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Chemical hydrogel sensors based on the bimorph effect with short response time 基于双压电晶片效应的短响应时间化学水凝胶传感器
IF 1 Q4 INSTRUMENTS & INSTRUMENTATION Pub Date : 2023-04-20 DOI: 10.5194/jsss-12-141-2023
Stefan Schreiber, Nadja Steinke, G. Gerlach
Abstract. Hydrogel sensors are well suited to measuring the concentration of substances in liquids, and, because the hydrogel is biocompatible, they are ideal for medical use. Hydrogels change their volume in response to stimuli. The larger the hydrogel, the more pronounced the measurement signal. However, a larger volume also leads to slower swelling due to the longer diffusion paths. One method of determining the degree of swelling is to measure the swelling pressure using a piezoresistive pressure sensor. With current approaches, measurement times of several minutes can be achieved. By exploiting the bimorph effect, we were able to reduce the thickness of the hydrogel and, thus, reduce the response time of the entire sensor to less than 1 min. The aim of this paper is now to show how a sensor with short response times can be designed and manufactured and, in particular, how to find a suitable hydrogel composition, how to appropriately structure the hydrogel layer and how a robust adhesion of the hydrogel to the sensor chip can be achieved. As a result, we were able to show that such hydrogel sensors with response times of just a few seconds are possible.
摘要水凝胶传感器非常适合测量液体中物质的浓度,而且由于水凝胶具有生物相容性,因此非常适合医疗用途。水凝胶根据刺激改变体积。水凝胶越大,测量信号就越明显。然而,由于较长的扩散路径,较大的体积也导致较慢的溶胀。确定膨胀程度的一种方法是使用压阻式压力传感器测量膨胀压力。使用当前的方法,可以实现几分钟的测量时间。通过利用双晶片效应,我们能够减少水凝胶的厚度,从而将整个传感器的响应时间减少到小于1 min。本文的目的是展示如何设计和制造响应时间短的传感器,特别是如何找到合适的水凝胶组合物,如何适当地构建水凝胶层,以及如何实现水凝胶与传感器芯片的牢固粘附。因此,我们能够证明这种响应时间仅为几秒钟的水凝胶传感器是可能的。
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引用次数: 0
Ultrasonic measurement setup for monitoring pre-thawing stages of food 用于监测食品解冻前阶段的超声波测量装置
IF 1 Q4 INSTRUMENTS & INSTRUMENTATION Pub Date : 2023-04-18 DOI: 10.5194/jsss-12-133-2023
R. Jha, W. Lang, R. Jedermann
Abstract. The food industry relies on various technical processes, fromstoring, freezing, thawing, and packaging to logistics. With the increasingpopulation and the equational growth in food production, it is preferred tohave increased automation in the food industry to reduce human labor. Toprovide an automated and green solution, it is required to monitor andcontrol food-processing steps, such as thawing. This research aims to design an ultrasound-based setup that can monitor the pre-thawing state of food. A change in the signal by 20 %–27 % for herring fish and 60.7 % forchicken soup was obtained when monitored from a frozen state to a room-temperature state. Various other sample food products were tested, and related challenges and observations are discussed.
摘要食品工业依赖于各种技术流程,从储存、冷冻、解冻、包装到物流。随着人口的增长和食品生产的同等增长,人们更倾向于在食品工业中增加自动化来减少人力劳动。为了提供自动化和绿色的解决方案,需要监控和控制食品加工步骤,例如解冻。本研究旨在设计一种基于超声波的装置,可以监测食物的预解冻状态。当从冷冻状态监测到室温状态时,鲱鱼的信号变化了20% - 27%,鸡汤的信号变化了60.7%。测试了各种其他样品食品,并讨论了相关的挑战和观察结果。
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引用次数: 0
Compact silicon-based attenuated total reflection (ATR) sensor module for liquid analysis 紧凑型硅基衰减全反射(ATR)传感器模块用于液体分析
IF 1 Q4 INSTRUMENTS & INSTRUMENTATION Pub Date : 2023-04-12 DOI: 10.5194/jsss-12-123-2023
A. Lambrecht, C. Bolwien, Hendrik Fuhr, G. Sulz, Annett Isserstedt-Trinke, A. Magi, S. Biermann, J. Wöllenstein
Abstract. Infrared attenuated total reflection (ATR) spectroscopy is a common laboratory technique for the analysis of highly absorbing liquids and solids, and a variety of ATR accessories for laboratory FTIR spectrometers are available. However, ATR spectroscopy is rarely found in industrial processes, where compact, robust, and cost-effective sensors for continuous operation are required. Here, narrowband photometers are more appropriate than FTIR instruments. We show the concept and implementation of a compact Si-based ATR module with a four-channel microelectromechanical systems (MEMS) detector. Measurements of liquid mixtures demonstrate the suitability for applications in the chemical industry. Apart from sapphire (for wavelengths below 5 µm) and diamond (extending to the far-infrared region), most materials for ATRelements do not have either high enough infrared transmission or sufficientmechanical and chemical stability to be exposed to process fluids, abrasivecomponents, or aggressive cleaning agents. However, using diamond coatingson Si improves the stability of the sensor surface. In addition, by properchoice of incidence angle and coating thickness, an enhancement of the ATRabsorbance is theoretically expected and demonstrated by first experimentsusing a compact sensor module with a diamond-coated Si ATR element.
