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A new low NOx emission technique for NH3/H2 blends in a flameless combustor through offset injection 在无焰燃烧器中通过偏置喷射实现 NH3/H2 混合物低氮氧化物排放的新技术
IF 5.6 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-10-24 DOI: 10.1016/j.joei.2024.101864
Mohammad Kalamuddin Ansari , Shawnam , Anand Shankar Singh , Bhupendra Khandelwal , Sudarshan Kumar
The application of ammonia (NH3) as a possible future fuel presents a plausible solution for green energy storage. It helps provide a carbon-neutral fuel alternative for industrial power generation and transportation. However, the combustion of NH3 presents a formidable challenge due to its low reactivity, inadequate flame stability, sluggish flame propagation, and high NOx emissions. Consequently, its integration into combustion systems necessitates substantial system and strategy modification to enable its deployment to industrial systems. The current study presents a novel fuel/air injection technique, which emphasizes the high recirculation of hot combustion products and the extended residence time of fuel/air mixtures. A comprehensive experimental and numerical investigation is conducted using a swirl air injection and offset fuel injection to achieve the flameless combustion mode for optimized NH3/H2 fuel blends. A range of mixture conditions (ϕ = 0.5–1.2) and NH3/H2 compositions (50/50–70/30) are experimentally examined. The investigations helped elucidate the effect of residence time and recirculation on NOx emissions through kinetic simulations using a reactor network model. Subsequently, 3-D numerical simulations helped identify regions of high recirculation, quantified through reactant dilution ratios and uniform temperature distribution. These aspects are determined using a new parameter, the temperature uniformity index along the axial direction of the combustor. The emissions of NOx, unburnt NH3, and unburnt H2 are quantified for different equivalence ratios and NH3 mole fractions in the fuel mixture. The investigations reveal that NOx emissions reached their minimum (450–654 ppm) and (344-211 ppm), when the burner operated at lean (ϕ = 0.5–0.8) and rich (ϕ = 1.0–1.2) conditions, respectively, for 70/30 NH3/H2 blend. The emissions of unburnt NH3 and H2 species remain minimal for lean conditions. Both lean and rich operational regimes demonstrated similar or superior emission characteristics in flameless combustion mode when compared to the conventional combustion mode.
氨(NH3)作为一种可能的未来燃料,为绿色能源储存提供了一种可行的解决方案。它有助于为工业发电和运输提供碳中和燃料替代品。然而,由于 NH3 的反应活性低、火焰稳定性不足、火焰传播缓慢以及氮氧化物排放量高,它的燃烧面临着严峻的挑战。因此,要将其集成到燃烧系统中,必须对系统和策略进行大量修改,才能将其应用到工业系统中。目前的研究提出了一种新型燃料/空气喷射技术,该技术强调热燃烧产物的高度再循环和燃料/空气混合物停留时间的延长。研究人员利用漩涡空气喷射和偏置燃料喷射进行了全面的实验和数值研究,以实现优化的 NH3/H2 混合燃料的无焰燃烧模式。实验研究了一系列混合条件(j = 0.5-1.2)和 NH3/H2 成分(50/50-70/30)。通过使用反应器网络模型进行动力学模拟,这些研究有助于阐明停留时间和再循环对氮氧化物排放的影响。随后,三维数值模拟帮助确定了高再循环区域,并通过反应物稀释比和均匀的温度分布进行了量化。这些方面是通过一个新参数,即沿燃烧器轴向的温度均匀性指数来确定的。针对燃料混合物中不同的当量比和 NH3 摩尔分数,对氮氧化物、未燃 NH3 和未燃 H2 的排放量进行了量化。研究表明,对于 70/30 NH3/H2 混合燃料,当燃烧器分别在贫油(j = 0.5-0.8)和富油(j = 1.0-1.2)条件下运行时,氮氧化物排放量分别达到最小值(450-654 ppm)和(344-211 ppm)。在贫油条件下,未燃烧的 NH3 和 H2 物种的排放量仍然很小。与传统燃烧模式相比,在无焰燃烧模式下,贫燃和富燃两种运行模式都具有相似或更优的排放特性。
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引用次数: 0
Experimental and modeling studies on char combustion under pressurized O2/H2O conditions 加压 O2/H2O 条件下木炭燃烧的实验和模型研究
IF 5.6 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-10-18 DOI: 10.1016/j.joei.2024.101858
Kun Chen, Chenxi Bai, Wenda Zhang, Yijun Zhao, Dongdong Feng, Shaozeng Sun
