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Self-powered UVC detectors based on α-Ga2O3 with enchanted speed performance 基于 α-Ga2O3 的自供电紫外线探测器,速度性能令人着迷
IF 5.1 4区 物理与天体物理 Q2 PHYSICS, CONDENSED MATTER Pub Date : 2024-07-31 DOI: 10.1088/1674-4926/24020001
Aleksei Almaev, Alexander Tsymbalov, Bogdan Kushnarev, Vladimir Nikolaev, Alexei Pechnikov, Mikhail Scheglov and Andrei Chikiryaka
Detectors were developed for detecting irradiation in the short-wavelength ultraviolet (UVC) interval using high-quality single-crystalline α-Ga2O3 films with Pt interdigital contacts. The films of α-Ga2O3 were grown on planar sapphire substrates with c-plane orientation using halide vapor phase epitaxy. The spectral dependencies of the photo to dark current ratio, responsivity, external quantum efficiency and detectivity of the structures were investigated in the wavelength interval of 200−370 nm. The maximum of photo to dark current ratio, responsivity, external quantum efficiency, and detectivity of the structures were 1.16 × 104 arb. un., 30.6 A/W, 1.65 × 104%, and 6.95 × 1015 Hz0.5·cm/W at a wavelength of 230 nm and an applied voltage of 1 V. The high values of photoelectric properties were due to the internal enhancement of the photoresponse associated with strong hole trapping. The α-Ga2O3 film-based UVC detectors can function in self-powered operation mode due to the built-in electric field at the Pt/α-Ga2O3 interfaces. At a wavelength of 254 nm and zero applied voltage, the structures exhibit a responsivity of 0.13 mA/W and an external quantum efficiency of 6.2 × 10−2%. The UVC detectors based on the α-Ga2O3 films demonstrate high-speed performance with a rise time of 18 ms in self-powered mode.
利用带有铂相互接触的高质量单晶α-Ga2O3 薄膜,开发了用于检测短波长紫外线(UVC)区间辐照的探测器。α-Ga2O3薄膜是利用卤化物气相外延技术在具有c平面取向的平面蓝宝石衬底上生长的。在 200-370 nm 波长范围内,研究了该结构的光暗电流比、响应度、外部量子效率和检测度的光谱依赖性。在波长为 230 nm、外加电压为 1 V 时,该结构的光暗电流比、响应率、外部量子效率和检测率分别达到 1.16 × 104 arb.由于 Pt/α-Ga2O3 界面的内置电场,基于 α-Ga2O3 薄膜的紫外线检测器可在自供电运行模式下工作。在波长为 254 nm、外加电压为零的条件下,该结构的响应率为 0.13 mA/W,外部量子效率为 6.2 × 10-2%。基于 α-Ga2O3 薄膜的紫外线检测器具有高速性能,在自供电模式下上升时间为 18 毫秒。
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引用次数: 0
Review of the SiC LDMOS power device 碳化硅 LDMOS 功率器件回顾
IF 5.1 4区 物理与天体物理 Q2 PHYSICS, CONDENSED MATTER Pub Date : 2024-07-31 DOI: 10.1088/1674-4926/24010029
Ziwei Hu, Jiafei Yao, Ang Li, Qi Sun, Man Li, Kemeng Yang, Jun Zhang, Jing Chen, Maolin Zhang and Yufeng Guo
Silicon carbide (SiC), as a third-generation semiconductor material, possesses exceptional material properties that significantly enhance the performance of power devices. The SiC lateral double-diffused metal–oxide–semiconductor (LDMOS) power devices have undergone continuous optimization, resulting in an increase in breakdown voltage (BV) and ultra-low specific on-resistance (Ron,sp). This paper has summarized the structural optimizations and experimental progress of SiC LDMOS power devices, including the trench-gate technology, reduced surface field (RESURF) technology, doping technology, junction termination techniques and so on. The paper is aimed at enhancing the understanding of the operational mechanisms and providing guidelines for the further development of SiC LDMOS power devices.