摘要红外衰减全反射(ATR)光谱是一种常用的实验室技术,用于分析高吸收液体和固体,各种ATR附件可用于实验室FTIR光谱仪。然而,ATR光谱在工业过程中很少发现,在工业过程中需要紧凑,坚固且具有成本效益的连续操作传感器。在这里,窄带光度计比FTIR仪器更合适。我们展示了一个具有四通道微机电系统(MEMS)探测器的紧凑型硅基ATR模块的概念和实现。液体混合物的测量证明了在化学工业中应用的适用性。除了蓝宝石(波长低于5µm)和钻石(延伸到远红外区域)之外,大多数用于ATRelements的材料要么没有足够高的红外透射率,要么没有足够的机械和化学稳定性,无法暴露于工艺流体、磨料成分或腐蚀性清洗剂中。然而,在硅上使用金刚石涂层提高了传感器表面的稳定性。此外,通过适当选择入射角和涂层厚度,理论上可以提高ATR吸光度,并通过使用具有金刚石涂层Si ATR元件的紧凑型传感器模块进行了首次实验。
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引用次数: 0
Digital twin concepts for linking live sensor data with real-time models 将实时传感器数据与实时模型连接起来的数字孪生概念
IF 1 Q4 INSTRUMENTS & INSTRUMENTATION Pub Date : 2023-04-11 DOI: 10.5194/jsss-12-111-2023
Abstract. For taking most advantage of live or real-time sensor measurements, data have to be processed by a single or even by a chain of models on the fly, in contrast to earlier offline simulation solutions. This requirement can be best met by concepts developed under the general term “digital twin” (DT). The step from the Internet of Things (IoT) to a fullexploitation of DT solutions entails new challenges but also provides newfeatures, which we discuss based on our example DT solution for remotemonitoring of fruit during ocean transportation. A crucial challenge is thetransformation of models into an updateable format, necessary to keep thephysical object and its modelled representation in sync. A basic new featureof DTs is new software solutions for easy and flexible linking of differentmodels through a streaming platform by implementing an event-drivenarchitecture. We demonstrate a solution for controlling model executionduring multiple life cycle phases of the fruit as physical object. Anevaluation of response times showed that server performance is sufficient tohandle more than 100 DT instances per second.
摘要为了最大限度地利用实时或实时传感器测量,与早期的离线仿真解决方案相比,数据必须由单个甚至一系列模型进行处理。这一要求可以通过一般术语“数字孪生”(DT)下开发的概念来最好地满足。从物联网(IoT)到充分利用DT解决方案的步骤带来了新的挑战,但也提供了新的功能,我们基于用于海洋运输过程中水果远程监控的DT解决方案示例来讨论这些新功能。一个关键的挑战是将模型转换为可更新的格式,这是保持物理对象及其建模表示同步所必需的。DTs的一个基本新特性是新的软件解决方案,通过实现事件驱动架构,可以轻松灵活地通过流平台链接不同的模型。我们展示了一个在水果作为物理对象的多个生命周期阶段控制模型执行的解决方案。对响应时间的评估表明,服务器性能足以每秒处理100多个DT实例。
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引用次数: 0
Evaluation of precision, accuracy and threshold for the design of vibrotactile feedback in eye tracking applications 眼动追踪应用中振动触觉反馈设计的精度、准确性和阈值评估
IF 1 Q4 INSTRUMENTS & INSTRUMENTATION Pub Date : 2023-04-05 DOI: 10.5194/jsss-12-103-2023
Anke Fischer, T. Wendt, Lukas Stiglmeier, P. Gawron, K. Van Laerhoven
Abstract. Novel approaches for the design of assistive technology controls propose the usage of eye tracking devices such as for smart wheelchairs and robotic arms. The advantages of artificial feedback, especially vibrotactile feedback, as opposed to their use in prostheses, have not been sufficiently explored. Vibrotactile feedback reduces the cognitive load on the visual and auditory channel. It provides tactile sensation, resulting in better use of assistive technologies. In this study the impact of vibration on the precision and accuracy of a head-worn eye tracking device is investigated. The presented system is suitable for further research in the field of artificial feedback. Vibration was perceivable for all participants, yet it does not produce any significant deviations in precision and accuracy.