The desorption kinetic parameters for pressurized combustion and gasification reactions were determined based on a C++ program coupled with the Langmuir-Hinshelwood (L-H) kinetic model developed and experimental data from pressurized char combustion, and the established L-H kinetic model for pressurized char-O2/H2O combustion was refined in the current paper. The activation energy for desorption in reactions involving pressurized char-O2 and char-H2O was determined to be 250.8 kJ/mol, accompanied by a pre-exponential factor of 5.42 × 1010 g/(m2 s). Using this foundation, the current research conducted simulations to investigate the impacts of temperature, pressure, and H2O concentration on the oxidation adsorption rate (Rads,oxi), desorption rate (Rdes), gasification adsorption rate (Rads,gas), and the competitive influences of kinetics and diffusion processes within the pressurized char-O2/H2O combustion. The simulation results indicate a gradual increase in Rdes and Rads,gas with char conversion to reach a peak, followed by a gradual decline. Conversely, the Rads,oxi varies smoothly throughout the char conversion process. At 1673 K/1.0 MPa, the char-O2/H2O reaction rate is primarily constrained by Rads,oxi and Rads,gas, with the adsorption reaction serving as the rate-controlling step. Moreover, it was noted that a rise in pressure resulted in a linear increase in Rads,oxi, Rdes, and Rads,gas. At elevated temperatures, the impact of pressure on them becomes more noticeable. However, the introduction of H2O mitigates this effect. Elevated temperature and pressure facilitate the competition on the kinetics of char-O2 combustion for O2 diffusion, resulting in the conversion of char being more susceptible to O2 diffusion rate limitation. With the addition of 20 % H2O, the competition effect was weakened. In the case of pressurized combustion involving char and O2/H2O, the char conversion is primarily constrained by the O2 diffusion rate and is scarcely influenced by the H2O diffusion rate.
本文基于 C++ 程序,结合建立的 Langmuir-Hinshelwood(L-H)动力学模型和加压炭燃烧的实验数据,确定了加压燃烧和气化反应的解吸动力学参数,并完善了已建立的加压炭-O2/H2O 燃烧 L-H 动力学模型。在涉及加压木炭-O2 和木炭-H2O 的反应中,解吸活化能被确定为 250.8 kJ/mol,预指数为 5.42 × 1010 g/(m2 s)。在此基础上,本研究进行了模拟,研究了温度、压力和 H2O 浓度对加压炭-O2/H2O 燃烧中氧化吸附率(Rads,oxi)、解吸率(Rdes)、气化吸附率(Rads,gas)的影响,以及动力学和扩散过程的竞争影响。模拟结果表明,随着炭转化率达到峰值,Rdes 和 Rads,gas 逐渐增加,随后逐渐下降。相反,在整个木炭转化过程中,Rads,oxi 变化平稳。在 1673 K/1.0 MPa 条件下,炭-O2/H2O 反应速率主要受 Rads,oxi 和 Rads,gas 的制约,吸附反应是速率控制步骤。此外,研究还发现,压力升高会导致 Rads,oxi、Rdes 和 Rads,gas 的线性增加。在高温条件下,压力对它们的影响更加明显。不过,引入 H2O 可以减轻这种影响。温度和压力的升高促进了炭-氧气燃烧动力学对氧气扩散的竞争,导致炭的转化更容易受到氧气扩散速率的限制。加入 20% H2O 后,竞争效应减弱。在涉及木炭和 O2/H2O 的加压燃烧中,木炭转化率主要受制于 O2 扩散速率,几乎不受 H2O 扩散速率的影响。
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引用次数: 0
Numerical investigation of NOx emission characteristics in air-staged combustion system fueled by premixed ammonia/methane 以预混氨/甲烷为燃料的空气分级燃烧系统中氮氧化物排放特性的数值研究
IF 5.6 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-10-18 DOI: 10.1016/j.joei.2024.101857
Weiguo Pan , Ningning Yao , Yifeng Chen , Lianwei Kang
For the purpose of achieving global CO2 reduction, decarbonization at the source of fuels is a practical approach. The transition phase of blending fossil fuels with carbon-free fuels for combustion is a hot topic in the current carbon emission reduction process. In order to achieve efficient and low-pollution combustion of NH3/CH4, the combustion and emission characteristics of NH3/CH4 under single-stage and air-staged combustion methods were numerically investigated in this work. The emissions were compared for different equivalence ratios and different ammonia content conditions. Rate of production (ROP) and sensitivity analysis were performed for NOx, and the reaction path of NH3/CH4 was analyzed. The results indicate that the C-N interaction of the NH3/CH4 mixed combustion process is not significant and turns weaker in the lean flames. HNO intermediate is an important specie for NO generation, and HCN together with HCO intermediate, are essential species for CO generation. NH2 and NH almost dominate the promotion and inhibition of NO generation. Given the contrasting NOx and CO emission behavior of NH3/CH4 in rich and lean flames, the single-stage combustion approach is not suitable. Air-staged combustion achieves both, ensuring the complete burning of NH3 and CH4 while reducing NOx and CO emissions. Moreover, the results suggest that Φpri = 1.2/Φtotal = 0.6 is the optimal NH3/CH4 combustion staging method for controlling NOx emissions.