碳化硅(SiC)作为第三代半导体材料,具有优异的材料特性,可显著提高功率器件的性能。碳化硅侧向双扩散金属氧化物半导体(LDMOS)功率器件经过不断优化,实现了击穿电压(BV)的提高和超低比导通电阻(Ron,sp)。本文总结了 SiC LDMOS 功率器件的结构优化和实验进展,包括沟槽栅极技术、减小表面场(RESURF)技术、掺杂技术、结端技术等。本文旨在加深对工作机制的理解,并为进一步开发 SiC LDMOS 功率器件提供指导。
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引用次数: 0
Peripheral carbazole units-decorated MR emitter containing B−N covalent bond for highly efficient green OLEDs with low roll-off 含有 B-N 共价键的外围咔唑单元装饰 MR 发射器,用于制造低滚降的高效绿色 OLED
IF 5.1 4区 物理与天体物理 Q2 PHYSICS, CONDENSED MATTER Pub Date : 2024-07-31 DOI: 10.1088/1674-4926/24040008
Danrui Wan, Jianping Zhou, Guoyun Meng, Ning Su, Dongdong Zhang, Lian Duan and Junqiao Ding
Boron−nitrogen doped multiple resonance (BN-MR) emitters, characterized by B−N covalent bonds, offer distinctive advantages as pivotal building blocks for facile access to novel MR emitters featuring narrowband spectra and high efficiency. However, there remains a scarcity of exploration concerning synthetic methods and structural derivations to expand the library of novel BN-MR emitters. Herein, we present the synthesis of a BN-MR emitter, tCz[B−N]N, through a one-pot borylation reaction directed by the amine group, achieving an impressive yield of 94%. The emitter is decorated by incorporating two 3,6-di-t-butylcarbazole (tCz) units into a B−N covalent bond doped BN-MR parent molecule via para-C−π−D and para-N−π−D conjugations. This peripheral decoration strategy enhances the reverse intersystem crossing process and shifts the emission band towards the pure green region, peaking at 526 nm with a narrowband full-width at half maximum (FWHM) of 41 nm. Consequently, organic light emitting diodes (OLEDs) employing this emitter achieved a maximum external quantum efficiency (EQEmax) value of 27.7%, with minimal efficiency roll-off. Even at a practical luminance of 1000 cd∙m−2, the device maintains a high EQE value of 24.6%.
掺杂硼氮的多重共振(BN-MR)发射体以 B-N 共价键为特征,具有独特的优势,是方便获得新型 MR 发射体的关键构件,具有窄带光谱和高效率的特点。然而,有关合成方法和结构衍生的探索仍然很少,无法扩展新型 BN-MR 发射体库。在此,我们介绍了一种 BN-MR 发射器 tCz[B-N]N的合成方法,该方法通过胺基引导的一锅硼酸化反应实现,收率高达94%。通过对位-C-π-D 和对位-N-π-D 共轭,将两个 3,6-二对丁基咔唑(tCz)单元并入掺杂了 B-N 共价键的 BN-MR 母分子中,从而对发射器进行了装饰。这种外围装饰策略增强了反向系统间交叉过程,并使发射带转向纯绿色区域,在 526 纳米处达到峰值,窄带半最大全宽(FWHM)为 41 纳米。因此,采用这种发射器的有机发光二极管(OLED)的最大外部量子效率(EQEmax)值为 27.7%,效率衰减极小。即使在 1000 cd∙m-2 的实际亮度下,该器件也能保持 24.6% 的高 EQE 值。
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引用次数: 0
Embedded high-quality ternary GaAs1−x Sb x quantum dots in GaAs nanowires by molecular-beam epitaxy 通过分子束外延在砷化镓纳米线中嵌入高质量的 GaAs1-x Sb x 三元量子点
IF 5.1 4区 物理与天体物理 Q2 PHYSICS, CONDENSED MATTER Pub Date : 2024-07-31 DOI: 10.1088/1674-4926/24030038
Xiyu Hou, Lianjun Wen, Fengyue He, Ran Zhuo, Lei Liu, Hailong Wang, Qing Zhong, Dong Pan and Jianhua Zhao
