control based on Bi2O2Se/WSe2 heterojunction 基于 Bi2O2Se/WSe2 异质结的带栅极电压控制的双向整流器
IF 5.1 4区 物理与天体物理 Q2 PHYSICS, CONDENSED MATTER Pub Date : 2024-01-01 DOI: 10.1088/1674-4926/45/1/012701
Ruonan Li, Fangchao Lu, Jiajun Deng, Xingqiu Fu, Wenjie Wang, He Tian
Two-dimensional (2D) WSe2 has received increasing attention due to its unique optical properties and bipolar behavior. Several WSe2-based heterojunctions exhibit bidirectional rectification characteristics, but most devices have a lower rectification ratio. In this work, the Bi2O2Se/WSe2 heterojunction prepared by us has a type Ⅱ band alignment, which can vastly suppress the channel current through the interface barrier so that the Bi2O2Se/WSe2 heterojunction device has a large rectification ratio of about 105. Meanwhile, under different gate voltage modulation, the current on/off ratio of the device changes by nearly five orders of magnitude, and the maximum current on/off ratio is expected to be achieved 106. The photocurrent measurement reveals the behavior of recombination and space charge confinement, further verifying the bidirectional rectification behavior of heterojunctions, and it also exhibits excellent performance in light response. In the future, Bi2O2Se/WSe2 heterojunction field-effect transistors have great potential to reduce the volume of integrated circuits as a bidirectional controlled switching device.
二维(2D)WSe2 因其独特的光学特性和双极行为而受到越来越多的关注。一些基于 WSe2 的异质结表现出双向整流特性,但大多数器件的整流比都较低。在这项工作中,我们制备的 Bi2O2Se/WSe2 异质结具有Ⅱ型带排列,可以极大地抑制通过界面势垒的沟道电流,从而使 Bi2O2Se/WSe2 异质结器件具有约 105 的较大整流比。同时,在不同的栅极电压调制下,器件的电流导通/截止比会发生近五个数量级的变化,最大电流导通/截止比有望达到 106。光电流测量揭示了重组和空间电荷禁锢行为,进一步验证了异质结的双向整流行为,而且在光响应方面也表现出优异的性能。未来,Bi2O2Se/WSe2 异质结场效应晶体管作为一种双向受控开关器件,在缩小集成电路体积方面具有巨大潜力。
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引用次数: 0
Optimized operation scheme of flash-memory-based neural network online training with ultra-high endurance 基于闪存的超高耐久性神经网络在线训练的优化运行方案
IF 5.1 4区 物理与天体物理 Q2 PHYSICS, CONDENSED MATTER Pub Date : 2024-01-01 DOI: 10.1088/1674-4926/45/1/012301
Yang Feng, Zhaohui Sun, Yueran Qi, Xuepeng Zhan, Junyu Zhang, Jing Liu, Masaharu Kobayashi, Jixuan Wu, Jiezhi Chen
With the rapid development of machine learning, the demand for high-efficient computing becomes more and more urgent. To break the bottleneck of the traditional Von Neumann architecture, computing-in-memory (CIM) has attracted increasing attention in recent years. In this work, to provide a feasible CIM solution for the large-scale neural networks (NN) requiring continuous weight updating in online training, a flash-based computing-in-memory with high endurance (109 cycles) and ultra-fast programming speed is investigated. On the one hand, the proposed programming scheme of channel hot electron injection (CHEI) and hot hole injection (HHI) demonstrate high linearity, symmetric potentiation, and a depression process, which help to improve the training speed and accuracy. On the other hand, the low-damage programming scheme and memory window (MW) optimizations can suppress cell degradation effectively with improved computing accuracy. Even after 109 cycles, the leakage current (Ioff) of cells remains sub-10pA, ensuring the large-scale computing ability of memory. Further characterizations are done on read disturb to demonstrate its robust reliabilities. By processing CIFAR-10 tasks, it is evident that ~90% accuracy can be achieved after 109 cycles in both ResNet50 and VGG16 NN. Our results suggest that flash-based CIM has great potential to overcome the limitations of traditional Von Neumann architectures and enable high-performance NN online training, which pave the way for further development of artificial intelligence (AI) accelerators.