为了实现全球二氧化碳减排目标,从燃料源头进行脱碳是一种切实可行的方法。化石燃料与无碳燃料混合燃烧的过渡阶段是当前碳减排过程中的热点话题。为了实现 NH3/CH4 的高效低污染燃烧,本研究对 NH3/CH4 在单级燃烧和空气分级燃烧方式下的燃烧和排放特性进行了数值研究。比较了不同当量比和不同氨含量条件下的排放情况。对氮氧化物的生成率(ROP)和敏感性进行了分析,并分析了 NH3/CH4 的反应路径。结果表明,NH3/CH4 混合燃烧过程中的 C-N 相互作用并不明显,而且在贫焰中会变弱。HNO 中间体是生成 NO 的重要物质,HCN 和 HCO 中间体是生成 CO 的重要物质。NH2 和 NH 几乎主导了 NO 生成的促进和抑制作用。鉴于 NH3/CH4 在富焰和贫焰中的氮氧化物和一氧化碳排放行为截然不同,单级燃烧方法并不合适。空气分级燃烧可同时实现这两个目标,既能确保 NH3 和 CH4 的完全燃烧,又能减少 NOx 和 CO 的排放。此外,研究结果表明,Φpri = 1.2/Φtotal = 0.6 是控制氮氧化物排放的最佳 NH3/CH4 分级燃烧方法。
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引用次数: 0
Numerical study on influences of intake temperature and swirl ratio on in-cylinder combustion and pollutant formation characteristics of ammonia/diesel dual-fuel engine 进气温度和涡流比对氨/柴油双燃料发动机缸内燃烧和污染物形成特性影响的数值研究
IF 5.6 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-10-18 DOI: 10.1016/j.joei.2024.101860
Yuhang Lu , Mingliang Wei , Xidong Wang , Qian Ji , Chengcheng Ao , Xintao Wang , Junheng Liu
In order to improve the combustion efficiency of ammonia fuel, and enhance the operational stability and emission level for ammonia engines, this study constructs an in-cylinder combustion numerical model of ammonia/diesel dual-fuel engine based on CONVERGE software, and investigates the effects of initial intake temperature and swirl intensity on in-cylinder combustion and pollutant formation characteristics of ammonia/diesel dual-fuel engine. The results show that increasing the intake temperature can improve the in-cylinder thermal atmosphere, advance the dual-fuel combustion reaction process, and increase the peak in-cylinder combustion pressure and temperature. The peak in-cylinder pressure increases from 6.05 to 6.44 MPa when the intake temperature is increased from 303 to 343 K. This is effective in improving the emissions of incomplete combustion for the ammonia/diesel dual-fuel engine. The in-cylinder unburned NH3, CO and HC emissions are reduced by 20.2 %, 77.1 % and 88.21 %, respectively. Increasing the swirl ratio enhances the in-cylinder gas disturbance, reduces the amount of fuel attached to the wall, and improves the quality of in-cylinder fuel-gas mixture. It also accelerates the process of combustible mixture formation, advances the starting point of ammonia fuel consumption, and accelerates the initial reaction rate. When the swirl ratio is increased from 0.5 to 3.0, the in-cylinder unburned NH3 emission is reduced by 14.85 %. Reasonable adjustment of intake temperature and swirl ratio helps to improve the distribution of direct injection fuel particles inside the cylinder, thereby optimizing the dual-fuel combustion process and enhancing engine performance.