Semiconductor quantum dots are promising candidates for preparing high-performance single photon sources. A basic requirement for this application is realizing the controlled growth of high-quality semiconductor quantum dots. Here, we report the growth of embedded GaAs1−xSbx quantum dots in GaAs nanowires by molecular-beam epitaxy. It is found that the size of the GaAs1−xSbx quantum dot can be well-defined by the GaAs nanowire. Energy dispersive spectroscopy analyses show that the antimony content x can be up to 0.36 by tuning the growth temperature. All GaAs1−xSbx quantum dots exhibit a pure zinc-blende phase. In addition, we have developed a new technology to grow GaAs passivation layers on the sidewalls of the GaAs1−xSbx quantum dots. Different from the traditional growth process of the passivation layer, GaAs passivation layers can be grown simultaneously with the growth of the embedded GaAs1−xSbx quantum dots. The spontaneous GaAs passivation layer shows a pure zinc-blende phase due to the strict epitaxial relationship between the quantum dot and the passivation layer. The successful fabrication of embedded high-quality GaAs1−xSbx quantum dots lays the foundation for the realization of GaAs1−xSbx-based single photon sources.
半导体量子点是制备高性能单光子源的理想候选材料。这一应用的基本要求是实现高质量半导体量子点的可控生长。在此,我们报告了通过分子束外延技术在砷化镓纳米线中生长嵌入式 GaAs1-xSbx 量子点的情况。研究发现 GaAs1-xSbx 量子点的尺寸可以由 GaAs 纳米线很好地确定。能量色散光谱分析表明,通过调节生长温度,锑含量 x 可以达到 0.36。所有 GaAs1-xSbx 量子点都呈现出纯锌蓝晶相。此外,我们还开发了一种在 GaAs1-xSbx 量子点侧壁生长 GaAs 钝化层的新技术。与传统的钝化层生长工艺不同,砷化镓钝化层可以与嵌入式砷化镓-xSbx 量子点的生长同时进行。由于量子点与钝化层之间严格的外延关系,自发的砷化镓钝化层呈现出纯净的蓝晶锌相。嵌入式高质量 GaAs1-xSbx 量子点的成功制备为实现基于 GaAs1-xSbx 的单光子源奠定了基础。
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引用次数: 0
Achievable hole concentration at room temperature as a function of Mg concentration for MOCVD-grown p-GaN after sufficient annealing 充分退火后 MOCVD 生长的 p-GaN 在室温下的可实现空穴浓度与镁浓度的函数关系
IF 5.1 4区 物理与天体物理 Q2 PHYSICS, CONDENSED MATTER Pub Date : 2024-07-31 DOI: 10.1088/1674-4926/24010017
Siyi Huang, Masao Ikeda, Feng Zhang, Minglong Zhang, Jianjun Zhu, Shuming Zhang and Jianping Liu
Relationship between the hole concentration at room temperature and the Mg doping concentration in p-GaN grown by MOCVD after sufficient annealing was studied in this paper. Different annealing conditions were applied to obtain sufficient activation for p-GaN samples with different Mg doping ranges. Hole concentration, resistivity and mobility were characterized by room-temperature Hall measurements. The Mg doping concentration and the residual impurities such as H, C, O and Si were measured by secondary ion mass spectroscopy, confirming negligible compensations by the impurities. The hole concentration, resistivity and mobility data are presented as a function of Mg concentration, and are compared with literature data. The appropriate curve relating the Mg doping concentration to the hole concentration is derived using a charge neutrality equation and the ionized-acceptor-density [ ] (cm−3) dependent ionization energy of Mg acceptor was determined as = 184 − 2.66 × 10−5 × [ ]1/3 meV.