摘要辅助技术控制设计的新方法提出了使用眼睛跟踪设备,例如用于智能轮椅和机械臂。人工反馈的优点,特别是振动触觉反馈,与它们在假肢中的应用相比,还没有得到充分的探索。可控反馈可以减少视觉和听觉通道上的认知负荷。它提供触觉,从而更好地使用辅助技术。在本研究中,研究了振动对头戴式眼动仪精度和准确性的影响。该系统适用于人工反馈领域的进一步研究。所有参与者都能感受到振动,但在精度和准确性方面没有产生任何重大偏差。
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引用次数: 0
Assisting the automated analysis of chemical–analytical measurements in spirits using validated algorithms and an intuitive user interface 使用经过验证的算法和直观的用户界面,协助自动分析烈酒中的化学分析测量值
IF 1 Q4 INSTRUMENTS & INSTRUMENTATION Pub Date : 2023-03-20 DOI: 10.5194/jsss-12-93-2023
Andreas T. Grasskamp, Satnam Singh, Helen Haug, T. Sauerwald
Abstract. Exhaustive analysis of chemical measurements requires considerable expenditure of time and personnel. However, many aspects of this can be automated by translating manual work into objective algorithmic routines. To this end, we developed adaptable software for gas chromatography data andvalidated analysis steps using whisky samples. We employed an unspecific, larger, in-house volatile organic compound (VOC) database and another specifically curated database of217 known whisky chemicals, to automate database-matching based on mass spectra and retention indices. We managed to reduce the amount of necessaryinteraction, facilitated complex analysis for the less experienced user, and showed that characteristic whisky components constituted the majorityof detected molecules in all 16 analyzed samples. With this approach, we present a decisive contribution towards the automated assessment of aromaprofiles in food.
摘要化学测量的详尽分析需要花费大量的时间和人力。然而,通过将手工工作转换为客观的算法例程,可以实现许多方面的自动化。为此,我们开发了适用于气相色谱数据的软件,并使用威士忌样品验证了分析步骤。我们使用了一个非特定的、较大的内部挥发性有机化合物(VOC)数据库和另一个专门管理的包含217种已知威士忌化学物质的数据库,以基于质谱和保留指数自动进行数据库匹配。我们设法减少了必要的相互作用,为经验不足的用户提供了复杂的分析,并表明在所有16个分析样品中,特征威士忌成分构成了大多数检测分子。通过这种方法,我们对食品中香气特征的自动评估做出了决定性的贡献。
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引用次数: 1
Energy analysis of a wireless sensor node powered by a Wiegand sensor Wiegand传感器供电的无线传感器节点的能量分析
IF 1 Q4 INSTRUMENTS & INSTRUMENTATION Pub Date : 2023-03-13 DOI: 10.5194/jsss-12-85-2023
Jonas Wiegner, H. Volker, Fabian Mainz, Andreas Backes, Michael Loeken, F. Huening
Abstract. This article describes an Internet of things (IoT) sensing devicewith a wireless interface which is powered by the energy-harvesting method of theWiegand effect. The Wiegand effect, in contrast to continuous sources likephotovoltaic or thermal harvesters, provides small amounts of energydiscontinuously in pulsed mode. To enable an energy-self-sufficientoperation of the sensing device with this pulsed energy source, the outputenergy of the Wiegand generator is maximized. This energy is used to power upthe system and to acquire and process data like position, temperature orother resistively measurable quantities as well as transmit these data via anultra-low-power ultra-wideband (UWB) data transmitter. A proof-of-conceptsystem was built to prove the feasibility of the approach. The energyconsumption of the system during start-up was analysed, traced back indetail to the individual components, compared to the generated energy andprocessed to identify further optimization options. Based on theproof of concept, an application prototype was developed.