为了提高氨燃料的燃烧效率,提高氨发动机的运行稳定性和排放水平,本研究基于 CONVERGE 软件构建了氨/柴油双燃料发动机缸内燃烧数值模型,研究了初始进气温度和漩涡强度对氨/柴油双燃料发动机缸内燃烧和污染物形成特性的影响。结果表明,提高进气温度可以改善缸内热气氛,推进双燃料燃烧反应过程,提高缸内燃烧压力和温度峰值。当进气温度从 303 K 提高到 343 K 时,缸内峰值压力从 6.05 MPa 提高到 6.44 MPa,从而有效改善了氨/柴油双燃料发动机的不完全燃烧排放。缸内未燃烧的 NH3、CO 和 HC 排放量分别减少了 20.2%、77.1% 和 88.21%。增加漩涡比可增强缸内气体扰动,减少附着在缸壁上的燃料量,并改善缸内燃料-气体混合物的质量。它还能加速可燃混合气的形成过程,提前氨燃料消耗的起点,加快初始反应速度。当漩涡比从 0.5 增加到 3.0 时,缸内未燃烧的 NH3 排放量减少了 14.85%。合理调节进气温度和涡流比有助于改善缸内直喷燃料颗粒的分布,从而优化双燃料燃烧过程,提高发动机性能。
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引用次数: 0
Effect of ammonia reforming on combustion and emission characteristics of a 4-valve engine with an active pre-chamber 氨气转化对带有主动前腔的四气门发动机燃烧和排放特性的影响
IF 5.6 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-10-16 DOI: 10.1016/j.joei.2024.101861
Lin Chen , Fangjia Yan , Ren Zhang , Haiqiao Wei , Jiaying Pan
Ammonia (NH3), as a hydrogen carrier and carbon-free fuel, offers an attractive opportunity for engines to achieve carbon neutrality. Turbulent jet ignition (TJI) combined with ammonia reforming shows the great capacity in ammonia-fueled engines. In this study, the effects of reforming strategy in an ammonia-fueled TJI are numerically studied, addressing the reforming ratio and reforming region. The results show that when only using reformate in the pre-chamber, the promoting effect of jet flame is more effective on the initial combustion phase. There are still very high NH3 emissions due to the low reactivity in the main chamber. Further using reformate both in the pre-chamber and the main chamber, all the combustion stages (ST-CA10, CA10-50, CA50-90) can be shortened almost linearly with the increase of reforming ratio. Besides, the unburned NH3 can be reduced to an acceptable level when the reforming ratio reaches 200 ‰ (hydrogen energy ratio of 18.50 %). The main reason is that the jet-induced strong flow field is coincident with the whole combustion stage. Further increasing the reforming ratio (pure hydrogen) in the pre-chamber, a high combustion efficiency and acceptable NH3 emission can be achieved at a low hydrogen energy ratio (7.08 %). However, knocking combustion will happen at high reforming ratio with a low knock intensity. The results can provide some guidance for making the best-promoting benefit of the limited hydrogen in ammonia TJI engines with different reforming strategies.
氨(NH3)作为一种氢载体和无碳燃料,为发动机实现碳中和提供了一个极具吸引力的机会。湍流喷射点火(TJI)结合氨气重整显示了氨气燃料发动机的巨大潜力。在本研究中,针对重整比和重整区域,对氨燃料 TJI 中重整策略的影响进行了数值研究。结果表明,如果只在前腔使用重整液,喷射火焰对初始燃烧阶段的促进作用更为有效。由于主燃烧室的反应活性较低,NH3 的排放量仍然很高。进一步在前室和主室中使用重整液,所有燃烧阶段(ST-CA10、CA10-50、CA50-90)都能随着重整比的增加而几乎线性地缩短。此外,当重整比达到 200 ‰(氢能比为 18.50 %)时,未燃烧的 NH3 可以减少到可接受的水平。主要原因是射流引发的强流场与整个燃烧阶段相吻合。进一步提高前室的重整比(纯氢),可在低氢能比(7.08 %)下实现高燃烧效率和可接受的 NH3 排放。然而,在高重整比、低爆震强度的情况下,会出现爆震燃烧。这些结果为采用不同重整策略的氨 TJI 发动机充分利用有限的氢气提供了指导。
{"title":"Effect of ammonia reforming on combustion and emission characteristics of a 4-valve engine with an active pre-chamber","authors":"Lin Chen ,&nbsp;Fangjia Yan ,&nbsp;Ren Zhang ,&nbsp;Haiqiao Wei ,&nbsp;Jiaying Pan","doi":"10.1016/j.joei.2024.101861","DOIUrl":"10.1016/j.joei.2024.101861","url":null,"abstract":"<div><div>Ammonia (NH<sub>3</sub>), as a hydrogen carrier and carbon-free fuel, offers an attractive opportunity for engines to achieve carbon neutrality. Turbulent jet ignition (TJI) combined with ammonia reforming shows the great capacity in ammonia-fueled engines. In this