本文研究了通过 MOCVD 技术生长的 p-GaN 在充分退火后室温下的空穴浓度与掺镁浓度之间的关系。对不同掺镁范围的 p-GaN 样品采用了不同的退火条件以获得充分的活化。通过室温霍尔测量表征了空穴浓度、电阻率和迁移率。通过二次离子质谱法测量了掺镁浓度以及 H、C、O 和 Si 等残留杂质,证实杂质的补偿作用可以忽略不计。空穴浓度、电阻率和迁移率数据是掺镁浓度的函数,并与文献数据进行了比较。利用电荷中性方程推导出了掺镁浓度与空穴浓度之间的适当曲线,并确定了镁受体的电离能与电离受体密度[ ](cm-3)有关,即 = 184 - 2.66 × 10-5 × [ ]1/3 meV。
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引用次数: 0
A highly sensitive ratiometric near-infrared nanosensor based on erbium-hyperdoped silicon quantum dots for iron(Ⅲ) detection 基于铒-超掺杂硅量子点的高灵敏近红外比率测量法纳米传感器,用于铁(Ⅲ)检测
IF 5.1 4区 物理与天体物理 Q2 PHYSICS, CONDENSED MATTER Pub Date : 2024-07-31 DOI: 10.1088/1674-4926/24020018
Kun Wang, Wenxuan Lai, Zhenyi Ni, Deren Yang and Xiaodong Pi
Ratiometric fluorescent detection of iron(Ⅲ) (Fe3+) offers inherent self-calibration and contactless analytic capabilities. However, realizing a dual-emission near-infrared (NIR) nanosensor with a low limit of detection (LOD) is rather challenging. In this work, we report the synthesis of water-dispersible erbium-hyperdoped silicon quantum dots (Si QDs:Er), which emit NIR light at the wavelengths of 810 and 1540 nm. A dual-emission NIR nanosensor based on water-dispersible Si QDs:Er enables ratiometric Fe3+ detection with a very low LOD (0.06 μM). The effects of pH, recyclability, and the interplay between static and dynamic quenching mechanisms for Fe3+ detection have been systematically studied. In addition, we demonstrate that the nanosensor may be used to construct a sequential logic circuit with memory functions.
铁(Ⅲ)(Fe3+)的比率荧光检测具有固有的自校准和非接触分析能力。然而,实现具有低检测限(LOD)的双发射近红外(NIR)纳米传感器却相当具有挑战性。在这项工作中,我们报告了水可分散铒超掺杂硅量子点(Si QDs:Er)的合成过程,该量子点可发射波长为 810 纳米和 1540 纳米的近红外光。基于可在水中分散的 Si QDs:Er 的双发射近红外纳米传感器能以极低的 LOD(0.06 μM)实现比率法检测 Fe3+。我们系统地研究了 pH 值、可回收性以及静态和动态淬灭机制对 Fe3+ 检测的影响。此外,我们还证明了该纳米传感器可用于构建具有记忆功能的顺序逻辑电路。
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引用次数: 0
A 128 × 128 SPAD LiDAR sensor with column-parallel 25 ps resolution TA-ADCs 配备列并行 25 ps 分辨率 TA-ADC 的 128 × 128 SPAD 激光雷达传感器
IF 5.1 4区 物理与天体物理 Q2 PHYSICS, CONDENSED MATTER Pub Date : 2024-07-31 DOI: 10.1088/1674-4926/24030019
Na Tian, Zhe Wang, Kai Ma, Xu Yang, Nan Qi, Jian Liu, Nanjian Wu, Runjiang Dou and Liyuan Liu
This paper presents a design of single photon avalanche diode (SPAD) light detection and ranging (LiDAR) sensor with 128 × 128 pixels and 128 column-parallel time-to-analog-merged-analog-to-digital converts (TA-ADCs). Unlike the conventional TAC-based SPAD LiDAR sensor, in which the TAC and ADC are separately implemented, we propose to merge the TAC and ADC by sharing their capacitors, thus avoiding the analog readout noise of TAC’s output buffer, improving the conversion rate, and reducing chip area. The reverse start-stop logic is employed to reduce the power of the TA-ADC. Fabricated in a 180 nm CMOS process, our prototype sensor exhibits a timing resolution of 25 ps, a DNL of +0.30/−0.77 LSB, an INL of +1.41/−2.20 LSB, and a total power consumption of 190 mW. A flash LiDAR system based on this sensor demonstrates the function of 2D/3D imaging with 128 × 128 resolution, 25 kHz inter-frame rate, and sub-centimeter ranging precision.