摘要本文描述了一种具有无线接口的物联网(IoT)传感设备,该设备由wiegand效应的能量收集方法供电。与光伏或热采集器等连续源相比,维冈效应在脉冲模式下不连续地提供少量能量。为了使感应装置的能量自给自足的操作与这个脉冲能量源,韦根发电机的输出能量是最大化的。该能量用于为系统供电,获取和处理位置、温度或其他电阻测量量等数据,并通过超低功耗超宽带(UWB)数据发射器传输这些数据。建立了一个概念验证系统来证明该方法的可行性。系统在启动期间的能耗进行了分析,详细追溯到各个组件,并与产生的能量进行了比较,以确定进一步的优化方案。在概念验证的基础上,开发了应用原型。
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引用次数: 0
Gauge to simultaneously determine the electrical conductivity, the Hall constant, and the Seebeck coefficient up to 800 °C 同时测定电导率、霍尔常数和塞贝克系数的仪表,最高可达800 °C
IF 1 Q4 INSTRUMENTS & INSTRUMENTATION Pub Date : 2023-02-27 DOI: 10.5194/jsss-12-69-2023
R. Werner, J. Kita, M. Gollner, F. Linseis, R. Moos
Abstract. A new high temperature gauge to simultaneously determinethe electrical conductivity, the Hall constant, and the Seebeck coefficienthas been developed. Screen-printed heating structures on a ceramic sampleholder are used to generate temperatures up to 800 ∘C by Jouleheating. The heating structures were designed using the finite element method (FEM) simulations and thetemperature distribution was validated by thermal imaging. To measure theSeebeck coefficient, Au/Pt thermocouples with different geometries wereinvestigated and successfully integrated into the gauge. Measurements onconstantan, a typical Seebeck coefficient reference material with highelectrical conductivity, high charge carrier concentration, and a knownSeebeck coefficient, as well as on a well-described boron-doped siliconwafer confirm the functionality of the gauge up to 800 ∘C.
摘要开发了一种同时测定电导率、霍尔常数和塞贝克系数的新型高温计。陶瓷采样器上的丝网印刷加热结构用于产生高达800的温度 ∘C.焦耳热。采用有限元模拟设计了加热结构,并通过热成像验证了温度分布。为了测量塞贝克系数,研究了不同几何形状的Au/Pt热电偶,并成功地将其集成到测量仪中。在具有高电导率、高电荷载流子浓度和已知塞贝克系数的典型塞贝克系数参考材料康坦上以及在描述良好的硼掺杂硅上进行的测量证实了该测量仪的功能高达800 ∘C
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引用次数: 0
Real-time active-gas imaging of small gas leaks 小气体泄漏的实时活性气体成像
IF 1 Q4 INSTRUMENTS & INSTRUMENTATION Pub Date : 2023-02-02 DOI: 10.5194/jsss-12-61-2023
Max Bergau, T. Strahl, B. Scherer, J. Wöllenstein
Abstract. To tackle global warming, the reduction of greenhouse gas leaks is of great public interest. While state-of-the-art optical gas imaging (OGI) cameras can visualize larger gas leaks with magnitudes of liters per minute in the case of methane, a much more sensitive laser-based approach is introduced here. This is accomplished using an infrared camera in combination with an interband cascade laser (ICL) as active illumination. The laser beam diverges suchthat it covers roughly half of the camera's field of view. Three-image batches are recorded to perform classic direct absorptionspectroscopy (DAS) at the image scale. The obtained concentration length in parts per million meter (ppm m) is validated using measurements with varying known methaneconcentrations, different reflective elements, and varying distances. The real-time camera was able to record and quantify a methaneleak as low as 40 mL min−1. Possible incorrect information due to moving objectsis taken into account using an adapted frame-difference approach.