随着机器学习的快速发展,人们对高效计算的需求越来越迫切。为了突破传统冯-诺依曼架构的瓶颈,内存计算(CIM)近年来越来越受到关注。本研究针对在线训练中需要持续更新权重的大规模神经网络(NN)提供了一种可行的 CIM 解决方案,研究了一种具有高耐用性(109 个周期)和超快编程速度的基于闪存的内存计算。一方面,所提出的通道热电子注入(CHEI)和热空穴注入(HHI)编程方案具有高线性度、对称电位和抑制过程,有助于提高训练速度和准确性。另一方面,低损伤编程方案和存储器窗口(MW)优化可以有效抑制单元退化,提高计算精度。即使经过 109 次循环,单元的漏电流(Ioff)也保持在 10pA 以下,确保了存储器的大规模运算能力。我们还对读取干扰进行了进一步的鉴定,以证明其强大的可靠性。通过处理 CIFAR-10 任务,可以明显看出,在 ResNet50 和 VGG16 NN 中,经过 109 次循环后,准确率可达到约 90%。我们的研究结果表明,基于闪存的 CIM 在克服传统冯-诺依曼架构的局限性和实现高性能 NN 在线训练方面具有巨大潜力,这为人工智能(AI)加速器的进一步发展铺平了道路。
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引用次数: 0
Electrical properties and structural optimization of GaN/InGaN/GaN tunnel junctions grown by molecular beam epitaxy 分子束外延生长的 GaN/InGaN/GaN 隧道结的电气特性和结构优化
IF 5.1 4区 物理与天体物理 Q2 PHYSICS, CONDENSED MATTER Pub Date : 2024-01-01 DOI: 10.1088/1674-4926/45/1/012503
Jun Fang, Fan Zhang, Wenxian Yang, Aiqin Tian, Jianping Liu, Shulong Lu, Hui Yang
The InGaN films and GaN/InGaN/GaN tunnel junctions (TJs) were grown on GaN templates with plasma-assisted molecular beam epitaxy. As the In content increases, the quality of InGaN films grown on GaN templates decreases and the surface roughness of the samples increases. V-pits and trench defects were not found in the AFM images. p++-GaN/InGaN/n++-GaN TJs were investigated for various In content, InGaN thicknesses and doping concentration in the InGaN insert layer. The InGaN insert layer can promote good interband tunneling in GaN/InGaN/GaN TJ and significantly reduce operating voltage when doping is sufficiently high. The current density increases with increasing In content for the 3 nm InGaN insert layer, which is achieved by reducing the depletion zone width and the height of the potential barrier. At a forward current density of 500 A/cm2, the measured voltage was 4.31 V and the differential resistance was measured to be 3.75 × 10−3 Ω·cm2 for the device with a 3 nm p++-In0.35Ga0.65N insert layer. When the thickness of the In0.35Ga0.65N layer is closer to the “balanced” thickness, the TJ current density is higher. If the thickness is too high or too low, the width of the depletion zone will increase and the current density will decrease. The undoped InGaN layer has a better performance than n-type doping in the TJ. Polarization-engineered tunnel junctions can enhance the functionality and performance of electronic and optoelectronic devices.
利用等离子体辅助分子束外延技术在 GaN 模板上生长了 InGaN 薄膜和 GaN/InGaN/GaN 隧道结 (TJ)。随着铟含量的增加,生长在氮化镓模板上的氮化镓薄膜的质量下降,样品的表面粗糙度增加。针对不同的 In 含量、InGaN 厚度和 InGaN 插入层中的掺杂浓度,研究了 p++-GaN/InGaN/n++-GaN TJ。当掺杂量足够高时,InGaN 插入层可促进 GaN/InGaN/GaN TJ 中良好的带间隧道,并显著降低工作电压。3 nm InGaN 插入层的电流密度随着 In 含量的增加而增加,这是通过减小耗尽区宽度和势垒高度实现的。在正向电流密度为 500 A/cm2 时,测量到的电压为 4.31 V,带有 3 nm p++-In0.35Ga0.65N 插入层的器件的差分电阻为 3.75 × 10-3 Ω-cm2。当 In0.35Ga0.65N 层的厚度更接近 "平衡 "厚度时,TJ 电流密度会更高。如果厚度过高或过低,耗尽区的宽度会增加,电流密度会降低。在 TJ 中,未掺杂 InGaN 层的性能优于 n 型掺杂层。极化工程隧道结可以增强电子和光电器件的功能和性能。
{"title":"Electrical properties and structural optimization of GaN/InGaN/GaN tunnel junctions grown by molecular beam epitaxy","authors":"Jun Fang, Fan Zhang, Wenxian Yang, Aiqin Tian, Jianping Liu, Shulong Lu, Hui Yang","doi":"10.1088/1674-4926/45/1/012503","DOIUrl":"https://doi.org/10.1088/1674-4926/45/1/012503","url":null,"abstract":"The InGaN films and GaN/InGaN/GaN tunnel junctions (TJs) were grown on GaN templates with plasma-assisted molecular beam epitaxy. As the In content increases, the quality of InGaN films grown on GaN templates decreases and the surface roughness of the samples increases. V-pits and trench defects were not found in the AFM images. p<sup>++</sup>-GaN/InGaN/n<sup>++</sup>-GaN TJs were investigated for various In content, InGaN thicknesses and doping concentration in the InGaN insert layer. The InGaN insert layer can promote good interband tunneling in GaN/InGaN/GaN TJ and significantly reduce operating voltage when doping is sufficiently high. The current density increases with increasing In content for the 3 nm InGaN insert layer, which is achieved by reducing the depletion zone width and the height of the potential barrier. At a forward current density of 500 A/cm<sup>2</sup>, the measured voltage was 4.31 V and the differential resistance was measured to be 3.75 × 10<sup>−3</sup> Ω·cm<sup>2</sup> for the device with a 3 nm p<sup>++</sup>-In<sub>0.35</sub>Ga<sub>0.65</sub>N insert layer. When the thickness of the In<sub>0.35</sub>Ga<sub>0.65</sub>N layer is closer to the “balanced” thickness, the TJ current density is higher. If the thickness is too high or too low, the width of the depletion zone will increase and the current density will decrease. The undoped InGaN layer has a better performance than n-type doping in the TJ. Polarization-engineered tunnel junctions can enhance the functionality and performance of electronic and optoelectronic devices.","PeriodicalId":17038,"journal":{"name":"Journal of Semiconductors","volume":"12 1","pages":""},"PeriodicalIF":5.1,"publicationDate":"2024-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139509724","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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Journal of Semiconductors
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