本文介绍了一种单光子雪崩二极管(SPAD)光探测与测距(LiDAR)传感器的设计,该传感器具有 128 × 128 像素和 128 列并行时间-模拟-合并-模拟-数字转换器(TA-ADC)。传统的基于 TAC 的 SPAD 激光雷达传感器中,TAC 和 ADC 是分开实现的,与此不同,我们建议通过共享电容来合并 TAC 和 ADC,从而避免 TAC 输出缓冲器的模拟读出噪声,提高转换率并减少芯片面积。采用反向启停逻辑降低了 TA-ADC 的功耗。我们的传感器原型采用 180 纳米 CMOS 工艺制造,时序分辨率为 25 ps,DNL 为 +0.30/-0.77 LSB,INL 为 +1.41/-2.20 LSB,总功耗为 190 mW。基于该传感器的闪光激光雷达系统展示了 128 × 128 分辨率、25 kHz 帧间速率和亚厘米级测距精度的 2D/3D 成像功能。
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引用次数: 0
Enhanced thermal emission from metal-free, fully epitaxial structures with epsilon-near-zero InAs layers 具有ε近零砷化镓层的无金属全外延结构的热辐射增强效应
IF 5.1 4区 物理与天体物理 Q2 PHYSICS, CONDENSED MATTER Pub Date : 2024-02-01 DOI: 10.1088/1674-4926/45/2/022101
Karolis Stašys, Andrejus Geižutis, Jan Devenson
We introduce a novel method to create mid-infrared (MIR) thermal emitters using fully epitaxial, metal-free structures. Through the strategic use of epsilon-near-zero (ENZ) thin films in InAs layers, we achieve a narrow-band, wide-angle, and p-polarized thermal emission spectra. This approach, employing molecular beam epitaxy, circumvents the complexities associated with current layered structures and yields temperature-resistant emission wavelengths. Our findings contribute a promising route towards simpler, more efficient MIR optoelectronic devices.
我们介绍了一种利用全外延、无金属结构制造中红外(MIR)热发射器的新方法。通过在 InAs 层中战略性地使用ε-近零(ENZ)薄膜,我们实现了窄带、广角和 p 偏振热发射光谱。这种采用分子束外延的方法避免了当前分层结构的复杂性,并产生了耐高温的发射波长。我们的研究成果为实现更简单、更高效的近红外光电器件开辟了一条前景广阔的道路。
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引用次数: 0
Controllable thermal rectification design for buildings based on phase change composites 基于相变复合材料的建筑物可控热整流设计
IF 5.1 4区 物理与天体物理 Q2 PHYSICS, CONDENSED MATTER Pub Date : 2024-02-01 DOI: 10.1088/1674-4926/45/2/022301
Hengbin Ding, Xiaoshi Li, Tianhang Li, Xiaoyong Zhao, He Tian
Phase-change material (PCM) is widely used in thermal management due to their unique thermal behavior. However, related research in thermal rectifier is mainly focused on exploring the principles at the fundamental device level, which results in a gap to real applications. Here, we propose a controllable thermal rectification design towards building applications through the direct adhesion of composite thermal rectification material (TRM) based on PCM and reduced graphene oxide (rGO) aerogel to ordinary concrete walls (CWs). The design is evaluated in detail by combining experiments and finite element analysis. It is found that, TRM can regulate the temperature difference on both sides of the TRM/CWs system by thermal rectification. The difference in two directions reaches to 13.8 K at the heat flow of 80 W/m2. In addition, the larger the change of thermal conductivity before and after phase change of TRM is, the more effective it is for regulating temperature difference in two directions. The stated technology has a wide range of applications for the thermal energy control in buildings with specific temperature requirements.