study, the effects of reforming strategy in an ammonia-fueled TJI are numerically studied, addressing the reforming ratio and reforming region. The results show that when only using reformate in the pre-chamber, the promoting effect of jet flame is more effective on the initial combustion phase. There are still very high NH<sub>3</sub> emissions due to the low reactivity in the main chamber. Further using reformate both in the pre-chamber and the main chamber, all the combustion stages (ST-CA10, CA10-50, CA50-90) can be shortened almost linearly with the increase of reforming ratio. Besides, the unburned NH<sub>3</sub> can be reduced to an acceptable level when the reforming ratio reaches 200 ‰ (hydrogen energy ratio of 18.50 %). The main reason is that the jet-induced strong flow field is coincident with the whole combustion stage. Further increasing the reforming ratio (pure hydrogen) in the pre-chamber, a high combustion efficiency and acceptable NH<sub>3</sub> emission can be achieved at a low hydrogen energy ratio (7.08 %). However, knocking combustion will happen at high reforming ratio with a low knock intensity. The results can provide some guidance for making the best-promoting benefit of the limited hydrogen in ammonia TJI engines with different reforming strategies.</div></div>","PeriodicalId":17287,"journal":{"name":"Journal of The Energy Institute","volume":"117 ","pages":"Article 101861"},"PeriodicalIF":5.6,"publicationDate":"2024-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142536062","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Desulfurization of pyrolytic oils from waste tire pyrolysis in a fluidized bed reactor with boron nitride adsorbents 利用氮化硼吸附剂在流化床反应器中对废轮胎热解产生的热解油进行脱硫
IF 5.6 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-10-16 DOI: 10.1016/j.joei.2024.101862
Rukan Can Seyfeli , Abdülvahap Çakmak , Esma Yeliz Kaya , Selim Ceylan
The study focused on producing hexagonal boron nitride (hBN) as an adsorbent which provides high efficiency in desulfurization processes. The synthesized hBN is used for sulfur removal from liquid fuel derived from end-of-life tires (ELTs). Characterization of hBN was performed using FTIR, XRD, TGA, and SEM-EDS analyses. Liquid fuel was produced in a fluidized bed reactor at 550 °C under a nitrogen gas flow. Post-desulfurization, the fuel's density, water content, and calorific value increased, while sulfur content and flash point decreased, with sulfur content showing a significant reduction of 79.23 %. The desulfurized fuel (PS-A) exhibited better combustion characteristics and closely resembled diesel fuel performance, though it slightly reduced engine effective efficiency by 1.06 % compared to diesel. Both PS-A and pre-desulfurized fuel (PS-B) significantly reduced soot emissions by 23.28 % and 20.81 %, respectively, compared to diesel. Additionally, CO emissions were lower for PS-A and PS-B, with reductions of 4.35 % and 2.00 %, respectively. However, CO2 emissions increased by 1.60 % for PS-A and 0.86 % for PS-B, attributed to higher fuel consumption. Overall, hBN effectively reduced sulfur content and improved several fuel properties of pyrolytic liquids. The study highlights the environmental and economic benefits of enhancing ELT-derived liquid fuels and suggests potential applications in real systems, serving as a foundation for new technologies and projects.