摘要为应对全球变暖,减少温室气体泄漏事关重大公共利益。虽然最先进的光学气体成像(OGI)相机可以看到更大的气体泄漏,在甲烷的情况下,每分钟泄漏升的数量级,但这里介绍了一种更灵敏的基于激光的方法。这是使用红外相机与带间级联激光器(ICL)作为主动照明相结合来完成的。激光束发散,覆盖了相机大约一半的视野。记录三个图像批次,在图像尺度上执行经典的直接吸收光谱(DAS)。使用不同已知甲烷浓度、不同反射元件和不同距离的测量来验证以百万分之一米(ppm m)为单位获得的浓度长度。实时摄像机能够记录和量化低至40 mL min - 1的甲烷泄漏。由于移动物体可能导致的不正确信息被考虑使用一种适应的帧差方法。
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引用次数: 2
Influence of measurement uncertainty on machine learning results demonstrated for a smart gas sensor 测量不确定度对智能气体传感器机器学习结果的影响
IF 1 Q4 INSTRUMENTS & INSTRUMENTATION Pub Date : 2023-01-27 DOI: 10.5194/jsss-12-45-2023
T. Dorst, T. Schneider, S. Eichstädt, A. Schütze
Abstract. Humans spend most of their lives indoors, so indoor air quality (IAQ) plays a key role in human health. Thus, human health is seriously threatened by indoor air pollution, which leads to 3.8 ×106 deaths annually, according to the World Health Organization (WHO). With the ongoing improvement in life quality, IAQ monitoring has become an important concern for researchers. However, in machine learning (ML), measurement uncertainty, which is critical in hazardous gas detection, is usually only estimated using cross-validation and is not directly addressed, and this will be the main focus of this paper. Gas concentration can be determined by using gas sensors in temperature-cycled operation (TCO) and ML on the measured logarithmic resistance of the sensor. This contribution focuses on formaldehyde as one of the most relevant carcinogenic gases indoors and on the sum of volatile organic compounds (VOCs), i.e., acetone, ethanol, formaldehyde, and toluene, measured in the data set as an indicator for IAQ. As gas concentrations are continuous quantities, regression must be used. Thus, a previously published uncertainty-aware automated ML toolbox (UA-AMLT) for classification is extended for regression by introducing an uncertainty-aware partial least squares regression (PLSR) algorithm. The uncertainty propagation of the UA-AMLT is based on the principles described in the Guide to the Expression of Uncertainty in Measurement (GUM) and its supplements. Two different use cases are considered for investigating the influence on ML results in this contribution, namely model training with raw data and with data that are manipulated by adding artificially generated white Gaussian or uniform noise to simulate increased data uncertainty, respectively. One of the benefits of this approach is to obtain a better understanding of where the overall system should be improved. This can be achieved by either improving the trained ML model or using a sensor with higher precision. Finally, an increase in robustness against random noise by training a model with noisy data is demonstrated.
摘要人类一生中大部分时间都在室内度过,因此室内空气质量对人类健康起着关键作用。因此,室内空气污染严重威胁人类健康,导致3.8 根据世界卫生组织(世界卫生组织)的数据,每年有106人死亡。随着生活质量的不断提高,室内空气质量监测已成为研究人员关注的一个重要问题。然而,在机器学习(ML)中,测量不确定性是危险气体检测中的关键,通常只使用交叉验证来估计,而不是直接解决,这将是本文的主要关注点。气体浓度可以通过在温度循环操作(TCO)中使用气体传感器和基于传感器的测量对数电阻的ML来确定。这一贡献侧重于甲醛作为室内最相关的致癌气体之一,以及数据集中作为室内空气质量指标测量的挥发性有机化合物(VOC)的总和,即丙酮、乙醇、甲醛和甲苯。由于气体浓度是连续量,因此必须使用回归。因此,通过引入不确定性感知偏最小二乘回归(PLSR)算法,将先前发布的用于分类的不确定性感知自动ML工具箱(UA-AMLT)扩展为回归。UA-AMLT的不确定度传播基于《测量不确定度表达指南》(GUM)及其补充文件中描述的原则。为了研究这一贡献对ML结果的影响,考虑了两种不同的用例,即分别使用原始数据和通过添加人工生成的白高斯或均匀噪声来模拟增加的数据不确定性的数据进行模型训练。这种方法的好处之一是更好地了解整个系统应该改进的地方。这可以通过改进训练的ML模型或使用具有更高精度的传感器来实现。最后,通过用噪声数据训练模型,证明了对随机噪声的鲁棒性的提高。
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引用次数: 2
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Journal of Sensors and Sensor Systems
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