相变材料(PCM)因其独特的热行为而被广泛应用于热管理领域。然而,热整流的相关研究主要集中在基础器件层面的原理探索,与实际应用存在差距。在此,我们提出了一种面向建筑应用的可控热整流设计,将基于 PCM 和还原氧化石墨烯(rGO)气凝胶的复合热整流材料(TRM)直接粘附到普通混凝土墙(CWs)上。结合实验和有限元分析对设计进行了详细评估。结果发现,TRM 可以通过热整流调节 TRM/CWs 系统两侧的温差。在热流量为 80 W/m2 时,两个方向的温差达到 13.8 K。此外,TRM 相变前后的导热系数变化越大,其调节双向温差的效果就越好。上述技术在具有特定温度要求的建筑物热能控制方面有着广泛的应用。
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引用次数: 0
Progress in efficient doping of Al-rich AlGaN 高效掺杂富铝氮化铝的进展
IF 5.1 4区 物理与天体物理 Q2 PHYSICS, CONDENSED MATTER Pub Date : 2024-02-01 DOI: 10.1088/1674-4926/45/2/021501
Jiaming Wang, Fujun Xu, Lisheng Zhang, Jing Lang, Xuzhou Fang, Ziyao Zhang, Xueqi Guo, Chen Ji, Chengzhi Ji, Fuyun Tan, Xuelin Yang, Xiangning Kang, Zhixin Qin, Ning Tang, Xinqiang Wang, Weikun Ge, Bo Shen
The development of semiconductors is always accompanied by the progress in controllable doping techniques. Taking AlGaN-based ultraviolet (UV) emitters as an example, despite a peak wall-plug efficiency of 15.3% at the wavelength of 275 nm, there is still a huge gap in comparison with GaN-based visible light-emitting diodes (LEDs), mainly attributed to the inefficient doping of AlGaN with increase of the Al composition. First, p-doping of Al-rich AlGaN is a long-standing challenge and the low hole concentration seriously restricts the carrier injection efficiency. Although p-GaN cladding layers are widely adopted as a compromise, the high injection barrier of holes as well as the inevitable loss of light extraction cannot be neglected. While in terms of n-doping the main issue is the degradation of the electrical property when the Al composition exceeds 80%, resulting in a low electrical efficiency in sub-250 nm UV-LEDs. This review summarizes the recent advances and outlines the major challenges in the efficient doping of Al-rich AlGaN, meanwhile the corresponding approaches pursued to overcome the doping issues are discussed in detail.
半导体的发展始终伴随着可控掺杂技术的进步。以氮化镓基紫外线(UV)发射器为例,尽管在波长为 275 纳米时的峰值插壁效率达到了 15.3%,但与氮化镓基可见光发光二极管(LED)相比仍存在巨大差距,这主要归因于氮化镓的掺杂效率随铝成分的增加而降低。首先,富铝 AlGaN 的 p 掺杂是一个长期存在的难题,低空穴浓度严重限制了载流子注入效率。虽然 p-GaN 包层作为一种折中方案被广泛采用,但空穴的高注入势垒以及不可避免的光提取损失不容忽视。而在 n 掺杂方面,主要问题是当铝的成分超过 80% 时,电性能会下降,从而导致 250 nm 以下紫外发光二极管的电效率较低。本综述总结了最近的研究进展,概述了高效掺杂富铝氮化铝的主要挑战,同时详细讨论了克服掺杂问题的相应方法。
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引用次数: 0
期刊
Journal of Semiconductors
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