这项研究的重点是生产六方氮化硼(hBN)作为一种吸附剂,它在脱硫过程中具有很高的效率。合成的 hBN 用于从报废轮胎(ELT)中提取的液体燃料中脱硫。利用傅立叶变换红外光谱、XRD、TGA 和 SEM-EDS 分析对 hBN 进行了表征。液体燃料是在流化床反应器中于 550 °C 氮气流下生产的。脱硫后,燃料的密度、含水量和热值增加,而硫含量和闪点降低,其中硫含量显著降低了 79.23%。脱硫燃料(PS-A)的燃烧特性更好,与柴油的性能非常接近,但与柴油相比,发动机的有效效率略微降低了 1.06%。与柴油相比,PS-A 和预脱硫燃料(PS-B)分别显著减少了 23.28% 和 20.81% 的烟尘排放。此外,PS-A 和 PS-B 的二氧化碳排放量也较低,分别减少了 4.35 % 和 2.00 %。然而,由于燃料消耗量增加,PS-A 和 PS-B 的二氧化碳排放量分别增加了 1.60 % 和 0.86 %。总之,hBN 有效降低了硫含量,并改善了热解液的多项燃料特性。该研究强调了提高 ELT 衍生液体燃料的环境和经济效益,并提出了在实际系统中的潜在应用,为新技术和新项目奠定了基础。
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引用次数: 0
Synergistic effects of multi-walled carbon nanotubes and Mn0.4Cu0.6Fe2O4 on mercury removal with high efficiency and sulfur resistance 多壁碳纳米管和 Mn0.4Cu0.6Fe2O4 在高效脱汞和抗硫方面的协同效应
IF 5.6 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-10-16 DOI: 10.1016/j.joei.2024.101863
Bo Xu , Wan-Yuan Shi , Lin Feng , Wan Sun , Liang-Ming Pan
Although ferrite-based adsorbents are the potential mercury removal materials for the high thermal stability, they usually suffer from a low efficiency in flue gas environment, especially under SO2 condition. In the present paper, the multi-walled carbon nanotubes (MWCNTs) are utilized to improve the adsorption capacity of the Mn0.4Cu0.6Fe2O4 adsorbents as well as inhibit the influence of flue gas composition. The influences of temperature, adsorbent type and the flue gas composition on Hg0 removal efficiency are evaluated by experiments. The physical adsorption property of MWCNTs provides a platform for Hg0 oxidation by Mn0.4Cu0.6Fe2O4. The synergistic effect between MWCNTs and Mn0.4Cu0.6Fe2O4 enhances the mercury removal efficiency as well we the sulfur resistance. The results find that the adsorbent of Mn0.4Cu0.6Fe2O4 containing 14 % MWCNTs has a high mercury removal efficiency of 95.6 % at 120 °C even under 1000 ppm SO2 concentration. The kinetic behaviors of adsorbent adsorption are analyzed by theoretical models. The mechanisms of porous carbon-containing modifier to improve the mercury removal performance of Mn0.4Cu0.6Fe2O4 are explored carefully. The present ferrite-based adsorbent exhibits promising prospects for the practical industrial applications of the low temperature mercury removal from coal-fired flue gas.
虽然亚铁基吸附剂具有较高的热稳定性,是一种潜在的脱汞材料,但它们在烟气环境中通常效率较低,尤其是在二氧化硫条件下。本文利用多壁碳纳米管(MWCNTs)来提高 Mn0.4Cu0.6Fe2O4 吸附剂的吸附能力,并抑制烟气成分的影响。实验评估了温度、吸附剂类型和烟气成分对 Hg0 去除效率的影响。MWCNTs 的物理吸附特性为 Mn0.4Cu0.6Fe2O4 氧化 Hg0 提供了一个平台。MWCNTs 与 Mn0.4Cu0.6Fe2O4 的协同效应提高了汞的去除效率和抗硫能力。结果发现,含有 14% MWCNTs 的 Mn0.4Cu0.6Fe2O4 吸附剂在 120 °C、1000 ppm 二氧化硫浓度条件下的汞去除率高达 95.6%。理论模型分析了吸附剂吸附的动力学行为。仔细探讨了多孔碳改性剂改善 Mn0.4Cu0.6Fe2O4 汞去除性能的机理。该铁氧体基吸附剂在燃煤烟气低温脱汞的实际工业应用中具有广阔的前景。
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引用次数: 0
Effect of Cu incorporation on Fe-based catalysts for selective CO2 hydrogenation to olefins 铜掺入对选择性二氧化碳加氢制烯烃的铁基催化剂的影响
IF 5.6 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-10-05 DOI: 10.1016/j.joei.2024.101849
Basiru O. Yusuf , Ijaz Hussain , Mustapha Umar , Aliyu M. Alhassan , Chennampilly Ummer Aniz , Khalid R. Alhooshani , Syed A. Ali , Babar Ali , Saheed A. Ganiyu
The process of converting CO2 into sustainable chemical feedstock and fuels through reaction with renewable hydrogen has been regarded as a promising direction in energy research. The enhancement of CO2 hydrogenation efficiency to produce valuable hydrocarbons (specifically olefins) on Fe catalysts through Cu modification has been extensively researched. However, there is ongoing vigorous debate regarding the impact of these modifications on catalytic properties and the underlying mechanism. When compared to unprompted iron-based catalysts for CO2 hydrogenation, the choice of desired products, such as C2-C4 and C5+, is relatively low. So, promoters are frequently employed to customize and enhance product distribution. This study investigates how adding Cu to Fe-based supported catalysts affects their performance in converting CO2 to hydrocarbons, with a specific emphasis on the interaction between Fe and Cu. To achieve this goal, catalysts were created using co-precipitation methods, varying the distribution of Fe and Cu within them. A set of composite catalysts underwent testing in a fixed bed setup using a reactant gas mixture at 350 °C and 30 bar pressure. Analysis techniques such as XRD, SEM, TEM, NH3-TPD, H2-TPR, and N2 adsorption-desorption isotherms revealed the presence of iron-copper interaction within the composite catalysts. This interaction between the two components synergistically enhances the catalytic activity in CO2 hydrogenation.
通过与可再生氢气反应将二氧化碳转化为可持续化学原料和燃料的过程一直被视为能源研究中一个前景广阔的方向。在铁催化剂上通过铜改性提高 CO2 加氢效率以生产有价值的碳氢化合物(特别是烯烃)已得到广泛研究。然而,关于这些改性对催化特性的影响及其内在机理的争论仍在继续。与用于 CO2 加氢的未催化铁基催化剂相比,C2-C4 和 C5+ 等所需产物的选择相对较少。因此,经常使用促进剂来定制和增强产物分布。本研究探讨了在铁基支撑催化剂中添加 Cu 如何影响其将 CO2 转化为碳氢化合物的性能,并特别强调了铁和 Cu 之间的相互作用。为实现这一目标,研究人员采用共沉淀方法制造催化剂,并改变其中铁和铜的分布。在 350 °C 和 30 bar 压力下,使用反应物气体混合物在固定床装置中对一组复合催化剂进行了测试。XRD、SEM、TEM、NH3-TPD、H2-TPR 和 N2 吸附-解吸等温线等分析技术显示,复合催化剂中存在铁-铜相互作用。这两种成分之间的相互作用协同增强了二氧化碳加氢的催化活性。
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引用次数: 0
CoCe composite catalyst for CO2 hydrogenation: Effect of pore structure 用于二氧化碳加氢的 CoCe 复合催化剂:孔结构的影响
IF 5.6 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-10-05 DOI: 10.1016/j.joei.2024.101856
Guilin Zhou , Liying Xie , Fengqiong Xie , Shuang Chen , Jia Zeng , Hongmei Xie
In order to realize the dual carbon goals of “carbon peaking” and “carbon neutrality”, the design and development CO2 hydrogenation catalyst with high performances is of great significance. In this study, the CoCe composite catalysts were prepared by different methods and used to CO2 catalytic hydrogenation. The physicochemical properties of the prepared catalysts were characterized by XRD, BET, TEM/HRTEM, and H2-TPD. The characterization results indicated that the studied CoCe composite catalytsts with different pore structure can be prepared by different preparation methods. The suitable preparation method can promote Co species to be dissolved into the CeO2 lattice to form Ce-O-Co solid solution, which can promote the corresponding Co species to be reduced by H2 to form active Co0 species. The large specific surface area and developed ordered mesoporous structure of the CoCe-HT catalyst precursor, which was prepared by hard-template method, are conducive to the formation of active Co0 species and activation of H2 to produce reactive H species. The CO2 hydrogenation activity of the studied CoCe composite catalysts follows the following order: CoCe-HT > CoCe-CP > CoCe-CA > CoCe-HY. The CoCe-HT catalyst showed high CO2 hydrogenation conversion of 53.9 % and good using stability at 360 °C for 600 min. However, the CoCe-CA prepared by complex method has a poor use stability.
为了实现 "碳调峰 "和 "碳中和 "的双碳目标,设计和开发高性能的二氧化碳加氢催化剂具有重要意义。本研究采用不同方法制备了 CoCe 复合催化剂,并将其用于 CO2 催化加氢。通过 XRD、BET、TEM/HRTEM 和 H2-TPD 对所制备催化剂的理化性质进行了表征。表征结果表明,所研究的不同孔结构的 CoCe 复合催化剂可通过不同的制备方法制备。合适的制备方法可以促进 Co 物种溶解到 CeO2 晶格中形成 Ce-O-Co 固溶体,从而促进相应的 Co 物种被 H2 还原形成活性 Co0 物种。硬模板法制备的 CoCe-HT 催化剂前驱体具有较大的比表面积和发达的有序介孔结构,有利于形成活性 Co0 物种并活化 H2 生成活性 H 物种。所研究的 CoCe 复合催化剂的 CO2 加氢活性按以下顺序排列:CoCe-HT;CoCe-CP;CoCe-CA;CoCe-HY。CoCe-HT 催化剂的二氧化碳加氢转化率高达 53.9%,在 360 °C 下 600 分钟的使用稳定性良好。然而,用复合方法制备的 CoCe-CA 的使用稳定性较差。
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引用次数: 0
Fuel consumption and exhaust emissions from Euro 6d vehicles fueled by innovative LPG/DME blend 以创新型液化石油气/二甲醚混合物为燃料的欧 6d 车辆的燃料消耗量和尾气排放量
IF 5.6 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-10-05 DOI: 10.1016/j.joei.2024.101851
T. Rossi , S. Lixi , S. Puricelli , M. Grosso , D. Faedo , S. Casadei
The aim of this research was to investigate the exhaust emissions from vehicles when fueled by a new and fully renewable fuel if made of bio-LPG and renewable dimethyl ether (DME), in comparison with standard gasoline. For this purpose, DME was mixed with liquefied petroleum gas (LPG) and used to fuel three bi-fuel LPG/gasoline spark-ignition engines light-duty vehicles. The suitable fuel blend was selected based on several octane tests using CFR engines. Exhaust emissions were tested over the WLTC and over the hot-start CADC cycles, as well as on the road. All Euro 6 standards were well fully met over the WLTC with both fuels. Switching from gasoline to LPG/DME fueling, the CO and NOx emission factors increased for two vehicles, whereas THC and NMHC decreased. Regarding particulates, for two vehicles the emission factors decreased, too. Generally, when the vehicles were driven on the CADC, lower gaseous emissions were observed compared to WLTC: excluding one vehicle, when switching from gasoline to LPG/DME fueling, the overall emission profiles reflected those of the same vehicles run on the WLTC. The unregulated particulate emissions measured over both testing cycles reflect what was detected for the regulated ones. Except for PN10, which was not measured, all regulated emissions were found to meet the (most severe) Euro 7 standards proposed at first by the European Commission. RDE tests showed that all vehicle emissions obtained from on-road tests were also found to meet the RDE standards, regardless of the fueling. Concerning CO2 emissions, LPG/DME fueling guaranteed a systematic decrease for all vehicles and cycles, both on road and in the laboratory. The present investigation aims at demonstrating that the innovative LPG/DME 80 %/20 % (m/m) blend not only can be deemed as potentially suitable for GHG emissions reduction, as long as both DME and propane are obtained from renewable sources, but even compliant with EN 589 and both Euro 6 and part of preliminary Euro 7 exhaust emission proposal.
这项研究的目的是调查车辆在使用由生物液化石油气和可再生二甲醚(DME)制成的新型完全可再生燃料时的尾气排放情况,并与标准汽油进行比较。为此,将二甲醚与液化石油气(LPG)混合,用于为三辆双燃料 LPG/ 汽油火花点火发动机轻型汽车提供燃料。根据使用 CFR 发动机进行的辛烷值测试,选择了合适的混合燃料。对废气排放进行了 WLTC 和热启动 CADC 循环测试以及道路测试。两种燃料在 WLTC 循环中均完全符合所有欧 6 标准。从汽油改用液化石油气/二甲醚燃料后,两辆车的一氧化碳和氮氧化物排放系数增加,而四氢大麻酚和非甲烷总烃则减少。在微粒方面,两辆车的排放系数也有所下降。一般来说,当车辆在 CADC 上行驶时,观察到的气体排放量低于 WLTC:除一辆车外,当从汽油燃料切换到 LPG/DME 燃料时,总体排放曲线反映了相同车辆在 WLTC 上行驶时的排放曲线。在两个测试周期中测得的非规范颗粒物排放反映了规范颗粒物的检测结果。除了未测量的 PN10 外,所有受管制的排放物均符合欧盟委员会最初提出的(最严格的)欧 7 标准。RDE 测试表明,无论使用何种燃料,从道路测试中获得的所有车辆排放也都符合 RDE 标准。在二氧化碳排放量方面,无论是在道路上还是在实验室中,液化石油气/二甲醚燃料都能保证所有车辆和循环的二氧化碳排放量都有系统地减少。本次调查旨在证明,只要二甲醚和丙烷都来自可再生资源,创新的液化石油气/二甲醚混合燃料(80%/20% (m/m))不仅可被视为减少温室气体排放的潜在选择,甚至还符合 EN 589 标准以及欧 6 和部分初步欧 7 废气排放建议。
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引用次数: 0
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Journal of The Energy Institute
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